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Keywords = diagenetic environment

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19 pages, 13286 KiB  
Article
Differential Evolutionary Mechanisms of Tight Sandstone Reservoirs and Their Influence on Reservoir Quality: A Case Study of Carboniferous–Permian Sandstones in the Shenfu Area, Ordos Basin, China
by Xiangdong Gao, You Guo, Hui Guo, Hao Sun, Xiang Wu, Mingda Zhang, Xirui Liu and Jiawen Deng
Minerals 2025, 15(7), 744; https://doi.org/10.3390/min15070744 - 16 Jul 2025
Viewed by 161
Abstract
The Carboniferous–Permian tight sandstone gas reservoirs in the Shenfu area of the Ordos Basin in China are characterized by the widespread development of multiple formations. However, significant differences exist among the tight sandstones of different formations, and their formation mechanisms and key controlling [...] Read more.
The Carboniferous–Permian tight sandstone gas reservoirs in the Shenfu area of the Ordos Basin in China are characterized by the widespread development of multiple formations. However, significant differences exist among the tight sandstones of different formations, and their formation mechanisms and key controlling factors remain unclear, hindering the effective selection and development of favorable tight gas intervals in the study area. Through comprehensive analysis of casting thin section (CTS), scanning electron microscopy (SEM), cathodoluminescence (CL), X-ray diffraction (XRD), particle size and sorting, porosity and permeability data from Upper Paleozoic tight sandstone samples, combined with insights into depositional environments, burial history, and chemical reaction processes, this study clarifies the characteristics of tight sandstone reservoirs, reveals the key controlling factors of reservoir quality, confirms the differential evolutionary mechanisms of tight sandstone of different formations, reconstructs the diagenetic sequence, and constructs an evolution model of reservoir minerals and porosity. The research results indicate depositional processes laid the foundation for the original reservoir properties. Sandstones deposited in tidal flat and deltaic environments exhibit superior initial reservoir qualities. Compaction is a critical factor leading to the decline in reservoir quality across all formations. However, rigid particles such as quartz can partially mitigate the pore reduction caused by compaction. Early diagenetic carbonate cementation reduces reservoir quality by occupying primary pores and hindering the generation of secondary porosity induced by acidic fluids, while later-formed carbonate further densifies the sandstone by filling secondary intragranular pores. Clay mineral cements diminish reservoir porosity and permeability by filling intergranular and intragranular pores. The Shanxi and Taiyuan Formations display relatively poorer reservoir quality due to intense illitization. Overall, the reservoir quality of Benxi Formation is the best, followed by Xiashihezi Formation, with the Taiyuan and Shanxi Formations exhibiting comparatively lower qualities. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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32 pages, 21563 KiB  
Article
Diagenetic Classification—A New Concept in the Characterization of Heterogeneous Carbonate Reservoirs: Permian–Triassic Successions in the Persian Gulf
by Hamzeh Mehrabi, Saghar Sadat Ghoreyshi, Yasaman Hezarkhani and Kulthum Rostami
Minerals 2025, 15(7), 690; https://doi.org/10.3390/min15070690 - 27 Jun 2025
Viewed by 299
Abstract
Understanding diagenetic processes is fundamental to characterizing heterogeneous carbonate reservoirs, where variations in pore structures and mineralogy significantly influence reservoir quality and fluid flow behavior. This study presents an integrated diagenetic classification approach applied to the upper Dalan and Kangan formations in the [...] Read more.
Understanding diagenetic processes is fundamental to characterizing heterogeneous carbonate reservoirs, where variations in pore structures and mineralogy significantly influence reservoir quality and fluid flow behavior. This study presents an integrated diagenetic classification approach applied to the upper Dalan and Kangan formations in the Persian Gulf. Utilizing extensive core analyses, petrographic studies, scanning electron microscopy (SEM) imaging, and petrophysical data, six distinct diagenetic classes were identified based on the quantification of key processes such as dolomitization, dissolution, cementation, and compaction. The results reveal that dolomitization and dissolution enhance porosity and permeability, particularly in high-energy shoal facies, while cementation and compaction tend to reduce reservoir quality. A detailed petrographic examination and rock typing, including pore type classification and hydraulic flow unit analysis using flow zone indicator methods, allowed the subdivision of the reservoir into hydraulically meaningful units with consistent petrophysical characteristics. The application of the Stratigraphic Modified Lorenz Plot facilitated large-scale reservoir zonation, revealing the complex internal architecture and significant heterogeneity controlled by depositional environments and diagenetic overprints. This diagenetic classification framework improves predictive modeling of reservoir behavior and fluid distribution, supporting the optimization of exploitation strategies in heterogeneous carbonate systems. The approach demonstrated here offers a robust template for similar carbonate reservoirs worldwide, emphasizing the importance of integrating diagenetic quantification with multi-scale petrophysical and geological data to enhance reservoir characterization and management. Full article
(This article belongs to the Special Issue Carbonate Petrology and Geochemistry, 2nd Edition)
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21 pages, 4887 KiB  
Article
The Formation Mechanisms of Ultra-Deep Effective Clastic Reservoir and Oil and Gas Exploration Prospects
by Yukai Qi, Zongquan Hu, Jingyi Wang, Fushun Zhang, Xinnan Wang, Hanwen Hu, Qichao Wang and Hanzhou Wang
Appl. Sci. 2025, 15(13), 6984; https://doi.org/10.3390/app15136984 - 20 Jun 2025
Viewed by 450
Abstract
This study systematically analyzes reservoir formation mechanisms under deep burial conditions, integrating macroscopic observations from representative ultra-deep clastic reservoirs in four major sedimentary basins in central and western China. Developing effective clastic reservoirs in ultra-deep strata (6000–8000 m) remains a critical yet debated [...] Read more.
This study systematically analyzes reservoir formation mechanisms under deep burial conditions, integrating macroscopic observations from representative ultra-deep clastic reservoirs in four major sedimentary basins in central and western China. Developing effective clastic reservoirs in ultra-deep strata (6000–8000 m) remains a critical yet debated topic in petroleum geology. Recent advances in exploration techniques and geological understanding have challenged conventional views, confirming the presence of viable clastic reservoirs at such depths. Findings reveal that reservoir quality in ultra-deep strata is preserved and enhanced through the interplay of sedimentary, diagenetic, and tectonic processes. Key controlling factors include (1) high-energy depositional environments promoting primary porosity development, (2) proximity to hydrocarbon source rocks enabling multi-phase hydrocarbon charging, (3) overpressure and low geothermal gradients reducing cementation and compaction, and (4) late-stage tectonic fracturing that significantly improves permeability. Additionally, dissolution porosity and fracture networks formed during diagenetic and tectonic evolution collectively enhance reservoir potential. The identification of favorable reservoir zones under the sedimentation–diagenesis-tectonics model provides critical insights for future hydrocarbon exploration in ultra-deep clastic sequences. Full article
(This article belongs to the Special Issue Advances in Reservoir Geology and Exploration and Exploitation)
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25 pages, 20771 KiB  
Article
Sedimentary and Early Diagenetic Responses to the Huaiyuan Movement During the Early–Middle Ordovician Transition in the Ordos Basin, North China
by Hao Quan, Zhou Yu, Zhanfeng Qiao, Chenqing Li, Pan Xia, Zhongtang Su, Huaguo Wen, Min Qin and Meng Ning
Geosciences 2025, 15(6), 219; https://doi.org/10.3390/geosciences15060219 - 12 Jun 2025
Viewed by 404
Abstract
The early Paleozoic Huaiyuan Movement created a major unconformity in the Ordos Basin, significantly influencing sedimentation and early diagenesis in both the overlying and underlying strata near the unconformity. However, the origins of the associated dolomite and silica near this unconformity remain poorly [...] Read more.
The early Paleozoic Huaiyuan Movement created a major unconformity in the Ordos Basin, significantly influencing sedimentation and early diagenesis in both the overlying and underlying strata near the unconformity. However, the origins of the associated dolomite and silica near this unconformity remain poorly understood. This study aims to reveal how this tectonic event controlled the Early–Middle Ordovician sedimentary environments and early diagenetic processes. The petrological and geochemical results indicate a progressive transition from a dolomitic tidal flat to an intra-platform depression, culminating in a mixed tidal flat during the Early-to-Middle Ordovician, driven by the Huaiyuan Movement. Furthermore, this movement, accompanied by intense weathering and erosion, increased the supply of marine dissolved silica (DSi) and terrestrial nutrients. Consequently, extensive tidal-edge biogenic silica accumulated, which later precipitated as siliceous-cemented dolomite during a shallow-burial stage. We propose a conceptual model of the sedimentary–early diagenetic processes in response to the Huaiyuan Movement, providing novel insights into the regional paleoenvironmental evolution across the Early–Middle Ordovician transition in the Ordos Basin. Full article
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20 pages, 7353 KiB  
Reply
Early Cretaceous Zn-Pb (Ba±Ag±Cu±Fe±Mn) Deposits of Iran: Irish Type or Mississippi Valley Type? Reply to Nejadhadad et al. Comment on “Rajabi et al. Barite Replacement as a Key Factor in the Genesis of Sediment-Hosted Zn-Pb±Ba and Barite-Sulfide Deposits: Ore Fluids and Isotope (S and Sr) Signatures from Sediment-Hosted Zn-Pb±Ba Deposits of Iran. Minerals 2024, 14, 671”
by Abdorrahman Rajabi, Pouria Mahmoodi, Pura Alfonso, Carles Canet, Colin J. Andrew, Reza Nozaem, Saeideh Azhdari, Somaye Rezaei, Zahra Alaminia, Somaye Tamarzadeh, Ali Yarmohammadi, Ghazaleh Khan Mohammadi, Negin Kourangi and Rasoul Saeidi
Minerals 2025, 15(6), 635; https://doi.org/10.3390/min15060635 - 11 Jun 2025
Viewed by 639
Abstract
This study critically examines the early Cretaceous carbonate-hosted Zn-Pb (±Ba±Cu) deposits of the Malayer-Esfahan (MEMB) and Yazd-Anarak (YAMB) metallogenic belts in Iran, which have been inaccurately classified as Mississippi Valley type (MVT) deposits by Nejadhadad et al. (2025). Our findings reveal significant differences [...] Read more.
This study critically examines the early Cretaceous carbonate-hosted Zn-Pb (±Ba±Cu) deposits of the Malayer-Esfahan (MEMB) and Yazd-Anarak (YAMB) metallogenic belts in Iran, which have been inaccurately classified as Mississippi Valley type (MVT) deposits by Nejadhadad et al. (2025). Our findings reveal significant differences in mineralogy, fluid inclusion characteristics, and geochemical signatures compared to typical MVT deposits. These deposits are more akin to Irish-type Zn-Pb mineralization and formed in extensional and passive margin environments around the Nain–Baft back-arc basin. The normal faults in this back-arc rift can transform significantly during inversion and compressional tectonics, reactivating to behave as reverse faults and leading to new geological structures and landscapes. Our study highlights barite replacement as a crucial factor in forming sediment-hosted Zn-Pb (±Ba±Cu) and barite-sulfide deposits. Based on textural evidence, fluid inclusion data, and sulfur isotope analyses, we propose that barite plays a fundamental role in controlling subsequent Zn-Pb (±Ba±Cu) mineralization by serving as both a favorable host and a significant sulfur source. Furthermore, diagenetic barite may act as a precursor to diverse types of sediment-hosted Zn-Pb (±Ba±Cu) mineralization, refining genetic models for these deposits. Sulfur isotope analyses of Irish-type deposits show a broad δ34S range (−28‰ to +5‰), indicative of bacterial sulfate reduction (BSR). Nevertheless, more positive δ34S values (+1‰ to +36‰) and textural evidence in shale-hosted massive sulfide (SHMS) deposits suggest a greater role for thermochemical sulfate reduction (TSR) in sulfide mineralization. Full article
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28 pages, 59439 KiB  
Article
The Middle–Late Permian to Late Cretaceous Mediterranean-Type Karst Bauxites of Western Iran: Authigenic Mineral Forming Conditions and Critical Raw Materials Potential
by Farhad Ahmadnejad, Giovanni Mongelli, Ghazal Rafat and Mohammad Sharifi
Minerals 2025, 15(6), 584; https://doi.org/10.3390/min15060584 - 29 May 2025
Viewed by 516
Abstract
The Sanandaj–Sirjan Zone and Zagros Fold–Thrust Belt in Iran host numerous Mediterranean-type karst bauxite deposits; however, their formation mechanisms and critical raw material potential remain ambiguous. This study combines mineralogical and geochemical analyses to explore (1) the formation of authigenic minerals, (2) the [...] Read more.
The Sanandaj–Sirjan Zone and Zagros Fold–Thrust Belt in Iran host numerous Mediterranean-type karst bauxite deposits; however, their formation mechanisms and critical raw material potential remain ambiguous. This study combines mineralogical and geochemical analyses to explore (1) the formation of authigenic minerals, (2) the role of microbial organic processes in Fe cycling, and (3) the assessment of their critical raw materials potential. Mineralogical analyses of the Late Cretaceous Daresard and Middle–Late Permian Yakshawa bauxites reveal distinct horizons reflecting their genetic conditions: Yakshawa exhibits a vertical weathering sequence (clay-rich base → ferruginous oolites → nodular massive bauxite → bleached cap), while Daresard shows karst-controlled profiles (breccia → oolitic-pisolitic ore → deferrified boehmite). Authigenic illite forms via isochemical reactions involving kaolinite and K-feldspar dissolution. Scanning electron microscopy evidence demonstrates illite replacing kaolinite with burial depth enhancing crystallinity. Diaspore forms through both gibbsite transformation and direct precipitation from aluminum-rich solutions under surface conditions in reducing microbial karst environments, typically associated with pyrite, anatase, and fluorocarbonates under neutral–weakly alkaline conditions. Redox-controlled Fe-Al fractionation governs bauxite horizon development: (1) microbial sulfate reduction facilitates Fe3⁺ → Fe2⁺ reduction under anoxic conditions, forming Fe-rich horizons, while (2) oxidative weathering (↑Eh, ↓moisture) promotes Al-hydroxide/clay enrichment in upper profiles, evidenced by progressive total organic carbon depletion (0.57 → 0.08%). This biotic–abiotic coupling ultimately generates stratified, high-grade bauxite. Finally, both the Yakshawa and Daresard karst bauxite ores are enriched in critical raw materials. It is worth noting that the overall enrichment appears to be mostly driven by the processes that led to the formation of the ores and not by the chemical features of the parent rocks. Divergent bauxitization pathways and early diagenetic processes—controlled by paleoclimatic fluctuations, redox shifts, and organic matter decay—govern critical raw material distributions, unlike typical Mediterranean-type deposits where parent rock composition dominates critical raw material partitioning. Full article
(This article belongs to the Section Mineral Deposits)
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22 pages, 12129 KiB  
Article
Metallogenic Age and Tectonic Setting of the Haigou Gold Deposit in Southeast Jilin Province, NE China: Constraints from Magmatic Chronology and Geochemistry
by Zhongjie Yang, Yuandong Zhao, Cangjiang Zhang, Chuantao Ren, Qun Yang and Long Zhang
Minerals 2025, 15(6), 582; https://doi.org/10.3390/min15060582 - 29 May 2025
Viewed by 378
Abstract
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily [...] Read more.
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO2, high K, and high Al2O3 and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article
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14 pages, 7293 KiB  
Article
The Genetic Mechanism and Geological Significance of Calcite in Buried-Hill Karstic Reservoirs: A Case Study of the Lower Paleozoic Carbonate Reservoirs in the Bohai Sea
by Xiuzhang Song, Tongyao Zhang, Peng Hao, Yahao Huang, Yinjun He and Chunyan Zang
Minerals 2025, 15(5), 508; https://doi.org/10.3390/min15050508 - 11 May 2025
Viewed by 438
Abstract
Calcite in hydrocarbon reservoirs records abundant information about diagenetic fluids and environments. Understanding the formation mechanisms of calcite is crucial for predicting reservoir characteristics and hydrocarbon migration. This study identifies the types of authigenic calcite present in the Lower Paleozoic carbonate reservoirs of [...] Read more.
Calcite in hydrocarbon reservoirs records abundant information about diagenetic fluids and environments. Understanding the formation mechanisms of calcite is crucial for predicting reservoir characteristics and hydrocarbon migration. This study identifies the types of authigenic calcite present in the Lower Paleozoic carbonate reservoirs of the Bohai Bay Basin through petrographic analysis, cathodoluminescence, and other experimental methods. By integrating electron probe microanalysis, in situ isotopic analysis, and fluid inclusion studies, we further constrain the source of the diagenetic fluids responsible for the authigenic calcite. The results show that there are at least three types of authigenic calcite in the Lower Paleozoic carbonate reservoirs of the Bohai Sea. Calcite cemented in the syn-depositional-to-early-diagenetic stage displays very weak cathodoluminescence, with δ13C and δ18O and paleo-salinity distributions similar to those of micritic calcite. These features suggest that the calcite was formed during burial heating by sedimentary fluids. Calcite filling fractures shows heterogeneous cathodoluminescence intensity, ranging from weak to strong, indicating multiple stages of cementation. The broad elemental variation and multiple cementation events suggest that the diagenetic fluid sources were diverse. Isotopic data show that samples with carbon isotope values greater than −2.9‰ likely formed through water–rock interaction with fluids retained within the strata, whereas samples exhibiting more negative δ13C were formed from a mixed-source supply of strata and mantle-derived fluids. Calcite that fills karst collapse pores exhibits alternating bright and dark cathodoluminescence, strong negative δ18O shifts, and variability in trace elements such as Mn, Fe, and Co. These characteristics indicate a mixed origin of diagenetic fluids derived from both meteoric freshwater and carbonate-dissolving fluids. Full article
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16 pages, 30990 KiB  
Article
Reservoir Characterization of Tight Sandstone Gas Reservoirs: A Case Study from the He 8 Member of the Shihezi Formation, Tianhuan Depression, Ordos Basin
by Zihao Dong, Xinzhi Yan, Jingong Zhang, Zhiqiang Chen and Hongxing Ma
Processes 2025, 13(5), 1355; https://doi.org/10.3390/pr13051355 - 29 Apr 2025
Viewed by 440
Abstract
Tight sandstone gas reservoirs, characterized by low porosity (typically < 10%) and ultra-low permeability (commonly < 0.1 × 10⁻3 μm2), represent a critical transitional resource in global energy transition, accounting for over 60% of total natural gas production in regions [...] Read more.
Tight sandstone gas reservoirs, characterized by low porosity (typically < 10%) and ultra-low permeability (commonly < 0.1 × 10⁻3 μm2), represent a critical transitional resource in global energy transition, accounting for over 60% of total natural gas production in regions such as North America and Canada. In the northern Tianhuan Depression of the Ordos Basin, the Permian He 8 Member (He is the abbreviation of Shihezi) of the Shihezi Formation serves as one of the primary gas-bearing intervals within such reservoirs. Dominated by quartz sandstones (82%) with subordinate lithic quartz sandstones (15%), these reservoirs exhibit pore systems primarily supported by high-purity quartz and rigid lithic fragments. Diagenetic processes reveal sequential cementation: early-stage quartz cementation provides a framework for subsequent lithic fragment cementation, collectively resisting compaction. Depositionally, these sandstones are associated with fluvial-channel environments, evidenced by a sand-to-mud ratio of ~5.2:1. Pore structures are dominated by intergranular pores (65%), followed by dissolution pores (25%) formed via selective leaching of unstable minerals by acidic fluids in hydrothermal settings, and minor intragranular pores (10%). Authigenic clay minerals, predominantly kaolinite (>70% of total clays), act as the main interstitial material. Reservoir properties average 7.01% porosity and 0.5 × 10⁻3 μm2 permeability, defining a typical low-porosity, ultra-low-permeability system. Vertically stacked sand bodies in the He 8 Member display large single-layer thicknesses (5–12 m) and moderate sealing capacity (caprock breakthrough pressure > 8 MPa), hosting gas–water mixed-phase occurrences. Rock mechanics experiments demonstrate that fractures enhance permeability by >60%, significantly controlling reservoir heterogeneity. Full article
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31 pages, 6101 KiB  
Article
Genesis of the Upper Jurassic Continental Red Sandstones in the Yongjin Area of the Central Junggar Basin: Evidence from Petrology and Geochemistry
by Yongming Guo, Chao Li, Likuan Zhang, Yuhong Lei, Caizhi Hu, Lan Yu, Zongyuan Zheng, Bingbing Xu, Naigui Liu, Yuedi Jia and Yan Li
Minerals 2025, 15(4), 347; https://doi.org/10.3390/min15040347 - 27 Mar 2025
Viewed by 641
Abstract
The sandstone sections in the Upper Jurassic red beds of the Yongjin area in the central Junggar Basin are important oil and gas reservoirs. The debate over whether red beds are of primary depositional or secondary diagenetic origin persists, leading to uncertainties in [...] Read more.
The sandstone sections in the Upper Jurassic red beds of the Yongjin area in the central Junggar Basin are important oil and gas reservoirs. The debate over whether red beds are of primary depositional or secondary diagenetic origin persists, leading to uncertainties in the interpretation of reservoir sedimentary facies. This study uses core samples and employs thin section microscope observations, scanning electron microscopy, X-ray diffraction, and major and trace element analyses to investigate the formation period and paleoclimate conditions of red beds and explore the origin of red sandstone. The Upper Jurassic red beds are mainly deposited in arid delta plain environments. The framework grains of the red sandstone are composed of quartz (averaging 22.6%), feldspar (averaging 16.3%), and rock fragments (averaging 36.7%). The rock fragments in the sandstone are mainly composed of intermediate basic volcanic rocks and cryptocrystalline acid volcanic rocks, which are rich in mafic silicate minerals such as olivine, pyroxene, ilmenite, and magnetite. In situ hematitization of ilmenite is observed in the rock fragments, suggesting that the in situ alteration of mafic silicate minerals in the parent rock is the main source of iron ions for hematite. Tiny hematite crystals (2.1 μm) are observed in clay mineral micropores via SEM. Abundant mixed-layer illite/smectite clay indicates early smectite transformation, providing a minor source of iron ions for hematite. Hematite in the red sandstone occurs as a grain-coating type, predating quartz overgrowth, feldspar overgrowth, and (ferroan) calcite and (ferroan) dolomite precipitation. Residual hematite coatings between detrital grain point contacts indicate that hematite is a product of syn-sedimentary or very early diagenetic precipitation, ruling out the possibility that red sandstone formation was caused by later atmospheric water leaching during the fold and thrust belt stage. The average chemical index of alteration (CIA) for the red sandstone is 52.2, whereas the CIA for the red mudstone averages 59.5, and the chemical index of weathering (CIW) reached a maximum of 69. These values indicate that the rocks have undergone mild chemical weathering in arid climates. Additionally, the ratios of trace elements indicate that the water bodies were in an oxidizing state during the sedimentary period. The arid climate and oxidative water conditions were ideal for hematite preservation, thus facilitating red bed formation. The red bed sediments in the study area represent a direct response to the Late Jurassic aridification event and can be compared to global climate change. The results have important implications for stratigraphic correlation and interpretation of reservoir sedimentary facies in the study area while also providing a valuable case study for global research on red beds. Full article
(This article belongs to the Topic Recent Advances in Diagenesis and Reservoir 3D Modeling)
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31 pages, 16566 KiB  
Article
The Role of Fluid Chemistry in the Diagenetic Transformation of Detrital Clay Minerals: Experimental Insights from Modern Estuarine Sediments
by Anas Muhammad Salisu, Abdulwahab Muhammad Bello, Abduljamiu O. Amao and Khalid Al-Ramadan
Minerals 2025, 15(3), 317; https://doi.org/10.3390/min15030317 - 19 Mar 2025
Viewed by 693
Abstract
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments [...] Read more.
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments like estuaries remain underexplored. This study investigates the impact of fluid composition on the transformation of modern estuarine sediments through hydrothermal experiments using sediments from the Gironde estuary, SW France. A range of natural and synthetic solutions including seawater (SW), 0.1 M KCl (SF1), 0.1 M NaCl, KCl, CaCl2·2H2O, MgCl2·6H2O (SF2), estuarine water (EW), and 0.1 M Na2CO3 (SF3) were used under temperatures from 50 °C to 250 °C for 14 days, with a fixed fluid-to-sediment ratio of 10:1. The results revealed distinct mineralogical transformations driven by fluid composition. Dissolution of detrital feldspars and clay materials began at lower temperatures (<100 °C). The authigenic formation of smectite and its subsequent illitization in K-rich fluids (SW, SF1) occurred between 150 °C and 250 °C, replicating potassium-driven illitization processes observed in natural sandstones. Additionally, chlorite formation occurred through the conversion of smectite in SF2 and EW. Geochemical analysis showed that SF2 produced Mg-rich chlorites, while EW yielded Fe-rich chlorites. This aligns with diagenetic trends in coastal environments, where Fe-rich chlorites are typically associated with estuarine systems. The resulting authigenic illite and chlorite exhibited morphological and chemical characteristics similar to those found in natural sandstones, forming through dissolution-crystallization and solid-state transformation mechanisms. In contrast to illite and chlorite, SF3 produced entirely different mineral phases, including halite and analcime (zeolite), attributed to the high alkalinity and Na-rich composition of the solution. These findings provide valuable insights into the role of fluid chemistry in the diagenetic alteration of modern sediments and their implications for the evolution of sandstone reservoirs, which is critical for energy exploration and transition. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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29 pages, 19276 KiB  
Article
Geochemistry of REE and Other Critical Elements in Deep-Sea Polymetallic Nodules from Interoceanmetal (IOM) Exploration Area in Eastern Part of Clarion–Clipperton Fracture Zone, NE Pacific
by Atanas Hikov, Zlatka Milakovska, Irena Peytcheva, Valcana Stoyanova, Elitsa Stefanova, Tomasz Abramowski, Milen Kadiyski, Silvia Chavdarova, Milen Stavrev and Dimitrina Dimitrova
Minerals 2025, 15(2), 154; https://doi.org/10.3390/min15020154 - 6 Feb 2025
Viewed by 1445
Abstract
Deep-sea Fe-Mn polymetallic nodules formed nowadays at the deep-sea ocean floor were evaluated as promising critical raw materials (CRMs). Here, we report results of polymetallic nodules from the H22_NE block of the Interoceanmetal (IOM) exploration area in the eastern part of the Clarion–Clipperton [...] Read more.
Deep-sea Fe-Mn polymetallic nodules formed nowadays at the deep-sea ocean floor were evaluated as promising critical raw materials (CRMs). Here, we report results of polymetallic nodules from the H22_NE block of the Interoceanmetal (IOM) exploration area in the eastern part of the Clarion–Clipperton Zone (CCZ), NE Pacific Ocean. The polymetallic nodules were studied with X-ray Diffraction, Raman spectroscopy, SEM-EDS, and LA-ICP-MS (bulk nodules and in situ nodule layers). Additionally, we combine geochemical data of polymetallic nodules with the previously reported data of pore waters and sediments from six stations. Our study aims to define the mineral composition and determine the content of CRMs in the polymetallic nodules and to assess the main factors controlling metal deposition and nodule enrichment in some CRMs. Mn content and the Mn/Fe ratio of the nodules classify them mostly as mixed hydrogenetic–diagenetic type. They are also enriched in Ni, Cu, Co, Zn, Mo, W, Li, Tl, and REE. The in situ REE patterns exhibit MREE and HREE enrichment and a variable Ce anomaly that argues for a changing oxic/suboxic environment and periodically changing of diagenetic and hydrogenetic nodule growth. The results of the joint study of the bottom sediments, pore waters, and polymetallic nodules show a complexity of processes that influence the formation of these deposits. The changing oxic and anoxic conditions are well documented in the chemistry of the nodule layers. Probably the most important controlling factors are sedimentation rate, bioturbation, adsorption, desorption, and oxidation. In addition, growth rates, water depth variations, electro-chemical speciation, phosphatization, and the structures of the Fe-Mn adsorbents are also considered. The polymetallic nodule deposits in the IOM contract area are estimated for future mining for Ni, Cu, Co, and Mn resources. They, however, contain additional metals of economic importance, such as REE and other trace elements (referred to as CRMs) that are potential by-products for metal mining. They can significantly increase the economic importance of exploited polymetallic nodules. Full article
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21 pages, 3195 KiB  
Review
Bone Diagenesis and Extremes of Preservation in Forensic Science
by Rhys Williams, Tim Thompson, Caroline Orr and Gillian Taylor
Humans 2025, 5(1), 2; https://doi.org/10.3390/humans5010002 - 24 Jan 2025
Cited by 1 | Viewed by 4309
Abstract
Understanding the composition and diagenetic processes of the deposition environment is pivotal to understanding why bone undergoes preservation or diagenesis. This research explores the complex nexus of diagenesis at the extremes of preservation, via the interdependent chemical, and short- and long-term microbial processes [...] Read more.
Understanding the composition and diagenetic processes of the deposition environment is pivotal to understanding why bone undergoes preservation or diagenesis. This research explores the complex nexus of diagenesis at the extremes of preservation, via the interdependent chemical, and short- and long-term microbial processes that influence diagenesis. These processes include dissolution, ion exchange, hydrolysis, recrystallisation, waterlogging, acidity and alkalinity, soil composition, redox potential, bacterial activity, and microbiome composition. Diagenetic processes are discussed in relation to typical sites and sites with extremes of preservation. Understanding site conditions that impact diagenetic processes is critical to understanding the visual features presented in recovered skeletal material, ensuring an appropriate post-mortem interval is assigned, and for subsequent post hoc analysis of bone. Full article
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32 pages, 13107 KiB  
Article
Terminal Fan Deposition and Diagenetic Control in the Lower Paleogene of the Shahejie Formation, Bonan Sag, Bohai Basin, China: Insights into Reservoir Quality
by Arthur Paterne Mioumnde, Liqiang Zhang, Yiming Yan, Jonathan Atuquaye Quaye, Kevin Mba Zebaze, Victor Sedziafa, Carole Laouna Bapowa, Zeeshan Zafar and Shahab Aman e Room
Minerals 2025, 15(2), 99; https://doi.org/10.3390/min15020099 - 21 Jan 2025
Viewed by 860
Abstract
In the Bonan area, the lower fourth member of the Shahejie Formation (Es4x) is buried beneath a sedimentary pile ranging from 2500 to 5000 m. Understanding the impact of diagenetic alterations on these deeply buried reservoirs is crucial for effective hydrocarbon exploration and [...] Read more.
In the Bonan area, the lower fourth member of the Shahejie Formation (Es4x) is buried beneath a sedimentary pile ranging from 2500 to 5000 m. Understanding the impact of diagenetic alterations on these deeply buried reservoirs is crucial for effective hydrocarbon exploration and production. This study employs a terminal fan sedimentation model, encompassing depositional environments such as feeder channels, distributary channels, floodplains, and basinal zones, to provide insights into the spatial distribution of reservoir properties and their influence on the localization of optimal reservoirs within the sag. The analysis integrates diagenetic facies with well log responses, subsurface porosity trends, and permeability variations across the formation. The petrographic analysis indicates that the sandstone is composed primarily of litharenite, feldspathic litharenite, lithic arkose, and minor amounts of arkose. The dominant clay cement is illite, accompanied by mixed-layer smectite/illite, chlorite, and kaolinite. Thin section observations reveal secondary porosity formed through the dissolution of quartz grains, volcanic rock fragments, and feldspar, along with their associated cements. These sandstones exhibit relatively good sorting, with average porosity and air permeability values of 14.01% and 12.73 mD, respectively. Diagenetic alterations are categorized into three processes: porosity destruction, preservation, and generation. Key diagenetic mechanisms include compaction, cementation, replacement, and dissolution, with compaction exerting the most significant control on reservoir porosity reduction. Statistical analysis indicates that the average porosity loss due to compaction is approximately 13.3%, accounting for about 38% of the original porosity. The detrital rock cement predominantly comprises quartz (42%), feldspar (32%), clay minerals (14%), and carbonate (12%). Under the prevailing depositional conditions, porosity is enhanced by dissolution and fracturing, while late-stage diagenetic cementation by clay and carbonate minerals—excluding chlorite—adversely affects reservoir quality. Consequently, the distributary zone is identified as the primary target for exploration. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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28 pages, 55581 KiB  
Article
Multiscale Pore Architecture and Its Influence on Porosity, Permeability, and Fluid Flow in Tight Gas Reservoirs of the Shihezi H8 Formation, Ordos Basin
by Muhammad Toseef Adnan, Guishan Zhang, Bin Chang, Hu Wei, Ren Peng, Wang Chang and Liang Wang
Energies 2024, 17(23), 5952; https://doi.org/10.3390/en17235952 - 27 Nov 2024
Cited by 2 | Viewed by 1108
Abstract
Characterizing pore network morphology and its influence on critical reservoir properties such as porosity, permeability, and fluid flow pathways is imperative for maximizing production from tight gas sandstone reservoirs. This study integrated petrographic and pore-scale analyses to investigate diagenetic effects on the Shihezi [...] Read more.
Characterizing pore network morphology and its influence on critical reservoir properties such as porosity, permeability, and fluid flow pathways is imperative for maximizing production from tight gas sandstone reservoirs. This study integrated petrographic and pore-scale analyses to investigate diagenetic effects on the Shihezi H8 Formation, Ordos Basin, China. Sixty core plug samples spanning depositional facies from wells were analyzed using thin-section petrography, scanning electron microscopy, laser grain size analysis, mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), and porosity–permeability measurements. Thin-section observations indicated that formation primarily comprises litharenite and sub-litharenite sandstones deposited in fluvial–deltaic environments composed primarily of quartz and feldspar grains. Diagenesis caused significant porosity reduction through initial mechanical compaction, 3–13% quartz cementation, and localized dissolution, resulting in secondary porosity of up to 5%. Three diagenetic facies were differentiated based on variations in mineralogy and diagenetic alterations. MICP classified pore networks into three reservoir types defined by mean throat radii ranging from 0.091 to 0.270 μm. NMR distinguished pore architectures as uniformly microporous, bimodally micro–mesoporous, and heterogeneously distributed multiscale pores. Larger throat radii correlated positively with higher porosity (up to 8.6%), gas porosity (10.5%), and permeability (0.1911 mD). Grain size analysis demonstrated a positive correlation between mean detrital grain diameter (>2.6 φ, 0.18 mm, (180 µm)), and significantly elevated average porosity (5–8%) compared to finer lithologies, implying depositional energy and sorting regimes. Integrating depositional features, diagenetic alterations, and multiscale pore architecture characterization quantitatively and qualitatively enhanced predictions of heterogeneity in hydrocarbon flow behavior amongst these tight reservoirs. The optimized insights from this integrated study provide a framework to guide development strategies and field appraisal methods for maximizing recovery from unconventional tight gas formations. Full article
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