Facile Synthesis of Silver-Doped Zinc Oxide Nanostructures as E ﬃ cient Sca ﬀ olds for Detection of p-Nitrophenol

: In this paper, silver-doped zinc oxide nanoparticles were synthesized by using a solution combustion technique, in which zinc nitrate is used as an oxidizer and tartaric acid as a fuel. The phase composition, morphology and structural properties of the as-synthesized zinc oxide and silver-doped zinc oxide were established by using powdered X-ray di ﬀ raction, ﬁeld emission scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy studies. Due to well-deﬁned morphologies and crystallinity, the pure zinc oxide and silver-doped zinc oxide nanostructures can be used as e ﬃ cient chemical sensors for the detection of p-nitrophenol (PNP). ZnO was found to show a low value of the limit of detection (LOD), i.e., 2.175 µ M / L, for p-nitrophenol sensing; moreover, a sharp decrease in the limit of detection was observed with an increase in the concentration of silver ions, and the LOD value decreased to 0.669 µ M / L for 10 mol % silver-doped zinc oxide. It is therefore concluded that Ag-doped ZnO shows a lower limit of detection as compared to pure ZnO for p-nitrophenol sensing.


Introduction
Rapid industrialization and various anthropogenic activities have led to the discharge of various types of toxic chemicals, which contaminate the environment and adversely affect the ecosystem. Among various toxic chemicals, the nitrophenols and organic dyes are the most emerging environmental pollutants. In particular, p-nitrophenol (PNP) is commercially very useful and finds application in various fields such as use as an intermediate in the synthesis of paracetamol and an important base material for the synthesis of commonly used pesticides such as acetophenetidine; it also plays an

Synthesis of ZnO Nanoparticles
Pure ZnO nanostructures were synthesized from zinc nitrate hexahydrate (oxidizer) and tartaric acid (fuel) using a typical reaction procedure of solution combustion by optimizing the stoichiometric ratio (φ = 1). In the synthesis process, 4.0 g of Zn(NO 3 ) 2 ·6H 2 O and 2.0 g of C 4 H 6 O 6 were dissolved in 50 mL of deionized water, separately. Then, the tartaric acid solution was added drop-wise to the Zn(NO 3 ) 2 ·6H 2 O solution with continuous stirring at room temperature. The resultant solution was thoroughly stirred at room temperature for 30 min, and the resulting solution was heated till the evaporation of the excess water content to obtain the gel-like materials. The resulting gel-like material was transferred into a muffle furnace in a silicate crucible at 500 • C for 1 h. In the muffle furnace, tartaric acid (fuel) and zinc nitrate hexahydrate (oxidizer) were combusted for the formation of the crystalline ZnO nanostructures, at high temperature. The synthesized nanostructures were further washed with distilled water followed by ethanol, and finally, the precipitates were dried in an oven at 60 • C.

Synthesis of Ag-Doped ZnO Nanostructures
The same procedure was adopted for the synthesis of Ag-doped ZnO by taking an appropriate amount of AgNO 3 . For the synthesis of 1%, 5% and 10% Ag-doped ZnO, 0.022, 0.114 and 0.228 g of AgNO 3 dissolved in 50 mL of water was added, respectively; after that, the same procedure was adopted as in Section 2.2.

Characterization
The synthesis of the nanostructures was confirmed by characterizing them for their morphological, structural and optical properties. The morphological investigation was carried out by using field emission scanning electron microscopy (SEM) with a FEI Quanta 200 FEG (Pittsburgh, PA, USA) with the energy dispersive X-ray spectrometer Bruker XFlash 4030 (EDS), while the structural characterization was performed using X-ray diffractometer (D8 Discover, Bruker AXS, Karlsruhe, Germany). The optical properties of the as-synthesized nanostructures were examined at room temperature by using UV-visible spectroscopy (AvaSpec-2048). The XPS study of the ZnO powder and Ag-doped ZnO powder was carried out by employing X-ray energy dispersion spectrometer (Bruker XFlash 4030, Karlsruhe, Germany). The sensing properties of the pure ZnO and Ag-doped ZnO nanostructures were recorded using room-temperature photoluminescence spectra (Perkin Elmer-LS55 fluorescence spectrophotometer, Waltham, MA, USA).

Luminescent Sensor Evaluation of ZnO and Ag-ZnO Nanoparticles
The Perkin Elmer LS55 fluorescence spectrophotometer was used at room temperature to determine the sensing properties of the pure ZnO and Ag-ZnO nanostructure. In this investigation, the pure ZnO and Ag-ZnO nanostructures were utilized to fabricate the luminescent sensor interface for the sensing of PNP. The obtained ZnO and Ag-ZnO nanostructures were dispersed in DI water (1.5 mg in 50 mL of H 2 O), and a 5 mM stock solution of PNP was also prepared for the entire experiment. All the solutions were prepared 30 min before performing the experiments. The sensing experiments were performed at different concentrations of PNP in the range of 0.833-9.980 µM.

FESEM of Ag x Zn 1−x O Nanostructure
The surface morphology and variation in the particle size were studied by using high-resolution FESEM. Typical low and high magnification FESEM images of the pure ZnO, 1% Ag-ZnO, 5% Ag-ZnO and 10% Ag-ZnO nanostructures are shown in Figure 1a-h. A careful observation of Figure 1 reveals that the as-synthesized nanostructures were uniformly grown at very high density. It was also observed that the structure of ZnO did not show any deviation with the doping of silver ions and remained uniform even at a high concentration of silver ions (10% Ag ions).   Figure 2a represents the XRD spectra of the pure ZnO and Ag-ZnO nanostructures, which were recorded in the range of 20-80°. The XRD spectra show that pure ZnO has characteristic diffraction peaks attributed to the crystalline nature of ZnO. A clear peak of silver ions was also observed for the Ag-ZnO composite, confirming the doping of Ag into ZnO. The intensity of the peak also   Figure 2a represents the XRD spectra of the pure ZnO and Ag-ZnO nanostructures, which were recorded in the range of 20-80 • . The XRD spectra show that pure ZnO has characteristic diffraction peaks attributed to the crystalline nature of ZnO. A clear peak of silver ions was also observed for the Ag-ZnO composite, confirming the doping of Ag into ZnO. The intensity of the peak also revealed that there is a slight intensity increase with an increasing concentration of silver ions.

PXRD
The data were found to be in reasonable agreement with the Joint Committee on Powder Diffraction Standards (JCPDS) card for ZnO (JCPDS 036-1451) [33]. In Figure 2a Figure 2a, it can be observed that as the concentration of Ag increases, the intensity of the Ag ion peaks becomes more predominant. The XRD spectra clearly indicate that only ZnO and Ag ions are present; no other peak is found corresponding to any other impurity atom such as Zn and Ag 2 O. This simply reveals that the as-synthesized nanostructures are crystalline and pure up to the detection limit of XRD.
Furthermore, a close comparison of the peaks (100), (002) and (101) is shown in Figure 2b, which clearly reveals that up to the studied concentration of silver ions (10% Ag), no deformation in the structure is observed. The crystallite size was calculated using the XRD peak with the Debye-Scherrer formula, which is given as: where k is the structural constant, λ is the wavelength of the X-ray, D is the size of the nanoparticle and β is the full width at half maximum. Using Equation (1), the crystallite particle sizes were determined to be 39, 32, 26 and 21 nm, respectively, for the pure ZnO and 1%, 5% and 10% Ag-doped ZnO nanostructures. The data were found to be in reasonable agreement with the Joint Committee on Powder Diffraction Standards (JCPDS) card for ZnO (JCPDS 036-1451) [33]. In Figure 2a Figure 2a, it can be observed that as the concentration of Ag increases, the intensity of the Ag ion peaks becomes more predominant. The XRD spectra clearly indicate that only ZnO and Ag ions are present; no other peak is found corresponding to any other impurity atom such as Zn and Ag2O. This simply reveals that the as-synthesized nanostructures are crystalline and pure up to the detection limit of XRD.
Furthermore, a close comparison of the peaks (100), (002) and (101) is shown in Figure 2b, which clearly reveals that up to the studied concentration of silver ions (10% Ag), no deformation in the structure is observed. The crystallite size was calculated using the XRD peak with the Debye-Scherrer formula, which is given as: where k is the structural constant, λ is the wavelength of the X-ray, D is the size of the nanoparticle and β is the full width at half maximum. Using Equation (1), the crystallite particle sizes were determined to be 39, 32, 26 and 21 nm, respectively, for the pure ZnO and 1%, 5% and 10% Ag-doped ZnO nanostructures.

EDS
The composition and purity of the as-synthesized ZnO and Ag-ZnO nanostructures were investigated by using EDS. The EDS data are provided as supplementary data ( Figures S1-S4), which confirmed that the nanoparticles were made of zinc, oxygen and silver atoms only.

EDS
The composition and purity of the as-synthesized ZnO and Ag-ZnO nanostructures were investigated by using EDS. The EDS data are provided as supplementary data (Figures S1-S4), which confirmed that the nanoparticles were made of zinc, oxygen and silver atoms only.

UV-Visible
The optical properties of the Ag x Zn 1−x O (x = 0, 0.01, 0.05 and 0.10) nanostructures were studied by using UV-visible (UV-Vis) spectroscopy. The results indicate that the maximum absorption peaks are at 375, 379, 382 and 385 nm ( Figure 3) for the pure ZnO, 1% Ag-ZnO, 5% Ag-ZnO and 10% Ag-ZnO nanostructures, respectively, corresponding to wurtzite hexagonal phase bulk ZnO [29]. The red shift due to the presence of Ag ions observed in the absorption maxima is attributed to the decrease in the band gap energy with an increase in the concentration of Ag ions. No other absorption peak was detected corresponding to impurities, which confirms that the synthesized Ag/ZnO nanostructures possess good optical properties. peaks are at 375, 379, 382 and 385 nm ( Figure 3) for the pure ZnO, 1% Ag-ZnO, 5% Ag-ZnO and 10% Ag-ZnO nanostructures, respectively, corresponding to wurtzite hexagonal phase bulk ZnO [29]. The red shift due to the presence of Ag ions observed in the absorption maxima is attributed to the decrease in the band gap energy with an increase in the concentration of Ag ions. No other absorption peak was detected corresponding to impurities, which confirms that the synthesized Ag/ZnO nanostructures possess good optical properties.

XPS
The XPS survey spectra for the ZnO and Ag-doped ZnO samples are presented in Figure 4. From the spectra, one can see that the main elements on the surface of the samples are zinc, oxygen, carbon and silver. It can be noted that the silver Ag 3d peak appears only for the Ag-doped ZnO samples. A low-intensity carbon C 1s peak at 285 eV is present, most likely due to atmospheric contaminants adsorbed on the surface of the sample. High-resolution spectra were acquired in the O 1s, Zn 2p and Ag 3d regions for obtaining the atomic concentrations (Table 1) and possible chemical bond identification. The data in Table 1 were determined by calculating the appropriate peak area after Shirley background subtraction. The zinc high-resolution XPS spectra in the Zn 2p region ( Figure 5) for the ZnO and Ag-doped ZnO samples show two peaks due to spin-orbit splitting: Zn 2p3/2 and Zn 2p1/2. The position of the Zn 2p3/2 peak at approximately 1021.7 eV is assigned to the ZnO bond since it is in good agreement with the known peak values and shape for ZnO (1021.7 eV) [34,35].

XPS
The XPS survey spectra for the ZnO and Ag-doped ZnO samples are presented in Figure 4. From the spectra, one can see that the main elements on the surface of the samples are zinc, oxygen, carbon and silver. It can be noted that the silver Ag 3d peak appears only for the Ag-doped ZnO samples. A low-intensity carbon C 1s peak at 285 eV is present, most likely due to atmospheric contaminants adsorbed on the surface of the sample. High-resolution spectra were acquired in the O 1s, Zn 2p and Ag 3d regions for obtaining the atomic concentrations (Table 1) and possible chemical bond identification. The data in Table 1 were determined by calculating the appropriate peak area after Shirley background subtraction. The zinc high-resolution XPS spectra in the Zn 2p region ( Figure 5) for the ZnO and Ag-doped ZnO samples show two peaks due to spin-orbit splitting: Zn 2p 3/2 and Zn 2p 1/2 . The position of the Zn 2p 3/2 peak at approximately 1021.7 eV is assigned to the ZnO bond since it is in good agreement with the known peak values and shape for ZnO (1021.7 eV) [34,35].    The deconvolution of the O 1s spectra (Figure 6b) showed a negligible shift (less than 0.1 eV) of the main peak (ZnO) position (530.4 eV) due to the incorporation of 10% Ag. The main difference between the two spectra is in the left side of the spectra. Namely, the peaks at 531.8 eV (oxygen-deficient regions within the matrix of ZnO, green curve) and 532.5 eV (C-O bonds and     The deconvolution of the O 1s spectra (Figure 6b) showed a negligible shift (less than 0.1 eV) of the main peak (ZnO) position (530.4 eV) due to the incorporation of 10% Ag. The main difference between the two spectra is in the left side of the spectra. Namely, the peaks at 531.8 eV (oxygen-deficient regions within the matrix of ZnO, green curve) and 532.5 eV (C-O bonds and The deconvolution of the O 1s spectra (Figure 6b) showed a negligible shift (less than 0.1 eV) of the main peak (ZnO) position (530.4 eV) due to the incorporation of 10% Ag. The main difference between the two spectra is in the left side of the spectra. Namely, the peaks at 531.8 eV (oxygen-deficient regions within the matrix of ZnO, green curve) and 532.5 eV (C-O bonds and chemisorbed atmospheric oxygen species, blue curve) are more intense for the 10% Ag sample. This variation of intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The highest binding energy peak at 532.5 eV is usually assigned to C-O bonds and chemisorbed atmospheric oxygen species [34][35][36]. Both peaks (531.8 and 532.5 eV) are more intense for the 10% Ag-doped sample (Figure 6b). This increase in intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The lower intensity peak positioned at 531.8 eV corresponds to the known values of binding energy for O 2− ions in oxygen-deficient regions within the matrix of ZnO [37] or O-C=O/C=O species bonds from adsorbed atmospheric contaminants [38]. In the Ag 3d spectra (Figure 7), two peaks were detected, fitted using a sum of Lorentzian-Gaussian (80:20) functions, with an asymmetric peak shape at positions 386.2 and 374.2 eV on the binding energy scale. The deconvoluted Ag 3d spectra for the 1% Ag-ZnO powder sample is shown in the supplementary data ( Figure S5). These peak positions are in good agreement with the well-known spin-orbit split energy values [39] of Ag 3d 5/2 and Ag 3d 3/2 doublet peaks for Ag 0 . The position and shape of these peaks indicate the presence of metallic silver in Ag-doped ZnO powder samples. chemisorbed atmospheric oxygen species, blue curve) are more intense for the 10% Ag sample. This variation of intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The highest binding energy peak at 532.5 eV is usually assigned to C-O bonds and chemisorbed atmospheric oxygen species [34][35][36]. Both peaks (531.8 and 532.5 eV) are more intense for the 10% Ag-doped sample (Figure 6b). This increase in intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The lower intensity peak positioned at 531.8 eV corresponds to the known values of binding energy for O 2− ions in oxygen-deficient regions within the matrix of ZnO [37] or O-C=O/C=O species bonds from adsorbed atmospheric contaminants [38]. In the Ag 3d spectra (Figure 7), two peaks were detected, fitted using a sum of Lorentzian-Gaussian (80:20) functions, with an asymmetric peak shape at positions 386.2 and 374.2 eV on the binding energy scale. The deconvoluted Ag 3d spectra for the 1% Ag-ZnO powder sample is shown in the supplementary data ( Figure S5). These peak positions are in good agreement with the well-known spin-orbit split energy values [39] of Ag 3d5/2 and Ag 3d3/2 doublet peaks for Ag 0 . The position and shape of these peaks indicate the presence of metallic silver in Ag-doped ZnO powder samples.   chemisorbed atmospheric oxygen species, blue curve) are more intense for the 10% Ag sample. This variation of intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The highest binding energy peak at 532.5 eV is usually assigned to C-O bonds and chemisorbed atmospheric oxygen species [34][35][36]. Both peaks (531.8 and 532.5 eV) are more intense for the 10% Ag-doped sample (Figure 6b). This increase in intensity could arise due to different amounts of adsorbed atmospheric contaminants on the sample surface. The lower intensity peak positioned at 531.8 eV corresponds to the known values of binding energy for O 2− ions in oxygen-deficient regions within the matrix of ZnO [37] or O-C=O/C=O species bonds from adsorbed atmospheric contaminants [38]. In the Ag 3d spectra (Figure 7), two peaks were detected, fitted using a sum of Lorentzian-Gaussian (80:20) functions, with an asymmetric peak shape at positions 386.2 and 374.2 eV on the binding energy scale. The deconvoluted Ag 3d spectra for the 1% Ag-ZnO powder sample is shown in the supplementary data ( Figure S5). These peak positions are in good agreement with the well-known spin-orbit split energy values [39] of Ag 3d5/2 and Ag 3d3/2 doublet peaks for Ag 0 . The position and shape of these peaks indicate the presence of metallic silver in Ag-doped ZnO powder samples.

Ag-ZnO Nanoparticles as Fluorescent Sensor for p-Nitrophenol
The stability of the synthesized Ag-doped ZnO nanostructures was studied by using a fluorescence spectrophotometer, and there was no change in the intensity and position of the peak, even after a time of 15 days. The reproducibility values of the fluorescence measurements were estimated to be ±0.1%. The as-synthesized Ag x Zn 1−x O (x = 0, 0.01, 0.05 and 0.10) samples were studied for the fluorescence sensing of p-nitrophenol (PNP). Before conducting the sensing experiments, photoluminescence (PL) spectra of pure ZnO and Ag-doped ZnO nanostructures were recorded at various excitation wavelengths in the range 330-410 nm with a regular gap of 10 nm in order to find out the excitation maxima for the nanostructures. In the PNP concentration-dependent studies, the concentration of PNP was changed gradually, while the concentrations of the nanostructures were kept constant (1.5 mg in 50 mL). The response of the PL quenching for ZnO and Ag-doped ZnO is illustrated in Figure 8.

Ag-ZnO Nanoparticles as Fluorescent Sensor for p-Nitrophenol
The stability of the synthesized Ag-doped ZnO nanostructures was studied by using a fluorescence spectrophotometer, and there was no change in the intensity and position of the peak, even after a time of 15 days. The reproducibility values of the fluorescence measurements were estimated to be ±0.1%. The as-synthesized AgxZn1-xO (x = 0, 0.01, 0.05 and 0.10) samples were studied for the fluorescence sensing of p-nitrophenol (PNP). Before conducting the sensing experiments, photoluminescence (PL) spectra of pure ZnO and Ag-doped ZnO nanostructures were recorded at various excitation wavelengths in the range 330-410 nm with a regular gap of 10 nm in order to find out the excitation maxima for the nanostructures. In the PNP concentration-dependent studies, the concentration of PNP was changed gradually, while the concentrations of the nanostructures were kept constant (1.5 mg in 50 mL). The response of the PL quenching for ZnO and Ag-doped ZnO is illustrated in Figure 8. The Stern and Volmer equation [40] initially deal with the kinetics analysis of fluorescence quenching, which has promising applications for investigating bimolecular interactions in the electronic excited state. The analysis of the fluorescence quenching processes was performed by using the Stern-Volmer equation [40]: where Io is the intensity before and after the addition of PNP, while I correspond to the intensity after the addition of PNP. Ksv and [Q] are the Stern-Volmer quenching constant and the concentration of the quencher, respectively. Figure 9 shows the variation of (Io/I)-1 vs. the concentration of the PNP The Stern and Volmer equation [40] initially deal with the kinetics analysis of fluorescence quenching, which has promising applications for investigating bimolecular interactions in the electronic excited state. The analysis of the fluorescence quenching processes was performed by using the Stern-Volmer equation [40]: where I o is the intensity before and after the addition of PNP, while I correspond to the intensity after the addition of PNP. K sv and [Q] are the Stern-Volmer quenching constant and the concentration of the quencher, respectively. Figure 9 shows the variation of (I o/ I)−1 vs. The concentration of the PNP quencher. In pure ZnO as well as Ag-doped ZnO, it was observed that the Stern-Volmer plots show exponential behavior (linear as well as non-linear) over the entire concentration range of PNP studied.
Linear behavior was observed upon increasing the concentration up to a certain level, implying the dominance of the static quenching over the dynamic quenching process; however, a further increase in concentration resulted in an exponential increase, which suggests that there exist both types of quenching, i.e., a combination of static and dynamic quenching by the same quencher [40].
quencher. In pure ZnO as well as Ag-doped ZnO, it was observed that the Stern-Volmer plots show exponential behavior (linear as well as non-linear) over the entire concentration range of PNP studied. Linear behavior was observed upon increasing the concentration up to a certain level, implying the dominance of the static quenching over the dynamic quenching process; however, a further increase in concentration resulted in an exponential increase, which suggests that there exist both types of quenching, i.e., a combination of static and dynamic quenching by the same quencher [40].   To resolve this ambiguity, on account of the non-linear response of the intensity ratio to the concentration of the analyte, a modified Stern-Volmer equation has been suggested [37,41]: Equation (3) can further be simplified as follows: where V is the static quenching constant and is obtained from Equation (4)   for the 1%, 5% and 10% Ag-doped ZnO nanostructures, respectively. The limits of detection (LODs), calculated following the 3σ IUPAC criteria, were found to be 2.17, 1.60, 1.18 and 0.66 µM for the pure ZnO and 1%, 5% and 10% Ag-doped ZnO nanostructures, respectively, which clearly indicates that the presence of Ag improved the LOD for a luminescent sensor for PNP. The sensing mechanism has been shown in Scheme 1. The PL quenching of Ag-doped ZnO can be attributed to the analytes binding on the surface of nanostructure, which traps the excited electron-by-electron transfer mechanism [42]. The LOD for PNP calculated for various samples of ZnO as well as Ag-doped ZnO is also compared with the literature ( Table 2).  [42]. The LOD for PNP calculated for various samples of ZnO as well as Ag-doped ZnO is also compared with the literature (Table 2).

Conclusions
In summary, we successfully synthesized ZnO and Ag-doped ZnO nanostructures via a solution combustion process. The synthesized ZnO and Ag-ZnO nanostructures were characterized by using various characterization techniques, which revealed the large-scale synthesis of well-crystalline nanostructures and successful incorporation of Ag ions in the ZnO matrix, showing excellent chemical sensing properties. ZnO was found to show a low value of the limit of detection, i.e., 2.175 µM/L, for p-nitrophenol sensing; moreover, a sharp decrease in the limit of detection was observed with an increase in the concentration of silver ions, and the LOD value decreased to 0.669 µM/L for the 10% silver-doped zinc oxide. It is therefore concluded that Ag-doped ZnO shows a lower limit of detection as compared to pure ZnO for p-nitrophenol sensing. We observed a decrease in the particle size with an increasing Ag ion concentration, as well as the presence of silver also decreasing the electron hole recombination rate, which led to the enhancement of the surface area and Ag also behaving as an electron scavenger. Hence, there was an increase in the chemical sensing efficiency owing to the separation of charge carriers, resulting in the restriction of their recombination. It is concluded that Ag-doped ZnO nanostructures are promising candidates for the detection of p-nitrophenol.

Conclusions
In summary, we successfully synthesized ZnO and Ag-doped ZnO nanostructures via a solution combustion process. The synthesized ZnO and Ag-ZnO nanostructures were characterized by using various characterization techniques, which revealed the large-scale synthesis of well-crystalline nanostructures and successful incorporation of Ag ions in the ZnO matrix, showing excellent chemical sensing properties. ZnO was found to show a low value of the limit of detection, i.e., 2.175 µM/L, for p-nitrophenol sensing; moreover, a sharp decrease in the limit of detection was observed with an increase in the concentration of silver ions, and the LOD value decreased to 0.669 µM/L for the 10% silver-doped zinc oxide. It is therefore concluded that Ag-doped ZnO shows a lower limit of detection as compared to pure ZnO for p-nitrophenol sensing. We observed a decrease in the particle size with an increasing Ag ion concentration, as well as the presence of silver also decreasing the electron hole recombination rate, which led to the enhancement of the surface area and Ag also behaving as an electron scavenger. Hence, there was an increase in the chemical sensing efficiency owing to the separation of charge carriers, resulting in the restriction of their recombination. It is concluded that Ag-doped ZnO nanostructures are promising candidates for the detection of p-nitrophenol.

Conflicts of Interest:
The authors declare no conflict of interest.