A Review of Cooling Technologies in Lithium-Ion Power Battery Thermal Management Systems for New Energy Vehicles

: The power battery is an important component of new energy vehicles, and thermal safety is the key issue in its development. During charging and discharging, how to enhance the rapid and uniform heat dissipation of power batteries has become a hotspot. This paper brieﬂy introduces the heat generation mechanism and models, and emphatically summarizes the main principle, research focuses, and development trends of cooling technologies in the thermal management of power batteries in new energy vehicles in the past few years. Currently, the commonly used models for battery heat generation are the electrochemical-thermal model and the electrical-thermal model. Scholars have conducted more research based on multidimensional electrochemical-thermal/electrical-thermal models because taking the actual characteristics of the battery into account can provide a more comprehensive and systematic description. Among various cooling technologies, the air-cooling system boasts the most economical manufacturing costs and a compact, reliable structure. The heat transfer coefﬁcient of the liquid-cooling system is very high, while the temperature remains uniform in the PCMs cooling system during the material phase transition process. Against the background of increasing energy density in future batteries, immersion liquid phase change cooling technology has great development prospects, but it needs to overcome limitations such as high cost and heavy weight. Therefore, the current lithium-ion battery thermal management technology that combines multiple cooling systems is the main development direction. Suitable cooling methods can be selected and combined based on the advantages and disadvantages of different cooling technologies to meet the thermal management needs of different users.


Introduction
Globally, with fossil energy reserves being depleted and the climate environment deteriorating, the new energy vehicle is an important measure to promote energy conservation and CO 2 reduction.The power battery is one of the most important components of new energy vehicles.Power batteries can be divided into four types: lead acid batteries, nickel metal hydride batteries, electric double layer capacitors, and lithium-ion batteries [1].As one of the most popular energy storage and power equipment, lithium-ion batteries have gradually become widely used due to their high specific energy and power, light weight, and high voltage output.The life cycle assessment method was adopted to conduct an environmental impact assessment on lithium-ion batteries, confirming that battery efficiency and power loss were very important parameters during the battery usage stage [2,3].
Since the batteries in the battery pack will generate a lot of heat during operation, the performance of the battery pack will be severely affected.As a result, new energy vehicles are increasingly being developed with a focus on enhancing the rapid and uniform heat dissipation of the battery pack during charging and discharging.The optimal operating temperature range for these power batteries was found to be between 25-40 • C, and the ideal temperature distribution between batteries in the battery pack should be below 5 • C [4].Sato [5] pointed out that when the battery temperature is higher than 50 • C, the charging speed, efficiency, and lifespan are reduced.The study [6] reviewed the heat sources and pointed out that most of the heat in the battery was generated from electrodes; hence, for the lithium-ion batteries to be thermally efficient, electrodes should be modified to ensure high overall ionic and electrical conductivity.At present, the analysis of the principle of battery heat generation is mostly based on Bernardi's battery heat generation theory [7].Corresponding electrochemical-thermal models [8][9][10][11][12] and electrical-thermal models [13][14][15][16][17] have been established to analyze the heat transfer and temperature change within the battery pack.To ensure the safe operation of batteries, a comprehensive thermal safety management system should be established, which can detect potential thermal failures and provide emergency cooling before accidents occur [18].
The battery thermal management system (BTMS) is essential for ensuring the best performance and extending the life of the battery pack in new energy vehicles.In order to remove excess heat from batteries, a lot of research has been done to develop a highefficiency BTMS which is suitable for new energy vehicles.The present common BTMS technologies often use some kind of cooling medium to take heat away from the battery surface.According to the different kinds of cooling media used, BTMS technologies are divided into three categories: air cooling, liquid cooling, and phase change materials (PCMs) cooling, as shown in Figure 1, which have different advantages and applications.The researchers [19][20][21][22] reviewed the development of new energy vehicles and high energy power batteries, introduced related cooling technologies, and suggested BTMS technology as a viable option based on cooling requirements and applications.They pointed out that liquid cooling should be considered as the best choice for high charge and discharge rates, and it is the most suitable for large-scale battery applications in high-temperature environments.The comparison of advantages and disadvantages of different cooling systems is shown in Table 1.Although the above studies have reviewed the thermal management techniques of power ba eries to a certain extent, the development of new energy vehicles is advancing rapidly.The related research conclusions are constantly driving the progress and development of the industry.Therefore, this paper investigates the research literature of the past decade (among the 176 references cited in this paper, 156 were published from 2013 to 2023, and 61 were published in the past three years) and combines insights into the heat generation mechanism and models of the lithium-ion ba eries to provide a clear description and systematic summary of the main principles, research focuses, and development trends in three cooling technologies.It also identifies future development prospects for cooling systems.The aim is to provide necessary assistance for research on heat generation and cooling system design for power ba eries in new energy vehicles.

Heat Generation of Lithium-Ion Ba eries
Lithium-ion ba eries generate heat mainly due to charge movement and chemical  Although the above studies have reviewed the thermal management techniques of power batteries to a certain extent, the development of new energy vehicles is advancing rapidly.The related research conclusions are constantly driving the progress and development of the industry.Therefore, this paper investigates the research literature of the past decade (among the 176 references cited in this paper, 156 were published from 2013 to 2023, and 61 were published in the past three years) and combines insights into the heat generation mechanism and models of the lithium-ion batteries to provide a clear description and systematic summary of the main principles, research focuses, and development trends in three cooling technologies.It also identifies future development prospects for cooling systems.The aim is to provide necessary assistance for research on heat generation and cooling system design for power batteries in new energy vehicles.

Heat Generation of Lithium-Ion Batteries
Lithium-ion batteries generate heat mainly due to charge movement and chemical reactions that take place during charging and discharging.As shown in the Figure 2b, during the discharge process, lithium ions detach from the microporous structure of the graphite anode and are embedded into the lithium iron phosphate through the internal structure of the battery.The amount of lithium ions embedded determines the depth of the discharge.At the same time, in order to achieve a balance transfer of positive and negative ions, the same number of electrons in the external circuit also migrate between the anode and the cathode, thereby achieving the charge balance and completing the redox reaction of the battery.In the process, heat is generated and accumulated, seriously influencing lithium-ion batteries' performance, lifespan, and safety.As a consequence, a key to battery thermal management is to develop a proper heat generation model that is capable of predicting and analyzing the characteristics of lithium-ion batteries under different operating conditions.

Heat Generation Mechanism
In order to simplify the study, according to D. Bernardi's ba ery heat generation theory [7], there are four main types of heat generated by ba eries: Joule heat Qj, polarization heat Qp, reaction heat Qr, and side reaction heat Qs [23].
1. Joule heat Qj: Ba eries are made up of different materials, including electrodes, separators, and so on, each with its own ohmic resistance, and the heat they generate when the current flows is known as Joule heat.The calculation formula is Equation (1).

Heat Generation Mechanism
In order to simplify the study, according to D. Bernardi's battery heat generation theory [7], there are four main types of heat generated by batteries: Joule heat Q j , polarization heat Q p , reaction heat Q r , and side reaction heat Q s [23].

1.
Joule heat Q j : Batteries are made up of different materials, including electrodes, separators, and so on, each with its own ohmic resistance, and the heat they generate when the current flows is known as Joule heat.The calculation formula is Equation (1).
In the formula, I-current during charging and discharging, A; R o -internal ohmic resistance of battery, Ω.

2.
Polarization heat Q p : When batteries are charged and discharged, polarization phenomena occur, resulting in electrode potentials that differ from equilibrium electrode potentials.The heat produced in the polarization phenomena is called polarization heat, which is irreversible.The calculation formula is Equation (2).
In the formula, R p -internal polarization resistance of battery, Ω.

3.
Reaction heat Q r : When positive or negative electrodes are inserted or removed, lithium ions also produce heat known as reaction heat.It is generally believed that reaction heat has a positive value when discharging and a negative value when charging.Reaction heat is reversible.The calculation formula is Equation (3).
In the formula, n-the number of batteries; m-the mass of each battery, kg; Q-total chemical reaction heat, J; M-molar mass, kg/mol; F-Faraday constant, C/mol.

4.
Side reaction heat Q s : In instances of thermal abuse, such as overcharging and over discharging, lithium battery electrode materials and electrolytes generate heat, contributing to the side reaction heat.As long as the working conditions are normal, it is possible to ignore this part of the heat.
As a result, the total heat generation in the battery pack can be calculated using Equation (4).

Heat Generation Models
For the study of battery temperature, the heat generation model of lithium-ion batteries is crucial.In order to establish models of heat generation, electrochemical-thermal models, electrical-thermal models, and thermal runaway models based on physical mechanisms can be used.According to the research methods, these models can be divided into theoretical analysis, experimental research, and numerical simulation.Additionally, considering different dimensions, there are also one-dimensional (1D), two-dimensional (2D), and three-dimensional models (3D).
Currently, the commonly used models for battery heat generation are electrochemicalthermal models and electrical-thermal models.The electrochemical-thermal models rely on the electrochemical process occurring within the battery, taking into account the impact of internal chemical reactions on heat production.Electrical-thermal models are based on the heat produced when the current passes through the internal resistance of the battery, taking the energy loss into account, which is then converted into thermal energy.At the same time, the models with two dimensions or three dimensions take the actual characteristics of the battery into account, such as external parameters and boundary conditions, which can provide a more comprehensive and systematic description of the heat generation effect of the battery.Therefore, currently, scholars have conducted more research based on multidimensional electrochemical-thermal/electrical-thermal models.

Electrochemical-Thermal Models
Current mainstream electrochemical-thermal models that can accurately reflect lithiumion batteries heat generation is the P2D model [8].This model involves the simultaneous solution of the transport equation of lithium ions in solid spheres of positive and negative electrode materials and electrolytes, the Bulter-Volmer equation, and the heat transfer control equation.When lithium-ion batteries are charged and discharged, this model accurately describes the heat generated and potential distribution within them.Researchers have developed many electrochemical-thermal coupling models based on this foundation.
Kemper et al. [9] introduced a simplified two-dimensional electrochemical-thermal model.They derived the concentration distribution of lithium ions based on the P2D model assumption and calculated the potential using the lithium-ion concentration at the boundary.This model improves the ability to predict pulse charges and constant currents.In the paper [10], Nie et al. proposed a method for simulating batteries of various sizes (14,650, 18,650, and 26,650) via electrochemical-thermal coupling, as shown in Figure 3.The battery temperatures rose sharply during discharge and peaks near the end.Larger battery sizes and higher discharge rates resulted in higher temperatures.A three-dimensional electrochemical-thermal coupling model for 30 Ah batteries was developed by Li et al. [11].
A number of discharge rates and ambient temperatures were studied in order to analyze the battery's internal electrochemical process and thermal characteristics.They found that the discharge rate significantly affected the electrochemical and thermal behavior of the battery.According to CHIEW et al. [12], the thermal characteristics of batteries were analyzed at different discharge rates, using a combination of pseudo two-dimensional electrochemical models and three-dimensional lumped thermal models.The effectiveness of the combined model was validated through experiments.

Electrical-Thermal Models
The ba ery's equivalent circuit can be constructed using voltage, capacitance, and resistance in the electrical-thermal model, which is coupled with the thermal model of the ba ery.As a result of the equivalent circuit, the thermal model receives the terminal voltage simulation and calculates the rate at which the ba ery generates heat.As a result of the thermal model, the equivalent circuit updates the resistance and capacitance data based on the average temperature, thus achieving mutual coupling between the two models, as shown in Figure 4.

Electrical-Thermal Models
The battery's equivalent circuit can be constructed using voltage, capacitance, and resistance in the electrical-thermal model, which is coupled with the thermal model of the battery.As a result of the equivalent circuit, the thermal model receives the terminal voltage simulation and calculates the rate at which the battery generates heat.As a result of the thermal model, the equivalent circuit updates the resistance and capacitance data based on the average temperature, thus achieving mutual coupling between the two models, as shown in Figure 4.
resistance in the electrical-thermal model, which is coupled with the thermal model of the ba ery.As a result of the equivalent circuit, the thermal model receives the terminal voltage simulation and calculates the rate at which the ba ery generates heat.As a result of the thermal model, the equivalent circuit updates the resistance and capacitance data based on the average temperature, thus achieving mutual coupling between the two models, as shown in Figure 4.The finite element method was applied by Kim et al. [13] to develop a model for polymer lithium-ion ba eries that incorporates two-dimensional electric-thermal coupling.Infrared thermal imaging was used to verify the model's effectiveness by analyzing discharge performance and temperature distribution.According to Xie et al. [14], a dynamic 3D resistance-based thermal model, as shown in Figure 5, can be used to predict the temperature distribution and evolution of a prismatic ba ery with a capacity of 50 Ah under different charging schemes and ambient temperatures.For be er computing efficiency, LI et al. [15] employed an electro-thermal model for analyzing ba ery heat generation during overcharging.Based on current and ambient conditions, Barcelona et al. [16] developed an integrated electro-thermal model that can predict the thermal behavior of ba eries.Due to the model's simplicity, it was tuned and validated based on experimental results, The finite element method was applied by Kim et al. [13] to develop a model for polymer lithium-ion batteries that incorporates two-dimensional electric-thermal coupling.Infrared thermal imaging was used to verify the model's effectiveness by analyzing discharge performance and temperature distribution.According to Xie et al. [14], a dynamic 3D resistance-based thermal model, as shown in Figure 5, can be used to predict the temperature distribution and evolution of a prismatic battery with a capacity of 50 Ah under different charging schemes and ambient temperatures.For better computing efficiency, Li et al. [15] employed an electro-thermal model for analyzing battery heat generation during overcharging.Based on current and ambient conditions, Barcelona et al. [16] developed an integrated electro-thermal model that can predict the thermal behavior of batteries.Due to the model's simplicity, it was tuned and validated based on experimental results, demonstrating its ability to predict battery temperature with reasonable accuracy.The mathematical model of Chin et al. [17] was coupled with the electric model in order to estimate voltages, core temperatures, and surface temperatures under thermal uncertainties.

The Effect of Temperature on Ba ery Performance
Since lithium-ion ba eries have a complex structure and are exposed to chemical reactions during discharge, they generate significant amounts of heat.The analysis of battery performance under different temperatures is critical and necessary.Lithium-ion ba eries may overheat when charged at high rates without a suitable cooling system, which may adversely affect the efficiency, capacity, lifetime, and cycle

The Effect of Temperature on Battery Performance
Since lithium-ion batteries have a complex structure and are exposed to chemical reactions during discharge, they generate significant amounts of heat.The analysis of battery performance under different temperatures is critical and necessary.

The Effect of High Temperature on Battery Performance
Lithium-ion batteries may overheat when charged at high rates without a suitable cooling system, which may adversely affect the efficiency, capacity, lifetime, and cycle times of the battery itself [24].Moreover, this can result in the battery exploding or spontaneously combusting [19].
Temperature increases result in a decrease in internal resistance, but irreversible reactions occur inside the battery, reducing its capacity, service life, and output power.With increasing temperature, the Arrhenius formula predicts that the battery's reaction rate increases exponentially.The higher the temperature, the faster the battery aging rate [25].Over time, the capacity will continue to decrease.By studying the cycling performance of Sony 18,650 lithium-ion battery with a 1.8 Ah capacity, the results showed that after 800 charging and discharging cycles at operating temperatures of 25 • C and 45 • C, the battery capacity decreased by 31% and 36%, respectively.When the working temperature is 50 • C, the battery capacity decreases by 60% after 500 charging and discharging cycles [26].Lithium-ion batteries experience a decrease in service life if temperatures exceed 50 • C. In general, every 10 • C increase in battery temperature doubles the internal chemical reaction rate and reduces its lifespan by half.When considering the power of the battery to determine its performance [27], it is obvious that the battery's capacity decreases at high temperatures due to the generation of dead zones and lithium evolution phenomena in the active substances inside the lithium battery.This results in a decrease in battery power due to an increase in impedance [28][29][30].Most lithium batteries operate at optimum temperatures between 25-40 • C [31,32], and if they are operated outside this range, their performance will be adversely affected.

The Effect of Non-Uniform Temperature on Battery Performance
New energy vehicles typically utilize a power battery pack with multiple battery cells connected in both series and parallel configurations.If the temperature distribution within the pack is not uniform, it can also adversely affect the battery's capacity, cycle life, and other characteristics.
Firstly, due to the structural characteristics of individual batteries, there is a difference in the thermal conductivity of power batteries in three dimensions, which can cause nonuniform temperature distribution among individual batteries, leading to mismatched battery performance.And this problem becomes more prominent as its size increases; for example, the heat generation of the positive pole during reaction can reach three times that of other parts [33].Secondly, due to inconsistent heat dissipation during usage, the current, discharge depth, and temperature distribution change in the battery pack.Consequently, the battery will suffer from issues such as its State of Charge (SOC), capacity impedance, and State of Health (SOH) [34,35].When the temperature difference in the battery pack reaches 5 • C, 10 • C, and 15 • C, the corresponding capacities are 90%, 85%, and 80% of the original capacity, respectively [36,37].Reference [38] studied the comparison of battery pack temperature non-uniformity on cycle life using simulation and experimental methods, and Figure 6 shows the comparison of cycle life performance.In the Figure 6, the red solid line represents the performance of two batteries without a temperature difference, with an average capacity decay of 0.1195 mAh per cycle (manufacturer data).The blue solid line represents the experimental results of series batteries with a temperature difference, with an average capacity decay of 0.7308 mAh per cycle.The slope is more than six times steeper than when there is no temperature difference.After only 996 cycles, the capacity decreases to 0.25 Ah (24% of the initial capacity).Reference [39] points out that the non-uniform distribution of temperature may accelerate the difference in capacity attenuation between parallel battery cells due to inconsistent current between individual battery cells.There is a general belief that the battery pack should not have a temperature difference exceeding 5 • C [40]. more than six times steeper than when there is no temperature difference.After only 996 cycles, the capacity decreases to 0.25 Ah (24% of the initial capacity).Reference [39] points out that the non-uniform distribution of temperature may accelerate the difference in capacity a enuation between parallel ba ery cells due to inconsistent current between individual ba ery cells.There is a general belief that the ba ery pack should not have a temperature difference exceeding 5 °C [40].

Air Cooling Technology
Ba ery packs are normally cooled with air cooling technology.Air cooling systems are characterized by their simplicity, direct and safe medium access, low viscosity, small size, high compactness, light weight, low maintenance cost, and low investment.

Air Cooling Technology
Battery packs are normally cooled with air cooling technology.Air cooling systems are characterized by their simplicity, direct and safe medium access, low viscosity, small size, high compactness, light weight, low maintenance cost, and low investment.

Principle of Air Cooling
There are two types of air cooling: passive air cooling and active air cooling.A passive air-cooling system and an active air-cooling system differ in whether they have a powerful motor to drive the air, such as fans, as shown in Figure 7.

Principle of Air Cooling
There are two types of air cooling: passive air cooling and active air cooling.A passive air-cooling system and an active air-cooling system differ in whether they have a powerful motor to drive the air, such as fans, as shown in Figure 7. Passive air cooling involves air flowing from the outside to the inside of the ba ery pack, cooling the ba eries because of the relative motion.As the vehicle moves, heat from the ba ery pack is removed by the air when passing through the gap in the ba ery pack and then vented from the opposite side.The low flow rate of the air results in a low heat transfer coefficient, so this technology is usually suitable for ba eries that have low energy density, vehicles equipped with hybrid electric motors or pure electric motors that are low cost and have a short driving range [42].
When faced with high ambient temperature and increased ba ery pack heat dissipation requirements, passive air-cooling technology is not effective.Therefore, aerodynamic equipment, such as fans, needs to be added to increase air speed and improve the heat transfer coefficient.It is possible to remove more heat in a ba ery pack if there is enough Passive air cooling involves air flowing from the outside to the inside of the battery pack, cooling the batteries because of the relative motion.As the vehicle moves, heat from the battery pack is removed by the air when passing through the gap in the battery pack and then vented from the opposite side.The low flow rate of the air results in a low heat transfer coefficient, so this technology is usually suitable for batteries that have low energy Processes 2023, 11, 3450 9 of 34 density, vehicles equipped with hybrid electric motors or pure electric motors that are low cost and have a short driving range [42].
When faced with high ambient temperature and increased battery pack heat dissipation requirements, passive air-cooling technology is not effective.Therefore, aerodynamic equipment, such as fans, needs to be added to increase air speed and improve the heat transfer coefficient.It is possible to remove more heat in a battery pack if there is enough airflow, which makes the temperature distribution uniform and the maximum temperature lower [43].Although the fans increase the cost of the air-cooling system, the active air-cooling system improves the overall heat dissipation performance and reliability, and its benefits outweigh the increased cost [44].

Focus Areas of Air-Cooling Systems
In air convection cooling, the low thermal conductivity and low specific heat capacity of air prevent it from lowering the maximum temperature and maintaining a uniform temperature in the battery pack when there is a lot of heat [45].However, battery performance is closely related to temperature [46].In some studies, uneven temperatures within the battery pack have been linked to unbalanced battery performance, which results in reduced battery performance of the entire vehicle.As a result, efforts in air cooling systems in recent years have mainly focused on the optimization of battery pack design, the improvement of the cooling channel, and the addition of thermal conductivity materials, so as to improve the comprehensive effect of the air-cooling system.
In terms of battery pack design optimization, various approaches have been explored, such as different battery pack layouts, including square, rectangular, and circular [47][48][49] (as shown in Figure 8), aligned, staggered, and cross-arranged configurations [50,51], changing the distance between batteries [49,50,52,53], and tilting the battery pack casing (as shown in Figure 9) [54], etc.These efforts try to enhance cooling performance as the air flows through the battery pack.At the same time, some functions and algorithms have also been proposed.For example, the function of battery size and the BTMS cost [55] and multiobjective evolutionary algorithms, as shown in Figure 10, have been used to study battery quantity, distance, and entrance channel location [56,57].Figure 8 shows the temperature distributions when the battery pack is designed as a square and rectangular shape.The results suggest that when using a BTMS with just passive air cooling methods, at full discharge, the rectangular shape with a lower maximum temperature for battery pack offers advantages over the square shape [48].As seen in Figure 11, the aligned arrangement has the best cooling performance and temperature uniformity, followed by the staggered arrangement, and finally, the cross arrangement [51].
In terms of cooling channel design, U-shaped channels, J-shaped channels, and Zshaped channels [58][59][60] are designed, as shown in Figure 12.Also, there are two-way cooling channel designs [61,62], distributed thin airflow channel designs [63], reciprocating airflow designs (as shown in Figure 13) [64], etc.In addition, changing the position of the air inlet and outlet [65][66][67][68] and setting the inlet static pressure box [69] can also increase the cooling effect.There are other measures to improve the air-cooling performance in the main channel through which the air flows.For example, adding fins or winglets in the air channel [68][69][70][71] etc., not only increases the heat exchange area, but also enhances the airflow disturbance.And, as shown in Figure 14, adding hydrophilic fibers and using the refrigerant in the hydrophilic fibers to absorb air heat [72] results in an average temperature decrease of 24 • C compared with no cooling, and 17 • C compared with air cooling, as shown in Figure 15a.Moreover, this approach helps improve temperature uniformity by more than 70% compared with no cooling, a 56% improvement compared with air cooling, as shown in Figure 15b.
temperature distributions when the ba ery pack is designed as a square and rectangular shape.The results suggest that when using a BTMS with just passive air cooling methods, at full discharge, the rectangular shape with a lower maximum temperature for ba ery pack offers advantages over the square shape [48].As seen in Figure 11, the aligned arrangement has the best cooling performance and temperature uniformity, followed by the staggered arrangement, and finally, the cross arrangement [51].study ba ery quantity, distance, and entrance channel location [56,57].Figure 8 shows the temperature distributions when the ba ery pack is designed as a square and rectangular shape.The results suggest that when using a BTMS with just passive air cooling methods, at full discharge, the rectangular shape with a lower maximum temperature for ba ery pack offers advantages over the square shape [48].As seen in Figure 11, the aligned arrangement has the best cooling performance and temperature uniformity, followed by the staggered arrangement, and finally, the cross arrangement [51].In terms of cooling channel design, U-shaped channels, J-shaped channels, and Zshaped channels [58][59][60] are designed, as shown in Figure 12.Also, there are two-way cooling channel designs [61,62], distributed thin airflow channel designs [63], reciprocating airflow designs (as shown in Figure 13) [64], etc.In addition, changing the position of the air inlet and outlet [65][66][67][68] and se ing the inlet static pressure box [69] can also increase the cooling effect.There are other measures to improve the air-cooling performance in the main channel through which the air flows.For example, adding fins or winglets in the air channel [68][69][70][71] etc., not only increases the heat exchange area, but also enhances the airflow disturbance.And, as shown in Figure 14, adding hydrophilic fibers and using the refrigerant in the hydrophilic fibers to absorb air heat [72] results in an average temperature decrease of 24 °C compared with no cooling, and 17 °C compared with air cooling, as shown in Figure 15a.Moreover, this approach helps improve temperature uniformity by more than 70% compared with no cooling, a 56% improvement compared with air cooling, as shown in Figure 15b.With regard to thermal conducting materials, metal materials with high thermal conductivity, such as aluminum foam [73], as shown in Figure 16, can enhance heat conduction.At the same time, the pores in the foam, as shown in Figure 17, can also increase turbulent flow effects.The combination of silicon dioxide and copper mesh can enhance heat conduction and heat dissipation [74].Embedding porous aluminum foam into aluminum finned heat sinks [75] or combining PCM and air cooling [76,77] can also increase the air-cooling performance.With regard to thermal conducting materials, metal materials with high thermal conductivity, such as aluminum foam [73], as shown in Figure 16, can enhance heat conduction.At the same time, the pores in the foam, as shown in Figure 17, can also increase turbulent flow effects.The combination of silicon dioxide and copper mesh can enhance heat conduction and heat dissipation [74].Embedding porous aluminum foam into aluminum finned heat sinks [75] or combining PCM and air cooling [76,77] can also increase the air-cooling performance.With regard to thermal conducting materials, metal materials with high thermal conductivity, such as aluminum foam [73], as shown in Figure 16, can enhance heat conduction.At the same time, the pores in the foam, as shown in Figure 17, can also increase turbulent flow effects.The combination of silicon dioxide and copper mesh can enhance heat conduction and heat dissipation [74].Embedding porous aluminum foam into aluminum finned heat sinks [75] or combining PCM and air cooling [76,77] can also increase the air-cooling performance.
ductivity, such as aluminum foam [73], as shown in Figure 16, can enhance heat conduction.At the same time, the pores in the foam, as shown in Figure 17, can also increase turbulent flow effects.The combination of silicon dioxide and copper mesh can enhance heat conduction and heat dissipation [74].Embedding porous aluminum foam into aluminum finned heat sinks [75] or combining PCM and air cooling [76,77] can also increase the air-cooling performance.

The Development Trends of Air Cooling Systems
The studies above show that improving the air cooling BTMS performance is commonly achieved by optimizing the ba ery pack design, improving cooling channel design, and adding high thermal conductive material to enhance heat conduction.With the optimal design of the ba ery pack and cooling channel and the addition of new substructures such as fins, local turbulence can be enhanced, convective heat transfer coefficient can be increased, and hot spots can be minimized.Further improving cooling capacity will be achieved by combining the most advanced thermally conductive materials.
Comparing the air cooling BTMS with other cooling methods, the former offers lowest manufacturing costs as well as the most compact and reliable design.However, it is still possible for the single air cooling BTMS to fail under certain extreme conditions, including long-term operation at a high rate of charging or discharge and extreme ambient temperatures.To deal with unpredictable ba ery failure and thermal runaway, the trends in developing air-cooling systems are improving cooling efficiency, reducing power consumption, and increasing high-temperature adaptability.
(1) Improving cooling efficiency: Future air-cooling systems will further improve cooling efficiency to meet the increasing power density of the ba ery.By optimizing the design of the cooling system, the air fluidity and heat dissipation area are improved.
Combining other cooling methods with air cooling, including PCM structures, liquid cooling, HVAC systems, heat pipes etc., an air-cooling system with these advanced enhancements should provide adequate cooling for new energy vehicles' high-energy ba ery packs.(2) Reducing power consumption: The air-cooling system will consume a certain amount of energy in the process of operation, so one of the future trends is to reduce the power consumption of the cooling system.By improving the fan design, optimizing the structure and flow characteristics of the cooling system, and reducing the air flow resistance and energy loss, more energy is saved in the air-cooling system.(3) Increasing high-temperature adaptability: The ba ery is easy to overheat in hightemperature environment, so the future air-cooling system will be be er adapted to high-temperature environments.High-temperature-resistant materials and structure designs are adopted to improve the high-temperature resistance performance of the

The Development Trends of Air Cooling Systems
The studies above show that improving the air cooling BTMS performance is commonly achieved by optimizing the battery pack design, improving cooling channel design, and adding high thermal conductive material to enhance heat conduction.With the optimal design of the battery pack and cooling channel and the addition of new substructures such as fins, local turbulence can be enhanced, convective heat transfer coefficient can be increased, and hot spots can be minimized.Further improving cooling capacity will be achieved by combining the most advanced thermally conductive materials.
Comparing the air cooling BTMS with other cooling methods, the former offers lowest manufacturing costs as well as the most compact and reliable design.However, it is still possible for the single air cooling BTMS to fail under certain extreme conditions, including long-term operation at a high rate of charging or discharge and extreme ambient temperatures.To deal with unpredictable battery failure and thermal runaway, the trends in developing air-cooling systems are improving cooling efficiency, reducing power consumption, and increasing high-temperature adaptability.
(1) Improving cooling efficiency: Future air-cooling systems will further improve cooling efficiency to meet the increasing power density of the battery.By optimizing the design of the cooling system, the air fluidity and heat dissipation area are improved.
Combining other cooling methods with air cooling, including PCM structures, liquid cooling, HVAC systems, heat pipes etc., an air-cooling system with these advanced enhancements should provide adequate cooling for new energy vehicles' high-energy battery packs.
(2) Reducing power consumption: The air-cooling system will consume a certain amount of energy in the process of operation, so one of the future trends is to reduce the power consumption of the cooling system.By improving the fan design, optimizing the structure and flow characteristics of the cooling system, and reducing the air flow resistance and energy loss, more energy is saved in the air-cooling system.(3) Increasing high-temperature adaptability: The battery is easy to overheat in hightemperature environment, so the future air-cooling system will be better adapted to high-temperature environments.High-temperature-resistant materials and structure designs are adopted to improve the high-temperature resistance performance of the cooling system, ensuring that the battery temperature can be effectively reduced under high-temperature conditions.

Liquid-Cooling Technology
Since liquids have higher thermal conductivity and are better at dissipating heat, liquid cooling technology is better suited for cooling large battery packs [78].Depending on whether the liquid is in direct contact with the batteries or not, the cooling liquid can be classified into indirect (non-contact) cooling liquid and immersion (contact) cooling liquid [79,80].

Indirect Liquid Cooling Technology
Today, indirect liquid cooling is a common method of dissipating heat in the BTMS of new energy vehicles.There are two main implementation methods, shown in Figure 18: (1) dissipating heat through the tubes or tube sheets in the battery pack [81][82][83] and (2) installing the batteries on the liquid cooling plate [84][85][86].These two methods work by making the cooling liquid flow into the tubes or the cooling plate, where the heat is exchanged with the batteries.
Processes 2023, 11, x FOR PEER REVIEW 15 of 36 whether the liquid is in direct contact with the ba eries or not, the cooling liquid can be classified into indirect (non-contact) cooling liquid and immersion (contact) cooling liquid [79,80].

Indirect Liquid Cooling Technology
Today, indirect liquid cooling is a common method of dissipating heat in the BTMS of new energy vehicles.There are two main implementation methods, shown in Figure 18: (1) dissipating heat through the tubes or tube sheets in the ba ery pack [81][82][83] and (2) installing the ba eries on the liquid cooling plate [84][85][86].These two methods work by making the cooling liquid flow into the tubes or the cooling plate, where the heat is exchanged with the ba eries.The indirect liquid cooling system can operate at temperatures ranging from −40 °C to 105 °C because it often uses water or glycol solution as coolant.A high thermal conductivity makes the liquid cooling BTMS more efficient and capable of achieving higher cooling capacity than other cooling systems.The indirect liquid cooling system can operate at temperatures ranging from −40 • C to 105 • C because it often uses water or glycol solution as coolant.A high thermal conductivity makes the liquid cooling BTMS more efficient and capable of achieving higher cooling capacity than other cooling systems.
At the same time, due to high heat capacity, liquid coolants' flow rate is much lower than that of other systems when removing heat at the same rate.The electric water pump is quieter than the electric fan when powered by the same amount of electricity.According to the study [87], the glycol coolant mass flow rate, cooling intervention time, and concentration were studied to determine their effects on the battery thermal field.When a 40% concentration ethylene glycol coolant was used, the standard deviation of the battery's temperature field and the pressure difference of its cooling plate were 0.92 • C and 5.81 Pa, respectively.It was also pointed out that battery packs with lower concentrations have better temperature uniformity.The thermal management requirements of electric vehicles can be met using an ethylene glycol solution at concentrations ranging from 20% to 40% in regions with mild climates.However, the indirect liquid cooling systems in electric vehicles have certain drawbacks, such as their large and heavy structures, which impact the driving range per charge [88], and the risk of leakage of electrically conductive coolants.
On one hand, the indirect liquid cooling system has more thermal resistance because the heat generated by the battery must first pass through the liquid-cooled tube wall before it can be transferred away.As the coolants flow, the temperature of the coolant will keep rising, causing a decrease in the temperature balance within the battery pack.Research on indirect liquid cooling has primarily focused on optimizing the structure of the coolant channels [89-97] (as shown in Figures 19 and 20), improving the performance of coolants [96,97], and coupling with solid-liquid phase change cooling [98,99].These efforts aim to improve the heat dissipation capacity of indirect liquid cooling and ensure a uniform battery pack temperature in recent years.Figure 21 shows that adding conductive material AgO and increasing the volume fraction of AgO (1%vf, 2%vf, 4%vf) in the liquid can realize a better cooling effect [96].Based on the results of the study [98], a new method of delayed liquid cooling was proposed, combining liquid cooling with PCM cooling.It demonstrated high-temperature uniformity and reduced pumping power, as shown in Figure 22.
Processes 2023, 11, x FOR PEER REVIEW 16 of 3 vehicles have certain drawbacks, such as their large and heavy structures, which impa the driving range per charge [88], and the risk of leakage of electrically conductive coo ants.
On one hand, the indirect liquid cooling system has more thermal resistance becaus the heat generated by the ba ery must first pass through the liquid-cooled tube wall be fore it can be transferred away.As the coolants flow, the temperature of the coolant wi keep rising, causing a decrease in the temperature balance within the ba ery pack.R search on indirect liquid cooling has primarily focused on optimizing the structure of th coolant channels [89-97] (as shown in Figures 19 and 20), improving the performance o coolants [96,97], and coupling with solid-liquid phase change cooling [98,99].These effor aim to improve the heat dissipation capacity of indirect liquid cooling and ensure a un form ba ery pack temperature in recent years.Figure 21 shows that adding conductiv material AgO and increasing the volume fraction of AgO (1%vf, 2%vf, 4%vf) in the liqui can realize a be er cooling effect [96].Based on the results of the study [98], a new metho of delayed liquid cooling was proposed, combining liquid cooling with PCM cooling.demonstrated high-temperature uniformity and reduced pumping power, as shown i Figure 22.    Figure 22.A new scheme of delayed liquid cooling and the corresponding results [98].
On the other hand, a crucial seal is required within the entire BTMS to ensure the safety of the system because of the high electric conductivity of the coolants.Typically,  On the other hand, a crucial seal is required within the entire BTMS to ensure the safety of the system because of the high electric conductivity of the coolants.Typically, electric vehicles use electric conductive coolants to run the motors, power modules, or cabins, in which leakage of coolants can lead to short circuits and terrible accidents On the other hand, a crucial seal is required within the entire BTMS to ensure the safety of the system because of the high electric conductivity of the coolants.Typically, electric vehicles use electric conductive coolants to run the motors, power modules, or cabins, in which leakage of coolants can lead to short circuits and terrible accidents [100,101].Consequently, ensuring absolute safety during the usage and maintenance primarily involves focusing on the sealing design of the liquid cooling system.Liquid cooling systems, therefore, are generally more expensive to manufacture than air cooling systems.

Immersion Liquid Cooling Technology
Immersion liquid cooling technology refers to the usage of an insulating and nonflammable coolant to completely immerse the battery.By circulating the coolants or undergoing phase changes between gas and liquid states, the heat generated by the battery is quickly dissipated to keep the field uniform in the battery pack.Immersion liquid cooling involves direct contact between the battery and the coolant, resulting in a more direct and efficient heat transfer [102].Since the immersion liquid cooling structure is very simple, there are no heat exchangers, tubes or other components, and the coolants are usually insulating and non-flammable liquids, there is no safety risk caused by coolant leakage.Therefore, immersion liquid cooling technology has the characteristics of safety, high heat transfer efficiency [103], good temperature uniformity and flexible layouts [104,105].
Nelson et al. [106] modeled and simulated the forced air cooling and immersion liquid (transformer oil) cooling of BTMSs.When compared to traditional air cooling, immersion liquid cooling achieved faster heating and cooling characteristics while using relatively little energy.LUO B [107] also pointed out that at discharge rates of 1C-4C and temperature environments of −20~40 • C, the immersion liquid cooling effect was obvious.Sundin et al. [108] used AmpCool AC-100 as coolant to conduct the experiment, showing that immersion liquid cooling technology had great advantages in maintaining optimal battery temperature, reducing battery temperature fluctuations, and improving battery temperature uniformity.Researchers studied immersion liquid cooling and indirect liquid cooling in Pulugundla et al. [109].It was demonstrated that immersion liquid cooling could reduce the heat transfer resistance between the battery pack and the heat gradient along its longitudinal axis.Figure 23 shows different immersion liquid BTMSs with stationary coolant and flowing coolant.
simple, there are no heat exchangers, tubes or other components, and the coolants are usually insulating and non-flammable liquids, there is no safety risk caused by coolant leakage.Therefore, immersion liquid cooling technology has the characteristics of safety, high heat transfer efficiency [103], good temperature uniformity and flexible layouts [104,105].
Nelson et al. [106] modeled and simulated the forced air cooling and immersion liquid (transformer oil) cooling of BTMSs.When compared to traditional air cooling, immersion liquid cooling achieved faster heating and cooling characteristics while using relatively li le energy.LUO B [107] also pointed out that at discharge rates of 1C-4C and temperature environments of −20~40 °C, the immersion liquid cooling effect was obvious.Sundin et al. [108] used AmpCool AC-100 as coolant to conduct the experiment, showing that immersion liquid cooling technology had great advantages in maintaining optimal ba ery temperature, reducing ba ery temperature fluctuations, and improving ba ery temperature uniformity.Researchers studied immersion liquid cooling and indirect liquid cooling in Pulugundla et al. [109].It was demonstrated that immersion liquid cooling could reduce the heat transfer resistance between the ba ery pack and the heat gradient along its longitudinal axis.Figure 23 shows different immersion liquid BTMSs with stationary coolant and flowing coolant.Since immersion liquid cooling technology has high heat transfer efficiency and good temperature uniformity, Table 2 below summarizes the focuses and conclusions of studies conducted on its performance with respect to heat dissipation.Since immersion liquid cooling technology has high heat transfer efficiency and good temperature uniformity, Table 2 below summarizes the focuses and conclusions of studies conducted on its performance with respect to heat dissipation.With an increase in oil immersion volume and flow rate, and by changing positions of inlet and outlet, the battery thermal effect will be significantly improved.

SS/BN composite + water
Single phase cooling

Different BN material ratios in SS
The composite material with 10wt% BN content should be the best choice for the battery surface coating material.

Different liquid level
There is a positive correlation between the heat dissipation ability of the coolant and the liquid level of the coolant.

Mineral oil Single phase cooling
Different battery pack aspect ratios, battery spacing A wider battery pack helps to improve temperature uniformity within the battery pack, while a narrower battery pack helps reduce system power consumption.

Different coolant channels, flow speeds, flow directions
With increasing height of the flow channel, maximum temperature, and maximum difference of temperature decrease, while power consumption increases with increasing flow rate.

Different manifold structure in flow channel
Compared with separator thickness and outlet width, manifold channel width and battery spacing are two important factors.

Dielectric fluid Single phase cooling
Weather the coolant is flow, weather there is tabs There is a 46.3% reduction in tab temperature of the battery thanks to the coolant flow and tab cooling aid.

Different flow rate, battery design arrangements and overheated batteries
A minimum flow rate of 0.5L/min is recommended for the battery pack in order to achieve less than 5 • C temperature non-uniformity.

Different coolant inlet temperature, inlet flow rate
With a faster coolant flow rate, the battery pack maximum temperature will be lower; with a slower coolant flow rate, the temperature difference in the battery will be smaller and the battery will perform better.In addition, study [122] suggested the original air-conditioning system could be expanded by adding paths because there is already an air-conditioning system in modern  In addition, study [122] suggested the original air-conditioning system could be expanded by adding paths because there is already an air-conditioning system in modern In addition, study [122] suggested the original air-conditioning system could be expanded by adding paths because there is already an air-conditioning system in modern vehicles, so that the refrigerant can directly enter the heat exchanger in the battery pack for heat exchange, as shown in Figure 26.Compared to other cooling methods, this suggestion is very simple and direct since there are no extra coolants and equipment [123].However, this cooling method has the problem of refrigerant evaporating to dryness, that is, the refrigerant may evaporate in advance in the middle or at end of the battery pack evaporator, and the gaseous refrigerant, having poor heat transfer capacity, may cause an inhomogeneous temperature distribution in the battery pack.At the same time, since it is a priority to consider battery safety, vehicles using this cooling method may affect the thermal comfort of passengers [124].Meanwhile, to ensure that the system cools effectively, the boiling process should be complexly designed, and a reasonable expansion valve control strategy should be set at the same time [125].This has led to studies on the cooling method in recent years, focusing on the optimization of system performance [126], the development of control strategies [127], and the influence on system performance due to refrigerant substitution [128] and the introduction of new refrigerants [129,130].
Processes 2023, 11, x FOR PEER REVIEW 21 of 36 vehicles, so that the refrigerant can directly enter the heat exchanger in the ba ery pack for heat exchange, as shown in Figure 26.Compared to other cooling methods, this suggestion is very simple and direct since there are no extra coolants and equipment [123].However, this cooling method has the problem of refrigerant evaporating to dryness, that is, the refrigerant may evaporate in advance in the middle or at end of the ba ery pack evaporator, and the gaseous refrigerant, having poor heat transfer capacity, may cause an inhomogeneous temperature distribution in the ba ery pack.At the same time, since it is a priority to consider ba ery safety, vehicles using this cooling method may affect the thermal comfort of passengers [124].Meanwhile, to ensure that the system cools effectively, the boiling process should be complexly designed, and a reasonable expansion valve control strategy should be set at the same time [125].This has led to studies on the cooling method in recent years, focusing on the optimization of system performance [126], the development of control strategies [127], and the influence on system performance due to refrigerant substitution [128] and the introduction of new refrigerants [129,130].

The Development Trends in Liquid Cooling Systems
Besides the complex internal structure of an indirect liquid cooling system, which contains a lot of coolant tubes and cold plates affecting the ba ery pack's energy density, the potential leakage risks of conductive coolants may have a certain negative impact on the safety of the ba ery pack.In the immersion liquid cooling system, insulating and nonflammable coolants are used.Many researchers focus on different coolant inlet temperatures, inlet flow rates, coolant channels, etc. to study the influencing factors and search for optimal design configurations.To help the liquid cooling system work well, current development trends include efficient cooling technology, intelligent cooling control, heat management integration, and lightweight design.
(1) Efficient cooling technology: For ba eries to remain safe, more efficient cooling systems are required as power increases.Some new cooling technologies, such as microchannel cooling, have been introduced into ba ery systems to improve cooling efficiency.(2) Intelligent cooling control: In order to be er manage the ba ery temperature, intelligent cooling control systems are ge ing more and more a ention.These systems can monitor the temperature of the ba ery in real time and adjust the working state of the cooling system as needed to keep the temperature of the ba ery in the proper range.(3) Heat management integration: To improve overall efficiency and save space, some new liquid cooling systems are integrated with other heat management systems.For

The Development Trends in Liquid Cooling Systems
Besides the complex internal structure of an indirect liquid cooling system, which contains a lot of coolant tubes and cold plates affecting the battery pack's energy density, the potential leakage risks of conductive coolants may have a certain negative impact on the safety of the battery pack.In the immersion liquid cooling system, insulating and non-flammable coolants are used.Many researchers focus on different coolant inlet temperatures, inlet flow rates, coolant channels, etc. to study the influencing factors and search for optimal design configurations.To help the liquid cooling system work well, current development trends include efficient cooling technology, intelligent cooling control, heat management integration, and lightweight design.
(1) Efficient cooling technology: For batteries to remain safe, more efficient cooling systems are required as power increases.Some new cooling technologies, such as microchannel cooling, have been introduced into battery systems to improve cooling efficiency.(2) Intelligent cooling control: In order to better manage the battery temperature, intelligent cooling control systems are getting more and more attention.These systems can monitor the temperature of the battery in real time and adjust the working state of the cooling system as needed to keep the temperature of the battery in the proper range.(3) Heat management integration: To improve overall efficiency and save space, some new liquid cooling systems are integrated with other heat management systems.For example, cooling systems can be combined with air conditioning or seat heating systems to better manage battery and interior temperatures.(4) Lightweight design: For the vehicle to be lightweight, the design of the liquid cooling system also focuses on weight reduction.The use of lightweight materials and structural optimization can reduce the weight of the system and improve the overall performance of the battery system.

Phase Change Materials Cooling Technology
Phase change materials (PCMs) usually have large latent heat that can be stored and released when phase changes occur.PCMs are usually packaged outside the batteries, as shown in Figure 27.The heat generated by the batteries first reaches the PCMs, where it is absorbed by the PCMs.When the temperature of PCMs reaches the phase change point, these materials undergo a phase transition.Before the complete phase transition, the temperature of PCMs is basically unchanged, so the battery can be kept at a suitable working temperature during most of the working time.The study [131] listed the main criteria for selecting suitable PCMs for BTMSs, among which the melting point ranked first.In fact, this value should be chosen within the desired operating temperature of the battery.PCM cooling technology belongs in the category of passive cooling technology, which can be further divided into solid-liquid phase change cooling and gas-liquid phase change cooling, according to the phase change processes.
tems to be er manage ba ery and interior temperatures.(4) Lightweight design: For the vehicle to be lightweight, the design of the liquid coolin system also focuses on weight reduction.The use of lightweight materials and struc tural optimization can reduce the weight of the system and improve the overall per formance of the ba ery system.

Phase Change Materials Cooling Technology
Phase change materials (PCMs) usually have large latent heat that can be stored and released when phase changes occur.PCMs are usually packaged outside the ba eries, a shown in Figure 27.The heat generated by the ba eries first reaches the PCMs, where i is absorbed by the PCMs.When the temperature of PCMs reaches the phase change poin these materials undergo a phase transition.Before the complete phase transition, the tem perature of PCMs is basically unchanged, so the ba ery can be kept at a suitable workin temperature during most of the working time.The study [131] listed the main criteria fo selecting suitable PCMs for BTMSs, among which the melting point ranked first.In fac this value should be chosen within the desired operating temperature of the ba ery.PCM cooling technology belongs in the category of passive cooling technology, which can b further divided into solid-liquid phase change cooling and gas-liquid phase change cool ing, according to the phase change processes.

Solid-Liquid Phase Change Cooling Technology
The solid-liquid phase change cooling technology has a simple structure, high effi ciency, and good temperature uniformity [132,133].The most common PCMs include or ganic materials, inorganic materials, and eutectic materials [134].Inorganic materials and eutectic materials are less studied due to their characteristics [135,136].In terms of organi materials, paraffin is considered excellent due to its high latent heat, good stability, non supercooling property, and low toxicity [137].As a result, it is widely used in solid-liquid phase change cooling systems.The melting temperature of paraffin is 40-44 °C, and th latent heat between the liquid state and solid state is 195 kJ/kg, and the solid and liquid densities are 822 kg/m 3 and 910 kg/m 3 , respectively.However, the thermal conductivity o paraffin is low, about 0.25 W/(m•K), so the melting is not uniform during the phase tran sition.The study [138] pointed out that when paraffin was used as a phase change mate rial, the temperature of the center increased by nearly 30 °C, and the temperature of th edge increased by only about 20 °C, resulting in a large thermal gradient between th ba eries in the ba ery pack.In addition, there was leakage risk of melted paraffin.
In order to solve the problems of low thermal conductivity and the large therma gradient, the researchers' efforts on solid-liquid phase change cooling technology in recen years mainly focus on the manufacture of composite PCMs.Adding other materials to th

Solid-Liquid Phase Change Cooling Technology
The solid-liquid phase change cooling technology has a simple structure, high efficiency, and good temperature uniformity [132,133].The most common PCMs include organic materials, inorganic materials, and eutectic materials [134].Inorganic materials and eutectic materials are less studied due to their characteristics [135,136].In terms of organic materials, paraffin is considered excellent due to its high latent heat, good stability, nonsupercooling property, and low toxicity [137].As a result, it is widely used in solid-liquid phase change cooling systems.The melting temperature of paraffin is 40-44 • C, and the latent heat between the liquid state and solid state is 195 kJ/kg, and the solid and liquid densities are 822 kg/m 3 and 910 kg/m 3 , respectively.However, the thermal conductivity of paraffin is low, about 0.25 W/(m•K), so the melting is not uniform during the phase transition.The study [138] pointed out that when paraffin was used as a phase change material, the temperature of the center increased by nearly 30 • C, and the temperature of the edge increased by only about 20 • C, resulting in a large thermal gradient between the batteries in the battery pack.In addition, there was leakage risk of melted paraffin.
In order to solve the problems of low thermal conductivity and the large thermal gradient, the researchers' efforts on solid-liquid phase change cooling technology in recent years mainly focus on the manufacture of composite PCMs.Adding other materials to the original PCMs can enhance structural stability, thermal conductivity, and heat dissipation effects.For example, adding expanded graphite [139][140][141], carbon foam [140], metal foam [142], metal particles [143] and so on have been considered.The range of thermal conductivity of composite PCMs in [45,138] can be increased to 3-16.6 W/(m•K). Figure 28 shows how to prepare the composite PCM/GNP and PCM/carbon foam, and the results demonstrate that by adding graphite and carbon foam to paraffin wax, its thermal properties are increased.In addition, leakage is prevented, contributing to its stable thermal performance [140].
x FOR PEER REVIEW 23 of 36 how to prepare the composite PCM/GNP and PCM/carbon foam, and the results demonstrate that by adding graphite and carbon foam to paraffin wax, its thermal properties are increased.In addition, leakage is prevented, contributing to its stable thermal performance [140].If only PCMs are used to control the ba ery temperature during continuous highrate charge and discharge cycles, the desired effect may not be achieved.Due to the poor effect of the passive cooling systems, some scholars have also proposed adding a lowpower active cooling system to form a hybrid cooling system to deal with the exhaustion of latent heat in PCMs in some extreme cases [144].Therefore, searching for extra methods to help PCM systems has always been a research focus.For example, an additional cooling system is needed to assist in heat dissipation, such as combining solid-liquid PCMs with air cooling systems [77,[145][146][147][148], with liquid cooling systems [98,99,[149][150][151][152], or with heat pipes [153][154][155] etc. Figures 29-31 show how the solid-liquid PCMs are combined with air cooling systems, liquid cooling systems, and heat pipes, respectively.If only PCMs are used to control the battery temperature during continuous high-rate charge and discharge cycles, the desired effect may not be achieved.Due to the poor effect of the passive cooling systems, some scholars have also proposed adding a low-power active cooling system to form a hybrid cooling system to deal with the exhaustion of latent heat in PCMs in some extreme cases [144].Therefore, searching for extra methods to help PCM systems has always been a research focus.For example, an additional cooling system is needed to assist in heat dissipation, such as combining solid-liquid PCMs with air cooling systems [77,[145][146][147][148], with liquid cooling systems [98,99,[149][150][151][152], or with heat pipes [153][154][155]

Gas-Liquid Phase Change Cooling Technology
Gas-liquid phase change cooling technology mainly means heat pipe cooling, in which liquid changes to gas when heated and the gas returns to a liquid state when cooled.The battery heats the evaporation section of the heat pipe, and the liquid inside the pipe core evaporates to steam as a result.During condensing, the steam releases latent heat and returns to liquid, which passes through the central channel of the heat pipe.After the liquid has been condensed, it flows by capillary or gravity back to the evaporation section, forming a closed cycle, as shown in Figure 32.Therefore, the condensation section absorbs a large amount of heat from the evaporation section, and then releases the heat to the external environment.At present, common heat pipes include capillary heat pipes (CHP), gravity heat pipes (GHP), and micro heat pipes (MHP) [156].Micro heat pipes mainly include pulsating heat pipes (PHP), micro-grooved flat heat pipes (MGFHP), and loop heat pipes (LHP).The characteristics of these different heat pipes, along with their advantages and disadvantages in the power battery heat dissipation process, are listed in Table 3 [157].
Processes 2023, 11, x FOR PEER REVIEW 25 of 36 Gas-liquid phase change cooling technology mainly means heat pipe cooling, in which liquid changes to gas when heated and the gas returns to a liquid state when cooled.The ba ery heats the evaporation section of the heat pipe, and the liquid inside the pipe core evaporates to steam as a result.During condensing, the steam releases latent heat and returns to liquid, which passes through the central channel of the heat pipe.After the liquid has been condensed, it flows by capillary or gravity back to the evaporation section, forming a closed cycle, as shown in Figure 32.Therefore, the condensation section absorbs a large amount of heat from the evaporation section, and then releases the heat to the external environment.At present, common heat pipes include capillary heat pipes (CHP), gravity heat pipes (GHP), and micro heat pipes (MHP) [156].Micro heat pipes mainly include pulsating heat pipes (PHP), micro-grooved flat heat pipes (MGFHP), and loop heat pipes (LHP).The characteristics of these different heat pipes, along with their advantages and disadvantages in the power ba ery heat dissipation process, are listed in Table 3 [157].Table 3. Differences between different types of heat pipes in power ba ery cooling [157].

Types
Advantages Disadvantages

CHP
It is capable of fulfilling the heat dissipation needs of different electric fan configurations, while also having less stringent placement angle requirements.
There is a capillary limit.It is not suitable for high heat production conditions, and the cost is high.

GHP
According to the battery heat dissipation conditions, it is easy to process into the required structure, and the cost is low.
It is greatly affected by gravity and the placement angle is limited.Designing a heat dissipation system is difficult.

PHP
Due to the large equivalent heat transfer coefficient, the battery has a good antigravity performance and can effectively reduce the temperature rise.It also starts quickly.
The operating characteristics are complex.There are many factors affecting performance.Theoretical and application research is in the initial phase.

MGFHP
It can reduce the temperature difference between batteries and the weight of the heat dissipation structure, and it has good antigravity performance.
Due to insufficient capillary force, it is not suitable for high heat production conditions, and it is difficult to produce.Table 3. Differences between different types of heat pipes in power battery cooling [157].

CHP
It is capable of fulfilling the heat dissipation needs of different electric fan configurations, while also having less stringent placement angle requirements.
There is a capillary limit.It is not suitable for high heat production conditions, and the cost is high.

GHP
According to the battery heat dissipation conditions, it is easy to process into the required structure, and the cost is low.
It is greatly affected by gravity and the placement angle is limited.Designing a heat dissipation system is difficult.

PHP
Due to the large equivalent heat transfer coefficient, the battery has a good antigravity performance and can effectively reduce the temperature rise.It also starts quickly.
The operating characteristics are complex.There are many factors affecting performance.Theoretical and application research is in the initial phase.

MGFHP
It can reduce the temperature difference between batteries and the weight of the heat dissipation structure, and it has good anti-gravity performance.
Due to insufficient capillary force, it is not suitable for high heat production conditions, and it is difficult to produce.

LHP
It is suitable for long-distance heat dissipation, the evaporation section and condensation section can be designed separately and is less affected by gravity.
It is not suitable for compact and distributed high heat flux cooling conditions, and it is difficult to start with low heat load.
Heat pipes have been used in electronics and aerospace because of their light weight, low cost, high flexibility, and especially high thermal conductivity.In the battery cooling system, early research used a combination of heat pipes and air cooling.The heat pipe coupled with air cooling can improve the insufficient heat dissipation under air cooling conditions [158][159][160][161], which proves that it can achieve a good heat dissipation effect for the power battery.However, the power battery is not able to dissipate the heat generated by increasing its contact area alone, as the heat generation increases.Some scholars have adopted the coupling of flat heat pipes and air cooling and found that the effect of heat pipe coupling with forced air cooling is better [162], but there are cases where the cooling rate of the battery gradually decreases with the increase of air speed [163].When air speed is increased, the cooling effect does not change significantly because of the poor thermal conductivity of the air.Even adding fins [164][165][166] to the condensation section of the heat pipe can only meet a part of the heat dissipation demand.
In addition to liquid cooling, heat pipes can help make up for the low specific heat capacity of air.Using CHP, Behi et al. [167] proved that the liquid-cooling-coupled heat pipe system outperforms an air-cooling-coupled heat pipe system in terms of cooling effect, and the maximum temperature of the battery is reduced by about 30%.At the same time, scholars have also studied the influence of heat pipe heights [168], inner diameters [169], working fluids [170], and coolant conditions [171][172][173] on the heat transfer performance in the case of a heat pipe coupled with liquid cooling.It is true that heat pipes combined with liquid cooling have better cooling performance, but problems such as complex structure, high costs, and easy leakage may hamper its development.
Figure 33 shows how heat pipes are combined with liquid cooling systems, while Figure 34 demonstrates that the height of the conduction element (H) has the largest effect on the performance of the heat pipes.The factors considered are the height of the conduction element(H), the circumference angle (θ), the thickness of the con duction element (δ), the battery spacing (D), and the random error (E).

LHP
tion section can be designed separately and is less affected by gravity.
flux cooling conditions, and it is difficult to start with low heat load.
Heat pipes have been used in electronics and aerospace because of their light weight, low cost, high flexibility, and especially high thermal conductivity.In the ba ery cooling system, early research used a combination of heat pipes and air cooling.The heat pipe coupled with air cooling can improve the insufficient heat dissipation under air cooling conditions [158][159][160][161], which proves that it can achieve a good heat dissipation effect for the power ba ery.However, the power ba ery is not able to dissipate the heat generated by increasing its contact area alone, as the heat generation increases.Some scholars have adopted the coupling of flat heat pipes and air cooling and found that the effect of heat pipe coupling with forced air cooling is be er [162], but there are cases where the cooling rate of the ba ery gradually decreases with the increase of air speed [163].When air speed is increased, the cooling effect does not change significantly because of the poor thermal conductivity of the air.Even adding fins [164][165][166] to the condensation section of the heat pipe can only meet a part of the heat dissipation demand.
In addition to liquid cooling, heat pipes can help make up for the low specific heat capacity of air.Using CHP, Behi et al. [167] proved that the liquid-cooling-coupled heat pipe system outperforms an air-cooling-coupled heat pipe system in terms of cooling effect, and the maximum temperature of the ba ery is reduced by about 30%.At the same time, scholars have also studied the influence of heat pipe heights [168], inner diameters [169], working fluids [170], and coolant conditions [171][172][173] on the heat transfer performance in the case of a heat pipe coupled with liquid cooling.It is true that heat pipes combined with liquid cooling have be er cooling performance, but problems such as complex structure, high costs, and easy leakage may hamper its development.
Figure 33 shows how heat pipes are combined with liquid cooling systems, while Figure 34 demonstrates that the height of the conduction element (H) has the largest effect on the performance of the heat pipes.The factors considered are the height of the conduction element(H), the circumference angle (θ), the thickness of the con duction element (δ), the ba ery spacing (D), and the random error (E).When the heat pipe is coupled with the solid-liquid PCMs, solid-liquid PCMs can absorb or store the heat generated by the ba ery through sensible heat or latent heat, and then transfer it away through the heat pipe, effectively reducing heat accumulation [31,[174][175][176]. Figure 35 shows the heat transfer and exchange process in a heat pipe combined with PCM.At this time, the heat taken by the heat pipe also needs to be taken away by air or liquid.The heat pipe combined with a solid-liquid PCM cooling system not only has good cooling performance, but also shows good thermal uniformity.The system can When the heat pipe is coupled with the solid-liquid PCMs, solid-liquid PCMs can absorb or store the heat generated by the battery through sensible heat or latent heat, and then transfer it away through the heat pipe, effectively reducing heat accumulation [31,[174][175][176]. Figure 35 shows the heat transfer and exchange process in a heat pipe combined with PCM.At this time, the heat taken by the heat pipe also needs to be taken away by air or liquid.The heat pipe combined with a solid-liquid PCM cooling system not only has good cooling performance, but also shows good thermal uniformity.The system can be supplemented with air cooling or liquid cooling to further improve the cooling performance, but the heat pipe needs to be reasonably designed, and choosing the appropriate cooling medium is also very important.When the heat pipe is coupled with the solid-liquid PCMs, solid-liquid PCMs can absorb or store the heat generated by the ba ery through sensible heat or latent heat, and then transfer it away through the heat pipe, effectively reducing heat accumulation [31,[174][175][176]. Figure 35 shows the heat transfer and exchange process in a heat pipe combined with PCM.At this time, the heat taken by the heat pipe also needs to be taken away by air or liquid.The heat pipe combined with a solid-liquid PCM cooling system not only has good cooling performance, but also shows good thermal uniformity.The system can be supplemented with air cooling or liquid cooling to further improve the cooling performance, but the heat pipe needs to be reasonably designed, and choosing the appropriate cooling medium is also very important.

The Development Trends of PCM Cooling Systems
For the solid-liquid PCMs and gas-liquid PCMs represented by the heat pipe, the combination of PCMs and other cooling systems has partly solved the limitations of phase change cooling technology and expanded their application range.In the future, the PCM cooling system will exhibit the following trends: increased cooling efficiency, miniaturization and integration, and sustainability.

The Development Trends of PCM Cooling Systems
For the solid-liquid PCMs and gas-liquid PCMs represented by the heat pipe, the combination of PCMs and other cooling systems has partly solved the limitations of phase change cooling technology and expanded their application range.In the future, the PCM cooling system will exhibit the following trends: increased cooling efficiency, miniaturization and integration, and sustainability.
(1) Increased cooling efficiency: The cooling system of PCMs will further improve cooling efficiency to cope with the increasing power density of the battery.By increasing the thermal conductivity and thermal capacity of PCMs, a more efficient cooling system is designed to improve the heat dissipation performance of the battery.(2) Miniaturization and integration: The future PCM cooling system will develop towards miniaturization and integration.In order to simplify the equipment and structure, PCMs cooling systems need to become more compact and lightweight to meet the needs.At the same time, PCM cooling systems may be integrated with other battery management systems or electronic devices to improve overall system performance and efficiency.(3) Sustainability: Future PCM cooling systems will focus on sustainability and environmental performance.The selection and preparation of phase change materials may be more environmentally friendly and reduce the impact on the environment.At the same time, PCM cooling systems may also be integrated with technologies such as renewable energy to achieve more sustainable energy management.

Summary
New energy vehicles are an important measure for global energy conservation and CO 2 reduction, and the power battery is its key component.This paper briefly introduces the heat generation mechanism and models, and emphatically summarizes the main principles, research focuses, and development trends of cooling technologies used in the thermal management of power batteries for new energy vehicles in the past few years.

Conclusions
Currently, the commonly used models for battery heat generation are electrochemicalthermal models and electrical-thermal models.Scholars have conducted more research based on multidimensional electrochemical-thermal/electrical-thermal models because taking the actual characteristics of the battery into account can provide a more comprehensive and systematic description.
The air cooling BTMS boasts the most economical manufacturing cost and a compact and reliable structure, making it suitable for small battery systems.The focus of air cooling systems in recent years has mainly been the optimization of battery pack design, the improvement of the cooling channel, and the addition of the thermal conductivity material, as well as the exploration of combinations with other cooling methods.To deal with unpredictable battery failure and thermal runaway, the trends in developing air-cooling systems are improving cooling efficiency, reducing power consumption, and increasing high-temperature adaptability.
The heat transfer coefficient of the liquid cooling system is high.Indirect liquid cooling BTMS has the disadvantage of a complex structure and the risk of leakage of electrically conductive coolant.While making use of an insulating and non-flammable coolant to completely immerse the battery, immersion liquid cooling technology achieves higher cooling performance.Searching for a suitable liquid coolant, optimal flow rate and temperature are the main focus of immersion liquid cooling technology.In addition, future development trends include efficient cooling technology, intelligent cooling control, heat management integration, and light weight design.
The PCM cooling system includes solid-liquid PCMs and liquid-gas PCMs represented by heat pipes.They use the characteristics of the phase change materials, absorbing a large amount of heat in the process of phase transition, to achieve a high-efficiency cooling effect.Searching for high thermal conductivity materials, optimal system design, and the exploration of combinations with other methods are the main focuses of PCM cooling systems.In the future, the PCM cooling system will witness development trends such as increasing cooling efficiency, miniaturization and integration, and sustainability.

Future Prospects
At present, against the background of increasing energy density in future batteries, immersion liquid phase change cooling technology has great development prospects.This liquid cooling system lowers the temperature of the battery by introducing coolant to improve its performance and lifespan.Compared to traditional air-cooling systems, liquid-cooling systems can provide higher cooling efficiency and better control of the temperature of batteries.In addition, immersion liquid phase change cooling technology can effectively solve the heat dissipation problem of high-power batteries and improve their safety performance.However, the high cost and heavy weight of liquid cooling systems, as well as the need to find suitable coolants, are the main challenges that need to be overcome.
Due to current technological limitations, there is currently no perfect cooling system.In the future, lithium-ion battery thermal management technology combining multiple cooling methods is the main development direction.Suitable thermal management technologies can be selected and combined based on the advantages and disadvantages of different cooling technologies to meet the thermal management needs of different users.At the same time, by adding sensors and intelligent control, the operation of the cooling systems can be dynamically adjusted to control the temperature of the battery more accurately.

Figure 2 .
Figure 2. Schematic diagram of (a) charging and (b) discharging of lithium-ion ba eries.

Figure 2 .
Figure 2. Schematic diagram of (a) charging and (b) discharging of lithium-ion batteries.

Figure 3 .
Figure 3. (a) Longitudinal section of a commercial lithium-ion cell, and (b) illustration of the pseudotwo-dimension electrochemical model [10].

Processes 2023 ,
11, x FOR PEER REVIEW 7 of 36 demonstrating its ability to predict ba ery temperature with reasonable accuracy.The mathematical model of CHIN et al. [17] was coupled with the electric model in order to estimate voltages, core temperatures, and surface temperatures under thermal uncertainties.

Figure 5 .
Figure 5. Coordinate system and layered structure of the prismatic ba ery [14].

2. 3 . 1 .
The Effect of High Temperature on Ba ery Performance

Figure 5 .
Figure 5. Coordinate system and layered structure of the prismatic battery [14].

Figure 8 .
Figure 8. Temperature distribution in the ba ery pack of (a) a square shape and (b) a rectangular shape at a full discharge point [48].

Figure 9 .
Figure 9.The overall structure of tilting the ba ery pack casing [54].

Figure 8 .
Figure 8. Temperature distribution in the battery pack of (a) a square shape and (b) a rectangular shape at a full discharge point [48].

Figure 8 .
Figure 8. Temperature distribution in the ba ery pack of (a) a square shape and (b) a rectangular shape at a full discharge point [48].

Figure 9 .
Figure 9.The overall structure of tilting the ba ery pack casing [54].Figure 9.The overall structure of tilting the battery pack casing [54].

Figure 11 .
Figure 11.The maximum temperature rise at the end of the discharge at a 2C discharge rate with different arrangements: (a) aligned, (b) staggered, (c) cross, and (d) schematic diagrams [51].

Figure 11 .
Figure 11.The maximum temperature rise at the end of the discharge at a 2C discharge rate with different arrangements: (a) aligned, (b) staggered, (c) cross, and (d) schematic diagrams [51].

Figure 15 .
Figure 15.Comparison among the three cooling types: no cooling, air cooling, and hybrid cooling, (a) average pack temperature, (b) temperature non-uniformity comparison [72].

Figure 22 .
Figure 22.A new scheme of delayed liquid cooling and the corresponding results [98].

Figure 22 .
Figure 22.A new scheme of delayed liquid cooling and the corresponding results [98].

Figure 24 .
Figure 24.Diagrams of (a) the DLC ba ery pack, (b) ba ery block, and (c) side views of the ba ery blocks with different flow channel configurations [117].

Figure 24 . 36 Figure 24 .
Figure 24.Diagrams of (a) the DLC battery pack, (b) battery block, and (c) side views of the battery blocks with different flow channel configurations [117].
etc. show how the solid-liquid PCMs are combined with air cooling systems, liquid cooling systems, and heat pipes, respectively.

Figure 29 .
Figure 29.Schematic diagram of the (a) PCM-based ba ery pack combined with air cooling, (b) experimental system [146].

Figure 32 .
Figure 32.Schematic diagram of the working principle of the heat pipe.

Figure 32 .
Figure 32.Schematic diagram of the working principle of the heat pipe.

Figure 33 .
Figure33.Heat pipe-based ba ery thermal management system combined with liquid cooling[171].Figure33.Heat pipe-based battery thermal management system combined with liquid cooling[171].

Figure 34 .
Figure 34.Different factors' effects on the range value of (a) maximum temperature and (b) temperature difference [168].

Figure 34 .
Figure 34.Different factors' effects on the range value of (a) maximum temperature and (b) temperature difference [168].

Figure 35 .
Figure 35.Heat transfer and exchange process in a heat pipe combined with PCM [174].

Figure 35 .
Figure 35.Heat transfer and exchange process in a heat pipe combined with PCM [174].

Table 1 .
The comparison of advantages and disadvantages of different cooling systems.

Table 2 .
Research on Immersion Liquid Cooling.
When coolant depth and flow rate are increased, both maximum temperature and maximum temperature difference will be reduced.

Table 2 .
Research on Immersion Liquid Cooling.