Mathematical Modeling and Simulation of a Gas Emission Source Using the Network Simulation Method

: A mathematical model for the simulation of the di ﬀ usion of the pollutants released from a point source is presented. All phenomena have been included, such as thermal and wind gradients, turbulence, fumigation, convective and di ﬀ usive e ﬀ ects, and atmospheric stabilities. To better understand the dynamics of these occurrences, the Network Simulation Method was used to provide the concentration of pollutants in three spatial coordinates. The model was simulated in open source software and validated with experimental data, satisfying the Hanna criteria. Additionally, this model selects for the appropriate expressions based on the physical phenomena that govern each case and allows for time-dependent data entry. The cases studied show the great coupling that exists between the variables of wind velocity and atmospheric stability for the pollutant di ﬀ usion. The model can be used for two important aims, to identify the behavior of the emission of pollutants, and to determine the concentration of a pollutant at various points, through an inverse problem, locating the source of the emission.


Introduction
Air pollution is understood as the existence of potentially harmful matter suspended in the air, which can be classified into basic chemical compounds (oxides of sulfur or nitrogen, carbon monoxide), particulate matter, high-risk radioactive compounds, or suspensions from a biological source, such as bacteria. All of which can produce harmful effects on the health of a population.
In all cases, the atmospheric dispersion of pollutants is essentially dependent on the air flow or wind velocity in the lower layers of the atmosphere. This dispersion represents an important environmental engineering problem in relation to the health of a population, particularly in areas where different pollution sources can be unhealthy and/or dangerous [1,2]. In city centers where the building density is high, emissions from chimneys accumulate in the open spaces between buildings due to the higher velocity of air flow and its turbulent nature in comparison with the open spaces.
For years, the main objective was to monitor the concentration of pollutants at each point in space and at each moment as a result of the dispersion caused by the movement of the atmospheric air in which the pollutants are suspended. The modeling of the atmospheric dispersion of pollutants elicits the mathematical and/or numerical study of these processes, seeking analytical or semi-analytical solutions that present increasingly accurate results.
The movement of pollutants released from a source involves numerous phenomena, such as turbulence, wind dragging, buoyancy forces, diffusive effects, etc. The governing equation that encompasses them is given by the following expression [12,[22][23][24]: where c p is the pollutant concentration in (µg/m 3 ), u x , u y , and u z are the wind velocities in the different space directions, x, y, and z, respectively, K x , K y , and K z are the diffusivity parameters in the different directions of space, R c (µg/m 3 s) is the term of reaction or decay due to physicochemical reactions in the atmosphere that depend on each pollutant [25], and Q p (µg/m 3 s) is the term that implements the source or sink of the pollutant. This last variable represents the emission of the polluting gas, and can be a continuous emission and take a constant value over time; it can be a quick release, that is, of a short period of time; it can be an instantaneous emission; or it can be variable as a function of time. Illustratively, Figure 1 is a schematic representation of the model showing the diffusion of the pollutant emitted by a point source in the direction of the wind, whose behavior is defined by Equation (1). Being an unbound medium, it is represented by a space large enough so that the pollutant diffusion does not reach the boundary. The different processes involved, as well as the boundary conditions, will be described in the next sections. Illustratively, Figure 1 is a schematic representation of the model showing the diffusion of the pollutant emitted by a point source in the direction of the wind, whose behavior is defined by Equation (1). Being an unbound medium, it is represented by a space large enough so that the pollutant diffusion does not reach the boundary. The different processes involved, as well as the boundary conditions, will be described in the next sections.

Atmospheric Stability
Stability conditions (which can be classified as neutral, stable or subadibatic, and unstable or superadibatic) define the atmospheric parameters. In neutral conditions, the buoyancy forces can be considered negligible while the drag forces of the wind on the earth's surface, together with the effects derived from the change of direction and wind velocity with height, are the cause of turbulent energy transport. In unstable conditions, the buoyancy forces induced by heat flows are added to the above. Stable conditions occur at night, where the surface cools more than the air itself. Given the limitation of the division of stability into three groups, Pasquill [22] established a subdivision into atmospheric stability categories, whose relationship with stability is shown in the following table (Table 1): Table 1. Relationship between stability and the category of atmospheric stability [22].

Stability
Pasquill's Stability Categories Unstable (UB) A, B, and C Neutral (NL) D Stable (SB) E, F, and G The category of atmospheric stability is a function of different parameters, among which insolation, wind velocity, and cloudiness stand out (Table 2) [22]. Wind velocity is usually measured at a reference height, vref, typically 10 m (zref), cloudiness is expressed as a percentage, and finally, insolation is a function of solar radiation and is established according to the following table (Table 3).

Atmospheric Stability
Stability conditions (which can be classified as neutral, stable or subadibatic, and unstable or superadibatic) define the atmospheric parameters. In neutral conditions, the buoyancy forces can be considered negligible while the drag forces of the wind on the earth's surface, together with the effects derived from the change of direction and wind velocity with height, are the cause of turbulent energy transport. In unstable conditions, the buoyancy forces induced by heat flows are added to the above. Stable conditions occur at night, where the surface cools more than the air itself. Given the limitation of the division of stability into three groups, Pasquill [22] established a subdivision into atmospheric stability categories, whose relationship with stability is shown in the following table (Table 1): Table 1. Relationship between stability and the category of atmospheric stability [22].

Stability Pasquill's Stability Categories
Unstable (UB) A, B, and C Neutral (NL) D Stable (SB) E, F, and G The category of atmospheric stability is a function of different parameters, among which insolation, wind velocity, and cloudiness stand out (Table 2) [22]. Wind velocity is usually measured at a reference height, v ref , typically 10 m (z ref ), cloudiness is expressed as a percentage, and finally, insolation is a function of solar radiation and is established according to the following table (Table 3).  Table 3. Relationship between solar radiation and insolation [26].

Solar Radiation (W/m 2 ) Insolation
>500 Strong 300-500 Moderate <300 Slight It is the solar radiation itself that establishes whether it is day or night. Thus, Table 2 can be expressed in terms of the three groups of stabilities: unstable, neutral, and stable (Table 4).

Vertical Heat Flux
This flux, H (W/m 2 ), is obtained from the energy balance in the ground-the energy received from outside minus the energy emitted. The phenomenon is depreciable for neutral conditions, but it is significant for other conditions. The importance of this flux lies in the effect it has on turbulence through buoyancy effects. Some authors, such as Holtslag and van Ulden [27], considered the fraction of heat absorbed by the water that is invested in evaporation without changing the ground temperature, a phenomenon that, in turn, conditions the temperature of the outside air. Other authors, such as Clarke, established it through the following expression [28].
where R solar is the incoming solar radiation (W/m 2 ). The importance of parameter H lies in its influence on turbulence, since if H > 0, the received energy is higher than that emitted (heating of the ground) and the atmosphere is superadibatic; if H ≤ 0, it is subadibatic (cooling of the ground); and finally, if H ≈ 0, it is a neutral atmosphere.

Wind Profiles
At levels close to the surface, the wind velocity is influenced by the effects of friction to a greater or lesser degree, being greater during the day, since these effects are determined by the topography and surface roughness (distribution and average height of the obstacles). The gradient decrease with height, showing a greater fall during the day. Thus, according to the American Society of Mechanical Engineers (ASME) [29], the velocity profiles have the shape indicated in Figure 2. The slope of these curves represents the inverse of the velocity gradient with height. By increasing the size of the obstacles, the velocities increase more slowly with the height.

Wind Profiles
At levels close to the surface, the wind velocity is influenced by the effects of friction to a greater or lesser degree, being greater during the day, since these effects are determined by the topography and surface roughness (distribution and average height of the obstacles). The gradient decrease with height, showing a greater fall during the day. Thus, according to the American Society of Mechanical Engineers (ASME) [29], the velocity profiles have the shape indicated in Figure 2. The slope of these curves represents the inverse of the velocity gradient with height. By increasing the size of the obstacles, the velocities increase more slowly with the height. As can be seen in Figure 2, there is turbulence of a mechanical origin associated with the horizontal components of the wind velocity, which is represented by the so-called friction velocity v * . As v * increases, so does the turbulence and the intensity with which the wind components mix.
Thus, in order to use the law of the wall = * , we need to determine or, what is the same, the velocity profile (vz) as a function of the height (z) [22]. The constant k was determined by von Karman [30][31][32] and takes a value of 0.35. The velocity profile gives us the magnitude of the velocity at each height (vz), which can be decomposed into its x and y components (ux and uy) through the wind angle with respect to the problem coordinate system, as seen in Figure 3. Regarding the vertical velocity of the wind, uz, it is assumed to be practically zero [12,22]. As can be seen in Figure 2, there is turbulence of a mechanical origin associated with the horizontal components of the wind velocity, which is represented by the so-called friction velocity v * . As v * increases, so does the turbulence and the intensity with which the wind components mix. Thus, in order to use the law of the wall ∂v ∂z = v * kz , we need to determine ∂v ∂z or, what is the same, the velocity profile (v z ) as a function of the height (z) [22]. The constant k was determined by von Karman [30][31][32] and takes a value of 0.35. The velocity profile gives us the magnitude of the velocity at each height (v z ), which can be decomposed into its x and y components (u x and u y ) through the wind angle with respect to the problem coordinate system, as seen in Figure 3. Regarding the vertical velocity of the wind, u z , it is assumed to be practically zero [12,22]. To determine the velocity profile, the modified logarithmic or potential approximation can be used. The first one takes into account the predominant floating effects, introducing a Monin-Obukhov length (L) and a dimensionless length (z/L) known as the Monin-Obukhov parameter [33]. In this way, the law of the wall is modified as follows where ϕM is a turbulent exchange coefficient due to mass. In this way, the wind profiles are based on atmospheric stabilities [31]. Thus, for neutral conditions, α1 and α2 take null values, 4.7 and 1, respectively, for stable conditions, and finally, −15 and −0.25, respectively, for unstable conditions [31]. Other authors, such as Dyer and Hicks [34] and Webb [35], have also adjusted these values. When solving the integral, the integration constant (zo) appears, which is called the roughness length. On aerodynamically rough surfaces, the velocity profiles are basically dependent on the roughness length, that is, on the distribution and height of rough elements (obstacles). This length takes different values depending on the terrain, such as in open spaces, forests, cities, and so on [22]. Thus, the solution for each of the atmospheric stabilities is given by the following: The potential approximation for the velocity profile is given by the following expression where the p-index is a parameter that depends on the Pasquill atmospheric stability category (Table  5) [5]. To determine the velocity profile, the modified logarithmic or potential approximation can be used. The first one takes into account the predominant floating effects, introducing a Monin-Obukhov length (L) and a dimensionless length (z/L) known as the Monin-Obukhov parameter [33]. In this way, the law of the wall is modified as follows where φ M is a turbulent exchange coefficient due to mass. In this way, the wind profiles are based on atmospheric stabilities [31]. Thus, for neutral conditions, α 1 and α 2 take null values, 4.7 and 1, respectively, for stable conditions, and finally, −15 and −0.25, respectively, for unstable conditions [31].
Other authors, such as Dyer and Hicks [34] and Webb [35], have also adjusted these values. When solving the integral, the integration constant (z o ) appears, which is called the roughness length. On aerodynamically rough surfaces, the velocity profiles are basically dependent on the roughness length, that is, on the distribution and height of rough elements (obstacles). This length takes different values depending on the terrain, such as in open spaces, forests, cities, and so on [22]. Thus, the solution for each of the atmospheric stabilities is given by the following: The potential approximation for the velocity profile is given by the following expression where the p-index is a parameter that depends on the Pasquill atmospheric stability category (Table 5) [5].

Monin-Obukhov Length
This parameter, which includes all the parameters that influence the mechanical phenomena that occur in air, is used to determine the stability, and is considered as a measure (m) of the thickness of the layer of mechanical mixing close to the surface [33,36]. This length is given by: where c h,a is the heat capacity of air and takes a value 1012 J/kgK, T r is the air temperature (K), g is the acceleration of gravity, and ρ a , is the air density (kg/m 3 ). The Monin-Obukhov length takes positive values for a stable stability, negative values for an unstable one, and infinite for a neutral one.

Air Density
Jones [37] recommends expression (9) for the calculation of air density and for use in standards laboratories. Thereby, the air density depends on the relative humidity (RH), on the ambient temperature (T a ), and on the atmospheric pressure at ground level (P 0 ).

Air Temperature Profile
There is also turbulence of a thermal origin, due to the vertical movements of the air caused by thermal gradients and to which atmospheric stability is traditionally associated. Mechanical and thermal turbulence occur simultaneously, contributing to the genesis and intensity of the global atmospheric turbulence. Given the turbulence of a thermal origin, air rises toward regions of lower pressure where it expands and cools. Under adiabatic or neutral conditions, the decrease rate in the dry air temperature with the height (dT/dz), one of the main constants in meteorology that is taken as a reference for real cases (not adiabatic), has the value dT/dz ≈ 0.01 • C/m or 1 • C/100 m [38,39]. The potential temperature of dry air (θ) is defined as that reached by an infinitesimal air volume when it is transported adiabatically from its pressure (P z ) to a reference pressure (surface pressure the earth, P 0 ). Its value, from the adiabatic relation T-P z , is where P z (Pa) is the atmospheric pressure at different heights and γ is the adiabatic coefficient of air with a value of 1.4. From this expression, it can be deduced that, at ground level, the ambient temperature and the potential temperature take the same value. The pressure is related to temperature through the following relation P z = ρ a R g T where R g is the ideal gas constant. Finally, the potential temperature profile is a function of stability and is given by the following expression [22] Mathematics 2020, 8,1996 8 of 18 where φ H is a turbulent exchange coefficient due to heat [12]. In this way, the temperature profiles are a function of atmospheric stabilities [31]. Thus, for neutral and stable conditions, α 3 , α 4, and α 5 take 0.74, 4.7, and 1, respectively, and for unstable conditions, 1.83, −16.44, and −0.5, respectively [31]. Again, when performing the integral, the integration constant (z o ) appears, which is called the roughness length.

Eddy Diffusivities
The horizontal diffusion coefficients, K H , and vertical, K V , (K x = K y = K H and K z = K V ), known as Eddy diffusivities, express the mechanical turbulent diffusivity. First, we will consider the vertical diffusivity as it is the most complex. For this case, a theory modified by dimensional arguments and stability considerations is applied that implies the convective boundary layer [2,12,40,41]. For this layer, the two main variables that control turbulence are the convective boundary layer depth, z c , and the convective velocity scale, w * . Another important length for the calculation of diffusivities is the boundary layer height, H b . The vertical transport of polluting material is dominated by turbulent diffusion under convective conditions that depends on different atmospheric conditions [12,22,40]. Thus, for stable conditions: where b is a constant with a value of 0.91, and f is the force or parameter of Coriolis (f = 2ωsenφ ≈ 1.15 × 10 −4 s −1 , where φ is the latitude and ω is the Earth angular velocity) [12,22]. For neutral conditions, where F is a factor that varies between 0.25 and 1 and whose recommended value is 0.455 [12,22,40]. Finally, for unstable conditions [12,22,40,42], Under unstable conditions, the convective boundary layer depth, z c , is the maximum value between two values [42].
h 2 is the lowest value where dθ dz takes a positive value.
Finally, for the case of horizontal diffusivity, K H , the variation produces negligible changes in the concentration distribution, and so it is assigned a constant value of 50 m 2 /s [12,43,44].

Boundary Conditions
Except for the boundary condition on the ground, a first-class condition (Dirichlet type) is applied to the entire boundary as, with this, the imperviousness of pollutants is also ensured. A medium large enough value is taken so that it can be assumed as infinity. For the surface (z = 0), the boundary condition is of the greatest interest due to its location of the deposition of pollutants. In this case, a second-class non-homogeneous condition (Neumann type) is applied, governed by the equation where v dep is the deposition velocity that takes values in a range between 0.0004 and 0.075 m/s. For this work, a value of 0.02 m/s was taken [12].

The Network Model
The procedure to design a network model is described in Sánchez-Pérez et al. [17,45] and González-Fernández and Alhama [20]. To obtain a clearer design interpretation, the design will be described below. Firstly, the equivalence between the variable and the electric voltage, c p ≡ V is established. Then, each of the distance variables, x, y, and z, are discretized in different volume elements. Applying the nomenclature in Figure 4, Equation (1) provides the following finite difference, Equation (26).
where the subscripts l, w, and h are the space coordinates. To develop Equation (26), we considered that the wind speed practically does not vary with respect to the x and y coordinates and takes a null value in the z direction. The K H variable will also take a constant value.
h is the lowest value where dθ dz takes a positive value.
Finally, for the case of horizontal diffusivity, KH, the variation produces negligible changes in the concentration distribution, and so it is assigned a constant value of 50 m 2 /s [12,43,44].

Boundary Conditions
Except for the boundary condition on the ground, a first-class condition (Dirichlet type) is applied to the entire boundary as, with this, the imperviousness of pollutants is also ensured. A medium large enough value is taken so that it can be assumed as infinity. For the surface (z = 0), the boundary condition is of the greatest interest due to its location of the deposition of pollutants. In this case, a second-class non-homogeneous condition (Neumann type) is applied, governed by the equation where vdep is the deposition velocity that takes values in a range between 0.0004 and 0.075 m/s. For this work, a value of 0.02 m/s was taken [12].

The Network Model
The procedure to design a network model is described in Sánchez-Pérez et al. [17,45] and González-Fernández and Alhama [20]. To obtain a clearer design interpretation, the design will be described below. Firstly, the equivalence between the variable and the electric voltage, cp ≡ V is established. Then, each of the distance variables, x, y, and z, are discretized in different volume elements. Applying the nomenclature in Figure 4, Equation (1) provides the following finite difference, Equation (26).  Following the scheme of Figure 5, each addend of Equation (26) is an electric current that is balanced at a central node. The fourth, fifth, and sixth addends, that is, the second derivatives, are implemented as simple resistors, R x , R y , and R z , for each of the spatial coordinates, respectively, where R x = ∆x 2 2K H , R y = ∆y 2 2K H , and R z = ∆z 2 2K v , and the time derivative are implemented as a capacitor (C r,i,j,k ). R = ∆ , R = ∆ , and R = ∆ , and the time derivative are implemented as a capacitor (Cr,i,j,k).
The rest of the addends are implemented as controlled current sources; however, the last two terms connect from earth to the central node and the terms that imply movement in one direction, wind velocity or diffusivity, connect from one end of the cell to the other, since they imply a direction and a sense. Thus, the terms of a chemical reaction and source or sink of pollutants are given by I R c = R c G R c and I Q = Q G Q , respectively. The terms of velocity and diffusivity are given by I =  The rest of the expressions are implemented as controlled voltage sources that allow the inclusion of conditioning factors and variable values. These sources, depending on each scenario, choose between the values assigned to Tables 1-4 and select the values for expressions (4) to (7) and (12). Furthermore, they use the appropriate expression between (13), (15), and (17) to (20) for each The rest of the addends are implemented as controlled current sources; however, the last two terms connect from earth to the central node and the terms that imply movement in one direction, wind velocity or diffusivity, connect from one end of the cell to the other, since they imply a direction and a sense. Thus, the terms of a chemical reaction and source or sink of pollutants are given by I R c = R c G R c and I Q = Q G Q , respectively. The terms of velocity and diffusivity are given by The rest of the expressions are implemented as controlled voltage sources that allow the inclusion of conditioning factors and variable values. These sources, depending on each scenario, choose between the values assigned to Tables 1-4 and select the values for expressions (4) to (7) and (12). Furthermore, they use the appropriate expression between (13), (15), and (17) to (20) for each case or determine the convective boundary layer depth by implementing a conditional code in the source. By allowing these sources to change the values, we can introduce different values that change with time, such as solar radiation, wind velocity, and temperature at the reference height, etc., through expressions or fixed values for a certain time. Finally, the release source and the physical-chemical reactions are implemented as controlled current sources.
The boundary conditions are implemented as very high value resistors, except for that of the ground, which uses a controlled current source for its implementation. Being an unbounded medium, the meshing must be sufficiently extensive so that the boundary does not influence the concentrations in the positions where we want to know them. As a criterion to choose a suitable mesh, the one where the concentrations in the boundary are practically zero is taken. Finally, to simulate the model, a circuit simulation software, such as NgSpice is used [14,46].

Validation and Results
To validate the model, we compared it with the experimental results obtained from the literature. Ma et al. [47] used, in their experimental tests, a gaseous pollutant whose density was similar to that of ambient air, so as to not be affected by gravity. These contaminants are known as neutrally-buoyant pollutants [47,48]. In addition, the pollutant does not transform into another compound, so there are no physicochemical reactions. Due to the significant number of variables that must be measured and that also influence the concentration measurement (variable wind velocity and direction, temperature, etc.), the experimental values are not exempt from error. This methodology, derived from the Prairie Grass experimental data, was used to verify and optimize the different emission methods [47,49]. Thus, Table 6 shows the input data of the problem [47]. Ma et al. [47] indicated in their article that they used a point source of continuous emission. Therefore, in the simulation, we adjusted the time following the criteria given by Hanna [39,47,48]. The simulation presents a scenario composed of a volume of 12,000 × 2500 × 100 m using a fine mesh of 2000 × 800 × 5 m close to the emission source. Figures 6-10 show the results of the simulation. Figures 6 and 7 are 3D representations with concentrations and two spatial coordinates. Thus, Figure 6 shows the concentration distribution at 0.50 m of height for a section of 12,000 for the x-coordinate and 2500 m for the y-coordinate. As can be seen, the concentration falls rapidly to very low values in the first 1000 m. Figure 7 shows the distribution in the y and z coordinates, setting x to a value of 50 m. This figure shows that the concentration starting from 40 m decays rapidly. For both figures, the concentration distribution on the y axis is symmetric with respect to the emission source. The rest of the figures are representations of the concentrations against a spatial coordinate. Figure 8 shows the concentration distribution on the x-axis in the wind direction with the same coordinates as the source for x and y. This figure has been used for the validation of the methodology used according to the criteria given by Hanna [39]. Figure 9 illustrates the concentration distribution on the x-axis in the direction of the wind at the same height and at 100 m from the emission source at the y-coordinate. Finally, Figure 10 shows a cross section to the wind direction at 100 m in the x-coordinate and at the same height as the emission source. These last two figures are the ones that best allow us to observe the behavior of the concentration distribution, particularly the one represented in the wind direction.
Finally, Table 7 shows the comparison of the results between those obtained by simulation and the experimental values including the ratio or degree of prediction. These values present a ratio that meets the factor of two of the observed values, satisfying the criterion of Hanna to evaluate a model as satisfactory [39,50]. The closer the ratio is to the unit, the better the prediction. The worst prediction occurred at 200 m, possibly because the measurement was wrong due to an experimental error, even though the value meets Hanna's criteria [39]. though the value meets Hanna's criteria [39].          Next, we studied different boundary conditions, both for the wind velocity and for the atmospheric Pasquill's stability categories. First, Case 2 shows a day with moderate insolation and a very low wind velocity; however, for Case 3, it occurs at night with a high wind velocity (Table 8). In   Next, we studied different boundary conditions, both for the wind velocity and for the atmospheric Pasquill's stability categories. First, Case 2 shows a day with moderate insolation and a very low wind velocity; however, for Case 3, it occurs at night with a high wind velocity (Table 8). In both Cases, the emission is continuous. Finally, Case 4 represents an instantaneous emission of one  Next, we studied different boundary conditions, both for the wind velocity and for the atmospheric Pasquill's stability categories. First, Case 2 shows a day with moderate insolation and a very low wind velocity; however, for Case 3, it occurs at night with a high wind velocity (Table 8). In both Cases, the emission is continuous. Finally, Case 4 represents an instantaneous emission of one minute where half the mass that is released in Case 1 per minute is released. The first case studied (Case 1), which was used for the validation of the model, corresponds to a light breeze with a moderately stable stability category that can produce a fumigation effect [22,51]. As shown in Figure 7, this effect produced a higher concentration than in the rest of the cases studied. The second case (Case 2) corresponds to a practically calm wind with a moderately unstable stability category that produces a dispersion of the pollutant known as "looping", favoring convection phenomena [22,51]. For the height studied, this effect decreased the concentration with respect to the previous case ( Figure 11). Finally, Case 3 corresponds to a wind that raises dust or shakes small trees with a neutral stability category that produces a "coning" type dispersion [22,51]. This combination makes the concentration even lower for the position studied than in the previous cases ( Figure 12). The first case studied (Case 1), which was used for the validation of the model, corresponds to a light breeze with a moderately stable stability category that can produce a fumigation effect [22,51]. As shown in Figure 7, this effect produced a higher concentration than in the rest of the cases studied. The second case (Case 2) corresponds to a practically calm wind with a moderately unstable stability category that produces a dispersion of the pollutant known as "looping", favoring convection phenomena [22,51]. For the height studied, this effect decreased the concentration with respect to the previous case ( Figure 11). Finally, Case 3 corresponds to a wind that raises dust or shakes small trees with a neutral stability category that produces a "coning" type dispersion [22,51]. This combination makes the concentration even lower for the position studied than in the previous cases ( Figure 12). Case 2 would be expected to present a higher concentration near the source as it has a lower wind velocity. However, the possible combination of the fumigation effect of stable conditions and the convective phenomena of its stability make its concentration lower than in Case 1. Finally, if cases 1 and 4 are compared, at positions close to the emission source, approximately half the concentration is obtained in Case 4 ( Figure 13) when compared with Case 1 (Figure 8). In more distant positions, the concentration decreased more rapidly in the instantaneous case, possibly by the amount of mass emitted and the release time. Clearly, with increasing time, the concentration of Case 4 decreased as this was an instantaneous emission.

Conclusions
This work presents a mathematical model of the diffusion of pollutants emitted from a point source, based on current bibliographies, which encompasses phenomena, such as turbulence, buoyancy forces, drag forces, thermal gradients, and diffusive effects. This model was solved using a numerical model, built using the Network Simulation Method, without linearization of the equations or making assumptions. All the conditioning factors of the mathematical model were implemented, allowing for the choice between the most appropriate equations at all times. In addition, this allows the input values to be variable over time, such as the velocity and direction of the wind, temperature, and atmospheric pressure.  Case 2 would be expected to present a higher concentration near the source as it has a lower wind velocity. However, the possible combination of the fumigation effect of stable conditions and the convective phenomena of its stability make its concentration lower than in Case 1. Finally, if cases 1 and 4 are compared, at positions close to the emission source, approximately half the concentration is obtained in Case 4 ( Figure 13) when compared with Case 1 (Figure 8). In more distant positions, the concentration decreased more rapidly in the instantaneous case, possibly by the amount of mass emitted and the release time. Clearly, with increasing time, the concentration of Case 4 decreased as this was an instantaneous emission.

Conclusions
This work presents a mathematical model of the diffusion of pollutants emitted from a point source, based on current bibliographies, which encompasses phenomena, such as turbulence, buoyancy forces, drag forces, thermal gradients, and diffusive effects. This model was solved using a numerical model, built using the Network Simulation Method, without linearization of the equations or making assumptions. All the conditioning factors of the mathematical model were implemented, allowing for the choice between the most appropriate equations at all times. In addition, this allows the input values to be variable over time, such as the velocity and direction of the wind, temperature, and atmospheric pressure. The proposed model allows the introduction of pollutant emissions as a function of time, including both instantaneous and continuous emissions

Conclusions
This work presents a mathematical model of the diffusion of pollutants emitted from a point source, based on current bibliographies, which encompasses phenomena, such as turbulence, buoyancy forces, drag forces, thermal gradients, and diffusive effects. This model was solved using a numerical model, built using the Network Simulation Method, without linearization of the equations or making assumptions. All the conditioning factors of the mathematical model were implemented, allowing for the choice between the most appropriate equations at all times. In addition, this allows the input values to be variable over time, such as the velocity and direction of the wind, temperature, and atmospheric pressure. The proposed model allows the introduction of pollutant emissions as a function of time, including both instantaneous and continuous emissions with a constant emission value. The model, which was validated with experimental data, meets the criterion of Hanna to evaluate a model as satisfactory. The results obtained from the simulation allow for the attainment of the concentration in a three-dimensional space of a pollutant that has been released by a point source. This model also allows for the representation of the concentration in one or two spatial coordinates, which facilitates understanding of the behavior of the pollutant.
The cases studied demonstrated the great influence that wind velocity and atmospheric stability have on the dispersion of a pollutant, since, a priori, it could be expected that the lower the wind velocity, the greater the concentration near the source of emission. However, the convective phenomena for unstable stability or the possible fumigation effect for stable conditions can make the concentration lower.
The use of precise models in the diffusion of pollutants has two important applications, the first to know, a priori, the behavior of the emission of pollutants, and the second, to know the concentration of a pollutant at various points, through an inverse problem, locating the emission source.