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Article

AgBr and Ag3PO4 Coupled with TiO2 as Active Powder Photocatalysts and Glass Coatings

1
Grupo de Catálisis, Universidad Pedagógica y Tecnológica de Colombia UPTC, Avenida Central del Norte, Tunja 150002, Boyacá, Colombia
2
Grupo de Investigación Agroalimentaria GIA, Escuela de Ciencias Básicas Tecnología e Ingeniería, Universidad Nacional Abierta y a Distancia UNAD, Sogamoso 152217, Boyacá, Colombia
3
Instituto de Ciencias Agro-alimentarias, Animales y Ambientales (ICA3), Campus Colchagua, Universidad de O’Higgins, San Fernando 2840440, Chile
4
Instituto de Ciencia de Materiales de Sevilla (ICMS), Centro Mixto CSIC–Universidad de Sevilla, Américo Vespucio 49, 41092 Seville, Spain
5
Grupo de Investigación de Farmacia y Medio Ambiente (FARQUIMA), Universidad Pedagógica y Tecnológica de Colombia UPTC, Avenida Central del Norte, Tunja 150003, Boyacá, Colombia
*
Authors to whom correspondence should be addressed.
Inorganics 2025, 13(12), 381; https://doi.org/10.3390/inorganics13120381 (registering DOI)
Submission received: 27 October 2025 / Revised: 18 November 2025 / Accepted: 21 November 2025 / Published: 23 November 2025
(This article belongs to the Special Issue Metal-Based Photocatalysts: From Synthesis to Applications)

Abstract

In this work, different materials based on TiO2 coupled with either AgBr or Ag3PO4 were synthesized. The Ag3PO4(50%)/TiO2 powder photocatalyst prepared by deposition–precipitation method showed higher antimicrobial activity than the bare TiO2 and also than the same coupled powder obtained by sol–gel method. This material achieved 100% E. coli, coliforms, and other enterobacteria elimination. The high bactericidal efficiency of this material could be attributed to the improved properties obtained by coupling Ag3PO4 and TiO2, such as high absorption in the visible region, low band-gap value, and high surface hydroxylation. The sol–gel method was chosen for the production of photocatalytic coatings on borosilicate glass tubes based on TiO2 and Ag3PO4/TiO2 materials due to the ease of its preparation procedure and its suitability for dip coating. In this series, the most effective elimination of E. coli, coliforms, and other enterobacteria was achieved with the glass tubes coated with the laboratory–prepared TiO2 sol. Interestingly, this material presented superior antimicrobial performance as coating (100% of E. coli elimination) compared to its powder form. The titania coating also showed the best efficiency in the degradation of methylene blue (i.e., 95.2%), though this material lost 30% of its photoactivity after four reaction cycles.
Keywords: AgBr; Ag3PO4; TiO2; dip coating; glass tubes; antimicrobial coatings AgBr; Ag3PO4; TiO2; dip coating; glass tubes; antimicrobial coatings
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MDPI and ACS Style

Murcia, J.J.; Marín-Polanco, P.; Hernández-Laverde, M.; Puga, F.; Navío, J.A.; Hidalgo, M.C.; Brijaldo, M. AgBr and Ag3PO4 Coupled with TiO2 as Active Powder Photocatalysts and Glass Coatings. Inorganics 2025, 13, 381. https://doi.org/10.3390/inorganics13120381

AMA Style

Murcia JJ, Marín-Polanco P, Hernández-Laverde M, Puga F, Navío JA, Hidalgo MC, Brijaldo M. AgBr and Ag3PO4 Coupled with TiO2 as Active Powder Photocatalysts and Glass Coatings. Inorganics. 2025; 13(12):381. https://doi.org/10.3390/inorganics13120381

Chicago/Turabian Style

Murcia, J. J., P. Marín-Polanco, M. Hernández-Laverde, F. Puga, J. A. Navío, M. C. Hidalgo, and M. Brijaldo. 2025. "AgBr and Ag3PO4 Coupled with TiO2 as Active Powder Photocatalysts and Glass Coatings" Inorganics 13, no. 12: 381. https://doi.org/10.3390/inorganics13120381

APA Style

Murcia, J. J., Marín-Polanco, P., Hernández-Laverde, M., Puga, F., Navío, J. A., Hidalgo, M. C., & Brijaldo, M. (2025). AgBr and Ag3PO4 Coupled with TiO2 as Active Powder Photocatalysts and Glass Coatings. Inorganics, 13(12), 381. https://doi.org/10.3390/inorganics13120381

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