Optical Characterization of a New Facility for Materials Testing under Concentrated Wavelength-Filtered Solar Radiation Fluxes

: The materials used to manufacture solar receivers for tower power plants must withstand high ﬂuxes of concentrated solar radiation (from 0.1 to even 1.5MWm − 2 ) and operate at high operating temperatures (>800°C). Durability is a key aspect in these systems, which must be en-sured under these demanding operating conditions, which also include daily heating–cooling cycles throughout the lifetime of these power plants. So far, to the authors’ knowledge, which wavelengths of concentrated solar radiation have the greatest inﬂuence on the mechanisms and speed of aging of materials used in solar receivers has not been analyzed. Yet, such an analysis is pertinent in order to implement strategies that delay or inhibit such phenomena, and, thus, increase the durability of central tower systems’ receivers. To perform such analyses, a new solar furnace was recently designed and installed at the Plataforma de Almería (Spain). This paper describes the components of this new solar furnace. The components are as follows: a heliostat to redirect the direct solar radiation towards a Fresnel lens that concentrates the solar radiation on the material under study, a shutter that allows varying the amount of concentrated solar radiation incident on the Fresnel lens, and reﬂective ﬁlters with selective reﬂectance that are placed between the Fresnel lens and the material. This paper also describes the procedure and the ﬁrst results of the energetic and spectral characterization of this new solar furnace. The ﬁrst experimental results of the characterization of this new test bed using the heliostat and the Fresnel lens showed that concentration ratios of up to 1000 suns (1 sun = 1000Wm − 2 ) could be achieved. Furthermore, the paper presents the results of the spectral characterization of the test system, using selective reﬂectance mirrors in the near-visible–IR wavelength range (400–1125nm) and in the visible–IR red region (700–2500nm).


Introduction
In recent years, a number of important global developments have highlighted the need for countries to increasingly reduce their energy dependence on other countries. The generation of solar thermal energy, and of any type of renewable energy, in general, avoids the importing of oil and other fossil fuels from third countries, thus reducing high energy dependence [1]. Spain currently has 50 concentrated solar power plants in operation with a total of 2300 MW of installed power capacity [2]. Quick growth of the technology is expected, supported by technical improvements, as well as benefiting from the stronger political support the decarbonization scenario of the last few years [3] has engendered. Solar thermal power plants, and, in particular, tower, or central receiver, power plants, have great potential for generating electricity, and they have the great advantage that the heat they produce in the receiver can be easily stored, so they can generate electricity on cloudy days or at night. One of the reasons why there are not more solar thermal tower power plants is because they need to improve their efficiency to meet energy demand. This can be done in two ways: either by increasing the heat transfer fluid temperature and, therefore, by increasing solar radiation concentration, or by reducing the costs associated Solar 2023, 3 with the components of such installations [4]. However, the materials used in the receivers of tower solar thermal power plants, and, specifically, those made of metal tubes, reach very high temperatures (>800°C) and endure high fluxes of concentrated solar radiation (>1000 kWm −2 ), so increasing the temperature at the solar receiver is not an easy task. The materials age quickly and last a relatively short time. Hence, it is vital to study these materials so to understand their behavior under concentrated solar radiation in the long term [5].
Improving the durability of these materials, together with increasing the efficiency in the conversion of concentrated solar radiation into heat, would contribute to making solar thermal energy more efficient and economical, as well as more durable [6].
To investigate these aspects of material behavior under concentrated solar radiation, a new testing platform at the Plataforma Solar de Almería (PSA) has been set up, which is able to both reach very high solar concentrated radiation and increase the material's temperature beyond 800°C. The new facility, that uses Fresnel lenses, as well as a selective reflectance mirror, contributes to the characterization of outdoor materials [7], with the particularity allowing active selection of the wavelength range of the impinging radiation on material samples [8].
Section 2 of this article includes a description of the new testing facility components, as well as a description of the methods used for the optical characterization of its components, individually and as a whole. Section 3 includes the results of the optical characterization carried out, with a complete discussion of the results. Finally, the article closes with the conclusions drawn from the present analysis, as well as planned future work at the facility.

Materials and Methods
A new facility is currently being commissioned at the PSA to facilitate investigation of the influence of wavelength on the characterization and aging of materials subjected to high fluxes of concentrated solar radiation [9] and high temperatures (>1 MWm −2 and >800°C respectively), such as metallic nickel alloys like Alloy 625, SiC, etc, which are used in the manufacture of receivers in solar thermal tower power plants. Material aging is a key concern in solar tower receivers as high performance us required to increase the efficiency of the system and its durability.
The new designed and built test facility is a solar furnace composed of a 12 m 2 flat heliostat located 10 m on the north side, far away from a container divided into two areas. One area of the container is a small control room and the second area is the main test room, where there is a Fresnel lens that concentrates the solar radiation on the focal plane where a secondary mirror is placed that focuses on the focal spot located on a test table. Any material sample to be tested is positioned on the test table. The system is completed with a cooling system to control the operating conditions during the experiments. A scheme of the new solar furnace is shown in Figure 1. Figure 2 shows the actual deployment of the facility under operation where the heliostat is redirecting the solar radiation to the solar furnace aperture, where it passes through the completely open shutter placed on the northern wall of the test room (blue container). The rest of the components (i.e., Fresnel lens, mirrors, . . .) are located inside this test room, as illustrated in Figure 1).   Figure 3 shows the optical components of the facility: the heliostat, which was manufactured at PSA, the Fresnel lens [10], and several selective spectral reflectance mirrors. These mirrors allow the filtering of specific wavelength bands of the solar spectrum to be incident on the material, making it possible to analyze the influence of wavelength on the aging of the material [11]. The heliostat (Figure 3a), which is responsible for following the sun throughout the day and reflecting the solar radiation to the aperture plane of the Fresnel lens (Figure 3b), located inside the test room, presents an area of 12 m 2 (3 × 4 m). It is composed of 12 flat mirror facets, manufactured by Guardian Glass, each sized 1 m 2 , with an average solar specular reflectance of 0.956. This specular reflectance was measured with a Devices & Services Portable Specular Reflectometer Model 15R-USB [12]. This specular reflectometer is able to measure the specular reflectance of a reflecting surface with an uncertainty of 1.5%.
The Fresnel lens is the optical component in this test bed, responsible for concentrating the solar radiation reflected by the heliostat on the focal plane. The Fresnel lens needs to be optically characterized for the following: the focal length of the lens, the concentration ratio and the size of the focal spot at the focal plane of the lens, defined by the radius of the circle containing 90% of the energy measured in the focal plane.
For this characterization, a Lambertian target [13], equipped with a radiometer, a CMOS camera and a data acquisition system, was used. The main characteristics of each of the components of the measurement system are described below [14]: The radiometer used is of the water-cooled Gardon type and its measurement is based on a copper-constantan differential thermocouple transducer (Seebeck effect). The incident power on the sensor is proportional to the voltage generated. The accuracy of the radiometer used on the measurement system equals 3.0% • Data acquisition system. The radiometer signals, as well as those of the cooling water temperature control thermocouples, were acquired with a SIEMENS 1231 14 bits data acquisition card.
All the constitutive components of the measurement system are shown in Figure 4.

Fresnel Lens Characterization Method
Once everything is ready in the new Fresnel solar furnace, the shutter is opened, allowing solar radiation to concentrate on the Fresnel lens and to focus on the Lambertian target. The digital camera facing the Lambertian target takes a digital image of gray levels (brightness level) and the radiometer gives a point measurement of the incident power at that point of the Lambertian target in engineering units (kWm −2 ), with a simple linear correlation between the illumination level of each of the pixels of the image taken and the reading of the radiometer, we can extend the point measurement of incident power, taken with the radiometer, to the entire surface of the Lambertian target, and, thus, have a map of incident power from which we can calculate the total energy in that target. The line of adjustment to be obtained with the linear relationship between the gray level (GL) and the radiometer reading (H) has the following form: The parameter A of Equation (1) converts the illumination levels of the pixels of the images taken with the CMOS camera to physical units of incident radiation power (kWm −2 ). In this way, the rest of the energy calculations for the Fresnel lens can be performed in energy and power units.
The total incident energy on the measurement plane is calculated by summing the power measured on each of the specified surface elements (pixels), then multiplying by S, so that the effective measurement area (size of the image on the Lambertian target in mm) can be presented as in Equation (2): where n are the surface elements in which this area has been divided in the image. On the other hand, the efficiency of the Fresnel lens is calculated as follows (Equation (3)): where G is the direct normal solar irradiance and S gross is the gross aperture of the lens (including frames). In the same way, net efficiency can be defined as follows: where, in this case, S net is restricted to the useful aperture of the concentrator, removing all the structural elements that do not transmit solar radiation, such as the metal profile that separates the two parts of the lens. The Fresnel lens is formed by two halves that, by means of their radial blades, form a focus when solar radiation falls on the lens. The net and gross surfaces of the Fresnel lens are, respectively, 1.4 m 2 and 1.62 m 2 . The gross total efficiency takes into account the area formed by the lens, together with the frame that contains it. It is the net efficiency that is of interest, since it represents the total efficiency only taking the Fresnel lens into account, without counting its frame. This net total efficiency represents the real efficiency of the Fresnel solar lens.

Fresnel Lens Characterization Results
The characterization of the Fresnel lens was performed on clear sky days and for both sides of the lens, since this lens reproduces focus in both directions. In this way, the lens can have two positions inside the Fresnel solar furnace: For each Fresnel lens position, so as to perform its characterization, several images were taken of the light spot on the Lambertian target at the corresponding focal distance for each position, defining different shutter apertures during the tests. Figure 5 shows two images for each one of the characterizations.  With these pictures, it is possible to establish a linear relation between the illumination of the images (GL) and incident power (H), calculating the slope of the linear fit for the experimental points obtained from the different images changing the shutter aperture of the solar furnace. Figure 6 shows the least squares fit of the experimental data for both characterizations (A and B).
With both slopes presented in Figure 6, for characterization A (red one) and characterization B (blue one), it is possible to calculate the total energy collected by the system at the focal plane, as well as the rest of the parameters that completely characterize the Fresnel lens. These results are shown in Table 1. Figure 7 shows the calibrated figures of the incident solar flux distribution at focal plane for both characterizations.
The first thing to notice is that the optimal focal length for both characterizations was not the same. The optical focal length depended on how the Fresnel lens was arranged with respect to the heliostat and the test table. It can be seen in both cases that, although the focal spot radius containing the 90% energy was small (28.7 mm and 27.0 mm, respectively), the peak power of the full Fresnel lens was quite high for both characterizations (1086.7 kWm −2 for characterization A and 1134.9 kWm −2 for characterization B), as well as the net efficiency (0.92 and 0.94, respectively). Therefore, it could be expected that with either position #1 or #2 of the Fresnel lens, good results would be obtained by concentrating the solar radiation on the material to be tested.   However, in order to know the optimal focal length and arrangement between the two characterization positions of the Fresnel lens, and to see which was more interesting in terms of concentration ratio (C), the peak power obtained in Table 1 could be divided by the direct normal solar irradiance (G) and, thus, the energy concentration ratio of the Fresnel lens calculated. The results are included on Table 2 showing higher concentration at characterization position #2 i.e., the rough side of the Fresnel lens facing the test table and the smooth side focused towards the heliostat, with a focal distance of 3.56 m.

Characterization Results of Selective Spectral Reflectance Mirrors
For spectrally filtering the solar radiation, the facility is equipped with six mirrors with selective spectral reflectances. Table 3 shows the spectral characteristics and specifications of these selective reflectance mirrors [15]. The six mirrors were characterized in the OPAC laboratory of the PSA with a spectrophotometer to determine the solar hemispherical reflectance of each of them (Table 3). From the analysis, the mirrors that seemed most interesting, from the spectral point of view, were mirrors #3 and #6. As can be seen in Figure 8, the spectral reflectance of mirrors #3 and #6 appear, together with the irradiance of the standard solar AM 1.5 spectrum [16], to be those that modify/filter the solar spectrum in the wavelength bands below 625 nm , which are those that, according to previous studies [6], photooxidize the material the most.  Figure 9 shows the irradiance of the standard AM 1.5 solar spectrum, as well as the spectrum of the solar radiation reflected by mirrors #3 and #6, respectively, taking into account the fact that optical losses are attached to the curves, due to the heliostat mirrors (0.04), and to the transmissivity of the Fresnel lens (0.09). Thus, the spectrum curves shown in Figure 9 were those that finally affect the material to be tested. As can be seen in Figure 9, mirror #3 (red curve) significantly reduced the ultraviolet and visible wavelengths, while keeping the infrared part of the solar spectrum unchanged. On the other hand, mirror #6 (blue curve) acted as a band-pass filter in the ultraviolet and near-infrared. Both mirrors would allow us to establish the dependence, if any, of the behavior of the materials under study on the wavelength of the solar spectrum.

Conclusions and Future Work
The results from the characterization process of the new solar furnace's components showed consistent results according to the design. Two configurations of the Fresnel lens were analyzed, and one of them (characterization B), was the selected option for future experiments, as it presented a focal distance of 3.56 m and allowed a peak power of more than 1 MWm −2 with a total energy of 1.13 ± 0.03 kW (@DNI = 873.4 Wm −2 ) to be reached in the focal spot, with a net efficiency of 0.92. These values were consistent with initial specifications for the test bed.
In any case, it was also concluded that the optical characterization of the test bed should be performed any time a testing campaign is to be performed in the solar furnace, to ensure accurate results on aging tests of each specific material to be tested.
Taking into account the fact that materials suffer bigger photooxidation with short wavelengths (<625 nm) [5], it was demonstrated that mirror #3 (700-10,000 nm band) and mirror #6 (400-1125 nm band) were suitable to test and age the material samples, with the aim of analyzing their optical and thermal behaviors during their lifetimes, so as to estimate their durability. As shown in Figure 9, these mirrors significantly modified the profile of the concentrated solar radiation impinging on the material surface, which would very likely modify its microstructure.
Once all the components of the new solar furnace installed at PSA are characterized, the system is ready for testing and studying the aging mechanism of materials that are currently used, or are candidates for use, in receivers of commercial solar tower systems. Future work will begin with the analysis of samples of Nickel 625 alloy (Inconel 625), as it is one of the most used in tube receivers of solar tower systems [4].