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Advanced Luminescent Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (31 July 2020) | Viewed by 8792

Special Issue Editor

Department of Energy and Chemical Engineering, Silla University, Busan 46958, Korea
Interests: phosphors; LEDs; structural-optical correlations; nanomaterials; photo-catalysts
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Luminescent materials, phosphors, were invented in the early 17th century. Luminescent materials as spectral-converting materials can be applied in the use of their down-shift, down-conversion, and up-conversion processes when they are excited by ultraviolet (UV) or infrared (IR) light. Recently, phosphor-converted light-emitting diodes (LEDs) have been extensively used as ‘‘smart’’ light sources in applications for lighting, automobiles, transportation, communication, imaging, and agriculture. Furthermore, up-conversion materials have also been developed for the purpose of solid-state 3D displays, oxygenic photosynthesis, optical sensing and imaging, photodynamic therapy, and solar cells. There are many other luminescent technologies and applications. The field of luminescent materials is broadly studying new areas of discovery.

It is my pleasure to invite you to submit a manuscript on advanced luminescent materials. Full papers, communications, and reviews are all welcome.

Dr. Sangmoon Park
Guest Editor

Manuscript Submission Information

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Keywords

  • luminescent materials
  • phosphors
  • spectral-converting materials
  • LED

Published Papers (4 papers)

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Research

9 pages, 4149 KiB  
Article
Luminescence Quenching Behavior of Hydrothermally Grown YVO4:Eu3+ Nanophosphor Excited under Low Temperature and Vacuum Ultra Violet Discharge
by Mihye Wu, Hyemin Park, Eun Gyu Lee, Sanghun Lee, Yu Jin Hong and Sungho Choi
Materials 2020, 13(15), 3270; https://doi.org/10.3390/ma13153270 - 23 Jul 2020
Cited by 3 | Viewed by 1673
Abstract
The luminescence quenching behavior and energy transfer process in hydrothermally grown Eu3+-doped YVO4 nanophosphors were studied using low temperature photoluminescence spectroscopy. The luminescence efficiency of nanophosphor is dependent on the acidity of its solution media and the post annealing condition [...] Read more.
The luminescence quenching behavior and energy transfer process in hydrothermally grown Eu3+-doped YVO4 nanophosphors were studied using low temperature photoluminescence spectroscopy. The luminescence efficiency of nanophosphor is dependent on the acidity of its solution media and the post annealing condition after hydrothermal processing. The overall results suggest that the abnormal luminescence behavior of Eu3+-doped nanocrystalline YVO4 under low temperature photoexcitation is due to the incorporated non-radiative hydroxyl groups often encountered in hydrothermal synthesis as well as to the inefficient energy transfer to luminescent ions from vanadate groups. Full article
(This article belongs to the Special Issue Advanced Luminescent Materials)
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8 pages, 3433 KiB  
Article
Bi3+ and Eu3+ Activated Luminescent Behaviors in Non-Stoichiometric LaO0.65F1.7 Structure
by Sungjun Yang and Sangmoon Park
Materials 2020, 13(10), 2326; https://doi.org/10.3390/ma13102326 - 19 May 2020
Cited by 6 | Viewed by 1811
Abstract
Optical materials composed of La1-p-qBipEuqO0.65F1.7 (p = 0.001–0.05, q = 0–0.1) were prepared via a solid-state reaction using La(Bi,Eu)2O3 and NH4F precursors at 1050 °C [...] Read more.
Optical materials composed of La1-p-qBipEuqO0.65F1.7 (p = 0.001–0.05, q = 0–0.1) were prepared via a solid-state reaction using La(Bi,Eu)2O3 and NH4F precursors at 1050 °C for two hours. X-ray diffraction patterns of the phosphors were obtained permitting the calculation of unit-cell parameters. The two La3+ cation sites were clearly distinguished by exploiting the photoluminescence excitation and emission spectra through Bi3+ and Eu3+ transitions in the non-stoichiometric host lattice. Energy transfer from Bi3+ to Eu3+ upon excitation with 286 nm radiation and its mechanism in the Bi3+- and Eu3+-doped host structures is discussed. The desired Commission Internationale de l’Eclairage values, including emissions in blue-green, white, and red wavelength regions, were obtained from the Bi3+- and Eu3+-doped LaO0.65F1.7 phosphors. Full article
(This article belongs to the Special Issue Advanced Luminescent Materials)
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17 pages, 6883 KiB  
Article
Highly Luminous Ba2SiO4−δN2/3δ:Eu2+ Phosphor for NUV-LEDs: Origin of PL-Enhancement by N3−-Substitution
by Donghyeon Kim, Tae Hun Kim, Tae Eun Hong, Jong-Seong Bae, Chang Hae Kim, Jaegyeom Kim, Seung-Joo Kim, Ki-Wan Jeon and Jung-Chul Park
Materials 2020, 13(8), 1859; https://doi.org/10.3390/ma13081859 - 15 Apr 2020
Cited by 3 | Viewed by 2555
Abstract
Ba2SiO4−δN2/3δ:Eu2+ (BSON:Eu2+) materials with different N3− contents were successfully prepared and characterized. Rietveld refinements showed that N3− ions were partially substituted for the O2− ions in the SiO4-tetrahedra because [...] Read more.
Ba2SiO4−δN2/3δ:Eu2+ (BSON:Eu2+) materials with different N3− contents were successfully prepared and characterized. Rietveld refinements showed that N3− ions were partially substituted for the O2− ions in the SiO4-tetrahedra because the bond lengths of Si‒(O,N) (average value = 1.689 Å) were slightly elongated compared with those of Si‒O (average value = 1.659 Å), which resulted in the minute compression of the Ba(2)‒O bond lengths from 2.832 to 2.810 Å. The average N3− contents of BSON:Eu2+ phosphors were determined from 100 nm to 2000 nm depth of grain using a secondary ion mass spectrometry (SIMS): 0.064 (synthesized using 100% α-Si3N4), 0.035 (using 50% α-Si3N4 and 50% SiO2), and 0.000 (using 100% SiO2). Infrared (IR) and X-ray photoelectron spectroscopy (XPS) measurements corroborated the Rietveld refinements: the new IR mode at 850 cm−1 (Si‒N stretching vibration) and the binding energy at 98.6 eV (Si-2p) due to the N3- substitution. Furthermore, in UV-region, the absorbance of N3−-substituted BSON:Eu2+ (synthesized using 100% α-Si3N4) phosphor was about two times higher than that of BSO:Eu2+ (using 100% SiO2). Owing to the N3− substitution, surprisingly, the photoluminescence (PL) and LED-PL intensity of BSON:Eu2+ (synthesized using 100% α-Si3N4) was about 5.0 times as high as that of BSO:Eu2+ (using 100% SiO2). The compressive strain estimated by the Williamson−Hall (W−H) method, was slightly increased with the higher N3− content in the host-lattice of Ba2SiO4, which warranted that the N3- ion plays an important role in the highly enhanced PL intensity of BSON:Eu2+ phosphor. These phosphor materials could be a bridgehead for developing new phosphors and application in white NUV-LEDs field. Full article
(This article belongs to the Special Issue Advanced Luminescent Materials)
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9 pages, 2569 KiB  
Article
Growth of β-NaYF4:Eu3+ Crystals by the Solvothermal Method with the Aid of Oleic Acid and Their Photoluminescence Properties
by Jianhua Huang, Xiaojing Wang, An Shao, Guoping Du and Nan Chen
Materials 2019, 12(22), 3711; https://doi.org/10.3390/ma12223711 - 11 Nov 2019
Cited by 5 | Viewed by 2286
Abstract
Lanthanide-doped hexagonal β-NaYF4 crystals have received much attention in recent years due to their excellent photoluminescence properties. However, lanthanide-doped β-NaYF4 crystals with micron and submicron scales as well as uniform morphology have received less attention. In this study, Eu3+-doped [...] Read more.
Lanthanide-doped hexagonal β-NaYF4 crystals have received much attention in recent years due to their excellent photoluminescence properties. However, lanthanide-doped β-NaYF4 crystals with micron and submicron scales as well as uniform morphology have received less attention. In this study, Eu3+-doped β-NaYF4 (β-NaYF4:Eu3+) crystals of micron and submicron size scales were synthesized using the solvothermal method with ethylene glycol as the solvent. The β-NaYF4:Eu3+ crystals were highly crystallized. A comparison of the characteristics of the β-NaYF4:Eu3+ crystals synthesized with and without the use of oleic acid as a surfactant was conducted. It was found that the utilization of oleic acid as a surfactant during their synthesis greatly decreased their particle size from micron to submicron scale, while adding a small amount of ethanol further reduced their particle size. In addition, they exhibited much smoother surfaces and more uniform morphologies, which were hexagonal prism bipyramids. The microstructural characteristics and photoluminescence properties of the β-NaYF4:Eu3+ crystals were studied in detail. Results showed that β-NaYF4:Eu3+ crystals prepared with the aid of oleic acid as a surfactant during their synthesis exhibited stronger photoluminescence. Full article
(This article belongs to the Special Issue Advanced Luminescent Materials)
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