P-Fluorous Phosphines as Electron-Poor/Fluorous Hybrid Functional Ligands for Precious Metal Catalysts: Synthesis of Rh(I), Ir(I), Pt(II), and Au(I) Complexes Bearing P-Fluorous Phosphine Ligands
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. General Comments
3.2. Synthesis of P-Perfluoroalkylated Phosphine Complex with Pt(II)
3.3. Synthesis of P-Perfluoroalkylated Phosphine Complex with Rh(I)
3.4. Synthesis of P-Perfluoroalkylated Phosphine Complex with Ir(I)
3.5. Hydrosilylation Reaction Catalyzed by Iridium Complex (4a)
3.6. Synthesis of P-Perfluoroalkylated Phosphine Complex with Au(I)
3.7. Au Complex-Catalyzed Addition Reaction of 2-Chloroethanol to 1-Octene
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Entry | RhCl(CO)(PR3)2 | ν(CO) (cm−1) |
---|---|---|
1 | RhCl(CO)(Ph2PnC10F21)2 | 2010 |
2 | RhCl(CO)(nBu2PnC10F21)2 | 1987 |
3 | RhCl(CO)(PPh3)2 | 1967 |
4 | RhCl(CO)(P(4-CF3C6H4)3)2 | 1990 |
5 | RhCl(CO)(P(C6F5)3)2 | 2008 |
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Kawaguchi, S.-i.; Saga, Y.; Sato, Y.; Minamida, Y.; Nomoto, A.; Ogawa, A. P-Fluorous Phosphines as Electron-Poor/Fluorous Hybrid Functional Ligands for Precious Metal Catalysts: Synthesis of Rh(I), Ir(I), Pt(II), and Au(I) Complexes Bearing P-Fluorous Phosphine Ligands. Inorganics 2017, 5, 5. https://doi.org/10.3390/inorganics5010005
Kawaguchi S-i, Saga Y, Sato Y, Minamida Y, Nomoto A, Ogawa A. P-Fluorous Phosphines as Electron-Poor/Fluorous Hybrid Functional Ligands for Precious Metal Catalysts: Synthesis of Rh(I), Ir(I), Pt(II), and Au(I) Complexes Bearing P-Fluorous Phosphine Ligands. Inorganics. 2017; 5(1):5. https://doi.org/10.3390/inorganics5010005
Chicago/Turabian StyleKawaguchi, Shin-ichi, Yuta Saga, Yuki Sato, Yoshiaki Minamida, Akihiro Nomoto, and Akiya Ogawa. 2017. "P-Fluorous Phosphines as Electron-Poor/Fluorous Hybrid Functional Ligands for Precious Metal Catalysts: Synthesis of Rh(I), Ir(I), Pt(II), and Au(I) Complexes Bearing P-Fluorous Phosphine Ligands" Inorganics 5, no. 1: 5. https://doi.org/10.3390/inorganics5010005