Biobased Polymer Composites: A Review

: Global environmental concerns, as well as the rapid depletion of non-renewable fossil fuel-based resources, have prompted research into the development of sustainable, environmentally friendly, and biodegradable materials for use in a variety of high-end applications. To mitigate the environmental setbacks caused by nonbiodegradable materials, the development of biocomposites with improved mechanical performance is gradually gaining momentum. Natural ﬁbers such as hemp, ﬂax, and sisal have been well incorporated into biocomposite development. Nonetheless, the impact of functional moieties in their life cycle cannot be underestimated. In this review paper, a detailed discussion of the characteristics and components of biocomposites is presented. The treatment of composite materials (alkali and acetylation), as well as several manufacturing processes (hand layup, 3D printing, extrusion, etc.) and the applications of biocomposites, which are not limited to the aerospace industry, packaging, biomedicine, etc., are presented. Biocomposites with excellent durability, performance, serviceability, and reliability must be produced to expand their applications.


Introduction
A growing number of industrialized economies throughout the world are becoming attracted to the production of novel materials made primarily of polymers because of their advantages and key roles in the circular economy concept and model [1].Despite this, waste from nonbiodegradable materials has increased over the years due to the increased and continued use of non-compostable materials and the low material efficiency of the linear industrialization system.Waste management, as put forward in the amended European Commission act, is defined as "the collecting, transporting, or processing of waste, including sorting, coupled with the monitoring of the aforementioned activities, as well as the following management of waste disposal sites and actions done as a waste seller or waste broker" [2].The classification of waste is determined by the sources of production as well as the level of setback or harm to the environment, animals, human health, or human life [3].While waste generation has led to a series of environmental setbacks, waste management, on the other hand, is an interesting pathway to job creation.The efforts of many developing countries center on the resource recovery through material reuse and recycling to reduce negative environmental impact and minimize the pressure on natural resources.Unfortunately, the use of plastic-based materials and consumers' increasing preference for nonbiodegradable materials is becoming a serious concern for environmental experts.Owing to their polluting effects, the waste produced from these materials threatens natural resources, such as soil, water, and air resources, thereby undermining the goals and objectives of the circular economy.As agreed by several scholars, reusing and remanufacturing in industrial processes could help to mitigate the adverse setbacks of waste generation and provide a framework for sustainable consumption initiatives [4][5][6].However, many consumers of these products prefer to use landfills for multi-material products (e.g., wind turbines, used tyres, solar panels, etc.) because of the high cost associated with recycling the materials [1].The landfill deposition of nonbiodegradable products is well rooted and widely adopted in all domains of the industrial and domestic sectors.The decomposition of deposited materials leads to the emission of hazardous leachate and gases.According to Dathurebandara and co-workers [7], the most emitted gases from landfills are methane and carbon dioxide, while leachate can travel to groundwater or even to surface water through cracks in the liners and pose a problem to aquifers.As a result, both the environment's quality and the public's health could be at risk from these pollutants.As sustainability and landfill reduction objectives continue to demand more actions through goal-oriented policies and research progress, there is a need for novel alternatives to develop materials with excellent characteristics to meet modern-day applications.
The utilization of synthetic fiber-reinforced composites in the aerospace, automobile and packaging industries is extensive due to their highly promising strength, flexibility, rigidity, and potential for an important and diverse range of applications [8].For many industries, composites have been an important raw material in their manufacturing processes, particularly for products such as cars, construction, or building materials.From a broad perspective, the uniqueness of composites reveals that they contain at least two microscopically different components which can be combined to address some drawbacks which are not limited to weakness and compatibility issues.Despite this appealing advantage, conventional composites are less desired for high-end applications because of their high energy requirement.Another particular disadvantage is that they are difficult to disassemble at the end of their use phase [9].To sidestep these drawbacks, synthetic fibers have been replaced with biofibers as composites.Interestingly, environmental concerns such as plastic waste generation and fuel scarcity and the growing concerns among people focusing on the carbon footprint strategies have led human beings to reconsider the consumption of plastics.According to the statistics, more than 300 metric tons of plastics are produced worldwide per year, demonstrating the large quantity of waste produced by the plastic sector [10].
Therefore, the recent studies seek possible alternatives through more eco-friendly and sustainable polymers and materials [11].It is worth mentioning that the emergence of the circular bioeconomy concept has sparked a lot of attention because of the new environmental policies.In this concept, the effective utilization of all material components is succinctly captured [12].Thus, many industrial by-products need to be dealt with by sustainable plans and policies to find their feasible applications [13].Outstanding reports have been published by scholars on the valorization of renewable bioresource materials.Starch, cellulose, and wood biomass, amongst numerous other biobased raw materials, are well rooted as biopolymers [14].They significantly contribute to lowering the carbon footprint compared to conventional plastics [15].Nonetheless, the cravings of the rapidly expanding population center on making the best use of developed innovative and sustainable products from these environmentally benign raw materials.As evidenced in the literature, starch, cellulose, alginate, and fiber-rich materials, such as flax, hemp, sisal, jute, etc., could be partially incorporated with another material or blended to form composites.The uniqueness of the end product has drawn attention from the scientific and commercial standpoints, and their uses for novel applications are currently gaining momentum.

Scope of the Review
This review paper aimed to provide information on biocomposites, with a focus on the various treatment methods, modes of compatibilization, and environmental impacts of the functional components in biocomposites.In addition, the use of biocomposites in revolutionary applications was documented in this paper.We utilized academic search engines (e.g., Google Scholar) to access all the information while all the articles cited were scientifically indexed and documented in databases such as Scopus, Web of Science, and ScienceDirect.To the best of our knowledge, preference was given first to published articles in the past decade (2012)(2013)(2014)(2015)(2016)(2017)(2018)(2019)(2020)(2021)(2022).Nonetheless, relevant articles from earlier years that captured the context of the keywords, such as "biopolymers", "biocomposites", "molding techniques", "compatibilization", "circular bioeconomy", "moieties", etc., were also used.The research gaps, the perspectives and uncertainties, and the outlook were summarized in this paper.

Characteristics of Biocomposites
Natural fibers and the matrix component make up biocomposites.Biodegradable or non-biodegradable polymers can be used to create the matrix.According to Sharma and co-workers [16], polymer matrix biocomposites comprise natural (PLA, PHA, PCL) or synthetic matrix materials (thermoplastic and thermosetting plastics) coupled with the addition of one or more reinforcements, such as carbon fibers, glass fibers, or natural fibers.The fibers give strength to the material, and the resin holds it together, which ensures that the product stays rigid and protects the fibers from moisture.The effect of the reinforcement on the polymer matrix composite was reviewed in the literature of Das Lala and colleagues [17].The authors noted that animal-fiber, protein, and biochemicalreinforced polymer matrix composites have a mechanical strength that makes them a potential material for scaffolds and implants in biomedical applications but advised that the relevant research should concentrate its efforts into finding other potential applications for polymer matrix composites.The aspect ratio and fiber size play essential roles in the strength of the composite [18].Although the integration of the small particles into the processing equipment is effective, low aspect ratios give rise to stress concentration, resulting in a lower strength when compared to a neat polymer [19,20].A higher aspect ratio results in superior mechanical characteristics as the load is transferred more effectively with the increasing L/D ratio [18].Biocomposites made from biopolymers and natural fibers are very appealing because of their ability to provide required functions at a cheaper price [21].They are biodegradable and recyclable; they can be disposed effortlessly after they have fulfilled their purpose, without negatively affecting the environment.This is not feasible in the case of synthetic composites derived from fossil fuel resources.According to the biocomposites market prediction research, the industry will expand from USD 23.90 billion in 2021 to USD 80.55 billion by 2029 [22].Plastic composites are being effectively substituted by biocomposites [23].

Natural Fibers as Reinforcement and Criteria for Selection
Plant fibers, such as bast, leaf, and wood fibers, have piqued the interest of many scholars and are being considered as reinforcing agents [24,25].They contain cellulose, lignin, hemicellulose, and pectin in different quantities [26].The chemical composition of plant fibers is also affected by the growth period, stalk height, and botanical classification of the fibers [27].Hemp, flax, kenaf, and jute, which are all components of bast fiber, are derived from the plant's stem and are widely employed for reinforcing composites because of their longer length as well as their high strength and stiffness [28].Interestingly, various non-wood fibers (e.g., flax, kenaf, sisal, and hemp) are also currently used commercially in biocomposites in proportion with polypropylene for applications in the automotive sectors.Native grass fibers are also attracting scientists' attention as reinforcement fibers.Some of the widely available fibers are rice, wheat, or corn straw fibers, which can be used as a very economical reinforcement for biocomposite materials [29].Low embodied energy, good influence on agriculture, and CO 2 sequestration are some of the benefits of utilizing natural fibers in composite materials [28].Natural fibers are recyclable and biodegradable, and this has resulted in the increased use of these fibers in composite reinforcement applications.Natural fibers absorb CO 2 while growing which ultimately reduces their carbon footprint compared to the petroleum-based fibers.Korol and colleagues [30] carried out a comparative analysis of the carbon, ecological, and water footprints of polypropylene (PP)-based composites containing cotton, jute, and kenaf fibers.Their results indicated that by incorporating 30% cotton, jute, and kenaf fibers into a polypropylene matrix the carbon footprint was reduced by 3%, 18%, and 18%, respectively.Nonetheless, jute and kenaf fibers performed better than glass fibers for these footprints.Another advantage of natural fibers when compared to glass fibers is their relatively cheap cost [31].The specific modulus of natural fibers is comparable to that of glass fibers which makes them of particular interest in engineering composites (Table 1).Substituting glass fibers with natural fibers in the development of the sun roof frame led to a 50% weight reduction on the 2017 Mercedes Benz E Class [32].Table 1 summarizes the properties of various natural and synthetic fibers.Natural fiber determines the mechanical characteristics of the composite.There are several factors that influence the performance of the fibers, including climate and the geographical location where they were harvested.Seed density, crop variety, extraction techniques, post treatment, etc., are some other factors.Fibers obtained from different sources have varying properties.As a result, one cannot simply choose one natural fiber over another, and the choice is mostly determined by the application needs.As the main application area is structural applications, the mechanical properties of the fiber are the most important parameters as they indubitably affect the performance of the composite.Specific modulus, specific strength, aspect ratio, elongation at break, moisture content, and cost are the major assessment criteria for the selection of fibers [37].Using continuous fibers produces composites with good structural characteristics for structural applications.However, the natural fibers are not available in continuous form in nature, and typically, the length is of a few millimetres to 20-30 mm [38].
Natural fibers are hydrophilic in nature, i.e., they attract water molecules.The hydrophilicity of natural fibers results in the delamination between the fiber and the polymeric matrix, which reduces the mechanical characteristics of the resulting composites [34].As depicted in Figure 1, the poor interfacial bonding gives rise to the fiber pull-out phenomenon that further deteriorates the mechanical properties [39].The thermal degradation temperature of the natural fibers is low (around 200 • C).The presence of waxes on the surfaces of the fibers makes it difficult to achieve good bonding between the fiber and the matrix.These disadvantages, which include hydrophilicity, poor bonding, and thermal instability, can be overcome by subjecting the fibers to physical and chemical treatments.[39]).

Treatment of Biocomposites
Composite qualities are determined by a number of parameters, including fibermatrix adhesion, fiber length, fiber content (loading), fiber treatment, and fiber dispersion in the matrix [40,41].As a result, progress has been made in recent years to understand the behavior of materials as influenced by any of these parameters.Outstandingly, the treatment of biocomposites has gained momentum and is increasingly attracting numerous inputs from scholars.Faruk and co-workers [34], in their report, documented the types of natural fibers addressable as biocomposites.The authors, however, observed that the interfacial adhesion between natural fibers and the matrix because of different treatment processes will continue to be the most important issue in terms of overall performance because it determines the final attributes of the composites.Physical treatments, such as plasma discharge and corona discharge, improve the bonding between the fiber and the matrix without modifying the chemical characteristics of the fibers [34].However, these physical treatment methods only affect the surface characteristics of the fiber.While plasma discharge roughens up the surface of the fiber in order to enhance better interfacial bonding, corona discharge, on the other hand, results in surface oxidation and leads to a better compatibility between the fiber and the matrix [42].Other examples of physical treatment methods include ultraviolet bombardment, laser, and gamma-ray [43].The chemical treatment of biocomposites is somewhat similar to plasma discharge, but it is usually carried out via a chemical reaction pathway.The most commonly reported chemical treatment methods in the literature are alkali treatment (mercerization) [44] and acetylation [45].Nonetheless, chemical treatments, such as silane treatment [46], benzoylation treatment [47], maleated coupling agents [48], permanganate treatment [49,50], and peroxide treatment [51,52], have been widely reported in the literature.Alkali treatment disrupts the H-H bond in the structure and hence increases the roughness in the fiber's surface, promoting better interlocking between the matrix and the fibers.Furthermore, the waxes, oils, and lignin present in the fiber's external surface are washed away, depolymerizing the cellulose, and the short crystallites are exposed due to this treatment [51].In acetylation treatment, an acetyl group is introduced in the cell wall of the fibers, replacing the hydroxyl group.The acetyl group repels water molecules, thus rendering the fibers hydrophobic.The hygroscopicity of nat-

Treatment of Biocomposites
Composite qualities are determined by a number of parameters, including fiber-matrix adhesion, fiber length, fiber content (loading), fiber treatment, and fiber dispersion in the matrix [40,41].As a result, progress has been made in recent years to understand the behavior of materials as influenced by any of these parameters.Outstandingly, the treatment of biocomposites has gained momentum and is increasingly attracting numerous inputs from scholars.Faruk and co-workers [34], in their report, documented the types of natural fibers addressable as biocomposites.The authors, however, observed that the interfacial adhesion between natural fibers and the matrix because of different treatment processes will continue to be the most important issue in terms of overall performance because it determines the final attributes of the composites.Physical treatments, such as plasma discharge and corona discharge, improve the bonding between the fiber and the matrix without modifying the chemical characteristics of the fibers [34].However, these physical treatment methods only affect the surface characteristics of the fiber.While plasma discharge roughens up the surface of the fiber in order to enhance better interfacial bonding, corona discharge, on the other hand, results in surface oxidation and leads to a better compatibility between the fiber and the matrix [42].Other examples of physical treatment methods include ultraviolet bombardment, laser, and gamma-ray [43].The chemical treatment of biocomposites is somewhat similar to plasma discharge, but it is usually carried out via a chemical reaction pathway.The most commonly reported chemical treatment methods in the literature are alkali treatment (mercerization) [44] and acetylation [45].Nonetheless, chemical treatments, such as silane treatment [46], benzoylation treatment [47], maleated coupling agents [48], permanganate treatment [49,50], and peroxide treatment [51,52], have been widely reported in the literature.Alkali treatment disrupts the H-H bond in the structure and hence increases the roughness in the fiber's surface, promoting better interlocking between the matrix and the fibers.Furthermore, the waxes, oils, and lignin present in the fiber's external surface are washed away, depolymerizing the cellulose, and the short crystallites are exposed due to this treatment [51].In acetylation treatment, an acetyl group is introduced in the cell wall of the fibers, replacing the hydroxyl group.The acetyl group repels water molecules, thus rendering the fibers hydrophobic.The hygroscopicity of natural fibers can be reduced by the acetylation treatment.As a result, the resulting composites have increased dimensional stability [53].Given the increased popularity of these two chemical approaches, it is critical to provide more detailed information regarding their distinctiveness and applications (Sections 5.1 and 5.2).The effects of the various treatments on the properties of fibers have been noted in Table 2.

Alkaline Treatment
The treatment of natural fibers with alkali solution removes waxes, hemicellulose, and oils, thereby increasing the roughness of the external surface of the fibers and rendering the fibers thermally stable.The increased roughness leads to better interlocking between the fibers and the matrix, enhancing the overall mechanical characteristics of the resulting composites [67].The concentration of the alkaline solution, the temperature, and the time of the alkaline treatment highly influences the effectiveness [68].The fiber fragmentation and separation rate increases with alkaline treatment [69].Sodium hydroxide (NaOH) is generally used for the treatment of natural fibers.Hemicellulose, waxes, oils, and lignin are removed when the fibers are treated with a NaOH solution.As a result, the fibrils are revealed, and the roughness of the fiber surface increases.Amorphous regions are created in the tightly packed cellulose lattice, thereby altering the orientation of the cellulose lattice.The new cellulose lattice has a comparatively larger distance between the cellulose molecules and water molecules fill the space between the cellulose molecules [70].OH groups sensitive to NaOH are thus broken down and eventually removed from the fiber structure.Hence, water-loving OH groups are removed, resulting in increased moisture resistance.Moreover, oils, waxes, and hemicelluloses are also removed [70].A Na + ion reacts with the fiber, as shown in the following chemical reaction [71].Figure 2 shows the schematic representation of the chemical reaction of the alkali treatment process.ural fibers can be reduced by the acetylation treatment.As a result, the resulting composites have increased dimensional stability [53].Given the increased popularity of these two chemical approaches, it is critical to provide more detailed information regarding their distinctiveness and applications (Sections 5.1 and 5.2).The effects of the various treatments on the properties of fibers have been noted in Table 2.
Table 2. Various chemical treatments and their effects.

Chemical Treatment Effect References
Alkaline treatment Surface roughness increases and hence there is better interlocking between fiber and matrix [44,[54][55][56] Acetylation

Alkaline Treatment
The treatment of natural fibers with alkali solution removes waxes, hemicellulose, and oils, thereby increasing the roughness of the external surface of the fibers and rendering the fibers thermally stable.The increased roughness leads to better interlocking between the fibers and the matrix, enhancing the overall mechanical characteristics of the resulting composites [67].The concentration of the alkaline solution, the temperature, and the time of the alkaline treatment highly influences the effectiveness [68].The fiber fragmentation and separation rate increases with alkaline treatment [69].Sodium hydroxide (NaOH) is generally used for the treatment of natural fibers.Hemicellulose, waxes, oils, and lignin are removed when the fibers are treated with a NaOH solution.As a result, the fibrils are revealed, and the roughness of the fiber surface increases.Amorphous regions are created in the tightly packed cellulose lattice, thereby altering the orientation of the cellulose lattice.The new cellulose lattice has a comparatively larger distance between the cellulose molecules and water molecules fill the space between the cellulose molecules [70].OH groups sensitive to NaOH are thus broken down and eventually removed from the fiber structure.Hence, water-loving OH groups are removed, resulting in increased moisture resistance.Moreover, oils, waxes, and hemicelluloses are also removed [70].A Na + ion reacts with the fiber, as shown in the following chemical reaction [71].Figure 2 shows the schematic representation of the chemical reaction of the alkali treatment process.
Fiber-OH + NaOH → Fiber-O-Na + + H2O + Surface Impurities Pannu et al. [73] investigated the influence of alkaline treatment on the mechanical properties of composites and found that the tensile strength and impact energy of the treated composites both increased by around 34% compared to the untreated one.The findings of the scholars were corroborated by Abdullah et al. [44], who observed that the alkaline treatment of seaweed fibers increased the tensile strength of composites by around 48% compared to the untreated one.This increment in tensile strength can be attributed to the greater adhesion between the seaweed fibers and polypropylene.The study also showed the increment of the impact strength of the composites to be 106%.The authors also noticed the lower water absorption in the treated composites compared to the untreated one [44].In most of the surveyed literature (Table 3), many of the scholars observed that alkaline treatment of the natural fibers leads to greater adhesion between the fiber and the matrix, which improves the composites' mechanical performance.PLA is well rooted as a matrix for the composite (Table 3).Considering the mechanical features, different matrix materials, such as PLA and polypropylene, amongst several other matrix precursors, offer significantly higher tensile strength.

Matrix Remarks References
Banana fibers PLA Increment in tensile strength and impact strength both around 34%. [73]

Seaweed fibers Polypropylene
Tensile strength improved by around 48% and the impact strength by around 106%.Water absorption rate was observed to be lower in treated composites.[44] Rice and einkorn wheat husk PLA The bending stress and modulus were increased, indicating the better interfacial adhesion [54] Hemp fiber Polypropylene The tensile properties of the resulting composite increased for fibers treated at higher temperature. [74] Alfa fiber Modified sunflower oil Interfacial adhesion was improved, resulting in better mechanical properties and thermal stability of the composites. [55] Eucalyptus microfibers PLA Mechanical properties were increased. [75]

Ground coffee HDPE
There was an improvement in interfacial adhesion, water resistance, impact, and tensile characteristics. [56] Kenaf fiber mat PLA The mechanical performance of the treated biocomposite was higher than that of the untreated one. [76]

Acetylation Treatment
Acetylation treatment modifies the mechanical and thermal properties plasticizing the natural fibers.Acetic anhydride is the commonly used chemical in this treatment.Acetyl groups are introduced in the cell walls of the fibers, replacing the OH groups, making the fibers hydrophobic [53].Acetic acid is also produced as the by-product, which must be removed before using the fiber.The chemical reaction [53] is shown below: Chung et al. [79] investigated the effect of acetylation treatment on the mechanical performance of kenaf fiber reinforced with PLA biocomposites and reported the increment in tensile strength and flexural strength of the treated composites compared to the untreated one.The findings agree with the study carried out by Kivade et al. [59], who reported that the tensile strength, impact strength, and flexural strength of the acetylation-treated banana fiber-reinforced composites was increased by around 98%, 58%, and 24% compared to the untreated one.The study also showed that the water absorption rate was lower in the treated composites [59].With acetylation treatment, the water absorbing tendency of the natural fibers is reduced, and the resulting composites are more dimensionally stable.Table 4 reviews the effect of acetylation treatment on the performance of the composites.

Matrix Remarks References
Combretum dolichopetalum fiber HDPE Ultimate tensile strength and impact strength increased by 18.78% and 58.73%, respectively, compared to untreated one. [78] Kenaf fiber PLA Increased mechanical characteristics and water resistance as well as the thermal stability.[79] Banana fiber Polyvinyl alcohol (PVA) Showed an increase of 98%, 58%, and 24% in tensile, flexural, and impact strength of the treated composites.The water absorption rate also reduced. [59]

Wood fiber HDPE
Resulted in improved interfacial adhesion, higher Young's modulus, and lower strain at failure. [82]

Softwood pulp fiber LDPE
There was no increment in mechanical characteristics but significant increment in moisture resistance properties.

Banana fiber Polypropylene
Improved homogeneous dispersion, interfacial adhesion, water resistance, and thermal stability compared to the untreated and alkaline-treated ones. [45]

Biopolymers as Matrix
Biopolymers are biodegradable and eco-friendly.Biopolymers are derived from agricultural resources, by-products, chemical processing, and microbiological actions [21].They may also be created by blending two biopolymers.The structure and origin of the polymer and the degradation conditions determine the polymer's biodegradability [86].Microbes attack the polymer during degradation and decompose it into small molecules, along with the emission of CO 2 [87].Biopolymers alone have weak mechanical characteristics; however, the addition of natural fibers improves their mechanical performance [88].Traditional polymers, such as polypropylene, polyester, polyethylene, and epoxy, have been around for a long time and have gone through the various stages of the research and commercialization process [89][90][91].A significant amount of time and resources has been poured into the development of these polymers, and this has resulted in their superior mechanical performance.Nevertheless, the problem of recycling and the underlying environmental concerns about their usage have moved the interest towards biopolymers [92].Out of 7 billion metric tonnes of plastics generated, more than three-fourths end up in landfills [93].PLA [94][95][96][97][98][99][100][101][102][103], PBS [104-107], PCL [108], and PHA [109,110] are some of the widely used biopolymer matrices.The intriguing features of these materials are succinctly elucidated in the following subsections.

PHA
PHA is a renewable, eco-friendly polymer produced from fatty acids, sugar, sucrose, molasses, starch, wheat, methane, and corn [93].Sucrose and glucose are used for the commercial production of PHA [93,111].The biodegradability of PHA depends upon its surroundings, water content, crystallinity, chemical composition, pH level, and surface area [93].Hong et al. developed novel heart valves for replacing diseased natural valves using PHA [112].The use of PHA can also be seen in drug delivery and packaging [113].Nevertheless, poor physical and mechanical characteristics and the relatively higher cost of production (7-10 EUR/kg) limits the introduction of PHA into the broader market [113,114].

PBS
PBS is biodegradable and produced from 1,4 butanediol and succinic acid with outstanding thermal (melting temperature of 115 • C) and mechanical performance (Young's modulus of 500 MPa and tensile yield strength of 35 MPa) [93].Blending PBS with other biopolymers, such as PLA, starch, and carbohydrates, can improve its mechanical performance.PBS is used to manufacture bottles, packages, shopping bags, etc [115].

PLA
Poly (lactic acid) or polylactide (PLA) is one of the widely used biopolymers presently.It is an aliphatic polyester (thermoplastic), which is obtained from lactic acid that is found abundantly in renewable resources, such as wheat, corn, cassava, sugar cane, and barley [116].The significant properties of PLA from a commercial perspective include its good mechanical properties (Young's modulus 5-10 GPa and flexural strength of up to 140 MPa) [117] and its manufacturing from renewable raw materials [118].PLA production has several advantages compared to other biopolymers.PLA production consumes CO 2 [119].It is compostable, recyclable, and bio-degradable [120,121].Its thermal processability is better when compared to PHA, PEG, and PCL.PLA can be produced using 25-55% less energy than that of conventional polymers [122].The tensile strength and elastic modulus of PLA and PET are comparable [123].Despite these benefits, PLA has poor toughness; it is extremely brittle [93].In addition, the degradation rate of PLA is slow [124].PLA is preferred in biomedical applications because of its biocompatibility.The degradation of PLA does not produce toxic by-products and does not interfere in the healing of tissues [122].Table 5 compares the mechanical properties of biopolymers such as PLA and PBS to that of synthetic polymers.

Bio-Epoxy Resins
Several bio-epoxy resins can be obtained from natural sources such as epoxidized vegetable oils (including soya oil and pine oil residues) or residues from other industrial processes, such as cellulose and biofuel production [127].Sorbitol derived from corn starch and glycerine derived from triglyceride vegetable oil are two common and crucial bioepoxies.Glycerol-derived epoxy resins, such as polyglycidyl ethers of polyglycerol and glycerol, are inexpensive, commercially available, and utilized in the paper and textile industries.Takada and colleagues explored the utilization of glycerine-epoxy bioresins to make composite materials and stated that glycerine-epoxy resins, because of their high thermal properties and mechanical performance, could be a potential replacement for fossil-based epoxy resins [128].Shibata's co-workers shared a similar standpoint when experimenting with glycerol and polyglycidyl ether of sorbitol polymerized with a tanninbased agent that had relatively good and balanced thermomechanical characteristics [129].Epoxy resins derived from vegetable oils are another broad category, and the most common ones used today are epoxidized linseed oils and soy vegetable oils.Miyawaga et al. [130] prepared biobased soybean oil nanocomposites and carbon fiber-reinforced organic clay and tested their thermal and mechanical performance.Their efforts have resulted in new and advanced materials with high modulus and strength properties.Ahmetli et al. [131] used sunflower residue fatty acids to alter a commercial synthetic epoxy resin.All the modifications improved the mechanical performance with greater strength and elongation, while the resin hardness was also considerably improved [131].Some other biobased resins are polyfurfuryl bioresin [132], hemp oil-based bioresin [133], furfuryl alcohol [134], epoxidized soybean oil [135], castor oil derivatives [136], and epoxidized hemp oil [137].Despite the advantages, biopolymers have some disadvantages, such as thermal instability, flammability, and low production volume, which in turn increases the processing costs.Microbial attacks can cause damage to biopolymers [138].So, depending on the uses, various antibacterial and antifungal components are required.Moisture uptake is high in starch-based biopolymers [139].Future significant areas of research for matrix materials include the design and creation of novel biopolymers that are thermally stable and have a lower processing temperature and are recyclable and stable while in storage, transportation, and service life and demonstrate good mechanical performance.New uses will emerge as these materials become resistant to moisture, more dimensionally stable, robust, and fire-resistant.The field of nanotechnology provides a good platform on which to develop the novel biocomposites possessing the aforementioned properties.Figure 3 shows the chemical structure of commonly used biopolymers.

Compatibilization of Biocomposites
Despite the fact that the combination of various polymers creates a product with superior properties to those of either of the parent polymers, most polymer pairs are thermodynamically immiscible [140].So, the interactions between phases are weak, resulting in poor mechanical performance [141,142].Hence, there is an increasing interest in the compatibilization of polymers in academic research and industry.

Non-Reactive Compatibilization
One of the compatibilization techniques is the adding of the third component in the polymer blends.This technique falls under the non-reactive compatibilization.Most of the additives are graft or block copolymer.The compatibility is improved via noncovalent reactions [143,144].Theoretically, it is suggested that the compatibilizer's effectiveness rises with its molecular weight [145].Compatibilization by addition affects the interfacial characteristics as well as the flow behaviour, which in turn affects the processing and performance [145].The various non-reactive compatibilizers reported in the literature are PE-PLA di-block copolymers (PE-b-PLLA) [146,147], maleic anhydride grafted PE (MAPE) [148][149][150], ethylene-glycidyl methacrylate copolymer (EGMA) [151,152], and ethylene-methyl acrylate-glycidyl methacrylate (EMA-GMA) terpolymer [152,153].MAPE and MAPP are commonly used compatibilizers for producing natural fiber-reinforced biocomposites [48].At temperatures higher than 170 °C, maleated polymer reacts with natural fibers via esterification.As a result, the long polymer chains are in a covalent bond with the natural fibers [154].This increases the interfacial adhesion between the matrix and the fibers.Therefore, various studies have reported that the addition of maleated polymer significantly enhances the characteristics of the biocomposites [48,65,66,155].

Compatibilization of Biocomposites
Despite the fact that the combination of various polymers creates a product with superior properties to those of either of the parent polymers, most polymer pairs are thermodynamically immiscible [140].So, the interactions between phases are weak, resulting in poor mechanical performance [141,142].Hence, there is an increasing interest in the compatibilization of polymers in academic research and industry.

Non-Reactive Compatibilization
One of the compatibilization techniques is the adding of the third component in the polymer blends.This technique falls under the non-reactive compatibilization.Most of the additives are graft or block copolymer.The compatibility is improved via non-covalent reactions [143,144].Theoretically, it is suggested that the compatibilizer's effectiveness rises with its molecular weight [145].Compatibilization by addition affects the interfacial characteristics as well as the flow behaviour, which in turn affects the processing and performance [145].The various non-reactive compatibilizers reported in the literature are PE-PLA di-block copolymers (PE-b-PLLA) [146,147], maleic anhydride grafted PE (MAPE) [148][149][150], ethylene-glycidyl methacrylate copolymer (EGMA) [151,152], and ethylene-methyl acrylate-glycidyl methacrylate (EMA-GMA) terpolymer [152,153].MAPE and MAPP are commonly used compatibilizers for producing natural fiber-reinforced biocomposites [48].At temperatures higher than 170 • C, maleated polymer reacts with natural fibers via esterification.As a result, the long polymer chains are in a covalent bond with the natural fibers [154].This increases the interfacial adhesion between the matrix and the fibers.Therefore, various studies have reported that the addition of maleated polymer significantly enhances the characteristics of the biocomposites [48,65,66,155].

Reactive Compatibilization
Another technique is reactive compatibilization.It is presently the dominant technique of compatibilization.In this strategy, the graft or block copolymers are formed in situ at the interface because of the specific chemical reaction between the polymers [156,157].
In this method, the copolymers are formed at the region where they should remain.As a result, the interfacial tension between the polymers is reduced; the coalescence of the particles is suppressed; and eventually, the interfacial adhesion is improved [142,158].This method is employed in the extruder during compounding.Functionalized compatibilizers which possess isocyanate, maleic anhydride, oxazoline, and epoxide as reactive groups are utilized in this method.The compatibilizers are fed into the extruder along with polymers at the same time.Moreover, an appropriate initiator, generally the peroxide with a low decomposition temperature (dicumyl peroxide) is introduced.The rapid decomposition of DCP takes place.The free radicals are formed along the polymers.The reaction between these active points and the compatibilizers takes place.Hence, the compatibilization occurs in the extruder via reaction.The product formed has a complicated structure with grafted polymers and compatibilizers at the interface.As a result, there is a reduction in the interfacial tension and the increment of the interfacial adhesion.There is a substantial reduction in the gap between the two incompatible polymers.There is an interplay between the polymers, and the transmission of the load is permitted from the dispersion to the matrix phase, which improves the overall characteristics [159].Using DCP as the initiator, the improvement in the interaction between PLA/PBS [160], PHB/PCL [161], and thermoplastic dry starch (DTPS)/PLA with maleic anhydride as the compatibilizer has been reported in the literature.Ferri et al. conducted a study on the impact of various compatibilizers, such as polyethylene vinyl acetate, polyvinyl alcohol, and DCP on a PLA/bio-polyethylene blend [162].The writers report the increment in ductile properties in the compatibilized blend.The highest impact energy and highest elongation at the break was observed when polyethylene vinyl acetate was used as the compatibilizer [162].
Naturally occurring lignin acts as a promising compatibilizer between hydrophobic matrices and hydrophilic fibers.Lignin, which is the second most prevalent renewable bio-resource after cellulose, is regarded as a waste product in a variety of industrial processes.Many studies and reviews have documented attempts to valorise lignin in recent years [163][164][165].Lignin has many advantages, including many functional groups, strong biocompatibility, high carbon content, and low toxicity, which can be converted into carbon materials and composites.Lignin-based materials are often low in cost and eco-friendly.The compatibility of hemp [166] and flax fibers [167] with thermoset matrices has been improved by treating the fibers with lignin, thereby increasing the mechanical characteristics of the resulting biocomposites.According to Graupner, the tensile characteristics of compression-molded PLA-cotton composites were improved when the fibers were treated with lignin [168].Kraft lignin as a compatibilizer was used in the preparation of jute fiber-reinforced polypropylene composites by Acha et al. [169].The writers report that the thermal degradation temperature increased by around 8 • C in the polypropylene-lignin blend (5% lignin) compared to the neat polypropylene.However, the study shows that there was improvement in the impact characteristics only [169].An investigation introducing kraft lignin to hemp-reinforced epoxy composites was conducted by Wood et al. [170].The authors noticed increment in the impact strength with increment in the lignin content.The study further reports that the tensile and flexural modulus also increased up to a 2.5 wt.% addition of lignin.This study showed an increase in the structural properties of the composites to a certain extent compared to the composites without lignin [170].Luo et al. conducted a study to study the effect of kraft lignin obtained from pulping waste on poplar wood flour-reinforced polypropylene composite [171].The study shows that the water absorption property was reduced, and the composites were more thermally stable compared to the composites without lignin.Moreover, the authors found that the impact strength, flexural strength, and tensile modulus increased when a small amount of lignin (0.5 wt.% and 1 wt.%) was added, although at higher a lignin content there was no change or even a decrease in properties was observed.This study suggested that the industrial lignin acts as a potential additive in wood flour-reinforced polypropylene composite [171].

Moieties in Polymer Compatibilization-Environmental Impact and Applications
To a certain extent, when compared with plastic-based materials, it is widely agreed that biocomposites are safer for people and other living things owing to their unique and appealing attributes.Flax, hemp, jute, etc., which are common sources of lignocellulosic fibers, have been reported in a plethora of reports owing to their compatibility with biodegradable hydrophobic polymers, such as PLA and PBAT, to form biocomposites [172].The findings of several scholars have documented the enormous benefits of the use of biodegradable hydrophobic polymers with natural fibers [173,174], whereas the manufacturing of biocomposites from recycled polypropylene (PP) matrix has shown the possibility of several phenolic compounds, as well as oxidized chemicals, such as alcohols, aldehydes, ketones, and carboxylic acids [175,176].The significance of this is that the uncontrolled consumption of manufactured composite materials incorporated with non-biodegradable moieties may cause adverse environmental impacts.It is worth mentioning that the chemicals produced by the breakdown of lignocellulosic fibers, such as carboxylic acids, alcohols, and esters, appear to be more prevalent than other components in the materials as they age.Depending on the type of polymer components and their environmental conditions, polymer blends experience diverse types of deterioration (e.g., photodegradation, oxidation, erosion, and hydrolysis) throughout processing, storage, use, and disposal.Even though the exact implications of the polymeric compatibilization of functional moieties on the environment are relatively known, these products have gained popularity and have been discovered to be important in practically every element of human life.In this regard, and as previously captured in this review, the need for fossil fuels and the problems with plastic waste's sustainability have prompted continued research developments in the field of more environmentally benign materials of natural origin.Utilizing some natural materials, such as vegetable oils, waste-derived liquids, and essential oils, profoundly creates new possibilities of reactive compatibilizers, active additives, or even natural plasticizers for the development of new polymer formulations with improved sustainability characteristics [177].Numerous studies have dwelled more on the mechanical performance and end use of the functional moieties than the environmental impacts.For instance, Weng and colleagues studied the interactive effect of block copolymer (BC) and ionic liquid (IL) as a functional moiety on PLA/PCL blends.The authors observed that BCIL copolymer strengthened the contacts between the two polymeric phases and that the particle size of PCL reduces owing to the interfacial reinforced compatibility of IL moiety.In addition, it was discovered that the dialkoxybenzene/dihydroxybenzene moieties either improved the polymers' already-existing features or merely introduced new ones.The dihydroxybenzene moiety guaranteed the polymer's metallic adsorption, redox activity, adhesion-promoting, and lacquer-coating abilities, whereas the dialkoxybenzene moiety increased the electrical conductivity and electroluminescence of the poly(para-phenylene)s (PPPs) and poly(phenylenevinylenes) (PPVs) and their associated properties.Cazin and co-workers [178] indicated that novel applications such as 4D printing, soft robotics, medication delivery systems, bioimaging, and tissue engineering are potential areas where functional moieties such as coumarin could play a significant role in the future owing to their electro-optical properties (e.g., absorbance and fluorescence).Despite these appealing outcomes of the research, it is still imperative to provide up-to-date information on the associated environmental impacts of functional moieties in biocomposites.
One of the most widely reported functional moieties with an excellent flexibility and tensile strength in polymer compatibilization is epoxy [179,180].It has strong mechanical properties, good heat resistance and abrasion, and adheres well to a variety of substrates.Being distinguished by a combination of these beneficial and outstanding properties, epoxy resins are often used in a vast array of different applications as structural adhesives.This suggests an increase in the demand for epoxy in the upcoming years.Currently, photosensitive (e.g., cinnamate, chalcone, stilbene, maleimide, and anthracene), ionic liquids, and coumarin moieties have been documented in the literature.Suresh and colleague opined that most photo-sensitive moieties easily go through photo-crosslinking upon irradiation [181].Ishiguro and colleagues' [182] report also provided insight into the photosensitivity and birefringence properties of amorphous polymers containing azobenzene and tolane moieties.In their findings, the scholars observed the degradation effects of the moieties.Degradation is an externally induced irreversible change in the physical characteristics of the compatibilized biocomposites, brought on by chemical reactions in the main or side-chain macromolecules [183,184].Chemical, thermal, mechanical, biological, and radiation-related degradation processes have been reported by numerous scholars.While chemical degradation is essentially promoted by chemical agents such as oxygen, water, acids, or bases, specifically oxidation and hydrolysis [176], thermal and mechanical degradation processes are caused by heat application and the influence of external stress (including UV light and electromagnetic exposure), respectively [185,186].On the other hand, biological agents such as fungi or bacteria act on decomposed biocomposites, leading to a disintegration of the polymer matrix, resulting in the creation of fragmented particles of varied sizes and leached additives.Nonetheless, some chemical industries have taken advantage of the leached additives and have used them in the manufacture of chemicals [187].Leached additives, however, may be wrongly considered as food for mammals such as birds and could potentially threaten their existence in the ecosystem [188].As observed by Lambert and Wagner [189], lower molecular weight additives travel more readily through a polymer matrix that exhibits a higher pore size; the rate at which additives are leached depends on the pore diameter of a certain polymer structure and the additives utilized.Hammer and co-workers [190] also stressed that the occurrence of plastic-based materials and their associated chemical additives in the aquatic environment is an emerging worldwide problem, and their impacts are now gaining a wider scientific and social audience.Plastic-based composite materials contaminate the environment through the ocean and/or land routes with human activities being the major carrier.In parallel to this, some degradable biocomposites incorporated with functional moieties take a number of years to completely degrade, and it is often found that users of these materials discard them into the ocean.However, this menace is increasingly being curbed through legislation and the enforcement of laws.However, the huge volume of uncontrollable environmental factors, such as wind or the subsequent runoff of rainfall, still compromises the waste reduction efforts [189].Likewise, a wide range of volatile and other low molecular weight compounds from polymerization residues may have been retained from synthesis, the incorporation of additives which further contaminates biobased composites during degradation.This leads to the emission of toxic substances with foul odors under high processing temperatures.As such, this drawback may not be beneficial to the textiles and construction industries.
Numerous research studies on the degradation of biocomposites have been carried out by researchers.According to John's report, most natural fibers are highly susceptible to moisture absorption in humid and wet conditions because of the interaction of water and hydroxyl groups inherent in cellulosic and hemicellulosic materials, which are significantly influenced by the hydrophilic nature of the fibers [191].Azwa and colleagues' [192] research demonstrated that natural fibers can absorb up to 22% of the water when exposed for an extended period of time, but this drastically reduced to 1.5% of the water after a week and 0.7% to 2% after 24 h when studied for several months.The mechanical properties of flax fiber-reinforced biocomposites were reduced by degradation under temperature (−40 • C to 140 • C) and humidity (25% to 85%) conditions [193].Some scholars also opined that different sources of water could potentially affect the degradation rate of biocomposites such as kenaf/PLA [194] and flax/PLA [195].The use of injection-molded flax/PLA biocomposites immersed in seawater for two years at temperatures ranging from −8 • C to 19 • C revealed biological development on the biocomposites' samples and a plateau value of 3.3% after two months.In the research work of Harmaen and co-workers [196], oil palm empty fruit bunch (EFB) fiber-containing PLA composites were mixed with a slow-releasing fertilizer, and degradation tests were carried out via soil burial experiments at a temperature and relative humidity of 30 • C and 80%, respectively.The scholars observed that the natural fiber bundles were evident on the surface of the composite samples, signifying the presence of shrinkage and roughness.Further analysis using a scanning electron micrograph (SEM) showed the presence of cracks and holes caused by the decomposition of the oil palm fibers.It was discovered that the samples with fibers and fertilizer degraded at a slower rate than neat PLA.Kumar et al. [197] studied how various additives affected the biodegradation of polylactic acid composites reinforced with flax fiber.In the scholars' methodology, soil burial tests on the samples were performed over an extended period of time.Their findings revealed that mandelic acid, which was employed as a compatibilizer, accelerated biodegradation, whereas dicumyl peroxide, which was intended to slow it down, had the opposite effect, and they attributed this observation to mandelic acid's amphiphilic properties.The authors further revealed that flax composites with nonwoven flax biodegraded more quickly than samples with woven flax.
The degradability of biocomposites is significantly influenced by several environmental conditions, including moisture, temperature, and humidity.Biocomposites' shortand long-term reactions to these environmental conditions can restrict their usability [191] because the chemical characteristics of the biocomposites themselves also play a considerable role in the degrading process.The assessment of the life cycle analysis (LCA) of biocomposites may be necessary to expand their application and overall sustainability.A unique advantage of LCA is that it could be used for evaluating products using the circular economy models by figuring out their shortcomings and their impact on variables such as climate change, water use, acidification, and global warming to build methods for continual improvement [198,199].According to Ita-Nagy and colleagues [200], the LCA of sugarcane-reinforced biocomposites outperformed 100% sugarcane bioPU and fossil-based PE when parameters such as global warming, ozone generation, terrestrial acidification, and the scarcity of fossil fuels were considered.The researchers came to a conclusion which was opposite to the findings of some scholars, noting that while the environmental impact of the original materials was lessened using bagasse fiber reinforcements, more property enhancement is required to make it more useful as a replacement for fossil-based PE.Similarly, De Vegt and Haije [201] in their study indicated that flax fiber-based biocomposites had better LCA points (1.85) compared to carbon and glass fiber composites.Schmehl and co-workers [202] adopted three crucial factors-human health, ecosystem quality, and resource availability-in the LCA of polycarbonate acid anhydride and hemp and glass fibers composites.Their findings revealed that the LCA value of the hemp fiber composite, 0.36, was 50% lower than that of the glass fiber composite (0.74).
In summary, a panacea to the recycling of useful materials with a promising value into the environment requires an adequate understanding of the structural and functional stability during processing and use, along with an appropriate waste management technique when discarded.In addition to the existing body of knowledge, studies should focus on the degradability characteristics of biobased composites when composting and designing a suitable waste management method.This is because the analysis of degradation processes in biocomposites is even more important than in conventional composites due to the environmental susceptibility of their components to many physical and chemical reactions.

Hand Layup
This process involves spreading over a mold after the fibers have been trimmed.A vacuum bag is then wrapped around the part to prevent air from escaping and to make the assembly more secure.Thermosetting polymer-based biocomposites lend themselves well to the hand-layup approach.Compared to other composite processing processes, the capital investment is smaller, but the rate of production is lower.A high reinforcement volume fraction is challenging to attain in the final composites.The hand-layup technique is widely used with thermoplastic polymers such as polyester/epoxy/MDI(diphenylmethane diisocyanate) [203][204][205].The hand-layup technique is often used in integration with other techniques such as compression molding [206] and 3D printing [94].Milenkovic et al. [94] integrated the hand-layup method with 3D printing.The PLA was 3D printed while adding long continuous polyvinylidenfluorid (PVDF) fibers by hand to produce reinforced PLA composites.The authors reported the improvement in ductility [94].Laying fibers by hand might lead to imperfections between layers.A simple hand-layup process is shown in Figure 4.
well to the hand-layup approach.Compared to other composite processing processes, the capital investment is smaller, but the rate of production is lower.A high reinforcement volume fraction is challenging to attain in the final composites.The hand-layup technique is widely used with thermoplastic polymers such as polyester/epoxy/MDI(diphenylmethane diisocyanate) [203][204][205].The hand-layup technique is often used in integration with other techniques such as compression molding [206] and 3D printing [94].Milenkovic et al. [94] integrated the hand-layup method with 3D printing.The PLA was 3D printed while adding long continuous polyvinylidenfluorid (PVDF) fibers by hand to produce reinforced PLA composites.The authors reported the improvement in ductility [94].Laying fibers by hand might lead to imperfections between layers.A simple hand-layup process is shown in Figure 4.

Resin Transfer Molding
Resin transfer molding is used to produce components with a smooth surface finish at low pressure.The fibers are initially spread out by hand in the mold and then the resin is poured into it.Then, the mold is heated and cured under pressure.Thermoset resins are preferred; however, thermoplastic resins with a low viscosity are also being used [208].Vacuum-assisted RTM is a variation of the RTM technique which uses a vacuum to fill the mold with resin.VARTM is preferred for manufacturing synthetic fiberreinforced composites on a large scale.The technique delivers a safer, cleaner, and more cost-effective way of manufacturing composites.Void and bubble formation and impurities are reduced, producing a homogeneous product with superior mechanical charac-

Resin Transfer Molding
Resin transfer molding is used to produce components with a smooth surface finish at low pressure.The fibers are initially spread out by hand in the mold and then the resin is poured into it.Then, the mold is heated and cured under pressure.Thermoset resins are preferred; however, thermoplastic resins with a low viscosity are also being used [208].Vacuum-assisted RTM is a variation of the RTM technique which uses a vacuum to fill the mold with resin.VARTM is preferred for manufacturing synthetic fiber-reinforced composites on a large scale.The technique delivers a safer, cleaner, and more cost-effective way of manufacturing composites.Void and bubble formation and impurities are reduced, producing a homogeneous product with superior mechanical characteristics [209].Sun et al. [210] used CRTM techniques (integration of compression molding and RTM) to produce composites that demonstrated superior mechanical characteristics to that of the RTM-prepared composites.The CRTM process has considerable mass production potential and might be utilized to mold structural components of vehicles [210].A schematic representation of an RTM is shown in Figure 5.
teristics [209].Sun et al. [210] used CRTM techniques (integration of compression molding and RTM) to produce composites that demonstrated superior mechanical characteristics to that of the RTM-prepared composites.The CRTM process has considerable mass production potential and might be utilized to mold structural components of vehicles [210].A schematic representation of an RTM is shown in Figure 5.The complete impregnation of the dry fibers is required; so, the resins with low viscosity as well as a wide injection temperature range are preferred for this method [212,213].Epoxy resins, esters, and polyurethane are commonly used resins [68,208,209,[214][215][216][217][218].Composites with an excellent surface quality and dimensional stability can be obtained by this method [210,212].Different ways to cure the resin are being investigated.Shimamoto et al. [219] investigated the effect of microwave radiation on the resin curing time and reported that the resin curing time was reduced by 15 times.Moreover, the composites demonstrated superior mechanical characteristics [219].Despite many advantages, there are some limitations to this technique.Accidental fires may occur while handling highly flammable epoxy resins during resin transfer molding.Much research has been conducted to reduce the flammability of the epoxies, with significant advancements [220][221][222][223]. Zhang et al. [223] produced flame-retardant epoxy composites with a limiting oxygen index (LOI) greater than 30%.

Extrusion Process
Extrusion is a method of producing long items with a uniform cross-section.The polymer is forced through a die containing an opening in this technique.Through a hopper, pellets of polymer are inserted into an extruder.A feeding screw then propels the material ahead and forces it through a die, transforming it into continuous product.The polymer is softened and then melted by placing heating sources above the barrel.Thermocouples are used to regulate the material's temperature.An air or water bath is used to cool the final product exiting the die.Unlike metal extrusion, polymer extrusion The complete impregnation of the dry fibers is required; so, the resins with low viscosity as well as a wide injection temperature range are preferred for this method [212,213].Epoxy resins, esters, and polyurethane are commonly used resins [68,208,209,[214][215][216][217][218].
Composites with an excellent surface quality and dimensional stability can be obtained by this method [210,212].Different ways to cure the resin are being investigated.Shimamoto et al. [219] investigated the effect of microwave radiation on the resin curing time and reported that the resin curing time was reduced by 15 times.Moreover, the composites demonstrated superior mechanical characteristics [219].Despite many advantages, there are some limitations to this technique.Accidental fires may occur while handling highly flammable epoxy resins during resin transfer molding.Much research has been conducted to reduce the flammability of the epoxies, with significant advancements [220][221][222][223]. Zhang et al. [223] produced flame-retardant epoxy composites with a limiting oxygen index (LOI) greater than 30%.

Extrusion Process
Extrusion is a method of producing long items with a uniform cross-section.The polymer is forced through a die containing an opening in this technique.Through a hopper, pellets of polymer are inserted into an extruder.A feeding screw then propels the material ahead and forces it through a die, transforming it into continuous product.The polymer is softened and then melted by placing heating sources above the barrel.Thermocouples are used to regulate the material's temperature.An air or water bath is used to cool the final product exiting the die.Unlike metal extrusion, polymer extrusion is a continuous process that lasts until the raw pellets are provided [224].A schematic representation of this process is presented in Figure 6.
is a continuous process that lasts until the raw pellets are provided [224].A schematic representation of this process is presented in Figure 6.Depending on the product, single-or double-screw extruders are used.The single screw provides the limited mixing, whereas the twin screw provides the intense mixing of the melt.A twin-screw extruder disperses natural fibers evenly in the melt [93].The thermal and mechanical characteristics are highly influenced by the processing parameters of the extrusion [226].Despite the better aspect ratio being achieved at the high temperature and pressure, the natural fibers deteriorate, resulting in high porosity in the end product [227].Under the combined action of high temperature and shear loading during extrusion, the delignification of wood flour resulted in greater plastic deformation [18].Wood flour obtained after the delignification process has low melt viscosity because of the highly porous and flexible structure of holocellulose [18].The plasticity of the rigid cell wall can be enhanced by altering its composition, which might improve the processability of wood-plastic composites (WPCs) [18].Previous research has used extrusion to manufacture biocomposites [228][229][230][231][232][233].Gupta et al. [228] used hemp powder as a filler to reinforce reinforced polybutylene adipate-co-terephthalate (PBAT) for producing PBAT-HP biocomposite via extrusion.The authors reported the homogeneous dispersion of the hemp powder in the PBAT matrix and a significant improvement in the mechanical performance of the biocomposites [228].Vandi et al. [229] conducted a statistical analysis to study the impact of the processing conditions on the mechanical characteristics of the composites.The authors reported that although the thermal stability of polyhydroxyalkanoate (PHA) is relatively low, its processing can be conducted even at a temperature as high as 190 °C by adjusting the extrusion parameters, such as the feeding rate and the speed of the screw [229].Etxabide et al. [230] manufactured a fish gelatin biocomposite via the novel approach of combining the extrusion and injection molding techniques.Panariello et al. [231] studied the effect of biobased chain extenders (epoxidized soybean oil (ESO) and biobased dicarboxylic acid (DCA)) on the PLA/PBSA blend.The authors reported a fair increment in melt viscosity of the blend [231].Silva et al. [232] successfully produced polyvinylidene fluoride-hydroxyapatite composite filaments at various angular velocities-by twin screw extruder and found that the produced filaments were suitable for 3D printing.Hietala et al. [233] found that pelletizing cellulose fibers with the help of a lubricant is a potential method for compacting them.The authors reported the reduction in fiber breakage and the increased dispersion of the fibers with the addition of a lubricant.Introducing the lubricant directly to the cellulose fiber pellets increased the mechanical properties of the composite as compared to adding lubricant while melt compounding [233].Depending on the product, single-or double-screw extruders are used.The single screw provides the limited mixing, whereas the twin screw provides the intense mixing of the melt.A twin-screw extruder disperses natural fibers evenly in the melt [93].The thermal and mechanical characteristics are highly influenced by the processing parameters of the extrusion [226].Despite the better aspect ratio being achieved at the high temperature and pressure, the natural fibers deteriorate, resulting in high porosity in the end product [227].Under the combined action of high temperature and shear loading during extrusion, the delignification of wood flour resulted in greater plastic deformation [18].Wood flour obtained after the delignification process has low melt viscosity because of the highly porous and flexible structure of holocellulose [18].The plasticity of the rigid cell wall can be enhanced by altering its composition, which might improve the processability of wood-plastic composites (WPCs) [18].Previous research has used extrusion to manufacture biocomposites [228][229][230][231][232][233].Gupta et al. [228] used hemp powder as a filler to reinforce reinforced polybutylene adipate-co-terephthalate (PBAT) for producing PBAT-HP biocomposite via extrusion.The authors reported the homogeneous dispersion of the hemp powder in the PBAT matrix and a significant improvement in the mechanical performance of the biocomposites [228].Vandi et al. [229] conducted a statistical analysis to study the impact of the processing conditions on the mechanical characteristics of the composites.The authors reported that although the thermal stability of polyhydroxyalkanoate (PHA) is relatively low, its processing can be conducted even at a temperature as high as 190 • C by adjusting the extrusion parameters, such as the feeding rate and the speed of the screw [229].Etxabide et al. [230] manufactured a fish gelatin biocomposite via the novel approach of combining the extrusion and injection molding techniques.Panariello et al. [231] studied the effect of biobased chain extenders (epoxidized soybean oil (ESO) and biobased dicarboxylic acid (DCA)) on the PLA/PBSA blend.The authors reported a fair increment in melt viscosity of the blend [231].Silva et al. [232] successfully produced polyvinylidene fluoride-hydroxyapatite composite filaments at various angular velocities-by twin screw extruder and found that the produced filaments were suitable for 3D printing.Hietala et al. [233] found that pelletizing cellulose fibers with the help of a lubricant is a potential method for compacting them.The authors reported the reduction in fiber breakage and the increased dispersion of the fibers with the addition of a lubricant.Introducing the lubricant directly to the cellulose fiber pellets increased the mechanical properties of the composite as compared to adding lubricant while melt compounding [233].

Injection Molding
Injection molding is a popular technique for manufacturing complex-shaped plastic parts due to its high accuracy, low cost, and high productivity [234].This technique accounts for more than 30% of the plastic parts manufactured worldwide [235].Injection molding is used with polymers such as polycarbonate, polystyrene, polypropylene, polyamide, ABS, and polybutylene terephthalate (PBT) [236].The process may be divided into three different stages for a certain injection molding process: filling, post-filling, and cooling [237].Initially, a polymer melt at high pressure is injected into the mold so that the melt takes the shape of the desired mold.The part is then released from the mold after solidification and cooling.Complications arise in the filling stage as various phenomena, such as heat and mass transfer, are happening.The quick hardening of the polymer melt upon contact with the mold may cause issues such as incomplete filling of the mold at narrow areas [234].This issue can be resolved by heating the mold at higher temperature; however, doing so would lengthen the cooling cycle.Therefore, the optimization of the process is necessary.The fibers are oriented in the melt flow direction in injection molded samples, whereas a random orientation was observed in the extruded samples [18].Gigante et al. produced horticulture pots using paper sludge as a filler via injection molding [13].Considering that these major sources are from fiber components, it may be interesting for scholars to address injection molding technology on other biomass components, especially sources having less fiber content, such as starch and protein.A schematic representation of this process is presented in Figure 7.

Injection Molding
Injection molding is a popular technique for manufacturing complex-shaped plastic parts due to its high accuracy, low cost, and high productivity [234].This technique accounts for more than 30% of the plastic parts manufactured worldwide [235].Injection molding is used with polymers such as polycarbonate, polystyrene, polypropylene, polyamide, ABS, and polybutylene terephthalate (PBT) [236].The process may be divided into three different stages for a certain injection molding process: filling, post-filling, and cooling [237].Initially, a polymer melt at high pressure is injected into the mold so that the melt takes the shape of the desired mold.The part is then released from the mold after solidification and cooling.Complications arise in the filling stage as various phenomena, such as heat and mass transfer, are happening.The quick hardening of the polymer melt upon contact with the mold may cause issues such as incomplete filling of the mold at narrow areas [234].This issue can be resolved by heating the mold at higher temperature; however, doing so would lengthen the cooling cycle.Therefore, the optimization of the process is necessary.The fibers are oriented in the melt flow direction in injection molded samples, whereas a random orientation was observed in the extruded samples [18].Gigante et al. produced horticulture pots using paper sludge as a filler via injection molding [13].Considering that these major sources are from fiber components, it may be interesting for scholars to address injection molding technology on other biomass components, especially sources having less fiber content, such as starch and protein.A schematic representation of this process is presented in Figure 7.

Three-Dimensional (3D) Printing
In recent years, three-dimensional (3D) printing has advanced quickly.Through digitised and computer-assisted procedures, this technology enables the creation of oneof-a-kind, complicated, and customizable structures, thereby lowering manufacturing costs and time [238].Furthermore, when compared to typical processing manufacturing, this technology produces less waste and requires less chemical usage.Among 3D printing technologies, fused deposition modeling (FDM) is popular; this involves melting thermoplastic materials at high temperatures and then solidifying them after they cool.Many people have shown an interest in using biomass and biomass-based components in FDM 3D printing in recent years.Three-dimensional printing allows the feasible and economical manufacturing of composites [239].Complex structures along with good fiber percentage and orientation can be obtained easily [240].Recently, researchers have been attracted towards using natural fibers as composite fillers for 3D printing.However, the mechanical performance of the composites is low.This may be due to the improper fiber orientation, the presence of pores, the low aspect ratio of the fibers, the poor

Three-Dimensional (3D) Printing
In recent years, three-dimensional (3D) printing has advanced quickly.Through digitised and computer-assisted procedures, this technology enables the creation of one-ofa-kind, complicated, and customizable structures, thereby lowering manufacturing costs and time [238].Furthermore, when compared to typical processing manufacturing, this technology produces less waste and requires less chemical usage.Among 3D printing technologies, fused deposition modeling (FDM) is popular; this involves melting thermoplastic materials at high temperatures and then solidifying them after they cool.Many people have shown an interest in using biomass and biomass-based components in FDM 3D printing in recent years.Three-dimensional printing allows the feasible and economical manufacturing of composites [239].Complex structures along with good fiber percentage and orientation can be obtained easily [240].Recently, researchers have been attracted towards using natural fibers as composite fillers for 3D printing.However, the mechanical performance of the composites is low.This may be due to the improper fiber orientation, the presence of pores, the low aspect ratio of the fibers, the poor characteristics of the chosen fibers, and the lower fiber content in the printed structure [241][242][243].Various works have been reported in the literature to produce 3D printing filaments reinforced with flax fibers [244], hemp fibers [241,243,245,246], hemp hurds [247], bagasse fibers [248], coconut fibers [249], bamboo fibers [244,250], wood particles [242,251], cocoa shell [240,252], waste macadamia nutshell [253], and harakeke fibers [241,243,254].PLA and ABS are widely used filaments for FDM 3D printing [255,256].The 3D printing of these filaments requires that the nozzle and the printing bed be maintained at a high temperature of 200 • C for PLA and 220 • C for ABS [257,258].However, melting lignocellulosic components for extrusion and injection molding techniques is quite difficult, unlike petroleum-based thermoplastic compounds.As a result, developing novel biomass-based materials suited for 3D printing is a challenging task [259][260][261].The high resistance to flow and the high thermal transition temperature of pure lignin composites limit their production [238].As a result, lignin is combined with other polymers, enhancing its melting and flow.Kraft softwood lignin [262] and organosolv hardwood lignin [238] have recently been used to make FDM filaments based on PLA and acrylonitrile-butadiene-styrene polymers, respectively.There are some disadvantages associated with using natural fibers in 3D printing.The fibers need to be fully dried before processing otherwise voids and pores will be present in the printed part [263].Moreover, the natural fibers need to be sieved to very fine particles of less than 75 microns.Otherwise, agglomeration may occur and there will be clogging in the nozzle of the 3D printer [264].A schematic representation of this process is presented in Figure 8. [241][242][243].Various works have been reported in the literature to produce 3D printing filaments reinforced with flax fibers [244], hemp fibers [241,243,245,246], hemp hurds [247], bagasse fibers [248], coconut fibers [249], bamboo fibers [244,250], wood particles [242,251], cocoa shell [240,252], waste macadamia nutshell [253], and harakeke fibers [241,243,254].PLA and ABS are widely used filaments for FDM 3D printing [255,256].The 3D printing of these filaments requires that the nozzle and the printing bed be maintained at a high temperature of 200 °C for PLA and 220 °C for ABS [257,258].However, melting lignocellulosic components for extrusion and injection molding techniques is quite difficult, unlike petroleum-based thermoplastic compounds.As a result, developing novel biomass-based materials suited for 3D printing is a challenging task [259][260][261].The high resistance to flow and the high thermal transition temperature of pure lignin composites limit their production [238].As a result, lignin is combined with other polymers, enhancing its melting and flow.Kraft softwood lignin [262] and organosolv hardwood lignin [238] have recently been used to make FDM filaments based on PLA and acrylonitrile-butadiene-styrene polymers, respectively.There are some disadvantages associated with using natural fibers in 3D printing.The fibers need to be fully dried before processing otherwise voids and pores will be present in the printed part [263].Moreover, the natural fibers need to be sieved to very fine particles of less than 75 microns.Otherwise, agglomeration may occur and there will be clogging in the nozzle of the 3D printer [264].A schematic representation of this process is presented in Figure 8.

Compression Molding
Compression molding refers to the molding of the material through compression.The feed material is placed in a heated mold cavity in this method.Then, the mold is en-

Compression Molding
Compression molding refers to the molding of the material through compression.The feed material is placed in a heated mold cavity in this method.Then, the mold is enclosed within the upper and lower part of the die, and the pressure is applied to spread the material inside the mold.The material is allowed to cure while maintaining heat and pressure.A schematic representation of this process is presented in Figure 9. Low processing time and a high production rate make compression molding a reliable method.The fibers are generally placed within layers of matrix [93].There are several routes to compression molding techniques.However, the most popular one, which is very widely used in several manufacturing processes, is hot compression molding (HCM).HCM is typically used to manufacture thermoplastic polymer composites reinforced with long fibers.Hot presses are effective techniques for providing the required high pressure and temperature necessary the composite consolidation [266,267].However, the heating rate is limited (less than 5 • C/min) in the traditional hot presses that are equipped with heat cartridges.There might already be the degradation of natural fibers at the isothermal stage [268].High pressure, temperature, and processing time favor the matrix flow and the impregnation of fibers but may thermally degrade the natural fibers, resulting in the formation of macro pores [268].Several techniques have been investigated by scholars to preserve the integrity of the natural fibers, such as vacuum-assisted oven consolidation (VAOC) [269] and fast heating systems [268].Ramakrishnan et al. [268] used the fast inductive heating system and noted that the fibers had limited thermal degradation.
Zhao et al. [270] used a new approach combining paper manufacturing and compression molding techniques to produce biocomposites from waste paper and poly(butylene succinate).The product demonstrated excellent biodegradability and robust mechanical characteristics.
cessing time and a high production rate make compression molding a reliable method.The fibers are generally placed within layers of matrix [93].There are several routes to compression molding techniques.However, the most popular one, which is very widely used in several manufacturing processes, is hot compression molding (HCM).HCM is typically used to manufacture thermoplastic polymer composites reinforced with long fibers.Hot presses are effective techniques for providing the required high pressure and temperature necessary for the complete thermoplastic composite consolidation [266,267].However, the heating rate is limited (less than 5 °C/min) in the traditional hot presses that are equipped with heat cartridges.There might already be the degradation of natural fibers at the isothermal stage [268].High pressure, temperature, and processing time favor the matrix flow and the impregnation of fibers but may thermally degrade the natural fibers, resulting in the formation of macro pores [268].Several techniques have been investigated by scholars to preserve the integrity of the natural fibers, such as vacuum-assisted oven consolidation (VAOC) [269] and fast heating systems [268].Ramakrishnan et al. [268] used the fast inductive heating system and noted that the fibers had limited thermal degradation.
Zhao et al. [270] used a new approach combining paper manufacturing and compression molding techniques to produce biocomposites from waste paper and poly(butylene succinate).The product demonstrated excellent biodegradability and robust mechanical characteristics.The various processing techniques, components, and the characteristics of the biocomposites that have been reported in the literature are reviewed in Table 6.The various processing techniques, components, and the characteristics of the biocomposites that have been reported in the literature are reviewed in Table 6.Hybrid composites made with banana fibers showed increment in ultimate tensile stress and yield strength with increasing fiber content.The jute fiber-based hybrid composites showed a similar pattern in ultimate stress, whereas yield strength did not. [284]

Notable Applicable Areas of Biocomposites
Only a few biocomposites have been marketed while the majority are still in research and development phase.For the cheaper production cost of biocomposites, new production techniques and technologies are being developed.Although the natural fibers are abundant in developing nations, lack of technology and resources hinders them from being used to produce composites.On the other hand, developed nations in Asia and Europe are manufacturing biocomposites [285].There are various issues associated with biocomposites, such as low reliability, poor mechanical performance, and production costs, that need to be addressed for producing these biocomposites on a large scale [21].Despite these obstacles, biocomposites offer enormous promise for utilization in a variety of applications.Although research has yielded encouraging results, further research and development are necessary for the successful commercialization of biocomposites [286].The goal is to acquire characteristics equivalent to synthetic composites.Public awareness and new environmental policies will result in significant advancements in the production of biocomposites.Furthermore, progress in the field of agricultural engineering will aid in the harvesting of fibers with better qualities.Biocomposites have the potential to fully eliminate the need for synthetic products in the coming future [287].Synthetic composites require a lot of energy to make, but biocomposites use less [288].Various governments have encouraged the use of biodegradable materials to combat waste and pollution [289].The mechanical properties of plant fibers vary from to place, making it difficult for their proper utilization in biocomposites [290].Various chemical treatments and processes mitigate these flaws.The key fields where biocomposites are utilized the most are automotive, construction, and food packaging.

Automotive Industry
Composites reinforced with synthetic fibers such as carbon and glass fibers dominate the automotive industry.Growing environmental concerns and the carbon footprint have attracted the usage of biocomposites in this industry.Biobased composites can become promising alternative, sustainable, and eco-friendly materials in the automotive industry.They are light weight, which improves the fuel efficiency of the vehicles.It has been reported that by using biocomposites instead of synthetic fiber composites, the energy and weight can be saved up to 80% and 10%, respectively [93].The damping characteristics of biocomposites reduce vibrations and noise [291].Due to the comparatively poor mechanical characteristics and moisture resistance, the biocomposites are mostly used in the automotive components of the interior, such as dashboards, door panels, cabins, etc. [292].The automobile manufacturer Ford uses seats made out of soy foams, and biobased cushions, and the front grills are made out of hemp-based composites in its several models [293].There are currently around 8 million Ford vehicles with seats made from soy foam, reducing fossil fuel utilization by around 5 million pounds per year.Nylon 11-derived pure castor bean oil used in the fuel tank tubes of Ford vehicles resulted in a reduction of approximately 1 million pounds of CO 2 per year [291].The interior panels, shelves and trunk covers, and rear panel shelves in Mercedes Benz vehicles are made out of jute fiber composites, flax fiber composites, and sisal-based composites, respectively [294].Similarly, various automobile manufacturers use biocomposites in seats, tire covers, toolbox areas, package trays, door panels, door inserts, dashboards, etc. [93].Table 7 summarizes the applications of biocomposites in the automotive sector.

Construction Industry/Interior Decorations
Biocomposites are used to make windows, doors, window frames, ceilings, floor mats, and roof tiles in the building sector.Floor slabs, beams, pipes, and tanks are all examples of load-bearing applications [93].Wood-plastic composites (WPCs) are used in making tables, decks, benches, floorings, and landscape timbers.Similarly, biocomposites are also used in the repair and rehabilitation of a variety of structural components [306].Natural fiber composites are employed as insulating and soundproofing materials because of their superior thermal and acoustic qualities.Hemp/lime/concrete composites have outperformed all other binders in terms of sound absorption [307].The thermal characteristics of the concrete can be improved by adding hemp.However, hemp needs to be mineralized first for its use with cement [308].Novakova et al. [308] successfully used hemp hurds as filler in lightweight concrete.Dweib et al. [309] successfully fabricated unit beams and structural beams out of natural fibers and soybean oil-based resin and noted some promising results.Blok et al. [310] designed and manufactured a 14 m-long footbridge out of biocomposites.The study reported that all the required tests, such as creep tests, tensile tests, and moisture content tests, were passed by the bridge.However, before utilizing any biocomposites as a construction material, life cycle assessment, durability qualities, and environmental concerns are considered.Low weight and equivalent mechanical qualities with synthetic composites are critical for building purposes.In addition, many countries are using biocomposite materials to combat environmental challenges.Due to future demand, many companies are investing in biocomposites [307].

Biomedicine
Extending life expectancy requires the use of novel technologies.Various innovative procedures and new technologies have been developed in this direction, resulting in lower morbidity and mortality rates [311].Tissue engineering, an aspect of biomedicine is one of the key areas where biocomposites are profoundly used because of the exceptional qualities of biocomposites to modify mechanical characteristics, degradation kinetics, and bioactivity [312].Nonetheless, the characteristics of biomaterial polymers could be improved by adding mineral polymer fillers (HA) to the primary polymer PET, which has poor bioactivity when compared to other biobased composites such as PLA, PLGA, and PCL [313].Combining these two polymers creates a new nano-biocomposite scaffold with better capabilities, which is deemed unusual because it concentrates on skin application rather than the more common application on hard tissues [314].Recently, there have been advances in areas such as wound healing and drug delivery, which the use of biocomposites is highly desired in these areas.Drozdov and colleagues [315], in their efforts to create healing biocomposites, prepared four medicaments with different characteristics.The authors observed that the wound healing rate with a biocomposite was 1.5 times faster than the control group (21 and 14 days for complete healing, respectively).They further observed that the use of a magnetite-based biocomposite resulted in a significant reduction in scar size.Other scholars, such as Bagheri et al., documented the synergistic antibacterial effects of chitosan nanofiber for biocomposites, with an outstanding scratch repair potential of chitosan fiber and polyethylene oxide [316].The efforts of scholars should be tailored towards addressing the overall long-term effects of these materials on other functional body parts of humans.

Packaging
The growing global economy and population necessitates a more efficient management of Earth's natural resources.By 2027, the food packaging sector in the world is predicted to hit the market value of USD 456.6 billion [317].Unleashing the potential for innovation in the packaging and cosmetics industries will help to boost job creation and competitiveness.Starch-based plastics are renewable, biodegradable, and combustible, due to which they have piqued a lot of interest in industrial applications [318].Lescher et al. [318] have demonstrated unique manufacturing applications.Starch-derived foam has insulation properties like those of polystyrene foam, which is being produced commercially [319].Starch-based foams can be used as loose-fill packaging materials to fill empty spaces in packages, effectively substituting polystyrene foams [320].Loose-fill packing materials protect, stabilise, and cushion packed goods and must have low density, sufficient resilience, and compressibility [321].When stored in atmosphere with high relative humidity, TPS foams are prone to moisture.The hydrogen bonds in starch are attacked by water molecules.As a result, they are weakened, and their functional characteristics are reduced [318].The blends of TPS with hydrophobic polymers are being utilized as oxygen barriers at a commercial level [322].In multi-layered materials, incorporating water-free TPS with hydrophobic polymers is beneficial in protecting gas barrier layers and foamed cores from moisture [318].Blends containing higher amylose content starch appeared to be more dimensionally stable [318].The synthesis of polyhydroxyalkanaotes from agro-food by-products, as well as the synthesis of lactic acid co-polymers, are both viable options for creating sustainable polymeric matrices [323].Natural fibers, polysaccharides (starch, cellulose, chitin, chitosan), cutin, and protein-rich by-products can all be found in abundance in the agro-food business.The research has evidenced the impact of biocomposite film based on high methoxyl pectin reinforced with zeolite Y in prolonging the shelf life of fruits [324].Table 8 summarizes the application of biocomposites in food packaging.
Increasing fuel prices have led aircraft sectors in search of lightweight materials.Around half of the operational costs in aircraft are accounted for by fuel costs.Fiberreinforced polymer composites increase the fuel efficiency of Boeing 787 by more than 20% [334].Lightweight aircraft use less fuel, allowing them to carry heavier cargo and cover longer distances.The primary goals of the aviation industry are to reduce carbon dioxide emissions, costs, and fuel consumption; hence, the use of biocomposites is gaining popularity in the aerospace industry.Biocomposites can be used to make aircraft interior sections (such as seats, decks, and floor) and external body panels.To be used in aircraft structures, biocomposites must possess high moisture resistance, flame retardancy, and high specific strength [335].Biocomposites have low flame retardancy making them questionable for use in aircraft.The external structure of aircraft needs to be flame resistant but the interior structure, such as cabin, decks, seats, and floors, which are less prone to fire hazards, can be manufactured with biocomposites.Cabin interior panels were made from phenolic resin and woven flax [336].A 12-14% weight reduction in the wing box was observed when compared to the 7000 series aluminium alloy using ramie fiber-reinforced composite [337].Composite laminates made using goat hair and banana fibers might be employed in aeronautical applications [338].

Conclusions
Natural materials, particularly those derived from plant materials, have been used for hundreds of years.Researchers have discovered improved ways for these materials to fulfill both social and industrial needs.The use of nonbiodegradable materials creates and compounds environmental and ecological issues, prompting a rapid change to more environmentally benign materials.Biocomposites provide advantages owing to their exceptional attributes, such as biodegradability, availability of raw materials, and applications.Even though many industrial sectors have tapped into the benefits, the commercialization of manufactured biocomposite materials is still in its early stages.The influence of moieties has various downsides, including the likelihood of harmful chemical release.Nonetheless, as this research area is attracting the interests of many academic and industrial contributions, it indicates that the commercialization of biocomposites is projected to rise in the future as people become more environmentally conscious, manufacturing processes become more efficient, and new applications are discovered.Scholars must also contend with the obstacles of establishing norms and standards for these materials.It is important to emphasize that, because of the poor mechanical and thermal characteristics, replacing standard synthetic composites entirely with biocomposites would require a body of scientific evidence necessary to create the change.At present, research work involving multiple reinforcing fibers and polymer blends appears to be scarce, even though such materials may offer greater production and tailoring flexibility.Because of the possibilities for novel applications, this subject must be researched further.Biocomposites with excellent durability, performance, serviceability, and reliability must be produced to broaden their applications.As scientific breakthroughs and technologies advance, fresh areas of applications of natural fiber-reinforced composites will emerge, influencing the always-expanding market for biobased composites.

Figure 3 .
Figure 3.Chemical structure of commonly used biopolymers.

Figure 3 .
Figure 3.Chemical structure of commonly used biopolymers.

Figure 6 .
Figure 6.Schematic diagram of a polymer extrusion machine.The barrel and screw are the two major industrial components (redrawn from Ref. [225]).

Figure 6 .
Figure 6.Schematic diagram of a polymer extrusion machine.The barrel and screw are the two major industrial components (redrawn from Ref. [225]).

Table 2 .
Various chemical treatments and their effects.

Table 3 .
Effect of alkaline treatment.

Table 4 .
Effect of acetylation treatment.

Table 5 .
Comparison of mechanical properties of PLA and PBS with synthetic polymers.

Table 6 .
Processing of various composites.

Table 8 .
Biobased plastics for food packaging.