Long-Term Stability Test for Femtosecond Laser-Irradiated SnO 2 -Nanowire Gas Sensor for C 7 H 8 Gas Sensing

: In this study, femtosecond (FS) laser irradiation with different laser energy densities of 138, 276, and 414 mJ/cm 2 is applied to SnO 2 -nanowire (NW) gas sensors, and the effect of the FS laser irradiation on the gas sensor response toward toluene (C 7 H 8 ) gas is investigated. The FS laser irradiation causes oxygen deficiency in the SnO 2 NWs and forms SnO and SnO x . Moreover, an embossing surface with multiple nano-sized bumps is created on the SnO 2 NW surface because of the FS laser irradiation. The FS laser-irradiated SnO 2 -NW gas sensor exhibits superior sensing performance compared with the pristine SnO 2 -NW gas sensor. Moreover, the FS laser energy density significantly affects gas-sensing performance, and the highest sensor response is achieved by the gas sensor irradiated at 138 mJ/cm 2 . The long-term stability test of the laser-irradiated SnO 2 -NW gas sensor is performed by comparing fresh and 6-month-old gas sensors in different gas concentrations and relative humidity levels. Comparable gas-sensing behaviors are examined between the fresh and 6-month-old gas sensor, and this verifies the robustness of the laser-irradiated SnO 2 -NW gas sensor.


Introduction
Gas sensors have been widely used to protect the environment and human health as well as to control production quality in industrial applications [1,2].Semiconducting metal oxide (SMO) gas sensors are one of the most widely used gas sensors because of their low cost, rapid response, and excellent sensitivity and stability [3].Toluene (C 7 H 8 ) is a well-known volatile organic compound (VOC) released from various household products such as flooring, furniture, and paintings.Therefore, we are repeatedly exposed to C 7 H 8 environments, which can cause short-and long-term health risks, including throat, nose, and eye irritation, as well as liver and kidney cancers [4].Therefore, to protect public health, the performance of SMO gas sensors should be further improved for an accurate and rapid examination of C 7 H 8 .
Photonics 2024, 11, 550 2 of 16 Applying external energy to sensing materials via irradiation induces structural defects (e.g., oxygen deficiency), and the associated non-stoichiometry contributes to increased interaction with gases.Therefore, non-stoichiometric metal oxides offer improved sensing performance [20].Among the irradiation techniques, laser irradiation is promising owing to its ease of control, rapid and precise process, and no requirement for a clean room or vacuum chamber.Hou et al. [18] reported that pulsed laser irradiation improved the response of an Al-doped ZnO gas sensor toward H 2 gas.Moreover, Zhang et al. [19] applied an excimer laser to a WO 3 gas sensor and demonstrated improved performance toward NO 2 gas.
Among the various SMO gas sensors, SnO 2 is a promising sensing material owing to its excellent stability, high electron mobility, non-toxicity, and low synthesis cost [21].The different morphologies of SnO 2 include nanoneedles, nanofibers, films, nanoparticles, nanowires, and hollow spheres [22][23][24][25][26][27][28][29].SnO 2 nanowires have been widely adopted as a sensing material owing to their large surface areas, which enables more target gases to be absorbed, thus resulting in better sensing response [27][28][29].However, the sensing performance should be enhanced to accurately examine the presence of C 7 H 8 .
In this study, the femtosecond (FS) laser is irradiated on the SnO 2 NWs, and the effect on the gas-sensing behavior of the NWs is investigated.Different laser energy densities are applied to the SnO 2 NWs, and the sensing behaviors of the pristine and laser-irradiated SnO 2 NWs toward C 7 H 8 are examined.The laser-irradiated SnO 2 NWs perform better in terms of gas-sensing behavior compared with that of the pristine SnO 2 NWs.Therefore, transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS) are performed to determine the changes in the surface morphology and chemical state of the SnO 2 NWs after the FS laser irradiation.The FS laser irradiation increases the surface area and results in structural defects in the SnO 2 NWs, which are characteristic of surface engineering and irradiation techniques.The results of this study verify that the ultrashort pulse laser irradiation is a promising approach for enhancing the sensing capability of SnO 2 NWs.

Synthesis of SnO 2 NWs
An Au-catalyzed vapor-liquid-solid (VLS) technique was adopted for the SnO 2 NWs' growth.Details regarding the VLS technique are available in our previous paper [30].A Si wafer with a SiO 2 layer (thickness: 200 nm) was utilized as the substrate.Tri-layered electrodes comprising Ti (50 nm), Pt (200 nm), and Au (3 nm) were deposited onto the substrate via sputtering.A tri-layer-deposited substrate with metallic Sn powder (99.9%,Sigma-Aldrich, St. Louis, MO, USA) was placed in a quartz tube furnace.The furnace was heated up to 900 • C under a gas flow comprising N 2 (300 sccm) and O 2 (10 sccm).Thus, a SnO 2 NW-based gas sensor device was fabricated.Figure 1 shows a field emission scanning electron microscopy (FE-SEM) image of a successfully grown network of SnO 2 NWs on tri-layered electrodes.

Femtosecond Laser Irradiation
The experimental setup for the FS laser irradiation is shown in Figure 1.An FS laser (Satsuma HP 3 , Amplitude Laser, Pessac, France) with a central wavelength of 1030 nm, pulse duration of 350 fs, and frequency of 15 kHz was applied to the gas sensor device.The laser beam quality (M 2 ) was measured to be 1.2 in both the horizontal and vertical directions.The laser pulse energy was controlled using a half-wave plate and thin-film polarizing beam splitter (PBS) combined, and the laser beam was delivered by a beam mirror train.The laser beam was focused on the gas sensor device through a 10× infinity corrected microscope objective lens, thus resulting in a laser beam diameter of 4.8 µm.The laser beam scanning speed was set to 80 mm/s using a computer-controlled motion system (M-414, PI Benelux, Karlsruhe, Germany).The FS laser was irradiated on a network of SnO2 NWs (at the dotted red region in the gas sensor device, as shown in Figure 1) at a hatch distance of 50 µm.Fifteen linear laser-beam scans were performed.The applied laser pulse energies were 0.025, 0.05, and 0.075 µJ, which were equivalent to the laser fluences of 138, 276, and 414 mJ/cm 2 , respectively.The laser fluence was calculated as follows: Laser fluence (mJ/cm 2 ) = Laser pulse energy (mJ)/Laser beam area (cm 2 ) (1)

Characterization
A qualitative analysis of the SnO2 NWs was conducted via X-ray diffraction (XRD, X'Pert PRO, PANalytical, Malvern, UK) using Cu-Ka radiation (λ = 1.5418Å).The morphology and microstructure of the SnO2 NWs was examined via FE-SEM (Hitachi S-4200) and transmission electron microscopy (TEM, Carl Zeiss LIBRA 200 MC).The fabricated SnO2 NWs were dispersed in isopropyl alcohol and deposited onto a Cu TEM grid (01890-F, Ted Pella, Inc., Redding, CA, USA) to prepare the TEM specimens.The electron energy loss spectroscopy (EELS) analysis was conducted to examine the chemical characteristics of the pristine and laser-irradiated SnO2 NWs.The first O peak in the EELS spectra (at approximately 532 eV) was used as a reference to align the EELS spectra of the pristine and laser-irradiated SnO2 NWs.Subsequently, peak analysis was conducted [31].

Gas-Sensing Measurements
A customized gas-sensing system was adopted to examine the gas-sensing behavior.A gas chamber was placed in a quartz tube furnace, and the operating temperature of the gas sensor was controlled.The concentration of the target gas (C7H8 gas in this study) was

Femtosecond Laser Irradiation
The experimental setup for the FS laser irradiation is shown in Figure 1.An FS laser (Satsuma HP 3 , Amplitude Laser, Pessac, France) with a central wavelength of 1030 nm, pulse duration of 350 fs, and frequency of 15 kHz was applied to the gas sensor device.The laser beam quality (M 2 ) was measured to be 1.2 in both the horizontal and vertical directions.The laser pulse energy was controlled using a half-wave plate and thin-film polarizing beam splitter (PBS) combined, and the laser beam was delivered by a beam mirror train.The laser beam was focused on the gas sensor device through a 10× infinity corrected microscope objective lens, thus resulting in a laser beam diameter of 4.8 µm.The laser beam scanning speed was set to 80 mm/s using a computer-controlled motion system (M-414, PI Benelux, Karlsruhe, Germany).The FS laser was irradiated on a network of SnO 2 NWs (at the dotted red region in the gas sensor device, as shown in Figure 1) at a hatch distance of 50 µm.Fifteen linear laser-beam scans were performed.The applied laser pulse energies were 0.025, 0.05, and 0.075 µJ, which were equivalent to the laser fluences of 138, 276, and 414 mJ/cm 2 , respectively.The laser fluence was calculated as follows: Laser fluence (mJ/cm 2 ) = Laser pulse energy (mJ)/Laser beam area (cm 2 ) (1)

Characterization
A qualitative analysis of the SnO 2 NWs was conducted via X-ray diffraction (XRD, X'Pert PRO, PANalytical, Malvern, UK) using Cu-Ka radiation (λ = 1.5418Å).The morphology and microstructure of the SnO 2 NWs was examined via FE-SEM (Hitachi S-4200, Tokyo, Japan) and transmission electron microscopy (TEM, Carl Zeiss LIBRA 200 MC, Jena, Germany).The fabricated SnO 2 NWs were dispersed in isopropyl alcohol and deposited onto a Cu TEM grid (01890-F, Ted Pella, Inc., Redding, CA, USA) to prepare the TEM specimens.The electron energy loss spectroscopy (EELS) analysis was conducted to examine the chemical characteristics of the pristine and laser-irradiated SnO 2 NWs.The first O peak in the EELS spectra (at approximately 532 eV) was used as a reference to align the EELS spectra of the pristine and laser-irradiated SnO 2 NWs.Subsequently, peak analysis was conducted [31].

Gas-Sensing Measurements
A customized gas-sensing system was adopted to examine the gas-sensing behavior.A gas chamber was placed in a quartz tube furnace, and the operating temperature of the gas sensor was controlled.The concentration of the target gas (C 7 H 8 gas in this study) was determined by mixing it with dry air, and the gas mixing ratio was controlled using mass-flow controllers.The mixture was flowed at 500 sccm.
The gas-sensing behavior was measured using a custom-developed gas-sensing system.The gas chamber was placed in a quartz tube furnace to control the operating temperature of the gas sensor.The target gas was mixed with dry air using mass-flow controllers to obtain its specific gas concentrations.The flow rate was maintained at 500 sccm.A Keithley source meter (Series 2400) was used to measure the electrical resistance during the sensing measurements in air (R a ) and target gas (R g ) atmospheres, and the sensor response was calculated as R = R g /R a .Moreover, the response time (τ res ) was measured at the time for the sensor to reach 90% of its final resistance value after supplying the target gas, whereas the recovery time (τ res ) was measured at the time for the sensor to reach 90% of its initial resistance value after the target gas supply was halted.To investigate the effect of humidity, we examined the sensing behavior at different relative humidity (RH) values.The long-term stability tests were conducted by comparing the fresh and 6-month-old gas sensors in various target gas concentrations and RH values.

Microstructures
Figure 2 shows the qualitative XRD analysis of the pristine SnO 2 NWs (Figure 2a) and laser-irradiated SnO 2 NWs with different laser energy densities of 138 (Figure 2b) and 414 (Figure 2c) mJ/cm 2 .For each specimen, the XRD patterns were consistent with those of crystalline SnO 2 (tetragonal rutile structure, JCPDS File No. 88-0287 [32]), and no additional peaks were observed.Figure 3a,b shows the TEM images of the pristine SnO 2 NW and laser-irradiated SnO 2 NW with a laser energy density of 138 mJ/cm 2 , respectively.High-resolution TEM images and selected area electron diffraction (SAED) patterns are shown in red boxes.For the pristine SnO 2 NW, a smooth and flat nanowire surface was observed.Moreover, both the d-spacing and SAED pattern analyses verified the tetragonal rutile structure of the SnO 2 NWs [33].For the laser-irradiated SnO 2 NW, the equivalent crystal structure was analyzed based on the d-spacing and SAED pattern, which indicated no crystal structure change after the FS laser irradiation.However, multiple FS laser irradiation-induced nano-sized bumps developed on the nanowire surface (denoted by red arrows).This embossing surface may create more adsorption sites for gas species, thus improving sensing performance.
The EELS analysis was performed to determine the chemical states before and after the FS laser irradiation.Figure 4 shows the energy-loss spectra of the pristine SnO 2 NWs and laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 .According to Moreno et al. [31], the EELS spectrum can be used to identify different Sn oxides (i.e., SnO 2 , SnO, and SnO x ); thus, in this study, the EELS spectra before and after the FS laser irradiation were used to examine the chemical state of Sn oxides.For the pristine SnO 2 NWs, the EELS spectrum was equivalent to that reported by Moreno et al. [31].The O K-edge in the energy range of 527-545 eV comprised two peaks, and the peak separation was 5.82 eV.Moreover, the Sn M 4,5 edges in the energy range of 490-505 eV and single distinct Sn M 4 and M 5 edges were examined at 495.83 and 501.26 eV, respectively.However, a slightly different EELS spectrum was observed for the laser-irradiated SnO 2 NWs with respect to the peak shifts and generations.A relatively large peak separation (6.25 eV) was detected at the O K-edge, and multiple Sn M 4,5 edges were observed at the Sn M edge.These modifications in the EELS spectrum contributed to the formation of SnO or SnO x phases after the FS laser irradiation.The SnO 2 and SnO have different peak positions at the O K edge and Sn M 4,5 edges [31].Consequently, the presence of SnO or SnO x (developed from a combination of SnO 2 and SnO) in SnO 2 resulted in a slightly larger O K edge separation and multiple Sn M 4,5 edges, thus indicating that the presence of different Sn oxides (i.e., SnO 2 , SnO, and SnO x ) was caused by the FS laser irradiation.

Gas-Sensing Studies
Figure 5a shows the transient resistance curves of the pristine gas sensor in the range of 50-350 °C for 10, 30, and 50 ppm of C7H8 gas, and the corresponding sensor response and base resistance are shown in Figure 5b.At 50 °C, no response was observed, whereas

Gas-Sensing Studies
Figure 5a shows the transient resistance curves of the pristine gas sensor in the range of 50-350 • C for 10, 30, and 50 ppm of C 7 H 8 gas, and the corresponding sensor response and base resistance are shown in Figure 5b.At 50 • C, no response was observed, whereas marginal resistance changes were indicated at 100 • C once the target gas supply was introduced and halted.The resistance decreased slightly as the target gas supply was introduced, which is characteristic of the gas-sensing behavior of n-type SMO gas sensors.As the temperature increases, more significant resistance changes and higher sensor responses were observed.Moreover, the optimum sensing performance was observed at 300 • C, where the sensor indicated a response level of 1.52 at 50 ppm of C 7 H 8 gas.Meanwhile, the resistance change and sensor response observed at 350 • C were lower than those observed at 300 • C. No gas sensor response was indicated at low temperatures because the target gas molecules did not possess sufficient energy to overcome the adsorption barrier.At 300 • C, the desorption rate of the oxygen molecules and the absorption rate of the target molecules were equivalent, thus resulting in the optimum sensing performance.At 350 • C, the desorption rate exceeded the adsorption rate; therefore, a relatively weaker sensor response was achieved compared with that achieved at 300 • C. Thus, subsequent gas-sensing tests were performed at 300 • C.
Photonics 2024, 11, x FOR PEER REVIEW 7 of 16 marginal resistance changes were indicated at 100 °C once the target gas supply was introduced and halted.The resistance decreased slightly as the target gas supply was introduced, which is characteristic of the gas-sensing behavior of n-type SMO gas sensors.As the temperature increases, more significant resistance changes and higher sensor responses were observed.Moreover, the optimum sensing performance was observed at 300 °C, where the sensor indicated a response level of 1.52 at 50 ppm of C7H8 gas.Meanwhile, the resistance change and sensor response observed at 350 °C were lower than those observed at 300 °C.No gas sensor response was indicated at low temperatures because the target gas molecules did not possess sufficient energy to overcome the adsorption barrier.At 300 °C, the desorption rate of the oxygen molecules and the absorption rate of the target molecules were equivalent, thus resulting in the optimum sensing performance.At 350 °C, the desorption rate exceeded the adsorption rate; therefore, a relatively weaker sensor response was achieved compared with that achieved at 300 °C.Thus, subsequent gassensing tests were performed at 300 °C. Figure 6a shows the dynamic resistance curves of the pristine SnO2 NWs and laserirradiated SnO2 NWs with the laser energy densities of 138, 256, and 414 mJ/cm 2 toward 10, 30, and 50 ppm of C7H8 gas. Figure 6b shows the corresponding sensor response and base resistance as a function of the laser energy density.The sensor response for the pristine SnO2 NWs was 1.52 at 50 ppm of C7H8 gas, whereas that for the laser-irradiated SnO2 Figure 6a shows the dynamic resistance curves of the pristine SnO 2 NWs and laserirradiated SnO 2 NWs with the laser energy densities of 138, 256, and 414 mJ/cm 2 toward 10, 30, and 50 ppm of C 7 H 8 gas. Figure 6b shows the corresponding sensor response and base resistance as a function of the laser energy density.The sensor response for the pristine SnO 2 NWs was 1.52 at 50 ppm of C 7 H 8 gas, whereas that for the laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 was 2.42.The sensor response decreased as the laser energy density increased; interestingly, the sensor with higher base resistance values exhibited better sensor response toward C 7 H 8 gas. Figure 6c shows the response and recovery times as a function of the laser energy density toward 50 ppm of C 7 H 8 gas.The shortest response and recovery times were indicated by the laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 , which demonstrated the highest sensor response.This result verifies that the FS laser irradiation improves the gas-sensing performance, and laser parameters significantly affect the gas-sensing performance.NWs with a laser energy density of 138 mJ/cm 2 was 2.42.The sensor response decreased as the laser energy density increased; interestingly, the sensor with higher base resistance values exhibited better sensor response toward C7H8 gas. Figure 6c shows the response and recovery times as a function of the laser energy density toward 50 ppm of C7H8 gas.
The shortest response and recovery times were indicated by the laser-irradiated SnO2 NWs with a laser energy density of 138 mJ/cm 2 , which demonstrated the highest sensor response.This result verifies that the FS laser irradiation improves the gas-sensing performance, and laser parameters significantly affect the gas-sensing performance.Gas-sensing tests were conducted at different RH values to examine the reliability of the SnO2 gas sensor.Figure 7 shows the dynamic resistance curves and the corresponding sensor response and base resistance for the pristine SnO2 NWs (Figure 7a) and laser-irradiated SnO2 NWs with a laser energy density of 138 mJ/cm 2 (Figure 7b) toward 10, 30, and 50 ppm of C7H8 gas.Both gas sensors showed deteriorated sensing performance as the RH level increased.This is because water molecules may adhere to the adsorption sites of the SnO2 NWs, where the target gas should be adsorbed, thus deteriorating the sensing performance as the RH level increases [34].Gas-sensing tests were conducted at different RH values to examine the reliability of the SnO 2 gas sensor.Figure 7 shows the dynamic resistance curves and the corresponding sensor response and base resistance for the pristine SnO 2 NWs (Figure 7a) and laserirradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 (Figure 7b) toward 10, 30, and 50 ppm of C 7 H 8 gas.Both gas sensors showed deteriorated sensing performance as the RH level increased.This is because water molecules may adhere to the adsorption sites of the SnO 2 NWs, where the target gas should be adsorbed, thus deteriorating the sensing performance as the RH level increases [34].

Gas-Sensing Mechanism
Oxygen molecules are adsorbed on the sensing materials (i.e., SnO2 NWs) when the gas sensor is exposed to air, and the following reaction can occur because of the high electron affinity of oxygen [35,36]: The adsorbed oxygen extracts electrons from the SnO2 NW surface.Consequently, an electron depletion layer (EDL) is developed at the subsurface, and electrons are confined at the core of the SnO2 NWs (known as the conduction volume or conduction channel).When a reducing target gas (C7H8 gas in this study) is supplied, the target gas adsorbs onto the SnO2 NW surface instead of onto oxygen.Therefore, the electrons extracted from the oxygen return to the SnO2 NWs, thus decreasing both the EDL width and sensor resistance.The relevant reactions are as follows [4,37]:

Gas-Sensing Mechanism
Oxygen molecules are adsorbed on the sensing materials (i.e., SnO 2 NWs) when the gas sensor is exposed to air, and the following reaction can occur because of the high electron affinity of oxygen [35,36]: The adsorbed oxygen extracts electrons from the SnO 2 NW surface.Consequently, an electron depletion layer (EDL) is developed at the subsurface, and electrons are confined at the core of the SnO 2 NWs (known as the conduction volume or conduction channel).When a reducing target gas (C 7 H 8 gas in this study) is supplied, the target gas adsorbs onto the SnO 2 NW surface instead of onto oxygen.Therefore, the electrons extracted from the oxygen return to the SnO 2 NWs, thus decreasing both the EDL width and sensor resistance.The relevant reactions are as follows [4,37]: C m H n (ads) + xO −y (ads) where, for toluene (C 7 H 8 ) gas, "m" and "n" values are 7 and 8, respectively.x value is equal to 2m + n/2; therefore, x value becomes 18 and y value is 1.As a result, the reaction is as follows: Next, we analyzed the mechanism of the improved sensor response after the FS laser was irradiated on the SnO 2 NWs.A higher initial sensor resistance facilitates better response by the chemosorbed gas sensor.This is because the sensor response is measured as R a /R g .For the laser-irradiated SnO 2 -NW gas sensors, two different factors, i.e., the embossing surface and oxygen deficiency, should be considered.First, the FS laser irradiation creates an embossing surface on the SnO 2 NWs, as shown in the TEM image, which may increase the surface area of the SnO 2 NWs.Therefore, a greater amount of oxygen is adsorbed onto the SnO 2 NWs, thus increasing both the base resistance and gas response.Second, the FS laser irradiation results in oxygen deficiency in the SnO 2 NWs by forming SnO and SnO x .This generates additional electron conduction, thus reducing both the base resistance and gas response.These two factors are conflicting; when the embossing surface effect is dominant, the sensor response is enhanced, whereas when the oxygen deficiency effect is dominant, the sensor response deteriorates.The sensor response was optimal at a laser energy density of 138 mJ/cm 2 but decreased as the laser energy density increased.This may be because the embossing surface effect was optimized at 138 mJ/cm 2 , whereas the oxygen deficiency effect became more prominent as the laser energy density increased, which is attributed to a decrease in the sensor response.Figure 8 summarizes the sensing mechanism of the FS laser-irradiated gas sensor for C 7 H 8 gas.

C H ads
xO ads → mCO n/2H O xye (7) where, for toluene (C7H8) gas, "m" and "n" values are 7 and 8, respectively. value is equal to 2 /2; therefore,  value becomes 18 and  value is 1.As a result, the reaction is as follows: Next, we analyzed the mechanism of the improved sensor response after the FS laser was irradiated on the SnO2 NWs.A higher initial sensor resistance facilitates better response by the chemosorbed gas sensor.This is because the sensor response is measured as Ra/Rg.For the laser-irradiated SnO2-NW gas sensors, two different factors, i.e., the embossing surface and oxygen deficiency, should be considered.First, the FS laser irradiation creates an embossing surface on the SnO2 NWs, as shown in the TEM image, which may increase the surface area of the SnO2 NWs.Therefore, a greater amount of oxygen is adsorbed onto the SnO2 NWs, thus increasing both the base resistance and gas response.Second, the FS laser irradiation results in oxygen deficiency in the SnO2 NWs by forming SnO and SnOx.This generates additional electron conduction, thus reducing both the base resistance and gas response.These two factors are conflicting; when the embossing surface effect is dominant, the sensor response is enhanced, whereas when the oxygen deficiency effect is dominant, the sensor response deteriorates.The sensor response was optimal at a laser energy density of 138 mJ/cm 2 but decreased as the laser energy density increased.This may be because the embossing surface effect was optimized at 138 mJ/cm 2 , whereas the oxygen deficiency effect became more prominent as the laser energy density increased, which is attributed to a decrease in the sensor response.Figure 8 summarizes the sensing mechanism of the FS laser-irradiated gas sensor for C7H8 gas.

Long-Term Stability Test
The fresh and 6-month-old SnO 2 gas sensor were used to examine the long-term stability of a laser-irradiated SnO 2 -NW gas sensor.To the best knowledge of the authors, this is the first time the long-term stability of a laser-irradiated SnO 2 -NW gas sensor has been investigated.Figure 9 shows the dynamic resistance curves and the corresponding sensor response for the pristine SnO 2 NWs (Figure 9a) and laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 (Figure 9b) toward 0.6, 1, 10, 30, and 50 ppm of C 7 H 8 gas.For the pristine and laser-irradiated SnO 2 NWs, the fresh and 6-month-old gas sensors showed comparable gas sensor performance.It is worth noting that the laser-irradiated SnO 2 NWs were able to sense 0.6 ppm of C 7 H 8 gas with a sensor response of 1.06 and 1.07 for the fresh and 6-month-old sensors.On the contrary, no sensor response was examined at the C 7 H 8 gas concentration of 0.6 ppm for the pristine SnO 2 NWs.This result supports the notion that FS laser irradiation enhances gas sensor sensitivity.

Long-Term Stability Test
The fresh and 6-month-old SnO2 gas sensor were used to examine the long-term stability of a laser-irradiated SnO2-NW gas sensor.To the best knowledge of the authors, this is the first time the long-term stability of a laser-irradiated SnO2-NW gas sensor has been investigated.Figure 9 shows the dynamic resistance curves and the corresponding sensor response for the pristine SnO2 NWs (Figure 9a) and laser-irradiated SnO2 NWs with a laser energy density of 138 mJ/cm 2 (Figure 9b) toward 0.6, 1, 10, 30, and 50 ppm of C7H8 gas.For the pristine and laser-irradiated SnO2 NWs, the fresh and 6-month-old gas sensors showed comparable gas sensor performance.It is worth noting that the laser-irradiated SnO2 NWs were able to sense 0.6 ppm of C7H8 gas with a sensor response of 1.06 and 1.07 for the fresh and 6-month-old sensors.On the contrary, no sensor response was examined at the C7H8 gas concentration of 0.6 ppm for the pristine SnO2 NWs.This result supports the notion that FS laser irradiation enhances gas sensor sensitivity.Figure 10 compares the gas-sensing behavior at different RH levels for the fresh and 6-month-old gas sensors of pristine SnO 2 NWs and laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 .Figure 10a,b shows the normalized resistance curve and corresponding sensor response for the fresh and 6-month-old pristine SnO 2 gas sensors, respectively.Moreover, Figure 10c,d presents the normalized resistance curve and corresponding sensor response for the fresh and 6-month-old laser-irradiated SnO 2 gas sensors, respectively.The fresh and 6-month-old gas sensors show similar gas-sensing behaviors for both pristine and laser-irradiated SnO 2 NWs.Comparable sensor response values were obtained at different RH levels for the fresh and 6-month-old gas sensors of pristine SnO 2 NWs and laser-irradiated SnO 2 NWs.The long-term stability tests in Figures 9 and 10 indicate that no deterioration was detected in the sensing performance for both pristine and laser-irradiated SnO 2 NWs, even after 6 months from the gas sensor's fabrication.These results verify the robustness of laser-irradiated SnO 2 -NW gas sensors.
Photonics 2024, 11, x FOR PEER REVIEW 12 of 16 energy density of 138 mJ/cm 2 .Figure 10a,b shows the normalized resistance curve and corresponding sensor response for the fresh and 6-month-old pristine SnO2 gas sensors, respectively.Moreover, Figure 10c,d presents the normalized resistance curve and corresponding sensor response for the fresh and 6-month-old laser-irradiated SnO2 gas sensors, respectively.The fresh and 6-month-old gas sensors show similar gas-sensing behaviors for both pristine and laser-irradiated SnO2 NWs.Comparable sensor response values were obtained at different RH levels for the fresh and 6-month-old gas sensors of pristine SnO2 NWs and laser-irradiated SnO2 NWs.The long-term stability tests in Figures 9 and 10 indicate that no deterioration was detected in the sensing performance for both pristine and laser-irradiated SnO2 NWs, even after 6 months from the gas sensor's fabrication.These results verify the robustness of laser-irradiated SnO2-NW gas sensors.Table 1 shows the sensitivity values of C 7 H 8 gas with different SnO 2 -based sensing materials.Compared with other studies, the FS laser-irradiated SnO 2 NWs showed a relatively low sensitivity value.However, those high sensitivity values were obtained with surface functionalization by using the heterojunction structure or catalytic effect.Different surface functionalization techniques or materials should be conducted to detect other target gases.Therefore, those approaches may have limited technological scalability.On the contrary, FS laser irradiation is a promising approach for enhancing the sensing performance toward multiple target gases because it is applicable to different types and shapes of SMOs.

Figure 1 .
Figure 1.Schematic diagrams of laser system, gas sensor electrode, and FS laser-irradiation procedure.

Figure 1 .
Figure 1.Schematic diagrams of laser system, gas sensor electrode, and FS laser-irradiation procedure.

Figure 2 .
Figure 2. XRD spectra for the (a) pristine SnO 2 NW, (b) laser-irradiated SnO 2 NW with a laser energy density of 138 mJ/cm 2 , and (c) laser-irradiated SnO 2 NW with a laser energy density of 414 mJ/cm 2 .

Figure 3 .
Figure 3. TEM image, high-resolution TEM image, and SAED pattern of the (a) pristine SnO2 NW and (b) laser-irradiated SnO2 NW with a laser energy density of 138 mJ/cm 2 .

Figure 4 .
Figure 4. EELS spectra of O K edge and Sn M4,5 edges for the pristine SnO2 NW and laser-irradiated SnO2 NW with a laser energy density of 138 mJ/cm 2 .

Figure
Figure 5a shows the transient resistance curves of the pristine gas sensor in the range of 50-350 °C for 10, 30, and 50 ppm of C7H8 gas, and the corresponding sensor response and base resistance are shown in Figure 5b.At 50 °C, no response was observed, whereas

Figure 3 . 16 Figure 3 .
Figure 3. TEM image, high-resolution TEM image, and SAED pattern of the (a) pristine SnO 2 NW and (b) laser-irradiated SnO 2 NW with a laser energy density of 138 mJ/cm 2 .

Figure 4 .
Figure 4. EELS spectra of O K edge and Sn M4,5 edges for the pristine SnO2 NW and laser-irradiated SnO2 NW with a laser energy density of 138 mJ/cm 2 .

Figure 4 .
Figure 4. EELS spectra of O K edge and Sn M 4,5 edges for the pristine SnO 2 NW and laser-irradiated SnO 2 NW with a laser energy density of 138 mJ/cm 2 .

Figure 5 .
Figure 5. (a) Dynamic resistance curves of the pristine SnO2 NWs for 10, 30, and 50 ppm of C7H8 gas at different sensing temperatures.(b) Corresponding sensor response and base resistance as a function of sensing temperature.

Figure 5 .
Figure 5. (a) Dynamic resistance curves of the pristine SnO 2 NWs for 10, 30, and 50 ppm of C 7 H 8 gas at different sensing temperatures.(b) Corresponding sensor response and base resistance as a function of sensing temperature.

Figure 6 .
Figure 6.(a) Dynamic resistance curves of the pristine and laser-irradiated SnO2 NWs (laser energy density: 138, 276, and 414 mJ/cm 2 ) for 10, 30, and 50 ppm of C7H8 gas.(b) Corresponding sensor response and base resistance as a function of laser energy density.(c) Corresponding response and recovery times as a function of laser energy density toward 50 ppm of C7H8 gas.

Figure 6 .
Figure 6.(a) Dynamic resistance curves of the pristine and laser-irradiated SnO 2 NWs (laser energy density: 138, 276, and 414 mJ/cm 2 ) for 10, 30, and 50 ppm of C 7 H 8 gas.(b) Corresponding sensor response and base resistance as a function of laser energy density.(c) Corresponding response and recovery times as a function of laser energy density toward 50 ppm of C 7 H 8 gas.

Figure 7 .
Figure 7. Dynamic resistance curves and corresponding sensor responses and base resistances at different RH levels for the (a) pristine and (b) laser-irradiated SnO 2 NWs with a laser energy density of 138 mJ/cm 2 .

Figure 8 .
Figure 8. Schematic diagram of sensing mechanism of the laser-irradiated SnO 2 NWs in terms of oxygen vacancy and electron depletion.

Figure 8 .
Figure 8. Schematic diagram of sensing mechanism of the laser-irradiated SnO2 NWs in terms of oxygen vacancy and electron depletion.

Figure 9 .
Figure 9. Dynamic resistance curves and corresponding sensor responses at different C7H8 gas concentrations for the fresh and 6-month-old gas sensors of (a) pristine and (b) laser-irradiated SnO2 NWs with laser energy density of 138 mJ/cm 2 .

Figure 10
Figure 10 compares the gas-sensing behavior at different RH levels for the fresh and 6-month-old gas sensors of pristine SnO2 NWs and laser-irradiated SnO2 NWs with a laser

Figure 9 .
Figure 9. Dynamic resistance curves and corresponding sensor responses at different C 7 H 8 gas concentrations for the fresh and 6-month-old gas sensors of (a) pristine and (b) laser-irradiated SnO 2 NWs with laser energy density of 138 mJ/cm 2 .

Table 1 .
Comparison of SnO 2 -based C 7 H 8 gas sensing behavior.