Temperature-Dependent Enhancement Effects for TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene) with 2-Methylimidazole-Intercalated α-Zirconium Phosphate as a Latent Thermal Initiator in the Reaction of Glycidyl Phenyl Ether
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental Section
3.1. Materials
3.2. Measurements
3.3. Typical Polymerization Procedure
3.4. Polymerization Procedure for Recovery of α-ZrP·2MIm (α-ZrP·2MIm-T-RXN) after the Reaction
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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After Reaction of Initiator | Temperature/°C | Deintercalation Ratio% | Composition |
---|---|---|---|
α-ZrP·2MIm-RXN | 100 | 4 | Zr(HPO4)2·0.91C4H6N2∙0.07C9H10O2 |
120 | 74 | Zr(HPO4)2∙0.25C4H6N2∙2.73C9H10O2 | |
α-ZrP·2MIm-T-RXN | 100 | 9 | Zr(HPO4)2∙0.86C4H6N2∙0.25C9H10O2 |
120 | 57 | Zr(HPO4)2∙0.41C4H6N2∙2.27C9H10O2 |
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Shimomura, O.; Sasaki, S.; Kume, K.; Ohtaka, A.; Nomura, R. Temperature-Dependent Enhancement Effects for TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene) with 2-Methylimidazole-Intercalated α-Zirconium Phosphate as a Latent Thermal Initiator in the Reaction of Glycidyl Phenyl Ether. Inorganics 2019, 7, 83. https://doi.org/10.3390/inorganics7070083
Shimomura O, Sasaki S, Kume K, Ohtaka A, Nomura R. Temperature-Dependent Enhancement Effects for TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene) with 2-Methylimidazole-Intercalated α-Zirconium Phosphate as a Latent Thermal Initiator in the Reaction of Glycidyl Phenyl Ether. Inorganics. 2019; 7(7):83. https://doi.org/10.3390/inorganics7070083
Chicago/Turabian StyleShimomura, Osamu, Suguru Sasaki, Kaori Kume, Atsushi Ohtaka, and Ryôki Nomura. 2019. "Temperature-Dependent Enhancement Effects for TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene) with 2-Methylimidazole-Intercalated α-Zirconium Phosphate as a Latent Thermal Initiator in the Reaction of Glycidyl Phenyl Ether" Inorganics 7, no. 7: 83. https://doi.org/10.3390/inorganics7070083