Effect of Cold-Spray Parameters on Surface Roughness, Thickness and Adhesion of Copper-Based Composite Coating on Aluminum Alloy 6061 T6 Substrate

: A solid-state cold-spray technique was employed for depositing the copper-coated graphite reinforced copper-based composite coatings on aluminum alloy 6061 T6 substrate under different process parameters. The optimum process parameters of the cold-sprayed coatings were predicted in terms of surface roughness, thickness and adhesion. The surface roughness was measured using a 3D proﬁlometer, the thickness and element constitution were detected by an optical microscope and scanning electron microscope furnished with an energy-dispersive spectral analyzer and the adhesion was detected by the scratch test method. The microstructures of the deposited coatings were also observed by a scanning electron microscope. The results show that when the coating is not oxidized and dense, the copper-coated graphite reinforced copper-based composite coating at 800 ◦ C, 5.5 MPa, possesses the lowest surface roughness, the maximum thickness and the highest adhesion among the cold-sprayed coatings. In addition, the surface roughness, thickness and adhesion of the deposited coatings are all linear with particle velocity.


Introduction
Owing to light weight, high toughness, excellent processing performance, good electrical conductivity and thermal conductivity and relatively low cost, aluminum alloys are widely used in various industrial applications, such as military and civil buildings, automobile and aircraft manufacturing industries [1,2].However, aluminum alloys suffer disadvantages in terms of low hardness, poor wear resistance and easy deformation [3].It is necessary that a suitable surface modification treatment technique is adopted to promote electrical conductivity, wear resistance and surface hardness of aluminum alloy.Coppercoated graphite reinforced copper-based composites (Cu@Gr/CBC) overcome the problem of no wetting between copper (Cu) and graphite, and combine attractive properties of Cu and graphite, exhibiting high electrical conductivity, good thermal conductivity and a low friction coefficient [4,5].Therefore, Cu@Gr/CBC coatings are suitable as coatings deposited on aluminum alloys to promote electrical and mechanical properties of aluminum alloys.
There are diverse vital issues that determine the quality of deposited coatings, such as surface roughness, thickness, adhesion, and so on.It is crucial to find these optimal preparation conditions for producing a high-quality coating on a substrate.The adhesion between coating and substrate is a complex phenomenon and depends on the preparation parameters.To control the numerous parameters of CS (related to spray parameters and feedstock powder), adhesion between coating and substrate can be promoted [21].Based on the above-mentioned point, it is necessary to apply an appropriate method to assess coating adhesion.There are some methods to examine the adhesive property of the coatings, such as the tensile test [22], the hang test with a kettle bell [23], the scratch test [24], the indentation test [25], the peel test [26] and the blister test [27].An examination approach to the adhesion of coatings relies on the sort of coating and the substrate.Among the diverse approaches, the scratch test is one of the quickest and most effective methods to determine the coating adhesion [28].The scratch test with a cone-shaped or Berkovich indenter is a widely applied technology to detect the adhesion between the coating and substrate [29][30][31][32].The scratch test technique was adopted to test the single-lane and single-layer coatings in this work.
For producing high-quality Cu@Gr/CBC coatings on aluminum alloy 6061 T6 (AA6061 T6) substrate, it is necessary to study the single-lane and single-layer coatings first.In this study, single-lane and single-layer coatings were deposited to an AA6061 T6 substrate at various spraying parameters by CS technology.The appearance, surface roughness, thickness, element constitution and adhesion of the coatings were examined with the corresponding testing techniques.

Experimental Details
AA6061 T6 (Jiangsu Annan Metal Product Co., Ltd., Xinghua, China) plate of size 100 × 100 × 3 mm was used as the substrate material, having the chemical composition presented in Table 1.Before the deposition process, all substrate surfaces were ground with an SJK 9070F dry sand blasting machine, followed by ultrasonic cleaning with alcohol.A water-atomized Cu powder (99.99%,Nangong City Chunxu Metal Material Factory, Xingtai, China) with a volume-weighted mean particle size of 17.4 µm was used, and electroplated Cu-coated graphite (Cu@graphite) powder (30 wt.% graphite, Nangong City Jinnuo Welding Material Co., Ltd., Xingtai, China) with a volume-weighted average particle size of 18.6 µm was used as the reinforcement.Cu and Cu@graphite powder mixtures of 7 wt.%Cu@graphite powder were homogenized in a QM-QX-4L MITR ball mill for 1 h with a PTFE container and agate balls.The morphology and microstructure of the mixture powders were characterized by scanning electron microscopy (SEM, Hitachi S-4800, Hitachi Ltd., Tokyo, Japan).The phases of the mixture powders were detected using an X-ray diffractometer (XRD, Bruker D8 Advance, Bruker Corp., Billerica, MA, USA) with Cu K α radiation in the 2θ range of 10-90 • at 3 • per minute scanning speed and 0.02 • scanning step.The particle size distribution of the mixture powders was represented by a laser diffraction sizer (Mastersizer3000, Malvern Instruments Ltd., Malvern, UK).The single-lane and single-layer Cu@Gr/CBC coatings were prepared by a cold-spray PCS-100 system (Plasma Giken Co., Ltd., Osato, Saitama, Japan) furnished with a PNFC-010 convergent-divergent (de-Laval type) nozzle, and N 2 was applied as an accelerating gas, as shown in Figure 1.The spray gun was shifted at a line rate of 50 mm s −1 over the substrate at a constant stand-off distance of 20 mm.The gas flow of the feeding was fixed at 180 SLM for all powder blends.The gas temperature was increased from 600 • C to 900 • C, and the gas pressure was changed from 4 MPa to 5.5 MPa at each gas temperature.The specific cold-spray parameters are given in Table 2.

Elements
Si Cr Cu Fe Mn Ti Zn Mg 6061 aluminum alloy plate 0.4-0.80.04-0.350.15-0.4≤0.7 ≤0.15 ≤0.15 ≤0.25 0.8-1.2B The single-lane and single-layer Cu@Gr/CBC coatings were prepared by a cold PCS-100 system (Plasma Giken Co., Ltd., Osato, Saitama, Japan) furnished with a 010 convergent-divergent (de-Laval type) nozzle, and N2 was applied as an accel gas, as shown in Figure 1.The spray gun was shifted at a line rate of 50 mm s −1 o substrate at a constant stand-off distance of 20 mm.The gas flow of the feeding wa at 180 SLM for all powder blends.The gas temperature was increased from 600 °C °C, and the gas pressure was changed from 4 MPa to 5.5 MPa at each gas tempe The specific cold-spray parameters are given in Table 2.  Different technologies were employed to analyze surface roughness, thickne crostructure and composition of the single-lane and single-layer Cu@Gr/CBC co The surface roughness Ra of the cold-sprayed coatings was assessed via a 3D profil (Bruker Contour X 100, Bruker Corp., Billerica, MA, USA) for a resolution of 0.1 n maximum measuring range of 500 μm, installed with Bruker Vision software.E ported Ra value is an average of ten readings.To examine the thickness and stu microstructure of the coatings, the specimens were cut along the cross sections b  Different technologies were employed to analyze surface roughness, thickness, microstructure and composition of the single-lane and single-layer Cu@Gr/CBC coatings.The surface roughness Ra of the cold-sprayed coatings was assessed via a 3D profilometer (Bruker Contour X 100, Bruker Corp., Billerica, MA, USA) for a resolution of 0.1 nm and maximum measuring range of 500 µm, installed with Bruker Vision software.Each reported Ra value is an average of ten readings.To examine the thickness and study the microstructure of the coatings, the specimens were cut along the cross sections by wire cutting into a dimension of 10 mm × 10 mm × 3 mm.The cross sections of the specimens were ground with wet abrasive papers, mechanically polished to obtain mirror-polished sections, and ultrasonically cleaned in alcohol.The thickness was measured at the highest position of the coatings with a Zeiss Axio scope A1 optical microscope (OM, Carl Zeiss, Jena, Thuringia, Germany).The microstructure and element constitution were examined using OM and SEM equipped with an energy-dispersive spectral analyzer (EDS).To characterize the microstructure, etching was performed with a liquid mixture of 20 mL HNO 3 of 65% mass concentration and 80 mL C 2 H 5 OH of ≥99.7% mass concentration.
The adhesive property of the deposited coatings was examined using the scratch test method.The adhesion of the Cu@Gr/CBC coatings on AA6061 T6 substrate was determined using a WS-2005 scratch tester under 100 N total load, 100 N min −1 scratch velocity and 4 mm scratch length.The WS-2005 scratch tester was furnished with a threesided pyramidal diamond (Berkovich) indenter of 0.2 mm tip radius for scratch testing.Figure 2 shows the schematic diagram of the scratch coating adhesion test.Prior to testing, the thickness of the deposited coatings was controlled at 20 µm by grinding and measuring, and the surface of the coatings was polished to mirror.The scratch test was replicated three times for each specimen and the average value was taken as the coating adhesion.The scratch morphology was examined using SEM, and the coating adhesion was determined according to the coating shed position and the scratch length.Corresponding to the entire length of the scratch (L total ), about 4 mm, the total load is 100 N. The critical length of the scratch L c (from the beginning point of the scratch to the delaminated position of the deposited coating), is defined as the critical load that causes a failure event.The value of the critical load is taken as an adhesion of the deposited coating with the substrate.The adhesion of the coatings was calculated as L c divided by L total and multiplied by a hundred.The formula [33] is: Jena, Thuringia, Germany).The microstructure and element constitution were examined using OM and SEM equipped with an energy-dispersive spectral analyzer (EDS).To characterize the microstructure, etching was performed with a liquid mixture of 20 mL HNO3 of 65% mass concentration and 80 mL C2H5OH of ≥99.7% mass concentration.
The adhesive property of the deposited coatings was examined using the scratch test method.The adhesion of the Cu@Gr/CBC coatings on AA6061 T6 substrate was determined using a WS-2005 scratch tester under 100 N total load, 100 N min −1 scratch velocity and 4 mm scratch length.The WS-2005 scratch tester was furnished with a three-sided pyramidal diamond (Berkovich) indenter of 0.2 mm tip radius for scratch testing.Figure 2 shows the schematic diagram of the scratch coating adhesion test.Prior to testing, the thickness of the deposited coatings was controlled at 20 μm by grinding and measuring, and the surface of the coatings was polished to mirror.The scratch test was replicated three times for each specimen and the average value was taken as the coating adhesion.The scratch morphology was examined using SEM, and the coating adhesion was determined according to the coating shed position and the scratch length.Corresponding to the entire length of the scratch (Ltotal), about 4 mm, the total load is 100 N. The critical length of the scratch Lc (from the beginning point of the scratch to the delaminated position of the deposited coating), is defined as the critical load that causes a failure event.The value of the critical load is taken as an adhesion of the deposited coating with the substrate.The adhesion of the coatings was calculated as Lc divided by Ltotal and multiplied by a hundred.The formula [33] is: The unit of the coating adhesion is N.In general, adhesive failure indicates the delamination of the coating from its substrate.Therefore, the critical load describes the adhesion of the deposited coating to the substrate.

Characterization
An SEM image of the morphology and microstructure of the mixture powders used for cold-spray is shown in Figure 3a, revealing that the Cu particles presented a nearspherical surface structure, while the Cu@graphite particles had a core-shell structure.The XRD result shows that the mixture powders are composed of graphite and Cu phases The unit of the coating adhesion is N.In general, adhesive failure indicates the delamination of the coating from its substrate.Therefore, the critical load describes the adhesion of the deposited coating to the substrate.

Characterization
An SEM image of the morphology and microstructure of the mixture powders used for cold-spray is shown in Figure 3a, revealing that the Cu particles presented a near-spherical surface structure, while the Cu@graphite particles had a core-shell structure.The XRD result shows that the mixture powders are composed of graphite and Cu phases (Figure 3b).The particle size distribution of the mixture powders is presented in Figure 3c.The dimensions of the mixture powders are D10 = 9.11 µm, D50 = 20.9µm, and D90 = 44.0µm.D10, 50 and 90 indicate the maximal particle size diameter which includes 10, 50 and 90% of the specimens (volume-weighted basis).
(Figure 3b).The particle size distribution of the mixture powders is presented in Figure 3c.The dimensions of the mixture powders are D10 = 9.11 μm, D50 = 20.9μm, and D90 = 44.0μm.D10, 50 and 90 indicate the maximal particle size diameter which includes 10, 50 and 90% of the specimens (volume-weighted basis).The typical appearance of the single-lane and single-layer Cu@Gr/CBC coating on AA6061 T6 substrate at 800 °C and 5.5 MPa is shown in Figure 4a.A coating strip of 100 mm length and 6 mm width was sprayed on the AA6061 T6 substrate.Figure 4b is the microstructure of the cross-section of the deposited coating and Figure 4c is the magnified cross-sectional micrograph of the coating in Figure 4b.The coating is dense and only has a few porosities.An area scanning analysis was performed for the deposited coating at 800 °C and 5.5 MPa in Figure 4d and the result shows that Cu was not oxidized during the spraying process.However, the cold-sprayed Cu@Gr/CBC coating was oxidized at 900 °C and 5.5 MPa by EDS analysis (Figure 4f).Figures 4d and 4f are the EDS analysis results of the area noted by the rectangular boxes in Figures 4c and 4e, respectively.The typical appearance of the single-lane and single-layer Cu@Gr/CBC coating on AA6061 T6 substrate at 800 • C and 5.5 MPa is shown in Figure 4a.A coating strip of 100 mm length and 6 mm width was sprayed on the AA6061 T6 substrate.Figure 4b is the microstructure of the cross-section of the deposited coating and Figure 4c is the magnified cross-sectional micrograph of the coating in Figure 4b.The coating is dense and only has a few porosities.An area scanning analysis was performed for the deposited coating at 800 • C and 5.5 MPa in Figure 4d and the result shows that Cu was not oxidized during the spraying process.However, the cold-sprayed Cu@Gr/CBC coating was oxidized at 900 • C and 5.5 MPa by EDS analysis (Figure 4f). Figure 4d,f are the EDS analysis results of the area noted by the rectangular boxes in Figure 4c and 4e, respectively.The surface morphology of the single-lane and single-layer Cu@Gr/CBC coating at 800 °C and 5.5 MPa is uneven and undulating (Figure 4a).The Ra of the Cu@Gr/CBC coatings obtained at various spraying parameters (Table 2) is shown in Figure 5a.The Ra of the coatings was between 7.05 and 12.69 μm, and sluggishly decreased with increasing gas pressure and gas temperature.Using 3D surface morphology color mapping, the Ra was apparently projected showing affluent color changes with the interweave of deep color and light color.Figure 5b-e is the 3D surface morphology of coatings deposited at 800 °C and different gas pressures.The surface of the deposited coatings gets more and more flat with few depressions and bulges, whereas the colors of the surfaces of the cold sprayed coatings were more or less alike in the 3D surface morphology color mappings.The surface morphology of the single-lane and single-layer Cu@Gr/CBC coating at 800 • C and 5.5 MPa is uneven and undulating (Figure 4a).The Ra of the Cu@Gr/CBC coatings obtained at various spraying parameters (Table 2) is shown in Figure 5a.The Ra of the coatings was between 7.05 and 12.69 µm, and sluggishly decreased with increasing gas pressure and gas temperature.Using 3D surface morphology color mapping, the Ra was apparently projected showing affluent color changes with the interweave of deep color and light color.Figure 5b-e is the 3D surface morphology of coatings deposited at 800 • C and different gas pressures.The surface of the deposited coatings gets more and more flat with few depressions and bulges, whereas the colors of the surfaces of the cold sprayed coatings were more or less alike in the 3D surface morphology color mappings.The thickness of the single-lane and single-layer Cu@Gr/CBC coatings deposited on AA6061 T6 substrate with varying cold spray parameters is presented in Figure 6.The thickness of the deposited coating increases significantly with increasing gas pressure and gas temperature.This is due to the higher the cold spray parameters (gas pressure and gas temperature) chosen, the more the powder materials in the stagnation zone are decelerated [34].The highest thickness is 175.6 μm for the deposited coating at 900 °C and 5.5 MPa, and the lowest thickness is 72.8 μm for the deposited coating at 600 °C and 4 MPa.This indicates that the quantity of the deposited mixture powders of Cu and Cu@graphite increases with the increase in gas pressure and gas temperature.The quantity of the deposited mixture powders is maximum for the cold-sprayed coating produced at 900 °C and 5.5 MPa, and the quantity of the deposited mixture powders is minimum for the coldsprayed coating produced at 600 °C and 4 MPa. Figure 6b-e are OM images for the thickness of coatings deposited at 800 °C and different gas pressures.It can obviously be seen The thickness of the single-lane and single-layer Cu@Gr/CBC coatings deposited on AA6061 T6 substrate with varying cold spray parameters is presented in Figure 6.The thickness of the deposited coating increases significantly with increasing gas pressure and gas temperature.This is due to the higher the cold spray parameters (gas pressure and gas temperature) chosen, the more the powder materials in the stagnation zone are decelerated [34].The highest thickness is 175.6 µm for the deposited coating at 900 • C and 5.5 MPa, and the lowest thickness is 72.8 µm for the deposited coating at 600 • C and 4 MPa.This indicates that the quantity of the deposited mixture powders of Cu and Cu@graphite increases with the increase in gas pressure and gas temperature.The quantity of the deposited mixture powders is maximum for the cold-sprayed coating produced at 900 • C and 5.5 MPa, and the quantity of the deposited mixture powders is minimum for the cold-sprayed coating produced at 600 • C and 4 MPa. Figure 6b-e are OM images for the thickness of coatings deposited at 800 • C and different gas pressures.It can obviously be seen that the coating thickness increases with the increasing gas pressure.The porosities of the deposited coatings showed little difference.
Processes 2023, 11, x FOR PEER REVIEW that the coating thickness increases with the increasing gas pressure.The porosities deposited coatings showed little difference.The microstructures of the corroded specimens of the cold-sprayed coatings ited at different cold-spray parameters were further observed in higher magnificatio SEM micrographs in Figure 7 show the cross-sectional microstructures of the sing and single-layer Cu@Gr/CBC coatings deposited on the AA6061 T6 substrate.It clearly seen that the compaction of the deposited Cu@Gr/CBC coatings decrease decreasing the working pressure and temperature of the cold spray process gas, the deformation of the powder particles used for deposition has the same trend with th paction of the deposited Cu@Gr/CBC coatings.The micrographs in Figure a3,b1,b2,c1) show that the mixture particles of Cu and Cu@graphite are heavily def during the deposition, which indicates that the particles have been successfully a The microstructures of the corroded specimens of the cold-sprayed coatings deposited at different cold-spray parameters were further observed in higher magnification.The SEM micrographs in Figure 7 show the cross-sectional microstructures of the single-lane and single-layer Cu@Gr/CBC coatings deposited on the AA6061 T6 substrate.It can be clearly seen that the compaction of the deposited Cu@Gr/CBC coatings decreases with decreasing the working pressure and temperature of the cold spray process gas, the plastic deformation of the powder particles used for deposition has the same trend with the compaction of the deposited Cu@Gr/CBC coatings.The micrographs in Figure 7(a1-a3,b1,b2,c1) show that the mixture particles of Cu and Cu@graphite are heavily deformed during the deposition, which indicates that the particles have been successfully accelerated to or above the critical velocity by the propellant N 2 gas.However, the micrographs in Figure 7(b3,c2,c3,d1-d3) are more or less not dense.Figure 8 presents the element scanning maps of the area noted by rectangular box in the deposited Cu@Gr/CBC coating on AA6061 T6 substrate at 800 • C, 5.5 MPa (Figure 7(b1)).The result of EDS mapping is that the irregular black area in the gray area is composed of a C element and the gray area is composed of a Cu element.This indicates that the irregular black area is the deformed graphite.
Processes 2023, 11, x FOR PEER REVIEW 9 of 16 the irregular black area in the gray area is composed of a C element and the gray area is composed of a Cu element.This indicates that the irregular black area is the deformed graphite.

Adhesion
In the literature [35,36], it is mentioned that the high peening influence of the powder materials and low processing temperature in the CS process results in high adhesion of the deposited coating.However, the study results of the adhesion of Cu@Gr/CBC coatings on AA6061 T6 substrate have some differences.Figure 9a shows the adhesion of the Cu@Gr/CBC coatings on the AA6061 T6 substrate under different spraying parameters.From Figure 9a, it can be seen that the coating adhesion increases with increasing gas pressure, while the coating adhesion also increases with increasing gas temperature, only not as significantly as with increasing gas pressure.The highest average value of adhesion at the coating/substrate interface is 69.8 N for the deposited coating at 900 °C and 5.5 MPa, and the lowest average value of adhesion at the coating/substrate interface is 35.6 N for the deposited coating at 600 °C and 4 MPa.The investigation of typical SEM pictures of scratches after testing (Figure 9b-e) shows that the length of the destruction area of the deposited coatings by the indenter (light area) in cold-sprayed coatings.The critical load with the SEM images of the critical length of the scratch Lc after scratch testing for the coatings formed at 800 °C and different gas pressures is also given in Figure 9b-e.Compared with Figure 9b-e, the Lc increases with the increase in gas pressure, and the corresponding critical load also increases with the increasing gas pressure.The delaminated position of the coatings from the substrate is exposed along the scratch direction when the applied load reaches the critical load.In Figure 9b-e, the highlighted morphologies of the scratch grooves are the delaminated coating positions, which are observed under the magnification as illustrated in the top left corner, respectively.

Adhesion
In the literature [35,36], it is mentioned that the high peening influence of the powder materials and low processing temperature in the CS process results in high adhesion of the deposited coating.However, the study results of the adhesion of Cu@Gr/CBC coatings on AA6061 T6 substrate have some differences.Figure 9a shows the adhesion of the Cu@Gr/CBC coatings on the AA6061 T6 substrate under different spraying parameters.
From Figure 9a, it can be seen that the coating adhesion increases with increasing gas pressure, while the coating adhesion also increases with increasing gas temperature, only not as significantly as with increasing gas pressure.The highest average value of adhesion at the coating/substrate interface is 69.8 N for the deposited coating at 900 • C and 5.5 MPa, and the lowest average value of adhesion at the coating/substrate interface is 35.6 N for the deposited coating at 600 • C and 4 MPa.The investigation of typical SEM pictures of scratches after testing (Figure 9b-e) shows that the length of the destruction area of the deposited coatings by the indenter (light area) in cold-sprayed coatings.The critical load with the SEM images of the critical length of the scratch L c after scratch testing for the coatings formed at 800 • C and different gas pressures is also given in Figure 9b-e.Compared with Figure 9b-e, the L c increases with the increase in gas pressure, and the corresponding critical load also increases with the increasing gas pressure.The delaminated position of the coatings from the substrate is exposed along the scratch direction when the applied load reaches the critical load.In Figure 9b-e, the highlighted morphologies of the scratch grooves are the delaminated coating positions, which are observed under the magnification as illustrated in the top left corner, respectively.Particle velocity Vp is the most significant factor to determine the bonding strength and the effectiveness of jet formation of the deposited coatings [37].The Vp can be given by the following equation [38], where Vg is gas velocity, D particle diameter, x axial position, ρp particle density, po supply pressure measured at the entrance of the nozzle, M local mach number = 1.35, γ ratio of specific heats = 1.4,T gas temperature, MW molecular weight of the gas.Figure 10 shows the Vp under different cold-spray parameters.As seen from Figure 10, Vp increases by increasing the working temperature and pressure of the cold-spray process gas.Because the Vg is higher, leading to a larger accelerating drag, the higher gas temperature increases Vp Particle velocity V p is the most significant factor to determine the bonding strength and the effectiveness of jet formation of the deposited coatings [37].The V p can be given by the following equation [38], where V g is gas velocity, D particle diameter, x axial position, ρ p particle density, p o supply pressure measured at the entrance of the nozzle, M local mach number = 1.35, γ ratio of specific heats = 1.4,T gas temperature, M W molecular weight of the gas.Figure 10 shows the V p under different cold-spray parameters.As seen from Figure 10, V p increases by increasing the working temperature and pressure of the cold-spray process gas.Because the V g is higher, leading to a larger accelerating drag, the higher gas temperature increases V p [39].By comparing the compaction of the deposited coatings under varying spraying parameters in Figure 7, it can be obtained that the coatings deposited at 900 • C and 5.5 MPa (Figure 7 10).The surface roughness, thickness and adhesion of the single-lane and single-layer Cu@Gr/CBC coatings are all linear with V p , as shown in Figure 11.The surface roughness is a linear decrease relation with V p , while the thickness and adhesion are a linear increase relation with V p .This indicates that a higher gas pressure and gas temperature increase the V p , thickness and adhesion of the deposited coatings while decreasing surface roughness.[39].By comparing the compaction of the deposited coatings under v rameters in Figure 7, it can be obtained that the coatings deposited at (Figure 7

Conclusions
Cold-sprayed coatings of the single-lane and single-layer Cu@Gr/CBC under different cold spray parameters have been successfully deposited on the AA6061 T6 substrate by using N2 as propellant gas.The Ra of the cold-sprayed coatings is gradually decreased with the increasing gas pressure and gas temperature.The thickness of the deposited coatings increases significantly with the increase in gas pressure and gas temperature.The mixture particles of Cu and Cu@graphite in the deposited coatings produced at 900 °C and 5.5 MPa, 900 °C and 4.5 MPa, 900 °C and 4 MPa, 800 °C and 5.5 MPa, 800 °C and 4.5 MPa, and 700 °C and 5.5 MPa are heavily deformed during the deposition, and the coatings are dense.However, the deposited coatings obtained at 800 °C and 4 MPa, 700 °C and 4.5 MPa, 700 °C and 4 MPa, 600 °C and 5.5 MPa, 600 °C and 4.5 MPa, and 600 °C and 4 MPa are more or less not dense.The critical load in the scratch test is used as a measure of scratch adhesion.The coating adhesion increases with the increase in gas pressure, while the coating adhesion also increases with increasing gas temperature, only not as significantly as with the increasing gas pressure.When the coating is not oxidized and dense, the Cu-coated graphite reinforced Cu-based composite coating at 800 °C, 5.5 MPa possesses the lowest surface roughness, the maximum thickness and the highest adhesion among the cold-sprayed coatings.The surface roughness of the single-lane and singlelayer Cu@Gr/CBC coatings is a linear decrease relation with Vp, while the thickness and adhesion are a linear increase relation with Vp.

Figure 2 .
Figure 2. Schematic diagram of scratch coating adhesion test.

Figure 2 .
Figure 2. Schematic diagram of scratch coating adhesion test.

Figure 3 .
Figure 3. SEM image showing the morphology of Cu and 7 wt.%Cu coated graphite mixture particles (a), XRD pattern presenting the phases of the mixture powders (b) and the size distribution curve of the mixture particles (c).

Figure 3 .
Figure 3. SEM image showing the morphology of Cu and 7 wt.%Cu coated graphite mixture particles (a), XRD pattern presenting the phases of the mixture powders (b) and the size distribution curve of the mixture particles (c).

Figure 4 .
Figure 4. Typical appearance of the single-lane and single-layer Cu@Gr/CBC coating on AA6061 T6 substrate at 800 °C and 5.5 MPa (a), SEM morphology of the cross-section of the deposited coating (b), higher magnification photo of the deposited coating (c), EDS analysis result of the area noted by rectangular box in (c,d), SEM micrograph of the cold sprayed coating at 900 °C and 5.5 MPa (e) and EDS analysis result of the area noted by rectangular box in (e,f).The lightest area is coating and the gray area is substrate in (b,c,e).

Figure 4 .
Figure 4. Typical appearance of the single-lane and single-layer Cu@Gr/CBC coating on AA6061 T6 substrate at 800 • C and 5.5 MPa (a), SEM morphology of the cross-section of the deposited coating (b), higher magnification photo of the deposited coating (c), EDS analysis result of the area noted by rectangular box in (c,d), SEM micrograph of the cold sprayed coating at 900 • C and 5.5 MPa (e) and EDS analysis result of the area noted by rectangular box in (e,f).The lightest area is coating and the gray area is substrate in (b,c,e).

Figure 5 .
Figure 5.Effect of cold spray parameters on the surface roughness Ra of the deposited Cu@Gr/CBC coatings on AA6061 T6 substrate (a), 3D surface morphology of coatings deposited at 800 °C and different gas pressures: 4 MPa (b), 4.5 MPa (c), 5 MPa (d) and 5.5 MPa (e).

Figure 5 .
Figure 5.Effect of cold spray parameters on the surface roughness Ra of the deposited Cu@Gr/CBC coatings on AA6061 T6 substrate (a), 3D surface morphology of coatings deposited at 800 • C and different gas pressures: 4 MPa (b), 4.5 MPa (c), 5 MPa (d) and 5.5 MPa (e).

Figure 8 .
Figure 8. Element scanning maps of the area noted by rectangular box in the deposited Cu@Gr/CBC coating on AA6061 T6 substrate at 800 °C and 5.5 MPa (Figure 7(b1)): SEM micrograph (a), Cu (b), and C (c).

Figure 8 .
Figure 8. Element scanning maps of the area noted by rectangular box in the deposited Cu@Gr/CBC coating on AA6061 T6 substrate at 800 • C and 5.5 MPa (Figure 7(b1)): SEM micrograph (a), Cu (b), and C (c).

Figure 9 .
Figure 9. Adhesion of Cu@Gr/CBC coatings on AA6061T6 substrate under different cold spray parameters (a), and critical load with the SEM image of the critical length of the scratch Lc after scratch testing for the coatings formed at 800 °C and different gas pressures: 4 MPa (b), 4.5 MPa (c),5 MPa (d) and 5.5 MPa (e).Magnification of the area noted by rectangular box in (b-e).

Figure 9 .
Figure 9. Adhesion of Cu@Gr/CBC coatings on AA6061T6 substrate under different cold spray parameters (a), and critical load with the SEM image of the critical length of the scratch L c after scratch testing for the coatings formed at 800 • C and different gas pressures: 4 MPa (b), 4.5 MPa (c), 5 MPa (d) and 5.5 MPa (e).Magnification of the area noted by rectangular box in (b-e).

Figure 10 .
Figure 10.Correlation of particle velocity Vp with gas temperatures and gas sprayed coatings of the single-lane and single-layer Cu@Gr/CBC.

Figure 10 .
Figure 10.Correlation of particle velocity V p with gas temperatures and gas pressures for the cold sprayed coatings of the single-lane and single-layer Cu@Gr/CBC.

Figure 11 .
Figure 11.Scaling of surface roughness, thickness, adhesion and particle velocity Vp for the cold sprayed coatings of the single-lane and single-layer Cu@Gr/CBC at different gas temperatures and gas pressures.Surface roughness as a function of Vp (a), correlation of thickness with Vp (b) and correlation of adhesion with Vp (c).

Table 2 .
Deposition parameters of Cu@Gr/CBC coatings prepared by CS technology.

Table 2 .
Deposition parameters of Cu@Gr/CBC coatings prepared by CS technology.