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Inorganics 2017, 5(4), 79; https://doi.org/10.3390/inorganics5040079

Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit

1
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
2
Graduate School of Natural Sciences, Nagoya City University, Yamanohata 1, Mizuho-cho, Mizuho-ku, Nagoya, Aichi 467-8501, Japan
*
Author to whom correspondence should be addressed.
Received: 21 October 2017 / Revised: 8 November 2017 / Accepted: 10 November 2017 / Published: 14 November 2017
(This article belongs to the Special Issue Coordination Chemistry of Silicon)
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Abstract

Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1,2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a halogenated oligometallane, a bis(chlorogermyl)dichlorosilane derivative. View Full-Text
Keywords: Si–Cl activation; germylene; digermene; digermacyclobutadiene Si–Cl activation; germylene; digermene; digermacyclobutadiene
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Sugahara, T.; Tokitoh, N.; Sasamori, T. Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit. Inorganics 2017, 5, 79.

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