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Authors = Jaehwan Ko

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17 pages, 4919 KiB  
Article
Properties of Surface Heating Textile for Functional Warm Clothing Based on a Composite Heating Element with a Positive Temperature Coefficient
by Han Na Choi, Seung Hyun Jee, Jaehwan Ko, Dong Joo Kim and Sun Hee Kim
Nanomaterials 2021, 11(4), 904; https://doi.org/10.3390/nano11040904 - 1 Apr 2021
Cited by 16 | Viewed by 3325
Abstract
A high-stretch positive temperature coefficient (PTC) surface heating textile (PTC-SHT) was fabricated using a composite of PTC powder and multiwall carbon nanotubes (MWCNTs). The PTC-SHT (heating area = 100 × 100 mm2) was produced by screen-printing the PTC-MWCNT composite paste onto [...] Read more.
A high-stretch positive temperature coefficient (PTC) surface heating textile (PTC-SHT) was fabricated using a composite of PTC powder and multiwall carbon nanotubes (MWCNTs). The PTC-SHT (heating area = 100 × 100 mm2) was produced by screen-printing the PTC-MWCNT composite paste onto a high-stretch textile with embroidered electrodes. Overall, the temperature increased to 56.1 °C with a power consumption of 5 W over 7 min. Subsequently, the surface temperature of the PTC-SHT remained constant despite the continued decrease in power consumption. This indicated that heating was accompanied by an increase in resistance of the PTC-SHT, which is typical of this process—i.e., heating to a constant temperature under a constant voltage over an extended period of time. In addition, 4.63 W power was required to heat the PTC-SHT surface from an external temperature of 5 to 45 °C in 10 min, after which stable low-temperature heat generation behavior was observed at a constant temperature of 50 °C, which was maintained over 40 min. In contrast, negative temperature coefficient (NTC) behavior has been observed in an NTC-SHT consisting of only MWCNTs, where a slow heating rate in the initial stage of power application and a continuous increase in surface temperature and power consumption were noted. The PTC-SHT consumed less power for heat generation than the NTC-SHT and exhibited rapid heating behavior in the initial stage of power application. The heat generation characteristics of the PTC-SHT were maintained at 95% after 100,000 cycles of 20% stretch–contraction testing, and the heating temperature remained uniformly distributed within ± 2 °C across the entire heating element. These findings demonstrated that an SHT with PTC characteristics is highly suitable for functional warm clothing applications that require low power consumption, rapid heating, stable warmth, and high durability. Full article
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13 pages, 633 KiB  
Article
Neutralizing Antibody Production in Asymptomatic and Mild COVID-19 Patients, in Comparison with Pneumonic COVID-19 Patients
by Jae-Hoon Ko, Eun-Jeong Joo, Su-Jin Park, Jin Yang Baek, Won Duk Kim, Jaehwan Jee, Chul Joong Kim, Chul Jeong, Yae-Jean Kim, Hye Jin Shon, Eun-Suk Kang, Young Ki Choi and Kyong Ran Peck
J. Clin. Med. 2020, 9(7), 2268; https://doi.org/10.3390/jcm9072268 - 17 Jul 2020
Cited by 90 | Viewed by 9174
Abstract
Objectives: To investigate antibody production in asymptomatic and mild COVID-19 patients. Methods: Sera from asymptomatic to severe COVID-19 patients were collected. Microneutralization (MN), fluorescence immunoassay (FIA), and enzyme-linked immunosorbent assay (ELISA) were performed. Results: A total of 70 laboratory-confirmed COVID-19 patients were evaluated, [...] Read more.
Objectives: To investigate antibody production in asymptomatic and mild COVID-19 patients. Methods: Sera from asymptomatic to severe COVID-19 patients were collected. Microneutralization (MN), fluorescence immunoassay (FIA), and enzyme-linked immunosorbent assay (ELISA) were performed. Results: A total of 70 laboratory-confirmed COVID-19 patients were evaluated, including 15 asymptomatic/anosmia, 49 mild symptomatic, and 6 pneumonia patients. The production of the neutralizing antibody was observed in 100% of pneumonia, 93.9% of mild symptomatic, and 80.0% of asymptomatic/anosmia groups. All the patients in the pneumonia group showed high MN titer (≥1:80), while 36.7% of mild symptomatic and 20.0% of asymptomatic/anosmia groups showed high titer (p < 0.001). Anti-SARS-CoV-2 antibodies could be more sensitively detected by FIA IgG (98.8%) and ELISA (97.6%) in overall. For the FIA IgG test, all patients in the pneumonia group exhibited a high COI value (≥15.0), while 89.8% of mild symptomatic and 73.3% of asymptomatic/anosmia groups showed a high value (p = 0.049). For the ELISA test, all patients in the pneumonia group showed a high optical density (OD) ratio (≥3.0), while 65.3% of mild symptomatic and 53.3% of asymptomatic/anosmia groups showed a high ratio (p = 0.006). Conclusions: Most asymptomatic and mild COVID-19 patients produced the neutralizing antibody, although the titers were lower than pneumonia patients. ELISA and FIA sensitively detected anti-SARS-CoV-2 antibodies. Full article
(This article belongs to the Special Issue COVID-19: From Pathophysiology to Clinical Practice)
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14 pages, 4226 KiB  
Article
Swelling Behavior of Polyacrylamide–Cellulose Nanocrystal Hydrogels: Swelling Kinetics, Temperature, and pH Effects
by Tippabattini Jayaramudu, Hyun-U Ko, Hyun Chan Kim, Jung Woong Kim and Jaehwan Kim
Materials 2019, 12(13), 2080; https://doi.org/10.3390/ma12132080 - 28 Jun 2019
Cited by 125 | Viewed by 10220
Abstract
This paper reports swelling behavior of cellulose nanocrystal (CNC)-based polyacrylamide hydrogels prepared by a radical polymerization. The CNC acts as a nanofiller through the formation of complexation and intermolecular interaction. FTIR spectroscopy and XRD studies confirmed the formation of intermolecular bonds between the [...] Read more.
This paper reports swelling behavior of cellulose nanocrystal (CNC)-based polyacrylamide hydrogels prepared by a radical polymerization. The CNC acts as a nanofiller through the formation of complexation and intermolecular interaction. FTIR spectroscopy and XRD studies confirmed the formation of intermolecular bonds between the acrylamide and hydroxyl groups of CNC. The swelling ratio and water retention were studied in de-ionized (DI) water at room temperature, and the temperature effect on the swelling ratio was investigated. Further, the pH effect on the swelling ratio was studied with different temperature levels. Increasing the pH with temperature, the prepared hydrogel shows 6 times higher swelling ratio than the initial condition. The swelling kinetics of the developed hydrogels explains that the diffusion mechanism is Fickian diffusion mechanism. Since the developed hydrogels have good swelling behaviors with respect to pH and temperature, they can be used as smart materials in the field of controlled drug delivery applications. Full article
(This article belongs to the Special Issue Smart Hydrogels in Biomedical Applications)
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13 pages, 3844 KiB  
Article
Poly(imide-co-siloxane) as a Thermo-Stable Binder for a Thin Layer Cathode of Thermal Batteries
by Ilwhan Oh, Jaeyoung Cho, Kwansu Kim, Jaehwan Ko, Haewon Cheong, Young Soo Yoon and Hyun Min Jung
Energies 2018, 11(11), 3154; https://doi.org/10.3390/en11113154 - 14 Nov 2018
Cited by 16 | Viewed by 4829
Abstract
The polymer binder, poly(imide-co-siloxane) (PIS), was synthesized and applied to form a thin cathode layer of composites for a thermal battery that has an unusually high operating temperature of 450 °C. The PIS was prepared through cross-linking of the polyimide with [...] Read more.
The polymer binder, poly(imide-co-siloxane) (PIS), was synthesized and applied to form a thin cathode layer of composites for a thermal battery that has an unusually high operating temperature of 450 °C. The PIS was prepared through cross-linking of the polyimide with polysiloxane. The morphology of FeS2/PIS composites showed that FeS2 particles was coated with the PIS cross-linked gel. The FeS2/PIS composites enabled to fabricate mechanically stable thin cathode layer that was 10–20% of the thickness of a conventional pellet-type cathode. The FeS2/PIS composites were stable up to 400 °C and maintained their morphology at this temperature. PIS coating layers decomposed at 450 °C, and a new residue was generated, which was observed by transmission electron microscopy, and the compositional change was analyzed. The FeS2/PIS composites showed enhanced thermal stability over that of FeS2 in thermogravimetric analysis. The thermal battery with the PIS polymer binder showed a 20% discharge capacity increase when compared to a conventional pellet-type cathode. Full article
(This article belongs to the Section D: Energy Storage and Application)
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11 pages, 2351 KiB  
Article
Electroactive Hydrogels Made with Polyvinyl Alcohol/Cellulose Nanocrystals
by Tippabattini Jayaramudu, Hyun-U Ko, Hyun Chan Kim, Jung Woong Kim, Ruth M. Muthoka and Jaehwan Kim
Materials 2018, 11(9), 1615; https://doi.org/10.3390/ma11091615 - 4 Sep 2018
Cited by 71 | Viewed by 7839
Abstract
This paper reports a nontoxic, soft and electroactive hydrogel made with polyvinyl alcohol (PVA) and cellulose nanocrystal (CNC). The CNC incorporating PVA-CNC hydrogels were prepared using a freeze–thaw technique with different CNC concentrations. Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction and scanning [...] Read more.
This paper reports a nontoxic, soft and electroactive hydrogel made with polyvinyl alcohol (PVA) and cellulose nanocrystal (CNC). The CNC incorporating PVA-CNC hydrogels were prepared using a freeze–thaw technique with different CNC concentrations. Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction and scanning electron microscopy results proved the good miscibility of CNCs with PVA. The optical transparency, water uptake capacity and mechanical properties of the prepared hydrogels were investigated in this study. The CNC incorporating PVA-CNC hydrogels showed improved displacement output in the presence of an electric field and the displacement increased with an increase in the CNC concentration. The possible actuation mechanism was an electrostatic effect and the displacement improvement of the hydrogel associated with its enhanced dielectric properties and softness. Since the prepared PVA-CNC hydrogel is nontoxic and electroactive, it can be used for biomimetic soft robots, actively reconfigurable lenses and active drug-release applications. Full article
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11 pages, 4563 KiB  
Article
Fabrication Method Study of ZnO Nanocoated Cellulose Film and Its Piezoelectric Property
by Hyun-U Ko, Hyun Chan Kim, Jung Woong Kim, Lindong Zhai and Jaehwan Kim
Materials 2017, 10(6), 611; https://doi.org/10.3390/ma10060611 - 2 Jun 2017
Cited by 14 | Viewed by 4433
Abstract
Recently, a cellulose-based composite material with a thin ZnO nanolayer—namely, ZnO nanocoated cellulose film (ZONCE)—was fabricated to increase its piezoelectric charge constant. However, the fabrication method has limitations to its application in mass production. In this paper, a hydrothermal synthesis method suitable for [...] Read more.
Recently, a cellulose-based composite material with a thin ZnO nanolayer—namely, ZnO nanocoated cellulose film (ZONCE)—was fabricated to increase its piezoelectric charge constant. However, the fabrication method has limitations to its application in mass production. In this paper, a hydrothermal synthesis method suitable for the mass production of ZONCE (HZONCE) is proposed. A simple hydrothermal synthesis which includes a hydrothermal reaction is used for the production, and the reaction time is controlled. To improve the piezoelectric charge constant, the hydrothermal reaction is conducted twice. HZONCE fabricated by twice-hydrothermal reaction shows approximately 1.6-times improved piezoelectric charge constant compared to HZONCE fabricated by single hydrothermal reaction. Since the fabricated HZONCE has high transparency, dielectric constant, and piezoelectric constant, the proposed method can be applied for continuous mass production. Full article
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10 pages, 1014 KiB  
Article
Fabrication of Cellulose ZnO Hybrid Nanocomposite and Its Strain Sensing Behavior
by Hyun-U Ko, Seongcheol Mun, Seung-Ki Min, Gi-Woo Kim and Jaehwan Kim
Materials 2014, 7(10), 7000-7009; https://doi.org/10.3390/ma7107000 - 16 Oct 2014
Cited by 40 | Viewed by 6480
Abstract
This paper reports a hybrid nanocomposite of well-aligned zinc oxide (ZnO) nanorods on cellulose and its strain sensing behavior. ZnO nanorods are chemically grown on a cellulose film by using a hydrothermal process, termed as cellulose ZnO hybrid nanocomposite (CEZOHN). CEZOHN is made [...] Read more.
This paper reports a hybrid nanocomposite of well-aligned zinc oxide (ZnO) nanorods on cellulose and its strain sensing behavior. ZnO nanorods are chemically grown on a cellulose film by using a hydrothermal process, termed as cellulose ZnO hybrid nanocomposite (CEZOHN). CEZOHN is made by seeding and growing of ZnO on the cellulose and its structural properties are investigated. The well-aligned ZnO nanorods in conjunction with the cellulose film shows enhancement of its electromechanical property. Strain sensing behaviors of the nanocomposite are tested in bending and longitudinal stretching modes and the CEZOHN strain sensors exhibit linear responses. Full article
(This article belongs to the Section Advanced Composites)
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