Mechanical Property Assessment of Interlocking Plastic Pavers Manufactured from Electronic Industry Waste in Brazil

The estimated production of world electronic waste until 2017 is approximately 6 Gt. Despite this enormous problem, there are no clear regulations regarding the orientation for disposal or treatment of this type of residuals in many countries. There is a federal public policy in Brazil that supports a network of Computer Reconditioning Centers—CRCs. These CRCs train young people and recover or recycle electronic equipment. Through this work, CRCs produce interlocking plastic pavers for application on pavements from recycled electronic industry waste. This article presents the characterization of these interlocking paver’s mechanical properties when applied on the pavement. This characterization is a necessary step to show the effectiveness of this product. We show that the plastic pavers behave similarly to the artifacts manufactured in concrete, thus creating commercial opportunities for this initiative, and contributing to the Brazilian Solid Waste Policy.


Generation of Electronic Waste in the World and Opportunities for the Circular Economy
It has been estimated that until 2017, 8.3 Gt of virgin polymers have been produced, about 75% became waste. Of this waste, in 2015, approximately 9% were recycled, 12% were incinerated, and 79% were accumulated. By 2050, primary waste generation is projected to reach about 25 Gt, with a tendency to stabilize waste disposal to approximately 13 Gt, an increase in incineration to approximately 12 Gt, and an increase in recycling to around 9 Gt [1].
Electronic waste is emerging as a new environmental challenge of the 21st century due to the rapid escalation of the electronic sector and increased consumption of electronic products [2]. Globally, a significant portion of the plastic waste generated ends up in landfills due to limited plastics management. Landfills were recognized as the primary source of plastic losses to the environment [3]. The speed with which products become obsolete further aggravates problems with the environment, which becomes the destination of waste generated and disposed of improperly in most cases. In this sense, urban prospecting techniques can serve to mitigate the negative impact that anthropic products cause on the environment [4].
Each year, approximately 50 million tons of electronic waste are generated worldwide. This electronic waste contains hazardous materials harmful to human health and the environment [5]. There is also a lack of knowledge available to control methods and strategies for handling electronic waste. Moreover, there is no agreement between the reuse, recycling, recovery, and reform industries. However, recycling is the main method for dealing with electronic waste [6]. solid waste and its disposal. The law reinforces the need to conduct research that contributes to reducing environmental impacts caused by the increasing generation of this waste [18]. Thus, it is essential to characterize products from the reuse of these residues. With the current waste generation scenario from the electronics industry, space is being created for new raw materials: WEEE [19]. In this case, recycling is one of the most essential actions to reduce impacts and boost production [20]. In a parallel way, it is very important the construction of an environment propitious to the creation of recycling actions, as discussed by Vieira et al. [21] Within the scope of the Digital Inclusion Policy, the Brazilian Federal Government and partners promote the implementation of CRC's-Computer Reconditioning Centers, responsible for the correct treatment of e-waste, promoting professional qualification for young people in vulnerable social condition, the reconditioning of computers and the environmentally proper disposal of waste [14].
According to the annual report of the ABRIN-Brazilian Association of Recycling and Innovation, 986 t of computer equipment discarded by the Brazilian federal government were processed by the CRC's in 2017 [16], 36% of which consists of CPUs, 4% of notebooks or laptops, 24% of monitors, 10% of printers, 25% of other IT-Information Technology items, and 1% of IT furniture [22]. The CRC "Programando o Futuro" of Valparaíso/GO produces interlocking plastic pavers from housings and plastic components. These pavers can be used for applications on floors, walkways, elevated walkways, and parking. Figure 1 illustrates the pavers' production flow and its application. It is worthy to say that the CRC program processed about 5% of total mass-produced by the federal government [10]. We think that commercial opportunities may be opened up for this action. For each ton of material disposal, based on average market data, for approximately US $0.5 per kg, there is an approximate amount of resources in the order of US $511 thousand in revenue for the CRC, if they operated in the correct commercial disposal and within the requirements of the current legislation [14].
The reuse of the ever-increasing electronic waste as a load in the manufacture of concrete beams can improve structural strength and allow its use in constructing buildings [23]. Other researchers showed that electronic waste's addition provided a It is worthy to say that the CRC program processed about 5% of total mass-produced by the federal government [10]. We think that commercial opportunities may be opened up for this action. For each ton of material disposal, based on average market data, for approximately US $0.5 per kg, there is an approximate amount of resources in the order of US $511 thousand in revenue for the CRC, if they operated in the correct commercial disposal and within the requirements of the current legislation [14].
The reuse of the ever-increasing electronic waste as a load in the manufacture of concrete beams can improve structural strength and allow its use in constructing buildings [23]. Other researchers showed that electronic waste's addition provided a decreasing trend of structural resistance [24]. Assessing the presence of other polymers applica-Recycling 2021, 6, 15 4 of 18 ble in pavers' production, the use of vulcanized rubber residue from unserviceable tires with residual aggregates from the demolition of civil construction and Portland cement was investigated [25].
The insertion of PET-Polyethylene Terephthalate-in concrete alloys for pavements generated a reduction in the concrete's compression strength when comparing the metered specimens with and without the aggregate. In contrast, the water absorption of parts manufactured with PET waste showed higher values than those observed for parts without waste. There are significant environmental advantages compared to traditional parts [26].
Considering the economic importance of reusing e-waste in civil construction, we proposed in the present research the characterization of those interlocking plastic pavers manufactured by the CRC "Programando o Futuro". In Brazil's case, it is typical for the creation of products for civil construction manufactured by using mining or mineral rejects since those are the country's critical economic activities. Characterization of products is a necessary step to define the benefits of recycling [27], as producing interlocking blocks with iron ore [28].
Different from the usual composites used in civil construction, where a substance to strength it is mixed into the concrete matrix, in the present work the interlocking blocks are manufactured exclusively with e-waste and some added charge, as we describe below. This is a new type of material. Thus, this fabrication process lacks the paver's characterization. This is a crucial step to the transition between an idea to a product. Re-use or recycling must show to be economical and effective. As we show in the present paper, the interlocking blocks produced from e-waste are suitable for civil construction. The attributes of interest are defined for application on walkways and parking lots. The results obtained are compared with those of other types of materials typically used in the construction industry, following international standards. This paper is organized as follows. The next section presents the methodology for materials characterization: International Standards have been used and the metrological procedures for the calculations of uncertainties were described. All the essays are specified, and the equipment identified to allow replicability of the results. After that, the essays' results are shown and compared with those obtained for standard pavers produced from concrete, and also under the regulatory or normalized definitions for some countries. Finally, the conclusions and scenarios for future researches are presented.

Materials and Methods
The interlocking plastic pavers studied in this research are produced from a mixture of polymers from computers or electronic equipment with other substances. As we have pointed out above, this manufacture is different for that of reinforcement of concrete blocks. In the transformation/recycling process, 100% of the plastic waste from the component/sub-assembly can be used. These residues, composed of ABS-Acrylonitrile Butadiene Styrene, and PS-PolyStyrene polymers, make up 70% of the main processed load. The remaining 30% of the cargo comprises other polymers or residual materials from the carcasses, such as metallic residues, sawdust, discarded toys, cigarettes, and mineral powder. This 30% load can also contribute to the reuse of non-recyclable waste.
The preferred polymers for the highest percentage of load, ABS and PS, have excellent characteristics such as low density, resistance to high temperatures, good mechanical resistance, high resistance to abrasion, dimensional stability, etc. [29].
The pavers under study have inclusions and pores, which are not expected to modify an interlocking paver's mechanical behavior, as they are small in size compared to the entire material. These inclusions come from metallic materials constituting the housings of computer components or other granular materials added as cargo during production. This residue is also desirable since the manufacture of the interlocked block must be economically viable. The non-treatment of the waste, together with the primary raw material, reduces the cost of the process; that is, even with the presence of inclusions, the To fuse the polymer particles' surface, a procedure known as agglutination is used, which is a technique for compacting and agglomerating polymeric and residual particles previously ground through heating and pseudo plastification of the material [30]. After this, the mixture is brought to constant pressure in a matrix made with the parameters of the block's dimension and shape. In this process, there is a reduction in the compacted material's free surface energy, minimizing the generation of pores and conditioning the stress relief on the surface atoms.
Rigid polymers, like PS, ABS, PC-Polycarbonate, can have high values for elastic modulus, ductility, and yield strength, determining the limits of tensile strength. These mechanical characteristics change with temperature. An increase in temperature produces a reduction in the modulus of elasticity and the limit of tensile strength, with a consequent improvement in ductility. For this control, polymers' melting, and glass transition, temperatures are used as essential parameters [31] for determining the agglutination temperature.
To obtain specimens for essays, 10 interlocking pavers were chosen at random from a batch produced in CRC "Programando o Futuro". The specimens have been produced in dimensions accordingly the Standards. Essays were defined from the materials' predetermined applications: resistance to compression load, surface hardness, medium absorption, medium density, resistance to micro-abrasive wear, and study of surface topography and phase contrast by SPM-Scanning Probe Microscopy. The flowchart of the essays is depicted in Figure 2.
Recycling 2021, 6, x FOR PEER REVIEW 5 of 18 material, reduces the cost of the process; that is, even with the presence of inclusions, the interlocked block must have resistance to the compression load compatible with the values defined in the Standards for the same models of artifacts of concrete. To fuse the polymer particles' surface, a procedure known as agglutination is used, which is a technique for compacting and agglomerating polymeric and residual particles previously ground through heating and pseudo plastification of the material [30]. After this, the mixture is brought to constant pressure in a matrix made with the parameters of the block's dimension and shape. In this process, there is a reduction in the compacted material's free surface energy, minimizing the generation of pores and conditioning the stress relief on the surface atoms.
Rigid polymers, like PS, ABS, PC-Polycarbonate, can have high values for elastic modulus, ductility, and yield strength, determining the limits of tensile strength. These mechanical characteristics change with temperature. An increase in temperature produces a reduction in the modulus of elasticity and the limit of tensile strength, with a consequent improvement in ductility. For this control, polymers' melting, and glass transition, temperatures are used as essential parameters [31] for determining the agglutination temperature.
To obtain specimens for essays, 10 interlocking pavers were chosen at random from a batch produced in CRC "Programando o Futuro". The specimens have been produced in dimensions accordingly the Standards. Essays were defined from the materials' predetermined applications: resistance to compression load, surface hardness, medium absorption, medium density, resistance to micro-abrasive wear, and study of surface topography and phase contrast by SPM-Scanning Probe Microscopy. The flowchart of the essays is depicted in Figure 2.

Manufacture of Interlocking Block
The manufacturing process of interlocking plastic pavers goes through the following steps:  Classification: Materials containing appropriate and preferred waste for recycling are organized;  Separation: The main raw material polymers (PS and ABS) are separated from other materials of the equipment, which might serve as cargo;  Shredding: The separated materials go through the shredding process and are stored in specific quantities for agglutination;  Agglutination: a compaction technique and agglomeration of previously ground particles with pseudo-plasticization [30] at temperatures between 115 °C and 140 °C. In this process, 70% PS or ABS and 30% load are used (which may be sawdust, fabric, other plastic waste, or even small metals aggregated in previously separated housings);  Pressing: Put the agglutinated mass in a specific mold (in the form of an interlocking floor, block, or brick) and start pressing for approximately 1 min, solidifying at room temperature (which is between ~20 °C and 30 °C in Valparaíso/GO).

Manufacture of Interlocking Block
The manufacturing process of interlocking plastic pavers goes through the following steps: • Classification: Materials containing appropriate and preferred waste for recycling are organized; • Separation: The main raw material polymers (PS and ABS) are separated from other materials of the equipment, which might serve as cargo; • Shredding: The separated materials go through the shredding process and are stored in specific quantities for agglutination; • Agglutination: a compaction technique and agglomeration of previously ground particles with pseudo-plasticization [30] at temperatures between 115 • C and 140 • C. In this process, 70% PS or ABS and 30% load are used (which may be sawdust, fabric, other plastic waste, or even small metals aggregated in previously separated housings); • Pressing: Put the agglutinated mass in a specific mold (in the form of an interlocking floor, block, or brick) and start pressing for approximately 1 min, solidifying at room temperature (which is between~20 • C and 30 • C in Valparaíso/GO).

•
Deburring: The mass is cleaned by trimming the burrs generated by the material purged in the compression.

Specimens
Since there are no specific standards for assessing the mechanical strength of interlocking floors made up of e-waste, procedures based on the following standards were adopted: The shape of a specimen and the method used, and the number of tests involved per essay were based on these Standards. The Standards EN ISO 604: 2002 and ASTM D695-02a are equivalent. The number of specimens to be tested depends on the materials' structure. For isotropic materials, at least five specimens from each material sample must be tested. For anisotropic materials, at least ten specimens of each sample should be tested in the perpendicular direction and five samples in the direction parallel to the main axis of the anisotropy [32].
The material produced from the process described above can be considered isotropic because there is no preferred direction in this process. Therefore, 5 interlocking blocks from the batch of 10 were randomly chosen. These were identified by blocks 3, 4, 5, 7, and 8. The specimens made to the mechanical evaluations were prepared by mechanical machining: cutting with a band saw, roughing by milling, and finishing by sanding. Figure 3 shows the steps to obtain the specimens.

Specimens
Since there are no specific standards for assessing the mechanical strength interlocking floors made up of e-waste, procedures based on the following standards w adopted: The shape of a specimen and the method used, and the number of tests involved essay were based on these Standards. The Standards EN ISO 604: 2002 and ASTM D6 02a are equivalent. The number of specimens to be tested depends on the materi structure. For isotropic materials, at least five specimens from each material sample m be tested. For anisotropic materials, at least ten specimens of each sample should be tes in the perpendicular direction and five samples in the direction parallel to the main a of the anisotropy [32].
The material produced from the process described above can be considered isotro because there is no preferred direction in this process. Therefore, 5 interlocking blo from the batch of 10 were randomly chosen. These were identified by blocks 3, 4, 5, 7, a 8. The specimens made to the mechanical evaluations were prepared by mechan machining: cutting with a band saw, roughing by milling, and finishing by sandi Figure 3 shows the steps to obtain the specimens.   To better understand the behavior of the blocks in different environmental conditions common in our country, four additional tests were carried out, classified from "a" to "d", as described below. Five specimens were prepared for each test specification.
In all the essays, the specimen is compressed parallel to its main axis at a constant speed until it breaks, or the tension decreases or when the length reaches a predetermined value [24,30].

Uncertainty Calculation
For all tests, uncertainty calculations were made accordingly to the GUM-Guide to the Expression of Uncertainty in Measurement [33]. The uncertainty calculations considered repeatability in five different specimens since there is no replication of the measurement at the same point because it is a destructive test. The main uncertainty factors are the instrument, the resolution, and the repeatability.
The sources of quantifiable uncertainty are presented in the Ishikawa diagram, as shown in Figure 4. The other possible components of uncertainty are considered nonquantifiable or do not influence the measure.

Evaluation of Resistance to a Compression Load
The tests to evaluate resistance to compression load were carried out at the Fracture Mechanics Laboratory of the Metallurgy Department-Escola de Minas-Universidade Federal de Ouro Preto (DEMET/EM/UFOP), with a servohydraulic testing system from the manufacturer MTS, model 810 Material Test System, Software Station Manager-M15 Flex test 40-2013, 10 × 10 3 kg capacity with a servo valve.
To better understand the behavior of the blocks in different environmental conditions common in our country, four additional tests were carried out, classified from "a" to "d", as described below. Five specimens were prepared for each test specification.
"a": Test at room temperature (which was about 24 °C); "b": Saturation test (24 h of immersion); "c": Hot test (70 °C); "d": Freezing test (0 °C). In all the essays, the specimen is compressed parallel to its main axis at a constant speed until it breaks, or the tension decreases or when the length reaches a predetermined value [24,30].

Uncertainty Calculation
For all tests, uncertainty calculations were made accordingly to the GUM-Guide to the Expression of Uncertainty in Measurement [33]. The uncertainty calculations considered repeatability in five different specimens since there is no replication of the measurement at the same point because it is a destructive test. The main uncertainty factors are the instrument, the resolution, and the repeatability.
The sources of quantifiable uncertainty are presented in the Ishikawa diagram, as shown in Figure 4. The other possible components of uncertainty are considered nonquantifiable or do not influence the measure. Given the above definitions, the uncertainty components' calculation is done in two steps: the repetition of measurements or Type A assessment of standard uncertainty; and uncertainty inherited from the instrument or Type B assessment of standard uncertainty.
As we conclude from the essays, the higher contribution to the uncertainty comes from the repetition of compression strength measurements. This uncertainty contribution will always exist because the material is composed of at least two different polymeric molecules and contains impurities and/or inclusions, which can cause a variation in the behavior in the different conditions. There is a broad interval in the measurements to Given the above definitions, the uncertainty components' calculation is done in two steps: the repetition of measurements or Type A assessment of standard uncertainty; and uncertainty inherited from the instrument or Type B assessment of standard uncertainty.
As we conclude from the essays, the higher contribution to the uncertainty comes from the repetition of compression strength measurements. This uncertainty contribution will always exist because the material is composed of at least two different polymeric molecules and contains impurities and/or inclusions, which can cause a variation in the behavior in the different conditions. There is a broad interval in the measurements to evaluate hot, cold, and saturated conditions. Worthy to say that it is important that the confidence intervals remain under the conditions of block application.
It is important to mention that the same type of approach for calculating the uncertainties was adopted in all the test procedures described below. For space savings, they will not be described here, but are available upon request.

Surface Hardness Assessment
The surface hardness assessment was obtained from a branded pen impact type durometer Time, model TH130, resolution 0.1 HRC. The instrument was provided by the Machining Company Torneamentos Mariana LTDA, Mariana-MG. In this evaluation, only one specimen was used, chosen randomly, repeating 5 measurements at three different points.

Evaluation of Average Water Absorption
To evaluate the average absorption, first, we measure the mass of a dry sample. After this measurement, the specimen is immersed in distilled water for 24 h, and the mass measurement is repeated. The absorption evaluation was calculated in 5 samples with five mass checks each, dry and saturated. These specimens were used in the resistance test to the saturated compression load (test "b" described above). The absorption value is obtained in percentage by the expression given by the ratio between the difference between wet and dry mass [34].
The measurements used an analytical balance: Shimadzu-Model AY220, resolution 0.0001 g, provided by the Laboratory of Polymers and Electronic Properties of Materials LAPPEM/ICEB/UFOP.
The block absorption analysis, since one does not have a proper standard, used the procedures for interlocking concrete blocks. This technique evaluates the increase of mass in a solid specimen with a porous appearance, suggesting water accumulation in the pores, which explains the variation in mass and, consequently, the absorption [35].
In the evaluation of average density, the ratio between the mass and the corresponding volume of the test pieces tested in the evaluation of average absorption was used. The volume was calculated from the Mitutoyo 300 mm universal caliper measurements, resolution 0.05 mm, provided by the Machining Company Torneamentos Mariana LTDA, Mariana-MG.

Evaluation of Resistance to Micro-Abrasive Wear
In the evaluation of resistance to micro-abrasive wear, two specimens were used. In each specimen, 5 tests were carried out; that is, there are 10 wear evaluation points. The tests were performed on equipment developed by the Foundry Laboratory DEMET/EM/UFOP. A Scanning Electron Microscope was used to measure the wear cap-MEV, from the manufacturer TESCAN, model VEGA 3 SEM, of the Laboratory NANOLab EM/UFOP. Wear was assessed by rotating a sphere against a static specimen, with abrasive mud between the sphere and the specimen. The spherical cap-shaped groove has a volume calculated from the sphere's radius and the spherical cap's diameter. Thus, the wear coefficient can be interpreted as the volume of material worn per unit of force and per unit of sliding distance (m 3 /Nm) [36].
After micro-abrasive essays, a study of the wear mechanism was carried out by SEM-Scanning Electron Microscope.

Study of Surface Topography and Phase Contrast with SPM
For the analysis of the microform of the material structure and the combination of the compound's different materials, an analysis of the surface topography was done using topography and phase-contrast images. An AFM-Atomic Force Microscope-was used, from the manufacturer Park Systems, model Park XE7, from the Microscopy Center of Instituto Federal de Minas Gerais-IFMG, Ouro Preto. The mode used in this test was tapping (intermittent contact), because a soft material with energy dissipation favors the distinction between attractive and repulsive regimes for image generation.
The set of techniques allows generating images, where the channels monitored in the tapping mode were topography, error, and NCM Phase in trace and retraction (a round trip of the AFM probe in different images). In the form of peaks and valleys, dimensional information on the surface morphology and phase difference of materials are observed [37].

Results and Discussions
The techniques for evaluating resistance to compression stress, surface hardness, absorption rate, density, and resistance to micro-abrasive wear were used in order to expose blocks produced from WEEE to conditions or application requests: as an interlocking block for pavements, walkways, parking, and walkways.

Resistance to Compression Load
A fragile fracture was observed in all samples. The compression load resistance values have been considered satisfactory when compared to those obtained for interlocking concrete blocks. The samples that presented lesser resistance showed a fracture in portions with some inclusion. As we have discussed above, the material does not treat the separation of aggregate residues. The material under study had a maximum breaking strength limit of approximately 9355 N.
The stress versus strain curves showed features of essays on polymers, with a linear relationship between stress/strain in some interval, which allows the evaluation of Young's module. The value is within the expected parameters for polymers, even for specimens treated at high temperatures, low temperatures, and saturation. As we have described above, five specimens have been tested for each essay. Figure 5 shows the stress-strain results for each essay. Results for saturated specimens, as well those for high temperatures, showed significant dispersion. The essay at room temperature showed lower dispersion, as shown in the uncertainty value presented in Table 1. The average values were considered in the uncertainty calculations for each measurement, as discussed above. The values of average compression strengths and average Young modules with respective estimated uncertainties are expressed in Table 1.
There is a reduction in resistance to compression in the case of the hotter specimen, and a small variation in Young's modulus concerning the other tests. This occurs due to the relative movement of adjoining polymer chains as tension increases, facilitated by reducing secondary bonding forces on a molecular scale. The material becomes softer and more ductile [31].
Comparing the results of the polymeric paver's compression load resistance with those required for concrete pavers, as shown in Table 2, the material has acceptable behavior.
Young's module. The value is within the expected parameters for polymers, even for specimens treated at high temperatures, low temperatures, and saturation. As we have described above, five specimens have been tested for each essay. Figure 5 shows the stressstrain results for each essay. Results for saturated specimens, as well those for high temperatures, showed significant dispersion. The essay at room temperature showed lower dispersion, as shown in the uncertainty value presented in Table 1. Figure 5. Stress x Strain graphs. The results for each test are presented for the four specimens obtained from each block (numbered as 3, 4, 5, 7, and 8, randomly selected as described above). Letters "a", "b", "c", and "d" refers to the different essays.

Surface Hardness
The material under study has high surface hardness because it has ABS in its composition. The evaluation took place at room temperature (~24 • C), and the values are shown in Table 3 below. Each column refers to each essay's three points: at the left, middle, and right parts of the specimen. The three columns at left present the measurements obtained directly, and the three columns at right present the results after corrections, which have been calculated from the calibration certificate. As one can observe, the several values obtained for a specific point are not the same, due to micro deformations on the tested surface, even though it is a non-destructive evaluation. The average surface hardness measurement with respective estimated uncertainty can be expressed as = (51.1 ± 1.0) HRC.
Since the hardness assessments in Portland concrete are currently made by axial compression with a sclerometer obtaining the sclerometric index (MPa), it is not possible to directly compare the results obtained in HRC for this work. Winslow [38] used the ASTM Standard E 18-79 "Rockwell Hardness and Rockwell Superficial Hardness of Metallic Materials", obtaining the concrete's average surface hardness ranging from 45 to 52 HR. Thus, the polymer block surface hardness meets Portland concrete specifications applied on floors, since we have obtained values between 50.1 and 52.1 HRC.

Average Water Absorption
Construction with interlocking blocks requests the existence of space between them, in the resulting application. This gap is necessary to allow rainwater to flow to the soil and be absorbed; the parking lot should not be impermeable. Thus, a necessary feature of pavers is the low absorption of water, allowing it to flow to the soil. For the interlocking blocks produced from e-waste, a low absorption rate was obtained, as shown in Table 4. This low rate indicates conditions for the flow of rainwater, and the construction of parking with these blocks, giving space between them for free movement, settlement, and drainage of water to the soil passing through the gap. The tests showed that the material has properties consistent with light paving, such as parking lots, sidewalks, bike paths, and walkways. The average value of the absorption rate was considered in the measurement of uncertainty calculations. With the respective estimated uncertainties, we have = (0.085 ± 0.004)%.

Average Density
The material under study has a low average density compared to the density of concrete that varies between 2.5 and 3 g/cm 3 , as shown in Table 5. The average density measurement with respective estimated uncertainty can be expressed as = (1.075615 ± 0.000019) g/cm 3 .

Resistance to Micro-Abrasive Wear
A circumferentially shaped cavity was generated, shown in a 35× zoom in Figure 6A. An inclusion is observed in this cavity, as o observed from the 130× zoom, shown in Figure 6B. The wear mechanism is uniform, even in the presence of different materials in the compost. The details on the wear surface and confirming the wear mechanism by scratching are shown in Figure 6C, where micropores can be observed. The scratch wear mechanism was observed, generating micropores. For this test, Aluminum Carbide was used as an abrasive, suitable for evaluating severe wear, resulting in uniformity as detected in Figure 6D. We assume that these micropores allow the penetration of contaminants, which might accelerate the material's degradation.
In the micro-abrasion resistance assessment equipment, the measurement replication was done in the same specimen, but at different points. The analyzes of the resistance to micro-abrasive wear were done in 2 specimens conditioned to loads of 1 N and 3 N, respectively. The evaluation of resistance to micro-abrasive wear showed values adequate to the designed application. Table 6 shows the loss of volume from the dimensions of the wear cavities.  The final results of the average micro-abrasive wear coefficients for the 1 N and 3 N loads with the respective standard uncertainties are: • K with load 1 N = (0.0010 ± 0.0002) m 3 /Nm. • K with load 3 N = (0.0002 ± 0.0002) m 3 /Nm. ABNT, ASTM, and BSEM standards are based on wear depth, even by different tests. Thus, to correlate the methods used, we calculate the respective depths of the spherical caps formed by the wear sphere: • K with load 1 N: 0.48 mm • K with load 3 N: 0.35 mm mechanism was observed, generating micropores. For this test, Aluminum Carbide was used as an abrasive, suitable for evaluating severe wear, resulting in uniformity as detected in Figure 6D. We assume that these micropores allow the penetration of contaminants, which might accelerate the material's degradation. In the micro-abrasion resistance assessment equipment, the measurement replication was done in the same specimen, but at different points. The analyzes of the resistance to By using the same methodology as this project, [36] obtained a wear coefficient K between 9.67 × 10 −13 m 3 /Nm and 19.02 × 10 −13 m 3 /Nm in the evaluation of abrasive wear resistance of grinding bodies produced with white cast iron high chrome. It is a metallic material with an average hardness of 80 HRC. Thus, we assume that the polymer under study has resistance to micro-abrasion equivalent to that expected.

Surface Topographic Analysis and Phase Contrast with SPM-Scanning Probe Microscopy
To analyze the microform of the material structure and the connection between the compound's different materials, an analysis of the surface topography was done using topography and phase-contrast images. Using the AFM-Atomic Force Microscopes technique, with the Force-Tip Sample ratio, topography, error, and phase-contrast images are generated in trace and retraction (round trip of the probe in different images), where it is observed in shape of peaks and valleys dimensional information of surface morphology and phase difference of materials [37].
The mode used in this test was Tapping (Intermittent contact), because the soft material with energy dissipation favors the distinction between attractive and repulsive regimes for image generation. According to [39], AFM can distinguish the different modules of elasticity of the constituent materials even though there is no difference in the sample's topography. This is thanks to the AFM needle that vibrates on the sample and detects the material's ability to absorb the energy of the shock with the needle. As the sample was manufactured from materials already processed, this mode will bring morphological and topographic information after reproducing the specimens' polymers.
It is possible to observe variations in the surface due to "voids", that is, variations in the measurements of the "high" and "low" points. The lower the darker surface (bottom of the "hole"): in this case, black. The higher, the clearer.
The red ruler in Figure 7, highlighted in Figure 7A, represents a depth of approximately 510 nm. The green ruler, represented in the graph of Figure 7A, has a point that stands out for its light color and in the lower left corner a dark color, showing a "very high" point and a "very low" point in approximately 560 nm.
As the probe identifies different materials by the attractive/repulsive action, detecting the material's ability to absorb the energy from the shock of the needle, Figure 8 shows the presence of more than one material in the compound under study, with blue being the largest quantity, the red represents the base for fixing the sample. A reasonable degree of homogeneity of the polymeric matrix under study is observed. As the probe identifies different materials by the attractive/repulsive action, detecting the material's ability to absorb the energy from the shock of the needle, Figure  8 shows the presence of more than one material in the compound under study, with blue being the largest quantity, the red represents the base for fixing the sample. A reasonable degree of homogeneity of the polymeric matrix under study is observed.

Conclusions
Production of electronic waste increases rapidly, and it is necessary the definition of public policies to deal with this. Recycling is one important line of action and recycling industrial residues for the production of basic materials for civil construction is a growing way to use these residuals. To this production be effective and economical, it is necessary for the characterization of those new materials.
In this work, we characterize the mechanical properties of interlocking plastic pavers produced with residues from the electric-electronic industry. These pavers are produced at the Computer Reconditioning Center Programando o Futuro, in the city of Valparaíso/GO. CRC is part of the public policy of the Ministry of Communications, which aims to the recondition equipment, the adequate disposal of e-waste, and education and training of young people in situations of social vulnerability.
The CRC developed a technique to produce pavers from e-waste. As we have discussed in the introduction, this type of action is adherent to other researches that aim to manufacture products for civil construction from the electrical and electronic industry residuals.
Pavers are produced from a mixture of different materials, but their main components-in the order of 70%-are computer housings composed of ABS, PS, and PC. The extra charge of material crushed with cigarettes, CDs, toys, or makeup packs is added. This mixture is heated at temperatures between 115° and 140° and pressed into molds.
Characterization of materials for civil constructions obtained from mineral or steel industries residuals, or even with the re-use of those originally used in the civil construction, is common in the literature. However, since the recycling of polymers

Conclusions
Production of electronic waste increases rapidly, and it is necessary the definition of public policies to deal with this. Recycling is one important line of action and recycling industrial residues for the production of basic materials for civil construction is a growing way to use these residuals. To this production be effective and economical, it is necessary for the characterization of those new materials.
In this work, we characterize the mechanical properties of interlocking plastic pavers produced with residues from the electric-electronic industry. These pavers are produced at the Computer Reconditioning Center Programando o Futuro, in the city of Valparaíso/GO. CRC is part of the public policy of the Ministry of Communications, which aims to the recondition equipment, the adequate disposal of e-waste, and education and training of young people in situations of social vulnerability.
The CRC developed a technique to produce pavers from e-waste. As we have discussed in the introduction, this type of action is adherent to other researches that aim to manufacture products for civil construction from the electrical and electronic industry residuals.
Pavers are produced from a mixture of different materials, but their main componentsin the order of 70%-are computer housings composed of ABS, PS, and PC. The extra charge of material crushed with cigarettes, CDs, toys, or makeup packs is added. This mixture is heated at temperatures between 115 • and 140 • and pressed into molds.
Characterization of materials for civil constructions obtained from mineral or steel industries residuals, or even with the re-use of those originally used in the civil construction, is common in the literature. However, since the recycling of polymers aiming at civil construction is very recent, one needs a description of the basic features of those new materials obtained from e-waste. This is also necessary to support public policies, as well as to define new Standards for these new materials.
Tests of resistance to compression, hardness, absorption, and micro-abrasion were performed. The topographic characteristics of the material were also verified, allowing us to visualize the structural arrangement of its components. From the tests carried out and the estimated uncertainty assessments, it is clear that interlocking plastic pavers manufactured from e-waste behave similar to blocks made from concrete. These evaluations showed that the material has properties consistent with those required for light paving, such as parking lots, sidewalks, bike paths, walkways, and walkways.
Future works and researches should be developed in the definition of Standards for this new type of material, as well as in the development of new methods for their characterization. We believe that this kind of work, mainly in Brazil or other developing countries, which produce tons of non-reused electronic equipment and where recycling of e-waste is a newborn activity, should influence public and private agents to support the creation of new cheap products for diverse applications. It is also necessary to create new essays, describing physical, chemical, and biological features. This type of recycling or reconditioning action contributes to at least two of the Sustainable Development Goals proposed by the UN [40] which must be implemented by all countries in the world by 2030.
Author Contributions: L.T.G.: conceptualization, testing and essays, data curation, investigation, methodology, and writing original draft. R.F.B.: supervision, investigation, writing-review and editing, and methodology. A.T.B.: conceptualization, investigation, formal analysis, methodology, writing-review and editing, and project administration. All authors have read and agreed to the published version of the manuscript.
Funding: This research was carried out with partial funding of the Coordination for the Improvement of Higher Education Personnel-Brazil (CAPES): Financing code 001; Funding from the Brazilian agencies CNPq and Fapemig, and financial support from PROPP-UFOP are also acknowledged.