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Special Issue "Recent Advances in Catalyst-Transfer Polycondensation"
Deadline for manuscript submissions: 15 March 2020.
Dr. Anton Kiriy Website E-Mail
Leibniz Inst Polymerforsch Dresden eV, Dept Polymer Structures, Hohe Str 6, D-01069 Dresden, Germany
Interests: developing new methods for controlled preparation of π-conjugated (semiconducting) polymers of various architectures for needs of organic electronics (e.g., solar cells, field transistors, light-emitting diodes, energy storage devices, sensors, etc.)
This Special Issue intends to highlight recent developments in the field of chain-growth Catalyst–Transfer Polycondensation (CTP). CTP is an emerging tool for preparation of conjugated (hetero)arene polymers with controllable molecular weights, copolymer sequences, end groups, and narrow dispersities—features that significantly influence polymers’ performance in organic electronic devices. Until now, the best CTP performance was achieved with relatively simple, electron-rich monomers. For example, CTP of AB-type thiophene monomers follows a near living mechanism in the presence of the Ni catalyst, having bidentate phosphine ligands. Recently, several carbene-ligated Ni- and Pd-based precatalysts have been shown to also be effective in CTP. Nevertheless, an important limitation is that these traditional CTP catalysts mostly lead to nonliving, non-chain-growth behavior when monomers having electron-deficient groups are utilized. Because these monomers often show the highest performance in electronic devices, there is a significant need to develop appropriate CTP catalysts. Aiming to extend the CTP monomer scope, significant experimental efforts and theoretical calculations were devoted to the investigation of the CTP mechanism.
Original and review papers, which address the above-mentioned and other related problems experimentally or by means of theoretical calculations, are the focus of this Special Issue.
Dr. Anton Kiriy
Manuscript Submission Information
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.
Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.
- Catalyst‐transfer polycondensation
- Controlled polymerization
- Externally-initiated polymerization
- Phosphine ligands
- N‐heterocyclic carbenes
- Conjugated block copolymers
- End-group analysis
- AB-type monomers
- Kumada CTP
- Suzuki CTP