Environmental and Social Pressures in Mining. Results from a Sustainability Hotspots Screening

In recent years, increased interest and actions have been taken to better understand, and mitigate, sustainability impacts of mining activities, by both industry and policy. The present work reports on a sustainability hotspots screening performed for the EU Horizon 2020 “Integrated Mineral Technologies for More Sustainable Raw Material Supply” (ITERAMS) project, which foresees a more efficient water recycling, tailings valorization, and minimization of environmental footprint. The focus of this paper is on social and environmental issues in mining. Different methodologies were explored, starting from a qualitative causal loop modelling. Afterwards, an environmental and social LCA screening was performed using well-accepted databases and methods, thus completing results with a literature research. The main findings related to the importance of the supply chain, the vulnerability of local communities, and the toxic emissions from tailings offer a starting point to reflect on the specific social, socio-economic, and environmental context which may influence these issues. A better understanding of the environmental and social pressures associated with mining is not only crucial to orient the sustainability assessment foreseen for the ITERAMS project, but also to contribute in terms of methodology to the challenges tackled by policy and research worldwide towards a more sustainable mining.


Mining and the Sustainable Development Goals
A mining activity is defined as "the process of extracting metallic, non-metallic mineral or industrial rock deposits from the Earth" [1]. As reported by the North American Industry Classification System (NAICS), it is often the case that "the term mining is used in the broad sense to include quarrying, well operations, beneficiating (e.g., crushing, screening, washing, and flotation), and other preparation customarily performed at the mine site, or as a part of mining activity" [2]. A number of social and environmental risks and impacts may be generated by these activities, hence preventing the sector and, at a broader level, our societies from a sustainable development, often quoted as the "development that meets the needs of the present, without compromising the ability of future generations to meet their own needs" [3].
In recent years, the mining industry has acknowledged its potential and duty to monitor and assess the sustainability of the raw materials sector, which is referred to the "key enablers of many critical sectors of the economy" [4], including for instance metals, minerals, and biotic materials. A number of programs and initiatives have been undertaken by the industry to take action on those issues that the mining activities have contributed to create or exacerbate. These issues include health problems, water and air pollution, environmental degradation, and restricted access to material • Efficient water recycling, through a reduction in water consumption up to more than 90%, improved water quality, efficient water treatment, and recovery of valuable elements from process water. • Tailings valorization, with the creation of geopolymers to be used as backfill material and tailings cover, or simply sold as products. Furthermore, the rest of the tailings is planned to be deposited as a filter dry cake. • Minimization of the environmental footprint, by reducing emissions to the environment, freshwater intake, and the risk of dam accidents.
The combined solutions proposed by ITERAMS are planned to be implemented and validated in three sites, the Kevitsa nickel copper mine in Finland, the Neves-Corvo copper zinc mine in Portugal, and an unspecified platinum mine in South Africa.
The identification and quantification of environmental and social pressures in mining have as a firm basis the definition of a multifaceted approach to capture, at first, issues in the sector at a broader level and, secondly, to characterize these topics for the context of the sites under study. The intention of this work is to present how different challenges related to social and environmental impacts of mining activities have been addressed for the preliminary sustainability hotspots identification in the ITERAMS project. The paper shows how the methodologies explored can help to achieve a better understanding of mining issues; indeed, comprehension is the first essential step towards the improvement of mining sustainability and the related achievement of social equity and environmental responsibility, as highly promoted by the SDGs and European policies and initiatives.

Qualitative Modelling Approach
A causal loop diagram (CLD) is an established modeling technique to sketch topics, states, influencing variables, and relations between them, in a graphical way, for any given subject, with by intention low formal overhead and boundaries. Drafting a causal loop diagram (CLD) may be useful in the early phase of a project to better define the system under study, hence identifying the main variables and how they influence and trigger each other. Often, CLDs allow a deeper understanding of the system under study, such as the identification of reinforcing variables, positive or negative feedback loops, or also trade-offs, which often may not be evident at first sight even to domain experts. This becomes important when tackling sustainability because environmental and social impacts may be not only complementary and overlapping, but actually contradictory.
The definition of qualitative cause-effect relationships among the different elements, variables, risks, and impacts of the ITERAMS project was the first operation performed for the hotspots screening, thus resulting in a CLD created in the Vensim software [33]. The intention was to obtain an overview on the issues to be further addressed by the Life Cycle Assessment (LCA) screening and complemented by literature research. Furthermore, attention was focused on those topics which are more difficult to evaluate with LCA, but equally important when interpreting the sustainability hotspots, such as qualitative social aspects and risks. In addition, the CLD shows few reasonings on Life Cycle Costing (LCC) impacts together with social and environmental ones. Although costs are not the focus of this paper, they are reported in the full diagram displayed in Section 3.1 "Results from the Qualitative CLD" not to extrapolate an incomplete picture from the original comprehensive model.
The CLD is referred to mine operation, hence excluding mine installation and closure and exploring the influence of water and tailings treatment technologies on mining.
Specifically, the different elements in the diagram can be described as following: • Variables: external measures and requirements that have an influence on ore mining and processing. This includes, for instance, water quality (see Figure 1a) and security prescriptions, which affect, respectively, the water cleaning effort and the workers' safety. • External conditions: the mining activity often depends on a number of external situations linked with the area where the site is located, such as hydrological and geological variables, Figure 1b. They may deeply affect the efficiency and the impacts of the operations; on the other side, it might be very difficult to influence the action of those external conditions. • State boxes: elements of the mining and processing operations, which are influenced by the external variables and conditions, consequently exercising a pressure on the environmental and social dimensions. See Figure 2a. • Arrows: they are crucial to define the cause-effect relations in the diagram. A blue arrow from "a" to "b" and a "+" sign indicate that "if "a" increases, then "b" increases"; a green arrow from "a" to "b" and a "-" sign indicate that "if "a" increases, then "b" decreases". For instance, Figure 2b shows that if dry tailings protection increases, tailings leaking may be reduced; on the other side, if tailings leaking occurs, the effort spent on leaking treatment increases. • Inputs: they are elementary and product flows used by processes related to ore mining and processing. These inputs include any energy and consumable, water, and land use, as displayed in Figure 3. • Risks, occurring in different stages of ore mining and processing, see Figure 4a. They can be reduced by mitigation measures or the implementation of specific new technologies.
• Impacts: pressures on the environment or societal stakeholders, Figure 4b. They can be either positive or negative. They include, for instance, impacts on local communities, workers, ecosystems, and resources.
from the Qualitative CLD" not to extrapolate an incomplete picture from the original comprehensive model. The CLD is referred to mine operation, hence excluding mine installation and closure and exploring the influence of water and tailings treatment technologies on mining.
Specifically, the different elements in the diagram can be described as following:  Variables: external measures and requirements that have an influence on ore mining and processing. This includes, for instance, water quality (see Figure 1a) and security prescriptions, which affect, respectively, the water cleaning effort and the workers' safety.  External conditions: the mining activity often depends on a number of external situations linked with the area where the site is located, such as hydrological and geological variables, Figure 1b. They may deeply affect the efficiency and the impacts of the operations; on the other side, it might be very difficult to influence the action of those external conditions. Arrows: they are crucial to define the cause-effect relations in the diagram. A blue arrow from "a" to "b" and a "+" sign indicate that "if "a" increases, then "b" increases"; a green arrow from "a" to "b" and a "-" sign indicate that "if "a" increases, then "b" decreases". For instance, Figure  2b shows that if dry tailings protection increases, tailings leaking may be reduced; on the other side, if tailings leaking occurs, the effort spent on leaking treatment increases.
(a) (b) Figure 2. Elements in the CLD for the ITERAMS project (a) Example of state box: waste water output; (b) Example of relations described via arrows: tailings leaking.
 Inputs: they are elementary and product flows used by processes related to ore mining and processing. These inputs include any energy and consumable, water, and land use, as displayed in Figure 3.  Risks, occurring in different stages of ore mining and processing, see Figure 4a. They can be reduced by mitigation measures or the implementation of specific new technologies.  Impacts: pressures on the environment or societal stakeholders, Figure 4b. They can be either positive or negative. They include, for instance, impacts on local communities, workers, ecosystems, and resources.  The full CLD diagram is displayed in Figure 5 in Section 3.1 "Results from the Qualitative CLD".

LCA Screening Approach
Beside a qualitative causal loop diagram, the LCA methodology was identified as the main approach to be used for the hotspots screening. LCA is a well-established and internationally recognized technique to assess potential positive and negative impacts occurring across the life cycle of a product or service. Hence, this scientific approach was applied both to the environmental (ELCA) and social (SLCA) dimensions. The already mentioned CLD was a crucial input to the LCA screening, further complemented with literature research [9,[20][21][22][23][24][25]34,35]. Therefore, it is important to highlight the meaningfulness of an iterative and complementary procedure among different screening approaches, namely CLD, LCA, and literature. In fact, this procedure enables a better "a" to "b" and a "-" sign indicate that "if "a" increases, then "b" decreases". For instance, Figure  2b shows that if dry tailings protection increases, tailings leaking may be reduced; on the other side, if tailings leaking occurs, the effort spent on leaking treatment increases.  Inputs: they are elementary and product flows used by processes related to ore mining and processing. These inputs include any energy and consumable, water, and land use, as displayed in Figure 3.   The full CLD diagram is displayed in Figure 5 in Section 3.1 "Results from the Qualitative CLD".

LCA Screening Approach
Beside a qualitative causal loop diagram, the LCA methodology was identified as the main approach to be used for the hotspots screening. LCA is a well-established and internationally recognized technique to assess potential positive and negative impacts occurring across the life cycle of a product or service. Hence, this scientific approach was applied both to the environmental (ELCA) and social (SLCA) dimensions. The already mentioned CLD was a crucial input to the LCA screening, further complemented with literature research [9,[20][21][22][23][24][25]34,35]. Therefore, it is important to highlight the meaningfulness of an iterative and complementary procedure among different screening approaches, namely CLD, LCA, and literature. In fact, this procedure enables a better interpretation of the outcomes in the specific local context of mining activities.
Mining processes representative for the first target of the ITERAMS solution (sulfide ore mining) were investigated in the different countries where the validation sites are located (Finland,  "a" to "b" and a "-" sign indicate that "if "a" increases, then "b" decreases". For instance, Figure  2b shows that if dry tailings protection increases, tailings leaking may be reduced; on the other side, if tailings leaking occurs, the effort spent on leaking treatment increases.  Inputs: they are elementary and product flows used by processes related to ore mining and processing. These inputs include any energy and consumable, water, and land use, as displayed in Figure 3.   The full CLD diagram is displayed in Figure 5 in Section 3.1 "Results from the Qualitative CLD".

LCA Screening Approach
Beside a qualitative causal loop diagram, the LCA methodology was identified as the main approach to be used for the hotspots screening. LCA is a well-established and internationally recognized technique to assess potential positive and negative impacts occurring across the life cycle of a product or service. Hence, this scientific approach was applied both to the environmental (ELCA) and social (SLCA) dimensions. The already mentioned CLD was a crucial input to the LCA screening, further complemented with literature research [9,[20][21][22][23][24][25]34,35]. Therefore, it is important to highlight the meaningfulness of an iterative and complementary procedure among different screening approaches, namely CLD, LCA, and literature. In fact, this procedure enables a better interpretation of the outcomes in the specific local context of mining activities.
Mining processes representative for the first target of the ITERAMS solution (sulfide ore mining) were investigated in the different countries where the validation sites are located (Finland, The full CLD diagram is displayed in Figure 5 in Section 3.1 "Results from the Qualitative CLD".

LCA Screening Approach
Beside a qualitative causal loop diagram, the LCA methodology was identified as the main approach to be used for the hotspots screening. LCA is a well-established and internationally recognized technique to assess potential positive and negative impacts occurring across the life cycle of a product or service. Hence, this scientific approach was applied both to the environmental (ELCA) and social (SLCA) dimensions. The already mentioned CLD was a crucial input to the LCA screening, further complemented with literature research [9,[20][21][22][23][24][25]34,35]. Therefore, it is important to highlight the meaningfulness of an iterative and complementary procedure among different screening approaches, namely CLD, LCA, and literature. In fact, this procedure enables a better interpretation of the outcomes in the specific local context of mining activities.
Mining processes representative for the first target of the ITERAMS solution (sulfide ore mining) were investigated in the different countries where the validation sites are located (Finland, Portugal, and South Africa). The processes were selected from well-accepted and renowned databases and calculated in the openLCA software. EXIOBASE and ecoinvent databases were used for the ELCA screening, while the Product Social Impact Life Cycle Assessment (PSILCA) database was identified for the performance of the SLCA screening. Furthermore, environmental and social impacts were evaluated with a number of Life Cycle Impact Assessment Methods (LCIAM) in order to (1) cover all the impact categories important for the project and (2) investigate whether some burdens are unwittingly shifted from one impact category to another. In addition, the application of different LCIAMs was crucial for the cross-checking and identification of those topics which emerged as common sustainability issues to the LCIAMs considered. Specifically, ILCD 2011 Midpoint+, ReCiPe Midpoint H, CML-IA Baseline, Boulay et al. (2011), and built-in EXIOBASE LCIAM were selected for the ELCA screening, while social impacts were calculated by applying the Social Impacts Weighting Method contained in the PSILCA database.
The following steps were undertaken to conduct the screening (as summarized in Table 1): • Definition of the processes to be investigated: the first focus was set on copper ore mining. However, when related processes were not available in the databases, the focus was extended to mining of metal ores.

•
Definition of the locations to be considered for the chosen processes: Finland, Portugal, and South Africa were set as the main focus of the study as the validation sites for the ITERAMS technologies are located in these three countries. Regarding the ELCA screening performed with EXIOBASE, the "copper ores and concentrates" sector was analyzed for Finland, Portugal, and South Africa.
On the other side, in the case of the ELCA screening with ecoinvent, the analysis of copper mining had to be extended to Europe as country-specific processes were not available in the database.
Copper mining impacts could not be assessed for South Africa using the ecoinvent database. However, moving beyond the first focus of the study, potential environmental impacts of copper mining in South America were evaluated using ecoinvent, given the intention of applying the ITERAMS combined solutions to that region as well in the future. Regarding the SLCA screening, Finland and Portugal were the only two countries analyzed as the third validation site in South Africa had not been identified at the time of the study. The interpretation of SLCA results, in fact, requires a number of background information, which cannot be collected in absence of a specific site location. • Performance of the environmental LCA screening. The starting point was the comparison of information contained in the databases and the specific details given by the ITERAMS project proposal, for instance regarding water consumption for copper ore processing. Afterwards, environmental hotspots were detected from the calculation of the impacts derived from the processes in the databases. Finally, this was followed by a reflection on the common and different issues which emerged from the analysis of the same process occurring in diverse geographic regions or countries. • Performance of the social LCA screening. At first, high and very high social risks were identified considering those directly associated with the mining processes to be analyzed. The identification procedure of high and very high social risks was based on the analysis of the risk levels reported in the PSILCA database for the different social indicators assigned to the metal ores mining sector in Finland and Portugal. Afterwards, potential social impacts were assessed including the upstream chain, hence leading to the definition of the social hotspots. Finally, results obtained from the calculation of mining processes were compared to social impacts generated by an average sector in the country. This latter operation was important to compare sector specific risks and impacts with the general social situation in the country.

•
The study was complemented by the definition of complementary and overlapping issues between the environmental and social dimensions. Furthermore, possible trade-offs were investigated as well, as further explained in Section 4.1. Literature research was crucial for the interpretation of results and the definition of the background situations with an influence on the impacts detected with the LCA study. Table 1 offers an overview of the processes, locations, databases, and LCIAMs investigated for the LCA screening study.

Definition of the "Background Situations"
The definition of the context of the mining operations is crucial to interpret the LCA results and, hence, identify the environmental and social hotspots. In particular, it is possible to determine the so-called "background situations" which may have either a positive or negative influence on the so-called "stressors". The stressors are pressures on the environmental and social dimensions that may be either mitigated or intensified by background existing conditions. For instance, the dependence of local communities on local water reserves can be considered as a background situation which may worsen the impact of water withdrawal for ore processing. Indeed, if those local water resources are used by local populations for agricultural practices, industrial water withdrawal has a greater impact than that it would have in an area with a different socio-economic condition. Table 2 shows an overview on the identified stressors and related background situations to be considered for the interpretation of the environmental and social impacts of the ITERAMS solution. Specifically, for the present LCA screening the following criteria were determined, most of them traceable in Table 2: • Vulnerability of local communities, such as the already mentioned dependence on local water reserves. The human capital may have an influence on the impacts as well, for instance if a consistent share of the population suffers from HIV or respiratory problems, impacts generated by mining operations may worsen the health conditions of those weaker individuals.

•
Conflicts with other competing sectors in the area, for instance, in terms of workforce or resource use. Considering the validation sites in Finland and Portugal, the local community in the area of the Portuguese mine lives from agriculture of olives and cork [36], while reindeer farming and nature tourism are two competing sectors in Northern Finland [9,20]. • Availability and status of local water and mineral resources. Information can be usually derived from national environment institutes. As for Finland, it is possible to highlight that the condition of freshwater is generally good, with the exception of coastal water where the ecological status is very poor due to eutrophication [37]. In Portugal, the condition of surface water is classified as "reasonable" in most areas; however, some areas on the coast and inner central southern territories display a poor or very poor condition [38]. It is necessary to clarify that data for Finland and Portugal are referred to 2015 and 2013 respectively.
• Importance of the sector for the national and local economy, considering for instance the contribution of mining in the national GDP or the share of local workers hired at the mine sites. For example, as of December 2015, 52% and 36% of workers in Kevitsa (Finland) are hired, respectively, locally (from Sodankylä) and regionally (from Lapland) [39]. • Risks at a national level, hence not related to the mining sector. They may include public sector corruption and sanitation and drinkable water coverage in the country. Indeed, social and socio-economic national and sector-specific risks can influence each other. • Stability of risks and impacts over the life cycle, which may be useful to detect the contribution of the supply chain to overall results, hence leading to the identification of direct and indirect risks and impacts of the mining activity in a given area.

Results from the Qualitative CLD
The CLD explores risks and impacts generated by the different processes of the mine operation, see Figure 5 for a complete picture. The focus is the investigation of the different variables and resource inputs which affect the water cycle at the mine site. Furthermore, attention is paid to the issue of Resources 2018, 7, 80 9 of 21 tailings disposal and on how this may be influenced by diverse hydrological conditions and water recycling approaches. Specifically, risks derived from process operation, untreated and uncaptured leaking, and dam accidents are highlighted in the diagram in Figure 5.  The CLD displays the influence of risks and technology choices on social and environmental impacts with reference to consequences on workers and local communities for the social side and on ecosystems, resources, land use, and human health for the environmental dimension. However, the human health issue can be related directly to the social sphere, hence stressing the complementarity between the two dimensions. Figure 6 explains the relations among the different elements in the diagram which affect human health impacts; brackets indicate that the element has already appeared in the diagram, in this case in Figure 6. Therefore, in this example, it is possible to detect the impact contribution of energy and material inputs for water cleaning and tailings treatment effort. Furthermore, a number of risks related to tailings leaking and dam accidents can exacerbate the potential consequences on human health. Finally, environmental conditions together with tailings deposit characteristics, such as the pond size, may have an additional role in the proportion by which tailings treatment affects health conditions of workers and local populations.
Resources 2018, 7, 80 11 of 22 Figure 6 explains the relations among the different elements in the diagram which affect human health impacts; brackets indicate that the element has already appeared in the diagram, in this case in Figure 6. Therefore, in this example, it is possible to detect the impact contribution of energy and material inputs for water cleaning and tailings treatment effort. Furthermore, a number of risks related to tailings leaking and dam accidents can exacerbate the potential consequences on human health. Finally, environmental conditions together with tailings deposit characteristics, such as the pond size, may have an additional role in the proportion by which tailings treatment affects health conditions of workers and local populations.  In addition, the CLD investigates the relations around the geopolymers creation which is a crucial point for the ITERAMS project. For instance, a good geopolymers performance may positively influence dry tailings protection, hence preventing tailings leaking and evaporation with a consequent reduction of impacts on human health and ecosystems. In addition, the CLD investigates the relations around the geopolymers creation which is a crucial point for the ITERAMS project. For instance, a good geopolymers performance may positively influence dry tailings protection, hence preventing tailings leaking and evaporation with a consequent reduction of impacts on human health and ecosystems.

Results from the Environmental LCA Screening
The ELCA screening reports results calculated with different databases and methods pursuing, this way, the method of triangulation. The processes analyzed with ecoinvent, namely "copper mine operation" and "copper production, primary", include a number of life cycle stages, such as copper mining in ground, blasting, grinding, flotation, concentration, and tailings disposal. Furthermore, the processes account for consumables and energy used during ore extraction and beneficiation, for instance chemicals, electricity, and fuel.
Toxicity categories emerged as crucial if the processes in ecoinvent are calculated with the different methods considered, see Figure 7a,b. These toxicity categories include both water related ones, such as freshwater and marine ecotoxicity, and human toxicity, additionally subdivided by the International Reference Life Cycle Data System (ILCD) method by cancer and non-cancer effects. The results presented below are normalized according to the following normalization sets:

Results from the Environmental LCA Screening
The ELCA screening reports results calculated with different databases and methods pursuing, this way, the method of triangulation. The processes analyzed with ecoinvent, namely "copper mine operation" and "copper production, primary", include a number of life cycle stages, such as copper mining in ground, blasting, grinding, flotation, concentration, and tailings disposal. Furthermore, the processes account for consumables and energy used during ore extraction and beneficiation, for instance chemicals, electricity, and fuel.
Toxicity categories emerged as crucial if the processes in ecoinvent are calculated with the different methods considered, see Figure 7a,b. These toxicity categories include both water related ones, such as freshwater and marine ecotoxicity, and human toxicity, additionally subdivided by the International Reference Life Cycle Data System (ILCD) method by cancer and non-cancer effects. The results presented below are normalized according to the following normalization sets: If the most contributing processes to the previously identified toxicity categories are investigated, the treatment of sulfidic tailings off-site clearly emerges as an environmental hotspot for both the water and human toxicity issues ( Figure 8). Therefore, this outcome reinforces the purpose of the ITERAMS project which has tailings valorization and reduction of effluents to the environment as core objectives.  If the most contributing processes to the previously identified toxicity categories are investigated, the treatment of sulfidic tailings off-site clearly emerges as an environmental hotspot for both the water and human toxicity issues ( Figure 8). Therefore, this outcome reinforces the purpose of the ITERAMS project which has tailings valorization and reduction of effluents to the environment as core objectives.
The ELCA screening reports results calculated with different databases and methods pursuing, this way, the method of triangulation. The processes analyzed with ecoinvent, namely "copper mine operation" and "copper production, primary", include a number of life cycle stages, such as copper mining in ground, blasting, grinding, flotation, concentration, and tailings disposal. Furthermore, the processes account for consumables and energy used during ore extraction and beneficiation, for instance chemicals, electricity, and fuel.
Toxicity categories emerged as crucial if the processes in ecoinvent are calculated with the different methods considered, see Figure 7a,b. These toxicity categories include both water related ones, such as freshwater and marine ecotoxicity, and human toxicity, additionally subdivided by the International Reference Life Cycle Data System (ILCD) method by cancer and non-cancer effects. The results presented below are normalized according to the following normalization sets: If the most contributing processes to the previously identified toxicity categories are investigated, the treatment of sulfidic tailings off-site clearly emerges as an environmental hotspot for both the water and human toxicity issues ( Figure 8). Therefore, this outcome reinforces the purpose of the ITERAMS project which has tailings valorization and reduction of effluents to the environment as core objectives.  Climate change has not emerged as a major issue from the normalized results presented. However, literature [6] and primary data from mining companies report that the stages of crushing and grinding require a consistent amount of electricity which is, hence, responsible for an important share of GHG emissions during operation. Considering the processes in ecoinvent and the different LCIAMs, the analysis of the most contributing processes to the climate change impact category confirms electricity and blasting as the main environmental hotspots. However, input values for electricity in the analyzed processes in ecoinvent appear to be underestimated if compared to primary data and secondary sources. In addition, the electricity reported by ecoinvent for the investigated mining processes is produced by hydro power; this may be considered as one reason for lower climate change values than expected.
Blue water withdrawal and consumption indicators were analyzed in EXIOBASE for the sector "Copper ores and concentrates" in different countries. Blue water is defined as the "water that has been sourced from surface or groundwater resources and is either evaporated, incorporated into a product or taken from one body of water and returned to another, or returned at a different time" [40]. Figure 9 displays results for Finland, showing that plastic, chemicals, and blending components have a major effect on blue water consumption and withdrawal for manufacturing. If total blue water withdrawal is analyzed, electricity production can be determined as an environmental hotspot, due to cooling operations. Please note that blue water consumption does not include water used for cooling processes, which is hence assumed to be released with a similar quality as the withdrawal.
Climate change has not emerged as a major issue from the normalized results presented. However, literature [6] and primary data from mining companies report that the stages of crushing and grinding require a consistent amount of electricity which is, hence, responsible for an important share of GHG emissions during operation. Considering the processes in ecoinvent and the different LCIAMs, the analysis of the most contributing processes to the climate change impact category confirms electricity and blasting as the main environmental hotspots. However, input values for electricity in the analyzed processes in ecoinvent appear to be underestimated if compared to primary data and secondary sources. In addition, the electricity reported by ecoinvent for the investigated mining processes is produced by hydro power; this may be considered as one reason for lower climate change values than expected.
Blue water withdrawal and consumption indicators were analyzed in EXIOBASE for the sector "Copper ores and concentrates" in different countries. Blue water is defined as the "water that has been sourced from surface or groundwater resources and is either evaporated, incorporated into a product or taken from one body of water and returned to another, or returned at a different time" [40]. Figure 9 displays results for Finland, showing that plastic, chemicals, and blending components have a major effect on blue water consumption and withdrawal for manufacturing. If total blue water withdrawal is analyzed, electricity production can be determined as an environmental hotspot, due to cooling operations. Please note that blue water consumption does not include water used for cooling processes, which is hence assumed to be released with a similar quality as the withdrawal. Figure 9. Copper ores and concentrates, Finland, from EXIOBASE. Process contribution (direct, without upstream chain) to the impact categories "Water Withdrawal Blue-Total", "Water Withdrawal Blue-Manufacturing", and "Water Consumption Blue-Manufacturing", calculated with EXIOBASE built-in LCIAMs (screenshot from openLCA 1.7).
If the same sector is investigated for South Africa and Portugal, it is interesting to compare the value of water withdrawal and consumption and the related hotspots between the three countries, see Table 3. Results include the upstream chain and display that water withdrawal in Finland is notably higher than in South Africa and Portugal. Furthermore, the results show that impacts are more widespread in the life cycle in comparison to the outcomes obtained from the calculation of the processes in ecoinvent with the different impact assessment methods. If the same sector is investigated for South Africa and Portugal, it is interesting to compare the value of water withdrawal and consumption and the related hotspots between the three countries, see Table 3. Results include the upstream chain and display that water withdrawal in Finland is notably higher than in South Africa and Portugal. Furthermore, the results show that impacts are more widespread in the life cycle in comparison to the outcomes obtained from the calculation of the processes in ecoinvent with the different impact assessment methods.

Results from the Social LCA Screening
The SLCA screening enabled, at first, the identification of those high and very high social risks directly linked to mining of metal ores in Finland and Portugal. Both countries present a very high risk of mining companies' involvement in corruption and bribery and of a not socially responsible behavior in the supply chain. Furthermore, a high (in Finland) and very high (in Portugal) risk of non-fatal accidents can be highlighted, with an additional very high risk of fatal accidents in Finland. Industrial water use emerged as an important issue for the Finnish sector, while women discrimination in the labor force and neglect of trade unionism rights could be considered as social issues in the Portuguese industry. The full documentation and explanation of social risks and impact categories in the database are available in the PSILCA manual [41].
The calculation of potential social impacts related to mining of metal ores in Finland highlights that a number of potential social impacts are not related to the sector as such, but they occur in the upstream chain. Thus, the life cycle under study ( Figure 10) displays the highest contribution to sector-specific social themes, such as "Social responsibility along the supply chain", "Non-fatal accidents", "Certified environmental management systems", "Trade unionism", and "Safety measures". However, the last three social topics could not be identified with the previous investigation of high and very high social risks directly linked to the mining process, meaning that those social impacts are largely related to processes part of the supply chain. Results are expressed in medium risk hours and referred to 1 USD output.
Considering that a high risk of water withdrawn for industrial purposes in Finland emerged from the previous process risk analysis, the process contribution to the related social issue was investigated. Furthermore, this social theme was seen crucial for the evaluation of the sustainability of the ITERAMS solution, as additionally confirmed by the CLD and the ELCA screening. Figure 11 displays that most impacts are linked to the upstream processes of basic metals and chemicals manufacturing, with a negligible contribution derived from metal ore mining itself.
sector-specific social themes, such as "Social responsibility along the supply chain", "Non-fatal accidents", "Certified environmental management systems", "Trade unionism", and "Safety measures". However, the last three social topics could not be identified with the previous investigation of high and very high social risks directly linked to the mining process, meaning that those social impacts are largely related to processes part of the supply chain. Results are expressed in medium risk hours and referred to 1 USD output. Considering that a high risk of water withdrawn for industrial purposes in Finland emerged from the previous process risk analysis, the process contribution to the related social issue was investigated. Furthermore, this social theme was seen crucial for the evaluation of the sustainability of the ITERAMS solution, as additionally confirmed by the CLD and the ELCA screening. Figure 11 displays that most impacts are linked to the upstream processes of basic metals and chemicals manufacturing, with a negligible contribution derived from metal ore mining itself. The Portuguese sector of mining of metal ores shows that a number of potential social impacts are associated with the sector, hence with a less contribution derived from processes happening in the upstream chain. This outcome is, therefore, different from the picture outlined for the Finnish mining sector previously analyzed, for which the supply chain emerged as important for most social impact categories. This may be explained, on one side, with the starting risk levels in the upstream processes of the two countries; on the other side, the activity variable (working hours) is more than three times higher for the Portuguese process than for the Finnish one. The activity variable is crucial for the quantification of a social risk and expresses its importance in the product life cycle. In the context of the two countries under study, the Portuguese sector needs 0.01827 working hours to produce 1 USD output of the sector, while only 0.00563 working hours are required in Finland to generate 1 USD output for the metal ores mining sector. Figure 12 displays the product life cycle contribution to social impacts for 1 USD output. A high amount of medium risk hours can be detected for "Trade unionism", "Social responsibility along the supply chain", "Non-fatal accidents", and "Active involvement of enterprises in corruption and bribery". A minor contribution from upstream processes can be noted for the mentioned sector-specific impact categories. Besides this, social risks at the country level can be highlighted, such as sanitation coverage and public-sector corruption. The Portuguese sector of mining of metal ores shows that a number of potential social impacts are associated with the sector, hence with a less contribution derived from processes happening in the upstream chain. This outcome is, therefore, different from the picture outlined for the Finnish mining sector previously analyzed, for which the supply chain emerged as important for most social impact categories. This may be explained, on one side, with the starting risk levels in the upstream processes of the two countries; on the other side, the activity variable (working hours) is more than three times higher for the Portuguese process than for the Finnish one. The activity variable is crucial for the quantification of a social risk and expresses its importance in the product life cycle. In the context of the two countries under study, the Portuguese sector needs 0.01827 working hours to produce 1 USD output of the sector, while only 0.00563 working hours are required in Finland to generate 1 USD output for the metal ores mining sector. Figure 12 displays the product life cycle contribution to social impacts for 1 USD output. A high amount of medium risk hours can be detected for "Trade unionism", "Social responsibility along the supply chain", "Non-fatal accidents", and "Active involvement of enterprises in corruption and bribery". A minor contribution from upstream processes can be noted for the mentioned sector-specific impact categories. Besides this, social risks at the country level can be highlighted, such as sanitation coverage and public-sector corruption. The geographic localization of social impacts related to metal ores mining in Portugal is less widespread for a number of impact categories if compared to Finland. Figure 13a displays the direct process contribution, without upstream chain, to "Non-fatal accidents". The highest share of the impacts is due exactly to the Portuguese mining sector as such. Basic metals manufacturing and the construction sector in Portugal can be identified as other social hotspots (both from commodities and industry fields). Furthermore, in this case, impacts can be localized in Portugal and, to a small extent, in Spain, Figure 13b.

Identification and Interpretation of the Sustainability Hotspots
The CLD provided a number of useful inputs to be further developed with both the LCA screening and the literature research. Several cause-effect relations in the diagram confirmed what was expected, for instance in terms of dam accidents which may be reduced or even eliminated with the ITERAMS implementation. Indeed, the risk of dam breakage and damage increases with the dam size which, in turn, generates a higher land use. Therefore, less wastewater output due to a more efficient water recycling and the production of dry tailings are supposed to decrease risks and impacts on ecosystems, human health, workers, and local communities. On the other side, the CLD shows less straightforward relations among the different items, leading to the identification of a number of trade-offs. The closed loop water cycle planned by ITERAMS, for instance, may lead to a The geographic localization of social impacts related to metal ores mining in Portugal is less widespread for a number of impact categories if compared to Finland. Figure 13a displays the direct process contribution, without upstream chain, to "Non-fatal accidents". The highest share of the impacts is due exactly to the Portuguese mining sector as such. Basic metals manufacturing and the construction sector in Portugal can be identified as other social hotspots (both from commodities and industry fields). Furthermore, in this case, impacts can be localized in Portugal and, to a small extent, in Spain, Figure 13b. The geographic localization of social impacts related to metal ores mining in Portugal is less widespread for a number of impact categories if compared to Finland. Figure 13a displays the direct process contribution, without upstream chain, to "Non-fatal accidents". The highest share of the impacts is due exactly to the Portuguese mining sector as such. Basic metals manufacturing and the construction sector in Portugal can be identified as other social hotspots (both from commodities and industry fields). Furthermore, in this case, impacts can be localized in Portugal and, to a small extent, in Spain, Figure 13b.

Identification and Interpretation of the Sustainability Hotspots
The CLD provided a number of useful inputs to be further developed with both the LCA screening and the literature research. Several cause-effect relations in the diagram confirmed what was expected, for instance in terms of dam accidents which may be reduced or even eliminated with the ITERAMS implementation. Indeed, the risk of dam breakage and damage increases with the dam size which, in turn, generates a higher land use. Therefore, less wastewater output due to a more efficient water recycling and the production of dry tailings are supposed to decrease risks and impacts on ecosystems, human health, workers, and local communities. On the other side, the CLD shows less straightforward relations among the different items, leading to the identification of a number of trade-offs. The closed loop water cycle planned by ITERAMS, for instance, may lead to a

Identification and Interpretation of the Sustainability Hotspots
The CLD provided a number of useful inputs to be further developed with both the LCA screening and the literature research. Several cause-effect relations in the diagram confirmed what was expected, for instance in terms of dam accidents which may be reduced or even eliminated with the ITERAMS implementation. Indeed, the risk of dam breakage and damage increases with the dam size which, in turn, generates a higher land use. Therefore, less wastewater output due to a more efficient water recycling and the production of dry tailings are supposed to decrease risks and impacts on ecosystems, human health, workers, and local communities. On the other side, the CLD shows less straightforward relations among the different items, leading to the identification of a number of trade-offs. The closed loop water cycle planned by ITERAMS, for instance, may lead to a more efficient water recycling, but concurrently to higher impacts on human health due to the higher energy required and produced to isolate the water cycle in the different ore beneficiation steps, Figure 14.
Resources 2018, 7, 80 17 of 22 more efficient water recycling, but concurrently to higher impacts on human health due to the higher energy required and produced to isolate the water cycle in the different ore beneficiation steps, Figure 14. The ELCA screening highlighted tailings treatment as the main environmental hotspot. In particular, tailings disposal may cause serious damages both to the environment and human health due to heavy metals toxic emissions which pollute air and water resources. Figure 15, for example, shows the most contributing flows to the impacts generated by the treatment of sulfidic tailings in the context of marine aquatic ecotoxicity. Furthermore, although a number of differences in results can be noticed between different geographic locations, environmental impacts are not excessively globally widespread, meaning that they are usually confined to the geographic region or continent. On the other hand, a different outcome may be highlighted for the SLCA screening where the supply chain and geographic impact distribution emerged as crucial for a number of social issues or even countries.
An interesting insight on social impacts is offered by the comparison between the mining sector and an average industry in the country. If this operation is performed for Finland (Figure 16), social impacts of metal ores mining result higher than those of an average Finnish sector, especially regarding "Contribution to environmental load", "Social responsibility along the supply chain", "Industrial water depletion", and "Safety measures". The ELCA screening highlighted tailings treatment as the main environmental hotspot. In particular, tailings disposal may cause serious damages both to the environment and human health due to heavy metals toxic emissions which pollute air and water resources. Figure 15, for example, shows the most contributing flows to the impacts generated by the treatment of sulfidic tailings in the context of marine aquatic ecotoxicity.
Resources 2018, 7, 80 17 of 22 more efficient water recycling, but concurrently to higher impacts on human health due to the higher energy required and produced to isolate the water cycle in the different ore beneficiation steps, Figure 14. The ELCA screening highlighted tailings treatment as the main environmental hotspot. In particular, tailings disposal may cause serious damages both to the environment and human health due to heavy metals toxic emissions which pollute air and water resources. Figure 15, for example, shows the most contributing flows to the impacts generated by the treatment of sulfidic tailings in the context of marine aquatic ecotoxicity. Furthermore, although a number of differences in results can be noticed between different geographic locations, environmental impacts are not excessively globally widespread, meaning that they are usually confined to the geographic region or continent. On the other hand, a different outcome may be highlighted for the SLCA screening where the supply chain and geographic impact distribution emerged as crucial for a number of social issues or even countries.
An interesting insight on social impacts is offered by the comparison between the mining sector and an average industry in the country. If this operation is performed for Finland (Figure 16), social impacts of metal ores mining result higher than those of an average Finnish sector, especially regarding "Contribution to environmental load", "Social responsibility along the supply chain", "Industrial water depletion", and "Safety measures". Furthermore, although a number of differences in results can be noticed between different geographic locations, environmental impacts are not excessively globally widespread, meaning that they are usually confined to the geographic region or continent. On the other hand, a different outcome may be highlighted for the SLCA screening where the supply chain and geographic impact distribution emerged as crucial for a number of social issues or even countries.
An interesting insight on social impacts is offered by the comparison between the mining sector and an average industry in the country. If this operation is performed for Finland (Figure 16), social impacts of metal ores mining result higher than those of an average Finnish sector, especially regarding "Contribution to environmental load", "Social responsibility along the supply chain", "Industrial water depletion", and "Safety measures". The main social hotspots related to a number of impact categories for mining of metal ores in Finland are basic metals and chemicals manufacturing in Finland, construction in China and India, and machinery production in Russia. This outcome stresses the high contribution of the processing stages, such as flotation, to overall impacts. Furthermore, several impacts occurring in the supply chain can be localized in Asian countries. In the case of the analyzed Portuguese mining sector, basic metals manufacturing in Portugal, metal products in China and Angola, and motor vehicles and engines manufacturing in USA can be regarded as social hotspots. Besides, construction in India and China together with the direct impacts linked to the mining sector itself show an important contribution to the product life cycle in Portugal. As for the Portuguese case, the impacts related to the mine and processing plant installation appear to be rather consistent.
The interpretation of the identified environmental and social sustainability hotspots can be further developed if the overlapping and complementarity between the two dimensions is further discussed. Indeed, a number of indicators or impact categories may cover the same issue; however, they often express different consequences as they investigate impacts on different stakeholders and characters. Figure 17 shows an example of how water resource depletion due to industrial water withdrawal and consumption for the mining activities may have consequences on the environment, leading to the destruction of material resources and environmental degradation. In parallel, the scarcity or exhaustion of water resources may destroy those local economies which need water for their operations. In both cases, local communities may be highly affected incurring in poverty and resettlement if they are dependent on local water reserves for their livelihood, and hence, easily vulnerable. A second demonstration of this complementarity is provided by tailings leaking which may lead to soil and, consequently, groundwater contamination with severe health problems for the local population, but also with ecosystem impairment. The main social hotspots related to a number of impact categories for mining of metal ores in Finland are basic metals and chemicals manufacturing in Finland, construction in China and India, and machinery production in Russia. This outcome stresses the high contribution of the processing stages, such as flotation, to overall impacts. Furthermore, several impacts occurring in the supply chain can be localized in Asian countries. In the case of the analyzed Portuguese mining sector, basic metals manufacturing in Portugal, metal products in China and Angola, and motor vehicles and engines manufacturing in USA can be regarded as social hotspots. Besides, construction in India and China together with the direct impacts linked to the mining sector itself show an important contribution to the product life cycle in Portugal. As for the Portuguese case, the impacts related to the mine and processing plant installation appear to be rather consistent.
The interpretation of the identified environmental and social sustainability hotspots can be further developed if the overlapping and complementarity between the two dimensions is further discussed. Indeed, a number of indicators or impact categories may cover the same issue; however, they often express different consequences as they investigate impacts on different stakeholders and characters. Figure 17 shows an example of how water resource depletion due to industrial water withdrawal and consumption for the mining activities may have consequences on the environment, leading to the destruction of material resources and environmental degradation. In parallel, the scarcity or exhaustion of water resources may destroy those local economies which need water for their operations. In both cases, local communities may be highly affected incurring in poverty and resettlement if they are dependent on local water reserves for their livelihood, and hence, easily vulnerable. A second demonstration of this complementarity is provided by tailings leaking which may lead to soil and, consequently, groundwater contamination with severe health problems for the local population, but also with ecosystem impairment.

Strength and Weakness of the Study
The different approaches presented in the article jointly led to the identification of the environmental and social hotspots associated with the mining industry and further developed in the context of the objectives of the ITERAMS project. Such an achievement was made possible by the mutual iteration between the CLD, LCA, and literature which from time to time triggered new challenges and reflections.
A number of limitations could be identified with reference to the use of existing databases for the LCA screening. Indeed, it should be considered that databases use statistical data to build some of the information they present; hence, uncertainties related to data gaps, quality, and assumptions may be present [42]. Furthermore, a specific reflection on the uncertainty derived from multi regional input output (IO) models should be made, considering the use of IO databases (EXIOBASE, PSILCA) for the study [43].
Regarding the LCA screening, results are taken directly from the selected databases without altering any input and output value. In this regard, the water and electricity requirements for copper ore mining and processing in ecoinvent are estimated to be rather low in contrast to primary data that will, in turn, be used for the next LCA assessment of ITERAMS. In addition, there is some criticism on the characterization models used to estimate toxicity from heavy metals [44].
Finally, the documentation of the data quality is crucial for the interpretation of results. Data quality is assessed in openLCA using the Pedigree matrix [41,45], further adapted for SLCA. In this latter case, for instance, it should be noted that information for "Trade unionism" and "Non-fatal accidents" is older than five years and that incomplete data are available for "Social responsibility along the supply chain" and "Certified environmental management systems". Few indicators, such as "Trade unionism", "Pollution", and "Industrial water depletion", present a low data quality for the criteria "Further technical conformance". This is due to the fact that data for these indicators are interpolated from the country average as sector-specific information is not available.

Conclusions
The sustainability hotspots screening study provided a valuable input to the ITERAMS project. Indeed, it enabled a better understanding of the environmental and social issues associated with mining which are crucial for the creation and evaluation of the specific life cycle model of the ITERAMS combined solutions. In fact, this work was the first step towards the prioritization of the

Strength and Weakness of the Study
The different approaches presented in the article jointly led to the identification of the environmental and social hotspots associated with the mining industry and further developed in the context of the objectives of the ITERAMS project. Such an achievement was made possible by the mutual iteration between the CLD, LCA, and literature which from time to time triggered new challenges and reflections.
A number of limitations could be identified with reference to the use of existing databases for the LCA screening. Indeed, it should be considered that databases use statistical data to build some of the information they present; hence, uncertainties related to data gaps, quality, and assumptions may be present [42]. Furthermore, a specific reflection on the uncertainty derived from multi regional input output (IO) models should be made, considering the use of IO databases (EXIOBASE, PSILCA) for the study [43].
Regarding the LCA screening, results are taken directly from the selected databases without altering any input and output value. In this regard, the water and electricity requirements for copper ore mining and processing in ecoinvent are estimated to be rather low in contrast to primary data that will, in turn, be used for the next LCA assessment of ITERAMS. In addition, there is some criticism on the characterization models used to estimate toxicity from heavy metals [44].
Finally, the documentation of the data quality is crucial for the interpretation of results. Data quality is assessed in openLCA using the Pedigree matrix [41,45], further adapted for SLCA. In this latter case, for instance, it should be noted that information for "Trade unionism" and "Non-fatal accidents" is older than five years and that incomplete data are available for "Social responsibility along the supply chain" and "Certified environmental management systems". Few indicators, such as "Trade unionism", "Pollution", and "Industrial water depletion", present a low data quality for the criteria "Further technical conformance". This is due to the fact that data for these indicators are interpolated from the country average as sector-specific information is not available.

Conclusions
The sustainability hotspots screening study provided a valuable input to the ITERAMS project. Indeed, it enabled a better understanding of the environmental and social issues associated with mining which are crucial for the creation and evaluation of the specific life cycle model of the ITERAMS combined solutions. In fact, this work was the first step towards the prioritization of the efforts and resources for the sustainability evaluation of the project. In addition, it provided an important overview to be accounted for when drafting the goal and scope of the following LCA study. Furthermore, this article highlighted the significance of exploring different methodologies and approaches in sustainability assessment. Indeed, once results are calculated, they need to be placed in the context of the mining activities, hence evaluating those specific local and national background situations which influence environmental and social pressures. The study on how the environmental and social dimensions interact with each other was equally fundamental, displaying how often environmental risks and impacts end up on risks and impacts on societal stakeholders. Furthermore, it is worth mentioning that the sustainability screening approach developed in the context of the ITERAMS project can be applied to both other mining case studies and, more broadly, to other different situations if the general reflections and insights given on the methodology, tools, and identification of the background situations are considered.
As a final point, the present study was important for the project as it helped to create a dialogue among the different project partners. The technical partners and the mining companies had, this way, the chance to understand the sense and the approach of LCA and sustainability assessment in general. These understanding and appraisal are crucial for the partners´commitment and participation to the next stages of the work, starting from the primary data collection at the different mine sites.

Author Contributions:
The two authors gave a contribution to conceptualization, methodology, validation, formal analysis, investigation, and visualization. A.C. contributed to software and resources, and was involved in data curation. C.D.N. was responsible for the original draft preparation, which was further reviewed and edited by A.C. Finally, A.C. supervised the whole work, as involved in project administration and funding acquisition.
Funding: This Project has received funding from the European Union H2020 program under grant agreement No 730480.