Search Results (4)

Epidote group minerals are one of the three most abundant kinds of heavy minerals in orogenic sediments, the other two being amphibole and garnet. They resist diagenesis better than amphibole and resist weathering in soils better than garnet. Their chemical composition and optical properties vary markedly and systematically with temperature and pressure conditions during growth. Useful information on the metamorphic grade of source rocks can thus be obtained by provenance analysis. In this study, we combine optical, SEM–EDS, and Raman analyses of nine standard crystals of epidote group minerals collected from different rock units exposed in the European Alps and Apennines and develop a Raman library for efficient discrimination of epidote, clinozoisite, zoisite, and allanite by establishing clear user-oriented relationships among optical properties, chemical composition, and Raman fingerprint. This new library allows us to distinguish and reliably determine, directly from their Raman spectrum, the chemical compositions of epidote group minerals during routine heavy mineral analyses of sand/sandstone and silt/siltstone samples down to the size of a few microns. The validity of the approach is illustrated by its application to 41 Bengal Fan turbidites collected from five cores during IODP Expedition 354 and ranging in grain size from medium sand to fine silt. Full article

U-Pb dating by LA ICP-MS is one of the most popular and successful isotopic techniques available to the Earth Sciences to constrain timing and rates of geological processes thanks to its high spatial resolution, good precision (absolute U/Pb age resolution of ca. 2%, 2s), rapidity and relative affordability. The significant and continuous improvement of instrumentation and approaches has opened new fields of applications by extending the range of minerals that can be dated by this method. Following the development and distribution to the community of good quality reference materials in the last decade, rutile U-Pb thermochronology (with a precision only slightly worse than zircon) has become a commonly used method to track cooling of deep-seated rocks. Its sensitivity to mid- to low-crustal temperatures (~450 °C to 650 °C) is ideal to constrain exhumation in active and ancient orogens as well as thermal evolution of slow-cooled terranes. Recrystallization and secondary growth during metamorphism and the presence of grain boundary fluids can also affect the U-Pb isotopic system in rutile. A growing body of research focusing on U-Pb dating of rutile by LA ICP-MS is greatly improving our understanding of the behavior of this mineral with regards to retention of radiogenic Pb. This is key to fully exploit its potential as a tracker of geological processes. The latest developments in this field are reviewed in this contribution. The combined application of U-Pb zircon and rutile chronology in provenance studies, particularly when complemented by lower-T thermochronometry data, allows the isotopic characterization of the sources across a wide range of temperatures. The benefits of applying detrital zircon-rutile U-Pb chronology as a coupled provenance proxy are presented here, with a focus on the Eastern Himalayan-Indo-Burman region, where a growing number of successful studies employs such an approach to help constrain river drainage and basin evolution and to infer feedback relationships between erosion, tectonics and climate. Full article

The Bangladesh lowlands are traversed by the largest sediment flux on the planet. Detritus generated mostly in Himalayan highlands and conveyed through the Ganga–Brahmaputra rivers and Meghna estuary reaches the Bay of Bengal, where it forms a composite deltaic system. This study integrates the vast existing database on Ganga–Brahmaputra sediments of all grain sizes from clay to sand with new petrographic, mineralogical, and geochemical data on estuarine and shallow-marine sands. A large spectrum of compositional signatures was used to: (i) assess the relative supply of the Ganga and Brahmaputra rivers to estuarine and shelfal sediments; (ii) define the compositional variability of estuarine sediments and the impact exerted by hydraulic sorting and climate-related chemical weathering on provenance signals; (iii) define the compositional variability of shelf sediments and the potential hydrodynamic segregation of fast-settling heavy minerals in coastal environments and of slow-settling platy micas on low-energy outer-shelf floors; (iv) consider the potential additional mud supply from the western subaerial part of the delta formerly built by the Ganga River; and (v) draw a preliminary mineralogical comparison between fluvio-deltaic sediments and turbidites of the Bengal–Nicobar deep-sea fan, thus tracing sediment dispersal across the huge sedimentary system extending from Tibet to the equatorial Indian Ocean. All investigated mineralogical and geochemical parameters, as well as Sr and Nd isotope ratios and clay–mineral assemblages, showed a clear prevalence in sediment supply from the Brahmaputra (60–70%) over the Ganga (30–40%). Heavy-mineral suites and Sr and Nd isotope fingerprints of Bengal shelf sediments are nearly identical to those of the Brahmaputra River and Meghna estuary, also because the Brahmaputra carries almost twice as many Ca-plagioclase grains and heavy minerals including epidote than the Ganga, and these minerals control the large majority of the Sr and Nd budgets. The experience gained in modern settings can be directly extrapolated only to the recent past, because sediments older than the late Pleistocene and buried more than a few hundred meters begin to lose less durable ferromagnesian minerals by selective chemical dissolution, which makes quantitative estimates progressively less robust in more deeply buried older strata. Full article

This article illustrates a multi-technique frontier approach for the provenance study of silt-size sediments. The mineralogical composition of low-density and heavy-mineral fractions of four samples of fine to very coarse silt deposited on the Bengal shelf was analyzed separately for six different grain-size classes by combining grain counting under an optical microscope, Raman spectroscopy, and X-ray diffraction. The geochemical composition was determined on both bulk-sediment samples and on their <5-μm classes. Such a “multiple-window” approach allowed capturing the full mineralogical information contained in each sample, as well as the size-dependent intra-sample variability of all compositional parameters. The comparison between grain-size distributions obtained by different methods highlighted a notable fallacy of laser granulometry, which markedly overestimated the size of the finest mode represented by fine silt and clay. As a test case, we chose to investigate sediments of the Bengal shelf, where detritus is fed from the Meghna estuary, formed by the joint Ganga and Brahmaputra Rivers and representing the largest single entry point of sediment in the world’s oceans. The studied samples show the typical fingerprint of orogenic detritus produced by focused erosion of collision orogens. Bengal shelf silt is characterized by a feldspatho-quartzose (F-Q) composition with a Q/F ratio decreasing from 3.0 to 1.7 with increasing grain size, plagioclase prevailing over K-feldspar, and rich transparent-heavy-mineral assemblages including mainly amphibole with epidote, and minor garnet and pyroxene. Such a detrital signature compares very closely with Brahmaputra suspended load, but mineralogical and geochemical parameters, including the anomalous decrease of the Q/F ratio with increasing grain size, consistently indicate more significant Ganga contribution for cohesive fine silt. The accurate quantitative characterization of different size fractions of Bengal shelf sediments represents an essential step to allow comparison of compositional signatures characterizing different segments of this huge source-to-sink system, from fluvial and deltaic sediments of the Himalayan foreland basin and Bengal shelf to the Bengal Fan. Full article