Experimental Insight into the Containment of Plastic Waste in Cement-Stabilised Soil as a Road Pavement Layer Material

: Plastic waste (PW) constitutes a nuisance to our environment despite several efforts to reduce, reuse and recycle it. This study experimentally explores the possibility of storing plastic waste within a cement-stabilised soil that can be used as a road pavement layer material without adversely affecting the geotechnical characteristics of the stabilised soil. The soil is an A-2-6 soil, according to classiﬁcation by the American Association of State Highway and Transportation Ofﬁcials (AASHTO). Compaction characteristics, the California bearing ratio (CBR) and the unconﬁned compressive strength (UCS) of soil with 10% cement were determined for the 0, 2, 5, 10 and 15% addition of PW. The cementing of soil particles, which played a vital role in enhancing its strength on the addition of cement, may have been activated by the pozzolanic reaction between cement and soil particles. However, the addition of PW to this cement-stabilised mix led to a decrease in strength parameters at all variations. The soil with 10% cement and 2% PW yielded higher strength when compared to other mix ratios with PW and is suitable for use as a layer material in road pavement construction. As a sustainable strategy for PW management in developing nations, the usage of PW in cement-stabilised soil layer is recommended.


Introduction
The total weight of virgin plastics in circulation around the world keeps skyrocketing, irrespective of the efforts and campaigns that have been put in place to checkmate these wastes from causing environmental nuisance and hazards to marine life [1].However, it is no news that the increasing volume of PW produced and discarded annually is mostly attributed to industrialisation and changes in human lifestyles.These wastes are produced by anthropogenic activities in huge proportions in product manufacturing, which poses a threat to the preservation and stability of our ecosystem [2].Following the traditional "take-make-dispose" linear material-flow economic paradigm has contributed significantly to the rapid expansion in the use of plastic products and the generation of PW since the advancement of plastic (or synthetic fibre) in the 1950s.These benefits include an affordable price, resistance to heat and corrosion and its significant light weight [3].Every year, a substantial quantity of PW enters the environment as a result of inappropriate disposal methods, raising several issues regarding its effects on ecosystem safety and natural resources [4].The Organisation for Economic Co-operation and Development (OECD) conducted a survey on worldwide plastic production and consumption in 2022 [5].This analysis predicts that in the absence of radical new regulations, the worldwide consumption of plastics would increase more quickly than that of most raw resources, from 460 million tonnes (Mt) in 2019 to 1231 Mt in 2060.Africa and Asia will see the quickest growth, despite the fact that in 2060, OECD countries will still produce 238 kg of plastic waste yearly per person on average, more than non-OECD nations (an average of 77 kg per year).The accumulation of plastic in lakes, rivers, and oceans is predicted to more than triple while plastic leakage into the environment is predicted to double to 44 Mt annually as plastic waste soars from 353 Mt in 2019 to 1014 Mt in 2060.Although leakage of microplastics or synthetic polymers with a diameter of less than 5 mm from objects such as industrial plastic pellets, textiles and tyre wear is alarming, the majority of pollution comes from larger debris termed as macroplastics.The projected increase in plastic consumption and waste will continue despite anticipated increases in the use of recycled plastic in the manufacture of new goods, technological innovations and regional economic changes that should result in an estimated 16% decrease in the amount of plastic required to generate 1 USD (US Dollar) of output production by 2060.Additionally, it is predicted that the percentage of effectively recycled plastic waste would increase to 17% in 2060 from 9% in 2019, while landfilling and incineration will progress to account for 50% and 20% of plastic waste, respectively.The amount of plastic in the world that bypasses waste management systems and instead ends up in unregulated dumpsites, is burned in open pits, or leaks into the ground or aquatic habitats is predicted to decrease from 22% to 15%.
Discharge of these PW can pose a serious hazard to health and the environment.It is anticipated that each year, 8 million tonnes or more of PW will enter the sea [6].Then, via land-based means including ground water runoff, combined sewer spills, pollution, industrial effluents, dumping of solid wastes and landfills, these wastes enter water bodies [7].As they move up the food chain from marine life to man through consumption of contaminated seafood, this contaminant enters tissues and skin [8].Additionally, PW from landfill disposal can release harmful compounds into the soil, which may seep into nearby subsurface water sources and other water sources.This poses a serious health risk to humans and other organisms that consume water and crops [9].
In large cities of developing nations such as Nigeria, plastic waste is frequently burned as an alternative to land filling.This process emits toxins such as ammonium, polyvinyl chloride, dioxins, furans and polychlorinated biphenyls (PCBs) that can pollute the environment [10].These chemicals can worsen respiratory conditions, raise the risk of heart disease, harm the kidney, liver, neurological system, and skin, result in cancer and even cause death [11].
Microplastics have even been suggested as a new global change factor [12].Anthropogenic microplastic pollution builds up gradually in ecological systems, endangering the health and quality of the soil, for example by reducing aggregate stability and modifying bio-activity [13].These microplastics typically operate as transport vectors for dangerous contaminants from the environment and have the ability to release chemicals into the atmosphere [14].PW are also well recognised for blocking drainage when they build up with time, preventing storm water from flowing freely [15].This is among the primary factors responsible for drainage blockage in developing countries as shown in Figure 1.The amount of PW generated yearly in big cities of developing countries such as Lagos, Nigeria continues to skyrocket, which ultimately affects the water-holding capacity of drains, river channels and reservoirs in these megacities as people dispose PW in these canals.
The constant growth of PW in the environment has sparked concern.Thus, efforts and strategies have been employed over time to manage these wastes.
Recycling, also known as 'renewing or reusing', is among the most common strategies.Recycling is a waste management technique, where waste is gathered and turned Figure 1.Plastic waste blocking a drainage system in Lagos, Nigeria [16].
The constant growth of PW in the environment has sparked concern.Thus, efforts and strategies have been employed over time to manage these wastes.
Recycling, also known as 'renewing or reusing', is among the most common strategies.Recycling is a waste management technique, where waste is gathered and turned into raw materials that may be utilised again to create other valuable items [17].Gathering discarded plastics, grouping them, washing them to remove impurities, shredding and resizing them, identifying and segregating the various types of plastics, and compounding are all steps in the recycling process [18].By minimising the quantity of carbon dioxide and other hazardous gases released into the atmosphere as a result of burning or incinerating these wastes, recycling serves to safeguard human life [19].However, throughout the recycling process, some chemicals are released into the environment.When inhaled by creatures that reside close to the recycling zones, some of these chemicals (including volatile gases derived from plastic waste constituents and organic chains of monomer units that create plastic cycles of organic toxins and ashes) kill plant structures and have a negative impact on wildlife [17].Plastics must be heated during the process in order to melt them, which results in the release of sulphur, carbon and other gases into the atmosphere.These gases can result in acid rain, the greenhouse effect and global warming; all of which have different negative environmental effects [20].Additionally, this may cause health problems for people who enter the recycling zone for plastics.Wastes are separated for continuous recycling after the downcycling of plastics, which explains why the plastic is ultimately unsuitable for further recycling.As a result, they are viewed as a secondary use of leftover plastic waste and end up in landfills [21].Incineration is another strategy that has been employed over the years [17].Waste incineration is the process of burning wastes in the presence of oxygen, also referred to chemically as complete combustion, which results in the emission of water molecules and carbon dioxide into the environment.Waste incineration makes significant efforts towards reducing waste and generating electricity from waste, both of which are crucial for modern industrialisation [22].Incineration as a chemical process offers benefits and drawbacks, as with all other biochemical or scientific operations.The incineration process has some limitations in comparison to other alternate waste management methods, such as costly setup.Waste incineration also emits waste ash that could be harmful to both people and the environment [23].Landfilling is another commonly used method.After being used, plastics are disposed of in various trash cans and end up in landfills.Landfills are any locations or areas where all disposable plastic wastes are discarded after use before burying it beneath the surface of the earth [17].During this landfill operation, every organic molecule goes through biodegradation and decomposition.Plastic bags and other lengthy polymer wastes might take ten to one hundred years to decompose in landfill processing [24].Landfills are a tremendous source of energy because of the carbon dioxide and methane gas produced during the biodegradation process.Landfills preserve sanitation, keep cities tidy and distinguish hazardous waste from other waste types.Additionally, this is a cost-effective method of managing plastic waste.Although this method can be used to manage plastic waste, it has a number of disadvantages, including the fact that it causes climate change and ignites methane (a combustible gas).Additionally, it harms wildlife and taints soil and water [25].The process of pyrolysis has also been employed as a management strategy for plastic wastes [17].The conversion of gases and fatty oils into hydrocarbons and recovered crude petrochemicals is known as pyrolysis.With this, even unrefined petrochemicals can be recovered, and plastic waste can be used to create renewable energy [26].By using catalytic methods of chemical processing or thermal reactions, the first derivative of petroleum refining cuts and petrochemicals are transformed to their monomers and other valuable elements, such as stabilisers and plasters [27].Despite the potential for large upfront costs, this scientific approach to waste management is effective [26].Microorganisms have also been employed to decompose wastes in a process referred to as bioremediation [28,29].The biotechnology aspect of bioremediation can also be described as having primary principles of detoxification and decontamination by using microorganisms to biodegrade entirely natural materials that can be treated under the biological degradation of plants, fungi, bacteria and algae [30].This process, however, requires huge investments in employing enzymes for the degradation of synthetic compounds.
Plastic wastes have also been employed as construction materials for sustainable development [31].By utilising polyethylene terephthalate (PET), scrap plastic wastes (SPW) and foundry sand (FS), sustainable productive bricks were created [32].Compressed earth bricks (CEB) were also produced using clayey sand and finely shred PET waste.During the CEB production process, soil and shreds of waste plastic were combined with a cementitious binder to increase the strength and durability [1].Plastic bottles (PET) filled with either dry sand, wet sand, or air have been used as building materials, with cement mortar being employed as the binding agent.Low thermal conductivity was an outcome, resulting in solid masonry walls [33].Taafe et al. [34] also utilised PET bottles in the production of eco-bricks with high sound reduction index.Greenhouse walls were constructed from plastic bottles by Mokhtar et al. [35] to cut down on CO 2 emissions into the atmosphere.It has also been discovered that PET polymeric wastes increase the efficiency of unfired clay bricks [36,37].When making interlocking bricks, clay and cement were swapped out for a binder made of polyethylene terephthalate (PET) and polyurethane (PU).These bricks were recommended for usage as a partition wall and were determined to be suitable as masonry bricks that do not support loads [38].However, waste plastics such as polyethylene, high-density polymer (nylon 66) and polythene terephthalate, as well as red soil, crushed stone and river sand were used to make bricks in a range of formulations [39].During the soundness test, no noise was heard and these bricks were strong and long-lasting.Results have shown that composite bricks made from fly ash and powdered polythene wastes are cost-effective and environmentally sustainable [40].Blocks for pavers were also made using polythene bags and demolition debris rather than cement [41].It was recommended that instead of cement, waste plastic bags may be melted down and used to make concrete blocks and bricks.Waste plastic may be transformed into construction materials such as bricks and concrete blocks due to its lightweight, great flexibility and capacity to be altered to meet particular technological requirements [42].In addition to paver blocks and bricks, plastic wastes have been used in making different tiles [43,44].This is already a common practice in certain regions of the world to improvise concrete for use in road construction.As a partial or complete alternative for aggregate, researchers have looked into various plastic admixtures [45][46][47][48][49][50].
PW outcomes of numerous research offer an encouraging implication to the opportunity for application of PW for stabilising or reinforcing of different soil [51][52][53][54][55].This employment disposes PW and reduces use of virgin materials [56].When compared to chemically stabilised soils, plastic fibre proffers a more affordable option to soil stabilisation for pavement constructions and feasible for sustainable road construction.One benefit of plastic fibre stabilisation against stabilisation with chemicals is that PW stabilisation does not result in carbon dioxide emissions, but chemical stabilisation does [57].Furthermore, the employment of PW was tagged an alternative innovative material compared to conventional materials in building masonry walls due to its good construction ability, low-cost, non-brittle characteristics and absorption of abrupt shock loads [58].This alternative material also poses an eco-friendly way of replacing bitumen in flexible pavement construction geared towards cost reduction [59] and the possible consequence of the elimination of many million metric tonnes of PW [60].More so, its impact as a pavement construction material in underdeveloped and developing countries cannot be overemphasised as it improves the economy and environment [15].Additionally, plastic material can be employed with fly ash and cement for rigid pavement construction.Even though the viability in concrete reduces as the percentage of plastic increases, this workability can be retained to a certain degree by increasing the water-cement (w/c) ratio [31].
As evidenced in applications such as road and lightweight aggregates, paving techniques and soil stabilisation, polymer concrete, separation membranes or geogrid, asphalt binders and sheet piling, the potential for use of these PW is continually expanding [61].
Regardless of the efforts made to reduce PW, its constant and incremental emergence in recent years is still very alarming.As of 2022, the world will produce twice as much PW as it did two decades prior [62].The majority of these wastes will be rid of by landfilling, burning, or even leaked into the environment.Although processes such as soil stabilisation have proved over the years to be advantageous in reducing PW from the ecosystem, its wide adoption has been limited.Rather than just stabilisation with conventional materials, attempts as to how these PW can be properly contained in a stabilised soil layer at a large magnitude should be examined.Thus, this study aims at exploring the possibilities of containing PW in cement-stabilised soil as a layer material for road pavement construction.
The use of cement as a binder dates back to the 1960s, when soil stabilisation technology was first developed.Because it can be used by itself to produce the necessary stabilising effect, it may be regarded as a primary stabilising agent or hydraulic adhesive [63].When cement is introduced to the fine soil particles, various pozzolanic processes are involved, increasing soil strength.Cement stabilisation is quicker and independent of the soil properties [64].Cement has calcium aluminates and calcium silicates, which hydrate to produce cementitious materials.Fast cement hydration results in quick strength gain in the stabilised soil [65].Its adequate mechanical qualities and accessibility make it the material of choice for geotechnical engineering projects.As a result, it is utilised in a variety of stabilisation methods, including deep cement mixing and grouting [66].The main benefits of using cement for stabilisation are that it is produced in accordance with strict ASTM standards, ensuring consistency of efficiency and durability; it is effective in soil stabilisation and has been used for more than 50 years on a diverse range of projects; it has a long track record of performance; it requires less volume increase than other materials; and it is widely available in bulk across nations [67].Enhancement of soil with cement has yielded desirable results over the years in the field of construction.This material can be used alone to give desirable results for soil stabilisation.Cement generally enhances any type of soil, improving its California bearing ratio (CBR), thus making it stronger for use as a pavement layer material [68].The durability obtained from soil-cement stabilisation has been known to be outstanding for years.Additionally, it helps pavement by evenly spreading the load, eliminating base rutting and lowering deflection as well as moisture issues [69].The use of cement as a soil stabiliser for enhancing the engineering characteristics of soils for base and sub-base courses on highways and rail tracks at the best levels has been examined and proven [67].Additionally, this stabilising material significantly decreases the coefficient of permeability of soil by filling up pore spaces within the fabric, making it less susceptible to the infiltration of water [70].
Cement has also been used jointly with other additives to improve the geotechnical properties of soil for the intent of construction.Lime is most commonly utilised with cement for stabilisation.A cement and lime mix improves the strength characteristics (angle of resistance and cohesion) of all soil types, even those with low bearing capacity such as peat [71].Researchers have employed other additives with cement for stabilisation so as to yield desirable results while minimising costs of excess cement usage.Through the reduction in soil plasticity and an increase in the California bearing ratio (CBR) for a pavement layer material, cement integrated with rice husk ash (RHA) has been used to enhance soil [72].Cement and calcium carbide-stabilised laterite is recommended for use as base materials for constructing road pavements due to its high strength [73].This is also a way of disposing calcium carbide waste.Further, the addition of fly ash to cement-stabilised clay strengthens the stabilising potential cement has on expansive clay [74].Moreover, shear strength and axial strain are improved by the addition of cement with ethylene vinyl acetate (EVA) to soil [64]; and this has been advanced for improving subgrade materials.Another way of improving subgrade is seen in the use of cement and copper slag.The incorporation of these materials improves the strength of subgrade material used for road embankment construction [75].Palm kernel shells have also been employed with soilcement mix to create a material for construction use [76].More so, studies have shown that a super-plasticiser mixed with cement improves the strength of soil compared to using cement alone [77].Cement is also well known for use in the process of full-depth reclamation for pavement construction [78][79][80].Contaminated soils are also not left out, as cement has proved to be effective in improving these soil conditions [81].
The wide range of cement usage in soil improvement cannot be elaborated enough, as it has proved to be effective in generating construction materials with high strength and durability.However, a significant gap exists in its combination with PW as a means of containing the growing circulation of plastic in the environment.Hence, the need for this study which is geared towards investigating the potentiality of incorporating PW in cementstabilised pavement layers for the purpose of containing this waste material.Studies have shown that different diameters of pulverised waste plastic have been employed for use in soil stabilisation.These include plastic materials passing the following sieve sizes; 12 mm [82], 10 mm [83], 5 mm [84], 4.75 mm [85], 2 mm [86] and 0.425 mm [87].Nevertheless, this research is limited to the use of fine particles (0.075 mm diameter) for pulverised plastic in contrast to previous studies done.Studies have shown that cement is used frequently in combination with materials of fine particle size due to ease of binding, mixing and adequate cementation [88].Additionally, the cement used in this case would principally function as a binder to contain these waste plastic materials in order to prevent the likelihood of microplastics leaching far beneath the soil and contaminating ground water, which can be hazardous to human health and pose a great threat to the ecosystem.
Terrestrial ecosystems can be directly affected by microplastics (primary microplastics) or indirectly (secondary microplastics) [89].Primary microplastics are produced for a variety of uses and commodities, such as cosmetics, medical items, aqueous paints, coatings, adhesives and electronics.Through air deposition, a significant part of primary microplastics infiltrate terrestrial habitats [90].In addition, the usage of sludge on agricultural fields and the dumping of waste materials in landfills all contribute to the primary build-up of microplastic in ecological systems [91].When bigger plastics break down into tiny pieces as a result of ultraviolet (UV) radiation, wind, tillage, bio-activity, chemical and mechanical breakdown, secondary microplastics are formed [92].Multiple sources, such as plastic mulches, greenhouse components, soil additives, irrigation water, municipal solid waste, climate invasions, inappropriate landfill disposal, and littering, all introduce secondary microplastics into terrestrial ecosystems [93][94][95].According to Zhang et al. [96], there is a notable significant interface between the number of years of mulching and the formation of soil microplastic.Furthermore, microplastics can constitute atmospheric inputs to terrestrial ecosystems due to wind transmission over long distances from surfaces such as roadways and landfills [93,97].Tillage, animal activity, such as earthworm ingestion and egestion, or water ingress brought on by digging are all methods by which plastic particles are assimilated into deep soil layers [92,93].Microplastics can be broken down by microbial activity [98], UV radiation [99], physical abrasion [100], thermal oxidation at high temperatures [101] or by reaction with soil colloids [102].Microplastics may age as a result of the cumulative effects of these conditions; nevertheless, each factor behaves differently depending on the season, the location and other circumstances.For example, light irradiation is important during the day but may have little impact at night [103].Furthermore, the aging of microplastics may be affected more by temperature in desert regions in the summer than in polar regions in the winter [103].Microplastics have physical and chemical properties that change with time, including colour, crystalline structure, chemical properties and surface characteristics [102].A number of chemicals, including phthalates, stabilisers, pigments, oligomers and oxygenated compounds (such as phenolic acids, acetophenones, and carboxylated compounds), may permeate into the soil as microplastics deteriorate [103].Microplastics may enter terrestrial food webs, be taken up by terrestrial plants and pollute groundwater as a result of biogenic transport in soil [104].Furthermore, runoff of microplastics could result in the pollution of freshwater ecosystems by ground microplastics [105,106], which will then give rise to marine microplastic contamination [107].
Mehra et al. [108] suggested three main strategies for managing microplastics-namely (1) measures should be taken to reduce the use of needless single-use plastics, such as plastic shopping bags, straws, and water bottles; (2) governments should implement rigorous regulations to ensure the necessity of bolstering waste collection and recycling systems in order to stop these wastes from escaping into the environment and increase recycling rates; (3) new techniques for disassembling plastic into its component parts, which can then be reformed to generate new plastics or other materials, should be explored.However, these smaller units of plastic can also be contained in a composite system for construction such as soil-cement mixture, as in the case of this research; for the main purpose of mitigating the increasing rate of plastic pollution in the environment.
A high percentage of cement (10%) was chosen so as to yield stronger binding forces [73,109].This high amount of cement boosts cementation within the soil-cement-PW mix which holds the plastic waste in place.A situation where the fine particles of the plastic wastes are not well bounded can pose an environmental issue as the seepage of microplastics into groundwater can contaminate ecological systems for a long time.Therefore, the percentage of cement utilised was explored to yield higher bonding of these waste plastics; holding them together and consequently preventing this discharge of microplastics.Cement content of less than 10% is typically recommended for soil-cement stabilisation.Therefore, the use of 10% cement will ensure that plastic waste is contained in a concrete matrix to prevent or minimise the migration of microplastics.It is due to these concepts that this research tends more towards providing a means of containment of plastic wastes rather than an outright stabilisation; taking the well-being of the environment as the key consideration.This technique of containment was also adopted by Genazzini et al. [110], where masonry blocks were used to contain hospital waste ash.This was used to form a new cement-ash composite system for applications in building materials.Plastic waste in itself does not possess the same degree of stabilisation when used as a 'stand-alone' stabiliser compared to when it is used with conventional stabilisers, as this yields better results [111].Treatment with conventional stabilisers (lime and cement) can impact brittleness in the soil over time, leading to the formation of cracks.This behaviour can be countered via the inclusion of plastics to the stabilised mix [111].Generally, the cement addition to the pulverised plastic would help in improving the compressive strength and durability of the natural soil used for construction [1].In summary, plastic waste does not possess any cementitious property.Consequently, the cement content of 10% in the soil-cement mixture will produce an effect that is similar to the soil-cement stabilisation with less than 10% cement content in the matrix.Cracking behaviour can be minimised by the inclusion of plastic waste to the stabilised mix.
An exploratory assessment of the effects of containing PW in cement-stabilised soil as a pavement layer material is presented in this paper.This work is distinctive since, as far as the authors are aware, no peer-reviewed paper in the open literature has discussed the use of cement-stabilised soil as a containment layer for PW in road pavements.It was hypothesised that applying PW in this fashion would considerably reduce the pollution from plastics in the environment, while providing a durable pavement layer.

Materials Preparation
Disturbed samples were procured at a 0.5 m depth from ground at Iju, Ota in Ogun State as shown in Figure 2. The area falls within latitude 6 • 40 50 N and longitude 3 • 8 24 E. The soil is brown in colour, with coarse, medium and fine components.Prior to being put into collection polythene bags and sacks, vegetative components were taken out of the samples.Exploratory geotechnical tests were used to identify the rudimental index qualities of the sample that was acquired.

Materials Preparation
Disturbed samples were procured at a 0.5 m depth from ground at Iju, Ota in Ogun State as shown in Figure 2. The area falls within latitude 6°40′50″ N and longitude 3°8′24″ E. The soil is brown in colour, with coarse, medium and fine components.Prior to being put into collection polythene bags and sacks, vegetative components were taken out of the samples.Exploratory geotechnical tests were used to identify the rudimental index qualities of the sample that was acquired.Portland cement was purchased locally in Ogun State, Nigeria, for this investigation as shown in Figure 3.For the purpose of stabilising the soil containing PW and stopping microplastics from entering subsurface water, cement was added by weight to the samples at 10%.The cement in the soil-cement-PW mix functions as a binder which holds the finer particles of the plastic waste together.The cement bond in the mix serves as a form of containment for the plastic, which prevents it from leaching into groundwater.Portland cement was purchased locally in Ogun State, Nigeria, for this investigation as shown in Figure 3.For the purpose of stabilising the soil containing PW and stopping microplastics from entering subsurface water, cement was added by weight to the samples at 10%.The cement in the soil-cement-PW mix functions as a binder which holds the finer particles of the plastic waste together.The cement bond in the mix serves as a form of containment for the plastic, which prevents it from leaching into groundwater.Bottles made of polyethylene terephthalate (PET) were gathered at Covenant University in Ota, Ogun State, Nigeria.They were melted, solidified and allowed to cool before they were crushed and then passed through a 0.075 mm sieve.The corresponding particle size was then used for this study.

Methods
The geotechnical characteristics of the natural soil were explored in accordance with ASTM standards.The tests conducted include natural moisture content [113], specific gravity [114], sieve analysis [115], Atterberg limits [116], permeability [117], compaction characteristics [118], the California bearing ratio (CBR) [119] and the unconfined compressive strength (UCS) [120].The soil was stabilised with cement at 10%.The cement used has chemical properties as shown in Table 1.PW was then introduced to soil samples that had been combined with cement in a variety of weight-based amounts (2, 5, 10 and 15%).The mixing was done with respect to optimum moisture content.Afterwards, the strength parameters of the samples were determined.The tests employed for the purpose of this study were chosen because majority of the standards [121][122][123] available in tropical Afri- Bottles made of polyethylene terephthalate (PET) were gathered at Covenant University in Ota, Ogun State, Nigeria.They were melted, solidified and allowed to cool before they were crushed and then passed through a 0.075 mm sieve.The corresponding particle size was then used for this study.

Methods
The geotechnical characteristics of the natural soil were explored in accordance with ASTM standards.The tests conducted include natural moisture content [113], specific gravity [114], sieve analysis [115], Atterberg limits [116], permeability [117], compaction characteristics [118], the California bearing ratio (CBR) [119] and the unconfined compressive strength (UCS) [120].The soil was stabilised with cement at 10%.The cement used has chemical properties as shown in Table 1.PW was then introduced to soil samples that had been combined with cement in a variety of weight-based amounts (2, 5, 10 and 15%).The mixing was done with respect to optimum moisture content.Afterwards, the strength parameters of the samples were determined.The tests employed for the purpose of this study were chosen because majority of the standards [121][122][123] available in tropical African countries use these engineering parameters as benchmark for selecting materials for use as sub-grades, sub-bases and road bases [124].The effects of adding PW to cement-stabilised soil as a way of containing these wastes within a road pavement layer were determined.

Geotechnical Properties of Natural Soil
The summary of the geotechnical characteristics of the natural soil is shown in Table 2.The natural soil has a plasticity index of 16.11% and a specific gravity of 2.56.While the Unified Soil Classification System (USCS) describes the soil as well-graded sand (SW), the AASHTO classification system classifies the soil as A-2-6, which designates it as a granular material with 35% or less passing the 0.075 mm sieve.Particle size distribution for the natural soil is illustrated in Figure 4.The Atterberg limits test results shows that the soil particles have a medium plasticity.The optimum moisture content and the maximum dry unit weight of the soil were 19.56% and 17.0 kN/m 3 , respectively.The coefficient of permeability was 1.85 × 10 −3 cm/s which means that it has medium permeability.A CBR of 1.7% was obtained, which is very poor [126].Additionally, the UCS value of the natural soil was 133.0 kPa.
Infrastructures 2022, 7, x FOR PEER REVIEW 10 of 20 particles have a medium plasticity.The optimum moisture content and the maximum dry unit weight of the soil were 19.56% and 17.0 kN/m 3 , respectively.The coefficient of permeability was 1.85 × 10 −3 cm/s which means that it has medium permeability.A CBR of 1.7% was obtained, which is very poor [126].Additionally, the UCS value of the natural soil was 133.0 kPa.

Results and Discussion
The strength parameters of the soil stabilised with 10% cement and modified with plastic waste at 0, 2, 5, 10 and 15% are summarised in Table 3.

Results and Discussion
The strength parameters of the soil stabilised with 10% cement and modified with plastic waste at 0, 2, 5, 10 and 15% are summarised in Table 3.

Compaction Characteristics
The maximum dry unit weight and OMC of the soil increased and decreased, respectively, upon the inclusion of 10% cement without PW.The maximum dry unit weight of the stabilised soil increased with the addition of cement because the specific gravity of cement was higher (3.15 in most cases) than that of natural soil (2.56).The rise in the maximum dry unit weight was also attributed to a decrease in the surface area of the clay fraction of the soil sample arising from the substitution of soil with the cement [73].This increase generally signifies improvement in soil properties [72].A corresponding decrease in OMC was also observed upon cement addition.This may be due to the reduction in porous voids filled by the cement.This condition results in the increase in dry density [76].Additionally, the soil fabric's ability to cement together its component parts improved.Due to this, the stabilised soil volume was reduced, which may also have caused its dry unit weight to increase [81].A decrease in OMC was seen at 2% addition of PW.This might be due to the zero absorption capacity of the plastic for water [127].Then, with the addition of plastic at 5, 10, and 15%, there was an increase that may be caused by an excess of water in the soil matrix that aided the exothermic reaction [128].Yohanna et al. [129] inferred that an increase in the OMC of a soil with plastic content can be as a result of the absorption of moisture by the plastic during the compaction process; thus, as the plastic content was increased, more water was needed to lubricate the soil surface which leads to an increase in OMC.A decrease in the maximum dry unit weight was then observed upon the addition of PW at 2, 5, 10 and 15%.The lightweight nature of plastic in comparison to soil weight can be responsible for this decline [130].The increase in the plastic content in the soil led to the plastic occupying more spaces within the soil fabric that are supposed to be filled with soil in the matrix, therefore creating some voids in the mixture.This brought about a corresponding decrease in dry density [129].The variation of OMC and the maximum dry unit weight with increasing PW content is illustrated in Figure 5.

The California Bearing Ratio (CBR)
The CBR values for plunger penetration of 2.5 mm were used for analysis, with a higher value compared to the penetration at 5 mm.An increase in unsoaked CBR was observed upon the addition of cement.This increase is related to cementitious compounds that form in the soil that has been stabilised with cement, such as calcium silicate hydrates (C-S-H) and calcium aluminate hydrates (C-A-H) [131].Gupta and Kumar [132] inferred that chemical hydration during the reaction between cement and water gives rise to additional materials (C-S-H and C-A-H) that bound particles together and enhances strength.The development of these products occurs during the formulation of crystals after water and cement are mixed together to yield cementation.This process of cementation brings about high strength gain within the soil-cement mix [133].This is an indicator for compacted soil strength and bearing capacity [88], as cement treatment creates strong binding between soil particles, consequently increasing the CBR [68].On the addition of PW at 2, 5, 10 and 15%, a decrease in CBR was observed as shown in Figure 6.This decline can be attributed to soil displacement induced by increase in the plastic content [85].The Nigerian General Specification states that soil with a CBR value greater than or equal to (≥) 80 is suitable as a layer material to be used for subgrade, sub-base or base course.Taking this into account, the samples treated with PW can be employed as road pavement layer materials [121].

The California Bearing Ratio (CBR)
The CBR values for plunger penetration of 2.5 mm were used for analysis, with a higher value compared to the penetration at 5 mm.An increase in unsoaked CBR was observed upon the addition of cement.This increase is related to cementitious compounds that form in the soil that has been stabilised with cement, such as calcium silicate hydrates (C-S-H) and calcium aluminate hydrates (C-A-H) [131].Gupta and Kumar [132] inferred that chemical hydration during the reaction between cement and water gives rise to additional materials (C-S-H and C-A-H) that bound particles together and enhances strength.The development of these products occurs during the formulation of crystals after water and cement are mixed together to yield cementation.This process of cementation brings about high strength gain within the soil-cement mix [133].This is an indicator for compacted soil strength and bearing capacity [88], as cement treatment creates strong binding between soil particles, consequently increasing the CBR [68].On the addition of PW at 2, 5, 10 and 15%, a decrease in CBR was observed as shown in Figure 6.This decline can be attributed to soil displacement induced by increase in the plastic content [85].The Nigerian General Specification states that soil with a CBR value greater than or equal to (≥) 80 is suitable as a layer material to be used for subgrade, sub-base or base course.Taking this into account, the samples treated with PW can be employed as road pavement layer materials [121].

The Unconfined Compressive Strength (UCS)
This test was carried out on all variations of the samples on a 7-day curing period.Cement addition enhanced the compressive strength of the natural soil.This rise is the result of cation exchange and cement product synthesis caused by the reaction of cement with water upon hydration, binding the soil particles together [134].Aparna et al. [88] stated that cement addition to soil leads to the gradual formation of cementitious compounds via the reaction between the cement and some amounts of calcium hydroxide (CaOH) present in the soil.The agglomeration of large size particles within the soil fabric increases the compressive strength of the soil [132].Upon the addition of PW at 2% to the soil-cement mix, it was observed that the UCS decreased.This is due to a reduction in the friction angle and maximum dry density.A further decrease in strength was noticed upon adding PW at 5%.The UCS value stayed constant up until 10%, which was then followed by a decrease upon the addition of PW at 15%.This behaviour is due to the increase in surface area of plastic, which easily gives rise to shear deformation of the soil [85].The changes in values are shown in Figure 7. Furthermore, the presence of PW resulted in the production of weak shear planes that cause the soil to fail under strain [130].

The Unconfined Compressive Strength (UCS)
This test was carried out on all variations of the samples on a 7-day curing period.Cement addition enhanced the compressive strength of the natural soil.This rise is the result of cation exchange and cement product synthesis caused by the reaction of cement with water upon hydration, binding the soil particles together [134].Aparna et al. [88] stated that cement addition to soil leads to the gradual formation of cementitious compounds via the reaction between the cement and some amounts of calcium hydroxide (CaOH) present in the soil.The agglomeration of large size particles within the soil fabric increases the compressive strength of the soil [132].Upon the addition of PW at 2% to the soil-cement mix, it was observed that the UCS decreased.This is due to a reduction in the friction angle and maximum dry density.A further decrease in strength was noticed upon adding PW at 5%.The UCS value stayed constant up until 10%, which was then followed by a decrease upon the addition of PW at 15%.This behaviour is due to the increase in surface area of plastic, which easily gives rise to shear deformation of the soil [85].The changes in values are shown in Figure 7. Furthermore, the presence of PW resulted in the production of weak shear planes that cause the soil to fail under strain [130].
Generally, the improvement in strength characteristics upon the addition of cement is accredited to the reaction product in the mixture of soil and cement [135].Wardani and Muntohar [136] stated that the cement-stabilised soil will produce the main products of tricalcium silicate; and secondary products of calcium silicate hydrates (C-S-H) and calcium aluminate hydrates (C-A-H).These secondary products yield additional cementation agents to strengthen the soil-cement mix by increasing the bond between particles, while the primary products solidify into high-strength additives.Additionally, the inclusion of plastic materials to soil typically weakens soil matrix, especially beyond its optimal proportions [137].This consequently leads to a decrease in soil strength characteristics.The results obtained suggest that the cement-stabilised sample with no amount of PW displayed the highest strength when compared to the cement-stabilised samples with PW.However, the soil with 10% cement and 2% PW has a higher strength when compared to all the soil-cement-PW mixtures; and does not adversely affect the geotechnical properties of the cement-stabilised mix.Generally, the improvement in strength characteristics upon the addition of cement is accredited to the reaction product in the mixture of soil and cement [135].Wardani and Muntohar [136] stated that the cement-stabilised soil will produce the main products of tricalcium silicate; and secondary products of calcium silicate hydrates (C-S-H) and calcium aluminate hydrates (C-A-H).These secondary products yield additional cementation agents to strengthen the soil-cement mix by increasing the bond between particles, while the primary products solidify into high-strength additives.Additionally, the inclusion of plastic materials to soil typically weakens soil matrix, especially beyond its optimal proportions [137].This consequently leads to a decrease in soil strength characteristics.The results obtained suggest that the cement-stabilised sample with no amount of PW displayed the highest strength when compared to the cement-stabilised samples with PW.However, the soil with 10% cement and 2% PW has a higher strength when compared to all the soil-cement-PW mixtures; and does not adversely affect the geotechnical properties of the cement-stabilised mix.
The results in this study are similar to that obtained by Amena and Chakeri [130], where the effect of lime and plastic strips on expansive soil strength properties was studied.It was inferred that adding lime alone to natural soil can enable the soil particles cement together and strengthen the soil.However, PW addition to the stabilised mix inevitably weakens it.This investigation also revealed that PW reduces the dry density of stabilised soils since it is lighter than soil relative to its weight.This trend was observed in the stabilisation of clay using plastic fibre and lime in subgrades [138]; and soil stabilisation with waste fibre and brick kiln dust [82].Both studies attributed the reduction in the maximum dry unit weight and the strength of soil to the inclusion of PW within the stabilised soil fabric.
When the findings of the soil strength properties are compared to the Nigerian General Specification [121], it is clear that the soil with 10% cement and 2% PW has the best strength when compared to the other mix ratios with plastic content, and is more The results in this study are similar to that obtained by Amena and Chakeri [130], where the effect of lime and plastic strips on expansive soil strength properties was studied.It was inferred that adding lime alone to natural soil can enable the soil particles cement together and strengthen the soil.However, PW addition to the stabilised mix inevitably weakens it.This investigation also revealed that PW reduces the dry density of stabilised soils since it is lighter than soil relative to its weight.This trend was observed in the stabilisation of clay using plastic fibre and lime in subgrades [138]; and soil stabilisation with waste fibre and brick kiln dust [82].Both studies attributed the reduction in the maximum dry unit weight and the strength of soil to the inclusion of PW within the stabilised soil fabric.
When the findings of the soil strength properties are compared to the Nigerian General Specification [121], it is clear that the soil with 10% cement and 2% PW has the best strength when compared to the other mix ratios with plastic content, and is more appropriate for use as a material for road pavement layering as it does not adversely affect the geotechnical characteristics of the cement-stabilised soil.Although the cement-stabilised samples modified with PW at 2, 5, 10 and 15% PW meet the CBR requirement for subgrade, sub-base and base course materials, the sample with 10% cement and 2% PW is recommended, with the higher value for bearing capacity.In order to obtain the appropriate strength at a lower cost, additional studies can be performed to examine the inclusion of smaller amounts of cement with varied proportions of PW.

Conclusions
This research was directed towards providing experimental insight into the containment of PW in cement-stabilised soil for utilisation in road pavement construction.The findings can be summarised as follows: i.
The Unified Soil Classification System (USCS) characterises the soil as well-graded sand (SW), while the AASHTO Classification System classifies it as belonging in group A-2-6.ii.The maximum dry unit weight, CBR and UCS increased when cement was applied to natural soil.This is attributed to chemical hydration during the reaction between cement and water, which gives rise to additional materials (C-S-H and C-A-H) that bound particles together and enhance strength.The cementing of soil particles, which played a vital role in enhancing its strength on the addition of cement, may have been activated by the pozzolanic reaction between the cement and soil particles.iii.PW addition to the cement-stabilised mix at 2, 5, 10, and 15% by weight brings about a reduction in soil strength as PW content increased.This is due to a reduction in the friction angle and maximum dry density.The increase in the plastic content in the soil easily gives rise to shear deformation, causing it to fail under strain.iv.The results obtained suggest that the cement-stabilised sample with no amount of PW displayed the highest strength when compared to the cement-stabilised samples with PW.However, the soil with 10% cement and 2% PW has a higher strength when compared to all the soil-cement-PW mixtures; and does not adversely affect the geotechnical properties of the cement-stabilised mix.v.
The various samples with PW are suitable for use as subgrade, sub-base and base course materials, as they meet the strength requirements based on the Nigerian General Specifications for CBR.However, the soil with 10% cement and 2% PW is recommended since it performed better than the other soil-cement-PW mixtures.vi.PW should be added optimally to stabilised soils to prevent a significant loss in durability and strength.
These findings are especially significant since they show the potential to use cementstabilised soil as a binder and containment for PW while also removing pollution from the environment as a result of the worrisome rise in PW pollution in our ecosystem.However, this study did not investigate the leaching of microplastics from the soil-cement-PW layer.Thus, it is recommended that future studies consider a leaching test to determine the amount of microplastics that would leach over the service life of the soil-cement-PW layer.Furthermore, the inclusion of lower amounts of cement with varied percentages of PW may be investigated in further research to obtain the appropriate strength at a lower cost.Additionally, further studies can be carried out to investigate how other cementitious materials can be used in containing PW that is circulating in the environment at an exponential rate.

Figure 2 .
Figure 2. A map showing the location where the soil was obtained [112].

Figure 2 .
Figure 2. A map showing the location where the soil was obtained [112].

Figure 3 .
Figure 3. Portland cement utilised for this study.

Figure 3 .
Figure 3. Portland cement utilised for this study.

Figure 4 .
Figure 4. Particle size distribution for the natural soil.

Figure 4 .
Figure 4. Particle size distribution for the natural soil.

Figure 5 .
Figure 5. Variation of compaction characteristics for cement-stabilised soil with PW content.

Figure 6 .
Figure 6.Variation of CBR for cement-stabilised soil with PW content.

Figure 6 .
Figure 6.Variation of CBR for cement-stabilised soil with PW content.

Figure 7 .
Figure 7. Variation of UCS of cement-stabilised soil with PW content.

Table 2 .
Geotechnical properties of the natural soil.

Table 2 .
Geotechnical properties of the natural soil.

Table 3 .
Effects of PW on the strength parameters of cement-stabilised soil.