Photonic Crystal Fiber Sensor for Detecting Sulfuric Acid in Different Concentrations

: A high-performance photonic crystal fiber sensor for sulfuric acid detection is designed and investigated, undertaken through a full vector Finite Element Method on COMSOL Multiphysics software to establish the optical properties of effective refractive index, power fraction, relative sensitivity, confinement loss, chromatic dispersion, and propagation constant. Different aqueous sulfuric acid concentrations of 0%, 10%, 20%, 30%, and 40% were selected as the test analytes. The dimensions of two cladding rings of the hexagon-and circular-shaped air holes and a circular core hole denoted outstanding outcomes of relative sensitivity and confinement loss. At 1.1 µm optimum wavelength, 0%, 10%, 20%, 30%, and 40% sulfuric acid concentrations depict relative sensitivities of 97.08%, 97.67%, 98.06%, 98.39%, and 98.67%, respectively, and confinement losses of 1.32 × 10 −12 dB/m, 4.11 × 10 −12 dB/m, 1.46 × 10 −12 dB/m, 6.34 × 10 −12 dB/m, and 2.12 × 10 −12 dB/m, respectively.


Introduction
Photonic Crystal Fibers (PCFs) are novel technology of optical fibers featuring a periodic array of air gaps or holes on the axis of the fiber and correspond to its vast recognition in the optics field [1][2][3].The structure of the PCF includes the core and cladding, which can be altered with the utilization of countless shapes and designs [4].In recent years, the flexibility of PCFs has been enthusiastically investigated by researchers to be proposed and implemented in various applications, mainly as sensors [5].It has been introduced in numerous sensing applications such as gas, temperature, pressure, chemical, and liquid sensors [6][7][8][9][10][11][12].
Sulfuric acid is a colorless and odorless aqueous solution with a molar mass of 98.1 g/mol and a density of 1.83 g/cm 3 .Sulfuric acid is the most adopted chemical employed in the industrial sector for its application in diverse areas of science and technology corresponding to its use in fertilizer production, batteries, mineral dissolution and processing, and manufacturing resins [13,14].As sulfuric acid has a high density and its nature is to corrode, it must be diluted to specific concentrations to accommodate the desired results [14].Moreover, this chemical has impacted the climate and environment through acid rain.Thus, a chemical sensor for sulfuric acid detection is needed.
Few researchers have suggested PCFs for chemical sensing, such as a group of researchers [15] who presented an analyte-infiltrated PCF sensor consisting of 9 circular core holes and 36 cladding air holes in three layers, operating within the infrared region (1.0 µm to 1.7 µm).At the optimal wavelength of 1.33 µm, the PCF sensor assessed relative sensitivity of 55.56% and other optical properties of V-Parameter, spot size, beam divergence, and nonlinearity.Podder et al. [16] suggested a PCF sensor design with three rings of cladding and an elaborative array of elliptical holes as the core with sulfuric acid of different concentrations as the test analyte.The complex core PCF sensor evaluated optical properties of birefringence, power fraction, relative sensitivity, confinement loss, and effective area.At its optimum wavelength and concentration, the chemical sensor assessed relative sensitivity of 62.1% and confinement loss of order 10 -15 dB/m.Caroline et al. [17] introduced a PCF sensor for sulfuric acid detection, which obtained 68.5% relative sensitivity and estimated 10 −3 dB/m for confinement loss.The fiber design consists of a complex core design of 16 circular and single rectangular hollow holes to be infiltrated with sulfuric acid and three rings cladding air holes.It also measured results of birefringence and effective area.Another group of researchers [18] proposed a PCF sensor with a suggested structure of three elliptical core holes and three layers of cladding air holes, evaluating performances of relative sensitivity, confinement loss, chromatic dispersion, effective area, and nonlinear coefficient.The hexagonal lattice sensor exhibits confinement loss of order 10 −10 dB/m and a relative sensitivity of 74.5%, at 1.3 µm operating wavelength.Then, a hexagonal lattice PCF sensor of five cladding rings and a hexagon core hole has been proposed by Eid et al. [19] for chemical sensing exhibiting outstanding results for relative sensitivity of 97.89% and order of 10 −10 dB/m for confinement loss.Additionally, other optical parameters of numerical aperture and nonlinearity were assessed to analyze its performance.
In the literature [15][16][17][18][19], the researchers have suggested elaborate designs that pose fabrication difficulties.These designs contain numerous core holes and larger layers of cladding air holes, which is susceptible to manufacturing errors.Hence, a simple design is needed to facilitate the ease of fabrication.In this research study, the proposed structure consists of 18 cladding air holes and a single hollow circular core hole to be infiltrated with a sulfuric acid analyte of different concentrations for detection.The design of a photonic crystal fiber chemical sensor is manipulated to assess remarkable results of relative sensitivity, confinement loss, chromatic dispersion, and propagation constant.With the variations in operating wavelength from 0.8 µm to 1.8 µm, the performance of the proposed PCF sensor has been studied carefully.At the optimum wavelength, it deduced relative sensitivity of more than 97% and confinement loss in the order of 10 −12 dB/m.

Design
A simple PCF sensor has been designed and planned for chemical sensing and the schematic cross-sectional diagram that consists of a core, cladding, and Perfectly Matched Layer (PML) is illustrated in Figure 1.For the ease of fabrication, a single circular air hole to be infiltrated is assigned as the core of the fiber with a diameter denoted as d.Two layers of air holes are situated along the cladding region to allow confinement of light in the core and achieve low loss of the design.The first layer consists of hexagonal air holes with a corner-to-corner length l in a hexagonal lattice, followed by circular air holes with diameter d in a similar lattice arrangement.According to the literature [20], hexagonal holes can be manufactured precisely and with fewer defects.The PML is offset on the outer structure of the fiber.Correspondingly, the air filling fraction of the cladding is posed at a high value to acquire an optically dense core than the cladding, which preserves the modified total internal reflection (m-TIR) as the guiding mechanism.The proposed infiltration technique for this fiber design may follow the suggestion in reference [21], where the method to fill liquid in the PCF is by capillarity.One fiber end is dipped into the liquid while the other is left open at room pressure.The condition is the affinity with the PCF material; the cohesive forces between the molecules of the liquid must be lower than the adhesion forces of the liquid with the channel material.However, for selective hole infiltration, this can be achieved by directly blocking one by one the selected holes with some other material such as polymerizable glue.Another method of infiltration is described in reference [22]; the PCF is spliced with a standard single-mode fiber (SMF), where the cores of the PCF and SMF are connected.The connection between the SMF and PCF is called the transition region and functions as a fiber mask.Thus, since the cladding core holes are blocked, liquid can be infiltrated into the core region only, flowing from the SMF into the PCF.

Methodology
The simulation process of the proposed PCF has been conducted using COMSOL Multiphysics version 5.5 by implementing a Full Vector Finite Element Method (FV-FEM) for numerical analysis.This simulation method maps small homogeneous triangular segments onto the axes of the PCF, a procedure called meshing.A finer element size meshing has been correctly mapped on the fiber design and has a complete mesh, which consists of 12,324 triangular elements, 1446 edge elements, and 96 vertex elements.For chemical sensing of sulfuric acid, the test analyte is allowed to be infiltrated into the fiber for detection.The refractive indices of sulfuric acid with different concentrations of 0%, 10%, 20%, 30%, and 40% at wavelengths from 0.8 to 1.8 µm is given in Table 1 [16,23,24].
The different concentrations of sulfuric acid are obtained through diluting with water; 0% sulfuric acid and 100% water, 10% sulfuric acid and 90% water, 20% sulfuric acid and 80% water, 30% sulfuric acid and 70% water, and 40% sulfuric acid and 60% water.The main optical properties numerically investigated for the proposed PCF design are effective refractive index, power fraction, relative sensitivity, confinement loss, chromatic dispersion, and propagation constant.The optical properties are assessed to govern its effectiveness and potential practical use for chemical sensing.
With the selected silica background material and the core hole injected with the test analyte, the effective refractive index neff can be measured and modelled using the Sellmeier's equation given by [25]: where λ is the operating wavelength, and Ai and Bi (i = 1, 2, and 3) are the Sellmeier coefficients for the specific material.Power fraction F is the quantification of power flowing through the desired region of the PCF, and it is defined as the ratio of power in a particular region to that of the total fiber.It is expressed by Poynting's theorem as [26][27][28] where, Ex, Ey, and Hx, Hy are the transverse electric and magnetic fields of the guided mode, respectively.The integral in the numerator is integrated over the liquid analyte samples at the core, while the integral in the denominator is integrated over all-fiber regions.
Relative sensitivity S determines the sensing capacity of the PCF sensor to detect analytes by matching the refractive indices and is achieved by measuring the light intensity, which interacts with the analyte.It is defined as [26][27][28]: where nr is the refractive index of the sensed material and F is the power fraction.Confinement loss L measures the degree of loss of the waveguide from the core region of the fiber, and is defined as [28][29][30][31]: = 40 ln (10) Im[ ] × 10 where Im[neff] is the imaginary part of the effective mode index.Chromatic dispersion D occurs when a fraction of light power propagating through the cladding region is faster than the core region.It can be quantified by [29,31]: where c is the speed of light and Re[neff] is the real part of the effective refractive index.Propagation constant P of an electromagnetic wave is the measure of alteration by the amplitude of the wave as it propagates in each direction.Therefore, the propagation constant is defined as [32,33]:

Results and Discussion
The performance of the proposed PCF with different concentrations of sulfuric acid diluted in water has been analyzed by considering the different results of optical properties including power fraction, relative sensitivity, confinement loss, chromatic dispersion, and propagation constant.Figure 2 shows the simulated mode profile of the PCF with the liquid test analyte at a wavelength of 1.1 µm that demonstrates the interaction of light and test analyte and confined within the core of the proposed fiber.The relationship between the power fraction of the PCF sensor with respect to wavelength is shown in Figure 4.It can be seen that the power fractions for 20%, 30%, and 40% concentrations of sulfuric acid decrease non-uniformly as the wavelength increases from 0.8 µm to 1.8 µm.However, sulfuric acid analyte concentrations of 0% and 10% increase up to 1.0 µm, before subsequently decreasing as wavelength further increases.The results of power fractions are above 92%, which deduces high power flowing through the core of the fiber sensor.Figure 5 presents the behavior of relative sensitivity with respect to the operating wavelength of sulfuric acid at different concentrations.Relative sensitivities of the PCF sensor rise as wavelength increases from 0.8 µm to 1.1 µm and subsequently decreases as the wavelength increases further.Relative sensitivity is closely related to effective refractive index and power fraction; therefore, a similar trend is noticed between the optical properties.Surrounding the core hole with hexagonal-shaped air holes permits nearly total confinement of light, hence, high interaction of waveguide and test analytes.Thus, tremendously high relative sensitivities have been attained.At 1.1 µm, the optimum values of relative sensitivity are obtained, which are 97.08%,97.67%, 98.06%, 98.39%, and 98.67% for concentrations of 0%, 10%, 20%, 30%, and 40% of sulfuric acid, respectively.The optimum results are found at a wavelength of 1.1 µm; thus, the other values of optical properties are also obtained at 1.1 µm.
Figure 6 illustrates the assessed results of confinement loss with the variation of operating wavelength between the range 0.8-1.8µm.It is distinguished that confinement loss increases with the increase of wavelength, a distinct behavior of the waveguide as light tends to escape through the core as wavelength increases.Moreover, applying hexagonal air holes about the core hole reduces the leakage of light into the cladding, hence, low results of confinement losses.A lower confinement loss is observed when a higher concentration of sulfuric acid is filled in the core of the proposed PCF sensor, while higher confinement losses are seen as the percentage concentration of the analyte is decreased.The optimum results of confinement losses of sulfuric acid at concentrations of 0%, 10%, 20%, 30%, and 40% are 1.32 × 10 −12 dB/m, 4.11 × 10 −12 dB/m, 1.46 × 10 −12 dB/m, 6.34 × 10 −12 dB/m, and 2.12 × 10 −12 dB/m, respectively, at 1.1 µm operating wavelength.With low confinement losses obtained, the PCF design displays potential implementation in optical transmissions, besides sensing applications.Chromatic dispersion results of the proposed PCF with respect to operating wavelength for the different sulfuric acid concentrations (0%, 10%, 20%, 30%, and 40%) are illustrated in Figure 7.It is observed from the graph that chromatic dispersion decreases as wavelength increases within the wavelength range of 0.8-1.8µm.For the different concentrations, it has an ultra-flattened chromatic dispersion as the variation change from 0.8 µm to 1.8 µm is small.The chromatic dispersions assessed at 1.1 µm are −0.0051ps/nm.km,−0.0052 ps/nm.km,−0.0053 ps/nm.km,−0.0054 ps/nm.km,and −0.0055 ps/nm.kmfor percentage concentration of 0%, 10%, 20%, 30%, and 40%, respectively.With such low chromatic dispersions, the PCF structure can also be used in optical communications.The propagation constant results with respect to the wavelength of the different concentrations of sulfuric acid are represented in Figure 8.For the concentrations of 0%, 10%, 20%, 30%, and 40%, propagation constant decreases with the wavelength increase from 0.8 µm to 1.8 µm.The propagation constant is linearly relative to the effective refractive index for the slight variation of the operating wavelength.Hence, with increasing wavelength, the propagation reduces with the function of effective refractive index and the propagation constant decreases non-uniformly.At operating wavelength of 1.1 µm, the propagation constants for sulfuric concentration of 0% is 7.47 × 10 6 rad/m, 10% is 7.56 × 10 6 rad/m, 20% is 7.63 × 10 6 rad/m, 30% is 7.70 × 10 6 rad/m, and 40% is 7.76 × 10 6 rad/m.In addition, to overview the performance of the proposed PCF sensor with the change in concentration of the analyte, the results of relative sensitivity and confinement loss at different concentrations of sulfuric acid for 0%, 10%, 20%, 30%, and 40% is shown in Figure 9.It can be observed that the relative sensitivities of the proposed PCF increase as the percentage concentration of sulfuric acid increases.At the same time, the results of confinement losses decrease with the increases in sulfuric acid concentration from 0% to 40%.This effect is due to the increase in the refractive index of the analyte when the concentration of sulfuric acid increases, which raises the interaction between the light and test analyte.2.Even with small modifications in the air hole diameter and pitch distance, the relative sensitivity does not deviate from the optimum value, as seen from the table.Thus, this demonstrates the durability of the proposed design.

Figure 1 .
Figure 1.Proposed PCF design for chemical sensing.

Figure 3
Figure3represents the effective refractive index of the test analytes in relation to the operating wavelength from 0.8 µm to 1.8 µm.It is evident that the effective refractive index decreases with the increase of operating wavelength.This behavior is because the electromagnetic signal at lower wavelengths prefers to propagate through the high refractive index region and as the wavelength increases, it has stronger capabilities to overflow to the cladding region.Furthermore, as the concentration of sulfuric acid increases, the values of the effective index increase.

Table 2 .
Performance analysis against the variation of global dimension at λ = 1.1 µm.Furthermore, a comparison between the proposed fiber and prior PCFs is presented in Table3.It can be observed from the table below that the proposed PCF establishes the highest relative sensitivity and lowest confinement loss.

Table 3 .
Comparison of performance among prior PCFs and proposed PCF at λ = 1.1 µm.