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37 pages, 5280 KB  
Review
Thermal Issues Related to Hybrid Bonding of 3D-Stacked High Bandwidth Memory: A Comprehensive Review
by Seung-Hoon Lee, Su-Jong Kim, Ji-Su Lee and Seok-Ho Rhi
Electronics 2025, 14(13), 2682; https://doi.org/10.3390/electronics14132682 - 2 Jul 2025
Cited by 2 | Viewed by 9007
Abstract
High-Bandwidth Memory (HBM) enables the bandwidth required by modern AI and high-performance computing, yet its three dimensional stack traps heat and amplifies thermo mechanical stress. We first review how conventional solutions such as heat spreaders, microchannels, high density Through-Silicon Vias (TSVs), and Mass [...] Read more.
High-Bandwidth Memory (HBM) enables the bandwidth required by modern AI and high-performance computing, yet its three dimensional stack traps heat and amplifies thermo mechanical stress. We first review how conventional solutions such as heat spreaders, microchannels, high density Through-Silicon Vias (TSVs), and Mass Reflow Molded Underfill (MR MUF) underfills lower but do not eliminate the internal thermal resistance that rises sharply beyond 12layer stacks. We then synthesize recent hybrid bonding studies, showing that an optimized Cu pad density, interface characteristic, and mechanical treatments can cut junction-to-junction thermal resistance by between 22.8% and 47%, raise vertical thermal conductivity by up to three times, and shrink the stack height by more than 15%. A meta-analysis identifies design thresholds such as at least 20% Cu coverage that balances heat flow, interfacial stress, and reliability. The review next traces the chain from Coefficient of Thermal Expansion (CTE) mismatch to Cu protrusion, delamination, and warpage and classifies mitigation strategies into (i) material selection including SiCN dielectrics, nano twinned Cu, and polymer composites, (ii) process technologies such as sub-200 °C plasma-activated bonding and Chemical Mechanical Polishing (CMP) anneal co-optimization, and (iii) the structural design, including staggered stack and filleted corners. Integrating these levers suppresses stress hotspots and extends fatigue life in more than 16layer stacks. Finally, we outline a research roadmap combining a multiscale simulation with high layer prototyping to co-optimize thermal, mechanical, and electrical metrics for next-generation 20-layer HBM. Full article
(This article belongs to the Section Semiconductor Devices)
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18 pages, 6897 KB  
Article
Thermal and Interfacial Stability of PPS-Fabricated Segmented Skutterudite Legs for Thermoelectric Applications
by Mirosław J. Kruszewski
Materials 2025, 18(13), 2923; https://doi.org/10.3390/ma18132923 - 20 Jun 2025
Viewed by 540
Abstract
The development of thermoelectric modules based on skutterudite materials requires stable, low-resistance interfaces between segments operating at different temperature ranges. This study investigates the microstructure, thermoelectric performance, and thermal stability of the following two joints: In0.4Co4Sb12/Co4 [...] Read more.
The development of thermoelectric modules based on skutterudite materials requires stable, low-resistance interfaces between segments operating at different temperature ranges. This study investigates the microstructure, thermoelectric performance, and thermal stability of the following two joints: In0.4Co4Sb12/Co4Sb10.8Te0.6Se0.6 (n-type) and CeFe3Co0.5Ni0.5Sb12/In0.25Co3FeSb12 (p-type), fabricated by pulse plasma sintering (PPS). Scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) analyses confirmed the formation of well-bonded interfaces without pores or cracks. Aging at 773 K for 168 h did not result in morphological or chemical degradation, and phase composition remained unchanged according to X-ray diffraction (XRD). Surface Seebeck coefficient mapping and contact resistance measurements showed negligible changes after annealing, confirming electrical stability. To provide context for potential applications, theoretical energy conversion efficiencies were estimated based on measured thermoelectric properties, yielding 13.2% and 10.1% for the n- and p-type segmented legs, respectively. Additionally, measured coefficients of thermal expansion (CTE) indicated low mismatch between jointed materials, supporting good mechanical compatibility. The results demonstrate that the selected material combinations are thermally, chemically, and electrically stable and can be effectively used in segmented thermoelectric legs for intermediate-temperature applications. Full article
(This article belongs to the Section Electronic Materials)
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24 pages, 7475 KB  
Article
Application of a Dual-Stream Network Collaboratively Based on Wavelet and Spatial-Channel Convolution in the Inpainting of Blank Strips in Marine Electrical Imaging Logging Images: A Case Study in the South China Sea
by Guilan Lin, Sinan Fang, Manxin Li, Hongtao Wu, Chenxi Xue and Zeyu Zhang
J. Mar. Sci. Eng. 2025, 13(5), 997; https://doi.org/10.3390/jmse13050997 - 21 May 2025
Cited by 1 | Viewed by 778
Abstract
Electrical imaging logging technology precisely characterizes the features of the formation on the borehole wall through high-resolution resistivity images. However, the problem of blank strips caused by the mismatch between the instrument pads and the borehole diameter seriously affects the accuracy of fracture [...] Read more.
Electrical imaging logging technology precisely characterizes the features of the formation on the borehole wall through high-resolution resistivity images. However, the problem of blank strips caused by the mismatch between the instrument pads and the borehole diameter seriously affects the accuracy of fracture identification and formation continuity interpretation in marine oil and gas reservoirs. Existing inpainting methods struggle to reconstruct complex geological textures while maintaining structural continuity, particularly in balancing low-frequency formation morphology with high-frequency fracture details. To address this issue, this paper proposes an inpainting method using a dual-stream network based on the collaborative optimization of wavelet and spatial-channel convolution. By designing a texture-aware data prior algorithm, a high-quality training dataset with geological rationality is generated. A dual-stream encoder–decoder network architecture is adopted, and the wavelet transform convolution (WTConv) module is utilized to enhance the multi-scale perception ability of the generator, achieving a collaborative analysis of the low-frequency formation structure and high-frequency fracture details. Combined with the spatial channel convolution (SCConv) to enhance the feature fusion module, the cross-modal interaction between texture and structural features is optimized through a dynamic gating mechanism. Furthermore, a multi-objective loss function is introduced to constrain the semantic coherence and visual authenticity of image reconstruction. Experiments show that, in the inpainting indexes for Block X in the South China Sea, the mean absolute error (MAE), structural similarity index (SSIM), and peak signal-to-noise ratio (PSNR) of this method are 6.893, 0.779, and 19.087, respectively, which are significantly better than the improved filtersim, U-Net, and AOT-GAN methods. The correlation degree of the pixel distribution between the inpainted area and the original image reaches 0.921~0.997, verifying the precise matching of the low-frequency morphology and high-frequency details. In the inpainting of electrical imaging logging images across blocks, the applicability of the method is confirmed, effectively solving the interference of blank strips on the interpretation accuracy of marine oil and gas reservoirs. It provides an intelligent inpainting tool with geological interpretability for the electrical imaging logging interpretation of complex reservoirs, and has important engineering value for improving the efficiency of oil and gas exploration and development. Full article
(This article belongs to the Special Issue Research on Offshore Oil and Gas Numerical Simulation)
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14 pages, 10536 KB  
Article
Regulation of Interface Compatibility and Performance in Soft Magnetic Composites with Inorganic Insulation Layers by FePO4 Intermediate Transition Layer
by Sanao Huang, Junjie Ma, Yang Liu, Hao He, Peisheng Lyu, Huaqin Huang and Bing Dai
Molecules 2024, 29(22), 5281; https://doi.org/10.3390/molecules29225281 - 8 Nov 2024
Cited by 2 | Viewed by 1369
Abstract
In the fabrication of soft magnetic composites, the lattice mismatch between the inorganic insulation layer and the iron matrix often leads to the formation of cracks during the molding process, which significantly impairs the operational performance of the materials. Consequently, it is imperative [...] Read more.
In the fabrication of soft magnetic composites, the lattice mismatch between the inorganic insulation layer and the iron matrix often leads to the formation of cracks during the molding process, which significantly impairs the operational performance of the materials. Consequently, it is imperative to develop novel strategies for inorganic insulation coatings that offer high electrical resistivity and thermal stability and are less susceptible to cracking during formation. This paper presents a new structure for soft magnetic composites that incorporates FePO4 as an intermediate transition layer between the iron-based soft magnetic particles and the inorganic ceramic insulation layer. This configuration is designed to provide insulation coatings with superior voltage and thermal resistance, as well as high electrical resistivity. The research details the processes forming the FePO4 intermediate transition layer and the SiO2 insulation layer on the iron powder surface, along with their interaction mechanisms. An analysis comparing the scenarios with and without the FePO4 intermediate transition layer shows its beneficial impact on the magnetic properties and mechanical strength of the soft magnetic composites. Further investigations reveal that at a phosphoric acid concentration of 1 wt.%, the FePO4 layer significantly enhances the interface compatibility between the Fe powder matrix and the SiO2 insulation layer. Under these conditions, the Fe@ FePO4/SiO2 soft magnetic composites demonstrate outstanding overall performance: the saturation magnetization stands at 215.60 emu/g, effective permeability at 83.2, resistivity at 57.42 Ω·m, power loss at 375.0 kW/m3 under 30 mT/100 kHz, and radial compressive strength at 15.95 Kgf. These findings offer novel insights and practical approaches for advancing inorganic insulation coating strategies and provide vital scientific support for further enhancing the magnetic and mechanical properties of soft magnetic composites. Full article
(This article belongs to the Section Inorganic Chemistry)
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32 pages, 15095 KB  
Article
Multi-Sensor Soil Probe and Machine Learning Modeling for Predicting Soil Properties
by Sabine Grunwald, Mohammad Omar Faruk Murad, Stephen Farrington, Woody Wallace and Daniel Rooney
Sensors 2024, 24(21), 6855; https://doi.org/10.3390/s24216855 - 25 Oct 2024
Cited by 9 | Viewed by 7708
Abstract
We present a data-driven, in situ proximal multi-sensor digital soil mapping approach to develop digital twins for multiple agricultural fields. A novel Digital Soil CoreTM (DSC) Probe was engineered that contains seven sensors, each of a distinct modality, including sleeve friction, tip [...] Read more.
We present a data-driven, in situ proximal multi-sensor digital soil mapping approach to develop digital twins for multiple agricultural fields. A novel Digital Soil CoreTM (DSC) Probe was engineered that contains seven sensors, each of a distinct modality, including sleeve friction, tip force, dielectric permittivity, electrical resistivity, soil imagery, acoustics, and visible and near-infrared spectroscopy. The DSC System integrates the DSC Probe, DSC software (v2023.10), and deployment equipment components to sense soil characteristics at a high vertical spatial resolution (mm scale) along in situ soil profiles up to a depth of 120 cm in about 60 s. The DSC Probe in situ proximal data are harmonized into a data cube providing vertical high-density knowledge associated with physical–chemical–biological soil conditions. In contrast, conventional ex situ soil samples derived from soil cores, soil pits, or surface samples analyzed using laboratory and other methods are bound by a substantially coarser spatial resolution and multiple compounding errors. Our objective was to investigate the effects of the mismatched scale between high-resolution in situ proximal sensor data and coarser-resolution ex situ soil laboratory measurements to develop soil prediction models. Our study was conducted in central California soil in almond orchards. We collected DSC sensor data and spatially co-located soil cores that were sliced into narrow layers for laboratory-based soil measurements. Partial Least Squares Regression (PLSR) cross-validation was used to compare the results of testing four data integration methods. Method A reduced the high-resolution sensor data to discrete values paired with layer-based soil laboratory measurements. Method B used stochastic distributions of sensor data paired with layer-based soil laboratory measurements. Method C allocated the same soil analytical data to each one of the high-resolution multi-sensor data within a soil layer. Method D linked the high-density multi-sensor soil data directly to crop responses (crop performance and behavior metrics), bypassing costly laboratory soil analysis. Overall, the soil models derived from Method C outperformed Methods A and B. Soil predictions derived using Method D were the most cost-effective for directly assessing soil–crop relationships, making this method well suited for industrial-scale precision agriculture applications. Full article
(This article belongs to the Section Smart Agriculture)
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21 pages, 7726 KB  
Article
Augmented Two-Stage Hierarchical Controller for Distributed Power Generation System Powered by Renewable Energy: Development and Performance Analysis
by Javed Khan Bhutto
Sustainability 2024, 16(14), 5872; https://doi.org/10.3390/su16145872 - 10 Jul 2024
Cited by 1 | Viewed by 1670
Abstract
The sustainable development of an area is highly reliant on a reliable electrical energy supply. Microgrids are important in integrating distributed energy resources (DERs) using power electronic converters. However, microgrid control becomes challenging with the increasing number of distributed generators and loads. With [...] Read more.
The sustainable development of an area is highly reliant on a reliable electrical energy supply. Microgrids are important in integrating distributed energy resources (DERs) using power electronic converters. However, microgrid control becomes challenging with the increasing number of distributed generators and loads. With the conventional droop control method, power contributions from DER converters cannot be accurately shared due to a mismatch of line impedances. In this paper, an augmented hierarchical control mechanism is proposed to solve the issues mentioned above. This hierarchical control mechanism consists of primary and secondary controllers. The primary stage utilized the droop controller to improve optimal power flow, mainly for the resistive network. The secondary stage is based on an improved methodology to compensate for the voltage and frequency variations during small and large signal disturbances. Moreover, the modelling and analysis for PMSG-based wind energy conversion systems are also presented. The response of the primary controller for active and reactive power sharing is investigated. The analysis emphasizes the demonstration of optimal power-sharing under normal and abnormal conditions for the considered load. Finally, the suggested robust controller’s performance is evaluated in a MATLAB environment, and simulation results show the proposed scheme’s superiority under different operating conditions. The frequency is stable at 50 Hz after a 50 KW load is added. Full article
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11 pages, 4738 KB  
Article
Assessing the Effect of Twisting and Twisting Fatigue on ZnO:Al Thin Film Performance on PEN and PET Substrates
by Dilveen W. Mohammed, Rayan M. Ameen, Rob Waddingham, Andrew J. Flewitt, James Bowen and Stephen N. Kukureka
Micromachines 2024, 15(7), 853; https://doi.org/10.3390/mi15070853 - 29 Jun 2024
Cited by 2 | Viewed by 1438
Abstract
This study examines the electromechanical characteristics of aluminium-doped zinc oxide (AZO) films. The films were produced using the RF magnetron sputtering process with a consistent thickness of 150 nm on various polymer substrates. The study focuses on assessing the electro-mechanical failure processes of [...] Read more.
This study examines the electromechanical characteristics of aluminium-doped zinc oxide (AZO) films. The films were produced using the RF magnetron sputtering process with a consistent thickness of 150 nm on various polymer substrates. The study focuses on assessing the electro-mechanical failure processes of coated segments using flexible substrates, namely polyethylene naphthalate (PEN) and polyethylene terephthalate (PET), with a specific emphasis on typical cracking and delamination occurrences. This examination involves conducting twisting deformation together with using standardised electrical resistance measurements and optical microscope monitoring instruments. It was found that the crack initiation angle is mostly dependent on the mechanical mismatch between the coating and substrate. Higher critical twisting angle values are observed for the AZO/PEN film during twisting testing. Relative to the perpendicular plane of the untwisted sample, it was found that cracks initiated at a twist angle equal to 42° ± 2.1° and 38° ± 1.7° for AZO/PEN and AZO/PET, respectively, and propagated along the sample length. SEM images indicate that the twisting motion results in deformation in the thin film material, leading to the presence of both types of stress in the film structure. These discoveries emphasise the significance of studying the mechanical properties of thin films under different stress conditions, as it can impact their performance and reliability in real-world applications. The electromechanical stability of AZO was found to be similar on both substrates during fatigue testing. Studying the electromechanical properties of various material combinations is important for selecting polymer substrates and predicting the durability of flexible electronic devices made from polyester. Full article
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18 pages, 4789 KB  
Article
Investigating On-Site Energy Consumption Patterns Using Vertical Electrical Sounding (VES) and Geographic Information System (GIS) Techniques
by Haris Abdullah, Hafiz Umar Farid, Maira Naeem, Nadeem Zubair, Zahid Mahmood Khan, Huzaifa Shahzad, Pervaiz Sikandar, Muhammad Abrar, Aamir Shakoor and Muhammad Mubeen
Sustainability 2023, 15(24), 16782; https://doi.org/10.3390/su152416782 - 13 Dec 2023
Viewed by 1499
Abstract
In recent decades, the fortunes of energy economies have been closely linked in Pakistan. A major energy inefficiency issue was found in Pakistan due to the mismatch between horsepower (HP) requirements and bore depth. Keeping this in view, a total of 194 tubewells [...] Read more.
In recent decades, the fortunes of energy economies have been closely linked in Pakistan. A major energy inefficiency issue was found in Pakistan due to the mismatch between horsepower (HP) requirements and bore depth. Keeping this in view, a total of 194 tubewells were chosen for an energy audit in the Multan region, Pakistan. The Terrameter SAS 4000 was used to measure the accurate demand of the head during the resistivity surveys at all of the selected locations. The results showed that the tubewell sets were installed arbitrarily at high power, irrespective of the provided flow and head, and these pumps used more energy for their flow. The results revealed that the efficiency of the tubewell sets increased from 35 to 54%, from 55 to 80%, from 49 to 80%, and from 48 to 75% for centrifugal pumps with electric motors and diesel engines and for turbines with electric motors and diesel engines, respectively. A weighted overlay analysis indicated that the efficiency of tubewells covering 838.12, 1131.8, and 2077.1 km2 for centrifugal pumps with electric motors, diesel engines, and turbines, respectively, was enhanced for the study area. Similarly, the energy saved for the study area covered 1423.8, 1161.1, and 1131.1 km2, as shown by the overlay analysis. The results revealed that the annual energy saving was found of 3486 kw for 194 tubewells, resulted in the saving of USD 0.204 million in operational costs over one year. The overall results indicate the strong need to adopt proper investigations of the head and power requirements before installing a system in the study area. Full article
(This article belongs to the Section Resources and Sustainable Utilization)
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18 pages, 4472 KB  
Article
Evaluation of Polymer-Coated Carbon Nanotube Flexible Microelectrodes for Biomedical Applications
by Chethani Ruhunage, Vaishnavi Dhawan, Chaminda P. Nawarathne, Abdul Hoque, Xinyan Tracy Cui and Noe T. Alvarez
Bioengineering 2023, 10(6), 647; https://doi.org/10.3390/bioengineering10060647 - 26 May 2023
Cited by 7 | Viewed by 4387
Abstract
The demand for electrically insulated microwires and microfibers in biomedical applications is rapidly increasing. Polymer protective coatings with high electrical resistivity, good chemical resistance, and a long shelf-life are critical to ensure continuous device operation during chronic applications. As soft and flexible electrodes [...] Read more.
The demand for electrically insulated microwires and microfibers in biomedical applications is rapidly increasing. Polymer protective coatings with high electrical resistivity, good chemical resistance, and a long shelf-life are critical to ensure continuous device operation during chronic applications. As soft and flexible electrodes can minimize mechanical mismatch between tissues and electronics, designs based on flexible conductive microfibers, such as carbon nanotube (CNT) fibers, and soft polymer insulation have been proposed. In this study, a continuous dip-coating approach was adopted to insulate meters-long CNT fibers with hydrogenated nitrile butadiene rubber (HNBR), a soft and rubbery insulating polymer. Using this method, 4.8 m long CNT fibers with diameters of 25–66 µm were continuously coated with HNBR without defects or interruptions. The coated CNT fibers were found to be uniform, pinhole free, and biocompatible. Furthermore, the HNBR coating had better high-temperature tolerance than conventional insulating materials. Microelectrodes prepared using the HNBR-coated CNT fibers exhibited stable electrochemical properties, with a specific impedance of 27.0 ± 9.4 MΩ µm2 at 1.0 kHz and a cathodal charge storage capacity of 487.6 ± 49.8 mC cm−2. Thus, the developed electrodes express characteristics that made them suitable for use in implantable medical devices for chronic in vivo applications. Full article
(This article belongs to the Special Issue Recent Advances of Biosensors for Biomedical Applications)
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16 pages, 3156 KB  
Article
Calibration Experiment and Temperature Compensation Method for the Thermal Output of Electrical Resistance Strain Gauges in Health Monitoring of Structures
by Zhihao Jin, Yuan Li, Dongjue Fan, Caitao Tu, Xuchen Wang and Shiyong Dang
Symmetry 2023, 15(5), 1066; https://doi.org/10.3390/sym15051066 - 11 May 2023
Cited by 7 | Viewed by 3725
Abstract
Electrical resistance strain gauges are widely used in asymmetric structures for measurement and monitoring, but their thermal output in changing temperature environments has a significant impact on the measurement results. Since thermal output is related to the coefficient of thermal expansion of the [...] Read more.
Electrical resistance strain gauges are widely used in asymmetric structures for measurement and monitoring, but their thermal output in changing temperature environments has a significant impact on the measurement results. Since thermal output is related to the coefficient of thermal expansion of the strain gauge’s sensitive grating material and the measured object, the temperature self-compensation technique of strain gauges fails to eliminate the additional strain caused by temperature because it cannot match the coefficient of thermal expansion of various measured objects. To address this problem, in this study, the principle of the thermal output of electrical resistance strain gauges was analyzed, a calibration experiment for thermal output in the case of a mismatch between the coefficient of linear expansion of the measured object and the strain gauge grating material was conducted, and the mechanism for temperature influence on thermal output was revealed. A method was proposed to obtain the thermal output curves for different materials by using thermostats with dual temperatures to conduct temperature calibration experiments. A linear regression method was used to obtain a linear formula for the thermal output corresponding to each temperature. The thermal output conversion relationship was derived for materials with different coefficients of linear expansion. An in situ temperature compensation technique for electrical resistance strain gauges that separates the measured strain into thermal and mechanical strains was proposed. The results showed that the thermal output curve for the measured object can be calibrated in advance and then deducted from the measured strain, thus reducing the influence of temperature-induced additional strain on the mechanical strain. In addition, a new method was provided for the calculation of the thermal output among materials with similar coefficients of linear expansion, providing a reference for the health monitoring of asymmetric structures. Full article
(This article belongs to the Section Engineering and Materials)
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10 pages, 4597 KB  
Article
N-Polar Indium Nitride Quantum Dashes and Quantum Wire-like Structures: MOCVD Growth and Characterization
by Vineeta R. Muthuraj, Wenjian Liu, Henry Collins, Weiyi Li, Robert Hamwey, Steven P. DenBaars, Umesh K. Mishra and Stacia Keller
Crystals 2023, 13(4), 699; https://doi.org/10.3390/cryst13040699 - 19 Apr 2023
Viewed by 1977
Abstract
The electrical properties of InN give it potential for applications in III-nitride electronic devices, and the use of lower-dimensional epitaxial structures could mitigate issues with the high lattice mismatch of InN to GaN (10%). N-polar MOCVD growth of InN was performed to explore [...] Read more.
The electrical properties of InN give it potential for applications in III-nitride electronic devices, and the use of lower-dimensional epitaxial structures could mitigate issues with the high lattice mismatch of InN to GaN (10%). N-polar MOCVD growth of InN was performed to explore the growth parameter space of the horizontal one-dimensional InN quantum wire-like structures on miscut substrates. The InN growth temperature, InN thickness, and NH3 flow during growth were varied to determine optimal quantum wire segment growth conditions. Quantum wire segment formation was observed through AFM images for N-polar InN samples with a low growth temperature of 540 °C and 1–2 nm of InN. Below 1 nm of InN, quantum dashes formed, and 2-D layers were formed above 2 nm of InN. One-dimensional anisotropy of the electrical conduction of N-polar InN wire-like samples was observed through TLM measurements. The sheet resistances of wire-like samples varied from 10–26 kΩ/□ in the longitudinal direction of the wire segments. The high sheet resistances were attributed to the close proximity of the treading dislocations at the InN/GaN interface and might be lowered by reducing the lattice mismatch of InN wire-like structures with the substrate using high lattice constant base layers such as relaxed InGaN. Full article
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25 pages, 5377 KB  
Review
Research Progress in Capping Diamond Growth on GaN HEMT: A Review
by Yingnan Wang, Xiufei Hu, Lei Ge, Zonghao Liu, Mingsheng Xu, Yan Peng, Bin Li, Yiqiu Yang, Shuqiang Li, Xuejian Xie, Xiwei Wang, Xiangang Xu and Xiaobo Hu
Crystals 2023, 13(3), 500; https://doi.org/10.3390/cryst13030500 - 14 Mar 2023
Cited by 13 | Viewed by 5681
Abstract
With the increased power density of gallium nitride (GaN) high electron mobility transistors (HEMTs), effective cooling is required to eliminate the self-heating effect. Incorporating diamond into GaN HEMT is an alternative way to dissipate the heat generated from the active region. In this [...] Read more.
With the increased power density of gallium nitride (GaN) high electron mobility transistors (HEMTs), effective cooling is required to eliminate the self-heating effect. Incorporating diamond into GaN HEMT is an alternative way to dissipate the heat generated from the active region. In this review, the four main approaches for the integration of diamond and GaN are briefly reviewed, including bonding the GaN wafer and diamond wafer together, depositing diamond as a heat-dissipation layer on the GaN epitaxial layer or HEMTs, and the epitaxial growth of GaN on the diamond substrate. Due to the large lattice mismatch and thermal mismatch, as well as the crystal structure differences between diamond and GaN, all above works face some problems and challenges. Moreover, the review is focused on the state-of-art of polycrystalline or nanocrystalline diamond (NCD) passivation layers on the topside of GaN HEMTs, including the nucleation and growth of the diamond on GaN HEMTs, structure and interface analysis, and thermal characterization, as well as electrical performance of GaN HEMTs after diamond film growth. Upon comparing three different nucleation methods of diamond on GaN, electrostatic seeding is the most commonly used pretreatment method to enhance the nucleation density. NCDs are usually grown at lower temperatures (600–800 °C) on GaN HEMTs, and the methods of “gate after growth” and selective area growth are emphasized. The influence of interface quality on the heat dissipation of capped diamond on GaN is analyzed. We consider that effectively reducing the thermal boundary resistance, improving the regional quality at the interface, and optimizing the stress–strain state are needed to improve the heat-spreading performance and stability of GaN HEMTs. NCD-capped GaN HEMTs exhibit more than a 20% lower operating temperature, and the current density is also improved, which shows good application potential. Furthermore, the existing problems and challenges have also been discussed. The nucleation and growth characteristics of diamond itself and the integration of diamond and GaN HEMT are discussed together, which can more completely explain the thermal diffusion effect of diamond for GaN HEMT and the corresponding technical problems. Full article
(This article belongs to the Special Issue Wide-Bandgap Semiconductors)
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12 pages, 4252 KB  
Article
Rapid Preparation of Novel Ionic Polymer–Metal Composite for Improving Humidity Sensing Effect
by Chun Zhao, Yujun Ji, Gangqiang Tang, Xin Zhao, Dong Mei, Jie Ru, Denglin Zhu and Yanjie Wang
Polymers 2023, 15(3), 733; https://doi.org/10.3390/polym15030733 - 31 Jan 2023
Cited by 9 | Viewed by 2112
Abstract
Ionic polymer–metal composites (IPMCs) have attracted attention in recent years due to their integration of actuation and sensing functions. As one of the main sensing functions of IPMCs, humidity sensing has been of consistent interest in wearable health monitors and artificial skin. However, [...] Read more.
Ionic polymer–metal composites (IPMCs) have attracted attention in recent years due to their integration of actuation and sensing functions. As one of the main sensing functions of IPMCs, humidity sensing has been of consistent interest in wearable health monitors and artificial skin. However, there are still some technical challenges in that classical IPMCs have poor humidity sensing performance due to their dense surface electrode, and IPMCs are damaged easily due to an electrode/membrane mismatch. In this work, through the spraying and electrodepositing process, we developed an efficient method to rapidly prepare a Au-shell-Ag-NW (silver nanowire)-based IPMC with high strength, low surface resistance and excellent humidity sensing performance. Meanwhile, we optimized the preparation method by clarifying the influence of solvent type and electrodepositing time on the performance of the Au-shell-Ag-NW-based IPMC, thus effectively improving the humidity sensing effect and strength of the IPMC. Compared with previous research, the humidity electrical response (~9.6 mV) of the Au-shell-Ag-NW-based IPMC is at least two orders of magnitude higher than that of the classical IPMC (~0.41 mV), which is mainly attributed to the sparse gap structure for promoting the exchange of water molecules in the environment and Nafion membrane, a low surface resistance (~3.4 Ohm/sq) for transmitting the signal, and a seamless connection between the electrode and Nafion membrane for fully collecting the ion charges in the Nafion membrane. Additionally, the Au-shell-Ag-NW-based IPMC could effectively monitor the human breathing process, and the humidity sensing performance did not change after being exposed to the air for 4 weeks, which further indicates that the Au-shell-Ag-NW-based IPMC has good application potential due to its efficient preparation technology, high stability and good reproducibility. Full article
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14 pages, 8127 KB  
Article
Strange Metallicity and Magnetic Order in the CoNi(Cr/V) Medium-Entropy Alloy System
by Faisal Mustafa, Mehmet Egilmez, Wael Abuzaid, Sami El-Khatib, Tahir Nawaz, Shahbaz Ahmad and Serhat Alagoz
Materials 2023, 16(3), 1044; https://doi.org/10.3390/ma16031044 - 24 Jan 2023
Cited by 15 | Viewed by 2591
Abstract
CoNiCr is a prototypical example of topical multi-principle element alloys with superior cryogenic and high-temperature mechanical strength, corrosion, oxidation resistance, and yet-to-be-explored magnetic and electronic functionalities. The remarkable properties of this transition metal ternary system are not only due to atomic radii, electronic [...] Read more.
CoNiCr is a prototypical example of topical multi-principle element alloys with superior cryogenic and high-temperature mechanical strength, corrosion, oxidation resistance, and yet-to-be-explored magnetic and electronic functionalities. The remarkable properties of this transition metal ternary system are not only due to atomic radii, electronic configurational mismatch, and atomic volume misfit but are also dependent on the debated magnetically driven chemical short-range order. The current study focuses on the electric and magnetic properties of the single-phase face-centered cubic CoNi(Cr/V) system in which V is introduced to the system at the expense of Cr to fine-tune the volume misfit in the system. All the samples exhibited ultra-small magnetic moments due to the complex magnetic interactions of the constituent elements. The electric transport measurements revealed a strange metallicity evidenced through the observation of the linear temperature dependence of the resistivity. Our findings support the recent theoretical studies on the magnetically driven chemical short-range order of the CoNiCr system. Full article
(This article belongs to the Special Issue Compositional Complex Alloys: From Amorphous to High-Entropy)
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15 pages, 5097 KB  
Article
Modeling of Optimized Lattice Mismatch by Carbon-Dioxide Laser Annealing on (In, Ga) Co-Doped ZnO Multi-Deposition Thin Films Introducing Designed Bottom Layers
by Jaeyong Yun, Min-Sung Bae, Jin Su Baek, Tae Wan Kim, Sung-Jin Kim and Jung-Hyuk Koh
Nanomaterials 2023, 13(1), 45; https://doi.org/10.3390/nano13010045 - 22 Dec 2022
Cited by 11 | Viewed by 3287
Abstract
In this study, modeling of optimized lattice mismatch by carbon-dioxide annealing on (In, Ga) co-doped ZnO multi-deposition thin films was investigated with crystallography and optical analysis. (In, Ga) co-doped ZnO multi-deposition thin films with various types of bottom layers were fabricated on sapphire [...] Read more.
In this study, modeling of optimized lattice mismatch by carbon-dioxide annealing on (In, Ga) co-doped ZnO multi-deposition thin films was investigated with crystallography and optical analysis. (In, Ga) co-doped ZnO multi-deposition thin films with various types of bottom layers were fabricated on sapphire substrates by solution synthesis, the spin coating process, and carbon-dioxide laser irradiation with post annealing. (In, Ga) co-doped ZnO multi-deposition thin films with Ga-doped ZnO as the bottom layer showed the lowest mismatch ratio between the substrate and the bottom layer of the film. The carbon-dioxide laser annealing process can improve electrical properties by reducing lattice mismatch. After applying the carbon-dioxide laser annealing process to the (In, Ga) co-doped ZnO multi-deposition thin films with Ga-doped ZnO as the bottom layer, an optimized sheet resistance of 34.5 kΩ/sq and a high transparency rate of nearly 90% in the visible light wavelength region were obtained. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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