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29 pages, 8624 KB  
Article
Optimal Geomechanical Parameter Selection for Enhanced ROP Modeling: A Systematic Field-Based Comparative Study
by Ahmed S. Alhalboosi, Musaed N. J. AlAwad, Faisal S. Altawati, Mohammed A. Khamis and Mohammed A. Almobarky
Processes 2026, 14(10), 1646; https://doi.org/10.3390/pr14101646 - 19 May 2026
Viewed by 273
Abstract
Accurate prediction of Rate of Penetration (ROP) in carbonate formations remains constrained by the arbitrary selection of geomechanical input parameters in empirical drilling models. This study presents the first systematic field-based evaluation of sixteen geomechanical properties—grouped into three categories: strength parameters [...] Read more.
Accurate prediction of Rate of Penetration (ROP) in carbonate formations remains constrained by the arbitrary selection of geomechanical input parameters in empirical drilling models. This study presents the first systematic field-based evaluation of sixteen geomechanical properties—grouped into three categories: strength parameters (uniaxial compressive strength (UCS), confined compressive strength (CCS), shear strength, thick-walled cylinder strength (TWC), friction angle, and cohesion), elastic moduli (Young’s modulus, shear modulus, bulk modulus, bulk compressibility, dynamic combined modulus (DCM), Poisson’s ratio, brittleness index), and in situ stress parameters (overburden pressure, minimum, and maximum horizontal stresses)—to identify optimal predictors for ROP modeling across PDC bit sizes of 12.25″ and 8.5″. Continuous wireline log data from two vertical carbonate wells in the Middle East (Well A: 1000–3370 m; Well B: 1945 to 3128 m; total intervals of 2370 m and 1183 m, respectively) penetrating formations comprising limestone, dolomite, sandstone, shale, anhydrite, and marly limestone were used. All sixteen geomechanical properties were computed using Interactive Petrophysics (IP) software with lithology-specific empirical correlations and validated against laboratory core measurements (R2 = 0.79–0.95). Pearson and Spearman correlation analyses quantified parameter–ROP relationships, and the Al-Abduljabbar empirical model, recalibrated via multiple nonlinear regression, served as the evaluation framework. DCM consistently exhibited the strongest negative correlation with ROP across both bit sizes and achieved the highest model accuracy (R2 = 0.54, AAPE = 25.33%), significantly outperforming the Bourgoyne and Young model (R2 = 0.26, AAPE = 36.55%). A statistically validated scale-dependent effect was identified: Fisher’s Z-transformation tests confirmed that the correlation reversal between CCS and UCS across bit sizes is statistically significant (CCS: Z = −16.84, p < 0.001; UCS: Z = −6.75, p < 0.001), establishing CCS as the superior predictor at 12.25″ and UCS as the superior predictor at 8.5″—a finding not previously reported in the ROP literature. This reversal is attributed to the larger contact area of the 12.25″ bit, which promotes confinement-dominated rock failure better described by CCS, whereas the smaller bit produces localized stress concentration better represented by UCS. These results establish that (1) optimal geomechanical input selection is bit-size dependent, (2) nonlinear modeling outperforms linear frameworks for strength–ROP relationships, and (3) parameter relevance outweighs coefficient tuning in model robustness. DCM is recommended as the most operationally practical universal input, requiring only conventional compressional sonic and density logs. This study provides a systematic framework for geomechanical parameter selection with direct implications for drilling optimization in heterogeneous carbonate reservoirs. Full article
(This article belongs to the Special Issue Development of Advanced Drilling Engineering)
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22 pages, 7911 KB  
Article
Genesis of the Wuyi Pb Deposit, SW China: Constraints from Fluid Inclusions and C-H-O-S-Pb Isotopes
by Jimin Cai, Jiahui Li, Wenbin Cheng, Wenli Xu, Bo Li, Xinghai Lang, Cuihua Chen, Yiwei Peng and Lei Peng
Minerals 2026, 16(5), 487; https://doi.org/10.3390/min16050487 - 6 May 2026
Viewed by 216
Abstract
The Sichuan–Yunnan–Guizhou (SYG) metallogenic belt hosts numerous carbonate-hosted Pb-Zn deposits, yet the genesis of lead-dominated deposits remains poorly understood. This study investigates the Wuyi Pb deposit, a representative lead-dominated deposit in the SYG belt, through an integrated approach including field geology, fluid inclusion [...] Read more.
The Sichuan–Yunnan–Guizhou (SYG) metallogenic belt hosts numerous carbonate-hosted Pb-Zn deposits, yet the genesis of lead-dominated deposits remains poorly understood. This study investigates the Wuyi Pb deposit, a representative lead-dominated deposit in the SYG belt, through an integrated approach including field geology, fluid inclusion microthermometry, and C-H-O-S-Pb isotope geochemistry. The ore bodies occur as stratoid and lenticular lenses within the dolomitic limestone of the Ordovician Dajing Formation, controlled by both lithology and the Wuyi composite fold structure. Mineralization is divided into two stages: (I) pyrite–sphalerite–dolomite–calcite, and (II) galena–calcite–quartz–anhydrite. Fluid inclusion studies reveal that the ore-forming fluids are of the NaCl-H2O system, characterized by moderate-low temperatures (Stage II, average 201 °C) and moderate-low salinities (Stage II, average 5.35 wt% NaCl eq.). Hydrogen and oxygen isotopes (δD = −100.97 to −76.33‰; δ18Ofluid = 7.09 to 12.10‰) indicate that the ore-forming fluids were predominantly meteoric in origin. Carbon isotopes (δ13C = −4.45 to 0.75‰) suggest that carbon was derived mainly from dissolution of the host carbonate rocks. Sulfur isotopes show a significant shift from Stage I (δ34S = −12.40 to −3.00‰) to Stage II (δ34S = −8.20 to −0.10‰ for sulfides; 25.00–29.40‰ for sulfates), indicating a transition from bacterial sulfate reduction (BSR) to thermochemical sulfate reduction (TSR) as the dominant sulfur reduction mechanism, with sulfur derived from Ordovician seawater sulfate. Lead isotopes (206Pb/204Pb = 18.10–25.37, 207Pb/204Pb = 15.50–21.72, 208Pb/204Pb = 38.29–53.90; μ = 9.30–21.05) demonstrate that metals were sourced predominantly from the Proterozoic basement rocks (Kunyang and Huili groups). Integration of geological, geochemical, and isotopic evidence indicates that the Wuyi Pb deposit formed during the Indosinian post-collisional intracontinental orogeny (ca. 230–200 Ma), when topography-driven meteoric water circulation extracted metals from the Precambrian basement and sulfur from Ordovician strata. Metal precipitation under the reduced sulfur model is caused by decreases in temperature and pressure and the water–rock reaction. This study establishes the Wuyi deposit as an MVT Pb deposit and provides a genetic model for lead-dominated mineralization in the SYG belt. Full article
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22 pages, 15691 KB  
Article
Deformation Characteristics and Sealing Capacity Evaluation of Dolomite-Bearing Anhydrite and Dolomitic Anhydrite Cap Rocks—A Case Study of the Middle Cambrian in the Eastern Tazhong Area
by Tao He, Lianqi Jia and Shunyu Liu
Appl. Sci. 2026, 16(5), 2486; https://doi.org/10.3390/app16052486 - 4 Mar 2026
Viewed by 398
Abstract
The Middle Cambrian salt–anhydrite succession in the Tarim Basin has been regarded as an effective regional cap-rock. However, numerous Ordovician hydrocarbon reservoirs have been discovered above the anhydrite, and recent drilling has identified industrial oil and gas flows beneath anhydrite-bearing intervals. These findings [...] Read more.
The Middle Cambrian salt–anhydrite succession in the Tarim Basin has been regarded as an effective regional cap-rock. However, numerous Ordovician hydrocarbon reservoirs have been discovered above the anhydrite, and recent drilling has identified industrial oil and gas flows beneath anhydrite-bearing intervals. These findings call into question the sealing effectiveness of anhydrite rocks in deep subsalt settings. In this study, X-ray diffraction (XRD), petrographic analysis, scanning electron microscopy (SEM), and triaxial compression tests were conducted to investigate the mineral composition, deformation behavior, and failure mechanisms of anhydrite rocks. The results indicate that: (1) dolomite-bearing anhydrite undergoes plastic deformation at depths greater than 4400~4600 m (~70 MPa confining pressure), whereas dolomitic anhydrite enters the plastic deformation regime below 5200~5400 m (~80 MPa confining pressure); (2) the deformation evolution of the cap rocks can be divided into four stages. Stages I–III are dominated by brittle deformation, with plasticity progressively increasing with confining pressure, whereas Stage IV is characterized by pervasive plastic deformation and strong sealing capacity, representing an effective cap rock during the critical period of hydrocarbon accumulation; (3) Middle Cambrian reservoirs in the eastern Tazhong area were destroyed by reverse faults that cut through brittle Middle Cambrian cap rocks. In contrast, Lower Cambrian gas reservoirs were charged during the Himalayan period, when the cap rocks remained intact, and exhibited strong sealing capacity. This study demonstrates the temporal variability in the sealing effectiveness of Middle Cambrian anhydrite cap rocks in the eastern Tazhong area and provides a methodological basis for deep and ultra-deep subsalt hydrocarbon exploration. Full article
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11 pages, 5740 KB  
Article
Microstructural Changes of Anhydrite–Gypsum Samples During Water Immersion
by Chiara Caselle, Arianna Paschetto, Emanuele Costa, Sabrina Bonetto, Emmanuele Giordano, Pietro Mosca and Anna Ramon
Appl. Sci. 2026, 16(4), 2050; https://doi.org/10.3390/app16042050 - 19 Feb 2026
Viewed by 540
Abstract
Sulphatic evaporites represent a critical challenge for underground engineering due to their high solubility, swelling potential, and sensitivity to changing hydraulic and thermal conditions. In this study, we investigate the temperature-dependent dissolution behavior and microstructural evolution of Triassic sulphate rocks consisting of anhydrite [...] Read more.
Sulphatic evaporites represent a critical challenge for underground engineering due to their high solubility, swelling potential, and sensitivity to changing hydraulic and thermal conditions. In this study, we investigate the temperature-dependent dissolution behavior and microstructural evolution of Triassic sulphate rocks consisting of anhydrite and minor portions of gypsum from the Western Alps. Twelve cylindrical samples were immersed in CaSO4-saturated water solutions at 15 °C, 40 °C, and 60 °C for six months. Periodic mass and volume measurements were combined with Scanner Electron Microscope (SEM) imaging to quantify dissolution and document mineralogical transformations. All samples experienced progressive mass loss, whereas volumetric changes remained below measurement resolution. Dissolution pathways varied strongly with temperature. At 15 °C, dissolution occurred mainly along anhydrite grain boundaries, producing rounded crystal edges, while less effect was observed in the gypsum veins, leaving the intergranular layers preserved. In contrast, at 40–60 °C, gypsum was preferentially dissolved, generating porosity around comparatively unaltered anhydrite grains. These results qualitatively reproduce the temperature-controlled solubility inversion between gypsum and anhydrite predicted by thermodynamic models. No secondary gypsum precipitation or swelling features were observed. The experimental evidence highlights the role of temperature and hydraulic regime in controlling the stability of sulphate rocks and provides insights relevant to tunnel excavation, underground storage facilities, and geomechanical modeling in evaporitic settings. Full article
(This article belongs to the Special Issue Advances in Rock Mechanics: Theory, Method, and Application)
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25 pages, 14734 KB  
Article
Tracing the Origin of Groundwater Salinization in Multilayered Coastal Aquifers Using Geochemical Tracers
by Mariana La Pasta Cordeiro, Johanna Wallström and Maria Teresa Condesso de Melo
Water 2026, 18(2), 252; https://doi.org/10.3390/w18020252 - 17 Jan 2026
Cited by 1 | Viewed by 584 | Correction
Abstract
Salinization represents a significant threat to freshwater resources worldwide, compromising water quality and security. In the Vieira de Leiria–Marinha Grande aquifer, salinization mechanisms are a complex interaction between seawater intrusion and evaporite dissolution. Near the coast, groundwater is mainly influenced by seawater, evidenced [...] Read more.
Salinization represents a significant threat to freshwater resources worldwide, compromising water quality and security. In the Vieira de Leiria–Marinha Grande aquifer, salinization mechanisms are a complex interaction between seawater intrusion and evaporite dissolution. Near the coast, groundwater is mainly influenced by seawater, evidenced by Na-Cl hydrochemical facies, high electrical conductivity, and Na+/Cl, Cl/Br and SO42−/Cl molar ratios consistent with marine signatures. In areas affected by diapiric dissolution, besides elevated electrical conductivity, groundwater is enriched in SO42− and Ca2+ and in minor elements like K+, Li+, B3+, Ba2+ and Sr2+, and high SO42−/Cl and Ca2+/HCO3 molar ratios, indicative of gypsum/anhydrite dissolution. The relationship between δ18O and electrical conductivity further supports the identification of distinct salinity sources. This study integrates hydrogeochemical tracers to investigate hydrochemical evolution in the aquifer with increasing residence time and influence of water–rock interaction, as well as the accurate characterization of salinization mechanisms in multilayer aquifers. A comprehensive understanding of these processes is essential for identifying vulnerable zones and developing effective management strategies to ensure the protection and sustainable use of groundwater resources. Full article
(This article belongs to the Section Water Quality and Contamination)
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23 pages, 666 KB  
Review
A Review of Caprock Integrity in Underground Hydrogen Storage Sites: Implication of Wettability, Interfacial Tension, and Diffusion
by Polyanthi-Maria Trimi, Spyridon Bellas, Ioannis Vakalas, Raoof Gholami, Vasileios Gaganis, Evangelia Gontikaki, Emmanuel Stamatakis and Ioannis V. Yentekakis
Hydrogen 2025, 6(4), 91; https://doi.org/10.3390/hydrogen6040091 - 20 Oct 2025
Cited by 4 | Viewed by 2895
Abstract
As industry moves from fossil fuels to green energy, substituting hydrocarbons with hydrogen as an energy carrier seems promising. Hydrogen can be stored in salt caverns, depleted hydrocarbon fields, and saline aquifers. Among other criteria, these storage solutions must ensure storage safety and [...] Read more.
As industry moves from fossil fuels to green energy, substituting hydrocarbons with hydrogen as an energy carrier seems promising. Hydrogen can be stored in salt caverns, depleted hydrocarbon fields, and saline aquifers. Among other criteria, these storage solutions must ensure storage safety and prevent leakage. The ability of a caprock to prevent fluid from flowing out of the reservoir is, thus, of utmost importance. In this review, the main factors influencing fluid flow are examined. These are the wettability of the caprock formation, the interfacial tension (IFT) between the rock and the gas or liquid phases, and the ability of gases to diffuse through it. To achieve effective sealing, the caprock formation should possess low porosity, a disconnected or highly complicated pore system, low permeability, and remain strongly water-wet regardless of pressure and temperature conditions. In addition, it must exhibit low rock–liquid IFT, while presenting high rock–gas and liquid–gas IFT. Finally, the effective diffusion coefficient should be the lowest possible. Among all of the currently reviewed formations and minerals, the evaporites, low-organic-content shales, mudstones, muscovite, clays, and anhydrite have been identified as highly effective caprocks, offering excellent sealing capabilities and preventing hydrogen leakages. Full article
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14 pages, 2531 KB  
Article
SEM-Based Approaches for the Identification and Quantification of Anhydrite
by Emmanuele Giordano, Arianna Paschetto, Emanuele Costa, Sabrina M. R. Bonetto, Pietro Mosca, Gianluca Frasca and Chiara Caselle
Appl. Sci. 2025, 15(17), 9584; https://doi.org/10.3390/app15179584 - 30 Aug 2025
Cited by 1 | Viewed by 1145
Abstract
For investigating and modeling the swelling potential of anhydrite rocks, it is important to define a fast but accurate, reliable, and repeatable procedure for mineral identification and quantification of anhydrite mineral in rock samples. We propose a quantitative evaluation of the applicability of [...] Read more.
For investigating and modeling the swelling potential of anhydrite rocks, it is important to define a fast but accurate, reliable, and repeatable procedure for mineral identification and quantification of anhydrite mineral in rock samples. We propose a quantitative evaluation of the applicability of two different SEM-based approaches (namely, image analysis and the use of the O/S atomic ratio) for the identification and quantification of anhydrite in polished slices of rock. We compare the results obtained with the bulk densities of the samples and with the outcomes of thermogravimetric analyses, demonstrating high convergence between the different data. We eventually propose a critical comparison between the proposed approaches and the existing methods, overall providing a practical guide for the selection of the best analytical procedure for the quantification of anhydrite content in rocks and, consequently, for the correct estimation of swelling potential. Full article
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29 pages, 2696 KB  
Article
Hydrogeochemical Characterization and Water Quality Index-Based Evaluation of Groundwater for Drinking, Livestock, and Irrigation Use in the Arid Ewaso Ng’iro–Lagh Dera Basin, Kenya
by Githinji Tabitha Wambui, Dindi Edwin Wandubi, Kuria Zacharia Njuguna, Olago Daniel Ochieng and Gicheruh Chrysanthus Muchori
Hydrology 2025, 12(7), 160; https://doi.org/10.3390/hydrology12070160 - 20 Jun 2025
Cited by 4 | Viewed by 3216
Abstract
Groundwater is the main source of water for both domestic and agricultural use in arid regions. This study assessed the hydrogeochemical characteristics and suitability of groundwater for drinking and irrigation in Kenya’s Ewaso Ng’iro–Lagh Dera Basin. A total of 129 borehole groundwater samples [...] Read more.
Groundwater is the main source of water for both domestic and agricultural use in arid regions. This study assessed the hydrogeochemical characteristics and suitability of groundwater for drinking and irrigation in Kenya’s Ewaso Ng’iro–Lagh Dera Basin. A total of 129 borehole groundwater samples were collected and analyzed for pH, electrical conductivity (EC), total hardness, and major ions. The groundwater was found to be mostly neutral to slightly alkaline and ranged from marginal to brackish in salinity. The dominant water type is Na-HCO3, with the ionic order Na+ > Ca2+ > Mg2+ > K+ and HCO3 > Cl > SO42− > NO3. Mineral saturation indices indicate that the water is undersaturated with gypsum and anhydrite but is saturated with calcite, dolomite, and aragonite. Groundwater chemistry is primarily influenced by ion exchange, the mixing of fresh and paleo-saline water, and rock weathering processes. The water quality index (WQI) reveals that 80.5% of groundwater is suitable for drinking. The rest have high levels of sodium, EC, and bicarbonate. Thus, they are not suitable. The irrigation water quality index (IWQI) places most samples in the moderate-to-severe restriction category due to high salinity and sodicity. These findings highlight the importance of properly treating groundwater before use. Full article
(This article belongs to the Section Water Resources and Risk Management)
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20 pages, 3140 KB  
Article
The Influence of Anhydrite on the Mechanical Performance of Calcium Sulfoaluminate Cement-Based Grouting Materials
by Lin Liao, Nathan Saye Teah, Zhiling Liao, Ruiqing Hao, Yubin Zhao and Wanwen Xue
Materials 2025, 18(7), 1547; https://doi.org/10.3390/ma18071547 - 29 Mar 2025
Viewed by 1224
Abstract
Cement-based grouting reinforcement technology is an essential method to enhance the mechanical performance of fractured rock depending on the type of grouting material used. To further understand the influence of anhydrite on the calcium sulfoaluminate cement-based grouting materials, this study investigates the sample [...] Read more.
Cement-based grouting reinforcement technology is an essential method to enhance the mechanical performance of fractured rock depending on the type of grouting material used. To further understand the influence of anhydrite on the calcium sulfoaluminate cement-based grouting materials, this study investigates the sample of the grouting material with (calcium sulfoaluminate cement, anhydrite, and quicklime) under different ratios with a series of experiments including compressive strength, setting time, and slurry pH test. The macro and micro mechanical characteristics of different calcium sulfoaluminate cement grouting samples were revealed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicate that anhydrite enriched the system with needle-like ettringite (AFt), and plume-shaped aluminum hydroxide (AH3), which contributed to the strength improvement. The optimal dosage of anhydrite-quicklime was 80:20 with a compressive strength of 9.5 MPa, 14.7 MPa, and 18.4 MPa at (1 d, 14 d, and 28 d), making up 38.5% of the total strength, and 80% independent of the quicklime dosage (14.2 MPa, 23.2 MPa, and 24.5 MPa), making up 52.5% of the total strength. Furthermore, X-ray diffraction and scanning electron microscopy results proved that anhydrite ratios are the main factor influencing grouting material reinforcement effectiveness and are more beneficial for improving the mechanical performance of calcium sulfoaluminate cement-based grouting material. Full article
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25 pages, 20418 KB  
Article
Differential Evolution and Main Controlling Factors of Inner-Platform Carbonate Reservoirs in Restricted–Evaporative Environment: A Case Study of O2m56 in the Ordos Basin, North China
by Mengying Yang, Xiucheng Tan, Zhaolei Fei, Zixing Lu, Wancai Nie, Ying Xiong, Di Xiao, Jie Xu, Shoukang Zhong and Jingkang Yong
Minerals 2025, 15(3), 236; https://doi.org/10.3390/min15030236 - 26 Feb 2025
Cited by 1 | Viewed by 1044
Abstract
The potential for oil and gas exploration within inter-salt reservoirs is substantial, primarily due to their significant heterogeneity, which complicates accurate predictions. This study focuses on the inter-salt reservoirs of the sixth sub-member of the fifth member of the Majiagou Formation (hereafter referred [...] Read more.
The potential for oil and gas exploration within inter-salt reservoirs is substantial, primarily due to their significant heterogeneity, which complicates accurate predictions. This study focuses on the inter-salt reservoirs of the sixth sub-member of the fifth member of the Majiagou Formation (hereafter referred to as O2m56) in the Ordos Basin, North China. Utilizing core samples, thin sections, and petrophysical data, we investigated the differential evolution and primary controlling factors of the inter-salt carbonate reservoirs. The key findings are as follows: (1) During the sedimentary phase of O2m56, high-energy sediments, such as shoals and microbial mounds, were deposited in highlands, while low-energy sediments, including dolomitic lagoons and gypsiferous lagoons, emerged in depressions from west to east. (2) In a restricted–evaporative environment, highlands are prone to karstification, which significantly enhances the development of inter-salt reservoirs and generates a variety of reservoir spaces, including interparticle dissolved pores, growth-framework dissolved pores, and micropores between vadose silts. (3) The presence of alternating highlands and depressions obstructs seawater flow, leading to a progressive increase in salinity from west to east. This process ultimately facilitates the infilling of reservoir spaces with calcite, anhydrite, and halite cements in the same direction. (4) The three components—reservoir rocks, karstification, and infilling features—exert varying effects in the region and collectively govern the north–south distribution of inter-salt reservoirs. Overall, this study examines the characteristics and controlling factors of carbonate reservoirs within a restricted–evaporative platform environment and provides pertinent research cases for the exploration of inter-salt reservoirs. Full article
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20 pages, 19513 KB  
Article
Seismic Sedimentology for the Characterization of Quaternary Evaporite Facies in Biogas-Bearing Taidong Area, Sanhu Depression, Qaidam Basin, NW China
by Guoyong Liu, Zhaohui Xu, Jiangtao Li, Yong Song, Hongliu Zeng, Xiaomin Zhu, Jixian Tian, Chunming Lin and Lei Jiang
Appl. Sci. 2025, 15(5), 2288; https://doi.org/10.3390/app15052288 - 20 Feb 2025
Viewed by 1418
Abstract
S-wave seismic data are unaffected by natural gas trapped in strata, making them a valuable tool to study evaporite facies comparing to P-wave data. S-wave seismic data were utilized to construct an isochronous framework and analyze evaporite facies by seismic sedimentology methods in [...] Read more.
S-wave seismic data are unaffected by natural gas trapped in strata, making them a valuable tool to study evaporite facies comparing to P-wave data. S-wave seismic data were utilized to construct an isochronous framework and analyze evaporite facies by seismic sedimentology methods in the Quaternary biogenic gas-bearing Taidong area, Sanhu Depression, Qaidam Basin, NW China, with calibration from wireline logs, geochemical evidences, and modern analogs. Techniques of phase rotation, frequency decomposition, R (Red), G (Green), B (Blue) fusion, and stratal slices were integrated to reconstruct seismic geomorphological features. Linear and sub-circular morphologies, resembling those observed in modern saline pans such as Lake Chad, were identified. Observations from Upper Pleistocene outcrops of anhydrite and halite at Yanshan (east of the Taidong area), along with lithological and paleo-environmental records from boreholes SG-5, SG-1, and SG-1b (northwest of the Taidong area), support the seismic findings. The slices generated from the S-wave seismic data indicate a progressive increase in the occurrence of evaporite features from the K2 standard zone upwards. The vertical occurrence of evaporite facies in the Taidong area increases, which coincides with the contemporary regional and global arid paleo-environmental changes. The interpretation of Quaternary stratal slices reveals a transition from a freshwater lake to brackish, saline, and finally, a dry saline pan, overlaid by silt. This analysis provides valuable insights into locating evaporites as cap rocks for biogenic gas accumulation and also into mining the evaporite mineral resources in shallow layers of the Taidong area. Full article
(This article belongs to the Section Earth Sciences)
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19 pages, 8323 KB  
Article
Pore Types and Dolomite Reservoir Genesis of the Fifth Member of the Ordovician Majiagou Formation in the Central and Eastern Ordos Basin
by Shilei Chen, Rong Dai and Shunshe Luo
Appl. Sci. 2024, 14(23), 10976; https://doi.org/10.3390/app142310976 - 26 Nov 2024
Cited by 1 | Viewed by 1655
Abstract
The Ordovician dolomite in the Ordos Basin is an important natural gas reservoir. Exploring dolomite genesis and the factors influencing reservoir characteristics is essential for deep carbonate rock exploration. This study offers a comprehensive analysis of dolomite evolution using methods such as thin-section [...] Read more.
The Ordovician dolomite in the Ordos Basin is an important natural gas reservoir. Exploring dolomite genesis and the factors influencing reservoir characteristics is essential for deep carbonate rock exploration. This study offers a comprehensive analysis of dolomite evolution using methods such as thin-section petrography, isotope analysis, and trace and rare earth elements. The analysis shows that: Based on petrographic observations of the Majiagou Formation in the study area, the dolomite in the study area can be divided into residual oolitic dolomite of synsedimentary or metasomatic origin, micritic dolomite of secondary metasomatism or recrystallization origin, powder crystal dolomite, and fine crystal dolomite. Reservoir pores mainly develop intergranular pores, mold pores, dissolved pores, and fractures. Combined with the characteristics of major elements, trace elements, carbon and oxygen isotopes, rare earth elements, and inclusions in the study area, it can be concluded that the fifth member dolomite of the Majiagou Formation is of shallow–medium burial origin. The diagenetic evolution sequence from the penecontemporaneous period to the middle–deep burial period in the study area is penecontemporaneous dolomite, anhydrite dissolution → seepage silt filling, freshwater dolomite, calcite, and gypsum filling, pressure solution compaction, calcite partial dissolution → gypsum filling, karst cave, buried hydrothermal dolomite, dolomite partial dissolution → calcite complete dissolution, pore dissolution expansion, and quartz pyrite filling. In the early stage of compaction and pressure solution, the primary pores are rapidly reduced, and in the later stage, sutures are generated to provide channels for reservoir fluid migration. The recrystallization reduces the porosity during the middle–deep burial period. Full article
(This article belongs to the Section Earth Sciences)
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17 pages, 6340 KB  
Article
Shale Oil Generation Conditions and Exploration Prospects of the Cretaceous Nenjiang Formation in the Changling Depression, Songliao Basin, China
by Wenjun Zhang, Wenyu Zhang, Shumin Lin, Xing Ke, Min Zhang and Taohua He
Minerals 2024, 14(9), 942; https://doi.org/10.3390/min14090942 - 15 Sep 2024
Cited by 1 | Viewed by 1827
Abstract
Low-maturity shale oil predominates in shale oil resources. China’s onshore shale oil, particularly the Cretaceous Nenjiang Formation in the Songliao Basin, holds significant potential for low-maturity shale oil, presenting promising exploration and development prospects. This study delves into the hydrocarbon generation conditions, reservoir [...] Read more.
Low-maturity shale oil predominates in shale oil resources. China’s onshore shale oil, particularly the Cretaceous Nenjiang Formation in the Songliao Basin, holds significant potential for low-maturity shale oil, presenting promising exploration and development prospects. This study delves into the hydrocarbon generation conditions, reservoir characteristics, and oil-bearing property analysis of the mud shale from the Nen-1 and Nen-2 sub-formations of the Nenjiang Formation to pinpoint favorable intervals for shale oil exploration. Through the integration of lithology, pressure, and fracture distribution data in the study area, favorable zones were delineated. The Nen-1 sub-formation is widely distributed in the Changling Depression, with mud shale thickness ranging from 30 to 100 m and a total organic content exceeding 2.0%. Type I kerogen predominated as the source rock, while some samples contained type II kerogen. Organic microcomponents primarily comprised algal bodies, with vitrinite reflectance (Ro) ranging from 0.5% to 0.8%. Compared to Nen-1 shale, Nen-2 shale exhibited less total organic content, kerogen type, and thermal evolution degree, albeit both are conducive to low-maturity shale oil generation. The Nen-1 and Nen-2 sub-formations predominantly consist of clay, quartz, feldspar, calcite, and pyrite minerals, with minor dolomite, siderite, and anhydrite. Hydrocarbons primarily reside in microfractures and micropores, including interlayer micropores, organic matter micropores, intra-cuticle micropores, and intercrystalline microporosity, with interlayer and intra-cuticle micropores being dominant. The free oil content (S1) in Nen-1 shale ranged from 0.01 mg/g to 5.04 mg/g (average: 1.13 mg/g), while in Nen-2 shale, it ranged from 0.01 mg/g to 3.28 mg/g (average: 0.75 mg/g). The Nen-1 and Nen-2 sub-formations are identified as potential intervals for shale oil exploration. Considering total organic content, oil saturation, vitrinite reflectance, and shale formation thickness in the study area, the favorable zone for low-maturity shale oil generation is primarily situated in the Heidimiao Sub-Depression and its vicinity. The Nen-2 shale-oil-enriched zone is concentrated in the northwest part of the Heidimiao Sub-Depression, while the Nen-1 shale-oil-enriched zone lies in the northeast part. Full article
(This article belongs to the Topic Petroleum Geology and Geochemistry of Sedimentary Basins)
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18 pages, 3399 KB  
Article
A New Mineral Calcioveatchite, SrCaB11O16(OH)5·H2O, and the Veatchite–Calcioveatchite Isomorphous Series
by Igor V. Pekov, Natalia V. Zubkova, Vladimir N. Apollonov, Vasiliy O. Yapaskupt, Sergey N. Britvin and Dmitry Yu. Pushcharovsky
Minerals 2024, 14(9), 901; https://doi.org/10.3390/min14090901 - 2 Sep 2024
Cited by 2 | Viewed by 1534
Abstract
The new mineral calcioveatchite, ideally SrCaB11O16(OH)5·H2O, is a Ca-Sr-ordered analogue of veatchite. It was found at the Nepskoe potassium salt deposit, Irkutsk Oblast, Siberia, Russia in halite-sylvite and sylvite-carnallite rocks, with boracite, hilgardite, kurgantaite, hydroboracite, [...] Read more.
The new mineral calcioveatchite, ideally SrCaB11O16(OH)5·H2O, is a Ca-Sr-ordered analogue of veatchite. It was found at the Nepskoe potassium salt deposit, Irkutsk Oblast, Siberia, Russia in halite-sylvite and sylvite-carnallite rocks, with boracite, hilgardite, kurgantaite, hydroboracite, volkovskite, veatchite, anhydrite, magnesite, and quartz. Calcioveatchite forms prismatic or tabular crystals up to 1 × 1.5 × 3 mm3 and crystal clusters up to 3 mm across. It is transparent and colourless with vitreous lustre. Calcioveatchite is brittle, cleavage is perfect on {010}, the Mohs’ hardness is ca 2, Dmeas is 2.58(1), and Dcalc is 2.567 g cm−3. Calcioveatchite is optically biaxial (+), α = 1.543(2), β = 1.550(5), γ = 1.626(2), 2Vmeas = 30(10)°, and 2Vcalc = 35°. The average chemical composition (wt.%, electron microprobe, H2O calculated by stoichiometry) is: CaO 7.05, SrO 20.70, B2O3 61.96, H2O 10.22, and total 99.93. The empirical formula, calculated based on 22 O apfu = O16(OH)5(H2O) pfu, is Sr1.23Ca0.78B10.99O16(OH)5·H2O. Calcioveatchite is monoclinic, space group P21, a = 6.7030(3), b = 20.6438(9), c = 6.6056(3) Å, β = 119.153(7)°, V = 798.26(8) Å3, and Z = 2. Polytype: 1M. The strongest reflections of the powder XRD pattern [d,Å(I,%)(hkl)] are: 10.35(100)(020), 5.633(12)(110), 5.092(10)(120), 3.447(14)(060), 3.362(13)(101, 051), 3.309(38)(–102), 2.862(10)(012), and 2.585(19)(080). The crystal structure was solved based on single-crystal XRD data, R1 = 0.0420. Calcioveatchite (calcioveatchite-1M) is an isostructural analogue of veatchite-1M with the 11-fold cation polyhedron occupied mainly by Sr [Sr0.902(8)Ca0.098(8)] whereas the 10-fold polyhedron is Ca dominant [Ca0.686(7)Sr0.314(7)]. The chemical composition of veatchite from five localities in Russia (Nepskoe), Kazakhstan (Shoktybay and Chelkar in the North Caspian Region), and the USA (Tick Canyon and Billie Mine in California) was studied, and it is shown to exist in nature as a continuous, almost complete isomorphous series which extends from Ca-free veatchite, Sr2B11O16(OH)5·H2O, to calcioveatchite with the composition Sr1.14Ca0.87B10.99O16(OH)5·H2O. Full article
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Article
The Origins of the Hydrogen Sulphide (H2S) Gas in the Triassic Montney Formation, British Columbia, Canada
by Gareth Chalmers, Pablo Lacerda Silva, Amanda Bustin, Andrea Sanlorenzo and Marc Bustin
Geosciences 2024, 14(8), 224; https://doi.org/10.3390/geosciences14080224 - 21 Aug 2024
Cited by 1 | Viewed by 3596
Abstract
The inexplicable distribution of souring wells (presence of H2S gas) of the unconventional Montney Formation hydrocarbon resource (British Columbia; BC) is investigated by analysing sulphur and oxygen isotopes, coupled with XRD mineralogy, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDX). [...] Read more.
The inexplicable distribution of souring wells (presence of H2S gas) of the unconventional Montney Formation hydrocarbon resource (British Columbia; BC) is investigated by analysing sulphur and oxygen isotopes, coupled with XRD mineralogy, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDX). The sulphur isotopic analysis indicates that the sulphur isotopic range for Triassic anhydrite (δ34S 8.9 to 20.98‰ VCDT) is the same as the H2S sulphur that is produced from the Montney Formation (δ34S 9.3 to 20.9‰ VCDT). The anhydrite in the Triassic rocks is the likely source of the sulphur in the H2S produced in the Montney Formation. The deeper Devonian sources are enriched in 34S and are not the likely source for sulphur (δ34S 17.1 and 34‰ VCDT). This is contradictory to studies on Montney Formation producers in Alberta, with heavier (34S-enriched) sulphur isotopic signatures in H2S gas of all souring Montney Formation producers. These studies conclude that deep-seated faults and fractures have provided conduits for sulphate and/or H2S gas to migrate from deeper sulphur sources in the Devonian strata. There are several wells that show a slightly heavier (34S-enriched) isotopic signature (δ34S 18 to 20‰ VCDT) within the Montney Formation H2S gas producing within close proximity to the deformation front. This variation may be due to such deep-seated faults that acted as a conduit for Devonian sulphur to migrate into the Montney Formation. Our geological model suggests the sulphate-rich fluids have migrated from the Charlie Lake Formation prior to hydrocarbon generation in the Montney Formation (BC). Sulphate has concentrated in discrete zones due to precipitation in conduits like fracture and fault systems. The model fits the observation of multi-well pads containing both sour- and sweet-producing wells indicating that the souring is occurring in very narrow and discrete zones with the Montney Formation (BC). Government agencies and operators in British Columbia should map the anhydrite-rich portions of the Charlie Lake Formation, together with the structural elements from three-dimensional seismic to reduce the risk of encountering unexpected souring. Full article
(This article belongs to the Section Geochemistry)
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