Extraction of Cobalt and Iron from Refractory Co ‐ Bearing Sulfur Concentrate

: In this study, oxidizing roasting, segregation roasting, and magnetic separation are used to extract cobalt and iron from refractory Co ‐ bearing sulfur concentrate. The Co ‐ bearing sulfur concentrate containing 0.68% Co, 33.26% Fe, and 36.58% S was obtained from V ‐ Ti magnetite in the Panxi area of China by flotation. Cobalt pyrite and linneite were the Co ‐ bearing minerals, and the gangue minerals were mica, chlorite, feldspar, and calcite in Co ‐ bearing sulfur concentrate. The results show that cobalt is transformed from Co ‐ pyrite and linneite to a Co 2 FeO 4 ‐ dominated new cobalt mineral phase, and iron is transformed from pyrite to Fe 2 O 3 and an Fe 3 O 4 ‐ dominated new iron mineral phase after oxidizing roasting. Cobalt changed from CoFe 2 O 4 to a new cobalt mineral phase dominated by [Co] Fe solid solution, and iron changed from Fe 2 O 3 to a new iron mineral phase dominated by metal Fe and Fe 3 O 4 after segregation roasting. Cobalt concentrate with a cobalt grade of 15.15%, iron content of 71.22%, and cobalt recovery of 90.81% as well as iron concentrate with iron grade of 60.06%, cobalt content of 0.11%, and iron recovery of 76.23% are obtained. The main minerals in the cobalt concentrate are Fe, [Co]Fe, Fe 3 O 4 , and SiO 2 , and the main minerals in the iron concentrate are Fe 3 O 4 , FeO, Ca 2 Si 2 O 4 , and Ca 2 Al 2 O 4 . solid Fe 2 3 a new iron mineral


Introduction
The unique physical and chemical properties of cobalt make this metal an important raw material in the fields of aerospace, petrochemicals, glass manufacturing, and medicine. Cobalt plays an important role in the development of strategic emerging industries. The content of cobalt in the crust is very low, and 90% of cobalt in the crust is in a dispersed state. In nature, cobalt is mostly associated with copper, nickel, iron, and other minerals, and there is no separate cobalt deposit. Both the United States and the European Union have included cobalt in the list of key minerals and materials that affect national and regional security and future economic development. According to the research of the China Mining Federation, cobalt will become one of the nine minerals in serious shortage by 2020. China is one of the world's major producers and consumers of refined cobalt, but China's cobalt reserves only account for 1.1% of the total global reserves. A large number of cobalt raw materials rely on imports. Most of the cobalt minerals found on the earth are associated with copper sulfide ore, nickel sulfide ore, pyrite, and other minerals, and only about 2% of the global Cobalt-sulfur concentrate is the most common raw material for industrial cobalt extraction. Pyrite is the most important sulfur-bearing mineral in cobalt sulfur concentrate. Because the cobaltsulfur concentrate mainly contains pyrite, pyrrhotite, and some gangue minerals such as talcum, quartz, and chlorite, it is difficult to obtain separate cobalt and sulfur concentrates. Most cobalt minerals are associated with other metal minerals. At present, the main cobalt minerals to be processed include cobaltite, skutterudite, thiocopper cobalt, thiocobaltite, nickel cobalt, cobaltite, iron manganese combined cobalt, etc. The most common process to recover cobalt minerals is flotation, which also includes manual separation and gravity separation. Single cobalt minerals, such as cobaltite and thiocobaltite, can be directly obtained from cobalt concentrate by flotation; for cobalt existing in pyrite and chalcopyrite, carrier flotation is generally used, and cobalt concentrate cannot be directly obtained. Recovery of associated cobalt in V-Ti-magnetite is essentially a mixture of pyrite, pyrrhotite, cobaltite, and thiocobaltite. The recovery of valuable metals from cobalt-bearing sulfur concentrate is usually carried out by the combination of pyrometallurgy and hydrometallurgy [3][4][5][6]. For example, the main disadvantage of direct sulfuric acid roasting in the Shandong Zibo cobalt plant is that the treatment capacity is low (3.0 t/m 2 •d), and the SO2 content in the flue gas is only 4-5%, which is not conducive to acid production. Aiming at the roasting leaching of cobalt sulfur concentrate with high cobalt content, low sulfur content, and a considerable amount of copper, the effects of roasting temperature, roasting time, additive dosage, leaching time, leaching temperature, and liquid-solid ratio were analyzed to investigate the influence of the leaching rates of copper and cobalt. After the cobalt-sulfur concentrate was mixed evenly, the temperature was raised to 620 °C at 2.7 °C/min, calcined for 3 h, and the calcine was leached at 80 °C with 33% slurry concentration of 30 g/L sulfuric acid for 2 h, the results showed leaching rates of Co and Cu of 91% and 90% respectively. The cobalt sulfur concentrate was oxidized roasted at 850-900 °C, and the cinder was mixed with some cobalt sulfur concentrate and chlorinating agent to carry out medium-temperature chlorination sulfuric acid roasting at about 650 °C. This way had a high bed capacity (17-18 t/m 2 •d), but the SO2 concentration in the flue gas was only 1-2%, which is difficult for acid production, and there was a certain amount of hydrogen chloride gas in the flue gas, which will lead to serious corrosion of the equipment [7][8][9][10].
There is a large amount of valuable mineral resources in the Panxi area of China, and the proven reserves of V-Ti magnetite are 10 billion tons. Among them, iron resources account for 20% of the domestic iron ore reserves, vanadium resources account for 62% of the national vanadium reserves, and titanium resources account for 90.5% of the national titanium reserves. In addition, there are 900,000 tons of cobalt, 700,000 tons of nickel, 250,000 tons of scandium, 180,000 tons of gallium, and other resources. The comprehensive utilization rate of nonferrous metal resources in the Panxi area of China is very low. Because of the low grade and scattered distribution, it is difficult to recover the sulfur and cobalt resources directly from the raw ore. Most of the associated valuable metal cobalt in V-Ti magnetite occurs in the form of pyrite, pyrrhotite, and cobaltite, and a very small amount of cobalt occurs in the form of thiocobaltite. Because the floatability difference among pyrite, pyrrhotite, cobalt nickel pyrite, and thiocobaltite is small, they basically exhibit the surface properties of pyrite minerals, so it is difficult to recover separate minerals by flotation.
At present, iron concentrate, titanium concentrate, and cobalt-bearing sulfur concentrate are obtained from V-Ti magnetite ores in the Panxi area of China by magnetic separation and flotation. In the process of flotation, cobalt enters into sulfur concentrate, which is closely related to pyrite. Generally, Co-bearing sulfur concentrate with a cobalt grade of about 0.6% can be enriched by flotation. It is difficult to further separate cobalt and sulfur using flotation or other physical beneficiation. In this paper, a technology of two-stage roasting and magnetic separation is adopted to extract cobalt and iron from the complex Co-bearing sulfur concentrate in the Panxi area of China. This will provide an important research basis for the efficient utilization of Co-bearing sulfur concentrate resources in Panxi [11][12][13][14].

Sampling
The Co-bearing sulfur concentrate sample was collected from a V-Ti magnetite dressing plant by flotation in the Panzhihua area of China. The Co-bearing sulfur concentrate contained Co 0.68%, Fe 33.26%, and S 36.58%. Pyrite was the main sulfide ore. Co-pyrite and linneite were Co-bearing minerals. Gangue minerals were mica, chlorite, feldspar, calcite, etc., in the Co-bearing concentrate. The main chemical composition analysis of the sample is shown in Table 2. The main mineral analysis of the sample is shown in Table 3, a grain-sized analysis of the sample is shown in Table 4, and the XRD analysis of the sample is shown in Figure 1.

Chemical Reagent and Equipment
The main chemical reagents used in this test were calcium chloride and sodium chloride with analytical purity from Guangzhou Chemical Regent, Co., Ltd., Guangzhou China. The coke from Shanxi Coking Coal Group Co. Ltd (Taiyuan, China). was crushed and divided into five particle sizes of −1 mm, −0.8 mm, −0.6 mm, −0.4 mm, and −0.2 mm as reducing agents in the process of segregation roasting. The entire quality analysis of coke is shown in Table 5.

Oxidizing Roasting Test
Oxidizing roasting tests were conducted in an electric atmosphere tube furnace, and Co-bearing sulfur concentrate was put into a corundum dry pot and put into the electric atmosphere tube furnace. The temperature was set to 600-1000 °C in an oxygen atmosphere. When the temperature of the electric atmosphere tube furnace rose to the set temperature, timing started. After roasting for 1-3 h, the oxygen supply was stopped, and the power supply was turned off. Meanwhile, the oxygenpassing tube was pulled out, and the roasting product was taken out for cooling, manual crushing, and grinding to <0.100 mm for segregation roasting. The oxidizing roasting conditions were confirmed to be reasonable according to the analysis of cobalt, iron, and sulfur contents in oxidizing roasting ores. Calculation of the desulfurization rate is shown in Formula (1).
Here, Q1 is the weight of Co-bearing sulfur concentrate, g; Q2 is the weight of oxidizing roasting ore, g; α is the sulfur content of Co-bearing sulfur concentrate, %; and β is the sulfur content of oxidizing roasting ore, %.

Segregation Roasting-Magnetic Separation Test
The Co-bearing concentrate, the chlorinating agent, and reducing agent were mixed and put into the roasting furnace. These mixtures were heated to a certain temperature (400-1100 °C) under a neutral or weak reducing atmosphere, where the chlorinating agent was used to form volatile metal chlorides. For each magnetic test, segregation roasting ores were put into a 6.25 dm 3 Φ 240 × 90 conical ball mill. The grinding density was set at 60%. The pulp was then placed in a XCGS-13(Φ 50, Overall dimensions 1000 × 800 × 500 mm) Davis Magnetic Tube (Jilin Exploration Machinery Plant, Shenyang China) with special magnetic field intensity. The products were filtered, dried, weighed, sampled, and tested for further evaluation based on the grade and recovery of cobalt and iron in magnetic products. The calculation formulas of cobalt recovery and iron recovery are shown in Formula (2).
Here, Q3 is the weight of cobalt concentrate, g; Q4 is the weight of iron concentrate, g; Q0 is the weight of segregation roasting ores, g; β1 is the cobalt grade of cobalt concentrate, %; β2 is the iron grade of cobalt concentrate, %; α1 is the cobalt grade of segregation roasting ores, %; and α2 is the iron grade of segregation roasting ores, %.

Procedure
The Co-bearing sulfur concentrate (mass of 100 g for each test) was placed in a tubular atmosphere furnace for oxidizing roasting. The reaction of the sulfide ore and oxygen was reversed to oxidize the ore, and the metals such as iron and cobalt were transformed into iron oxide and cobalt oxide. Oxidizing roasting ore (mass of 50 g for each test) after cooling, chlorinating agent, and coke were mixed and put into the muffle furnace for segregation chlorination roasting, which turned cobalt into a new metal cobalt mineral phase and iron into a new magnetite mineral phase. Metal cobalt is a ferromagnetic metal, and magnetite is a highly magnetic minerals. The specific magnetic susceptibility of cobalt metal is greater than the magnetic susceptibility of magnetite. Cobalt was recovered from segregation after grinding with a magnetic separator; iron was recovered from magnetic separation tailings by two-stage magnetic separation. The process of oxidizing roastingsegregation roasting-magnetic separation is shown in Figure 2.

Analysis and Characterization
The chemical composition of solid materials was analyzed by a Z-2000 atomic absorption spectrophotometer (Hitachi Co., Ltd. Tokyo, Japan); the direction grating was Zenier-tana type, 1800 lines/mm; the flash wavelength was 200 nm, the wavelength range was 190~900 nm; and the automatic peak seeking setting and the spectral bandwidth was divided into 4 grades (0.2, 0.4, 1.3, and 2.6 nm) to analyze the chemical composition of the mineral.

Effect of Roasting Temperature
The roasting temperature test was conducted to investigate the influence of sulfur removal under the conditions employed, which were roasting time of 2 h and oxygen content of 80%, and the results are shown in Figure 3.
In the oxidizing roasting process, the ignition point of pyrite was generally about 400 °C, but the temperature fluctuated with the chemical composition of the material. When the temperature rose to 900 °C, the sulfur content in the oxidizing roasting ore was the lowest (10.52%), and the desulfurization rate was 71.24%. When the temperature increased from 900 °C to 1000 °C, the sulfur content in the oxidized roasted ore increased to 14.36%, and the desulfurization rate was 60.74%. Therefore, the oxidizing roasting temperature of 900 °C was reasonable.

Effect of Roasting Time
Tests with different roasting times were carried out to investigate the influence of sulfur removal under the conditions employed, which were roasting temperature of 900 °C and oxygen content of 80%, and the results are shown in Figure 4.
Prolonging the roasting time was conducive to the removal of sulfur, but when the roasting time was more than 3.0 h, the sulfur content in the roasting ore increased regularly. Therefore, 3.0 h was suitable for oxidizing roasting, and 4.85% sulfur-bearing oxidizing roasting ore could be obtained with a desulfurization rate of 86.74%.

Effect of Roasting Atmosphere
Tests under various atmospheric conditions were conducted to investigate the influence of sulfur removal under the conditions employed, which were roasting temperature of 900 °C and roasting time of 3.0 h, and the results are shown in Figure 5.
It is known from Figure 5 that the increase in oxygen content had an obvious effect on the removal of sulfur. With the increase of oxygen content, the sulfur content in the oxidizing roasting ore decreased gradually and tended to be stable at 70% oxygen or higher. This shows that the Cobearing sulfur concentrate needs an oxygen-enriched atmosphere for oxidizing roasting. The oxygen content was 80%, the sulfur content in the oxidizing roasting ore was 0.63%, and the desulfurization rate was 98.28%. Compared with the sulfur content in the Co-bearing sulfur concentrate, the desulfurization effect was remarkable. The sulfides effectively transformed into oxides, and favorable conditions were created for the separation and extraction of cobalt and iron.

Analysis and Characterization of Oxidizing Roasting Ores
Repeated tests were conducted using the comprehensive conditions employed, which were Cobearing sulfur concentrate mass of 500 g, oxidizing roasting temperature of 900 °C, oxidizing roasting time of 3.0 h, and oxygen content of 80%. Moreover, the multiple oxidizing roasting ore times were merged into a comprehensive sample for analysis and characterization, and cobalt and iron were extracted by magnetic separation of samples. The main chemical composition of oxidizing roasting ores is shown in Table 6, and the main minerals of oxidizing roasting ores by X-ray diffraction (XRD) are shown in Figure 6.  Results in Table 6 show that the sulfur content in the oxidizing roasting ore obtained from the repeated test under comprehensive conditions was 0.62%, which is basically consistent with the desulfurization effect of the single-condition test and also shows that the obtained oxidizing roasting conditions are repeatable. XRD mineral composition showed that, after the oxidizing roasting of cobalt-bearing sulfur concentrate, cobalt changed from Co-pyrite and linneite to a CoFe2O4dominated new cobalt mineral phase, and iron changed from pyrite to Fe2O3 and an Fe3O4-dominated new iron mineral phase. At the same time, new gangue mineral phases such as Mg3Si4O10 (OH)2 and Ca3Fe3(SiO4)3 also appeared.

Effect of Chlorinating Agent Dosage
Calcium chloride and sodium chloride tests with varies dosages were conducted to investigate the influences of cobalt grade and recovery. The conditions employed were roasting temperature of 900 °C, roasting time of 60 min, coke dosage of 8%, coke size of <0.6 mm, magnetic separation grinding fineness of <60 μm occupying 85%, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 7.
During the segregation roasting process, the chlorinator reacts with SiO2, Al2O3, and other acid oxides and H2O in the ore to generate hydrogen chloride gas. The valuable metal cobalt and iron react with hydrogen chloride to produce CoCl2 and FeCl2. Because CoCl2 and FeCl2 are unstable, they are easily reduced to metal particles by H2 and adsorb on the surface of coke; meanwhile, hydrogen chloride gas will react with its elements in chlorination, with too much or too little dosage, which will affect the separation and extraction of cobalt and iron. The grade and recovery of cobalt concentrate can be improved by increasing the amount of calcium chloride or sodium chloride [15]. When the amount of calcium chloride was 6%, the highest cobalt grade was 6.22%, but the lowest recovery was 66.14%; when the amount of calcium chloride was 12%, the highest recovery of cobalt was 82.11%, and the cobalt grade was 4.12%. When sodium chloride was used as the chlorinating agent, the grade of cobalt was lower than 3%, and the recovery of cobalt was lower with the increase of dosage. The results showed that calcium chloride was suitable as chlorinating agent, taking into account cobalt grade and cobalt recovery, and the amount of calcium chloride was 12%.

Effect of Roasting Temperature
Tests with different temperatures were conducted to investigate the influence of cobalt grade and recovery. The conditions employed were roasting time of 60 min, calcium chloride dosage of 12%, coke dosage of 8%, coke size of < 0.6 mm, magnetic separation grinding fineness of < 60 μm occupying 85%, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 8. Figure 8 shows that the roasting temperature was also one of the key factors to determine whether the separation process was going on. Raising the temperature is conducive to the reaction and accelerating the reaction rate. If the temperature is too low to reach the critical point of the chemical reaction of the ore, this will result in slow or difficult chemical reaction process [16,17]. With the increase of roasting temperature, the grade of cobalt increased, and the recovery of cobalt increased first and then decreased. When the temperature increased to 950 °C, the grade of cobalt increased to 7.63%, and the recovery rate of cobalt was 85.47%; when the temperature increased to 1000 °C, the grade of cobalt increased to 8.23%, but the recovery rate of cobalt decreased to 71.81%. At the same time, it was found that when the temperature of segregation roasting was 1000 °C, the segregation roasting ore was in a melting state, and obvious metal particles appeared, so it was difficult to grind the material to a particle size less than 60 μm. Therefore, 950 °C was suitable for segregation roasting, and cobalt concentrate with cobalt grade of 7.63% and recovery of 85.47% could be obtained.

Effect of Roasting Time
Tests with different segregation roasting times were conducted to investigate the influence of cobalt grade and recovery. The conditions employed were roasting temperature of 950 °C, calcium chloride dosage of 12%, coke dosage of 8%, coke size of <0.6 mm, magnetic separation grinding fineness of <60 μm occupying 85%, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 9.  Figure 9 show that the cobalt grade and recovery rate increased first and then decreased as time continued. The reason for this phenomenon is that the chemical reactions in the segregation roasting process are mainly divided into decomposition, chlorination, and reduction, but decomposition, chlorination, reduction, and other reactions are not only sequential chemical reactions, they are also complex phase changes. The segregation roasting time mainly affects the degree of chemical reaction in the process of segregation roasting. The longer the segregation roasting time, the more the chemical reaction is complete. However, the shorter the segregation roasting time, the less complete the effective chemical reaction is [18,19]. For this, it is difficult to achieve the ideal separation effect. Considering that the separation roasting time was 75 min, a cobalt concentrate with a cobalt grade of 7.72% and a cobalt recovery of 86.79% could be obtained.

Effect of Coke Dosage
Tests with varies coke dosages were carried out to investigate the influence of cobalt grade and recovery. The conditions employed were roasting temperature of 950 °C, roasting time of 75 min, calcium chloride dosage of 12%, coke size of <0.6 mm, magnetic separation grinding fineness of <60 μm occupying 85%, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 10. Figure 10 reveals that the solid reducing agent was mainly used for coke, lignite, anthracite, bituminous coal, and charcoal, among which coke was most commonly used. Because of more impure elements in coal, this will produce certain ash and affect the product quality. Charcoal from wood is generally used for beneficiation or smelting of precious metals. When the amount of coke increased to 10%, the highest cobalt grade was 7.52%, and the recovery rate of cobalt was 87.85%. When the amount of coke exceeded 10%, the grade of cobalt decreased obviously, and the recovery rate of cobalt increased to a certain extent. Because coke is a reduction carrier for volatile metal chloride in the process of chlorination segregation roasting, and it adjusts the atmosphere of chlorination and segregation properly, too much or too little coke will affect the grade and recovery of cobalt. Therefore, it was reasonable to use 10% coke.

Effect of Coke Size
A coke size test was conducted to investigate its influence on cobalt grade and recovery. The conditions employed were oxidizing roasting ore mass of 50 g, roasting temperature of 950 °C, roasting time of 75 min, calcium chloride dosage of 12%, coke dosage of 10%, magnetic separation grinding fineness of <60 μm occupying 85%, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 11.
The specific surface area (as = As/m) is an important index in measuring the adsorption capacity of coke. The smaller the coke particle size, the stronger its adsorption capacity. Figure 11 shows that with the decrease of coke particle size, the grade of cobalt increased, and the recovery of cobalt increased first and then decreased. In the process of segregation roasting, the reductant can adjust the atmosphere for chloride separation and absorb and reduce the volatile metal chloride [19,20].

Recovery (%)
Therefore, coke was used as the reducing agent and the carrier of adsorbing metal particles in the process of separation and roasting. Too much or too little coke is not conducive to the separation and extraction of cobalt. The size of coke was < 0.4 mm, which was suitable to obtain a cobalt concentrate with a cobalt grade of 9.03% and a cobalt recovery of 87.77%. Figure 11. Effect of coke size on cobalt extraction.

Effect of Magnetic Separation Conditions of Segregation Roasting Ores
The grinding fineness and magnetic field intensity are important factors that affect cobalt grade and cobalt recovery in the magnetic separation process of segregation roasting ores. Reasonable grinding fineness and magnetic field intensity are beneficial to improve the separation and extraction index of cobalt. Magnetic separation fineness grinding of segregation roasting ores was conducted to investigate its influence on cobalt grade and recovery, and the conditions employed were segregation roasting temperature of 950 °C, segregation roasting time of 75 min, calcium chloride dosage of 12%, coke dosage of 10%, coke size of <0.4 mm, and magnetic separation field intensity H1 = 0.06 T, and the results are shown in Figure 12a. Grinding fineness is the key factor that reflects the degree of dissociation of the mineral monomer, and basic dissociation of the mineral is the primary factor to realize mineral separation. In the process of magnetic separation, it is beneficial to improve the cobalt grade of cobalt concentrate. Figure 12a shows that 90% of particles finer than 60 μm were suitable for cobalt magnetic separation, and cobalt concentrate with a cobalt grade of 15.63% and cobalt recovery of 82.38% were obtained. If the grinding fineness is too high, the recovery rate of cobalt concentrate decreases significantly, and the particle size becomes smaller.

Recovery (%)
In the process of magnetic separation, the effect of external forces becomes more obvious. To improve the magnetic separation index, the field intensity of magnetic separation needs to be changed. A magnetic separation field intensity test for the segregation roasting ores was conducted to investigate the influence of cobalt grade and recovery. The conditions employed were oxidizing roasting ore mass of 50 g, segregation roasting temperature of 950 °C, segregation roasting time of 75 min, calcium chloride dosage of 12%, coke dosage of 10%, coke size of <0.4 mm, and magnetic separation grinding fineness of <60 μm occupying 90%, and the results are shown in Figure 12b.
With the increase of magnetic field intensity, the grade of cobalt decreased and the recovery of cobalt increased. In the process of magnetic separation, different magnetic minerals received the combined action of magnetic field force, gravity, medium resistance, and other external mechanical forces in the magnetic field. When the magnetic field force of the mineral particles is greater than the mechanical external force, they will enter the magnetic products and become the concentrate; otherwise, they will enter the non-magnetic products and become the tailings. Therefore, the magnetic field intensity H1 = 0.08 T was suitable, and the cobalt concentrate with cobalt grade of 15.13% and cobalt recovery of 90.04% was obtained.

Iron Extraction from Cobalt Magnetic Separation Tailings by Magnetic Separation
The magnetism of new cobalt minerals and iron minerals was different in segregation roasting ores, and the effective extraction index of cobalt was obtained from segregation roasting ores by onestage magnetic separation. Extraction of iron from cobalt magnetic separation tailings was conducted by changing the magnetic field intensity using second-stage magnetic separation. Different magnetic separation field intensity (H2) tests were investigated, and the test results are shown in Figure 13.
The iron recovery rate of iron concentrate improved by increasing the magnetic field intensity, and the iron grade in Figure 13 reveals a regular increase as the magnetic field intensity decreased. The existing iron and steel enterprises require that the iron grade of iron and steel concentrate is more than 55%, so the magnetic field intensity is H2 = 0.14 T, which is suitable to obtain iron concentrate with iron grade of 60.02% and iron recovery of 80.01%.

The Entire Co, Fe Extraction Process Test
The entire process of cobalt and iron extraction was conducted to investigate the influence of cobalt grade and recovery, and the conditions employed were oxidizing roasting temperature of 900 °C, oxidizing roasting time of 3.0 h, oxygen content of 80%, segregation roasting temperature of 950 °C, segregation roasting time of 75 min, calcium chloride dosage of 12%, coke dosage of 10%, coke size of <0.4 mm, magnetic separation grinding fineness of <60 μm occupying 90%, cobalt magnetic separation field intensity H1 = 0.08 T, and iron magnetic separation field intensity H2 = 0.14 T. The results are shown in Tables 7-9.   Tables 7-9 show the extraction effects of cobalt and iron from Co-bearing sulfur concentrate in the Panxi area using the oxidizing roasting-segregation roasting-magnetic separation process. Cobalt concentrate with Co grade of 15.15%, Fe content of 71.22%, and cobalt recovery of 90.81% as well as iron concentrate with Fe grade of 60.06%, Co content of 0.11%, and iron recovery of 76.23% were obtained. The content of harmful elemental sulfur in the iron concentrate was also lower, which met the product quality requirements for highly efficient extraction and separation of valuable metal cobalt and iron. Sulfur was produced in the form of SO2 in the oxidizing roasting process, which can be used as an important raw material for the preparation of sulfuric acid.

Cobalt and Iron Phase Transformation in the Segregation Roasting Process
Analysis and characterization of segregation roasting ores, cobalt concentrate, and iron concentrate were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy spectroscopy (EDS) to find out the mineral phase evolution of cobalt minerals and iron minerals. XRD phase analysis results of cobalt concentrate and iron concentrate are shown in Figure  14. SEM and EDS images of cobalt and iron minerals are shown in Figure 15.
According to the existing kinetic mechanism, the separation roasting stage can be divided into five stages. (1) Solid phase sintering reaction stage: oxidizing roasting, chlorinating agent, and reducing agent are dried at low temperature and then put into the baking furnace. Before chlorination segregation roasting, the pellet sintering process is shown, which is actually a series of solid-phase sintering reactions. (2) Decomposition stage: this stage is mainly the decomposition reaction of calcium chloride to form hydrogen chloride gas with strong activity, The reaction of the reducing agent and water vapor produces hydrogen and carbon monoxide. A catalyst promotes the positive reaction direction of the separation process to proceed rapidly. (3) Gas-solid reaction stage: the ore is still in the solid state because the separation roasting temperature is at 950 °C, which is not high enough for the softening point is more of a gas-solid reaction. Hydrogen chloride gas with strong volatilization activity reacts rapidly with metal in ores to form volatile chloride, and the decomposition pressure of various metal chlorides is different. The promotion and inhibition of catalysts and promoters can improve the volatilization rate of the metal cobalt target. (4) Reduction adsorption stage: the formation of volatile metal chlorides through the gas-solid phase reaction forms a strong physical and chemical adsorption on the surface of the reducing agent. The decomposition pressures of various volatile metal chlorides are high and low, and the corresponding double effects of adsorption and reduction on the surface of the reducing agent form fine metal particles. (5) New phase formation stage: the size of metal particles formed in the early stage of new phase formation is very fine, the corresponding specific surface area is large, and the fine particles themselves have strong adsorption, which belongs to the thermodynamic instability system. Then, the ʺmetal coreʺ in the early stage makes the metal particles formed in the later stage continuously rearrange and pile up, and the crystal particles grow, finally forming a certain size of metal particle compounds [21][22][23][24][25].
After the separation roasting of oxidized roasted ore, cobalt changes from CoFe2O4 to a new cobalt mineral phase dominated by a [Co] Fe solid solution; iron changes from Fe2O3 to a new iron mineral phase dominated by metal Fe and Fe3O4. Cobalt and iron belong to ferromagnetic metals. Magnetite belongs to strong magnetic minerals, and their specific magnetization coefficients are different to some extent. The main minerals in the cobalt concentrate obtained from the separation roasting ore after grinding were Fe, [Co]Fe, Fe3O4, and SiO2; the main minerals in the iron concentrate obtained from the second-stage magnetic separation were Fe3O4, FeO, Ca2Si2O4, and Ca2Al2O4. In the process of magnetic separation, a small amount of gangue minerals such as SiO2, Ca2Si2O4, and Ca2Al2O4 entered into cobalt concentrate and iron concentrate as a result of mechanical entrainment. Therefore, there are many complex phase changes in the segregation roasting process. Combined with the analysis results, the possible chemical reactions in the segregation roasting process are shown in Equations (3) (7) CoCl2 + H2 → Co + HCl (8) FeCl3 + 3H2 → 2Fe + 6HCl (9) 2Co + 2FeCl3 + 3H2→ 2[Co]Fe + 6HCl (10) In the system, the relationship between the difficulties in the reduction of iron cobalt metal chloride is FeCl3 < CoCl2, and cobalt is a kind of iron-soluble oxide. FeCl3 itself is a kind of chlorinating agent, promoting the chlorination and segregation of cobalt, and forms the solid solution of [Co] Fe.

Conclusions
(1) The refractory Co-bearing sulfur concentrate sample was collected from a V-Ti magnetite dressing plant by flotation in the Panzhihua area of China, and the Co-bearing sulfur concentrate contained Co 0.68%, Fe 33.26%, and S 36.58%. Pyrite was the main sulfide ore; Co-pyrite and linneite were Co-bearing minerals; gangue minerals were mica, chlorite, feldspar, calcite, etc., in Co-bearing concentrate.
(2) A new process of oxidizing roasting-segregation roasting-magnetic separation is used to process the complex Co-bearing sulfur concentrate. The cobalt concentrate with Co of 15.15%, Fe 71.22%, and cobalt recovery of 90.81% as well as iron concentrate with Fe of 60.06%, Co of 0.11%, and iron recovery of 76.23% were obtained under the comprehensive conditions of oxidizing roasting temperature of 900 ℃, oxidizing roasting time of 3.0 h, oxygen content of 80%, segregation roasting time of 950 °C, segregation roasting time of 75 min, calcium chloride dosage of 12%, coke dosage of 10%, coke size of <0.4 mm, magnetic separation grinding fineness of <60 μm occupying 90%, cobalt magnetic separation magnetic field intensity of H1 = 0.08 T, and iron magnetic separation intensity of H2 = 0.14 T. Extraction of cobalt and iron is obvious.
(3) The results of cobalt and iron phase transformations show that cobalt is transformed from Co-pyrite and linneite to a Co2FeO4-dominated new cobalt mineral phase. Iron is transformed from pyrite to Fe2O3 and an Fe3O4-dominated new iron mineral phase after oxidizing roasting. Sulfur is produced in the form of SO2 after oxidizing roasting; cobalt changed from CoFe2O4 to a new cobalt mineral phase dominated by [Co]Fe solid solution. Iron changed from Fe2O3 to a new iron mineral phase dominated by metal Fe and Fe3O4 after segregation roasting.
(4) SEM, EDS, and XRD analyses of segregation roasting ores, cobalt concentrate, and iron concentrate show that the main minerals in cobalt concentrate are Fe, [Co] Fe, and a small amount of Fe3O4; the main minerals in iron concentrate are Fe3O4 and FeO; and there was a small amount of gangue minerals such as SiO2, Ca2Si2O4, and Ca2Al2O4 in the cobalt concentrate and iron concentrate because of mechanical entrainment.