Search Results (8)

The utilization of polyethylene terephthalate (PET) powder as aggregate in the development of environmentally friendly high-ductility composites (P-EHDC) offers a promising pathway for advancing sustainable and high-performance concrete materials. Despite its potential, the fracture behavior of P-EHDC—particularly under the influence of alkali-activated precursors—remains insufficiently explored. In this study, the fracture performance of P-EHDC was evaluated by varying the precursor composition ratios (GGBS:FA = 4:6, 3:7, and 2:8) and PET powder replacement ratios (0%, 15%, 30%, and 45% by volume). Fracture modes, Mode I fracture energy (G_F), and crack propagation behavior were analyzed using the J-integral method. All specimens exhibited ductile fracture characteristics, a clear contrast to the brittle failure observed in conventional concrete. The replacement of 15 vol% PET powder significantly increased G_F in precursor systems with higher GGBS content (4:6 and 3:7), and 30 vol% was more effective in fly ash-rich systems (2:8). The J-integral method, which offers broader applicability compared to conventional methods such as the double-K fracture model, provided a more comprehensive understanding of the fracture behavior. The results showed that PET powder reduced the matrix fracture toughness, promoted matrix cracking, and weakened the fiber-bridging effect, leading to enhanced energy absorption via fiber pull-out. At low PET powder replacement ratios (e.g., 15 vol%), the cracking threshold of the matrix was not significantly reduced, while more fibers engaged during the crack instability stage to absorb fracture energy through pull-out. This behavior highlights the synergistic toughening effect between PET powder and fibers in the P-EHDC system. The effect became more pronounced when the PET content was below 45 vol% and the precursor matrix contained a higher proportion of GGBS, leading to enhanced ductility. This study introduces a novel approach to fracture behavior analysis in PET-modified alkali-activated composites and provides theoretical support for the toughening design of high-performance, low-carbon concrete materials. Full article

The fracture mechanism and macro-properties of SVSAC were studied using a novel test system combined with numerical simulations, which included three-point bending beam tests, the digital image correlation (DIC) technique, scanning electron microscopy (SEM), and ABAQUS analyses. In total, 9 groups and 36 specimens were fabricated by considering two critical parameters: initial notch-to-depth ratios (a₀/h) and concrete mix components (seawater and volcanic scoria coarse aggregate (VSCA)). Changes in fracture parameters, such as the load-crack mouth opening displacement curve (P-CMOD), load-crack tip opening displacement curve (P-CTOD), and fracture energy (G_f), were obtained. The typical double-K fracture parameters (i.e., initial fracture toughness ($K_{\mathrm{IC}}^{\mathrm{ini}}$) and unstable fracture toughness ($K_{\mathrm{IC}}^{\mathrm{un}}$)) and tension-softening (σ-CTOD) curve were analyzed. The test results showed that the initial cracking load (P_ini), G_f, and characteristic length (L_ch) of the SVSAC increased with decreasing a₀/h. Compared with the ordinary concrete (OC) specimen, the P-CMOD and P-CTOD curves of the specimen changed after using seawater and VSCA. The evolution of the crack propagation length was obtained through the DIC technique, indicating cracks appeared earlier and the fracture properties of specimen decreased after using VSCA. Generally, the $K_{\mathrm{IC}}^{\mathrm{un}}$ and $K_{\mathrm{IC}}^{\mathrm{ini}}$ of SVSAC were 36.17% and 8.55% lower than those of the OC specimen, respectively, whereas the effects of a₀/h were negligible. The reductions in P_ini, G_f, and L_ch of the specimen using VSCA were 10.94%, 32.66%, and 60.39%, respectively; however, seawater efficiently decreased the negative effect of VSCA on the fracture before the cracking width approached 0.1 mm. Furthermore, the effects of specimen characteristics on the fracture mechanism were also studied through numerical simulations, indicating the size of the beam changed the fracture toughness. Finally, theoretical models of the double-K fracture toughness and the σ-CTOD relations were proposed, which could prompt their application in marine structures. Full article

The aim of this research is to investigate basalt as a natural mineral-based fibre together with a vitrimeric resin as a sustainable alternative to standard composite materials. Vitrimers combine the properties of thermoset and thermoplastic polymers, enabling the repair of specimens and hence prolonging the lifetime of the composite material. The micro-mechanical characteristics between the basalt fibres and the vitrimer resin are reported and shown to match those of a standard Skyflex K51 epoxy resin. Discontinuous (4 mm) basalt fibres were employed to produce aligned discontinuous fibre-reinforced composites (ADFRCs) using the high-performance discontinuous fibre (HiPerDiF) technology. The mechanical characteristics of the laminates were investigated through tensile testing and the fracture zones were analysed under a scanning electron microscope. By normalising the results by their respective fibre volume fraction, it was discovered that the vitrimer–basalt ADFRCs exhibited, on average, a 4% higher strength and a 25% higher stiffness compared to their basalt epoxy counterparts. The repair potential of the vitrimer ADFRC specimens was explored during low-temperature compression repair. Two approaches were tested using double-sided local- and full-patch repair. Both successfully recovered a significant amount of their prime strength. In conclusion, the potential of the sustainable vitrimer–basalt composite is shown by its competitive mechanical performance. Combining this with the manufacturing flexibility, repair potential, and recyclability of the material, the vitrimer–basalt composite seems to be a competitive alternative to standard glass epoxies. Full article

Lost circulation control remains a challenge in drilling operations. Self-healing gels, capable of self-healing in fractures and forming entire gel block, exhibit excellent resilience and erosion resistance, thus finding extensive studies in lost circulation control. In this study, layered double hydroxide, Acrylic acid, 2-Acrylamido-2-methylpropane sulfonic acid, and CaCl₂ were employed to synthesize organic-inorganic nanocomposite gel with self-healing properties. The chemical properties of nanocomposite gels were characterized using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, X-ray photoelectron spectroscopy and thermogravimetric analysis. layered double hydroxide could be dispersed and exfoliated in the mixed solution of Acrylic acid and 2-Acrylamido-2-methylpropane sulfonic acid, and the swelling behavior, self-healing time, rheological properties, and mechanical performance of the nanocomposite gels were influenced by the addition of layered double hydroxide and Ca²⁺. Optimized nanocomposite gel AC₆L₃, at 90 °C, exhibits only a self-healing time of 3.5 h in bentonite mud, with a storage modulus of 4176 Pa, tensile strength of 6.02 kPa, and adhesive strength of 1.94 kPa. In comparison to conventional gel, the nanocomposite gel with self-healing capabilities demonstrated superior pressure-bearing capacity. Based on these characteristics, the nanocomposite gel proposed in this work hold promise as a candidate lost circulation material. Full article

This study examined the fracture and failed performance of foamed concrete materials by testing normalized notched beams under three-point bending via three methods: inverse analysis, digital image correlation (DIC), and finite element modeling (FEM). It also discussed both experimental and FEM characteristics. However, inverse analysis is only applicable for specimens with a notch height of 30 mm. Bilinear softening of the tested beams was estimated to identify the fracture energy (G_F), critical crack length (a_c), and elastic modulus (E). Additionally, the fracture toughness was calculated by adopting the double-K method (initiation fracture, unstable fracture, and cohesive fracture). Two-dimensional FEA modeling of the fracture was conducted using the traction-separation law (TSL), incorporating the extended finite element method (XFEM) and cohesive zone (CZM) techniques. A finite element sensitivity for the XFEM and CZM was performed, with the global mesh size of 2 and the damage stabilization cohesion of 1 × 10⁻⁵ showed good convergence and were used in other models. Further comparison of the DIC experiment findings with those from the FEM demonstrated good agreement in terms of crack propagation simulation. Full article

Saturated concrete is significantly different from dry concrete in fracture mechanical properties. Using the wedge-splitting tensile method to research the rule of change in moisture content, double-K fracture toughness and fracture energy of three strength grades (C20, C30, and C40) of concrete immersed in a free water environment for 0 h, 2 h, 5 h, 24 h, and 120 h were studied in order to provide support for the safety evaluation of concrete structures in a water environment. The initial cracking fracture toughness of C20, C30, and C40 concrete in saturated state were, respectively, 29.6%, 23.2%, and 33.4% lower than that in dry state. The unstable fracture toughness of C20, C30, and C40 concrete in saturated state were, respectively, 22.7%, 23.9% and 33.8% lower than that in dry state. The fracture energy of C20, C30, and C40 concrete in saturated state are only 71.99%, 70.29%, and 66.11% of that in dry state, respectively. The initial cracking fracture toughness and unstable fracture toughness of concrete all show a linear, decreasing trend with an increase in moisture content. Before the crack initiation, the measured P–CMOD curve had an obvious linear elastic stage, stable expansion stage, and unstable expansion stage. The critical crack opening displacement gradually decreases with an increase in moisture content; the deformation capacity and toughness of concrete are shown to decrease. The humidity state should be fully considered when evaluating the fracture mechanical properties of concrete. Full article

Natural rubber latex (NRL) is commonly employed to manufacture medical protective appliances. However, the characteristics of weakness and fragility of NRL membranes limit their further application. To achieve excellent strength and damage-resistance of the rubber membrane, this work reported a facile core–shell structure construction strategy via self-assembly with modified sodium lignosulfonate (MSLS) and NRL to create a tough membrane. The double network can be formed after introducing polyamide epichlorohydrin resin (PAE) into the NRL membrane. Specifically, the first robust MSLS-PAE network can break in advance to dissipate applied energy, thereby achieving high fracture energy and tensile strength of ~111.51 kJ m⁻² and ~37 MPa, respectively, which overtakes numerous soft materials. This work facilitates more studies on latex/lignin-based products with high performance and good stability for the functional application of biopolymer. Full article

This paper presents the results of an experimental program aimed at the assessment of the freeze–thaw (F–T) resistance of concrete based on the evaluation of fracture tests accompanied by acoustic emission measurements. Two concretes of similar mechanical characteristics were manufactured for the experiment. The main difference between the C1 and C2 concrete was in the total number of air voids and in the A300 parameter, where both parameters were higher for C1 by about 35% and 52%, respectively. The evaluation of the fracture characteristics was performed on the basis of experimentally recorded load–deflection and load–crack mouth opening displacement diagrams using two different approaches: linear fracture mechanics completed with the effective crack model and the double-K model. The results show that both approaches gave similar results, especially if the nonlinear behavior before the peak load was considered. According to the results, it can be stated that continuous AE measurement is beneficial for the assessment of the extent of concrete deterioration, and it suitably supplements the fracture test evaluation. A comparison of the results of fracture tests with the resonance method and splitting tensile strength test shows that all testing methods led to the same conclusion, i.e., the C1 concrete was more F–T-resistant than C2. However, the fracture test evaluation provided more detailed information about the internal structure deterioration due to the F–T exposure. Full article