Mechanical Strength of Bamboo Filled PLA Composite Material in Fused Filament Fabrication

: Through the past two decades, there has been a continued push for renewable resources and future sustainability of materials and processes. This has prompted more developments of providing environmentally friendly practices and products, both in terms of higher recyclability and greater use of renewable resources. An important area of interest are materials for construction and manufacturing purposes, speciﬁcally “green” sustainable reinforcement materials for thermoplastic composite materials. During this time, there has also been an evolution in manufacturing methods. Additive manufacturing (AM) has continued to grow exponentially since its inception for its extensive beneﬁts. This study aims to investigate an additive manufactured composite material that is a greener alternative to other composites that are not reinforced by natural ﬁbers. A bamboo ﬁlled polylactic acid (PLA) composite manufactured by fused ﬁlament fabrication was evaluated in order to gather mechanical strength characteristics by means of tensile, ﬂexure, compression, impact, and shear tests. In this material, the bamboo reinforcing material and the PLA matrix material can both be sourced from highly renewable resources. In this study, a variety of test samples were manufactured at di ﬀ erent manufacturing parameters to be used for mechanical testing. The results were recorded with respect to varying manufacturing parameters (raster angle orientation). It was found that the 0 ◦ raster angle orientation performed the best in every category except tensile. Additively manufactured bamboo ﬁlled PLA was also seen to have comparable strength to certain traditionally manufactured bamboo ﬁber reinforced plastics.


Introduction
Growing demand for renewable resources and environmentally friendly practices have prompted research in many different areas [1][2][3]. One of which includes the mechanics (or strength) of materials. Plastics are especially notorious for negative environmental impact. Plastics are polymers, which consist of repeated monomers (simple molecules) that are covalently bonded to one another in a chain like structure. The benefits of such polymers are widely known and utilized, such as excellent strength to weight ratio as well as resistance to corrosion. In order to further increase the strength of the material while retaining the benefits of polymers, composite materials have been created to attempt to combine the advantageous properties of multiple materials while minimizing the disadvantages. One type of composite material incorporates continuous or chopped fibers of a strengthening material within a matrix polymer. Many polymer-matrix composites have been investigated and they have been widely used across many industrial applications. One of the most common is carbon fiber reinforced polymers (CFRP). However, with growing demand for sustainable and biodegradable materials, carbon fiber is not ideal, because much of it is manufactured using a petroleum-based product [4,5]. Additionally, it is manufactured using a variety of other costly materials and methods, making it not economical for many composite materials that were used in FFF. Makerbot Desktop slicing software (Makerbot Desktop, Makerbot, Brooklyn, NY, USA) [29] was used for G-code compilation. Depending on the mechanical test, the following raster orientation were evaluated: 0 • , 90 • , alternating 0 • /90 • , and alternating −45 • /45 • . The bamboo filled PLA filament was manufactured by eSUN and is sold under the material name EBamboo [30]. Table 1 presents all of the relevant build parameters for the specimens. Limited information pertaining to the bamboo filled PLA filament was available from the manufacturer. In order to gain a better understanding of the composition of the filament, the percentage of bamboo filler to PLA matrix was estimated by testing samples of the bamboo filament and recording volume measurements taken on Micromeritics AccuPyc II 1340 pycnometer (Micromeritics Instrument Corporation, Norcross, GA, USA). The mass of the samples was then recorded and used to calculate the density of the filament. This process was also completed with standard PLA filament available from eSUN, assumed to be the same as the EBamboo matrix material. An average density of 0.9 g/cm 3 was assumed for bamboo. The percentage of bamboo filler in the material was determined to be 11.8% using Equation (1).
FFF of the bamboo filled PLA composite produced satisfactory high-quality parts with limited defects and it was easily printed. It has a light brown color similar to bamboo with a woody-like texture and aroma, very similar to other wood-filled polymers available for FFF. Figure 1 displays magnified cross sectional views of the filament with the right side of the figure being powder size distribution measurements. Darker brown spots are the bamboo particles that are infused into the composite material. Through image processing, the bamboo could be isolated from the PLA matrix, and powder size measurements were taken. Assuming the measured areas to be circular, the powder sizes ranged from 5 µm to 35 µm in diameter. Figure 2 shows an average representation of print quality of Bamboo/PLA FFF printed parts. As can be seen, the parts printed well and were of high quality. Few defects were present and only in areas where the nozzle started/stopped. These problems can likely be reduced/removed by fine-tuning retraction settings and/or by using a Z-hop maneuver.

Mechanical Testing
Each specimen's cross-sectional area was measured at multiple locations along the test section prior to conducting testing, as per the American Society for Testing and Materials (ASTM) testing standard for each test type. These cross-sectional area measurements were then averaged and used to calculate stress/strain for each test. Tensile, flexural and shear tests were all conducted using an MTS Insight load frame with a 5 kN MTS load cell. Compression testing was completed on an MTS Landmark load frame with a 100 kN load cell.
For each type of mechanical test conducted, samples from a variety of raster angles were tested, similar to [32]. In all cases, raster angles of 0° are the printing orientation that aligns the toolpath in the lengthwise direction (strongest orientation). The orientation angle increases in the CCW direction that was measured from the specimen's longitudinal axis. The different raster angles employed in this study are shown in Figure 3, where the x-axes represent the specimen's longitudinal axis. One potential cause for concern was the degradation of bamboo during the AM process. The filament was extruded at a temperature of 230 • C in this study. Prior research has evaluated thermal degradation of bamboo reinforced epoxy composites through Thermogravimetric Analysis (TGA). It was found that degradation occurred at 250 • C independent upon filler percentage. Contrary, specifically, Bambusa vulgaris fibers showed low thermal stability and degradation occurring at 220 • C [31]. It should be noted that, during TGA, the temperature was increased at a rate of 10 • C/min. Being that the TGA process slowly heated the material (10 • C/min), it cannot be directly compared to the AM extrusion process where the filament is heated to 230 • C and then immediately starts cooling. However, we could expect very little bamboo degradation during the FFF process that was based on the previous research [31].

Mechanical Testing
Each specimen's cross-sectional area was measured at multiple locations along the test section prior to conducting testing, as per the American Society for Testing and Materials (ASTM) testing standard for each test type. These cross-sectional area measurements were then averaged and used to calculate stress/strain for each test. Tensile, flexural and shear tests were all conducted using an MTS Insight load frame with a 5 kN MTS load cell. Compression testing was completed on an MTS Landmark load frame with a 100 kN load cell.
For each type of mechanical test conducted, samples from a variety of raster angles were tested, similar to [32]. In all cases, raster angles of 0 • are the printing orientation that aligns the toolpath in the lengthwise direction (strongest orientation). The orientation angle increases in the CCW direction that was measured from the specimen's longitudinal axis. The different raster angles employed in this study are shown in Figure 3, where the x-axes represent the specimen's longitudinal axis.

Tensile
Tensile tests were conducted in accordance to ASTM D638 Standard Test Methods for Tensile Properties of Plastics [33]. Tensile tests were displacement controlled at a rate of 5 mm/min. while data (force, grip displacement, and strain) was collected at a rate of 100 Hz. Strain was measured using an MTS Model 634.31F-24 extensometer (MTS, Eden Prairie, MN, USA). Six specimens of each

Tensile
Tensile tests were conducted in accordance to ASTM D638 Standard Test Methods for Tensile Properties of Plastics [33]. Tensile tests were displacement controlled at a rate of 5 mm/min. while data (force, grip displacement, and strain) was collected at a rate of 100 Hz. Strain was measured using an MTS Model 634.31F-24 extensometer (MTS, Eden Prairie, MN, USA). Six specimens of each of the four raster orientations were tested. The dimensions of the tensile specimens follow Type IV in ASTM D638, which means cross sectional areas of approximately 6 mm × 4 mm.

Flexural
Flexural specimens were tested in accordance to ASTM D790 Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials [34]. Flexural tests were conducted using an MTS 3-point flexure fixture with a support span of 5 cm, while displacement controlled at a rate of 1.3 mm/min. Following the recommendations for specimen size in ASTM D790 leads to samples of cross-sectional area of 4 mm × 12.7 mm.

Compression
Compression tests were completed in accordance to ASTM D695 Standard Test Method for Compressive Properties of Rigid Plastics [35]. Two platens that were attached to each grip were used to apply the compressive load while the displacement of each specimen was measured with the built-in linear variable differential transformer (LVDT). The tests were displacement controlled at a rate of 1.3 mm/min. Specimens were round cylinders measuring approximately 12.75 mm in diameter and 50 mm in length. Due to the simplicity/symmetry of the geometry, the 0 • and 90 • as well as the 0 • /90 • and −45 • /45 • raster orientations were effectively the same. Therefore, six specimens of just two orientations (0 • and −45 • /45 • ) were tested (see Figure 4).

Impact
The impact tests were conducted in accordance to ASTM D256 Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics while using a calibrated custom build Izod Impact tester [36]. Figure 5 shows a picture of the Impact testing setup along with an example of impact specimens. Six specimens of 0°, 90°, and −45°/45° raster orientations were tested.

Impact
The impact tests were conducted in accordance to ASTM D256 Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics while using a calibrated custom build Izod Impact tester [36]. Figure 5 shows a picture of the Impact testing setup along with an example of impact specimens. Six specimens of 0 • , 90 • , and −45 • /45 • raster orientations were tested.

Impact
The impact tests were conducted in accordance to ASTM D256 Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics while using a calibrated custom build Izod Impact tester [36]. Figure 5 shows a picture of the Impact testing setup along with an example of impact specimens. Six specimens of 0°, 90°, and −45°/45° raster orientations were tested.

Shear
The shear tests were conducted in accordance to ASTM D5379-19 Standard Test Method for Shear Properties of Composite Materials by the V-Notched Beam Method using a v-notched beam test fixture as shown in Figure 6 [37]. Prior to testing, the specimens were prepped for digital image correlation (DIC) strain measurement by spray painting a fully white background and then black speckles were applied by spray paint can. The speckles would be tracked by DIC software. Three specimens of 0 • , 90 • , and −45 • /45 • raster orientations were tested. The shear tests were conducted in accordance to ASTM D5379-19 Standard Test Method for Shear Properties of Composite Materials by the V-Notched Beam Method using a v-notched beam test fixture as shown in Figure 6 [37]. Prior to testing, the specimens were prepped for digital image correlation (DIC) strain measurement by spray painting a fully white background and then black speckles were applied by spray paint can. The speckles would be tracked by DIC software. Three specimens of 0°, 90°, and −45°/45° raster orientations were tested. Strain data were collected while using a custom created DIC capture system. This system uses a LabView program that captures and image and a load cell measurement simultaneously. The pictures are captured using an Allied Vision Technologies Marlin F-046 camera (Allied Vision Technologies, Stadtroda, Thuringia, Germany). Pictures and corresponding load values are then converted into stress/strain values using GOM Correlate [38]. Strain data were collected while using a custom created DIC capture system. This system uses a LabView program that captures and image and a load cell measurement simultaneously. The pictures are captured using an Allied Vision Technologies Marlin F-046 camera (Allied Vision Technologies, Stadtroda, Thuringia, Germany). Pictures and corresponding load values are then converted into stress/strain values using GOM Correlate [38].

Tensile
The average tensile testing results with standard deviations are shown for each raster orientation in Table 2. Figure 7 shows representative stress-strain curves of each raster orientation.   Table 3 shows the average flexural testing results and standard deviations for each raster orientation. Figure 8 displays representative stress-strain curves from the flexural testing for each raster orientation.  All of the raster orientations resulted in comparable ultimate tensile strengths with variations between the four orientations. However, there was a notable difference seen in the ductility of the material, depending on raster orientation. The 0 • /90 • orientation was found to be the most ductile. Table 3 shows the average flexural testing results and standard deviations for each raster orientation. Figure 8 displays representative stress-strain curves from the flexural testing for each raster orientation.  The 90° orientation resulted in the lowest ultimate flexural strength as well as the least ductility. This result matches intuition. Because it should be expected that side by side bonding would be not as strong as continuous length of material extruded (as in the 0° direction). The 0° and −45°/45° orientation produced higher ultimate flexural strengths. Alternating orientation of 0°/90° had lower strength at the benefit of better ductility. Overall, the 0° orientation had the best fracture toughness by having comparable strength to the best results, while also being the most ductile. The 90 • orientation resulted in the lowest ultimate flexural strength as well as the least ductility. This result matches intuition. Because it should be expected that side by side bonding would be not as strong as continuous length of material extruded (as in the 0 • direction). The 0 • and −45 • /45 • orientation produced higher ultimate flexural strengths. Alternating orientation of 0 • /90 • had lower strength at the benefit of better ductility. Overall, the 0 • orientation had the best fracture toughness by having comparable strength to the best results, while also being the most ductile.

Compression
The average results and standard deviations from compression testing is shown in Table 4. No significant difference was seen in the compressive properties between the different orientations. Figure 9 illustrates the representative compressive stress-strain curves.

Compression
The average results and standard deviations from compression testing is shown in Table 4. No significant difference was seen in the compressive properties between the different orientations. Figure 9 illustrates the representative compressive stress-strain curves.

Impact
Izod impact tests were conducted in order to record the energy absorption of the material before fracturing in a fast impact fracture. Table 5 shows the average results and standard deviation for various raster orientations. Significant differences were seen between the varying orientations. The 0° orientation clearly performed the best with an impact energy absorption double the −45°/45° and triple the 90°.

Impact
Izod impact tests were conducted in order to record the energy absorption of the material before fracturing in a fast impact fracture. Table 5 shows the average results and standard deviation for various raster orientations. Significant differences were seen between the varying orientations. The 0 • orientation clearly performed the best with an impact energy absorption double the −45 • /45 • and triple the 90 • .

Shear
The ultimate shear strength and shear chord modulus of elasticity were recorded from shear tests. Table 6 shows the results. Figure 10 shows shear stress-strain curves. It can be noted that all of the shear tests show brittle behavior. The 0 • orientation had the highest ultimate shear strength (29 MPa) when compared to the other orientations, as expected. The −45 • /45 • orientations had the lowest ultimate shear strength at 25 MPa. Interestingly, the 0 • orientation also had the lowest shear modulus of elasticity.

Discussion
The composite material that was evaluated in this study used bamboo as a reinforcement material, not fibers, but a bamboo powder filler. Bamboo's sustainable natural reinforcement fibers provides an environmentally friendly option to compete with other composites. Specifically, bamboo infused PLA for AM is a topic that has limited data available.
From the results of the testing in this study, orientation had little effect on ultimate tensile strength with all orientations being within 3 MPa of each other. However, a more notable change in ductility was seen in different orientations. The 0° orientation was seen to be the least ductile at a maximum elongation of 2.428 ± 0.49%, while the 0°/90° orientation was the most ductile at 5.074 ± 1.23%. Flexural testing showed slight changes that were based on orientation. The 0° orientation was determined in order to perform the best under flexure, for it had nearly the highest ultimate flexure strength while also being the must ductile, providing the highest fracture toughness. Compression testing concluded that there were no notable differences in mechanical strength between orientations

Discussion
The composite material that was evaluated in this study used bamboo as a reinforcement material, not fibers, but a bamboo powder filler. Bamboo's sustainable natural reinforcement fibers provides an environmentally friendly option to compete with other composites. Specifically, bamboo infused PLA for AM is a topic that has limited data available.
From the results of the testing in this study, orientation had little effect on ultimate tensile strength with all orientations being within 3 MPa of each other. However, a more notable change in ductility was seen in different orientations. The 0 • orientation was seen to be the least ductile at a maximum elongation of 2.428 ± 0.49%, while the 0 • /90 • orientation was the most ductile at 5.074 ± 1.23%. Flexural testing showed slight changes that were based on orientation. The 0 • orientation was determined in order to perform the best under flexure, for it had nearly the highest ultimate flexure strength while also being the must ductile, providing the highest fracture toughness. Compression testing concluded that there were no notable differences in mechanical strength between orientations and similar results can be expected independent upon orientation. Impact testing found that nearly triple the amount of impact energy can be absorbed in the 0 • orientation when compared to the 90 • and double the amount of impact energy when compared to the −45 • /45 • . Shear testing found that the composite material was extremely brittle in shear and no notable differences were seen in the ultimate shear strength, while, again, the 0 • orientation still had a slight advantage over the other orientations.
When comparing the AM bamboo filled PLA to other bamboo fiber reinforced polymer composites made from tradition methods, it was found to have comparable if not better (assuming 11.8% bamboo filler as calculated in Equation (1)) tensile and flexural strength [25]. The AM of the material was also found to produce satisfactory parts of limited defects with relative ease. Reviewing neat PLA, the AM bamboo/PLA composite produced strength that was nearly half that of neat PLA in tensile and flexural testing [32]. However, the bamboo/PLA looked to be less mechanically susceptible to print orientations differences, which could be of use when used in applications of varying loading directions. Overall, the results of this study found that the AM of bamboo filled PLA composite is an effective means of producing an environmentally friendly, recyclable, and sustainable bamboo reinforced polymer-matrix composite.

Conclusions
Bamboo filled PLA composite material was AM using FFF. Four raster orientation angles (0 • , 90 • , 0 • /90 • , and −45 • /45 • ) were evaluated for anisotropic effects. Tensile, flexure, compression, impact, and shear tests were all conducted in order to provide mechanical strength characteristics. It was found that the raster orientation had the largest effect on ductility and impact energy absorption. The 0 • orientation was found to perform the best in all categories, except tensile testing, where it was found to have the least strength and ductility of the four orientations.
AM bamboo filled PLA was found to produce satisfactory parts with limited defects. The AM bamboo composites were also seen to have similar mechanical properties to certain bamboo fiber reinforced plastics, of which were traditionally manufactured and have nearly half the strength of neat PLA. Future work could include a mechanistic analysis of bamboo percentage affects. The material is also an environmentally friendly option when compared to other polymer-matrix composites due to the natural and sustainable reinforcement fibers that bamboo offers.