Special Issue "Advances in Optical Nonlinearity and Ultrafast Phenomena of Nanoscale and Two-Dimensional Materials"

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanophotonics Materials and Devices".

Deadline for manuscript submissions: closed (28 February 2023) | Viewed by 2316

Special Issue Editor

State-Key Laboratory of Optoelectronic Materials and Technologies, School of Physics, Sun Yat-Sen University, Guangzhou 510275, China
Interests: femtosecond laser techniques; ultrafast laser spectroscopy; ultrafast carrier and spin dynamics in condensed matter, including nanoscale materials and structures

Special Issue Information

Dear Colleagues,

Nanoscale materials, so-called nanomaterials, including superlattice quantum wells, quantum wires and dots, have unique quantum natures which can increase or improve not only optical, thermal, mechanical, chemical and electrical properties of materials, but also photonic and photoelectronic properties due to their larger surface-to-volume ratio, high-density surface states and quantum size-induced splitting of energy bands. In recent decades, the advent of new two-dimensional materials, such as graphene, transition metal-dichalcogenides (TMDCs), black phosphorus and topological insulators etc., has enriched the selection of available nanoscale materials. Nanomaterials have been widely used in chemical catalysis, solar cells, biomedicine, nonlinear optics, ultrafast photonic and photoelectronic devices etc. Application examples include the generation of ultrashort laser pulses based on nanomaterials’ saturable absorption mode-locking and ultrafast graphene photodetectors. Many new ultrafast phenomena have emerged in novel nanomaterials, such as ultrafast transport of photocarriers in graphene, valley spin relaxation in TMDCs, and interlayer exciton relaxation in 2D heterostructures. For the development of ultrafast photonic, photoelectronic and spintronic devices, it is crucial that the ultrafast optical nonlinear response and dynamics of photocarriers, phonon, spin, and their interactions are understood.

This Special Issue is focused on advances in the optical nonlinearity and ultrafast photonic and photoelectronic dynamics of nanoscale and two-dimensional materials. Main topics include:

(1) the characterization of optical nonlinearity and the synthesis of novel nanomaterials;

(2) the generation of ultrashort laser pulses and/or ultrawide-bandwidth frequency combs based on the saturable absorption of nanomaterials;

(3) novel ultrafast and ultrahigh spatiotemporal resolved spectroscopy for the dynamic mapping of nanomaterials;

(4) ultrafast dynamics of photocarriers, phonons and/or spin, as well as their interactions in nanomaterials;

(5) nanomaterial-based ultrafast photodetectors with or without a bias voltage;

(6) ultrafast electron and/or spin transport dynamics in 2D heterostructures.

Prof. Dr. Tianshu Lai
Guest Editor

Manuscript Submission Information

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Keywords

  • nanomaterials
  • two-dimensional materials
  • optical nonlinearity
  • ultrafast photonics
  • ultrafast dynamics
  • ultrafast photodetection
  • electron and spin transport

Published Papers (3 papers)

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Research

Article
Ultrafast Photocarrier Dynamics in Vertically Aligned SnS2 Nanoflakes Probing with Transient Terahertz Spectroscopy
Nanomaterials 2023, 13(1), 5; https://doi.org/10.3390/nano13010005 - 20 Dec 2022
Viewed by 486
Abstract
By employing optical pump Terahertz (THz) probe spectroscopy, ultrafast photocarrier dynamics of a two-dimensional (2D) semiconductor, SnS2 nanoflake film, has been investigated systematically at room temperature. The dynamics of photoexcitation is strongly related to the density of edge sites and defects in [...] Read more.
By employing optical pump Terahertz (THz) probe spectroscopy, ultrafast photocarrier dynamics of a two-dimensional (2D) semiconductor, SnS2 nanoflake film, has been investigated systematically at room temperature. The dynamics of photoexcitation is strongly related to the density of edge sites and defects in the SnS2 nanoflakes, which is controllable by adjusting the height of vertically aligned SnS2 during chemical vapor deposition growth. After photoexcitation at 400 nm, the transient THz photoconductivity response of the films can be well fitted with bi-exponential decay function. The fast and slow processes are shorter in the thinner film than in the thicker sample, and both components are independent on the pump fluence. Hereby, we propose that edge-site trapping as well as defect-assisted electron-hole recombination are responsible for the fast and slow decay progress, respectively. Our experimental results demonstrate that the edge sites and defects in SnS2 nanoflakes play a dominant role in photocarrier relaxation, which is crucial in understanding the photoelectrochemical performance of SnS2 nanoflakes. Full article
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Article
Terahertz Emission Spectroscopy of Ultrafast Coupled Spin and Charge Dynamics in Nanometer Ferromagnetic Heterostructures
Nanomaterials 2022, 12(23), 4267; https://doi.org/10.3390/nano12234267 - 30 Nov 2022
Viewed by 624
Abstract
Due to its high sensitivity and because it does not rely on the magneto-optical response, terahertz (THz) emission spectroscopy has been used as a powerful time-resolved tool for investigating ultrafast demagnetization and spin current dynamics in nanometer-thick ferromagnetic (FM)/heavy metal (HM) heterostructures. Here, [...] Read more.
Due to its high sensitivity and because it does not rely on the magneto-optical response, terahertz (THz) emission spectroscopy has been used as a powerful time-resolved tool for investigating ultrafast demagnetization and spin current dynamics in nanometer-thick ferromagnetic (FM)/heavy metal (HM) heterostructures. Here, by changing the order of the conductive HM coating on the FM nanometer film, the dominant electric dipole contribution to the laser-induced THz radiation can be unraveled from the ultrafast magnetic dipole. Furthermore, to take charge equilibration into account, we separate the femtosecond laser-induced spin-to-charge converted current and the instantaneous discharging current within the illuminated area. The THz emission spectroscopy gives us direct information into the coupled spin and charge dynamics during the first moments of the light–matter interaction. Our results also open up new perspectives to manipulate and optimize the ultrafast charge current for promising high-performance and broadband THz radiation. Full article
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Article
Ultrafast Dynamics of Demagnetization in FeMn/MnGa Bilayer Nanofilm Structures via Phonon Transport
Nanomaterials 2022, 12(22), 4088; https://doi.org/10.3390/nano12224088 - 20 Nov 2022
Cited by 1 | Viewed by 635
Abstract
Superdiffusive spin transport has been proposed as a new mechanism of ultrafast demagnetization in layered magnetic nanostructures and demonstrated experimentally. However, it is unknown if it is possible for phonon transport to occur and manipulate ultrafast demagnetization. Here, we explore the ultrafast dynamics [...] Read more.
Superdiffusive spin transport has been proposed as a new mechanism of ultrafast demagnetization in layered magnetic nanostructures and demonstrated experimentally. However, it is unknown if it is possible for phonon transport to occur and manipulate ultrafast demagnetization. Here, we explore the ultrafast dynamics of demagnetization of an antiferromagnet/ferromagnet bilayer nanostructure, of a FeMn/MnGa bilayer film prepared by molecular beam epitaxy. Ultrafast dynamics of a two-step demagnetization were observed through the time-resolved magneto-optical Kerr effect. The first-step fast component of the two-step demagnetization occurred within ~200 fs, while the second-step slow component emerged in a few tens of picoseconds. For a single MnGa film, only the ultrafast dynamics of the first-step fast demagnetization were observed, revealing that the second-step slow demagnetization originates from interlayer phonon transport. A four-temperature model considering phonon transport was developed and used to effectively reproduce the observed ultrafast dynamics of two-step demagnetization. Our results reveal the effect of phonon transport on demagnetization for the first time and open up a new route to manipulate ultrafast demagnetization in layered magnetic structures. Full article
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