Noble Metal Nanomaterials: Controllable Preparation and Properties

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: 15 May 2026 | Viewed by 285

Special Issue Editors


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Guest Editor
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-Efficiency Display and Lighting Technology, School of Materials Science and Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China
Interests: noble materials; low dimension materials; energy and environmental applications; fuel cell; water splitting

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Guest Editor
School of Advanced Energy, IGCME, Shenzhen Campus of Sun Yat-Sen University, Shenzhen 518107, China
Interests: theory, catalyst design and key technologies of solar water splitting to produce hydrogen and high value-added chemicals

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Guest Editor
Henan Key Laboratory of Quantum Materials and Quantum Energy, School of Quantum Information Future Technology, Henan University, Zhengzhou 450046, China
Interests: controllable preparation and photocatalytic/electrocatalytic properties of noble metal nanocrystals; controllable preparation and photocatalytic/electrocatalytic properties of two-dimensional materials; preparation and application of topological materials

Special Issue Information

Dear Colleagues,

The functionalized and synergistic properties of noble metal-based nanomaterials have gained a significant amount of consideration for their diverse catalytic applications. Several design principles for adjusting the catalytic performance by tuning the atomic distribution, size, morphology, composition, and crystal structure have been formulated through a combination of experimental and theoretical research. In spite of the tremendous progress made in this research area, the chemical synthesis of noble metal-based nanomaterials with optimum catalytic properties, such as excellent performance, product selectivity, long-term stability, and scalability, remains a challenge.

The present Special Issue of Nanomaterials is aimed at the controllable preparation and properties of noble metal nanomaterials. In the present Special Issue, we have invited contributions from leading groups in the field with the aim of providing an in-depth understanding of the synthesis of noble metal nanomaterials and the correlation between their structure and catalytic performance.

Dr. Juntao Zhang
Dr. Yazhou Zhang
Dr. Jiabao Ding
Guest Editors

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Keywords

  • noble metal
  • nanomaterials
  • controllable preparation
  • catalytic performance

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Published Papers (1 paper)

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Research

18 pages, 4721 KB  
Article
Tetrametallic Au@Ag-Pd-Pt Nanozyme with Surface-Exposed Active Sites for Enhanced Catalytic Activity
by Vasily G. Panferov, Nadezhda A. Byzova, Konstantin B. Shumaev, Anatoly V. Zherdev and Boris B. Dzantiev
Nanomaterials 2025, 15(23), 1833; https://doi.org/10.3390/nano15231833 - 4 Dec 2025
Viewed by 218
Abstract
Metal nanoparticles (NPs) with enzyme-mimicking activities, known as nanozymes, are being actively explored for biomedical and analytical applications. Enhancing their catalytic activity and metal utilization efficiency is crucial for advancing these technologies. Here, we report an aqueous-phase, room-temperature synthesis of tetra-metallic Au@Ag-Pd-Pt NPs [...] Read more.
Metal nanoparticles (NPs) with enzyme-mimicking activities, known as nanozymes, are being actively explored for biomedical and analytical applications. Enhancing their catalytic activity and metal utilization efficiency is crucial for advancing these technologies. Here, we report an aqueous-phase, room-temperature synthesis of tetra-metallic Au@Ag-Pd-Pt NPs that exhibit superior peroxidase-like activity compared to their mono-, bi-, and trimetallic counterparts. The synthesis involves a sequential, seed-mediated approach comprising the formation of Au NP seeds, the overgrowth of a Ag shell, and the galvanic replacement of Ag with Pd and Pt ions. We systematically investigated the effects of the Au core diameter (15, 40, 55 nm), Ag precursor concentration (50–400 µM), and the Pd-to-Pt ratio on the optical and catalytic properties. By changing the particle composition, we were able to tune the absorbance maximum from 520 nm to 650 nm while maintaining high extinction coefficients (109–1010 M−1cm−1) comparable to that of the initial Au nanoparticles. Mapping of chemical element distributions in the nanoscale range confirmed a core–shell–shell architecture with surface-enriched Pd and Pt. This structure ensures the surface-exposed localization of catalytically active atoms, yielding a more than 10-fold improvement in specific peroxidase-like activity while utilizing up to two orders of magnitude less Pt and Pd than bimetallic particles. The synthesized NPs thus combine high catalytic activity with tunable optical properties, making them promising multifunctional labels for biosensing. Full article
(This article belongs to the Special Issue Noble Metal Nanomaterials: Controllable Preparation and Properties)
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