Search Results (25)

The efficacy of water resource management and protection hinges on a profound understanding of the controlling factors and regulatory mechanisms that shape groundwater chemistry within aquifers. Despite this, our comprehension of how groundwater chemistry and ion sources vary across diverse aquifer types remained limited. To bridge this gap, our study conducted a detailed hydrochemical and statistical investigation of porous, fissured, and karst aquifers. By applying multivariate statistical techniques, including principal component analysis (PCA) and hierarchical cluster analysis (HCA), the hydrochemical characteristics and main ion sources of each aquifer type, as well as distinct controlling factors and regulation patterns, were determined. Notably, evaporation predominantly affected the hydrochemistry of porous aquifers, whereas mineral dissolution and rock weathering processes played a pivotal role in shaping the groundwater evolution of fissured and karst aquifers. HCO₃⁻ and SO₄²⁻ are the most common anions of all types, while Na⁺ is dominant in porous and fissured aquifers and Ca²⁺ is dominant in karst aquifers. The most common hydrochemical types identified were HCO₃-Ca·Mg (accounting for approximately 56.84%) and SO₄·Cl-Na (constituting approximately 21.75%). PCA results revealed that lateral recharge from fissured aquifers in hilly regions into the groundwater of porous aquifer, and wastewater discharge and agricultural fertilizer application, significantly impact the groundwater chemistry across all three aquifer types. It is worth noting that the dissolution of carbonate minerals, often influenced by human activities, had a profound effect on the hydrochemistry of each aquifer. Conversely, the dissolution of evaporitic minerals affected groundwater chemistry primarily through cation exchange processes. In summary, the hydrochemical characteristics of these aquifer types were predominantly shaped by a complex interplay of mineral dissolution, cation exchange, evaporation, and anthropogenic activities, with notable contributions from fissured aquifer recharge and pollution. These insights were critical for informing national-level strategies for groundwater resource protection and management. Full article

This study systematically unravels the hydrochemical evolution mechanisms and driving forces in multi-aquifer systems of Qingdao, a coastal economic hub. Integrated hydrochemical analysis of porous, fissured, and karst water, combined with PHREEQC modeling and Positive Matrix Factorization (PMF), deciphers water–rock interactions and anthropogenic perturbations. Groundwater exhibits weak alkalinity (pH 7.2–8.4), with porous aquifers showing markedly higher TDS (161.1–8203.5 mg/L) than fissured (147.7–1224.8 mg/L) and karst systems (361.1–4551.5 mg/L). Spatial heterogeneity reveals progressive hydrochemical transitions (HCO₃-Ca → SO₄-Ca·Mg → Cl-Na) in porous aquifers across the Dagu River Basin. While carbonate (calcite) and silicate weathering govern natural hydrochemistry, evaporite dissolution and seawater intrusion drive severe groundwater salinization in the western Pingdu City and the Dagu River Estuary (localized TDS up to 8203.5 mg/L). PMF source apportionment identifies acid deposition-enhanced dissolution of carbonate/silicate minerals, with nitrate contamination predominantly sourced from agricultural runoff and domestic sewage. Landfill leachate exerts pronounced impacts in Laixi and adjacent regions. This study offering actionable strategies for salinity mitigation and contaminant source regulation, thereby providing a scientific framework for sustainable groundwater management in rapidly urbanizing coastal zones. Full article

With the intensification of human activities, the water resource environment in the karst mountainous area of central Shandong has undergone significant changes, directly manifested in the cessation of karst spring flows and the occurrence of karst collapses within the spring basin in the Laiwu Basin. To support the scientific development and management of karst water, this study utilizes comprehensive analysis and deuterium-oxygen isotope test data from surveys and sampling of 20 typical karst springs conducted between 2016 and 2018. By integrating mathematical statistics, correlation analysis, and ion component ratio methods, the study analyzes the genesis, hydrochemical ion component sources, and controlling factors of typical karst springs in the Laiwu Basin. The results indicate that the genesis of karst springs in the Laiwu Basin is controlled by three factors: faults, rock masses, and lithology, and can be classified into four types: water resistance controlled by lithology, by faults, by basement, and by rock mass. The karst springs are generally weakly alkaline freshwater, with the main ion components being HCO₃⁻ and Ca²⁺, accounting for approximately 55.02% and 71.52% of the anion and cation components, respectively; about 50% of the sampling points have a hydrochemical type of HCO₃·SO₄-Ca·Mg. Stable isotope (δ¹⁸O and δD) results show that atmospheric precipitation is the primary recharge source for karst springs in the Laiwu Basin. There are varying degrees of evaporative fractionation and water–rock interaction during the groundwater flow process, resulting in significantly higher deuterium excess (d-excess) in the sampling points on the southern side of the basin compared to the northern side, indicating clear differentiation. The hydrochemical composition of the karst groundwater system is predominantly governed by water–rock interactions during flow processes and anthropogenic influences. Carbonate dissolution (primarily calcite) serves as the principal source of HCO₃⁻, SO₄²⁻, Ca²⁺, and Mg²⁺, while evaporite dissolution and reverse cation exchange contribute to the slight enrichment of Ca²⁺ and Mg²⁺ alongside depletion of Na⁺ and K⁺ in spring waters. Saturation indices (SI) reveal that spring waters are saturated with respect to gypsum, aragonite, calcite, and dolomite, but undersaturated for halite. The mixing of urban domestic sewage, agricultural planting activities, and the use of manure also contributes to the formation of Cl⁻ and NO₃⁻ ions in karst springs. Full article

Uncovering the characteristics of groundwater pollution and its driving mechanisms are crucial for maintaining its ecological functions. This study focuses on hydrochemical changes and their driving factors in groundwater from different aquifers in industrial zones, taking Zibo City, Shandong Province, China, as the research area. During the dry and flood seasons of 2022, samples of phreatic water in pore media (17 sites) and karst confined water (23 sites) were collected and monitored. Piper trilinear diagrams, Gibbs diagrams, ion ratio diagrams, and a principal component analysis (PCA) were used for in-depth analyses. Pore phreatic water had higher excess rates of Na⁺, Cl⁻, and NO₃⁻ than karst confined water, which indicated a greater degree of human impact compared with karst confined water. The main hydrochemical type was HCO₃·SO₄-Ca, but in the dry season, pore phreatic water shifted to HCO₃·SO₄·Cl-Ca. The ion ratios and PCA indicated that the groundwater quality was mainly controlled by water–rock interactions and industrial activities. In the flood season, pore phreatic water was influenced by evaporite dissolution, industrial activities, and domestic sewage, while in the dry season, it was affected by halite and carbonate weathering dissolution and domestic sewage. Karst confined water was controlled by water–rock interactions and industrial activities in both seasons. The findings reveal that the key drivers of groundwater quality displayed significant differences depending on the aquifer type and seasonal variations. As such, customized approaches are essential to efficiently address and counteract the decline in groundwater quality. Full article

Alcalá de Ebro is located 35 km northwest of the city of Zaragoza, on the right bank of the Ebro River at the outlet of a ravine (Juan Gastón) towards the river, with a catchment area of more than 230 km². Over time, urbanisation and agricultural development have eliminated the last stretch of the drainage channel, and these water inputs have been channelled underground, filtering through the ground. This section of the Ebro Valley rests on a marly tertiary substratum, which promotes dissolution-subbing processes that can lead to sinkholes. The ground tends to sink gradually or suddenly collapse. Many studies have been carried out to understand not only the origin of the phenomenon but also its geometry and the area affected by it in the town of Alcalá de Ebro. In this sense, it has been possible to model an area around the main access road, where numerous collapsing sinkholes have been found, blocking the road and affecting houses. It also affects the embankment that protects the town from the floods of the river Ebro. These studies have provided specific knowledge, enabling us to evaluate and implement underground consolidation measures, which have shown apparent success. Several injection campaigns have been carried out, initially with expansion resins and finally with columnar development, using special low-mobility mortars to fill and consolidate the undermined areas and prevent new subsidence. These technical solutions propose a method of ground treatment that we believe is novel for this type of geological process. The results have been satisfactory, but it is considered necessary to continue monitoring the situation and to extend attention to a wider area to prevent, as far as possible, new problems of subsidence and collapse. In this sense, the objective is to continue the control and monitoring of possible phenomena related to subsidence problems in the affected area and its immediate surroundings, to detect and, if necessary, anticipate subsidence or collapse phenomena that could affect the body of the embankment. Full article

Sinkholes can cause significant damage to infrastructures, agriculture, and endanger lives in active karst regions like the Dead Sea’s eastern shore at Ghor Al-Haditha. The common sinkhole mapping methods often require costly high-resolution data and manual, time-consuming expert analysis. This study introduces an efficient deep learning model designed to improve sinkhole mapping using accessible satellite imagery, which could enhance management practices related to sinkholes and other geohazards in evaporite karst regions. The developed AI system is centered around the U-Net architecture. The model was initially trained on a high-resolution drone dataset (0.1 m GSD, phase I), covering 250 sinkhole instances. Subsequently, it was additionally fine-tuned on a larger dataset from a Pleiades Neo satellite image (0.3 m GSD, phase II) with 1038 instances. The training process involved an automated image-processing workflow and strategic layer freezing and unfreezing to adapt the model to different input scales and resolutions. We show the usefulness of initial layer features learned on drone data, for the coarser, more readily-available satellite inputs. The validation revealed high detection accuracy for sinkholes, with phase I achieving a recall of 96.79% and an F1 score of 97.08%, and phase II reaching a recall of 92.06% and an F1 score of 91.23%. These results confirm the model’s accuracy and its capability to maintain high performance across varying resolutions. Our findings highlight the potential of using RGB visual bands for sinkhole detection across different karst environments. This approach provides a scalable, cost-effective solution for continuous mapping, monitoring, and risk mitigation related to sinkhole hazards. The developed system is not limited only to sinkholes however, and can be naturally extended to other geohazards as well. Moreover, since it currently uses U-Net as a backbone, the system can be extended to incorporate super-resolution techniques, leveraging U-Net based latent diffusion models to address the smaller-scale, ambiguous geo-structures that are often found in geoscientific data. Full article

In various areas of the Ebro valley in Spain, including the region discussed here, the risk of sinkholes is becoming particularly severe, particularly impacting urban areas and roadways where land subsidence from karstic processes is common. However, knowledge of the area, its geological–geotechnical configuration, and the carrying out of specific research studies are allowing solutions to be tested in an attempt to resolve these situations. A case in point is the examination of settlement issues along a stretch of the access road leading to the city of Gallur from the east (known as Camino Real) in the Zaragoza province, Spain. Numerous surface manifestations of recent subsidence and/or collapse activities have been observed, manifesting as craters and ground undercuts, some several meters in diameter. The prevalence of highly karstifiable materials in the area, evident from the existence of subsidence pockets and collapse dolines, poses significant safety concerns, particularly for traffic and town access, prompting the closure of Camino Real for several years. Local and provincial authorities have embarked on studies to try to recognise this type of situation. Reports aimed at defining karstification processes, conducting geomechanical analyses of subsidence and cavity collapses, and proposing technical measures to mitigate risks have been prepared. Finally, a consolidation solution was proposed based on injections at column-depth of mortar with special characteristics, combined with the replacement and reinforcement of the most superficial soil by means of high-tensile-strength geotextile meshes. Full article

To elucidate the hydrochemical characteristics, controlling factors, sources and mechanisms of strontium ion enrichment in groundwater in the northwest plain of Shandong Province, China, 88 groundwater samples were collected, including 51 shallow pore groundwater samples, 29 deep pore groundwater samples and 8 karst groundwater samples. The hydrochemical characteristics of the different types of groundwater were quite different. The karst groundwater samples were all fresh water with a single hydrochemical type, either HCO₃-Ca or HCO₃-Ca·Mg. The deep pore groundwater samples were mainly brackish water, and the shallow pore groundwater samples were brackish water–salt water, which has complex hydrochemical types. The hydrochemical characteristics of all the types of groundwater were controlled by mineral dissolution and active positive cation exchange. In shallow pore groundwater, deep pore groundwater and karst groundwater, the dissolution of silicate, evaporite and carbonate minerals dominated the hydrogeochemical process. The strontium in groundwater was derived from the dissolution of minerals with strontium isomorphism. The average contents of strontium in shallow, deep and karst groundwater were 1.59 mg/L, 0.58 mg/L and 0.50 mg/L, respectively. The strontium in shallow pore groundwater was mainly derived from the enrichment of groundwater runoff, and its sources are abundant, with silicic rock being the main source. The deep pore groundwater mainly derived from the evaporative minerals containing strontium, and the karst water mainly derived from carbonate rock dissolution with similar characteristics. Full article

Tropical coastal karst areas represent dynamic, fragile, and biodiverse environments. Central America’s karst regions have been scarcely studied, with most of the research focused on the northern part of the region and on several larger cave systems. The coastal carbonate zones of the Central American region represent a unique karstic landscape, which, so far, has been insufficiently studied. Therefore, in this paper, we aim to describe the (i) landscape geomorphology and (ii) chemical conditions that define Ciénega de El Mangle in Panama as a distinctive karstic site. Carried geomorphological mapping and the characterization of karstic features have resulted in the identification of the different karstic forms and processes that are present within this unique karstic area. Considering that the chosen karstic study area is located in a marine–coastal fringe on the periphery of a lagoon, it is affected by a combination of several factors and processes, including seawater intrusion (through sinkholes), the formation of conchiferous limestone (CaCO₃), and NaCl precipitation related to efflorescence. Due to the seasonally humid tropical climate, the chemical weathering processes are intense, thus forming alkaline soils that are hindering the development of mangrove vegetation. The geomorphology of the area results from intense evaporation combined with an influx of brackish groundwater, due to which a landscape has evolved in the marine–coastal strips, of seasonal tropical climates, that exhibit saline beaches, known as a littoral shott. In total, 24 karstic microdolines have evolved within the shott, of which six represent domical geoforms formed by gradual evaporitic precipitation, while seven other geoforms represent active karstic sinkholes filled with brackish water. These results are key for understanding the past and present climate interactions and conditions that have led to the formation of tropical karst environments. Full article

Springs provide ideal monitoring points for groundwater chemistry, which are important for managing groundwater resources. The chemistry of these spring waters aggregate geochemical reactions along the flow path. In this paper, part two of a two-part investigation, 104 perennial springs in the classic karst landscape of the Mitchell Plateau, Indiana, USA were sampled at base flow. Many of these springs are historically important for domestic, agricultural, commercial, and recreational use. Multifactor analysis of field measurements, principal ions, and stable isotopes revealed five primary clusters of springs emerging from the Mitchell Aquifer. Two clusters represented earth-alkaline-type karst groundwater that were discriminated by temperature and inorganic carbon concentration. Two other clusters comprised mineralized alkaline-earth-type groundwater with excess alkalis and elevated sulfate. The fifth cluster appeared to be groundwater that included meteoric and mineralized sources. Using the longitudinal data over two years from part one of this investigation, two mixing lines were used to describe the data set. The mixing lines pointed to sources of sulfur in mineralized springs from deep brines and from evaporite dissolution. Collectively, these regional data allow for a better delineation of water types and differentiation between the Upper and Lower Mitchell Aquifer. Full article

Carbonic acid and sulfuric acid speleogenesis describe a dichotomy between epigenetic and hypogenetic caves and carbon and sulfur cycling in karst, but do not acknowledge the global spectrum of cave formation. This paper, part one of a two-part investigation, tests and revises speleogenetic models from a classic karst landscape using dissolved ion concentrations δ¹³C_DIC, and δ³⁴S in water samples collected at four sites across the Bluespring and Lost River karst basins in the Mitchell Plateau, Indiana, USA. Analyses revealed elevated sulfur in both karst basins but differently sourced; H₂S (δ³⁴S = −14.2‰) evolved from petroleum seeps in Bluespring Caverns accounted for up to 61% of sulfur in the cave stream, while evaporite beds (δ³⁴S = [+14.50‰, +17.91‰]) of the St. Louis Limestone contributed up to 100% of sulfur at Orangeville Rise, a terminal spring of the Lost River karst basin. These results have implications for carbon–sulfur cycle linkages, particularly the potential acceleration of carbon flux from sulfuric acid dissolution in otherwise epigenetic settings. We suggest a new paradigm for speleogenesis in the North American midcontinent—speleogenesis in the Mitchell Plateau and similar settings is not epigenetic or hypogenetic, but instead polygenetic with competing chemical processes varying across space and time. Full article

Sinkholes are a severe problem in urban areas located in karstic regions, especially where evaporitic rocks such as gypsum exist. Identification and proposal of mitigation measures are needed to reduce this geo-hazard effect on buildings and social urban living. This paper presents a case study of the town of Alcalá de Ebro (Spain), which is located in the highest sinkhole risk region of Europe. The identification and mitigation of a series of sinkholes that appeared are analyzed. The former involves a geological investigation, including boreholes, field tests and geophysics. The latter is addressed by the use of geogrids, mortar injections and polyurethane injections. A complementary finite element analysis is carried out to set the ground behavior associated with the sinking process and assess its future evolution. The Ebro River appears to be the main cause of sinkholes, and results show that ground treatments applied were successful in their purpose, as there are no apparent deformations indicating that the subsidence or sinking process is still active in the area. The use of different techniques depending on the size of the sinkhole, the objectives pursued and the element affected is discussed. Full article

On the edge of sedimentary basins, karst aquifers can be fed by several water sources from both autogenic and allogenic recharge. In some cases, assessing water origins can be hard and cause some difficulties for water resource management. The main goal of this study is to show the implementation of the mobile sources mixing model approach. More precisely, this research develops how a monitoring method using a multi-proxy approach can be used to quantify waters sources contributions from several origins at the outlets of a karst system. The study site is the Ouysse karst system, located in western France. The site offers the opportunity to understand the mixing processes between allogenic and autogenic water recharges. The karst system covers a 650 km² watershed, and is fed by three different chemical facies: (i) Autogenic water from the direct infiltration on the karstified limestones with high HCO₃⁻ values (median: 436 mg.L⁻¹); (ii) Water coming from sinking rivers fed by spring coming from igneous rocks with low mineralization but relatively higher K⁺ values (median: 4.2 mg.L⁻¹); (iii) Highly mineralized water coming from deep evaporitic layers and feeding another sinking river with very high sulfate concentrations (median: 400 mg.L⁻¹). Sliding window cross-correlation analyses and hydrochemical analyses during a flood event are performed to implement a mobile source mixing model approach. This approach shows significant differences with a simple fixed source mixing model and appears more reliable but requires more time and money to carry out. The results and conclusion of this study will be used for forecasting and managing operational actions for resource management. Full article

Atmospheric CO₂ concentrations can reach high levels inside natural caves, representing a hazardous condition for both humans frequenting the underground environment and its safeguard due to the corrosion of speleothems induced by the acidification of atmospheric moisture. These issues are particularly critical for the eco-sustainable management of caves protected as nature reserves and undergoing touristic exploitation. In this paper we present the results of the C6 project, which was activated in 1999 for the monitoring of air quality inside three caves protected as nature reserves in Sicily (Italy). Near-real-time and spot measurements of air temperature and CO₂ concentration have been carried out since the year 2000, giving the opportunity of evaluating the gas hazard for visitors and its potential impact on the protected underground environments, as well as the influence of meteorological and hydrological conditions in driving carbon dioxide accumulations. The analysis of data acquired in the hypogeal atmosphere, and their comparison with analogous epigeal measures, indicates that carbon dioxide accumulation is controlled by a complex interaction among cave topography, meteorological dynamics, gaseous exchanges between groundwaters and the atmosphere, and human fruition. This last factor, under particular conditions, can surprisingly diminishing underground CO₂ concentrations. Full article

The present study aimed to identify the seasonal changes in the hydrochemical characteristics of the Huixian karst wetland and the underlying mechanism. Conventional ions and isotopes of 130 groundwater samples collected during the wet and dry seasons were analyzed. The hydrochemical characteristics of groundwater in the Huixian karst wetland were clarified using mathematical statistics and hydrochemical methods, including Durov diagrams, ionic ratios, Gibbs diagrams, and H and O isotopes. The hydrochemical evolution and sources of major ions in the Huixian karst wetland were also investigated. The results showed that cations and anions in groundwater in the study area were dominated by Ca²⁺ and HCO₃⁻, respectively, sourced mainly from calcite weathering. The ions of some groundwater samples were regulated by weathering of dolomite, dolomitic limestone, and pyrite, resulting in relatively high concentrations of Mg²⁺ and SO₄²⁻. K⁺, Na⁺, SO₄²⁻, NO₃⁻, and Cl⁻ in groundwater originated from precipitation, Na⁺ and Cl⁻ originated from domestic sewage, K⁺ was related to the application of potassium fertilizer in agriculture, and NO₃⁻ mainly originated from chemical fertilizer. Groundwater ions were primarily controlled by rock weathering, followed by evaporative concentration. The sources of major ions were dependent on the dissolution and precipitation of carbonate rock, as well as the chemical weathering of silicate rock and evaporite. Samples from the various water sources were scattered on both sides of the local meteoric water line (δD = 3.13δ¹⁸O − 13.9), which indicated isotopic composition was affected by evaporation and precipitation. Full article