Solar

This work aimed to show the possibility of applying anthocyanins extracted from blueberries following a straightforward path as potential impregnation dyes in dye-sensitized solar cells (DSSCs), particularly in the presence of co-adsorbents, such as silver nanoparticles, as an alternative in order to profit from large amounts of discarded fruits. Following a simple procedure, anthocyanins (mainly delphinidin-3-glucoside) were obtained from blueberries (Southern Highbush type). Complete characterization was carried out in order to prove the utility of delphinidin-3-glucoside as a sensitizer in DSSCs. The analyzed anthocyanin is suitable for sensitizing because of its high molar absorptivity values within the visible region of the light spectra, the adsorption ability to a FTO/TiO₂ electrode (FTO, fluorine-doped tin oxide) as confirmed by Fourier transform infrared (FTIR) as well as thermogravimetry coupled to differential scanning calorimetry (TG-DSC), a potential oxidation value near 1 V, and adequate thermal as well as light stabilities. Moreover, the cell’s conversion efficiency is improved in the presence of silver nanoparticles, reaching 0.24% (nearly a 25% increase). The sum of all these characteristics points to the application of delphinidin-3-glucoside as a sensitizer in DSSCs, offering a technological use with potential interest for countries where agricultural production offers an abundant origin of extraction. Full article

The paper presents the analysis of energy retrofitting, integration of renewable energy and activation of energy flexibility in a cluster of buildings in the surroundings of a port on the Mediterranean Sea in Southern Italy, with the aim of checking the potential for it to achieve the status of positive energy district (PED). The objective of this study is to improve the contemporaneity between local energy generation and energy demand and reduce CO_2eq emissions by considering signals that reflect the environmental variability of the electricity grid, through flexibility solutions applied to the HVAC system. The proposed scenarios are based on the dynamic simulation of the district and analyze the effect of actions that activate the energy flexibility of buildings through advanced control strategies of the air conditioning system. The results show that the joint action of energy efficiency strategies, integration of solar energy and energy flexibility improves the environmental sustainability of the district and the balance of energy flows. Specifically, the activation of energy flexibility contributes to a 10% reduction in operational CO_2eq emissions and increases in self-consumption of energy per year. The operational emissions of the district vary from the base value of 33.37 tons CO_2eq/y to 19.52 tons CO_2eq/y in the scenario based on the integration of solar energy systems and energy efficiency measures, and to 17.39 tons CO_2eq/y when also the demand-side energy flexibility is activated. Full article

The use of traditional Dye-sensitized solar cells (DSSCs) is limited due to the use of toxic and non-environmentally safe solvents. In this review, water is proposed as a viable alternative to developing green chemistry and sustainable materials for DSSCs. However, water-based DSSCs (WBDSSCs) require improvement in their photovoltaic parameters. The detachment of dye molecules from the semiconductor and the poor solubility of iodine in water are the primary reasons for their low efficiency. This review analyzes the best results achieved by 100% aqueous electrolytes containing synthetic, organic, and natural dyes to identify the best conditions to overcome these limitations. Developing a suitable photoanode/electrolyte interface and finding a compromise in the choice of dye are the main research goals in the coming years. WBDSSCs can contribute significantly to producing clean energy using sustainable and environmentally friendly materials. Furthermore, here we report the state of the art of the emerging technology of underwater dye-sensitized solar cells, which are a promising technology for generating renewable energy in aquatic environments. Recent advancements in material science and device engineering have shown promising results in enhancing their efficiency and durability. Further research and development can make these devices a viable alternative for sustainable energy generation in a wide range of underwater applications. Full article

This paper provides an overview of the development of a 3D formed and metal-based facade element that combines a custom design and solar thermal functionality. To achieve this, a novel simplified solar thermal collector structure was developed using formed sheet metal half-shells with an integrated channel structure on the inside and a special absorber coating on the outside. The sheet metal half-shells were manufactured by highly innovative incremental sheet forming (ISF), which allows seamless integration into existing facades. As a part of this paper, the initial test results on thermal efficiency and the energy accumulation of the new collector type are presented. Full article

Concentrating Photovoltaic Thermal (CPVT) collectors are suitable for integration in limited roof space due to their higher solar conversion efficiency. Solar sunlight can be used more effectively by CPVT collectors in comparison to individual solar thermal collectors or PV modules. In this study, the experimental investigation of a novel CPVT collector called a PC (power collector) has been carried out in real outdoor conditions, and the test set-up has been designed based on ISO 9806:2013. A quasi-dynamic testing method has been used because of the advantages that this method can offer for collectors with a unique construction, such as the proposed collector, over the steady-state testing method. With a quasi-dynamic testing method, it is possible to characterize the collector within a wide range of incidence angles and a complex incidence angle modifier profile. The proposed novel collector has a gross area of 2.57 m². A maximum power output per collector unit area of 1140 W is found at 0 °C reduced temperature (1000 W/m² irradiance level), while at a higher reduced temperature (70 °C), it drops down to 510 W for the same irradiance level. The data have been fitted through a multiple linear regression method, and the obtained efficiency curve coefficients are 0.39, 0.192, 1.294, 0.023, 0.2, 0, −5929 and 0 for K_θd, b₀, c₁, c₂, c₃, c₄, c₅ and c₆, respectively. The experimental characterization carried out on the collector proved that the output powers calculated by using the obtained parameters of the quasi-dynamic testing method are in good agreement with experimental points. Full article

Reverse breakdown in Cu(In,Ga)S${\mathrm{e}}_2$ (CIGS) solar cells can lead to defect creation and performance degradation. We present pulsed reverse-bias experiments, where we stress CIGS solar cells with a short reverse voltage pulse of ten milliseconds and detect the electrical and thermal response of the cell. This way, we limit the duration of the reverse stress, allowing us to study the initial stages of reverse-bias defect creation in CIGS solar cells and modules. Our results show that permanent damage can develop very fast in under milliseconds. Furthermore, we find the location of defect creation as well as the susceptibility to defect creation under reverse bias depends strongly on whether the cell is encapsulated or not, where encapsulated cells are generally more robust against reverse bias. Full article

On one side, the capacity of the world’s photovoltaic (PV) systems is experiencing unprecedented growth; on the other side, the number of connected devices is rapidly increasing due to the development of advanced communication technologies. These fields are not completely independent, and recent studies show that indoor energy harvesting is a great candidate for answering the energy challenges of future generations of telecommunications, namely 5G and 6G, ideal for internet-of-things (IoT) scenarios, i.e., smart homes, smart cities, and smart factories. The emerging PV technologies have shown amazing capabilities for indoor energy harvesting, displaying high power conversion efficiency, good flexibility, and champion-specific powers. Recently, the excellent dynamic performance of PV devices enabled them to be used as data receivers in optical wireless communication (OWC) scenarios, calling forth an innovative system able to simultaneously harvest energy and receive communication data with a single PV device. This article reviews the recent literature devoted to the exploitation of photovoltaic technologies for simultaneous indoor energy harvesting and OWC data reception. This contribution highlights the strong potential of the approach toward the next generation of Green IoT systems and the current challenges that need to be addressed with regard to the physics of solar cells, from laboratory to large-scale applications. Full article

Concentrating solar power (CSP) is a high-potential renewable energy source that can leverage various thermal applications. CSP plant development has therefore become a global trend. However, the designing of a CSP plant for a given solar resource condition and financial situation is still a work in progress. This study aims to develop a mathematical model to analyze the levelized cost of electricity (LCOE) of Thermal Energy Storage (TES)-integrated CSP plants in such circumstances. The developed model presents an LCOE variation for 18 different CSP configurations with TES incorporated for Rankine, Brayton, and combined power generation cycles, under regular TES materials and nano-enhanced TES materials. The model then recommends the most economical CSP plant arrangement. Within the scope of this study, it was found that the best configuration for electricity generation is a solar power tower with nano-enhanced phase change materials as the latent heat thermal energy storage medium that runs on the combined cycle. This returns an LCOE of 7.63 ct/kWh with a 22.70% CSP plant efficiency. The most favorable option in 50 MW plants is the combined cycle with a regular TES medium, which has an LCOE of 7.72 ct/kWh with a 22.14% CSP plant efficiency. Full article

In parabolic trough technology, the development of thermally and structurally stable solar coatings plays a key role in determining the efficiency, durability, and economic feasibility of tube receivers. A cermet-based solar coating is typically constituted by a thin film stratification, where a multilayer graded cermet is placed between an infrared metallic reflector and an antireflection filter. This work reports the realization of materials based on Al₂O₃ and W characterized by high structural and chemical stability in vacuum at high temperature, obtained through the optimization of high-deposition-rate processes. Al₂O₃ material, employed as the antireflection layer, was deposited through a reactive magnetron sputtering process at a high deposition rate. Cermet materials based on W-Al₂O₃ were deposited and employed as absorber layers by implementing reactive magnetron co-sputtering processes. An investigation into the stability of the realized samples was carried out by means of several material characterization methods before and after the annealing process in vacuum (1 × 10⁻³ Pa) at high temperature (620 °C). The structural properties of the samples were evaluated using Raman spectroscopy and XRD measurements, revealing a negligible presence of oxides that can compromise the structural stability. Spectrophotometric analysis showed little variations between the deposited and annealed samples, clearly indicating the high structural stability. Full article

Cu-oxide nanophases (CuO, Cu₂O, Cu⁰) constitute highly potent nanoplatforms for the development of efficient Artificial Photosynthesis catalysts. The highly reducing conduction band edge of the d-electrons in Cu₂O dictates its efficiency towards CO₂ reduction under sunlight excitation. In the present review, we discuss aspects interlinking the stability under photocorrosion of the (CuO/Cu₂O/Cu⁰) nanophase equilibria, and performance in H₂-production/CO₂-reduction. Converging literature evidence shows that, because of photocorrosion, single-phase Cu-oxides would not be favorable to be used as a standalone cathodic catalyst/electrode; however, their heterojunctions and the coupling with proper partner materials is an encouraging approach. Distinction between the role of various factors is required to protect the material from photocorrosion, e.g., use of hole scavengers/electron acceptors, band-gap engineering, nano-facet engineering, and selectivity of CO₂-reduction pathways, to name a few possible solutions. In this context, herein we discuss examples and synthesis efforts that aim to clarify the role of interfaces, faces, and phase stability under photocatalytic conditions. Full article

The materials used to manufacture solar receivers for tower power plants must withstand high fluxes of concentrated solar radiation (from $0.1$ to even $1.5$ MWm${}^{-2}$) and operate at high operating temperatures (>800 °C). Durability is a key aspect in these systems, which must be ensured under these demanding operating conditions, which also include daily heating–cooling cycles throughout the lifetime of these power plants. So far, to the authors’ knowledge, which wavelengths of concentrated solar radiation have the greatest influence on the mechanisms and speed of aging of materials used in solar receivers has not been analyzed. Yet, such an analysis is pertinent in order to implement strategies that delay or inhibit such phenomena, and, thus, increase the durability of central tower systems’ receivers. To perform such analyses, a new solar furnace was recently designed and installed at the Plataforma de Almería (Spain). This paper describes the components of this new solar furnace. The components are as follows: a heliostat to redirect the direct solar radiation towards a Fresnel lens that concentrates the solar radiation on the material under study, a shutter that allows varying the amount of concentrated solar radiation incident on the Fresnel lens, and reflective filters with selective reflectance that are placed between the Fresnel lens and the material. This paper also describes the procedure and the first results of the energetic and spectral characterization of this new solar furnace. The first experimental results of the characterization of this new test bed using the heliostat and the Fresnel lens showed that concentration ratios of up to 1000 suns (1 sun = 1000 Wm${}^{-2}$) could be achieved. Furthermore, the paper presents the results of the spectral characterization of the test system, using selective reflectance mirrors in the near-visible–IR wavelength range (400–1125 nm) and in the visible–IR red region (700–2500 nm). Full article

This work presents the modeling and energy management of a microgrid through models developed based on physical equations for its optimal control. The microgrid’s energy management system was built with one of the most popular control algorithms in microgrid energy management systems: model predictive control. This control strategy aims to satisfy the load demand of an office located in the CIESOL bioclimatic building, which was placed in the University of Almería, using a quadratic cost function. The simulation scenarios took into account real simulation parameters provided by the microgrid of the building. For case studies of one and five days, the optimization was aimed at minimizing the input energy flows of the microgrid and the difference between the energy generated and demanded by the load, subject to a series of physical constraints for both outputs and inputs. The results of this work show how, with the correct tuning of the control strategy, the energy demand of the building is covered through the optimal management of the available energy sources, reducing the energy consumption of the public grid, regarding a wrong tuning of the controller, by 1 kWh per day for the first scenario and 7 kWh for the last. Full article

Renewable energy systems design using average year weather data is a standard approach that works well for grid-tied systems, but for stand-alone ones, it leads to dramatic mistakes. We considered the effect of meteorological data temporal resolution (5, 10, 15, 20, 30 min; 1, 2, 3, 4 h) on a stand-alone hybrid system’s layout in terms of equipment cost, power supply reliability and maximum duration of interruption for monitoring equipment in the Alps. We have shown that lifecycle costs could be strongly (order of magnitude) underestimated for off-grid systems, as well as their reliability overestimated. Lower temporal resolution data lead to the underestimation of energy storage charge–discharge cycles (considering depth of discharge too)—real batteries are to be replaced more often, which matches our practical experience as well. Even a 5 to 10 min decrease in weather data temporal resolution leads to the estimated annual expenses being halved. In general, we recommend using 30 min resolution. Full article

This paper presents a model of an energy system for a private household extended by a lifetime prognosis. The energy system was designed for fully covering the year-round energy demand of a private household on the basis of electricity generated by a photovoltaic (PV) system, using a hybrid energy storage system consisting of a hydrogen unit and a lithium-ion battery. Hydrogen is produced with a Proton Exchange Membrane (PEM) electrolyser by PV surplus during the summer months and then stored in a hydrogen tank. Mainly during winter, in terms of lack of PV energy, the hydrogen is converted back into electricity and heat by a fuel cell. The model was created in Matlab/Simulink and is based on real input data. Heat demand was also taken into account and is covered by a heat pump. The simulation period is a full year to account for the seasonality of energy production and demand. Due to high initial costs, the longevity of such an energy system is of vital interest. Therefore, this model was extended by a lifetime prediction in order to optimize the dimensioning with the aim of lifetime extension of a hydrogen-based energy system. Lifetime influencing factors were identified on the basis of a literature review and were integrated in the model. An extensive parameter study was performed to evaluate different dimensionings regarding the energy balance and the lifetime of the three components, electrolyser, fuel cell and lithium-ion battery. The results demonstrate the benefits of a holistic modelling approach and enable a design optimization regarding the use of resources, lifetime and self-sufficiency of the system. Full article

TiO₂ photocatalysts can provide carbon-capture utilization and storage by converting atmospheric CO₂ to green hydrogen, but the efficiency of the current photocatalysts is still too low for economical usage. Anatase TiO₂ is effective in transferring the electrons and holes produced by the photoelectric effect to reactants because of its oxygen-terminated surfaces. However, the anatase TiO₂ bandgap is 3.2 eV, which requires photons with wavelengths of 375 nm or less to produce electron–hole pairs. Therefore, TiO₂ is limited to using a small part of the solar spectrum. Strain engineering has been used to design ZrO₂@TiO₂ [email protected] structures with large strains in the TiO₂ shell, which reduces its bandgap but maintains octahedral facets for charge separation and oxygen-terminated surfaces for the catalysis of reactants. Finite element analysis shows that shell thicknesses of 4–12 nm are effective at obtaining large strains in a large portion of the shell, with the largest strains occurring next to the ZrO₂ surface. The c-axis strains for 4–12 nm shells are up to 7%. The strains reduce the bandgap in anatase TiO₂ up to 0.35 eV, which allows for the use of sunlight with wavelengths up to 421 nm. For the AM 1.5 standard spectrum, electron–hole pair creation in 4 nm thick and 10 nm thick TiO₂ shells can be increased by a predicted 25% and 23%, respectively. The 10 nm thick shells provide a much larger volume of TiO₂ and use proportionally less ZrO₂. In addition, surface-plasmon resonators could be added to further extend the usable spectrum and increase the production of electron–hole pairs many-fold. Full article

We present our own Interdigitated Back Contact (IBC) technology, which was developed at ISC Konstanz and implemented in mass production with and at SPIC Solar in Xining, China, with production efficiencies of over 24%. To our knowledge, this is the highest efficiency achieved in the mass production of crystalline silicon solar cells without the use of charge-carrier-selective contacts. With an adapted screen-printing sequence, it is possible to achieve open-circuit voltages of over 700 mV. Advanced module technology has been developed for the IBC interconnection, which is ultimately simpler than for conventional double-sided contacted solar cells. In the next step, we will realize low-cost charge-carrier-selective contacts for both polarities in a simple sequence using processes developed and patented at ISC Konstanz. With the industrialisation of this process, it will be possible to achieve efficiencies well above 25% at low cost. We will show that with the replacement of silver screen-printed contacts by copper or aluminium metallisation, future IBC technology will be the end product for the PV market, as it is the best performing c-Si technology, leading to the lowest cost of electricity, even in utility-scale applications. Full article

Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency (PCE) to more than 25% in recent years. However, the instability of these devices is still a strong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI₃ and CsPbI₂Br as the perovskite layer have shown enhanced long-term stability, which makes them potential candidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configuration have not yet reached the high efficiency achieved in the normal n-i-p structure. However, the inverted p-i-n architecture has recently drawn attention of researchers because it is more suitable to prepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCs based on CsPbI₃ and CsPbI₂Br as the perovskite layer was carried out using SCAPS-1D software (ver. 3.3.09). The performance of different architectures of PSC was examined and compared by means of numerical simulations using various inorganic materials as the hole transport layer (HTL) and the electron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTL and ETL, respectively. In addition, the performance of the devices was significantly improved by optimizing the hole mobility in CuI as well as the thickness, doping density, and defect density in the absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditions for the inverted all-inorganic CsPbI₃- and CsPbI₂Br-based PSCs, respectively. These results indicate that further improvements in the performance of such devices are still possible. Full article

The electricity crisis is a common issue in Bangladesh; however, recently the electricity scenario has been getting worse due to various reasons including power generation and distribution all over the country. Meanwhile, the large number of people requires a huge amount of energy which is not possible to be met by the national grid due to the limited power generation from different plants. Among all renewable energy sources, the solar photovoltaics (PV) system is the best choice as a generation source, either off-grid or with a grid-tied connection, to reduce the pressure on the national grid. In Bangladesh, there are more than 175,000 schools, and it is possible to generate a huge amount of renewable (solar) power to supply all the schools by using rooftop PV systems. We propose a new approach that combines solar energy harvesting and savings to make the schools self-sufficient and energywise. We performed a Hybrid Optimization Model for Multiple Energy Resources (HOMER) pro simulation and find that it was possible to generate approximately 200 megawatts (MW) of power. We conducted a feasibility study on generating power from rooftop PV systems on school buildings and reduced the power consumption using retrofitted thin-film-coated glass by around 16–20% per day depending on the school size, which can help the national power grid system by either making all the schools off-grid or grid-connected to supply power to the national grid. In addition, we perform a HelioScope simulation to investigate the maximum upscaling of PV sizing for the rooftops of school buildings in Bangladesh to realize how to make each school a mini solar power station in the future. The HelioScope simulation performance showed that it was possible to generate approximately 96,993 kWh per year from one school building. Full article