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22 pages, 1048 KiB  
Article
Forests and Green Transition Policy Frameworks: How Do Forest Carbon Stocks Respond to Bioenergy and Green Agricultural Technologies?
by Nguyen Hoang Dieu Linh and Liang Lizhi
Forests 2025, 16(8), 1283; https://doi.org/10.3390/f16081283 - 6 Aug 2025
Abstract
Forests play a crucial role in storing excess carbon released into the atmosphere. By mitigating climate change, forest carbon stocks play a vital role in achieving green transitions. However, limited information is available regarding the factors that affect forest carbon stocks. The primary [...] Read more.
Forests play a crucial role in storing excess carbon released into the atmosphere. By mitigating climate change, forest carbon stocks play a vital role in achieving green transitions. However, limited information is available regarding the factors that affect forest carbon stocks. The primary objective of this analysis is to investigate the impact of green agricultural technologies and bioenergy on forest carbon stocks. The empirical investigation was conducted using the method of moments quantile regression (MMQR) technique. Results using the MMQR approach indicate that bioenergy is beneficial in augmenting forest carbon stores at all levels. A 1% increase in bioenergy is associated with an increase in forest carbon stocks ranging from 3.100 at the 10th quantile to 1.599 at the 90th quantile. In the context of developing economies, similar findings are observed; however, in developed economies, bioenergy only fosters forest carbon stocks at lower and middle quantiles. In contrast, green agricultural technologies have an adverse effect on forest carbon stocks. Green agricultural technologies have a significant negative impact on forest carbon stocks, particularly between the 10th and 80th quantiles, with their influence declining in magnitude from −2.398 to −0.619. This negative connection is observed in both developed and developing countries at most quantiles, except for higher quantiles in developed economies. Gross domestic product (GDP) has an adverse effect on forest carbon stores only in developing countries, whereas human capital diminishes forest carbon stocks in both developed and developing nations. Governments should provide support for the creators of bioenergy and agroforestry technologies so that forest carbon stocks can be increased. Full article
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20 pages, 16139 KiB  
Article
XCH4 Spatiotemporal Variations in a Natural-Gas-Exploiting Basin with Intensive Agriculture Activities Using Multiple Remote Sensing Datasets: Case from Sichuan Basin, China
by Tengnan Wang and Yunpeng Wang
Remote Sens. 2025, 17(15), 2695; https://doi.org/10.3390/rs17152695 - 4 Aug 2025
Viewed by 108
Abstract
The Sichuan Basin is a natural-gas-exploiting area with intensive agriculture activities. However, the spatial and temporal distribution of atmospheric methane concentration and the relationships with intensive agriculture and natural gas extraction activities are not well investigated. In this study, a long-term (2003–2021) dataset [...] Read more.
The Sichuan Basin is a natural-gas-exploiting area with intensive agriculture activities. However, the spatial and temporal distribution of atmospheric methane concentration and the relationships with intensive agriculture and natural gas extraction activities are not well investigated. In this study, a long-term (2003–2021) dataset of column-averaged dry-air mole fraction of methane (XCH4) over the Sichuan Basin and adjacent regions was built by integrating multi-satellite remote sensing data (SCIAMACHY, GOSAT, Sentinel-5P), which was calibrated using ground station data. The results show a strong correlation and consistency (R = 0.88) between the ground station and satellite observations. The atmospheric CH4 concentration of the Sichuan Basin showed an overall higher level (around 20 ppb) than that of the whole of China and an increasing trend in the rates, from around 2.27 ppb to 10.44 ppb per year between 2003 and 2021. The atmospheric CH4 concentration of the Sichuan Basin also exhibits clear seasonal changes (higher in the summer and autumn and lower in the winter and spring) with a clustered geographical distribution. Agricultural activities and natural gas extraction contribute significantly to atmospheric methane concentrations in the study area, which should be considered in carbon emission management. This study provides an effective way to investigate the spatiotemporal distribution of atmospheric CH4 concentration and related factors at a regional scale with natural and human influences using multi-source satellite remote sensing data. Full article
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13 pages, 1870 KiB  
Article
Study on the Spatiotemporal Distribution Characteristics and Constitutive Relationship of Foggy Airspace in Mountainous Expressways
by Xiaolei Li, Yinxia Zhan, Tingsong Cheng and Qianghui Song
Appl. Sci. 2025, 15(15), 8615; https://doi.org/10.3390/app15158615 (registering DOI) - 4 Aug 2025
Viewed by 56
Abstract
To study the generation and dissipation process of agglomerate fog in mountainous expressways and deeply understand the hazard mechanisms of agglomerate fog sections in mountainous expressways, based on the analysis of the geographical location characteristics of mountainous expressways and the spatial and temporal [...] Read more.
To study the generation and dissipation process of agglomerate fog in mountainous expressways and deeply understand the hazard mechanisms of agglomerate fog sections in mountainous expressways, based on the analysis of the geographical location characteristics of mountainous expressways and the spatial and temporal distribution characteristics of agglomerate fog, the airspace constitutive model of agglomerate fog in mountainous expressways was constructed based on Newton constitutive theory. Firstly, the properties of the Newtonian fluid and cluster fog were compared and analyzed, and the influence mechanism of environmental factors such as the altitude difference, topography, water system, valley effect, and vegetation on the generation and dissipation of agglomerate fog in mountainous expressways was analyzed. Based on Newton’s constitutive theory, the constitutive model of temperature, humidity, wind speed, and agglomerate fog points in the foggy airspace of the mountainous expressway was established. Then, the time and spatial distribution of fog in Chongqing and Guizhou from 2021 to 2023 were analyzed. Finally, the model was verified by using the meteorological data and fog warning data of Liupanshui City, Guizhou Province in 2023. The results show that the foggy airspace of mountainous expressways can be defined as “the space occupied by the agglomerate fog that occurs above the mountain expressway”; The temporal and spatial distribution of foggy airspace on expressways in mountainous areas is closely related to the topography, water system, vegetation distribution, and local microclimate formed by thermal radiation. The horizontal and vertical movements of the atmosphere have little influence on the foggy airspace on expressways in mountainous areas. The specific manifestation of time distribution is that the occurrence of agglomerate fog is concentrated from November to April of the following year, and the daily occurrence time is mainly concentrated between 4:00–8:00 and 18:00–22:00. The calculation results of the foggy airspace constitutive model of the expressway in the mountainous area show that when there is low surface radiation or no surface radiation, the fogging value range is [90, 100], and the fogging value range is [50, 70] when there is high surface radiation (>200), and there is generally no fog in other intervals. The research results can provide a theoretical basis for traffic safety management and control of mountainous expressway fog sections. Full article
(This article belongs to the Section Transportation and Future Mobility)
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21 pages, 7111 KiB  
Article
Seasonal Variation in Energy Balance, Evapotranspiration and Net Ecosystem Production in a Desert Ecosystem of Dengkou, Inner Mongolia, China
by Muhammad Zain Ul Abidin, Huijie Xiao, Sanaullah Magsi, Fang Hongxin, Komal Muskan, Phuocthoi Hoang and Muhammad Azher Hassan
Water 2025, 17(15), 2307; https://doi.org/10.3390/w17152307 - 3 Aug 2025
Viewed by 209
Abstract
This study investigates the seasonal dynamics of energy balance, evapotranspiration (ET), and Net Ecosystem Production (NEP) in the Dengkou desert ecosystem of Inner Mongolia, China. Using eddy covariance and meteorological data from 2019 to 2022, the research focuses on understanding how these processes [...] Read more.
This study investigates the seasonal dynamics of energy balance, evapotranspiration (ET), and Net Ecosystem Production (NEP) in the Dengkou desert ecosystem of Inner Mongolia, China. Using eddy covariance and meteorological data from 2019 to 2022, the research focuses on understanding how these processes interact in one of the world’s most water-limited environments. This arid research area received an average of 109.35 mm per annum precipitation over the studied period, classifying the region as a typical arid ecosystem. Seasonal patterns were observed in daily air temperature, with extremes ranging from −20.6 °C to 29.6 °C. Temporal variations in sensible heat flux (H), latent heat flux (LE), and net radiation (Rn) peaked during summer season. The average ground heat flux (G) was mostly positive throughout the observation period, indicating heat transmission from atmosphere to soil, but showed negative values during the winter season. The energy balance ratio for the studied period was in the range of 0.61 to 0.80, indicating challenges in achieving energy closure and ecological shifts. ET exhibited two annual peaks influenced by vegetation growth and climate change, with annual ET exceeding annual precipitation, except in 2021. Net ecosystem production (NEP) from 2019 to 2020 revealed that the Dengkou desert were a net source of carbon, indicating the carbon loss from the ecosystem. In 2021, the Dengkou ecosystem shifted to become a net carbon sink, effectively sequestrating carbon. However, this was sharply reversed in 2022, resulting in a significant net release of carbon. The study findings highlight the complex interactions between energy balance components, ET, and NEP in desert ecosystems, providing insights into sustainable water management and carbon neutrality strategies in arid regions under climate change effect. Full article
(This article belongs to the Special Issue The Observation and Modeling of Surface Air Hydrological Factors)
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16 pages, 3421 KiB  
Article
The Role of Ocean Penetrative Solar Radiation in the Evolution of Mediterranean Storm Daniel
by John Karagiorgos, Platon Patlakas, Vassilios Vervatis and Sarantis Sofianos
Remote Sens. 2025, 17(15), 2684; https://doi.org/10.3390/rs17152684 - 3 Aug 2025
Viewed by 91
Abstract
Air–sea interactions play a pivotal role in shaping cyclone development and evolution. In this context, this study investigates the role of ocean optical properties and solar radiation penetration in modulating subsurface heat content and their subsequent influence on the intensity of Mediterranean cyclones. [...] Read more.
Air–sea interactions play a pivotal role in shaping cyclone development and evolution. In this context, this study investigates the role of ocean optical properties and solar radiation penetration in modulating subsurface heat content and their subsequent influence on the intensity of Mediterranean cyclones. Using a regional coupled ocean–wave–atmosphere model, we conducted sensitivity experiments for Storm Daniel (2023) comparing two solar radiation penetration schemes in the ocean model component: one with a constant light attenuation depth and another with chlorophyll-dependent attenuation based on satellite estimates. Results show that the chlorophyll-driven radiative heating scheme consistently produces warmer sea surface temperatures (SSTs) prior to cyclone onset, leading to stronger cyclones characterized by deeper minimum mean sea-level pressure, intensified convective activity, and increased rainfall. However, post-storm SST cooling is also amplified due to stronger wind stress and vertical mixing, potentially influencing subsequent local atmospheric conditions. Overall, this work demonstrates that ocean bio-optical processes can meaningfully impact Mediterranean cyclone behavior, highlighting the importance of using appropriate underwater light attenuation schemes and ocean color remote sensing data in coupled models. Full article
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20 pages, 4489 KiB  
Article
Effects of Large- and Meso-Scale Circulation on Uprising Dust over Bodélé in June 2006 and June 2011
by Ridha Guebsi and Karem Chokmani
Remote Sens. 2025, 17(15), 2674; https://doi.org/10.3390/rs17152674 - 2 Aug 2025
Viewed by 264
Abstract
This study investigates the effects of key atmospheric features on mineral dust emissions and transport in the Sahara–Sahel region, focusing on the Bodélé Depression, during June 2006 and 2011. We use a combination of high-resolution atmospheric simulations (AROME model), satellite observations (MODIS), and [...] Read more.
This study investigates the effects of key atmospheric features on mineral dust emissions and transport in the Sahara–Sahel region, focusing on the Bodélé Depression, during June 2006 and 2011. We use a combination of high-resolution atmospheric simulations (AROME model), satellite observations (MODIS), and reanalysis data (ERA5, ECMWF) to examine the roles of the low-level jet (LLJ), Saharan heat low (SHL), Intertropical Discontinuity (ITD), and African Easterly Jet (AEJ) in modulating dust activity. Our results reveal significant interannual variability in aerosol optical depth (AOD) between the two periods, with a marked decrease in June 2011 compared to June 2006. The LLJ emerges as a dominant factor in dust uplift over Bodélé, with its intensity strongly influenced by local topography, particularly the Tibesti Massif. The position and intensity of the SHL also play crucial roles, affecting the configuration of monsoon flow and Harmattan winds. Analysis of wind patterns shows a strong negative correlation between AOD and meridional wind in the Bodélé region, while zonal wind analysis emphasizes the importance of the AEJ and Tropical Easterly Jet (TEJ) in dust transport. Surprisingly, we observe no significant correlation between ITD position and AOD measurements, highlighting the complexity of dust emission processes. This study is the first to combine climatological context and case studies to demonstrate the effects of African monsoon variability on dust uplift at intra-seasonal timescales, associated with the modulation of ITD latitude position, SHL, LLJ, and AEJ. Our findings contribute to understanding the complex relationships between large-scale atmospheric features and dust dynamics in this key source region, with implications for improving dust forecasting and climate modeling efforts. Full article
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11 pages, 985 KiB  
Article
Strengthening Western North Pacific High in a Warmer Environment
by Sanghyeon Yun and Namyoung Kang
Climate 2025, 13(8), 162; https://doi.org/10.3390/cli13080162 - 1 Aug 2025
Viewed by 146
Abstract
The geographical response of western North Pacific subtropical high (SH) to environmental conditions such as the El Niño-Southern Oscillation (ENSO) and global warming has been one of the main concerns with respect to extreme events induced by tropical convections. By considering observed outgoing [...] Read more.
The geographical response of western North Pacific subtropical high (SH) to environmental conditions such as the El Niño-Southern Oscillation (ENSO) and global warming has been one of the main concerns with respect to extreme events induced by tropical convections. By considering observed outgoing longwave radiation (OLR) as the strength of subtropical high, this study attempts to further understand the geographical response of SH strength to ENSO and global warming. Here, “SH strength” is defined as the inhibition of regional convections under SH environment. A meridional seesaw pattern among SH strength anomalies is found at 130°–175° E. In addition, the La Niña environment with weaker convections at lower latitudes is characterized by farther westward expansion of SH but with a weaker strength. Conversely, the El Niño environment with stronger convections at lower latitudes leads to shrunken SH but with a greater strength. The influence of the seesaw mechanism appears to be modulated by global warming. The western North Pacific subtropical high strengthens overall under warming in both the La Niña and El Niño environments. This suggests that the weakening effect by drier tropics is largely offset by anomalous highs induced by a warming atmosphere. It is most remarkable that the highest SH strengths appear in a warmer El Niño environment. The finding implies that every new El Niño environment may experience the driest atmosphere ever in the subtropics under global warming. The value of this study lies in the fact that OLR effectively illustrates how the ENSO variation and global warming bring the zonally undulating strength of boreal-summer SH. Full article
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24 pages, 2455 KiB  
Article
Impact of Glycerol and Heating Rate on the Thermal Decomposition of PVA Films
by Ganna Kovtun and Teresa Cuberes
Polymers 2025, 17(15), 2095; https://doi.org/10.3390/polym17152095 - 30 Jul 2025
Viewed by 192
Abstract
This study analyzes the thermal degradation of PVA and PVA/glycerol films in air under varying heating rates. Thermogravimetric analysis (TGA) of pure PVA in both air and inert atmospheres confirmed that oxidative conditions significantly influence degradation, particularly at lower heating rates. For PVA/glycerol [...] Read more.
This study analyzes the thermal degradation of PVA and PVA/glycerol films in air under varying heating rates. Thermogravimetric analysis (TGA) of pure PVA in both air and inert atmospheres confirmed that oxidative conditions significantly influence degradation, particularly at lower heating rates. For PVA/glycerol films in air, deconvolution of the differential thermogravimetry (DTG) curves during the main degradation stage revealed distinct peaks attributable to the degradation of glycerol, PVA/glycerol complexes, and PVA itself. Isoconversional methods showed that, for pure PVA in air, the apparent activation energy (Ea) increased with conversion, suggesting the simultaneous occurrence of multiple degradation mechanisms, including oxidative reactions, whose contribution changes over the course of the degradation process. In contrast, under an inert atmosphere, Ea remained nearly constant, consistent with degradation proceeding through a single dominant mechanism, or through multiple steps with similar kinetic parameters. For glycerol-plasticized films in air, Ea exhibited reduced dependence on conversion compared with that of pure PVA in air, with values similar to those of pure PVA under inert conditions. These results indicate that glycerol influences the oxidative degradation pathways in PVA films. These findings are relevant to high-temperature processing of PVA-based materials and to the design of thermal treatments—such as sterilization or pyrolysis—where control over degradation mechanisms is essential. Full article
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14 pages, 6012 KiB  
Article
Decoding the Primacy of Transportation Emissions of Formaldehyde Pollution in an Urban Atmosphere
by Shi-Qi Liu, Hao-Nan Ma, Meng-Xue Tang, Yu-Ming Shao, Ting-Ting Yao, Ling-Yan He and Xiao-Feng Huang
Toxics 2025, 13(8), 643; https://doi.org/10.3390/toxics13080643 - 30 Jul 2025
Viewed by 249
Abstract
Understanding the differential impacts of emission sources of volatile organic compounds (VOCs) on formaldehyde (HCHO) levels is pivotal to effectively mitigating key photochemical radical precursors, thereby enhancing the regulation of atmospheric oxidation capacity (AOC) and ozone formation. This investigation systematically selected and analyzed [...] Read more.
Understanding the differential impacts of emission sources of volatile organic compounds (VOCs) on formaldehyde (HCHO) levels is pivotal to effectively mitigating key photochemical radical precursors, thereby enhancing the regulation of atmospheric oxidation capacity (AOC) and ozone formation. This investigation systematically selected and analyzed year-long VOC measurements across three urban zones in Shenzhen, China. Photochemical age correction methods were implemented to develop the initial concentrations of VOCs before source apportionment; then Positive Matrix Factorization (PMF) modeling resolved six primary sources: solvent usage (28.6–47.9%), vehicle exhaust (24.2–31.2%), biogenic emission (13.8–18.1%), natural gas (8.5–16.3%), gasoline evaporation (3.2–8.9%), and biomass burning (0.3–2.4%). A machine learning (ML) framework incorporating Shapley Additive Explanations (SHAP) was subsequently applied to evaluate the influence of six emission sources on HCHO concentrations while accounting for reaction time adjustments. This machine learning-driven nonlinear analysis demonstrated that vehicle exhaust nearly always emerged as the primary anthropogenic contributor in diverse functional zones and different seasons, with gasoline evaporation as another key contributor, while the traditional reactivity metric method, ozone formation potential (OFP), tended to underestimate the role of the two sources. This study highlights the primacy of strengthening emission reduction of transportation sectors to mitigate HCHO pollution in megacities. Full article
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14 pages, 2075 KiB  
Article
Quantifying Polar Mesospheric Clouds Thermal Impact on Mesopause
by Arseniy Sokolov, Elena Savenkova, Andrey Koval, Nikolai Gavrilov, Karina Kravtsova, Kseniia Didenko and Tatiana Ermakova
Atmosphere 2025, 16(8), 922; https://doi.org/10.3390/atmos16080922 - 30 Jul 2025
Viewed by 210
Abstract
The article is focused on the quantitative assessment of the thermal impact of polar mesospheric clouds (PMCs) on the mesopause caused by the emission of absorbed solar and terrestrial infrared (IR) radiation by cloud particles. For this purpose, a parameterization of mesopause heating [...] Read more.
The article is focused on the quantitative assessment of the thermal impact of polar mesospheric clouds (PMCs) on the mesopause caused by the emission of absorbed solar and terrestrial infrared (IR) radiation by cloud particles. For this purpose, a parameterization of mesopause heating by PMC crystals has been developed, the main feature of which is to incorporate the thermal properties of ice and the interaction of cloud particles with the environment. Parametrization is based on PMCs zero-dimensional (0-D) model and uses temperature, pressure, and water vapor data in the 80–90 km altitude range retrieved from Solar Occultation for Ice Experiment (SOFIE) measurements. The calculations are made for 14 PMC seasons in both hemispheres with the summer solstice as the central date. The obtained results show that PMCs can make a significant contribution to the heat balance of the upper atmosphere, comparable to the heating caused, for example, by the dissipation of atmospheric gravity waves (GWs). The interhemispheric differences in heating are manifested mainly in the altitude structure: in the Southern Hemisphere (SH), the area of maximum heating values is 1–2 km higher than in the Northern Hemisphere (NH), while quantitatively they are of the same order. The most intensive heating is observed at the lower boundary of the minimum temperature layer (below 150 K) and gradually weakens with altitude. The NH heating median value is 5.86 K/day, while in the SH it is 5.24 K/day. The lowest values of heating are located above the maximum of cloud ice concentration in both hemispheres. The calculated heating rates are also examined in the context of the various factors of temperature variation in the observed atmospheric layers. It is shown in particular that the thermal impact of PMC is commensurate with the influence of dissipating gravity waves at heights of the mesosphere and lower thermosphere (MLT), which parameterizations are included in all modern numerical models of atmospheric circulation. Hence, the developed parameterization can be used in global atmospheric circulation models for further study of the peculiarities of the thermodynamic regime of the MLT. Full article
(This article belongs to the Special Issue Observations and Analysis of Upper Atmosphere (2nd Edition))
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16 pages, 378 KiB  
Article
The Influence of Environmental Policy on Green Total Factor Productivity in the Chinese Construction Industry
by Weizhong Zhou, Chunlu Liu, Yu Zhou, Qihui Li and Yuanhua Wang
Buildings 2025, 15(15), 2688; https://doi.org/10.3390/buildings15152688 - 30 Jul 2025
Viewed by 239
Abstract
As an environmental policy, the Action Plan of Atmosphere Pollution Control in Beijing-Tianjin-Hebei and Surrounding Areas in Autumn and Winter (Action Plan of APC) was implemented in 2017, with the goal of achieving the sustainable growth of the regional economy. This study examines [...] Read more.
As an environmental policy, the Action Plan of Atmosphere Pollution Control in Beijing-Tianjin-Hebei and Surrounding Areas in Autumn and Winter (Action Plan of APC) was implemented in 2017, with the goal of achieving the sustainable growth of the regional economy. This study examines the effect of the Action Plan of APC on green total factor productivity (GTFP) in the Chinese construction industry employing a difference-in-differences (DID) approach. The findings indicate the following: Firstly, the environmental policy of the Action Plan of APC has significantly improved the GTFP of the aforementioned areas, and the result is still valid after robustness testing; secondly, the dynamic effect testing reveals that the influence follows an increasing trend over time; thirdly, due to the different degrees of marketization, the influence of the Action Plan of APC on GTFP in Chinese construction industry exhibits notable regional heterogeneity. From the perspectives of both the government and enterprises, this study offers recommendations for promoting the GTFP of China’s construction industry. It also provides a novel framework for assessing the effect of environmental policies on the GTFP of the Chinese construction industry. Full article
(This article belongs to the Special Issue Promoting Green, Sustainable, and Resilient Urban Construction)
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13 pages, 1480 KiB  
Article
Physicochemical Properties of Coconut and Waste Cooking Oils for Biofuel Production and Lubrication
by Ahissan Innocent Adou, Laura Brelle, Pedro Marote, Muriel Sylvestre, Gerardo Cebriàn-Torrejòn and Nadiège Nomede-Martyr
Fuels 2025, 6(3), 57; https://doi.org/10.3390/fuels6030057 - 30 Jul 2025
Viewed by 303
Abstract
Vegetable oils are an important alternative to the massive use of fuels and lubricants from non-renewable energy sources. In this study, the physicochemical properties of coconut oil and waste cooking oil are investigated for biofuels and biolubricant applications. A transesterification of both oils [...] Read more.
Vegetable oils are an important alternative to the massive use of fuels and lubricants from non-renewable energy sources. In this study, the physicochemical properties of coconut oil and waste cooking oil are investigated for biofuels and biolubricant applications. A transesterification of both oils was reached, and the transesterified oils were characterized by infrared analysis and gas chromatography. The lubricant performances of these oils have been evaluated using a ball-on-plane tribometer under an ambient atmosphere. Different formulations were developed using graphite particles as solid additive. Each initial and modified oil has been investigated as a base oil and as a liquid additive lubricant. The best friction reduction findings have been obtained for both initial oils as liquid additives, highlighting the key role of triglycerides in influencing tribological performances. Full article
(This article belongs to the Special Issue Biofuels and Bioenergy: New Advances and Challenges)
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20 pages, 3936 KiB  
Article
ARIMAX Modeling of Hive Weight Dynamics Using Meteorological Factors During Robinia pseudoacacia Blooming
by Csilla Ilyés-Vincze, Ádám Leelőssy and Róbert Mészáros
Atmosphere 2025, 16(8), 918; https://doi.org/10.3390/atmos16080918 - 29 Jul 2025
Viewed by 205
Abstract
Apiculture is among the most weather-dependent sectors of agriculture; however, quantifying the impact of meteorological factors remains challenging. Beehive weight has long been recognized as an important indicator of colony health, strength, and food availability, as well as foraging activity. Atmospheric influences on [...] Read more.
Apiculture is among the most weather-dependent sectors of agriculture; however, quantifying the impact of meteorological factors remains challenging. Beehive weight has long been recognized as an important indicator of colony health, strength, and food availability, as well as foraging activity. Atmospheric influences on hive weight dynamics have been a subject of research since the early 20th century. This study aims to estimate hourly hive weight variation by applying linear time-series models to hive weight data collected from active apiaries during intensive foraging periods, considering atmospheric predictors. We employed a rolling 24 h forward ARIMAX and SARIMAX model, incorporating meteorological variables as exogenous factors. The median estimates for the study period resulted in model RMSE values of 0.1 and 0.3 kg/h. From numerous meteorological variables, the hourly maximum temperature was found to be the most significant predictor. ARIMAX model results also exhibited a strong diurnal cycle, pointing out the weather-driven seasonality of hive weight variations. Full article
(This article belongs to the Special Issue Climate Change and Agriculture: Impacts and Adaptation (2nd Edition))
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18 pages, 11346 KiB  
Article
Comparative CFD Analysis Using RANS and LES Models for NOx Dispersion in Urban Streets with Active Public Interventions in Medellín, Colombia
by Juan Felipe Rodríguez Berrio, Fabian Andres Castaño Usuga, Mauricio Andres Correa, Francisco Rodríguez Cortes and Julio Cesar Saldarriaga
Sustainability 2025, 17(15), 6872; https://doi.org/10.3390/su17156872 - 29 Jul 2025
Viewed by 204
Abstract
The Latin American and Caribbean (LAC) region faces persistent challenges of inequality, climate change vulnerability, and deteriorating air quality. The Aburrá Valley, where Medellín is located, is a narrow tropical valley with complex topography, strong thermal inversions, and unstable atmospheric conditions, all of [...] Read more.
The Latin American and Caribbean (LAC) region faces persistent challenges of inequality, climate change vulnerability, and deteriorating air quality. The Aburrá Valley, where Medellín is located, is a narrow tropical valley with complex topography, strong thermal inversions, and unstable atmospheric conditions, all of which exacerbate the accumulation of pollutants. In Medellín, NO2 concentrations have remained nearly unchanged over the past eight years, consistently approaching critical thresholds, despite the implementation of air quality control strategies. These persistent high concentrations are closely linked to the variability of the atmospheric boundary layer (ABL) and are often intensified by prolonged dry periods. This study focuses on a representative street canyon in Medellín that has undergone recent urban interventions, including the construction of new public spaces and pedestrian areas, without explicitly considering their impact on NOx dispersion. Using Computational Fluid Dynamics (CFD) simulations, this work evaluates the influence of urban morphology on NOx accumulation. The results reveal that areas with high Aspect Ratios (AR > 0.65) and dense vegetation exhibit reduced wind speeds at the pedestrian level—up to 40% lower compared to open zones—and higher NO2 concentrations, with maximum simulated values exceeding 50 μg/m3. This study demonstrates that the design of pedestrian corridors in complex urban environments like Medellín can unintentionally create pollutant accumulation zones, underscoring the importance of integrating air quality considerations into urban planning. The findings provide actionable insights for policymakers, emphasizing the need for comprehensive modeling and field validation to ensure healthier urban spaces in cities affected by persistent air quality issues. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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33 pages, 4670 KiB  
Article
Universal Prediction of CO2 Adsorption on Zeolites Using Machine Learning: A Comparative Analysis with Langmuir Isotherm Models
by Emrah Kirtil
ChemEngineering 2025, 9(4), 80; https://doi.org/10.3390/chemengineering9040080 - 28 Jul 2025
Viewed by 217
Abstract
The global atmospheric concentration of carbon dioxide (CO2) has exceeded 420 ppm. Adsorption-based carbon capture technologies, offer energy-efficient, sustainable solutions. Relying on classical adsorption models like Langmuir to predict CO2 uptake presents limitations due to the need for case-specific parameter [...] Read more.
The global atmospheric concentration of carbon dioxide (CO2) has exceeded 420 ppm. Adsorption-based carbon capture technologies, offer energy-efficient, sustainable solutions. Relying on classical adsorption models like Langmuir to predict CO2 uptake presents limitations due to the need for case-specific parameter fitting. To address this, the present study introduces a universal machine learning (ML) framework using multiple algorithms—Generalized Linear Model (GLM), Feed-forward Multilayer Perceptron (DL), Decision Tree (DT), Random Forest (RF), Support Vector Machine (SVM), and Gradient Boosted Trees (GBT)—to reliably predict CO2 adsorption capacities across diverse zeolite structures and conditions. By compiling over 5700 experimentally measured adsorption data points from 71 independent studies, this approach systematically incorporates critical factors including pore size, Si/Al ratio, cation type, temperature, and pressure. Rigorous Cross-Validation confirmed superior performance of the GBT model (R2 = 0.936, RMSE = 0.806 mmol/g), outperforming other ML models and providing comparable performance with classical Langmuir model predictions without separate parameter calibration. Feature importance analysis identified pressure, Si/Al ratio, and cation type as dominant influences on adsorption performance. Overall, this ML-driven methodology demonstrates substantial promise for accelerating material discovery, optimization, and practical deployment of zeolite-based CO2 capture technologies. Full article
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