New Cyanido-Bridged Heterometallic 3d-4f 1D Coordination Polymers: Synthesis, Crystal Structures and Magnetic Properties

: Three new 1D cyanido-bridged 3d-4f coordination polymers, {[Gd(L)(H 2 O) 2 Fe(CN) 6 ] · H 2 O} n ( 1 GdFe ), {[Dy(L)(H 2 O) 2 Fe(CN) 6 ] · 3H 2 O} n ( 2 DyFe ), and {[Dy(L)(H 2 O) 2 Co(CN) 6 ] · H 2 O} n ( 3 DyCo ), were assembled following the building-block approach (L = pentadentate bis -semicarbazone ligand resulting from the condensation reaction between 2,6-diacetyl-pyridine and semicarbazide). The crystal structures consist of crenel-like Ln III -M III alternate chains, with the Ln III ions connected by the hexacyanido metalloligands through two cis cyanido groups. The magnetic properties of the three complexes have been investigated. Field-induced slow relaxation of the magnetization was observed for compounds 2 DyFe and 3 DyCo . Compound 3 DyCo is a new example of chain of Single Ion Magnets.


Introduction
The discovery of slow relaxation of the magnetization phenomena for discrete metal complexes (Single Molecule Magnets, SMMs) and 1D coordination polymers (Single Chain Magnets, SCMs) has stimulated the development of an intensive interdisciplinary research field. Beyond their relevance in fundamental Physics and Chemistry, spectacular applications in quantum computing and high-density information storage from these molecules are expected [1]. Although the field of SMMs was initially dominated by transition metalbased-systems, the focus of research shifted to lanthanides, which increase the energy barriers of SMMs [2,3]. The lanthanide ions (especially Tb III , Dy III , and Ho III ), bring large magnetic moments and high uniaxial magnetic anisotropy, which are essential prerequisites for the observation of slow relaxation of the magnetization. While SMMs can be mono-and oligonuclear (homo-and heteronuclear) complexes, most of the SCMs are constructed from two different spin carriers (e.g., 3d-3d , 3d-4f, 2p-3d, and 2p-4f) [4]. Homospin SCMs are rare and rather serendipitously obtained [5,6]. Examples of lanthanide-based Single-Chain Magnets are also limited, and most of them result from the association of lanthanide ions with nitronyl-nitroxide (paramagnetic) ligands [7,8]. Lanthanide ions can be linked to other paramagnetic metal ions through small bridging ligands, which facilitate the exchange interactions. The building-block approach, relying on the employment of metalloligands, represents an excellent strategy to generate heterometallic coordination compounds [9]. Anionic cyanido complexes are very popular in this respect. The self-assembly processes between [M(CN) 6 ] 3− metalloligands and cationic Ln III complexes led to a rich variety of structural architectures. The assembling complex cations are either solvated Ln III species or heteroleptic complexes, containing chelating ligands and weakly coordinated anions or solvent molecules, which can be easily replaced by the cyanido bridge. The dimensionality of the resulting coordination polymers is dependent on the number of accessible positions at the lanthanide ions. For example, nitrogen donor blocking ligands attached to Ln III ions, such as 1,10-phenanthroline, 2,2 -bipyridine, 2,2 :6 ,2 -terpyridine, 2,4,6-tri(2-pyridyl)-1,3,5-triazine, favor the aggregation of 1D coordination polymers, employing [M(CN) 6 ] 3− as metalloligands [10][11][12][13][14][15][16][17][18]. When the reactions between the lanthanide salts and the hexacyanido building block occur in dimethylformamide (DMF) or dimethyl sulfoxide (DMSO), depending on the experimental conditions, discrete species, 1D, 2D, or even 3D coordination polymers have been obtained [19][20][21][22][23][24]. By decreasing the number of cyanido groups within the metalloligand, the formation of low-dimensionality coordination polymers is favored [25]. Most of these 3d-4f cyanido-bridged complexes show interesting physical properties, mainly magnetic [26][27][28] and optical [29][30][31], and in some cases combined slow magnetic relaxation and light emission were revealed [32,33].

Materials and Physical Measurements
All reagents and solvents for synthesis were commercially purchased and used without any further purification. The bis-semicarbazone ligand L was synthesized according to the method reported in the literature [42].
IR spectra were recorded on a FTIR Bruker Tensor V-37 spectrophotometer (KBr pellets) in the range of 4000−400 cm −1 . Elemental analysis was performed on a EuroEA Elemental Analyzer.
Magnetic Studies: DC magnetic susceptibility data (2-300K) were collected on powdered samples using a SQUID magnetometer (Quantum Design MPMS-XL), applying a magnetic field of 0.1 T. All data were corrected for the contribution of the sample holder and the diamagnetism of the samples estimated from Pascal's constants [43,44]. The field dependence of the magnetization (up to 5 T) was measured between 2.0 and 5.0 K. AC magnetic susceptibility was measured between 2 and 7 K with an oscillating field magnitude of Hac = 3.0 Oe and frequency ranging between 1 and 1488 Hz in presence of a dc field up to Hdc = 4000 Oe. Fitting of the variable parameters and estimation of errors was performed with lsqcurvefit solver in MATLAB, and jacobian matrix was used to generate Scheme 1. The structure of bis-semicarbazone ligand, L.
The new compounds have been characterized by single-crystal X-ray diffraction, and their magnetic properties have been investigated.

Materials and Physical Measurements
All reagents and solvents for synthesis were commercially purchased and used without any further purification. The bis-semicarbazone ligand L was synthesized according to the method reported in the literature [42].
IR spectra were recorded on a FTIR Bruker Tensor V-37 spectrophotometer (KBr pellets) in the range of 4000-400 cm −1 . Elemental analysis was performed on a EuroEA Elemental Analyzer.
Magnetic Studies: DC magnetic susceptibility data (2-300 K) were collected on powdered samples using a SQUID magnetometer (Quantum Design MPMS-XL), applying a magnetic field of 0.1 T. All data were corrected for the contribution of the sample holder and the diamagnetism of the samples estimated from Pascal's constants [43,44]. The field dependence of the magnetization (up to 5 T) was measured between 2.0 and 5.0 K. AC magnetic susceptibility was measured between 2 and 7 K with an oscillating field magnitude of H ac = 3.0 Oe and frequency ranging between 1 and 1488 Hz in presence of a dc field up to H dc = 4000 Oe. Fitting of the variable parameters and estimation of errors was performed with lsqcurvefit solver in MATLAB, and jacobian matrix was used to generate 95% confidence intervals on the fitted parameters. Typical examples of this analysis are presented in Figures S3-S6.
X-ray powder diffraction data were measured on a Proto AXRD benchtop using Cu-Kα radiation with a wavelength of 1.54059 Å in the range of 5-35º (2θ).

Single Crystal X-ray Crystallography
X-ray diffraction data were collected at 293 K on a Rigaku XtaLAB Synergy-S diffractometer operating with Mo-Kα (λ = 0.71073 Å) micro-focus sealed X-ray tube. The structures were solved by direct methods and refined by full-matrix least squares techniques based on F 2 . The non-H atoms were refined with anisotropic displacement parameters. Calculations were performed using SHELX-2014 or SHELX-2018 crystallographic software package [45,46]. Supplementary X-ray crystallographic data in CIF format have been deposited with the CCDC with the following reference numbers: 2069217 (1 GdFe ), 2069215 (2 DyFe ), and 2069216 (3 DyCo ). A summary of the crystallographic data and the structure refinement for crystals 1-3 are given in Table S1.

Synthesis of Complexes
The three compounds are synthesized following the same general procedure: LnCl 3 ·6H 2 O (0.06 mmol) and L (0.06 mmol) in 10 mL H 2 O were stirred at 80 • C for 30 min. The abovecooled solution was filtered and transferred to a 30 mL test tube. Additional 5 mL of water was layered over the aqueous solution of the mononuclear complexes, and finally, a 10 mL H 2 O solution containing 0.06 mmol K 3 [Fe(CN) 6 ] or K 3 [Co(CN) 6 ] was then slowly layered on top. The whole set up was kept undisturbed and slow diffusion of these two solutions led, after 2 weeks, to single crystals. The reaction mixture was mechanically stirred and was filtered off through frit followed by drying under vacuum to obtain a polycrystalline solid. Single crystals required for the X-ray data collections were picked up from the crystalline mixtures prior to mechanical stirring.   6 ] in 1:1 molar ratio. All complexes show C=O and C=N IR absorption peaks in the range of 1654-1657 cm −1 , which indicate the presence of the semicarbazone ligand. The split bands at 2200-2100 cm −1 are assigned to both the monodentate and bridging cyanido groups [47]. The crystalline phase purity of the samples was confirmed by the good agreement between the PXRD patterns and the ones simulated using single-crystal data ( Figure S1). The FTIR spectra are displayed in Figure S2.
Complexes 1 GdFe and 3 DyCo are isostructural, and they crystallize in the orthorhombic space group Pbca with one crystallization water molecule/formula unit. Complex 2 DyFe crystallizes in the monoclinic system, space group P2 1 /c, with three lattice water molecules/formula unit. In all complexes, the metal ions have similar coordination environments, and the topology of the heterometallic chains is identical.
Compounds 1 GdFe and 3 DyCo consist of heterometallic chains with alternating distributions of the 3d and 4f metal ions. Since the two compounds are isostructural, we will describe only the crystal structure of the compound 1 GdFe . The general appearance of the chains is crenel-like, due to the fact that the [Fe(CN) 6 ] 3− metalloligand acts as a bridge trough two cis cyanido groups and the two neighboring connecting [Fe(CN) 6 ] 3− moieties are placed on the same side of the organic ligand coordinated to the lanthanide ion ( Figure 1). One of the two water molecules coordinated to the lanthanide ion is involved in intra-chain hydrogen interaction with a cyanido group from a [Fe(CN) 6 ] 3− metalloligand coordinated to a neighboring lanthanide ion. The chains are running along the crystallographic a axis.
at 2200-2100 cm −1 are assigned to both the monodentate and bridging cyanido groups [47]. The crystalline phase purity of the samples was confirmed by the good agreement between the PXRD patterns and the ones simulated using single-crystal data ( Figure S1). The FTIR spectra are displayed in Figure S2.
Complexes 1GdFe and 3DyCo are isostructural, and they crystallize in the orthorhombic space group Pbca with one crystallization water molecule/formula unit. Complex 2DyFe crystallizes in the monoclinic system, space group P21/c, with three lattice water molecules/formula unit. In all complexes, the metal ions have similar coordination environments, and the topology of the heterometallic chains is identical.
Compounds 1GdFe and 3DyCo consist of heterometallic chains with alternating distributions of the 3d and 4f metal ions. Since the two compounds are isostructural, we will describe only the crystal structure of the compound 1GdFe. The general appearance of the chains is crenel-like, due to the fact that the [Fe(CN)6] 3− metalloligand acts as a bridge trough two cis cyanido groups and the two neighboring connecting [Fe(CN)6] 3− moieties are placed on the same side of the organic ligand coordinated to the lanthanide ion ( Figure  1). One of the two water molecules coordinated to the lanthanide ion is involved in intrachain hydrogen interaction with a cyanido group from a [Fe(CN)6] 3− metalloligand coordinated to a neighboring lanthanide ion. The chains are running along the crystallographic a axis.  (Table S2) [48].
Compound 2DyFe consists also of heterometallic chains running in this case along the crystallographic b axis, and crystallization water molecules. The 1D chains are formed in a similar manner by connecting [Dy(L)(H2O)2] 3+ complex cations by the [Fe(CN)6] 3− metalloligands, which employ two cis cyanido groups for bridging ( Figure 4). The Dy III ion is nine-coordinated by the pentadentate ligand (O1, O2, N3, N4, and N5), two nitrogen atoms arising from the cyanido bridges (N8, N13), and two aqua ligands (O3, O4). The coordination geometry of the dysprosium ion is also spherical capped square antiprism (Table S2). The Dy-N and Dy-O bond lengths are in the range of 2.503(2)-2.553(2) and 2.3298(18)-2.3783(13) Å, respectively. The two Dy-N bond distances (nitrogen atoms arising from the bridging cyanido groups) are Dy1-N8 = 2.556(2) and Dy1 -N13' = 2.533(2) Å (symmetry code: ' = 1 − x, −0.5 + y, 1.5 − z). The Fe III ions show a slightly distorted octahedral geometry with Fe1-C bond lengths ranging from 1.929 (3)    The main differences between crystals 1GdFe and 2DyFe appear in hydrogen interactions established between the supramolecular layers. Compound 2DyFe has two more crystallization water molecules per unit comparing with the crystals 1GdFe and 3DyCo. The O4 coordinated water molecule is also involved as donor in hydrogen interactions with two crystallization water molecules, O5 and O5 i , (Figure 6). Each of these crystallization water molecules is acceptor for two hydrogen interactions with two coordinated water mole- lization water molecules per unit comparing with the crystals 1 GdFe and 3 DyCo . The O4 coordinated water molecule is also involved as donor in hydrogen interactions with two crystallization water molecules, O5 and O5 i , (Figure 6). Each of these crystallization water molecules is acceptor for two hydrogen interactions with two coordinated water molecules from neighboring layers and acts as donor for only one cyanido group (O5 is donor for N11 i atom). The other two crystallization water molecules are involved in hydrogen bonding with one NH 2 group and one cyanido group (O6), respectively, and two cyanido groups  The main differences between crystals 1GdFe and 2DyFe appear in hydrogen interactions established between the supramolecular layers. Compound 2DyFe has two more crystallization water molecules per unit comparing with the crystals 1GdFe and 3DyCo. The O4 coordinated water molecule is also involved as donor in hydrogen interactions with two crystallization water molecules, O5 and O5 i , (Figure 6). Each of these crystallization water molecules is acceptor for two hydrogen interactions with two coordinated water molecules from neighboring layers and acts as donor for only one cyanido group (O5 is donor for N11 i atom). The other two crystallization water molecules are involved in hydrogen bonding with one NH2 group and one cyanido group (O6), respectively, and two cyanido groups ( Table S3.

Magnetic Properties of the Complexes
Static magnetic characterizations. The magnetic susceptibility data for compounds 1-3 were measured on polycrystalline samples in the temperature range of 2-300 K as shown in Figure 7, in the form of χ M T vs. T curves. The observed χ M T values at 300 K for 1 GdFe , 3 DyCo , and 2 DyFe are of 8.265, 15.454, and 16.305 cm 3 mol −1 K, which are slightly higher than the expected values for a non-interacting spin system of one Gd III (7.88 cm 3 mol −1 K, S = 7/2, 8 S 7/5 , g = 2.00), Dy III (14.17 cm 3 mol −1 K, S = 5/2, 6 H 15/2 , g = 4/3) [49], and one low-spin S = 1 2 Fe III ion or one diamagnetic Co III ion [44]. Upon cooling, the χ M T values stay almost constant in the high temperature region, while at low temperatures, the χ M T values show a rapid decrease and reach the values of 6.833, 12.722, and 11.210 cm 3 mol −1 K, respectively, at 2.0 K. In the case of 1 GdFe, the decrease in χ M T with temperature may be associated with Fe III -Gd III antiferromagnetic interactions along the heterometallic alternating chain. The possible presence of intermolecular interactions can also contribute to this decrease. The expected ferrimagnetic behavior (i.e., the characteristic minimum on the χ M T vs. T curve) is not observed, probably due to the small magnitude of the exchange interactions along the chain. The evolution of the temperature dependence of the magnetic susceptibility for 3 DyCo is exclusively defined by the presence of strongly anisotropic Dy III ions, which are isolated by diamagnetic low spin Co III ions. The decrease in χ M T with the temperature is due to the depopulation of M J (Stark) sublevels of the Dy III centers in 3 DyCo [50]. This effect is certainly present in the case of compound 2 DyFe . Additionally, a Fe III -Dy III magnetic coupling along the chain can be expected. In the case of 2 DyFe , the evolution of χ M T shows a more important slope compared to compound 3 DyCo (Figure 7), with a lower value of susceptibility at 2.0 K (11.210 cm 3 mol −1 K). This indicates the presence of some antiferromagnetic impact, which contributes to the observed decreasing χ M T values. For 2 DyFe , the existence of magnetic interactions similar to those in 1 GdFe also suggests the formation of a ferrimagnetic chain, which, associated with strong magnetic anisotropy, could lead to a Single Chain Magnet. Unfortunately, as in the case of 1 GdFe , the increase in χ M T at low temperatures and the characteristic minimum were not detected for 2 DyFe (Figure 7). This behavior is probably due to the very small antiferromagnetic interactions along the chain. The magnetization measurements ( Figure S3) support the presence of an important magnetic anisotropy in 2 DyFe and 3 DyCo . Dynamic magnetic characterizations. Dynamic magnetic properties of the compounds 1GdFe, 2DyFe, and 3DyCo were studied by measuring the temperature and field dependence ac (alternative current) magnetic susceptibility. Compound 1GdFe does not have any manifestation of the out-of-phase component (χ"ac) of the ac magnetic susceptibility at 2 K and zero dc (direct current) field. After applying small dc field (2000 Oe) no modification was observed in χ"ac component of ac susceptibility.
For 3DyCo, no signal was observed under zero dc field at 2.0 K, in χ"ac component of ac susceptibility. After applying of small dc fields (up to 4000 Oe), a frequency dependent out-of-phase signal appears (Figure 8b) and has a rich evolution in function of the field. Such behavior is consistent with presence of strongly anisotropic paramagnetic centers Dy III and indicates the presence of field-induced slow magnetic relaxation. The intensity of the out-of-phase signals gradually increases till about 2000 Oe, and then, it slightly decreases. To investigate the nature of slow magnetic relaxation, additional ac susceptibility data were collected under fixed dc field (2000 Oe) and stable temperatures between 2.0 and 5.0 K (with a 0.2 K increment)- Figure 8d-f. The temperature sweeping of the ac susceptibility shows the important evolution of the χ"ac component and supports the presence of field-induced slow magnetic relaxation in 3DyCo. Since the Co III ion is diamagnetic, Dynamic magnetic characterizations. Dynamic magnetic properties of the compounds 1 GdFe , 2 DyFe , and 3 DyCo were studied by measuring the temperature and field dependence ac (alternative current) magnetic susceptibility. Compound 1 GdFe does not have any manifestation of the out-of-phase component (χ ac ) of the ac magnetic susceptibility at 2 K and zero dc (direct current) field. After applying small dc field (2000 Oe) no modification was observed in χ ac component of ac susceptibility.
For 3 DyCo , no signal was observed under zero dc field at 2.0 K, in χ ac component of ac susceptibility. After applying of small dc fields (up to 4000 Oe), a frequency dependent outof-phase signal appears (Figure 8b) and has a rich evolution in function of the field. Such behavior is consistent with presence of strongly anisotropic paramagnetic centers Dy III and indicates the presence of field-induced slow magnetic relaxation. The intensity of the out-of-phase signals gradually increases till about 2000 Oe, and then, it slightly decreases. To investigate the nature of slow magnetic relaxation, additional ac susceptibility data were collected under fixed dc field (2000 Oe) and stable temperatures between 2.0 and 5.0 K (with a 0.2 K increment)-Figure 8d-f. The temperature sweeping of the ac susceptibility shows the important evolution of the χ ac component and supports the presence of field-induced slow magnetic relaxation in 3 DyCo . Since the Co III ion is diamagnetic, compound 3 DyCo can be described as being a chain of Single Ion Magnets.
Magnetochemistry 2021, 7, x FOR PEER REVIEW 10 of 15 (χs) (see Equations (S1) and (S2)). The deconvolution of two relaxations process is presented in Figure S4, Figure S5, Figure S6, and Figure S7. Variable parameters derived from the best fits of the ac susceptibility are shown in Figure S9 and Figure S10 and Figure S11 and Figure S12. In both compounds, the first relaxation process LF (Low Frequency) is well defined, while the second HF (High Frequency) process has large errors on the variable parameters. The distributions of relaxation times for the LF process are rather broad (α1 = 0.3 ÷ 0.5). The extracted temperature and field dependence of relaxation times for 2DyFe and 3DyCo can be modulated based on four relaxation mechanisms according to the following equation [54][55][56][57][58]: The first term represents the Quantum Tunneling of Magnetization (QTM), the second term corresponds to Orbach, the third to Direct, and the last one to Raman process; moreover, H = applied dc magnetic field and T = temperature. In order to constrain the variable parameters and avoid the overparameterization problem, temperature and field dependence of relaxation times were fitted simultaneously [56] (vector of data: τ −1 in s −1 , T in Kelvin, and H in kOe). Only LF signals will be discussed below, as the second process (HF) is poorly defined. Different combinations of the four mechanisms of relaxation have been used in order to simulate the evolution of the relaxation times. For the LF signals, with both compounds, the contribution of Quantum Tunneling of Magnetization (QTM) is indispensable to simulate the relaxation data. The continuous decreasing trend of τ −1 vs. applied field (H) excludes the presence of significant contribution of Direct relaxation A similar strategy of measurements was used in the dynamic analysis of 2 DyFe . As in the case of 3 DyCo , at T = 2.0 K and zero dc field, no signal was detected in the out-ofphase component of the ac susceptibility. The signals appear when a small magnetic dc field was applied and has similar evolutions as in the case of 3 DyCo (Figure S8a-c). A dc field of 3000 Oe was used to perform the temperature sweeping measurements of the ac susceptibility in the case of 2 DyFe (Figure S8d-f).
For both compounds (2 DyFe and 3 DyCo ), the visual analysis of the out-of-phase susceptibilities, as well of the χ ac vs. χ ac plots (Cole-Cole plots), suggests the presence of at least two distinct relaxation processes. In consequence, the ac susceptibility data (field sweeping and temperature sweeping measurements) for 3 DyCo and 2 DyFe were evaluated with generalized (extended) Debye equations combining two-relaxation processes [51][52][53]. The two relaxation times (τ 1 , and τ 2 ,) and two distribution parameters (α 1 , and α 2 ) occur along with two isothermal susceptibilities (χ T1 and χ T2 ) and one common adiabatic susceptibility (χ s ) (see Equations (S1) and (S2)). The deconvolution of two relaxations process is presented in Figures S4-S7. Variable parameters derived from the best fits of the ac susceptibility are shown in Figures S9-S12.
In both compounds, the first relaxation process LF (Low Frequency) is well defined, while the second HF (High Frequency) process has large errors on the variable parameters. The distributions of relaxation times for the LF process are rather broad (α 1 = 0.3 ÷ 0.5). The extracted temperature and field dependence of relaxation times for 2 DyFe and 3 DyCo can be modulated based on four relaxation mechanisms according to the following equation [54][55][56][57][58]: The first term represents the Quantum Tunneling of Magnetization (QTM), the second term corresponds to Orbach, the third to Direct, and the last one to Raman process; moreover, H = applied dc magnetic field and T = temperature. In order to constrain the variable parameters and avoid the overparameterization problem, temperature and field dependence of relaxation times were fitted simultaneously [56] (vector of data: τ −1 in s −1 , T in Kelvin, and H in kOe). Only LF signals will be discussed below, as the second process (HF) is poorly defined. Different combinations of the four mechanisms of relaxation have been used in order to simulate the evolution of the relaxation times. For the LF signals, with both compounds, the contribution of Quantum Tunneling of Magnetization (QTM) is indispensable to simulate the relaxation data. The continuous decreasing trend of τ −1 vs. applied field (H) excludes the presence of significant contribution of Direct relaxation mechanism. The other contributions in relaxation times can be Raman and/or Orbach, which have the same increasing evolutions with temperature variation [57]. In this restricted range of temperature, it is difficult to separate these two components. In order to have some information regarding the manifestation of these mechanisms, the comparative fits on the temperature dependence of relaxation time for 2 DyFe and 3 DyCo have been done (Figures S13-S15). Both mechanisms can reproduce the time of evolution. The quality of the Orbach mechanism is slightly better. It should be mention here that the distribution parameters (α) have important impact on uncertainties relaxation time [59] and can also be an argument in favor of one or another mechanism. The analysis presented in Figures S13-S15 shows the similarity in uncertainties of relaxation times for both mechanisms. Based on this argument and a low temperature range (2-4 K) of relaxation data for 3 DyCo and 2 DyFe , as well the traditional representation of relaxation phenomena in SMM, our analysis of LF relaxation process is limited to two contributions: QTM and Orbach. The best fit for LF relaxation processes based on the two mechanisms has been obtained for the following sets of parameters: 3 DyCo : U eff /k = 7.1 K; τ 0 = 7.5 × 10 −5 s; Q 1 = 121 s −1 ; Q 2 = 1.05 kOe −2 2 DyFe : U eff /k = 10.8 K; τ 0 = 5.9 × 10 −4 s; Q 1 = 200 s −1 ; Q 2 = 0.05 kOe −2 .
The obtained relaxation parameters are similar for compounds 2 DyFe and 3 DyCo . Due to the diamagnetic Co III ions in 3 DyCo , the slow magnetic relaxation is solely associated with the anisotropic Dy III ions. The existence of intrachain magnetic interaction in 2 DyFe does not change significantly the energy barrier of slow relaxation of the magnetization (see the temperature dependence in Figure 9), but affects more the field dependence, which becomes much more redistributed. This probably can be associated to redistribution/mixing the different energy levels in the 2 DyFe as a result of the small antiferromagnetic interaction along the chain and of intermolecular (interchain) interaction. The splitting of M J (Stark) sublevels of the Dy III centers under variation of the magnetic field also contributes to this redistribution. As in the case of static magnetic measurements, these competitive interactions cannot be quantified at the reported range of temperatures.
In a recent paper, Ma et al. report on a family of discrete, tetranuclear 3d-4f complexes assembled from a cationic lanthanide complexes and [M(CN) 6 ] 3− metalloligands (M = Fe, Co), the ligand attached to the lanthanide(III) ions (Tb, Dy, and Ho) being also pentadentate [60]. The field-induced slow relaxation of the magnetization, with a low energy barrier (11.17 K), was observed only with the [Dy 2 Co 2 ] derivative. The presence of the paramagnetic Fe III ion does not improve the SMM behavior: for the [Dy 2 Fe 2 ] derivative, the slow relaxation is not observed even by applying dc fields.

Conclusions
In this paper, we have shown that the pentadentate bis-semicarbazone ligand, L, generates robust cationic Ln III complexes, which are useful modules for constructing heterometallic coordination polymers. The metalloligands, [M(CN)6] 3− , employ two cis cyanido groups as bridges against the Ln III ions, resulting in a wave-like chain topology for the three compounds. The investigation of the magnetic properties reveals that the two Dy IIIcontaining coordination polymers exhibit slow relaxation of the magnetization, with rather low energy barriers. From the magnetic point of view, compound 3DyCo behaves like a chain of Single Ion Magnets. These results open interesting perspectives for the synthesis of new cyanido-bridged 3d-4f complexes, using not only homoleptic but also heteroleptic cyanido tectons, as well as other types of metalloligands. Further work is in progress in our laboratory.
Supplementary Materials: crystallographic data (single crystal and PXRD), bond distances and angles, infrared spectra; magnetic data; treatment of the ac magnetic data.

Conflicts of Interest:
The authors declare no conflicts of interest."

Conclusions
In this paper, we have shown that the pentadentate bis-semicarbazone ligand, L, generates robust cationic Ln III complexes, which are useful modules for constructing heterometallic coordination polymers. The metalloligands, [M(CN) 6 ] 3− , employ two cis cyanido groups as bridges against the Ln III ions, resulting in a wave-like chain topology for the three compounds. The investigation of the magnetic properties reveals that the two Dy III -containing coordination polymers exhibit slow relaxation of the magnetization, with rather low energy barriers. From the magnetic point of view, compound 3 DyCo behaves like a chain of Single Ion Magnets. These results open interesting perspectives for the synthesis of new cyanidobridged 3d-4f complexes, using not only homoleptic but also heteroleptic cyanido tectons, as well as other types of metalloligands. Further work is in progress in our laboratory.

Supplementary Materials:
The following are available online at https://www.mdpi.com/article/10 .3390/magnetochemistry7050057/s1, Crystallographic data (single crystal and PXRD), bond distances and angles, infrared spectra; magnetic data; treatment of the ac magnetic data.