Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit
1
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
2
Graduate School of Natural Sciences, Nagoya City University, Yamanohata 1, Mizuho-cho, Mizuho-ku, Nagoya, Aichi 467-8501, Japan
*
Author to whom correspondence should be addressed.
Inorganics 2017, 5(4), 79; https://doi.org/10.3390/inorganics5040079
Received: 21 October 2017 / Revised: 8 November 2017 / Accepted: 10 November 2017 / Published: 14 November 2017
(This article belongs to the Special Issue Coordination Chemistry of Silicon)
Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1,2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a halogenated oligometallane, a bis(chlorogermyl)dichlorosilane derivative.
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Keywords:
Si–Cl activation; germylene; digermene; digermacyclobutadiene
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MDPI and ACS Style
Sugahara, T.; Tokitoh, N.; Sasamori, T. Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit. Inorganics 2017, 5, 79. https://doi.org/10.3390/inorganics5040079
AMA Style
Sugahara T, Tokitoh N, Sasamori T. Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit. Inorganics. 2017; 5(4):79. https://doi.org/10.3390/inorganics5040079
Chicago/Turabian StyleSugahara, Tomohiro; Tokitoh, Norihiro; Sasamori, Takahiro. 2017. "Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit" Inorganics 5, no. 4: 79. https://doi.org/10.3390/inorganics5040079
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