Characterization of Microstructural and Mechanical Properties of 17-4 PH Stainless Steel by Cold Rolled and Machining vs. DMLS Additive Manufacturing

: The 17-4 PH stainless steel is widely used in the aerospace, petrochemical, chemical, food, and general metallurgical industries. The present study was conducted to analyze the mechanical properties of two types of 17-4 PH stainless steel—commercial cold-rolled and direct metal laser sintering (DMLS) manufactured. This study employed linear and nonlinear tensile FEM simulations, combined with various materials characterization techniques such as tensile testing and nanoindentation. Moreover, microstructural analysis was performed using metallographic techniques, optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The results on the microstructure for 17-4 PH DMLS stainless steel reveal the layers of melting due to the laser process characterized by complex directional columnar structures parallel to the DMLS build direction. The mechanical properties obtained from the simple tension test decreased by 17% for the elastic modulus, 7.8% for the yield strength, and 7% for the ultimate strength for 17-4 PH DMLS compared with rolled 17-4 PH stainless steel. The FEM simulation using the experimental tension test data revealed that the 17-4 PH DMLS stainless steel experienced a decrease in the yield strength of ~8% and in the ultimate strength of ~11%. A reduction of the yield strength of the material was obtained as the grain size increased.


Introduction
The present research focuses on the precipitation-hardened martensitic stainless steel 17-4 PH, a material well known for its applications in aviation [1], automotive [2], medical [3], tooling [4], marine [5], nuclear, military, food, and petroleum sectors [6][7][8], due to its good resistance to high temperature, fracture, oxidation, and corrosion, the main objective being to find the differences in the mechanical and microstructural properties of this material manufactured via cold rolling and DMLS.
It is well known that the mechanical properties of the materials change depending on the method of its manufacture, such as conventional manufacturing processes (stamping, rolling, forging, etc.) or additive manufacturing processes, which is why some studies have been carried out regarding the differences in the mechanical properties of different materials under different manufacturing processes, finding differences in tensile strengths, Young's modulus, fatigue limits, ductility, etc. [9,10].For example, Luecke performed a study that demonstrated that the tensile mechanical properties of the 17-4 PH SS fabricated by selective laser melting are very different from those of wrought steel [11], the differences being in the microstructure, something crucial for the performance of the material.These findings were supported by Yeon, because he found that laser powder bed fusion (L-PBF)-processed 17-4 PH stainless steel generally exhibits a non-equilibrium microstructure consisting mostly of columnar δ-ferrite grains and a substantial fraction of retained austenite and martensite, contrary to 17-4 PH SS wrought with a fully martensite structure and coarse grains [12].Another study made a comparison of the tribological behavior of 17-4 PH SS manufactured via conventional and additive manufacturing methods, and the results showed that AM parts have good potential to be an alternative to counterparts in terms of friction and wear behavior [13].To summarize, processing conditions can affect the final metallurgical, mechanical, and geometrical properties of the material [14].
Analyzing the conventional processes separately, one of the most common is called the rolling process, commonly used to produce different shapes such as bars [15], pipes [16], sheets [17], and strips [18].In the rolling process, an input feed of metal is forced to pass through two specially designed rollers, which roll in opposite directions [19], obtaining different shapes depending on whether it is applied to cold or hot rolled techniques.Cold rolling is usually applied during the processing of austenitic stainless steel, which can be used for strengthening, work-hardening, and grain refinement during annealing.This method impacts microstructure, phase transformation, and mechanical properties [20].For all these reasons, rolling techniques in metal forming operations have been widely studied to analyze the defects and potential application areas for products and components [21].
On the other hand, since the emergence of additive manufacturing technologies, barriers to design have been removed, and the way products are manufactured has changed dramatically [22].Additive manufacturing (AM) operates on the principle of constructing a three-dimensional model layer by layer, facilitated by computer-aided design (CAD) software [23].In the realm of metal printing technologies, prominent examples include laser metal fusion (LMF), selective laser melting (SLM), and direct metal laser sintering (DMLS) [24,25].These methodologies have undergone extensive investigation to elucidate their impact on material performance, considering factors such as porosity [26], process parameters, building atmosphere, post-heat treatments, and initial powder characteristics.These investigations have focused on phase transformation, microcrack formation, microstructure evolution, and mechanical properties, particularly in stainless steel materials [27][28][29].Additionally, comparative studies have been undertaken regarding similar AM technologies.For example, a comparison made by Nezhadfar regarding 17-4 PH manufactured via laser powder bed fusion (L-PBF) and laser powder directed energy deposition showed that the L-PBF specimens have a finer microstructure (ferrite + lath martensite) than the LP-DED ones (massive ferrite + Widmanstätten ferrite) in non-heat treated conditions [30].Another example was performed by Akessa in which the mechanical properties of 17-4 PH manufactured via Markforged metal X (MfMX) describe a lower tensile strength but a similar hardness compared with others fabricated via laser powder bed fusion [31].
Due to several factors that can modify or influence the mechanical properties of the stainless steels manufactured via AM technologies, such as powder chemistry, processing environment, grain diameter, etc. [32], it is essential to provide more details of the most important ones: 1. Printing orientation: Cases where 316 SS was printed via atomic diffusion additive manufacturing (ADAM) in the direction of loading showed strength and strain to failure improvement of greater than 10% compared with other orientations [33].Printed spec-imens of 17-4 PH and 316 SS in different orientations and using selective laser melting (SLM) showed a noticeable effect on tensile properties [34,35].The same happens with other studies related to the same material where the best tensile properties are shown on specimens printed in a flat layout compared with the vertical layout [36][37][38], results reinforced by the research carried out by Alkindi, where the specimens were printed from 0 • until 90 • increasing 10 • by each other obtaining the same results [39].
2. Heat treatment: The study carried out by Malakshah analyzes the effect of heat treatment on the mechanical behavior of 17-4 PH and demonstrates that corrosion resistance and fatigue resistance were superior [40], results that are supported by Nezhadfar finding that fatigue strength is improved considerably [41].Meanwhile, Huber improved the ultimate tensile strength (UTS), the elongation break, and the hardness with the influence of sintering temperature and hold time on densification [42].Another study performed by Wilcox involved the same material being treated at different temperatures to give a wide range of mechanical properties [43].
3. Particle size: Feng demonstrates that the characteristics of the raw metal powder affect the microstructure and performance of the 17-4 PH processed by SLM [44], results supported by other authors using different metal powders with different chemical compositions and particle sizes, obtaining different properties related to hardness, elongation, and UTS [45,46].
4. Process environment during AM processes: Sandy demonstrates that the presence of oxide layers in stainless steel manufactured via AM technologies was correlated with the interaction of atmospheric oxygen with the chromium present in these materials [47].
5. Chemical composition, laser power, and scan speed: The study carried out by Sarma indicates that the variation in chemical composition is reflected in variations in relative density and microhardness.In addition, the same investigation found that changes in laser power and scan speed in the printing process impact the density and microhardness of the 17-4 PH SS [48].
The main advantages of AM are that this technology produces near net shapes in less time compared to conventional manufacturing processes [49].Also, this technology can fabricate parts with extremely complicated structures that cannot be fabricated by traditional methods [50].However, there are some disadvantages like porosity, remelting, solidification, and rapid melting of the powder during the production of parts, and a complex microstructure [50].Moreover, the mechanical properties of AM such as yield strength, ultimate tensile strength, and elongation at fracture are influenced by the microstructure [51].In addition, due to the complexity of AM structures and variables involved in the mechanical behavior of materials, it can be simulated using experimental data, extracting properties from the experimental tests and using this information as input for numerical models to obtain accurate mechanical properties predictions [52,53].This study aims to evaluate the impact on the mechanical properties and microstructure of 17-4 PH stainless steel specimens produced through two different manufacturing processes: traditional machining from commercial cold rolled 17-4 PH stainless steel and direct metal laser sintering DMLS 17-4 PH stainless steel.The mechanical properties evaluation is conducted through experimental tensile testing and nanoindentation analysis.The experimental results were used to generate the materials database for finite element simulations, which will be useful for predicting the mechanical behavior of structures produced by different manufacturing processes.

Experimental Procedure
In this study, 17-4 PH stainless steel specimens were produced using two different manufacturing processes: traditional machining from commercial cold rolled 17-4 PH and direct metal laser sintering (DMLS).The schematic of the metal removal machining process and direct metal laser sintering (DMLS) are shown in Figure 1.To manufacture the tensile test samples with the metal removal machining process, commercial circular cold rolled 17-4 PH with 30 mm diameter and 100 mm length was sectioned and machined using the conventional metal removal process.The parameters used for the removal process involved cutting velocity, feed per revolution, and cutting depth, which were 80 m/min, 0.02 mm/r, and 0.5 mm, respectively.The DMLS tensile specimens were also manufactured with an EOS M 300-4 series printer with DMLS technology, as shown in Figure 1.The selected DMLS parameters of laser beam diameter, power, and scanning speed were 0.1 mm, 400 W, and 7 m/s, respectively.The small-size samples were selected according to ASTM A370-03a [54], as shown in Figure 2.
J. Manuf In this study, 17-4 PH stainless steel specimens were produced using two different manufacturing processes: traditional machining from commercial cold rolled 17-4 PH and direct metal laser sintering (DMLS).The schematic of the metal removal machining process and direct metal laser sintering (DMLS) are shown in Figure 1.To manufacture the tensile test samples with the metal removal machining process, commercial circular cold rolled 17-4 PH with 30 mm diameter and 100 mm length was sectioned and machined using the conventional metal removal process.The parameters used for the removal process involved cutting velocity, feed per revolution, and cutting depth, which were 80 m/min, 0.02 mm/r, and 0.5 mm, respectively.The DMLS tensile specimens were also manufactured with an EOS M 300-4 series printer with DMLS technology, as shown in Figure 1.The selected DMLS parameters of laser beam diameter, power, and scanning speed were 0.1 mm, 400 W, and 7 m/s, respectively.The small-size samples were selected according to ASTM A370-03a [54], as shown in Figure 2.   1.In this study, 17-4 PH stainless steel specimens were produced using two different manufacturing processes: traditional machining from commercial cold rolled 17-4 PH and direct metal laser sintering (DMLS).The schematic of the metal removal machining process and direct metal laser sintering (DMLS) are shown in Figure 1.To manufacture the tensile test samples with the metal removal machining process, commercial circular cold rolled 17-4 PH with 30 mm diameter and 100 mm length was sectioned and machined using the conventional metal removal process.The parameters used for the removal process involved cutting velocity, feed per revolution, and cutting depth, which were 80 m/min, 0.02 mm/r, and 0.5 mm, respectively.The DMLS tensile specimens were also manufactured with an EOS M 300-4 series printer with DMLS technology, as shown in Figure 1.The selected DMLS parameters of laser beam diameter, power, and scanning speed were 0.1 mm, 400 W, and 7 m/s, respectively.The small-size samples were selected according to ASTM A370-03a [54], as shown in Figure 2.   1.   1. Two tensile test samples of rolled 17-4 PH and 17-4 PH (DMLS) were analyzed for microstructure.Prior to the test, the samples were cut on the cross-section in both longitudinal and transversal directions.They were then mounted and polished using a conventional metallographic polishing procedure.An electrolytic process involving a solution containing 10 mL of H 3 PO 4 , 40 mL of HNO 3 , and 50 mL of H 2 SO 4 was used to etch the samples.The voltage was set at 3 V and the current at 3.5 A for 3 s.The cross-section of longitudinal and transversal sections of rolled 17-4 PH and 17-4 PH (DMLS) substrate melted area were observed under an optical microscope.Scanning electron microscopy (SEM, Tescan Mira 3(TESCAN GROUP, a.s., Kohoutovice, Czech Republic)) with energy dispersive X-ray spectroscopy (EDS, Bruker (Bruker, Hamburg, Germany)) was used to evaluate the microstructure and semi-quantitative chemical composition of the samples.The crystalline phases were determined by an X-ray diffraction analysis (XRD, Phillips X'Pert 3040, Bragg-Brentano (PANALITICAL, Great Malvern, UK) over a 2-theta range from 40 to 90 degrees by using Cu-Kα radiation at 25 kV-30 mA.
The mechanical properties were experimentally assessed using a tensile test which was performed three times for each condition of rolled 17-4 PH and 17-4 PH stainless steel manufactured by direct metal laser sintering (DMLS) using an INSTRON model 8502 (INSTRON, Norwood, MA, USA) universal testing machine at a rate of 5 mm/min test speed.During the tensile test for both conditions, the elongation was recorded with an extensometer by using a gauge length.The microhardness and elastic modulus were determined via nanoindentation tests using an RTec Instrument with a 300 mN load and a 12 s hold time.

Simulation Configuration Numerical Simulation by Finite Element Method
The 3D CAD model dimensions of the tensile test samples were used according to standard ASTM A370-03a for rolled 17-4 PH and 17-4 PH stainless steel manufactured by direct metal laser sintering (DMLS).The numerical simulation tensile test was performed using the commercial SolidWorks ®® software 2022.Numerical tensile test simulations using the finite element method were performed using linear and advanced nonlinear simulations with dynamic analysis.The meshes of rolled 17-4 PH and 17-4 PH DMLS were created using a fine mesh with a curvature-based mesh with a minimum and maximum element size of 1.2 mm (average size), resulting in 57,353 tetrahedral elements and 83,819 nodes (as shown in Figure 3).A mesh independence analysis was performed, decreasing five different element sizes from medium to fine, being from 2.5 mm to 1.2 mm, to determine the converged solution to optimize the computational time.The mechanical properties of elastic modulus, Poisson´s ratio, tensile strength, and yield strength of materials were determined by experimental tensile tests, and data using the average experimental stressstrain curves were set in the simulation model type of plasticity-von Mises to create the stress-strain curves available in SolidWorks ®® software 2022.The boundary conditions for the samples were set on one side, and were totally fixtured.Meanwhile, the constraint for the other side was a cylindrical axial translation according to the experimental maximum lengths of 5.2 mm and 4.2 mm for rolled 17-4 PH and 17-4 PH stainless steel manufactured by direct metal laser sintering (DMLS), respectively.The stress analysis for the tensile test samples under translation conditions was considered using the experimental tensile velocity of 2.5 mm/min.

Microstructural Characterization
The microstructure at low magnifications for the rolled 17-4 PH and 17-4 PH stainless steel obtained longitudinal and transversal cross-sections of tensile samples, which are shown in Figure 4.The micrographs in Figure 4a show the microstructure of the rolled 17-

Microstructural Characterization
The microstructure at low magnifications for the rolled 17-4 PH and 17-4 PH stainless steel obtained longitudinal and transversal cross-sections of tensile samples, which are shown in Figure 4.The micrographs in Figure 4a show the microstructure of the rolled 17-4 PH stainless steel with the presence of a typical martensitic structure.The crosssection microstructure in longitudinal and transversal regions showed a fine crystalline martensitic microstructure.The comparison of the cross-section micrographs shows that the microstructure that appeared in both areas is the same.The micrographs of Figure 4b reveal the layers or levels of melting of the steel powder due to the laser.These layers have a thickness of 70 µm; this is seen in the longitudinal section of the figure, while the transversal section, with a lower magnification, shows the elongated shapes of microstructure on the material in the transversal direction manufactured by the DMLS process.

Microstructural Characterization
The microstructure at low magnifications for the rolled 17-4 PH and 17-4 PH stainless steel obtained longitudinal and transversal cross-sections of tensile samples, which are shown in Figure 4.The micrographs in Figure 4a show the microstructure of the rolled 17-4 PH stainless steel with the presence of a typical martensitic structure.The cross-section microstructure in longitudinal and transversal regions showed a fine crystalline martensitic microstructure.The comparison of the cross-section micrographs shows that the microstructure that appeared in both areas is the same.The micrographs of Figure 4b reveal the layers or levels of melting of the steel powder due to the laser.These layers have a thickness of 70 µm; this is seen in the longitudinal section of the figure, while the transversal section, with a lower magnification, shows the elongated shapes of microstructure on the material in the transversal direction manufactured by the DMLS process.The 17-4 PH DMLS stainless steel microstructure is characterized by complex directional columnar structures parallel to the DMLS build direction shown in Figure 5c.According to the microstructures presented in optical and SEM micrographs shown in Figures 4 and 5, respectively, the difference in grain morphology and size distribution can be seen, showing for the rolled 17-4 PH a small grain compared with those obtained by the DMLS process, impacting the mechanical properties of the materials analyzed.According to Porro et al. [51], who analyzed the Hall-Petch effect, it shows a correlation between yield strength and grain size, describing a reduction of the yield strength of the material as the grain size increases.This effect is supported by the results obtained, having a rolled small grain of 358.9 µm 2 (767 ± 6.4 MPa) and for DMLS a large grain of 2539.6 µm 2 (707 ± 13.3 MPa).
Diffraction XRD patterns for both rolled 17-4 PH and 17-4 PH DMLS stainless steel samples were analyzed for the cross-sections in longitudinal and transversal directions, as shown in Figure 6a  Based on the diffraction patterns, the microstructure contains both ferritic and martensitic microstructures in the 17-4 PH DMLS stainless steel, as does austenitic gamma microstructure, shown in Figure 6b.These results agree with other authors' observations [55,56].

Experimental Characterization of Mechanical Properties
The mechanical properties of steel under different manufacturing methods are important due to the change in their behavior and mechanical strength.For this case study, after analyzing the data obtained by the tensile testing machine, the stress-strain graph was obtained for the materials bar of 17-4 PH and 17-4 PH DMLS stainless steel (see Figure 7a,b).The parameters obtained from the simple tension test are the yield stress, obtained through a linear regression of the linear-elastic zone, and the method is applied at 0.2% of the unit strain.The ultimate stress is found in the plastic deformation zone, which reaches the maximum stress.Finally, the elastic modulus is determined by the slope in the linear-elastic region.The numerical values of the mechanical properties of elastic modulus, yield stress, ultimate stress, and HRC hardness of the materials are shown in Table 2 of the steel tensile and hardness test results.The stress-strain for both processing methods was defined in the linear elastic behavior with the engineering stress using Equation (1): and the strain using Equation (2): was determined to calculate the mechanical properties shown in Table 2.The parameters were taken from the corresponding experimental stress-strain curves shown in Figure 7.
When making a comparison between both the processing methods analyzed, some differences can be observed regarding the strength of the material, information that is presented in Table 2.The results show a reduction of rigidity of 17% in the material manufactured via DMLS compared with that manufactured by rolling and, after researching the mechanical properties of SS materials with different manufacturing methods, it was observed that variations in the mechanical properties could be focused more on the material processed with AM technologies; different factors could be the reason for this, such as chemical composition, the AM technology used for the manufacturing process, printing parameters, powder particle size, etc.For example, the lowest rigidity was reported by Suwanpreecha with 159 GPa [36], while Henry found 176 GPa [33], and a maximum value of 206.7 GPa was reported by Carneiro [9].On the other hand, for the case of the

Experimental Characterization of Mechanical Properties
The mechanical properties of steel under different manufacturing methods are important due to the change in their behavior and mechanical strength.For this case study, after analyzing the data obtained by the tensile testing machine, the stress-strain graph was obtained for the materials bar of 17-4 PH and 17-4 PH DMLS stainless steel (see Figure 7a,b).The parameters obtained from the simple tension test are the yield stress, obtained through a linear regression of the linear-elastic zone, and the method is applied at 0.2% of the unit strain.The ultimate stress is found in the plastic deformation zone, which reaches the maximum stress.Finally, the elastic modulus is determined by the slope in the linear-elastic region.The numerical values of the mechanical properties of elastic modulus, yield stress, ultimate stress, and HRC hardness of the materials are shown in Table 2 of the steel tensile and hardness test results.

Experimental Characterization of Mechanical Properties
The mechanical properties of steel under different manufacturing methods are important due to the change in their behavior and mechanical strength.For this case study, after analyzing the data obtained by the tensile testing machine, the stress-strain graph was obtained for the materials bar of 17-4 PH and 17-4 PH DMLS stainless steel (see Figure 7a,b).The parameters obtained from the simple tension test are the yield stress, obtained through a linear regression of the linear-elastic zone, and the method is applied at 0.2% of the unit strain.The ultimate stress is found in the plastic deformation zone, which reaches the maximum stress.Finally, the elastic modulus is determined by the slope in the linear-elastic region.The numerical values of the mechanical properties of elastic modulus, yield stress, ultimate stress, and HRC hardness of the materials are shown in Table 2 of the steel tensile and hardness test results.Other parameters to take into consideration are the yield stress and UTS.The values reported in the present investigation for the AM material are 707 ± 13.3 MPa and 897 ± 22.9 MPa, respectively, while others report similar values.For example, Henry found values of 600 MPa for yield stress and 800 MPa for UTS [33]; then Suwanpreecha reported 668 ± 40 MPa for yield stress and 745 ± 6 MPa for UTS [36], and other studies report higher mechanical properties, for example, Sghaier found 992 MPa for yield stress and 1018 MPa for UTS.Still, the material faced a post-processing treatment [27].
The hardness value obtained was 298 ± 3.8 HV for rolled and 312 ± 8.76 HV for AM, similar to those obtained by other authors.For example, Gatoes mentions a range of 250-460 HV for rolled and 306 ± 11 HV for AM [28], while Akessa reports a hardness of 331 ± 28 HV for AM material [31].
The mechanical properties with nanoindentation for rolled 17-4 PH and 17-4 PH DMLS stainless steel samples were measured with three nanoindentation curves in the cross-sections in longitudinal and transversal directions, as shown in PH DMLS ranged from 2046 to 2178 µm for the longitudinal and from 1876 to 1934 µm for the transversal section, as shown in Figure 8c,d.On the other hand, as detailed in Figure 8a-d, the presence of the "nose" during unloading is evidence of the mechanical behavior of the indented material, which depends on the time [57,58].This phenomenon can be interpreted as a recovery (elastic or plastic) during unloading under the conditions of the tests.Comparatively, the 17-4 PH DMLS sample displays a slight elastic deformation in the transversal direction compared to the longitudinal direction.Meanwhile, the "nose" is more marked in both directions of the 17-4 PH samples as well as in the longitudinal direction of the 17-4 PH sample, which indicates slight plastic deformation.In this case, as suggested in the literature [57][58][59], another way to evaluate or confirm this mechanical behavior is to calculate the coefficient of elastic recovery parameter (k e ) using the equation that describes the effect of the maximum load on elastic/plastic deformation.In this case, the k e parameter reflects the elastic recovery of the material during the unloading process.Therefore, k e can be calculated from the data extracted from the curve obtained by applying the nanoindentation technique and using Equation (3): where k e (%) is the coefficient of elastic recovery, h max (µm) is the maximum penetration depth, and h f (µm) is the residual depth after unloading.
In this sense, Table 3 presents the values of the elastic recovery parameter of both samples.It is shown in detail that the 17-4 PH DMLS sample in the transversal direction has a higher value of elastic recovery of ~28.50% than in the longitudinal direction.By contrast, the 17-4 PH sample has values of ~22.38% in the longitudinal direction and 22.23% in the transversal direction, which establish a less elastic recovery parameter.Likewise, the average maximum indentation depth, elastic modulus E, nanohardness H, contact stiffness S, and elastic recovery parameter (k e ) are summarized in Table 3.It is possible to observe a difference in elastic modulus E, which results in longitudinal and transversal directions for 17-4 PH DMLS due to the superposition of the DMLS layers.Alfieri et al. have discussed this anisotropic behavior in terms of the influence of building direction [60].The simulations of linear tensile test results for rolled 17-4 PH and 17-4 PH DMLS were performed to evaluate the transient evolution of von Mises stress and axial displacement at yield strength as shown in Figure 9a.The ultimate strength and fracture strength for rolled 17-4 PH and 17-4 PH DMLS stainless steel samples were nonlinearly simulated using the plasticity-von Mises model for multi-linear stress-strain curve definition, where the stressstrain curves were experimentally obtained, as shown in Figure 9b and Figure 9c, respectively.The simulations of linear tensile test results for rolled 17-4 PH and 17-4 PH DMLS were performed to evaluate the transient evolution of von Mises stress and axial displacement at yield strength as shown in Figure 9a.The ultimate strength and fracture strength for rolled 17-4 PH and 17-4 PH DMLS stainless steel samples were nonlinearly simulated using the plasticity-von Mises model for multi-linear stress-strain curve definition, where the stress-strain curves were experimentally obtained, as shown in Figure 9b and Figure 9c, respectively.
The von Mises stress and axial displacement at yield strength were 770.04 MPa and 0.13 mm (Figure 9a).These values correspond to the maximum linear behavior according to Hooke's law.After this, the nonlinear behavior is reached in the strain-hardening with 983.9 MPa and 2.795 mm (Figure 9b).Finally, the necking region is obtained until fracture The von Mises stress and axial displacement at yield strength were 770.04 MPa and 0.13 mm (Figure 9a).These values correspond to the maximum linear behavior according to Hooke's law.After this, the nonlinear behavior is reached in the strain-hardening with 983.9 MPa and 2.795 mm (Figure 9b).Finally, the necking region is obtained until fracture strength reaches 1116 MPa and 5.5 mm (Figure 9c).In the same way, DMLS stainless steel was evaluated in the linear and nonlinear regions for yield strength, ultimate strength, and fracture strength, as shown in Figure 10a, Figure 10b and Figure 10c, respectively.The von Mises stress and axial displacement at yield strength were 708.2 MPa and 0.156 mm in the linear behavior, as shown in Figure 10a.After this point, the nonlinear behavior is reached in the strain-hardening with 871.5 MPa and 2.08 mm, as shown in Figure 10b.The necking region and fracture strength are reached with 957.2 MPa and 4.2 mm (Figure 10c).According to the experimental and simulated and experimental tests, the DMLS 17-4 PH compared with the rolled 17-4 PH stainless steel samples decreased the yield strength by ~8% and ultimate strength by ~11%.This mechanical behavior could be attributed to defects in the DMLS process, such as defects due to unfused voids and porosity [28,29].The results provided by simulation fit with those from experimental analysis; this is due to the integration of the experimental values (elastic modulus, tensile strength, yield strength of material, and the average experimental stress-strain curves) into the numerical model to predict the mechanical properties of the material and generating information about the mechanical properties of the materials.In this sense, the procedure followed by Zhang et al. [53] introduced the yielding and ultimate points into the numerical analysis by applying a minimal calibration to the strength coefficient and intrinsic strength term.A similar procedure was performed by Promsuwan et al. [52], where the numerical model is obtained from the strength coefficient and the strain hardening is obtained from the experimental procedure.
The SEM micrographs of fractography morphologies from the tensile fracture surface of rolled 17-4 PH and 17-4 PH DMLS stainless steel samples after tensile tests are shown in Figure 10.The fracture morphology of the surface of rolled 17-4 PH stainless steel presents the typical cone shape fracture as shown in Figure 11a,b.According to Figure 11b, large quantities of fine dimples characterize a ductile fracture mode.The fracture surface of 17-4 PH DMLS stainless steel samples showed elongated defects present in the fracture surfaces; they are associated with a partially fragile fracture mode and some defects due to unfused voids (see Figure 11c,d).On the other hand, the laser sintering caused strength and plasticity to decrease, which is exhibited in Figure 7b, causing the material to become brittle.strength reaches 1116 MPa and 5.5 mm (Figure 9c).In the same way, DMLS stainless steel was evaluated in the linear and nonlinear regions for yield strength, ultimate strength, and fracture strength, as shown in Figure 10a, Figure 10b, and Figure 10c, respectively.The von Mises stress and axial displacement at yield strength were 708.2 MPa and 0.156 mm in the linear behavior, as shown in Figure 10a.After this point, the nonlinear behavior is reached in the strain-hardening with 871.5 MPa and 2.08 mm, as shown in Figure 10b.
The necking region and fracture strength are reached with 957.2 MPa and 4.2 mm (Figure 10c).According to the experimental and simulated and experimental tests, the DMLS 17-4 PH compared with the rolled 17-4 PH stainless steel samples decreased the yield strength by ~8% and ultimate strength by ~11%.This mechanical behavior could be attributed to defects in the DMLS process, such as defects due to unfused voids and porosity [28,29].The results provided by simulation fit with those from experimental analysis; this is due to the integration of the experimental values (elastic modulus, tensile strength, yield strength of material, and the average experimental stress-strain curves) into the numerical model to predict the mechanical properties of the material and generating information about the mechanical properties of the materials.In this sense, the procedure followed by Zhang et al. [53] introduced the yielding and ultimate points into the numerical analysis by applying a minimal calibration to the strength coefficient and intrinsic strength term.A similar procedure was performed by Promsuwan et al. [52], where the numerical model is obtained from the strength coefficient and the strain hardening is obtained from the experimental procedure.The SEM micrographs of fractography morphologies from the tensile fracture surface of rolled 17-4 PH and 17-4 PH DMLS stainless steel samples after tensile tests are shown in Figure 10.The fracture morphology of the surface of rolled 17-4 PH stainless steel presents the typical cone shape fracture as shown in Figure 11a,b.According to Figure 11b, large quantities of fine dimples characterize a ductile fracture mode.The fracture surface of 17-4 PH DMLS stainless steel samples showed elongated defects present in the fracture surfaces; they are associated with a partially fragile fracture mode and some defects due to unfused voids (see Figure 11c,d).On the other hand, the laser sintering caused strength and plasticity to decrease, which is exhibited in Figure 7b, causing the material to become brittle.

Conclusions
This study analyzed the effect on the mechanical properties and microstructure of two manufacturing procedures-conventional machining and direct metal laser sintering-using experimental tensile tests and nanoindentation, as well as linear and nonlinear tensile finite element simulations.The study was conducted on commercial

Conclusions
This study analyzed the effect on the mechanical properties and microstructure of two manufacturing procedures-conventional machining and direct metal laser sintering-using experimental tensile tests and nanoindentation, as well as linear and nonlinear tensile finite element simulations.The study was conducted on commercial cold-rolled 17-4 PH and 17-4 PH stainless steel manufactured using direct metal laser sintering (DMLS).The findings are listed below: • The rolled 17-4 PH stainless steel microstructure showed the typical martensitic struc- ture for the longitudinal and transversal cross-sections.The microstructure for 17-4 PH DMLS stainless steel reveals the layers or levels of melting of the steel powder due to the laser process, characterized by complex directional columnar structures parallel to the DMLS build direction.showed similar values for the longitudinal and transversal cross-sections.Meanwhile, the properties of 17-4 PH DMLS stainless steel samples presented an anisotropic behavior with a variation in the elastic modulus as result of the superposition of the DMLS layers.• According to the experimental and simulated tests, the DMLS 17-4 PH compared with rolled 17-4 PH stainless steel samples decreased the yield strength by ~8% and the ultimate strength by ~11%.This mechanical behavior could be attributed to defects in the DMLS process, such as defects due to unfused voids and porosity.• The fracture morphology of the surface of rolled 17-4 PH stainless steel presented the typical cone shape fracture, showing a ductile fracture mode that is characterized by the presence of large quantities of fine dimples.The fracture surface of 17-4 PH DMLS stainless steel samples showed elongated defects in the fracture surfaces associated with partially fragile fracture mode and some defects due to unfused voids.Also, the laser sintering process causes a decrease in strength and plasticity, resulting in the material's brittle behavior.

Figure 4 .
Figure 4. Optical micrographs of cross-sections for longitudinal and transverse planes for (a) rolled 17-4 PH and (b) 17-4 PH DMLS.SEM micrographs of the microstructure at high magnifications and EDS semiquantitative chemical compositions for the rolled 17-4 PH and 17-4 PH DMLS stainless

Figure 4 .
Figure 4. Optical micrographs of cross-sections for longitudinal and transverse planes for (a) rolled 17-4 PH and (b) 17-4 PH DMLS.SEM micrographs of the microstructure at high magnifications and EDS semi-quantitative chemical compositions for the rolled 17-4 PH and 17-4 PH DMLS stainless steel obtained longitudinal and transversal cross-sections of tensile samples, which are shown in Figure 5.The micrographs of Figure 5a,b show the longitudinal and transversal microstructures for the rolled 17-4 PH stainless steel and a typical martensitic structure.The EDS and semiquantitative chemical composition show the chemical elements for 17-4 PH stainless steel.The 17-4 PH DMLS stainless steel microstructure is characterized by complex directional columnar structures parallel to the DMLS build direction shown in Figure5c.According to the microstructures presented in optical and SEM micrographs shown in Figures4 and 5, respectively, the difference in grain morphology and size distribution can be seen, showing for the rolled 17-4 PH a small grain compared with those obtained by the DMLS process, impacting the mechanical properties of the materials analyzed.According toPorro et al. [51], who analyzed the Hall-Petch effect, it shows a correlation between yield strength and grain size, describing a reduction of the yield strength of the material as the grain size increases.This effect is supported by the results obtained, having a rolled small grain of 358.9 µm 2 (767 ± 6.4 MPa) and for DMLS a large grain of 2539.6 µm 2 (707 ± 13.3 MPa).Diffraction XRD patterns for both rolled 17-4 PH and 17-4 PH DMLS stainless steel samples were analyzed for the cross-sections in longitudinal and transversal directions, as shown in Figure6aand Figure6b, respectively.The diffraction of rolled 17-4 PH stainless and Figure 6b, respectively.The diffraction of rolled 17-4 PH stainless steel presents an austenitic (γ) phase (ICDD:04-020-7293) ((111) at 43.57 • , (200) at 51.11 • , (220) at 75.19 • ), and a ferritic (α) phase (ICDD:04-011-9042) ((110) at 44.68 • , (200) at 65.03 • , (211) at 82.34 • )), shown in Figure 6a.The XRD patterns of 17-4 PH DMLS stainless steel show the presence of both ferritic alpha (α) or martensitic phase (Ref.code: 00-044-1290) ((101) at 44.18 • , (110) at 44.80 • , (200) at 65.22 • , (211) at 82.16 • ), and austenitic (γ) phase.

Figure 8 .
The curves of rolled 17-4 PH and 17-4 PH DMLS stainless steel for longitudinal and transversal directions are shown in Figure 8a,b and Figure 8c,d, respectively.The values of maximum depth for rolled 17-4 PH ranged from 2036 up to 2074 µm for the longitudinal and from 2033 up to 2083 µm for the transversal section, which is indicative of higher deformation compared with 17-4 PH DMLS, as shown in Figure 8a,b.The depth values for rolled 17-4

Figure 8 .
Figure 8. Nanoindentation experimental load-unload curves of the cross-section for rolled 17-4 PH: (a) longitudinal, (b) transversal, and for 17-4 PH DMLS: (c) longitudinal, (d) transversal.The three colors (blue, gray and orange) represent the results of three nanoindentation repetitions for each test condition

Figure 8 .
Figure 8. Nanoindentation experimental load-unload curves of the cross-section for rolled 17-4 PH: (a) longitudinal, (b) transversal, and for 17-4 PH DMLS: (c) longitudinal, (d) transversal.The three colors (blue, gray and orange) represent the results of three nanoindentation repetitions for each test condition.

Figure 9 .
Figure 9. FEM simulation von Mises stress and axial displacement for rolled 17-4 PH at (a) yield strength, (b) ultimate strength, and (c) fracture strength.

Figure 9 .
Figure 9. FEM simulation von Mises stress and axial displacement for rolled 17-4 PH at (a) yield strength, (b) ultimate strength, and (c) fracture strength.

Table 2 .
Mechanical properties determined by tensile test of rolled 17-4 PH and 17-4 PH DMLS stainless steel.

Table 3 .
Mechanical properties by nanoindentation at 300 mN.

Table 3 .
Mechanical properties by nanoindentation at 300 mN.
• Diffraction XRD patterns for rolled 17-4 PH stainless steel present ferritic (α) and austenitic (γ) phases.The XRD patterns for 17-4 PH DMLS stainless steel show the presence of both ferritic (α) or martensitic and austenitic (γ) phases.• The mechanical properties obtained from the simple tension test decreased by 17% for the elastic modulus, 7.8% for the yield strength, and 7% ultimate strength for 17-4 PH DMLS compared with rolled 17-4 PH stainless steel.• The nanoindentation results of mechanical properties analyzed for rolled 17-4 PH