Special Issue "Natural Separation Sciences and Non-polluting Approaches in Sustainable Water Remediation"

A special issue of Separations (ISSN 2297-8739). This special issue belongs to the section "Environmental Separations".

Deadline for manuscript submissions: 31 December 2023 | Viewed by 1842

Special Issue Editors

Department of Food Technology, University North, 48000 Koprivnica, Croatia
Interests: general statistics; research methodology; experimental design; mathematical modeling; multivariate analysis; novel food processing and extraction technologies
Special Issues, Collections and Topics in MDPI journals
Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad Faculty of Sciences, 21000 Novi Sad, Serbia
Interests: environmental chemistry; advanced oxidation processes; photocatalytic decomposition; emerging organic pollutants; wastewater purification; kinetic methods of analysis; nanoparticles; semiconductors
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The environmental pollution caused by human negligence is an urgent global concern. All natural resources are currently being exposed to various dangerous effects from societies at large, especially in the developing countries. The scarcity of pure and sanitarily adequate water is a well-known and serious risk. This problem leads to severe health disorders and economic, social and even political costs. Water ecosystems are contaminated with persistent organic pollutants, most of which originate from industry, agriculture and urban wastewaters. Currently, the most widely researched topic is the development of cost-effective, feasible and eco-inspired sustainable technologies for purification of water. Furthermore, green and plant-based synthesis pathways are also being investigated in the fabrication of nanoparticles, a practice which could be successfully applied in water remediation. Thus, non-chemical and efficient extraction techniques should also be developed to reach and harvest biomolecules from plants. On the other hand, due to the matrix of natural samples and because of the complex organic pollutants, adequate separation techniques should be also established in order to properly conduct chemical analyses and to obtain precise and correct results.

This Special Issue of Separations is focused on presenting outstanding and promising developments in water remediation processes. This includes the application and enhancement of non-polluting, nature-derived advanced oxidation processes (AOPs). Articles regarding individual and hybrid AOPs (e.g., including photocatalysis, subcritical water treatments, ultrasound, plasma-based AOP, (photo)-Fenton, and catalytic ozonation) are also welcomed. Furthermore, discussions of original and cutting-edge separation techniques (such as adsorption, membranes, filtration, etc.) and their application in water purification are also invited. Besides, innovative and chemical-free plant extraction techniques are appreciated. Additionally, the newest studies about the application of plant-based extracts in the fabrication of nanoparticles for water purification purposes are also desirable. Moreover, due to the complex matrix of natural waters, we will also accept research into innovative and eco-friendly sample preparation techniques (solid phase extraction, 3D-printed platforms, etc.), as well as precise and accurate analytical methods for analysis and pollutant determination, for instance chromatography (liquid chromatography, liquid chromatography coupled with tandem mass spectrometry, ion chromatography, etc.).

The articles presented in this Special Issue will cover various topics, starting from application of AOPs and various trending separation techniques in wastewater treatments. Additionally, modern and chemical-free extraction techniques will also be presented, together with plant extract application in the synthesis of nanoparticles for organic pollutant removal. Likewise, new efforts are encouraged, both in the wastewater sample preparation and in the development of accurate analytical methods for environmental analysis.

Topics of interest include, but are not limited to the following:

  • Environmental remediation;
  • Advanced oxidation processes;
  • Hybrid AOPs;
  • Adsorption;
  • Filtration
  • Membranes; 
  • Chemical-free extraction;
  • Plant-based extracts;
  • Green nanotechnology;
  • Sample preparation;
  • Environmental analysis;
  • Analytical methods;
  • Chromatography.

Prof. Dr. Predrag Putnik
Prof. Dr. Daniela Šojić Merkulov
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Separations is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • environmental protection
  • advanced oxidation technology
  • catalysis
  • hybrid AOPs
  • adsorption
  • filtration
  • membranes
  • low impact extraction
  • plant extracts
  • green synthesis
  • sample preparation
  • environmental analysis
  • chromatography

Published Papers (2 papers)

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Research

Article
Sunlight-Driven Degradation of Alprazolam and Amitriptyline by Application of Binary Zinc Oxide and Tin Oxide Powders
Separations 2023, 10(5), 316; https://doi.org/10.3390/separations10050316 - 19 May 2023
Viewed by 681
Abstract
In recent years, much attention has been paid to pharmaceuticals as potential toxic bioactive substances in the worldwide environment. These compounds are continuously introduced into the surroundings in small concentrations, which certainly affects the quality of water, ecosystem, and the general health of [...] Read more.
In recent years, much attention has been paid to pharmaceuticals as potential toxic bioactive substances in the worldwide environment. These compounds are continuously introduced into the surroundings in small concentrations, which certainly affects the quality of water, ecosystem, and the general health of living organisms. Photocatalysis is a promising technique for treating pharmaceutically active compounds as organic pollutants over traditional technologies. This study proposes the application of photocatalysts composed of zinc oxide (ZnO) and tin oxide (SnO2), synthesized using a solid-state method, for the photocatalytic degradation of two selected psychoactive drugs, amitriptyline (AMI) and alprazolam (ALP), under simulated solar and UV irradiation in an aqueous system. The newly synthesized photocatalysts were characterized using the following techniques: SEM/EDS, XRD, DLS, and UV/Vis spectroscopy. The obtained data confirmed the successful synthesis and the possible photocatalytic application of the new materials. Concerning the photocatalytic evaluation, the main results indicate that the highest removal efficiency of AMI and ALP was reached in the presence of ZnO/SnO2 synthesized in a molar ratio of 2:1 and calcined at 700 °C, under 1.0 mg/mL catalyst loading. Based on the reutilization findings, it can be concluded that the mentioned photocatalyst had not lost its efficiency after three successive runs for the photodegradation of ALP. Additionally, pure ZnO powders showed the highest activity after calcination at 500 °C, in the case of both examined pollutants. The experiments with tert-butanol, sodium fluoride, and ethylenediaminetetraacetic acid suggested that the relative contribution of various reactive species changed in the following order: positively charged holes > OHfree > OHads. Full article
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Article
Characterization and Photocatalytic Performance of Newly Synthesized ZnO Nanoparticles for Environmental Organic Pollutants Removal from Water System
Separations 2023, 10(4), 258; https://doi.org/10.3390/separations10040258 - 16 Apr 2023
Cited by 1 | Viewed by 902
Abstract
Most countries are facing problems of environmental pollution due to toxic organic pollutants being discharged into the environment from various man-made sources. Heterogeneous photocatalysis is a possible solution for the mentioned problem, and it has been widely applied for the removal of pollutants [...] Read more.
Most countries are facing problems of environmental pollution due to toxic organic pollutants being discharged into the environment from various man-made sources. Heterogeneous photocatalysis is a possible solution for the mentioned problem, and it has been widely applied for the removal of pollutants from aqueous solutions, thanks to its high removal efficiency and environmental friendliness. Among the commonly used metal oxides, ZnO has attracted researchers’ interests due to its ecofriendly and nontoxic nature. In this work, ZnO nanoparticles (ZnO-NPs) were prepared by the precipitation method from water (w) and ethanol solutions of the corresponding metal precursors (zinc–acetate dihydrate, A_ZnO, and zinc–nitrate hexahydrate, N_ZnO) followed by calcination at different temperatures. The structure and morphology of the prepared catalysts were characterized by different techniques (XRD, BET, and SEM). Based on the XRD results, it can be seen that the synthesized NPs possess high purity. Furthermore, at a higher calcination temperature, a higher crystal size was observed, which was more intense in the case of the ethanol solution of the precursors. The BET analysis showed macropores at the surface and also indicated that the increased temperature led to decreased surface area. Finally, SEM images showed that in the case of the water precursor solution, an irregular, rod-like shape of the NPs was observed. The photocatalytic properties of newly synthesized ZnO-NPs exposed to simulated sunlight were examined during the removal of pesticide clomazone (CLO) and the antidepressant drug amitriptyline (AMI). ZnO-NPs prepared by the precipitation method from the water solution of zinc–acetate dihydrate and calcined at 500 °C (A_ZnOw_500) showed the highest performance under simulated sunlight. Furthermore, the activity of A_ZnOw_500 and N_ZnOw_500 catalysts in the removal of three organic pollutants from water—two pesticides (sulcotrione (SUL) and CLO) and one pharmaceutical (AMI)—was also compared. Results showed that decreased photocatalytic activity was observed in the presence of N_ZnOw_500 NPs in all investigated systems. Finally, the effect of the initial pH was also examined. It was found that in the case of CLO and SUL, there was no influence of the initial pH, while in the case of AMI the kapp was slightly increased in the range from pH ~7 to pH ~10. Full article
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