Search Results (175)

The effect of the curvature of the boundary of semi-infinite cold plasma on the parameters and properties of surface oscillations localized near this boundary is considered. An analytical description of various cases of the impact of static deformation of the plasma boundary on the characteristics of the oscillating surface charge is obtained, and the results of the exact numerical solution of the initial equations are found to confirm the reliability of the derived analytical formulas. A significant role of the boundary perturbation shape in the formation of the spatial distribution of surface oscillation parameters is revealed. With the help of analytical formulas and precise numerical calculations, a description of this nonlinear interaction is presented. The availability of such a description is crucial both for determining the possibility of using the examined effect for specific applications and, on the other hand, for exciting it in plasma, which requires knowledge of the field structure features. Full article

Microplastics (MPs), as an emerging persistent contaminant, pose a potential threat to ecosystems and human health. The adsorptive removal of MPs from aqueous environments using magnetic nanoparticles has become a particularly promising remediation technology. Nevertheless, there remain significant knowledge gaps regarding its adsorption mechanism, especially how the key physical properties of magnetic nanoparticles regulate their adsorption behavior towards MPs. This study first investigated the relationship between the particle size of Fe₃O₄ nanoparticles and their adsorption efficacy for MPs. The results demonstrated a non-monotonic, size-dependent adsorption of MPs by Fe₃O₄ nanoparticles, with the adsorption efficiency and capacity following the order: 300 nm > 15 nm > 100 nm. This non-linear relationship suggested that factors other than specific surface area (which would favor smaller particles) are significantly influencing the adsorption process. Isotherm analysis indicated that the adsorption is not an ideal monolayer coverage process. Kinetic studies showed that the adsorption process could be better described by the pseudo-second-order model, while intra-particle diffusion played a critical role throughout the adsorption process. Furthermore, the effect of pH on adsorption efficiency was examined, revealing that the optimal performance occurs under neutral to weak acidic conditions, which is consistent with measurements of surface charges of nanoparticles. These findings suggest that the adsorption is not determined by specific surface area but is dominated by electrostatic interactions. The size-dependent adsorption of MPs by Fe₃O₄ nanoparticles provides new insights for the modification of magnetic adsorbents and offers a novel perspective for the sustainable and efficient remediation of environmental MPs pollution. Full article

In the research, a novel accelerometer concept leveraging the mode-localization phenomenon is put forward. The sensor measures external acceleration through monitoring changes in the relative amplitude ratio among coupled resonators. The sensing part of the presented accelerometer comprises a doubly clamped beam coupled with a cantilever beam. Its design ensures the initial bending mode of the clamped beam approximates the secondary bending mode of the cantilever. Drawing on Euler–Bernoulli beam theory, the governing formulas of the coupled resonators are deduced and analyzed via Galerkin discretization integrated with the multiple-scale method. During working in both linear as well as nonlinear operating regions, this sensor’s dynamic behavior can be tuned by adjusting the drive voltage. The obtained results demonstrate that the nonlinear dynamics increases the accelerometer sensitivity, which can be further enhanced by adjusting the coupling voltage without severe mode overlap. The presented model offers one viable method to enhance the overall performance in multi-mode MEMS accelerometers. Full article

As MEMS design encounters growing challenges, particularly stiction between movable and stationary electrodes, dielectric charging, pull-in instability, and multi-valued response characteristics, the integration of dimple-equipped structures has emerged as a pivotal solution to mitigate these fundamental issues. Consequently, this study investigates the dynamic behavior of an electrostatically actuated double-clamped microbeam incorporating dimples and contact pads. While the dimples enhance the beam’s travel range, they may also induce an impact mode upon contact with the landing pads, leading to complex nonlinear dynamic phenomena. A reduced-order model was developed to numerically solve the governing equation of motion. The microbeam’s response was analyzed both with and without dimples using multiple analytical techniques, including bifurcation diagrams and discrete excitation procedures near the impacting regime. The findings demonstrate that the inclusion of dimples effectively suppresses stiction, pull-in instability, and multi-valued responses. The results indicate that upon contacting the landing pads, the beam exhibits pronounced nonlinear dynamic behaviors, manifesting as higher-period oscillations such as period-3, period-4 and period-5 and then fully developed chaotic attractors. Indeed, this specifically demonstrates the potential of using the dynamic transition from a steady-state to a chaotic response to build novel MEMS sensors. Full article

Wireless sensor networks (WSNs) are fundamental to applications in the Internet of Things, smart cities, and environmental monitoring, where coverage optimization is critical for maximizing monitoring efficacy under constrained resources. Conventional approaches often suffer from low global coverage efficiency, high computational overhead, and a tendency to converge to local optima. To address these challenges, this study proposes the fusion multi-strategy gray wolf optimizer (FMGWO), an advanced variant of the Gray Wolf Optimizer (GWO). FMGWO integrates various strategies: electrostatic field initialization for uniform population distribution, dynamic parameter adjustment with nonlinear convergence and differential evolution scaling, an elder council mechanism to preserve historical elite solutions, alpha wolf tenure inspection and rotation to maintain population vitality, and a hybrid mutation strategy combining differential evolution and Cauchy perturbations to enhance diversity and global search capability. Ablation studies validate the efficacy of each strategy, while simulation experiments demonstrate FMGWO’s superior performance in WSN coverage optimization. Compared to established algorithms such as PSO, GWO, CSA, DE, GA, FA, OGWO, DGWO1, and DGWO2, FMGWO achieves higher coverage rates with fewer nodes—up to 98.63% with 30 nodes—alongside improved convergence speed and stability. These results underscore FMGWO’s potential as an effective solution for efficient WSN deployment, offering significant implications for resource-constrained optimization in IoT and edge computing systems. Full article

Synaptic activity is fundamental to memory and learning in the nervous system. However, most artificial synaptic devices are limited to mimicking static plasticity, and tunable plasticity has not been achieved at the device level. Here, we introduce a dynamic all-optical synapse based on photonic crystal nanobeam cavities with a ferroelectric carrier injection valve. By leveraging the nonlinear and ferroelectric electrostatic doping effects in silicon, integrated with Hf_0.5Zr_0.5O₂ (HZO) film as the ferroelectric layer and indium tin oxide (ITO) as the top electrode, we enhance linearity and reduce power consumption. Increasing the bias voltage further improves linearity while decreasing power consumption. This innovation offers a promising pathway for developing energy-efficient nanophotonic devices in neuromorphic computing. Full article

The present work analyzes the combined viscoelectric and steric effects on electroosmotic flow in a soft channel with polyelectrolyte coating. The structured channel surface, which controls the electric potential, creates two different flow regions: the electrolyte flow within the permeable polyelectrolyte layer (PEL) and the bulk electrolyte. Thus, this study discusses the interaction of various electrostatic effects to predict the electroosmotic flow field. The nonlinear governing equations describing the fluid flow are the modified Poisson–Boltzmann equation for the electric potential distribution, the mass conservation equation, and the modified Navier–Stokes equations for the flow field, which are solved numerically using a one-dimensional (1D) scheme. The results indicate that the flow enhances when increasing the electric potential magnitude across the channel cross-section via the rise in different dimensionless parameters, such as the PEL thickness, the steric factor, and the ratio of the electrokinetic parameter of the PEL to that of the electrolyte layer. This research demonstrates that the PEL significantly enhances control over electroosmotic flow. However, it is crucial to consider that viscoelectric effects at high electric fields and the friction generated by the grafted polymer brushes of the PEL can reduce these benefits. Full article

In this work, we described the synthesis of 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate by reacting 5-bromofuroic acid with methylparaben in the incorporation of DCC/DMAP (Steglich esterification) as coupling agents. Later on, we subsequently synthesized a series of 4-(methoxycarbonyl)phenyl 5-aryl furan-2-carboxylates (5a–5e) through Suzuki coupling catalyzed by palladium (0) between 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate (3) with several substituted arylated and heteroaryl boronic acids (4). DFT calculations were computed to elucidate electronic structural features of synthesized molecules (5a–5e) and to validate these findings by correlating with theoretical and experimental spectroscopic analysis. Furthermore, geometrical optimization, thermodynamic features, as FMO orbitals, MESP maps, NLO behavior and reactivity descriptors, were also determined from the PBE0 D3BJ/def2-TZVP/SMD_1,4-dioxane theory level to confirm the structural features of synthesized molecules. Full article

Arginine plays a critical role in biomolecular interactions due to its guanidinium side chain, which enables multivalent electrostatic and hydrogen bonding contacts. In this study, atomistic molecular dynamics simulations were conducted across a broad concentration range (26–605 mM) to investigate the thermodynamic and structural features of arginine self-assembly in aqueous solution. Key observables—including hydrogen bond count, radius of gyration, contact number, and isobaric heat capacity—were analyzed to characterize emergent behavior. A three-regime aggregation pattern (dilute, cooperative, and saturated) was identified and quantitatively modeled using the Hill equation, revealing a non-linear transition in clustering behavior. Spatial analyses were supplemented with trajectory-based clustering and radial distribution functions. The heat capacity peak observed near 360 mM was interpreted as a thermodynamic signature of hydration rearrangement. Trajectory analyses utilized both GROMACS tools and the MDAnalysis library. While force field limitations and single-replica sampling are acknowledged, the results offer mechanistic insight into how arginine concentration modulates molecular organization—informing the understanding of biomolecular condensates, protein–nucleic acid complexes, and the design of functional supramolecular systems. The findings are in strong agreement with experimental observations from small-angle X-ray scattering and differential scanning calorimetry. Overall, this work establishes a cohesive framework for understanding amino acid condensation and reveals arginine’s concentration-dependent behavior as a model for weak, reversible molecular association. Full article

In this paper we discuss some results on the existence of solutions for an elliptic system appearing in physical sciences. In particular the system appears when we look at standing wave solutions in the electrostatic situation for the Schrödinger equation coupled, with the minimal coupling rule, with the electromagnetic equations of Born–Infeld theory. Many difficulties appear, especially due to the fact we are in an unbounded domain (the whole space ${\mathbb{R}}^3$) and to the intrinsic nonlinear nature of the equations. We are able to prove the existence of a minimal energy solution by showing an approximating procedure that can be adapted depending on the value of the parameter p, which is in the nonlinearity. Full article

A novel 3-amino-5-mercapto-1,2,4-triazole functionalized graphene oxide composite (GO-ATT) was successfully prepared via a covalent coupling method, then employed for the removal of p-nitrophenol (PNP) from wastewater. The morphology as well as the composition of GO-ATT composite were investigated using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), X-ray diffraction spectroscopy (XRD), and X-ray photoelectron spectroscopy (XPS). The surface charge of GO-ATT composite was evaluated by Zeta potential analyses. The surface area and pore size distribution of GO-ATT composite were analyzed using specific surface analyses using the Brunauer–Emmett–Teller (BET) method. Batch adsorption experiments were performed to investigate the effects of conditional factors, including contact time, solution pH, initial PNP concentration, and contact temperature, on the adsorption process. A maximum adsorption capacity of PNP by GO-ATT composite (0.287 mmol g⁻¹) could be obtained at 25 °C. Freundlich isotherm (R² > 0.92505) can better describe the adsorption behavior of PNP on GO-ATT composite. The thermodynamic functions (ΔG°, ΔH°, ΔS°) indicate that adsorption is a spontaneous, endothermic, entropy-increasing process and features physisorption. The adsorption behavior of PNP on GO-ATT composite conformed to the nonlinear pseudo-second-order kinetic model. Adsorption mechanism investigation indicated that the electrostatic, π-π stacking, and hydrogen bonding interactions were involved in the adsorption process. After 10 adsorption–desorption cycles, the adsorbent exhibited a stable and efficient removal rate (94%) for PNP. Due to its advantages of a high efficiency, excellent reusability, and high stability, the covalently coupled GO-ATT composite might be used as an effective adsorbent for the removal of phenolic contaminants from wastewater. Full article

Compared with traditional immunoassay methods, microfluidic immunoassay restricts the immune response in confined microchannels, significantly reducing sample consumption and improving reaction efficiency, making it worthy of widespread application. This paper proposes an exciting multi-frequency electrothermal flow (MET) technique by applying combined standing-wave and traveling-wave voltage signals with different oscillation frequencies to a three-period quadra-phase discrete electrode array, achieving rapid immunoreaction on functionalized electrode surfaces within straight microchannels, by virtue of horizontal pumping streamlines and transverse stirring vortices induced by nonlinear electrothermal convection. Under the approximation of a small temperature rise, a linear model describing the phenomenon of MET is derived. Although the time-averaged electrothermal volume force is a simple superposition of the electrostatic body force components at the two frequencies, the electro-thermal-flow field undergoes strong mutual coupling through the dual-component time-averaged Joule heat source term, further enhancing the intensity of Maxwell–Wagner smeared structural polarization and leading to mutual influence between the standing-wave electrothermal (SWET) and traveling-wave electrothermal (TWET) effects. Through thorough numerical simulation, the optimal working frequencies for SWET and TWET are determined, and the resulting synthetic MET flow field is directly utilized for microfluidic immunoassay. MET significantly promotes the binding kinetics on functionalized electrode surface by simultaneous global electrokinetic transport along channel length direction and local chaotic stirring of antigen samples near the reaction site, compared to the situation without flow activation. The MET investigated herein satisfies the requirements for early, rapid, and precise immunoassay of test samples on-site, showing great application prospects in remote areas with limited resources. Full article

This paper investigates the effect of electrostatic nonlinearity on the rate-sensing performance of imperfect ring-based Coriolis Vibrating Gyroscopes (CVGs) for devices having 8 and 16 evenly distributed electrodes. Mathematical models are developed for CVGs operating in (i) an open loop for a linear electrostatically trimmed device, (ii) a closed loop where a sense force balancing is applied to negate the sense quadrature response, and the effects of electrostatic nonlinearity are investigated for increasing drive amplitudes. The modeling indicates the nonlinear responses for 8- and 16-electrode arrangements are quite different, and this can be attributed to the nonlinear frequency imbalance, which depends on the drive and sense frequency softening as well as the presence of self-induced parametric excitation in the sense response. In open loop the 16-electrode arrangement exhibits much weaker levels of nonlinearity than the 8-electrode arrangement because the nonlinear frequency imbalance is less sensitive to drive amplitude. For devices operating in closed-loop with sense force balancing to ensure the drive and sense responses are in-phase/anti-phase, it is shown that ideal rate-sensing performance is achieved at large drive amplitudes for both 8- and 16-electrode arrangements. Using sense force balancing, rate sensing can be achieved using either the sense response or the required balancing voltage. For the latter, large nonlinear frequency imbalances and low damping levels enhance rate-sensing performance. Full article

An analysis of the Magnetospheric Multiscale (MMS) spacecraft data shows the presence of slow electrostatic solitary waves (SESWs) in the Earth’s plasma sheet, which have been interpreted as slow electron holes (SEHs). An alternative mechanism based on slow ion-acoustic solitons is proposed for these SESWs. The SESWs are observed in the region where double humped ion distributions and hot electrons co-exist. Our theoretical model considers the plasma in the SESW region to consist of hot electrons with a vortex distribution, core Maxwellian protons drifting parallel to the magnetic field, B and beam protons drifting anti-parallel to B. Parallel propagating nonlinear ion-acoustic waves are studied using the Sagdeev pseudopotential technique. The analysis yields four types of modes, namely, two slow ion-acoustic (SIA1 and SIA2) solitons and two fast ion-acoustic (FIA1 and FIA2) solitons. All solitons have positive potentials. Except the FIA1 solitons which propagate parallel to B; the other three types propagate anti-parallel to B. Good agreement is found between the amplitudes of electrostatic potential, the electric field, the widths and speed of SIA1 and SIA2 solitons, and the observed properties of SESWs by the MMS spacecraft. Full article

Sprite halos are transient luminous phenomena in the lower ionosphere triggered by tropospheric lightning. The effect of removed charge distributions on sprite halos has not been sufficiently discussed. A three-dimensional (3D) quasi-electrostatic (QES) field model was developed in this paper, including the ionospheric nonlinear effect and optical emissions. Simulation results show that, for a total charge of 150 C removed within 1 ms with different spatial distributions, higher altitudes of charge removal lead to stronger electric fields and increase sprite halos’ emission intensities. The non-axisymmetric horizontal distribution of charge affects mesospheric electric fields, and the corresponding scales and intensities of emissions vary with observation orientations. Considering the tilted dipole charge structure due to wind shear, the generated electric field and the corresponding position of sprite halos shift accordingly with the tropospheric removed charge, providing an explanation for the horizontal displacement between sprite halos and the parent lightning. Full article