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Separations

Separations - formerly Chromatography - is an international, peer-reviewed, open access journal on separation and purification science and technology in all areas of chemical, biological, physical science, and separation performance published monthly online by MDPI.
The Central European Group of Separation Sciences (CEGSS) is affiliated with Separations and their members receive discounts on the article processing charges.
Quartile Ranking JCR - Q3 (Chemistry, Analytical)

All Articles (2,297)

Spent automotive catalysts (SAC) not only contain significant amounts of platinum group metals (PGMs) but also hazardous heavy metals, rendering them a solid waste. A harmless technology for the efficient recovery of PGMs through copper smelting has been proposed. By investigating the effects of the CaO/SiO2 mass ratio and Al2O3 content on the properties of the slag, the composition of the slag was adjusted. The influence of copper dosage, Na2B4O7 dosage, smelting temperature, and smelting time on the recovery efficiency of PGMs was also discussed. The determined composition of the target slag was 36.44 wt% CaO, 45.56 wt% SiO2, 12.00 wt% Al2O3, and 6.00 wt% MgO. The optimal processing conditions included 12 wt% Cu, 4 wt% Na2B4O7, smelting temperature 1450 °C, and smelting time 90 min. Ultimately, the recovery efficiency of PGMs reached 99.5%. Compared to traditional plasma furnace smelting methods, PGMs were efficiently recovered at a lower melting temperature. A pilot-scale experiment with a mass of 30 kg also achieved a recovery rate of over 99% for PGMs. TCLP results indicate that the heavy metals were immobilized within the glass slag.

11 November 2025

Standard Gibbs free energy of possible reactions during smelting (a) Reactions (1)~(6); (b) Reactions (7)~(12).

Coalbed methane (CBM) is a vital clean energy resource, yet its extraction efficiency is often hindered by rapid production decline and low production rates in medium-shallow reservoirs. This study investigates the potential of CO2 huff-and-puff technology to enhance CBM recovery and achieve CO2 storage in low-productivity wells. A comprehensive model, constructed based on the geological conditions of the Qinshui Basin, was developed. Numerical simulations revealed that CO2 huff-and-puff significantly improves CH4 production by displacing adsorbed CH4 and maintaining reservoir pressure. Key findings indicate that higher CO2 injection volumes yield substantial increases in both peak CH4 production and cumulative production compared with conventional extraction. Optimal soaking times balance recovery efficiency and operational costs. Sensitivity analysis identified gas diffusion coefficients, initial permeability, and Langmuir volume constants as critical geological parameters influencing the performance. This study preliminarily demonstrates the feasibility of large-scale CO2 huff-and-puff for enhancing production in low-productivity CBM wells and provides theoretical insights for revitalizing China’s underperforming CBM wells while advancing carbon neutrality goals, although further experimental validation is still required.

11 November 2025

Annual CBM production and well development statistics (accumulated and newly drilled wells) in China from 2003 to 2021 [16], Copyright 2023 Coal Geology & Exploration.

An improved multi-module gas purification device is capable of removing micro-particles with an overall efficiency of over 95% at an average velocity of 16 m/s under a flow distribution ratio of 50/50. Its operation is based on the separation and filtration effect, and the multi-module design increases gas flow processing capacity without increasing the size of the device, and ensures good sustainable development as an innovation. The effects of one, dual, and triple-module configurations were experimentally investigated in terms of gas flow and distribution in channels, including pressure drag and separation level. For a comparative analysis of three pilot models of the device, granite micro-dust and wood ash were used as test particles. At an average micro-dust concentration of 4.5 g/m3, a pressure drop of less than 1600 Pa and a separation level of more than 93% were achieved.

11 November 2025

Multi-modules multi-channel cyclone 3-D view: (a) principal scheme; (b) physical model; (c) 1—dusted gas flow inlet, 1.1–8.3—gas flow velocity measurement points, 2—inlet opening, 3—cyclone separation chamber, 4—cleaned gas flow outlet, 5—segment circular spacings, 6—curvilinear quarter–rings with folded opening slots, 7—folded opening slots of quarter–rings, 8—cyclone channels, 9—one-module, 10—dual-modules, 11—triple-modules.

The advancement of miniaturized liquid chromatography (M-LC) systems has drawn considerable attention for their ability to enhance sensitivity, expedite analysis, and minimize the environmental impact of chemical usage in various analytical processes. This review explores the fundamental principles and recent innovations in M-LC technology, including diverse pump designs, advanced column techniques, and the reduction in connection devices. Emphasizing the need for components that operate efficiently at the capillary or nanoscale with minimal dead volumes, we also discuss the development of benchtop instruments and mass spectrometry integrations. The review further highlights the growing applications of M-LC in food, environmental, and biological analyses, highlighting its potential as a powerful and emerging tool in separation science. Looking forward, addressing problems such as limited robustness, fabrication complexity, and integration with sensitive detectors will be instrumental to advancing M-LC technology. Modern innovation in microfabrication, materials science, and hyphenated methods holds great promise for allowing real-time, high-throughput, and portable analytical solutions in the near future.

11 November 2025

Cell morphogenesis in an inoculated microchip. (a) Physical diagram of the microchip after cell inoculation. (b) Illustration of the inoculated chip. (c) Corresponding cell layer on each hydrogel surface after the continuous flow culture. (d) Corresponding cell layer on each hydrogel surface after the static culture. (Scale bar = 200 μm) [55]. Reprinted with permission from Ref. [55]. Copyright 2025, Elsevier. All rights reserved.

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Separations - ISSN 2297-8739