Desorption of Arsenic from Calcareous Mine Affected Soils by Phosphate Fertilizers Application in Relation to Soil Properties and As Partitioning
Abstract
:1. Introduction
2. Materials and Methods
2.1. Soils
2.2. Stock Solutions and Reagents
2.3. Batch Experiments
2.3.1. Effect of Contact Time
2.3.2. As Desorption—P Sorption Batch Experiments
2.3.3. Calculation of As Desorption and P Sorption Percentage
2.4. Analytical Determinations
2.5. Statistics
3. Results
3.1. Soil Properties
3.2. Solutions pH
3.3. Arsenic Desorption
3.4. Added Phosphorus Sorption
3.5. Distribution of Organic and Inorganic Forms of Added P
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Soil Properties | ||
---|---|---|
Soil 1 | Soil 2 | |
Clay (g kg−1) | 328 | 230 |
Silt (g kg−1) | 214 | 210 |
Sand (g kg−1) | 458 | 560 |
pH (1:1) | 8 | 7.7 |
CaCO3 (g kg−1) | 115 | 64 |
Act. CaCO3 (g kg−1) | 27 | 3 |
O.C. (g kg−1) | 11 | 26 |
CEC (cmolc kg−1) | 30 | 27 |
Fed (mg kg−1) | 41.5 | 45.3 |
Feo (mg kg−1) | 4.8 | 7 |
Ald (mg kg−1) | 728.3 | 574.8 |
Alo (mg kg−1) | 2389.5 | 1098 |
As total (mg kg−1) | 852 | 1745 |
P total (mg kg−1) | 733 | 1061 |
P in. (mg kg−1) | 391 | 796 |
P org. (mg kg−1) | 342 | 265 |
P avail. (mg kg−1) | 10.7 | 11 |
As fractions obtained by SEP | ||
W1: Nonspecifically sorbed As (mg kg−1) | 5 | 4.1 |
W2: Specifically sorbed As (mg kg−1) | 103.6 | 64.3 |
W3: As sorbed on amorphous Fe-Al oxides (mg kg−1) | 313.3 | 644.9 |
W4: As sorbed on crystalline Fe-Al oxides (mg kg−1) | 240.8 | 393.8 |
W5: Residual As (mg kg−1) | 106 | 302.9 |
SOIL 1 | ||||
Factor | SS | DF | MS | p |
P treatment | 86.17 | 2 | 43.09 | <0.001 |
P rate | 15116.6 | 6 | 2519.36 | <0.001 |
P treatment X P rate | 271.81 | 12 | 22.65 | <0.001 |
SOIL 2 | ||||
Factor | SS | DF | MS | p |
P treatment | 58.99 | 2 | 29.50 | <0.05 |
P rate | 1381.34 | 6 | 230.22 | <0.001 |
P treatment X P rate | 225.91 | 12 | 18.83 | <0.01 |
Langmuir Constants | Freundlich Constants | ||||||||
---|---|---|---|---|---|---|---|---|---|
qm (mg/g) | bL (L/mg) | R2 | p-Value | KF (mg/g) (L/mg)1/n | 1/n | R2 | p-Value | ||
Soil 1 | T1 | 0.68 | 0.090 | 0.968 | <0.001 | 12.81 | 0.525 | 0.960 | <0.001 |
T2 | 0.48 | 0.167 | 0.996 | <0.001 | 12.07 | 0.468 | 0.957 | <0.001 | |
T3 | 0.73 | 0.070 | 0.932 | <0.01 | 13.06 | 0.511 | 0.995 | <0.001 | |
Soil 2 | T1 | 1.36 | 0.018 | 0.776 | <0.01 | 31.26 | 0.762 | 0.998 | <0.001 |
T2 | 0.81 | 0.034 | 0.886 | <0.01 | 26.14 | 0.675 | 0.994 | <0.001 | |
T3 | 0.99 | 0.024 | 0.648 | <0.05 | 26.58 | 0.676 | 0.946 | <0.01 |
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Zafeiriou, I.; Gasparatos, D.; Kalyvas, G.; Ioannou, D.; Massas, I. Desorption of Arsenic from Calcareous Mine Affected Soils by Phosphate Fertilizers Application in Relation to Soil Properties and As Partitioning. Soil Syst. 2019, 3, 54. https://doi.org/10.3390/soilsystems3030054
Zafeiriou I, Gasparatos D, Kalyvas G, Ioannou D, Massas I. Desorption of Arsenic from Calcareous Mine Affected Soils by Phosphate Fertilizers Application in Relation to Soil Properties and As Partitioning. Soil Systems. 2019; 3(3):54. https://doi.org/10.3390/soilsystems3030054
Chicago/Turabian StyleZafeiriou, Ioannis, Dionisios Gasparatos, Georgios Kalyvas, Dafni Ioannou, and Ioannis Massas. 2019. "Desorption of Arsenic from Calcareous Mine Affected Soils by Phosphate Fertilizers Application in Relation to Soil Properties and As Partitioning" Soil Systems 3, no. 3: 54. https://doi.org/10.3390/soilsystems3030054