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17 pages, 3043 KB  
Article
3D Effects on the Stability of Upstream-Raised Tailings Dams in Narrow Valleys
by Raul Conceição, Gonçalo Ferreira, Henrique Lopes and João Camões Lourenço
Infrastructures 2025, 10(10), 277; https://doi.org/10.3390/infrastructures10100277 - 15 Oct 2025
Viewed by 305
Abstract
Tailings dams are unique structures due to the materials they store and the methods applied in their construction, often resulting in complex three-dimensional (3D) problems. Most current slope-stability analyses neglect the 3D effects without significant consequences. However, certain conditions, such as the valley [...] Read more.
Tailings dams are unique structures due to the materials they store and the methods applied in their construction, often resulting in complex three-dimensional (3D) problems. Most current slope-stability analyses neglect the 3D effects without significant consequences. However, certain conditions, such as the valley shape, the spatial variability of the tailings’ resistance, and the presence of internal dikes, may render the 2D simplification inadequate. For translational slides, the sliding-mass width-to-height ratio (W/H) is a reliable estimator of the 3D effects. However, it is unclear whether this geometric ratio is the most suitable for rotational slides, where the width of the sliding mass varies along its height. This paper presents a parametric study of the 3D effects of the dam’s height (HM) and the valley shape, namely the abutments’ slope angle with the horizontal (β) and the thalweg width (LM), on the overall stability of a tailings dam raised by the upstream method, by means of 2D and 3D Limit Equilibrium (LE) analyses. The study evaluates the dam stability using a straightforward and practical methodology, specifically the FS3D to FS2D ratio (R3D/2D), to compare the results of the 3D and 2D analyses, adapting current state-of-the-art techniques originally for translational slides, focused on pre-defined, closed-form slip-surface geometry, to rotational ones where the main focus is the geometry of the whole structure as a physical constraint for the sliding mass. The results show that the model average width-to-height ratio (WM,avr/HM), developed in this study, may be a better estimator of the 3D effects for rotational slides than the W/H ratio. Full article
(This article belongs to the Special Issue Preserving Life Through Dams)
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12 pages, 2368 KB  
Article
Effect of Oblique Impact Angles on Fracture Patterns in Laminated Glass Plates Impacted by a 10 mm Steel Ball
by Sanghee Kim
Appl. Sci. 2025, 15(20), 10898; https://doi.org/10.3390/app152010898 - 10 Oct 2025
Viewed by 330
Abstract
Many studies have examined normal impacts on glass, but data on oblique impacts are limited, and, in particular, there is very limited experimental data on oblique impacts at various angles under consistent experimental conditions. Therefore, this study investigated fracture patterns of 5 mm [...] Read more.
Many studies have examined normal impacts on glass, but data on oblique impacts are limited, and, in particular, there is very limited experimental data on oblique impacts at various angles under consistent experimental conditions. Therefore, this study investigated fracture patterns of 5 mm thick low-emissivity (low-e) glass impacted by a 10 mm steel ball at velocities of 40 to 50 m/s at various oblique impact angles from 0° to 80°. Results showed that fracture patterns varied clearly with impact angle. Truncated cone fractures occurred in all specimens at 0° to 60°, while three of six specimens did not fracture at 80° because the normal energy dropped to below damage limit energy. Damage parameters normalized by kinetic energy showed that Cmax/KE and Cmin/KE remained stable at 5.7–6.4 and 4.9–5.3 mm/J from 0° to 45°, but dropped sharply to 0.7 and 0.6 mm/J at 80°. The aspect ratio of cone cracks remained relatively constant (1.2–1.3) regardless of oblique impact angle, while the aspect ratio of perforated holes increased from 1.0 (0°) to 1.6 (60°) before decreasing at 80°. Steel ball size comparison confirmed that normalized damage patterns are not significantly affected by projectile size variations. Mechanism-based analysis revealed that cone cracks and perforated holes are governed by fundamentally different physical processes. Cone cracks form through axisymmetric stress fields following Hertzian contact theory, showing limited angular sensitivity (15.4% maximum eccentricity change). In contrast, perforated holes result from trajectory-dependent mechanical penetration, exhibiting extreme angular sensitivity with 338.9% eccentricity increase from 0° to 60°. This 22-fold difference demonstrates a dual damage mechanism framework that explains the pronounced angular dependence of hole geometry versus the relative stability of cone crack patterns. These findings provide essential data for forensic glass analysis and impact-resistant glazing design, while the dual mechanism concept offers new insights into angle-dependent fracture behavior of brittle materials. Full article
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20 pages, 8941 KB  
Article
Transient Stability Enhancement of a PMSG-Based System by Saturated Current Angle Control
by Huan Li, Tongpeng Mu, Yufei Zhang, Duhai Wu, Yujun Li and Zhengchun Du
Appl. Sci. 2025, 15(20), 10861; https://doi.org/10.3390/app152010861 - 10 Oct 2025
Viewed by 312
Abstract
This paper investigates the transient stability of Grid-Forming (GFM) Permanent Magnet Synchronous Generator (PMSG) systems during grid faults. An analysis demonstrates how a fixed saturated current angle can trap the system in undesirable operating points, while reactive power coupling can degrade performance. Both [...] Read more.
This paper investigates the transient stability of Grid-Forming (GFM) Permanent Magnet Synchronous Generator (PMSG) systems during grid faults. An analysis demonstrates how a fixed saturated current angle can trap the system in undesirable operating points, while reactive power coupling can degrade performance. Both factors pose a risk of turbine overspeed and instability. To overcome these vulnerabilities, a dual-mechanism control strategy is proposed, featuring an adaptive saturated current angle control that, unlike conventional fixed-angle methods, which risk creating Current Limiting Control (CLC) equilibrium points, dynamically aligns the current vector with the grid voltage to guarantee a stable post-fault trajectory. The effectiveness of the proposed strategy is validated through time-domain simulations in MATLAB/Simulink. The results show that the proposed control not only prevents overspeed trip failures seen in conventional methods but also reduces post-fault recovery time by over 60% and significantly improves system damping, ensuring robust fault ride-through and enhancing overall system stability. Full article
(This article belongs to the Section Applied Physics General)
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18 pages, 3996 KB  
Article
Electropolymerization of 5-Indolylboronic Acid: Morphological, Spectroscopic, and Electrochemical Characterization with Perspective Toward Functional Applications
by Danilo Ramos, María Jesús Aguirre and Francisco Armijo
Polymers 2025, 17(19), 2702; https://doi.org/10.3390/polym17192702 - 8 Oct 2025
Viewed by 488
Abstract
Poly(5-indolylboronic acid) was synthesized electrochemically via cyclic voltammetry using various electrodes, including screen-printed carbon electrodes, glassy carbon electrodes, highly oriented pyrolytic graphite, and 304 stainless steel. This study provides a thorough analysis of the resulting conducting polymer’s electrochemical behavior, morphological and structural characteristics, [...] Read more.
Poly(5-indolylboronic acid) was synthesized electrochemically via cyclic voltammetry using various electrodes, including screen-printed carbon electrodes, glassy carbon electrodes, highly oriented pyrolytic graphite, and 304 stainless steel. This study provides a thorough analysis of the resulting conducting polymer’s electrochemical behavior, morphological and structural characteristics, and potential applications. The following techniques were employed: cyclic voltammetry, electrochemical impedance spectroscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, and field-emission scanning electron microscopy. The polymer exhibits pH-dependent redox activity within the pH range of 4–10, displaying Nernstian behavior and achieving a specific areal capacitance of 0.234 mF∙cm−2 on an SPCE electrode. This result highlights the electrode’s efficiency in terms of charge storage. Impedance data indicate that the modified electrodes demonstrate a substantial decrease in charge transfer resistance and improved interfacial conductivity compared to bare electrodes. Contact angle measurements show that the presence of boronic acid groups makes the polymer hydrophilic. However, when 5PIBA was incubated in the presence of molecules containing hydroxyl groups or certain proteins, such as casein, no adsorption was observed. This suggests limited interaction with functional groups such as amino, hydroxide, and carboxyl groups present in these molecules, indicating the potential application of the polymer in biocorrosion. 5PIBA forms homogeneous, stable, and electroactive coatings on various substrates, making it a promising and versatile material for electrochemical technologies, and paving the way for future functionalization strategies. Full article
(This article belongs to the Special Issue Advanced Electrically Conductive Polymers and Composites)
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29 pages, 9652 KB  
Article
Overcurrent Limiting Strategy for Grid-Forming Inverters Based on Current-Controlled VSG
by Alisher Askarov, Pavel Radko, Yuly Bay, Ivan Gusarov, Vagiz Kabirov, Pavel Ilyushin and Aleksey Suvorov
Mathematics 2025, 13(19), 3207; https://doi.org/10.3390/math13193207 - 7 Oct 2025
Viewed by 720
Abstract
A key direction of the development of modern power systems is the application of a continuously increasing number of grid-forming power converters to provide various system services. One of the possible strategies for the implementation of grid-forming control is a control algorithm based [...] Read more.
A key direction of the development of modern power systems is the application of a continuously increasing number of grid-forming power converters to provide various system services. One of the possible strategies for the implementation of grid-forming control is a control algorithm based on a virtual synchronous generator (VSG). However, at present, the problem of VSG operation under abnormal conditions associated with an increase in output current remains unsolved. Existing current saturation algorithms (CSAs) lead to the degradation of grid-forming properties during overcurrent limiting or reduce the possible range of current output. In this regard, this paper proposes to use the structure of modified current-controlled VSG (CC-VSG) instead of traditional voltage-controlled VSG. A current vector amplitude limiter is used to limit the output current in the CC-VSG structure. At the same time, the angle of the current reference vector continues to be regulated based on the emerging operating conditions due to the voltage feedback in the used VSG equations. The presented simulation results have shown that it was possible to achieve a wide operating range for the current phase from 0° to 180° in comparison with a traditional VSG algorithm. At the same time, the properties of the grid-forming inverter, such as power synchronization without phase-locked loop controller, voltage, and frequency control, are preserved. In addition, in order to avoid saturation of the voltage controller, it is proposed to use a simple algorithm of blocking and switching the reference signal from the setpoint to the current voltage level. Due to this structure, it was possible to prevent saturation of integrators in the control loops and to provide a guaranteed exit from the limiting mode. The results of adding this structure showed a five-second reduction in the overvoltage that occurs when it is absent. A comparison with conditional integration also showed that it prevented lock-up in the limiting mode. The results of experimental verification of the developed prototype of the inverter with CC-VSG control and CSA are also given, including a comparison with the serial model of the hybrid inverter. The results obtained showed that the developed algorithm excludes both the dead time and the load current loss when the external grid is disconnected. In addition, there is no tripping during overload, unlike a hybrid inverter. Full article
(This article belongs to the Special Issue Applied Mathematics and Intelligent Control in Electrical Engineering)
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12 pages, 2665 KB  
Article
Enhanced Transdermal Delivery via Electrospun PMMA Fiber Mats Incorporating Ibuprofen-Intercalated Layered Double Hydroxides
by Van Thi Thanh Tran, Shusei Yamashita, Hideaki Sano, Osamu Nakagoe, Shuji Tanabe and Kai Kamada
Ceramics 2025, 8(4), 124; https://doi.org/10.3390/ceramics8040124 - 4 Oct 2025
Viewed by 415
Abstract
This study reports the development of electrospun poly(methyl methacrylate) (PMMA) fiber mats incorporating ibuprofen (IBU)-intercalated layered double hydroxides (LDH) for enhanced transdermal drug delivery systems (TDDS). IBU, in its anionic form, was successfully intercalated into LDH, which possesses anion exchange capabilities, and subsequently [...] Read more.
This study reports the development of electrospun poly(methyl methacrylate) (PMMA) fiber mats incorporating ibuprofen (IBU)-intercalated layered double hydroxides (LDH) for enhanced transdermal drug delivery systems (TDDS). IBU, in its anionic form, was successfully intercalated into LDH, which possesses anion exchange capabilities, and subsequently embedded into PMMA fibers via electrospinning. In vitro drug release experiments demonstrated that UPMMA–LDH–IBU fibers exhibited significantly higher IBU release than PMMA–IBU controls. This enhancement was attributed to the improved hydrophilicity and water absorption imparted by the LDH, as confirmed by contact angle and water uptake measurements. Furthermore, artificial skin permeation tests revealed that the UPMMA–LDH–IBU fibers maintained comparable release rates to those observed during buffer immersion, indicating that the rate-limiting step was the diffusion of IBU within the fiber matrix rather than the interface with the skin or buffer. These findings highlight the critical role of LDH in modulating drug release behavior and suggest that UPMMA–LDH–IBU electrospun fiber mats offer a promising and efficient platform for advanced TDDS applications. Full article
(This article belongs to the Special Issue Ceramics Containing Active Molecules for Biomedical Applications)
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18 pages, 3387 KB  
Article
Machine Learning-Assisted Reconstruction of In-Cylinder Pressure in Internal Combustion Engines Under Unmeasured Operating Conditions
by Qiao Huang, Tianfang Xie and Jinlong Liu
Energies 2025, 18(19), 5235; https://doi.org/10.3390/en18195235 - 2 Oct 2025
Viewed by 386
Abstract
In-cylinder pressure provides critical insights for analyzing and optimizing combustion in internal combustion engines, yet its acquisition across the full operating space requires extensive testing, while physics-based models are computationally demanding. Machine learning (ML) offers an alternative, but its application to direct reconstruction [...] Read more.
In-cylinder pressure provides critical insights for analyzing and optimizing combustion in internal combustion engines, yet its acquisition across the full operating space requires extensive testing, while physics-based models are computationally demanding. Machine learning (ML) offers an alternative, but its application to direct reconstruction of full pressure traces remains limited. This study evaluates three strategies for reconstructing cylinder pressure under unmeasured operating conditions, establishing a machine learning-assisted framework that generates the complete pressure–crank angle (P–CA) trace. The framework treats crank angle and operating conditions as inputs and predicts either pressure directly or apparent heat release rate (HRR) as an intermediate variable, which is then integrated to reconstruct pressure. In all approaches, discrete pointwise predictions are combined to form the full P–CA curve. Direct pressure prediction achieves high accuracy for overall traces but underestimates HRR-related combustion features. Training on HRR improves combustion representation but introduces baseline shifts in reconstructed pressure. A hybrid approach, combining non-combustion pressure prediction with combustion-phase HRR-based reconstruction delivers the most robust and physically consistent results. These findings demonstrate that ML can efficiently reconstruct in-cylinder pressure at unmeasured conditions, reducing experimental requirements while supporting combustion diagnostics, calibration, and digital twin applications. Full article
(This article belongs to the Section I2: Energy and Combustion Science)
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41 pages, 2987 KB  
Review
Coordinated Optimization of Building Morphological Parameters Under Urban Wind Energy Targets: A Review
by Yingwen Qin and Biao Wang
Energies 2025, 18(18), 5002; https://doi.org/10.3390/en18185002 - 20 Sep 2025
Viewed by 613
Abstract
Against the backdrop of global energy crises and accelerated urbanization, urban wind energy has garnered increasing attention through its integration with building environments. This study investigates the synergistic optimization of architectural parameters (including floor layouts, three-dimensional forms, and roof configurations) with wind capture [...] Read more.
Against the backdrop of global energy crises and accelerated urbanization, urban wind energy has garnered increasing attention through its integration with building environments. This study investigates the synergistic optimization of architectural parameters (including floor layouts, three-dimensional forms, and roof configurations) with wind capture efficiency. By employing parameterized design and multi-scale flow field analysis, we systematically examine how architectural morphology modulates wind fields and enhances energy performance. Our key findings reveal the following: spatially arranged floor plans significantly influence wind speed distribution; three-dimensional form openings effectively enhance wind velocity while reducing wind-induced vibration responses; and roof configurations and floor layouts demonstrate the highest contribution to wind energy efficiency, with curved roofs showing particularly notable power generation improvements in low-wind environments. The building “density + layout angle + roof form” collaborative strategy has been validated for practical implementation. Current limitations include simulation errors in complex geometries, efficiency bottlenecks in vertical axis turbines, and inadequate lifecycle assessments. Future efforts should focus on multi-field coupled simulations, integrated turbine–architecture design, and enhanced low-carbon evaluation systems to facilitate the transformation of buildings into distributed energy production entities. Full article
(This article belongs to the Section G: Energy and Buildings)
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24 pages, 12807 KB  
Article
Oriented-Attachment-Driven Heteroepitaxial Growth During Early Coalescence of Single-Crystal Diamond on Iridium: A Combined Multiscale Simulation and Experimental Validation
by Yang Wang, Junhao Chen, Zhe Li, Shilin Yang and Jiaqi Zhu
Crystals 2025, 15(9), 803; https://doi.org/10.3390/cryst15090803 - 12 Sep 2025
Viewed by 747
Abstract
The scalable synthesis of high-quality single-crystal diamond films remains pivotal for next-generation extreme-performance devices. Iridium substrates offer exceptional promise for heteroepitaxy, yet early-stage growth mechanisms limiting crystal quality are poorly understood. An integrated multiscale investigation combining first-principles DFT calculations, molecular dynamics simulations, and [...] Read more.
The scalable synthesis of high-quality single-crystal diamond films remains pivotal for next-generation extreme-performance devices. Iridium substrates offer exceptional promise for heteroepitaxy, yet early-stage growth mechanisms limiting crystal quality are poorly understood. An integrated multiscale investigation combining first-principles DFT calculations, molecular dynamics simulations, and experimental validation is presented to resolve the oriented attachment process governing diamond growth on Ir(100). Robust interfacial bonding at the interface and optimal carbon coverage are revealed to provide thermodynamic driving forces for primary nucleation. A critical angular tolerance enabling defect-free coalescence through crystallographic realignment is identified by molecular dynamics. Concurrent nucleation growth pathways are experimentally confirmed through SEM, AFM, and Raman spectroscopy, where nascent crystallites undergo spontaneous orientational registry to form continuous epitaxial domains. Grain boundary annihilation is observed upon lattice rotation aligning adjacent grains below the critical angle. Crucially, intrinsic atomic steps are generated on the resultant coalesced layer, eliminating conventional etching requirements for homoepitaxial thickening. This work advances fundamental understanding of single-crystal diamond growth mechanisms, facilitating enhanced quality control for semiconductor device manufacturing and quantum applications. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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20 pages, 3921 KB  
Article
Design of an Experimental Teaching Platform for Flow-Around Structures and AI-Driven Modeling in Marine Engineering
by Hongyang Zhao, Bowen Zhao, Xu Liang and Qianbin Lin
J. Mar. Sci. Eng. 2025, 13(9), 1761; https://doi.org/10.3390/jmse13091761 - 11 Sep 2025
Viewed by 1809
Abstract
Flow past bluff bodies (e.g., circular cylinders) forms a canonical context for teaching external flow separation, vortex shedding, and the coupling between surface pressure and hydrodynamic forces in offshore engineering. Conventional laboratory implementations, however, often fragment local and global measurements, delay data feedback, [...] Read more.
Flow past bluff bodies (e.g., circular cylinders) forms a canonical context for teaching external flow separation, vortex shedding, and the coupling between surface pressure and hydrodynamic forces in offshore engineering. Conventional laboratory implementations, however, often fragment local and global measurements, delay data feedback, and omit intelligent modeling components, thereby limiting the development of higher-order cognitive skills and data literacy. We present a low-cost, modular, data-enabled instructional hydrodynamics platform that integrates a transparent recirculating water channel, multi-point synchronous circumferential pressure measurements, global force acquisition, and an artificial neural network (ANN) surrogate. Using feature vectors composed of Reynolds number, angle of attack, and submergence depth, we train a lightweight AI model for rapid prediction of drag and lift coefficients, closing a loop of measurement, prediction, deviation diagnosis, and feature refinement. In the subcritical Reynolds regime, the measured circumferential pressure distribution for a circular cylinder and the drag and lift coefficients for a rectangular cylinder agree with empirical correlations and published benchmarks. The ANN surrogate attains a mean absolute percentage error of approximately 4% for both drag and lift coefficients, indicating stable, physically interpretable performance under limited feature inputs. This platform will facilitate students’ cross-domain transfer spanning flow physics mechanisms, signal processing, feature engineering, and model evaluation, thereby enhancing inquiry-driven and critical analytical competencies. Key contributions include the following: (i) a synchronized local pressure and global force dataset architecture; (ii) embedding a physics-interpretable lightweight ANN surrogate in a foundational hydrodynamics experiment; and (iii) an error-tracking, iteration-oriented instructional workflow. The platform provides a replicable pathway for transitioning offshore hydrodynamics laboratories toward an integrated intelligence-plus-data literacy paradigm and establishes a foundation for future extensions to higher Reynolds numbers, multiple body geometries, and physics-constrained neural networks. Full article
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22 pages, 6551 KB  
Article
A Coupled SVM-NODE Model for Efficient Prediction of Ship Roll Motion
by Yaxiong Zheng, Fei Peng, Zhanzhi Wang and Siwen Tian
J. Mar. Sci. Eng. 2025, 13(9), 1750; https://doi.org/10.3390/jmse13091750 - 10 Sep 2025
Viewed by 316
Abstract
Traditional analyses of ship roll damping and added moment of inertia rely on free roll decay and forced roll tests, but acquiring linear (small angles) and nonlinear (large angles) relationships demands extensive computational cases and parameter fitting, limiting efficiency. To address this, this [...] Read more.
Traditional analyses of ship roll damping and added moment of inertia rely on free roll decay and forced roll tests, but acquiring linear (small angles) and nonlinear (large angles) relationships demands extensive computational cases and parameter fitting, limiting efficiency. To address this, this study couples Support Vector Machine (SVM) and Neural Ordinary Differential Equation (NODE) networks: SVM solves for added moment of inertia, linear damping, and nonlinear damping, while NODE constructs a complete model for the roll motion equation. Using the DTMB5415 hull form, Computational Fluid Dynamics (CFD) simulations of forced roll build a “time-angle-moment” sample space, and the coupled model learns and predicts free roll decay under different initial angles. The results show that SVM effectively determines roll damping and added moment of inertia from constant-amplitude variable-frequency and constant-frequency variable-amplitude data, reducing required cases significantly. NODE’s simulation of free roll decay validates coefficient accuracy. Within a certain angle range, the SVM-NODE model meets rapid roll motion analysis needs, providing an innovative method for ship roll research and engineering. Full article
(This article belongs to the Section Ocean Engineering)
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16 pages, 4967 KB  
Article
Topology Optimization of Polymer-Based Bending Tools Manufactured via Additive Technology: Numerical and Experimental Validation
by Luca Giorleo and Kudret Irem Deniz
J. Manuf. Mater. Process. 2025, 9(9), 310; https://doi.org/10.3390/jmmp9090310 - 9 Sep 2025
Viewed by 529
Abstract
Sheet metal forming is a widely used manufacturing process, but the high cost and long production time of traditional forming tools limit its flexibility, especially for prototyping and small-batch production. Additive manufacturing offers a promising alternative, enabling the rapid and cost-effective fabrication of [...] Read more.
Sheet metal forming is a widely used manufacturing process, but the high cost and long production time of traditional forming tools limit its flexibility, especially for prototyping and small-batch production. Additive manufacturing offers a promising alternative, enabling the rapid and cost-effective fabrication of customized tools. In this study, bending tools were produced using Fused Filament Fabrication and optimized through a topology optimization approach. A combined experimental and numerical approach was applied to validate standard tool geometries and extract load conditions for use in a topology optimization process. The resulting optimized punch and die achieved a mass reduction of approximately 50% while maintaining structural integrity and safety factors well above critical thresholds. Finite Element Analysis revealed an increase in elastic deformation and stress concentration in non-critical regions, without compromising tool functionality. Experimental tests with the optimized tools confirmed their suitability for sheet metal bending, although a decrease of about 2° in the bending angle and an increase in variability were observed, consistent with simulation results. The study demonstrates the feasibility of using topology-optimized polymer tools for low-volume forming applications, offering a lightweight, cost-effective, and sustainable alternative to traditional metal tooling. Full article
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23 pages, 30393 KB  
Article
An Acid-Cleavable Lamellar Block Copolymer for Sub-30-nm Line Spacing Patterning via Graphoepitaxial Directed Self-Assembly and Direct Wet Etching
by Jianghao Zhan, Caiwei Shang, Muqiao Niu, Jiacheng Luo, Shengguang Gao, Zhiyong Wu, Shengru Niu, Yiming Xu, Xingmiao Zhang, Zili Li and Shisheng Xiong
Polymers 2025, 17(18), 2435; https://doi.org/10.3390/polym17182435 - 9 Sep 2025
Cited by 1 | Viewed by 1282
Abstract
Graphoepitaxial directed self-assembly (DSA) of block copolymers (BCPs) has emerged as a promising strategy for sub-30 nm line spacing patterning in semiconductor nanofabrication. Among the available BCP systems, polystyrene-block-poly (methyl methacrylate) (PS-b-PMMA) has been extensively utilized due to its well-characterized phase [...] Read more.
Graphoepitaxial directed self-assembly (DSA) of block copolymers (BCPs) has emerged as a promising strategy for sub-30 nm line spacing patterning in semiconductor nanofabrication. Among the available BCP systems, polystyrene-block-poly (methyl methacrylate) (PS-b-PMMA) has been extensively utilized due to its well-characterized phase behavior and compatibility with standard lithographic processes. However, achieving a high-fidelity pattern with PS-b-PMMA remains challenging, owing to its limited etch contrast and reliance on UV-assisted degradation for PMMA removal. In this study, we report the synthesis of an acid-cleavable lamellar BCP, PS-N=CH-PMMA, incorporating a dynamic Schiff base (-N=CH-) linkage at the junction. This functional design enables UV-free wet etching, allowing selective removal of PMMA domains using glacial acetic acid. The synthesized copolymers retain the self-assembly characteristics of PS-b-PMMA and form vertically aligned lamellar nanostructures, with domain spacings tunable from 36.1 to 40.2 nm by varying the PMMA block length. When confined within 193i-defined trench templates with a critical dimension (CD) of 55 nm (trench width), these materials produced well-ordered one-space-per-trench patterns with interline spacings tunable from 15 to 25 nm, demonstrating significant line spacing shrinkage relative to the original template CD. SEM and FIB-TEM analyses confirmed that PS-N=CH-PMMA exhibits markedly improved vertical etch profiles and reduced PMMA residue compared to PS-b-PMMA, even without UV exposure. Furthermore, Ohta–Kawasaki simulations revealed that trench sidewall angle critically influences PS distribution and residual morphology. Collectively, this work demonstrates the potential of dynamic covalent chemistry to enhance the wet development fidelity of BCP lithography and offers a thermally compatible, UV-free strategy for sub-30 nm nanopatterning. Full article
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16 pages, 4426 KB  
Article
Scalable Fabrication of Biomimetic Antibacterial Nanospikes on PMMA Films Using Atmospheric-Pressure Low-Temperature Plasma
by Masashi Yamamoto, Kentaro Tada, Ayumu Takada and Atsushi Sekiguchi
Biomimetics 2025, 10(9), 601; https://doi.org/10.3390/biomimetics10090601 - 8 Sep 2025
Viewed by 627
Abstract
Antibacterial surfaces inspired by biological micro- and nanostructures, such as those found on the wings of cicadas and dragonflies, have attracted interest due to their ability to inhibit bacterial adhesion and damage microbial membranes without relying on chemical agents. However, conventional fabrication techniques [...] Read more.
Antibacterial surfaces inspired by biological micro- and nanostructures, such as those found on the wings of cicadas and dragonflies, have attracted interest due to their ability to inhibit bacterial adhesion and damage microbial membranes without relying on chemical agents. However, conventional fabrication techniques like photolithography or nanoimprinting are limited by substrate shape, size, and high operational costs. In this study, we developed a scalable method using atmospheric-pressure low-temperature plasma (APLTP) to fabricate sharp-edged nanospikes on solvent-cast polymethyl methacrylate (PMMA) films. The nanospikes were formed through plasma-induced modification of pores in the film, followed by annealing to control surface wettability while maintaining structural sharpness. Atomic force microscopy confirmed the formation of micro/nanostructures, and contact angle measurements revealed reversible hydrophilicity. Antibacterial performance was evaluated against Escherichia coli using ISO 22196 standards. While the film with only plasma treatment reduced bacterial colonies by 30%, the film annealed after plasma treatment achieved an antibacterial activity value greater than 5, with bacterial counts below the detection limit (<10 CFU). These findings demonstrate that APLTP offers a practical route for large-area fabrication of biomimetic antibacterial coatings on flexible polymer substrates, holding promise for future applications in healthcare, packaging, and public hygiene. Full article
(This article belongs to the Section Biomimetic Surfaces and Interfaces)
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25 pages, 8643 KB  
Article
2D to 3D Modification of Chang–Chang Criterion Considering Multiaxial Coupling Effects in Fiber and Inter-Fiber Directions for Continuous Fiber-Reinforced Composites
by Yingchi Chen, Junhua Guo and Wantao Guo
Polymers 2025, 17(17), 2416; https://doi.org/10.3390/polym17172416 - 5 Sep 2025
Viewed by 736
Abstract
Fiber-reinforced composites are widely used in aerospace and other fields due to their excellent specific strength, specific stiffness, and corrosion resistance, and further study of their failure criteria is essential to improve the accuracy and reliability of failure behavior prediction under complex loads. [...] Read more.
Fiber-reinforced composites are widely used in aerospace and other fields due to their excellent specific strength, specific stiffness, and corrosion resistance, and further study of their failure criteria is essential to improve the accuracy and reliability of failure behavior prediction under complex loads. There are still some limitations in the current composite failure criterion research, mainly reflected in the lack of promotion of three-dimensional stress state, lack of sufficient consideration of multi-modal coupling effects, and the applicability of the criteria under multiaxial stress and complex loading conditions, which limit the wider application of composites in the leading-edge fields to a certain degree. In this work, a generalized Mohr failure envelope function approach is adopted to obtain the stress on the failure surface as a power series form of independent variable, and the unknown coefficients are determined according to the damage conditions, to extend the Chang–Chang criterion to the three-dimensional stress state, and to consider the coupling effect between the fiber and matrix failure modes. The modified Chang–Chang criterion significantly enhances the failure prediction accuracy of composite materials under complex stress states, especially in the range of multi-axial loading and small off-axis angles, which provides a more reliable theoretical basis and practical guidance for the safe design and performance optimization of composite structures in aerospace and other engineering fields. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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