Preparation and Temperature Susceptibility Evaluation of Crumb Rubber Modiﬁed Asphalt Applied in Alpine Regions

: In alpine regions, the durability of asphalt pavement is worse due to the harsh climate. However, crumb rubber modiﬁed asphalt has the potential to improve the durability of pavement. Based on matrix asphalt, crumb rubber, Trans-Polyoctenamer Rubber Reactive Modiﬁer (TOR), and an orthogonal test, the preparation scheme of crumb rubber modiﬁed asphalt suitable for alpine regions was obtained. The crumb rubber was selected 30 mesh, and the content of crumb rubber was 24% of the quality of matrix asphalt. Shearing time was 60 min, and preparation temperature was 205 ◦ C. Shearing rate was 5000 r/min, and optimum TOR content was set as 4.5% of the quality of crumb rubber. The temperature susceptibility of matrix asphalt (JZ), crumb rubber modiﬁed asphalt (AR), crumb rubber modiﬁed asphalt mixed with TOR (TAR) was investigated. The high temperature performance indexes, including phase angle, the complex modulus index, and rutting factor, and the low temperature performance indexes including creep rate and stiffness modulus, the ratio of creep rate and stiffness modulus, Burgers model parameters, dissipated energy ratio, and the derivative of creep compliance were analyzed in depth with multiple parameters. Meanwhile, the mechanisms of prepared AR and TAR were explored. The results indicate that the PG grading is PG64-22 of JZ, PG70-34 of AR, and PG82-28 of TAR. The deformation resistance of TAR at high temperature is superior to AR. The addition of crumb rubber not only improves the temperature susceptibility, but also enhances its viscoelasticity at low temperatures. After the crumb rubber swell in the asphalt system, the network structures are crosslinked and the physical and chemical effects are produced, such as cracking and repolymerization in the asphalt system. TOR can further enhance the swelling and network crosslinking effects of rubber-asphalt. The TAR has the strongest weather resistance. The study provides guidance for AR and TAR to be used in alpine regions. 2848 cm − 1 is produced by symmetric expansion of –CH 2 –; 1655 cm − 1 is produced by the vibration of C=O double bond in the carboxy group; 1448 cm − 1 is produced by the variable angle vibration of –CH 2 –; and 1092 cm − 1 is produced by the scaling of C–O. The wave number 1539 cm − 1 is the stretching vibration result of NO 2 in the R–NO 2 . The wave numbers of 743, 834, and 1375 cm − 1 are generated by out-of-plane and in-plane bending vibration of the benzene torus. The wave number of 965 cm − 1 is produced by the out-of-plane bending vibration of the C–H bond in the trans unsaturated group of butadiene. main of crumb natural and styrene-butadiene rubber.


Introduction
The alpine region is characterized by low temperature, high altitude, large temperature difference, and intense ultraviolet radiation. The daily temperature difference can reach more than 35 • C. Winds in the mountain pass areas can reach force 10 to 12 [1]. The number of freeze-thaw cycles is as high as 80 times per year. The alternating time of positive and negative temperature is more than 6 months per year [2]. The average relative humidity is only 35 percent, far less than 65 percent in eastern China [3]. Asphalt pavement is rapidly aged under strong ultraviolet radiation. Continuous low temperature action, high and low temperature cycle change, and damage of freeze-thaw and frost heaving make asphalt surfaces crack, and the pavement performances are significantly reduced [2,3]. With the extension of service life, the expressways with excellent pavement performance may generate various diseases [4,5]. The coupling effects of multiple factors in the environment lead to the aggravation of temperature fatigue of pavement structures and accelerate the fatigue damage and performance degradation of pavement structures and materials. It brings about frequent pavement diseases in early service [6][7][8][9]. Meanwhile, the increasing traffic volume proposes a severe test to the stability and durability of the pavement surface in alpine regions [10][11][12].
With the development and improvement of crumb rubber modified asphalt technology, the application and system are gradually being perfected. Generally, when the crumb rubber content is about 10%, modified asphalt has relatively weak performance improvement. The main purpose of its use is to improve the adhesion of asphalt and aggregate and reduce the temperature sensitivity of asphalt pavement. The crumb rubber modified asphalt is mostly used for asphalt pavements with low traffic volume. When the crumb rubber content is about 15%, the performance of crumb rubber modified asphalt has been significantly improved [13]. The use of crumb rubber modified asphalt can slow down the occurrence of road diseases and improve pavement durability, and the advantages of anti-skid and wear resistance are obtained. It is used for the pavement surface layers of heavy traffic and worse original road condition [13]. The plant-produced crumb rubber asphalt shows good storage stability and satisfying road properties compared to other binders, while the asphalt mixture prepared with plant-produced crumb rubber asphalt shows satisfying road performances. In general, the plant-produced crumb rubber asphalt could be a promising replacement for SBS modified asphalt based on the mixture type evaluated [14,15]. State departments of transportations are currently experimenting with use of ground tire rubber (crumb rubber) in bituminous construction and as a crack sealer [16]. The performances of the recycled asphalt concrete with stable crumb rubber asphalt binder were investigated. Both the normal recycled asphalt mixtures and the stable crumb rubber asphalt recycled asphalt mixtures were prepared with 0%, 30%, or 50% content of the reclaimed asphalt pavement. The stable crumb rubber asphalt is much better than the virgin asphalt in recycling the aged asphalt mixtures, with large reclaimed asphalt pavement content which could reach 50% [17][18][19]. The microstructure and performance of crumb rubber modified asphalt were explored. The crumb rubber modified asphalt have better performance compared with matrix asphalt. The properties of crumb rubber display significant effects on the performance of crumb rubber modified asphalt. The performance of crumb rubber modified asphalt are improved with the decrease in ash content and the increase in acetone extract. Micrographs of crumb rubber modified asphalt prepared under different conditions showed that, compared with crumb rubber modified asphalt prepared by the traditional preparation process, the scattering state of rubber powder and matrix asphalt in crumb rubber modified asphalt prepared by matrix asphalt preblending process is excellent and even, and a perfect polymer reticular structure is formed in the sample system [20][21][22].
Crumb rubber modified asphalt mixture can reduce the thickness of pavement surface, the incidences of reflective cracks and temperature shrinkage cracks [14,15]. Meanwhile, crumb rubber comes from waste tire containing high polymers such as natural rubber, which is beneficial for enhancing asphalt performance [23,24]. The use of waste tire is also an environmentally friendly waste material recycling technology, and reduces carbon emissions [25,26]. The mechanical response of two gap-graded asphalt rubber mixtures manufactured by the dry process (AR dry ) were evaluated. The observed behavior was compared with that of a similar gap-graded mixture without rubber granulate, used as reference. The results were also compared with analogous asphalt rubber mixes produced elsewhere by the wet process (AR wet ). The laboratory results and behavior concluded that mechanical performance of the tested AR dry is better than that measured for the reference blend, and was at the same level of performance as AR wet , provided that a proper mixture design and some construction directives are used [27].
The test sections and physical projects using crumb rubber modified asphalt are involved in south, southwest, and light freezing regions of China. However, research on the specific preparation process and temperature susceptibility of crumb rubber modified asphalt suitable for alpine regions is scarce. Meanwhile, the final performances of crumb rubber modified asphalt are closely related to the chemical composition of the matrix asphalt, physical and chemical properties of the crumb rubber, such as type, size, amount, etc., and preparation parameters, such as the preparation of temperature, shearing rate, mixing time, etc. [28,29]. Raw materials and preparation process are strictly controlled. The crumb rubber modified asphalt of high quality and best performance is prepared. In addition, the technical application system of crumb rubber modified asphalt in alpine regions is still incomplete. In view of this, preparation and temperature susceptibility evaluations of crumb rubber modified asphalt applied in alpine regions were investigated, and modified mechanisms were analyzed.

Materials
Crumb rubber modified asphalt is a complex combination system consisting of SK-90# matrix asphalt, crumb rubber, and admixtures. The performance of each raw material has important influences on the performance indexes of crumb rubber modified asphalt. This section mainly studies the properties of SK-90# matrix asphalt, crumb rubber, and admixtures.

Matrix Asphalt
The SK-90# matrix asphalt was used in alpine regions. Table 1 shows its technical indicators, and Figure 1 shows the diagrams of atomic force microscope, which was made by Park Systems in Suwon, Korea. The dispersion phases with peak structure are evenly distributed on the asphalt surface. The structures are thought to be the rise and fall of asphalt in a flat area, which are represented by "spikes" in the three-dimensional diagram. The "bee-structure" of SK-90# matrix asphalt mainly comes from asphaltene and some colloid in the asphalt. The wax elements in asphalt will crystallize at the tip of the "beestructure", which is not conducive to the adhesion of asphalt and aggregates. The R q of root mean square roughness is 6.73 nm calculated. Waste truck radial tire was used as raw material to prepare crumb rubber by normal temperature grinding process. Figure 2 shows the structure of load radial tire, and Table

Crumb Rubber
Waste truck radial tire was used as raw material to prepare crumb rubber by normal temperature grinding process. Figure 2 shows the structure of load radial tire, and Table 2 shows the differences in material compositions of different tires by test analysis.  Figure 3 shows the grinding process at normal temperature. As the particles have an irregular shape and large relative specific surface area by process. It is conducive to full interaction with asphalt, and the cost is the lo     Figure 3 shows the grinding process at normal temperature. As the crumb rubber particles have an irregular shape and large relative specific surface area by the grinding process. It is conducive to full interaction with asphalt, and the cost is the lowest [30,31].

Crumb Rubber
Waste truck radial tire was used as raw material to prepare crumb rubber by temperature grinding process. Figure 2 shows the structure of load radial tire, an 2 shows the differences in material compositions of different tires by test analysis  Figure 3 shows the grinding process at normal temperature. As the crumb particles have an irregular shape and large relative specific surface area by the g process. It is conducive to full interaction with asphalt, and the cost is the lowest   The crumb rubber images of a scanning electron microscope (SEM) and an infrared spectrum are shown in Figures 4 and 5. Hitachi S-4800 cold field emission scanning electron microscope was made by Japanese high-tech manufacturer, and Fourier transform infrared spectrometer (BRUKER TENSOR II) was made by Germany. Wave numbers of 2958 and 2917 cm −1 are the results of stretching vibration of C-H bond in -CH 3 and -CH 2 -. In total, Coatings 2022, 12, 496 5 of 26 2848 cm −1 is produced by symmetric expansion of -CH 2 -; 1655 cm −1 is produced by the vibration of C=O double bond in the carboxy group; 1448 cm −1 is produced by the variable angle vibration of -CH 2 -; and 1092 cm −1 is produced by the scaling of C-O. The wave number 1539 cm −1 is the stretching vibration result of NO 2 in the R-NO 2 . The wave numbers of 743, 834, and 1375 cm −1 are generated by out-of-plane and in-plane bending vibration of the benzene torus. The wave number of 965 cm −1 is produced by the outof-plane bending vibration of the C-H bond in the trans unsaturated group of butadiene. The main components of crumb rubber are natural rubber and styrene-butadiene rubber. The technical specifications are shown in Tables 3 and 4.
The crumb rubber images of a scanning electron microscope (SEM) and an spectrum are shown in Figures 4 and 5. Hitachi S-4800 cold field emission scann tron microscope was made by Japanese high-tech manufacturer, and Fourier tr infrared spectrometer (BRUKER TENSOR II) was made by Germany. Wave num 2958 and 2917 cm −1 are the results of stretching vibration of C-H bond in -CH3 an . In total, 2848 cm −1 is produced by symmetric expansion of -CH2-; 1655 cm −1 is p by the vibration of C=O double bond in the carboxy group; 1448 cm −1 is produce variable angle vibration of -CH2-; and 1092 cm −1 is produced by the scaling of C wave number 1539 cm −1 is the stretching vibration result of NO2 in the R-NO2. T numbers of 743, 834, and 1375 cm −1 are generated by out-of-plane and in-plane vibration of the benzene torus. The wave number of 965 cm −1 is produced by the plane bending vibration of the C-H bond in the trans unsaturated group of bu The main components of crumb rubber are natural rubber and styrene-butadiene The technical specifications are shown in Tables 3 and 4.    The crumb rubber images of a scanning electron microscope (SEM) and an infrared spectrum are shown in Figures 4 and 5. Hitachi S-4800 cold field emission scanning electron microscope was made by Japanese high-tech manufacturer, and Fourier transform infrared spectrometer (BRUKER TENSOR II) was made by Germany. Wave numbers of 2958 and 2917 cm −1 are the results of stretching vibration of C-H bond in -CH3 and -CH2-. In total, 2848 cm −1 is produced by symmetric expansion of -CH2-; 1655 cm −1 is produced by the vibration of C=O double bond in the carboxy group; 1448 cm −1 is produced by the variable angle vibration of -CH2-; and 1092 cm −1 is produced by the scaling of C-O. The wave number 1539 cm −1 is the stretching vibration result of NO2 in the R-NO2. The wave numbers of 743, 834, and 1375 cm −1 are generated by out-of-plane and in-plane bending vibration of the benzene torus. The wave number of 965 cm −1 is produced by the out-ofplane bending vibration of the C-H bond in the trans unsaturated group of butadiene The main components of crumb rubber are natural rubber and styrene-butadiene rubber The technical specifications are shown in Tables 3 and 4.

Trans-Polyoctenamer Rubber Reactive Modifier
Trans-Polyoctenamer Rubber Reactive Modifier (TOR) is a polymer with a double bond structure. As shown in Figure 6, TOR is translucent crystalline particles. TOR crosslinks the sulfur in the asphalt to the sulfur on the crumb rubber surface. The network structures of rings and chains of polymers are formed.

Trans-Polyoctenamer Rubber Reactive Modifier
Trans-Polyoctenamer Rubber Reactive Modifier (TOR) is a polymer with a doubl bond structure. As shown in Figure 6, TOR is translucent crystalline particles. TOR cross links the sulfur in the asphalt to the sulfur on the crumb rubber surface. The network structures of rings and chains of polymers are formed. Figure 7 shows the infrared spectrum diagram of TOR. TOR is mainly composed o saturated and unsaturated carbon chains. The absorption peak of TOR is produced by th antisymmetric absorption vibration of C-H bond in methylene CH2-at 2917 cm −1 . In tota 2849 cm −1 is the symmetric vibration effect of C-H in alkane and cycloalkane. The absorp tion peak of 1467 cm −1 is the bending vibration in C-H bond plane. The wave number o 965 cm −1 is produced by the out-of-plane bending vibration of the C-H bond in the tran unsaturated group of butadiene. The in-plane wobble vibration produced by saturated methylene is approximately 719 cm −1 . The technical specifications are shown in Table 5.    Figure 7 shows the infrared spectrum diagram of TOR. TOR is mainly composed of saturated and unsaturated carbon chains. The absorption peak of TOR is produced by the antisymmetric absorption vibration of C-H bond in methylene CH 2 -at 2917 cm −1 . In total, 2849 cm −1 is the symmetric vibration effect of C-H in alkane and cycloalkane. The absorption peak of 1467 cm −1 is the bending vibration in C-H bond plane. The wave number of 965 cm −1 is produced by the out-of-plane bending vibration of the C-H bond in the trans unsaturated group of butadiene. The in-plane wobble vibration produced by saturated methylene is approximately 719 cm −1 . The technical specifications are shown in Table 5.

Preparation Method of Crumb Rubber Modified Asphalt
The matrix asphalt selected SK-90#. It was referred to as JZ. Crumb rubber modified asphalt was referred as AR. When TOR was added, crumb rubber modified asphalt was referred as TAR.
In order to prepare crumb rubber modified asphalt suitable for pavement in alpine regions, the orthogonal test method was adopted. Penetration (25 • C, 100 g, 5 s), softening point, ductility (5 • C), segregation softening point difference (48 h, 163 • C), elastic recovery rate (25 • C), the |B| value of viscosity-temperature regression coefficient, and shearing strength (25 • C) were selected as evaluation indexes. According to Equation (1), the shearing strength was obtained through cone penetration test. The cone penetration value of crumb rubber modified asphalt was tested by cone penetration tester, as shown in Figure 8. |B| values were acquired by Equation (2) and regression analysis of crumb rubber modified asphalt viscosity with temperatures of 135, 150, 165, 180, and 195 • C.
in which τ is shearing strength, kPa; Q is total mass of conical needle, connecting rod and weights, 195 g; h is cone penetration, mm; and α is the angle of cone tip, 30 • .
According to the orthogonal test scheme, the preparation process of crumb rubber modified asphalt is shown in Figure 9. On the basis of Standard Test Methods of Bitumen and Bituminous Mixtures for Highway Engineering (JTG E20-2011) and test results, the best preparation process and parameters were determined.

Determination of TOR Content
TOR was added to improve pavement performance of crumb rubber modified asphalt. TOR was 0, 4.0%, 4.5%, or 5.0% of the content of crumb rubber. This is represented as W 0 , W 4 . 0 , W 4 . 5 , or W 5 . 0 , respectively. According to Standard Test Methods of Bitumen and Bituminous Mixtures for Highway Engineering (JTG E20-2011), the experiments of penetration, softening point, ductility, elastic recovery rate, cone penetration, segregation softening point difference, and Brinell viscosity at 135, 150, 165, 180, and 195 • C were conducted. The optimal content of TOR was determined in crumb rubber modified asphalt. Meanwhile, shear strength is converted from the cone penetration, according to Equation (1). The Viscosity-Temperature-Susceptibility was calculated by Equation (2).

Dynamic Shear Rheological Test
Referring to AASHTO-TP5 test method, the dynamic shear rheological test was carried out by DHR-1 dynamic shear rheometer. The strain control mode was selected. The strain value was 8%. The frequency was 10 rad/s. The temperature scanning test was carried out in the temperature range of 46-82 • C. Through comparative analysis of phase angle, the complex modulus index GTS, and rutting factor, the effects of crumb rubber and TOR on the high temperature performance of crumb rubber modified asphalt were investigated.

Bending Beam Rheometer Test
The bending beam rheometer is used to test the low temperature performance of asphalt samples. After the three kinds of asphalt samples were aged by TFOT and PAV, the beam samples were prepared. Its length, width, and thickness were 127 ± 2.0, 12.7 ± 0.1, and 6.4 ± 0.1 mm, respectively. The test temperature of JZ was set to 6, −12, and −18 • C. The test temperature of AR/TAR were set to −12, −18, −24, and −30 • C. The stiffness modulus and creep rates of different asphalt were obtained by testing under constant stress of 240 s and set temperature. The stiffness modulus and creep rate were calculated by Equations (3) and (4), respectively [32][33][34].
in which S is stiffness modulus, MPa; m is creep rate; l is the span of the beam, mm; v(t) is deformation of beam midpoint at some moment, mm; h is the height of the beam, mm; p is the constant load, N; and b is the width of the beam, mm.

Microcosmic Test of Crumb Rubber Modified Asphalt
The prepared JZ, AR, and TAR were placed under a fluorescence microscope, scanning electron microscope, and Fourier infrared spectrometer, respectively. The magnifications of the scanning electron microscope and Fourier microscope were selected 1000 and 5000 times, respectively. The magnification of fluorescence microscope is 100 times. The microstructures of three kinds of asphalts were observed, and mechanisms were analyzed. Figure 10 shows flow chart of material preparations and experimental programs.
ings 2022, 12, x FOR PEER REVIEW 10 of Figure 10. Flow chart of material preparations and experimental programs.

Analysis of Orthogonal Test Results
According to the designed orthogonal test scheme, 16 groups of crumb rubber mo ified asphalt were prepared. Test results are shown in Table 8. The range values of penetration, softening point, ductility, segregation softeni point difference, elastic recovery rate, |B| value, and shearing strength were analyze

Analysis of Orthogonal Test Results
According to the designed orthogonal test scheme, 16 groups of crumb rubber modified asphalt were prepared. Test results are shown in Table 8. The range values of penetration, softening point, ductility, segregation softening point difference, elastic recovery rate, |B| value, and shearing strength were analyzed. The range values of various factors and the effects of factor level on the corresponding index were calculated, with the results shown in Table 9. The performances of crumb rubber modified asphalt prepared under different combination schemes are different. The crumb rubber mesh has the most significant effect on the softening point value. The softening point values of crumb rubber modified asphalt prepared by 30 mesh and 40 mesh crumb rubber are higher. However, the softening point value of crumb rubber modified asphalt prepared by 60 mesh crumb rubber is minimal. The content of crumb rubber has a significant effect on the low temperature ductility and viscosity of crumb rubber modified asphalt. When the content of crumb rubber is 24%, the ductility and viscosity are about 1.5 times and 3 times higher, respectively, than those of the 12% sample. Therefore, the high content of crumb rubber is beneficial to improve the low temperature performance. Shear time has the most effect on elastic recovery rate and |B| value. With the extension of shear time, elastic recovery rate first increases and then decreases, while the |B| value is the opposite. When shear time is 60 min, elastic recovery rate is the strongest and temperature sensitivity is the lowest. Preparation temperature significantly affects the penetration, segregation softening point difference, and shear strength of the crumb rubber modified asphalt. With the increase in preparation temperature, the penetration gradually increases, and it is also affected by the crumb rubber mesh. The segregation softening point difference first decreases and then increases with the increase in the preparation temperature, and the minimum value is obtained when the preparation temperature is 205 • C. The shear strength decreases significantly with the increase in the preparation temperature. The reason is that the effect of temperature will lead to desulfurization of crumb rubber in asphalt. The shear rate has no significant effect on the performances of crumb rubber modified asphalt.
According to performance requirements of crumb rubber modified asphalt in alpine regions, proper analysis were conducted for penetration, softening point, ductility and elastic recovery rate, segregation softening point difference, shearing strength, and |B| value. The optimal combination schemes required by composite corresponding indexes were selected, as shown in Table 10.
The optimal combination schemes for the preparation of crumb rubber modified asphalt is A 2 -B 4 -C 2 -D 3 -E 4 , that is, the crumb rubber mesh is 30. The content of crumb rubber is 24%. The shear time is 60 min. The preparation temperature is 205 • C, and the shear rate is 5000 r/min. The confirmed process flow charts of preparation of crumb rubber modified asphalt are shown in Figure 11. The optimal combination schemes for the preparation of crumb rubber modified asphalt is A2-B4-C2-D3-E4, that is, the crumb rubber mesh is 30. The content of crumb rubber is 24%. The shear time is 60 min. The preparation temperature is 205 °C , and the shear rate is 5000 r/min. The confirmed process flow charts of preparation of crumb rubber modified asphalt are shown in Figure 11.

Determination of TOR Content
When the content of TOR is different, the performances of crumb rubber modified asphalt is shown in Figures 12 and 13. In Figure 12, the softening point, elastic recovery rate, and shear strength of crumb rubber modified asphalt enhance with the increase in TOR, while the penetration, low temperature ductility, segregation softening point difference, and VTS decrease, indicating that TOR significantly improved the flexibility, temperature susceptibility, and storage stability of crumb rubber modified asphalt at low temperatures. With the increase in TOR content, the elastic recovery rate increases by 1%, 7%, and 10%, respectively. The shear strength increases by 5%, 51%, and 79%, respectively.

Determination of TOR Content
When the content of TOR is different, the performances of crumb rubber modified asphalt is shown in Figures 12 and 13. In Figure 12, the softening point, elastic recovery rate, and shear strength of crumb rubber modified asphalt enhance with the increase in TOR, while the penetration, low temperature ductility, segregation softening point difference, and VTS decrease, indicating that TOR significantly improved the flexibility, temperature susceptibility, and storage stability of crumb rubber modified asphalt at low temperatures. With the increase in TOR content, the elastic recovery rate increases by 1%, 7%, and 10%, respectively. The shear strength increases by 5%, 51%, and 79%, respectively. The VTS decreases by 1%, 6%, and 9%, respectively. The difference of segregation softening point decreases by 9%, 8%, and 7%, respectively. When the content of TOR is 4.5%, all the evaluation indexes change significantly. When the content of TOR increases from 4.5% to 5%, the difference of the segregation softening point increases from 0.7 to 1.2, and the viscosity at 150 • C increases from 4700 to 6075 cp, as shown in Figure 13. Considering the high viscosity, poor storage stability of crumb rubber modified asphalt, the climate of alpine regions, and economical analysis, the appropriate TOR content is determined to be 4.5%.
The VTS decreases by 1%, 6%, and 9%, respectively. The difference of segregation softening point decreases by 9%, 8%, and 7%, respectively. When the content of TOR is 4.5%, al the evaluation indexes change significantly. When the content of TOR increases from 4.5% to 5%, the difference of the segregation softening point increases from 0.7 to 1.2, and the viscosity at 150 °C increases from 4700 to 6075 cp, as shown in Figure 13. Considering the high viscosity, poor storage stability of crumb rubber modified asphalt, the climate of alpine regions, and economical analysis, the appropriate TOR content is determined to be 4.5%.

Phase Angle
The parameters of dynamic shear rheological test were performed in the temperature range of 46-82 °C . The strain value was 8%, and the frequency was 10 rad/s. The results are shown in Figure 14. The VTS decreases by 1%, 6%, and 9%, respectively. The difference of segregation ing point decreases by 9%, 8%, and 7%, respectively. When the content of TOR is the evaluation indexes change significantly. When the content of TOR increases fro to 5%, the difference of the segregation softening point increases from 0.7 to 1.2, viscosity at 150 °C increases from 4700 to 6075 cp, as shown in Figure 13. Conside high viscosity, poor storage stability of crumb rubber modified asphalt, the clima pine regions, and economical analysis, the appropriate TOR content is determin 4.5%.

Phase Angle
The parameters of dynamic shear rheological test were performed in the temp range of 46-82 °C . The strain value was 8%, and the frequency was 10 rad/s. The are shown in Figure 14.

Phase Angle
The parameters of dynamic shear rheological test were performed in the temperature range of 46-82 • C. The strain value was 8%, and the frequency was 10 rad/s. The results are shown in Figure 14. As shown in Figure 14, the values of phase angle gradually increase ture increases. Under the same temperature, the values of phase angle ar The delay time of asphalt response to stress is affected by asphalt type a condition. When the temperature is 64 °C , the δAR/δJZ and δTAR/δJZ are 0.76 tively, before the short-term aging. The reason is that the incorporation increases the elastic components in the complex modulus of asphalt. Th ture deformation resistance of asphalt under load is enhanced. The addi ther enhances the effect. After short-term aging, the phase angles of th asphalts decrease; δAR/δJZ and δTAR/δJZ are 0.75 and 0.67, respectively. Mea components of asphalt volatilize. The asphalts become hardened by oxid components of asphalt increase, and the phase angles decrease. The sig short-term aging effect on the three kinds of asphalts is TAR > AR = JZ.

Complex Modulus Exponent
The complex modulus exponent method is used to characterize the t sitivity of medium and high temperature regions of asphalt by dynamic test. The complex modulus exponent was calculated by Equation (5) [35-lg(lgG * ) = GTS × lgT + C in which G* is complex modulus, Pa; GTS is the complex modulus expone and T is the test temperature, K.
Dynamic shear rheometer was used to test the rheological propertie ples at 58, 64, 70, 76, and 82 °C. Figure 15 shows the regression equat regression coefficient results. The greater the absolute value of GTS, the perature sensitivity of asphalt. The complex modulus G* double logarit As shown in Figure 14, the values of phase angle gradually increase as the temperature increases. Under the same temperature, the values of phase angle are JZ > AR > TAR. The delay time of asphalt response to stress is affected by asphalt type and temperature condition. When the temperature is 64 • C, the δ AR /δ JZ and δ TAR /δ JZ are 0.76 and 0.72, respectively, before the short-term aging. The reason is that the incorporation of crumb rubber increases the elastic components in the complex modulus of asphalt. The high temperature deformation resistance of asphalt under load is enhanced. The addition of TOR further enhances the effect. After short-term aging, the phase angles of the three kinds of asphalts decrease; δ AR /δ JZ and δ TAR /δ JZ are 0.75 and 0.67, respectively. Meanwhile, the light components of asphalt volatilize. The asphalts become hardened by oxidation. The elastic components of asphalt increase, and the phase angles decrease. The significant order of short-term aging effect on the three kinds of asphalts is TAR > AR = JZ.

Complex Modulus Exponent
The complex modulus exponent method is used to characterize the temperature sensitivity of medium and high temperature regions of asphalt by dynamic shear rheometer test. The complex modulus exponent was calculated by Equation (5) [35][36][37]. lg(lgG * ) = GTS × lgT + C (5) in which G* is complex modulus, Pa; GTS is the complex modulus exponent; C is constant; and T is the test temperature, K. Dynamic shear rheometer was used to test the rheological properties of asphalt samples at 58, 64, 70, 76, and 82 • C. Figure 15 shows the regression equations of GTS and regression coefficient results. The greater the absolute value of GTS, the greater the temperature sensitivity of asphalt. The complex modulus G* double logarithms of the three kinds of asphalts have good linear relationships with the temperature logarithm.

Rutting Factor
In Figure 16, as the temperature increases, the rutting factors of the asphalts exhibit decreasing trends. The reason is that asphalts behave as an low temperature. As the temperature increases, the asphalt changes into a state, and the strain caused by the shear force decreases gradually. Under perature, the rutting factors are TAR > AR > JZ. When temperature is 64 short-term aging, the rutting factors of AR and TAR increase by 2.3 and 0 pared with JZ. The adding of crumb rubber enhances the rutting resistance high temperature. The reason is that the swelling effect of the compounds o crumb rubber increases the elastic components of asphalt. Moreover, the ad enhances the interactions between asphalt and crumb rubber, so TOR enhan mation resistance of TAR at high temperature. At 58 °C , after the short-te rutting factors of the three kinds of asphalts increase by 0.8, 0.3, and 0.7 times The reason is that the rutting factors increase after short-term aging, while affected by short-term aging. Meanwhile, after short-term aging, the PG gra reduced by one grade. The final PG grading temperature of high temperat (JZ), 70 °C (AR), and 82 °C (TAR).

Rutting Factor
In Figure 16, as the temperature increases, the rutting factors of the three kinds of asphalts exhibit decreasing trends. The reason is that asphalts behave as an elastic state at low temperature. As the temperature increases, the asphalt changes into a viscous flow state, and the strain caused by the shear force decreases gradually. Under the same temperature, the rutting factors are TAR > AR > JZ. When temperature is 64 • C, before the short-term aging, the rutting factors of AR and TAR increase by 2.3 and 0.6 times compared with JZ. The adding of crumb rubber enhances the rutting resistance of asphalts at high temperature. The reason is that the swelling effect of the compounds of asphalt and crumb rubber increases the elastic components of asphalt. Moreover, the addition of TOR enhances the interactions between asphalt and crumb rubber, so TOR enhances the deformation resistance of TAR at high temperature. At 58 • C, after the short-term aging, the rutting factors of the three kinds of asphalts increase by 0.8, 0.3, and 0.7 times, respectively. The reason is that the rutting factors increase after short-term aging, while AR is the least affected by short-term aging. Meanwhile, after short-term aging, the PG grading of AR is reduced by one grade. The final PG grading temperature of high temperatures are 64 • C (JZ), 70 • C (AR), and 82 • C (TAR).

Low Temperature Creep Test
According to the SHRP evaluation methods, the BBR test results of three kinds of asphalts are shown in Tables 11 and 12. When the temperature is −12 • C, compared with m JZ and S JZ , m AR increases by 19% and S AR decreases by 73%. The results show that crumb rubber can enhance the relaxation ability at low temperature and crack resistance of asphalt. Under the same temperature, compared with AR and TAR, the m JZ is slightly lower, and the S JZ is slightly higher. In conclusion, the low temperature performances of the three kinds of asphalts are AR > TAR > JZ. According to the specification, the slope m of the creep curve is not less than 0.3, and the stiffness modulus S is not more than 300 MPa. The PG grading temperatures of low temperature can be obtained as −22 • C (JZ), −34 • C (AR), and −28 • C (TAR). mation resistance of TAR at high temperature. At 58 °C , after the short-term ag rutting factors of the three kinds of asphalts increase by 0.8, 0.3, and 0.7 times, respe The reason is that the rutting factors increase after short-term aging, while AR is t affected by short-term aging. Meanwhile, after short-term aging, the PG grading reduced by one grade. The final PG grading temperature of high temperatures a (JZ), 70 °C (AR), and 82 °C (TAR).    Figure 17 shows the variations of creep rate and stiffness modulus changing with time. The creep rate decreases with the decrease in temperature, while the stiffness modulus increases. At the 87th load action, the creep rate curves of AR intersect at −18 and −24 • C, and then continue to accumulate with the number of load actions. However, m −24 • C is larger than m −18 • C . It shows that PG grading cannot completely distinguish the low temperature performance of asphalt. It is limited to reflect the low temperature performance of asphalt only by m or S. Therefore, multiple processing and calculation methods should be used to evaluate [38][39][40].

m/S Value in Creep Compliance
The m/S ratio was adopted to evaluate the low temperature performance of asphalt. As the m/S ratio increases, the low temperature performance of asphalt is better [41,42]. Figure 18 shows the variations of m/S values with loading time. With the increase in loading time, the m/S values increase gradually and eventually tend to be flat. These show that the low temperature performances of three kinds of asphalts tend to be stable with the increase in loading time. At −12 • C, the m/S values of AR and TAR are significantly higher than JZ, indicating that the addition of crumb rubber improves the low temperature performance of asphalt. The m/S differences between AR and TAR decrease with decreas-ing temperature. The results show that the effects of crumb rubber and TOR on the low temperature performance of asphalt are reduced at lower temperature. Figure 17 shows the variations of creep rate and stiffness modulus changing with time. The creep rate decreases with the decrease in temperature, while the stiffness modulus increases. At the 87th load action, the creep rate curves of AR intersect at −18 and −24 °C , and then continue to accumulate with the number of load actions. However, m−24 °C is larger than m−18 °C . It shows that PG grading cannot completely distinguish the low temperature performance of asphalt. It is limited to reflect the low temperature performance of asphalt only by m or S. Therefore, multiple processing and calculation methods should be used to evaluate [38][39][40].

m/S Value in Creep Compliance
The m/S ratio was adopted to evaluate the low temperature performance of asphalt. As the m/S ratio increases, the low temperature performance of asphalt is better [41,42]. Figure 18 shows the variations of m/S values with loading time. With the increase in

Determine Burgers Model Parameters
According to the creep compliance (Equation (6)) of Burgess model and the Leve berg-Marquardt (LM) method, the asphalt creep data were fitted. The elastic modulus ( E2) and viscosity coefficient (η1, η2) were obtained by fitting. The relaxation time (λ) a delay time (τ) were obtained according to Equations (7) and (8) [43][44][45]. Table 13 sho the Burgers model parameter results at different temperatures.
in which J(t) is creep compliance of Burgess model, Pa; E 1 is the elastic coefficient of Maxwell model, Pa; η 1 is the damping coefficient of Maxwell model, Pa; E 2 is the elastic coefficient of Kelvin model, Pa; η 2 is the damping coefficient of Kelvin model, Pa; and t is the load time, s.  Figures 19 and 20 show the relaxation time (λ) and delay time (τ) changes of the three kinds of asphalts at different temperatures. The relaxation time can represent the variation of stress in the material with time. The larger λ is, the lower the stress relaxation ratio is, which is not conducive to rapid stress dissipation. Under the same temperature, the relaxation time of asphalts is λ JZ > λ TAR > λ AR . The low temperature relaxation capacities of AR and TAR are much higher than JZ, because the blend of crumb rubber increases the viscosity of asphalt. TOR causes crumb rubber and asphalt to form network structures of large rings and chains polymers. At low temperatures, the intermolecular motion is difficult. The stress relaxation time is long. laxation time of asphalts is λJZ > λTAR > λAR. The low temperature relaxation capacities of AR and TAR are much higher than JZ, because the blend of crumb rubber increases the viscosity of asphalt. TOR causes crumb rubber and asphalt to form network structures of large rings and chains polymers. At low temperatures, the intermolecular motion is difficult. The stress relaxation time is long.
The relaxation time of asphalt increases with decreasing temperature. On one hand, with the decrease in temperature, the ratio of elastic component to viscous component in asphalt gradually increases. The energy consumption of asphalt under stress decreases. The relaxation capacity decreases, and the relaxation time increases. On the other hand, the molecular motion of the swelling crumb rubber polymer in asphalt is temperature dependent. At low temperatures, the internal friction of relative motion between molecular chains is larger, which leads to a longer stress relaxation time.

Dissipated Energy Ratio
Dissipated energy ratio is the ratio of dissipated energy to stored energy, which can reflect the stress relaxation capacity. The higher the ratio of dissipated energy, the better the stress relaxation capacity and low temperature performance will be. The dissipated energy ratio varies with time. According to the established storage energy (Equation (9)) and dissipated energy (Equation (10)), the dissipated energy ratio at t = 60 s was explored to analyze the low temperature performances of the three kinds of asphalts [46][47][48]. laxation time of asphalts is λJZ > λTAR > λAR. The low temperature relaxation capacities o AR and TAR are much higher than JZ, because the blend of crumb rubber increases the viscosity of asphalt. TOR causes crumb rubber and asphalt to form network structures o large rings and chains polymers. At low temperatures, the intermolecular motion is diffi cult. The stress relaxation time is long.
The relaxation time of asphalt increases with decreasing temperature. On one hand with the decrease in temperature, the ratio of elastic component to viscous component in asphalt gradually increases. The energy consumption of asphalt under stress decreases The relaxation capacity decreases, and the relaxation time increases. On the other hand the molecular motion of the swelling crumb rubber polymer in asphalt is temperature dependent. At low temperatures, the internal friction of relative motion between molecu lar chains is larger, which leads to a longer stress relaxation time.

Dissipated Energy Ratio
Dissipated energy ratio is the ratio of dissipated energy to stored energy, which can reflect the stress relaxation capacity. The higher the ratio of dissipated energy, the bette the stress relaxation capacity and low temperature performance will be. The dissipated energy ratio varies with time. According to the established storage energy (Equation (9) and dissipated energy (Equation (10)), the dissipated energy ratio at t = 60 s was explored to analyze the low temperature performances of the three kinds of asphalts [46][47][48]. The relaxation time of asphalt increases with decreasing temperature. On one hand, with the decrease in temperature, the ratio of elastic component to viscous component in asphalt gradually increases. The energy consumption of asphalt under stress decreases. The relaxation capacity decreases, and the relaxation time increases. On the other hand, the molecular motion of the swelling crumb rubber polymer in asphalt is temperature dependent. At low temperatures, the internal friction of relative motion between molecular chains is larger, which leads to a longer stress relaxation time.

Dissipated Energy Ratio
Dissipated energy ratio is the ratio of dissipated energy to stored energy, which can reflect the stress relaxation capacity. The higher the ratio of dissipated energy, the better the stress relaxation capacity and low temperature performance will be. The dissipated energy ratio varies with time. According to the established storage energy (Equation (9) (10)), the dissipated energy ratio at t = 60 s was explored to analyze the low temperature performances of the three kinds of asphalts [46][47][48].
in which G s (t) is storage energy; G d (t) is dissipated energy; E 1 is the elastic coefficient of Maxwell model, Pa; η 1 is the damping coefficient of Maxwell model, Pa; E 2 is the elastic coefficient of Kelvin model, Pa; η 2 is the damping coefficient of Kelvin model, Pa; t is the load time, s; and σ 0 is the stress, MPa. Figure 21 is the variations of dissipated energy ratio at different temperatures. When the temperature decreases, the dissipated energy ratios of the three kinds of asphalts decrease gradually, and the reduction amplitudes also decrease gradually. These show that the elastic component of asphalt increases as the temperature decreases. When temperature is low, to a certain extent, the asphalt behaves as an elastomer. The stored energy increases in the asphalt, but the dissipated energy decreases. The stress relaxation capacity declines, which is not good for the crack resistance of AR and TAR at low temperature. Under the same temperature, the dissipated energy ratios of AR and TAR are much higher than JZ. The reason is that the adding of crumb rubber can enhance the energy dissipation in asphalt, and reduce the energy storage. Therefore, the stress relaxation capacity is enhanced. With the continuous decrease in temperature, the dissipated energy ratios of AR and TAR are close to the same, indicating that the influences of crumb rubber and TOR on the energy dissipation and storage capacity are much less than temperature.
in which Gs(t) is storage energy; Gd(t) is dissipated energy; E1 is the elastic coefficien Maxwell model, Pa; η1 is the damping coefficient of Maxwell model, Pa; E2 is the ela coefficient of Kelvin model, Pa; η2 is the damping coefficient of Kelvin model, Pa; t is load time, s; and σ0 is the stress, MPa. Figure 21 is the variations of dissipated energy ratio at different temperatures. W the temperature decreases, the dissipated energy ratios of the three kinds of asphalts crease gradually, and the reduction amplitudes also decrease gradually. These show the elastic component of asphalt increases as the temperature decreases. When temp ture is low, to a certain extent, the asphalt behaves as an elastomer. The stored ene increases in the asphalt, but the dissipated energy decreases. The stress relaxation capa declines, which is not good for the crack resistance of AR and TAR at low temperat Under the same temperature, the dissipated energy ratios of AR and TAR are much hig than JZ. The reason is that the adding of crumb rubber can enhance the energy dissipa in asphalt, and reduce the energy storage. Therefore, the stress relaxation capacity is hanced. With the continuous decrease in temperature, the dissipated energy ratios of and TAR are close to the same, indicating that the influences of crumb rubber and T on the energy dissipation and storage capacity are much less than temperature.

Derivative of Creep Compliance
The derivative of creep compliance with respect to time reflects the change rat creep compliance with time. The higher the derivative of creep compliance, the better crack resistance of asphalt at low temperature. Equation (11) is the derivative of Equa (6), which is J′(t) [48].
According to Equation (11), J'(t) values at different temperatures within 240 s w obtained. Its curves, changing with time, are shown in Figure 22.

Derivative of Creep Compliance
The derivative of creep compliance with respect to time reflects the change rate of creep compliance with time. The higher the derivative of creep compliance, the better the crack resistance of asphalt at low temperature. Equation (11) is the derivative of Equation (6), which is J (t) [48]. According to Equation (11), J'(t) values at different temperatures within 240 s were obtained. Its curves, changing with time, are shown in Figure 22. In Figure 22, with the increase in loading time, J'(t) values gradually decrease and eventually tend to be stable. Therefore, the longtime load makes the low temperature crack resistances of asphalts tend to be stable, and the low temperature performances of three kinds of asphalts are no longer affected by the load action time. When the loading time is short, the J''(t) values of the same asphalt decrease with the decrease in temperature. When the temperature is low, J'(t) values tend to be stable, indicating that temperature has the most significant effect on the low temperature performances of three kinds of asphalts.
Based on viscoelastic theory and BBR creep test, the low temperature performances of JZ, AR, and TAR were evaluated and analyzed by m and S values, dissipated energy ratio, m/s value, and creep compliance derivative. The results of the four evaluation methods are consistent. The low temperature performances of the three kinds of asphalts are AR > TAR > JZ. Figure 23 shows fluorescence microscope images of three kinds of asphalts. The JZ is green-yellow. The additions of crumb rubber and TOR cause the color to deepen, so AR and TAR are dark green. The crumb rubber particles are black without fluorescence, and evenly disperse in the asphalt. TOR particles have no fluorescence effect and appear white. TOR particles evenly disperse in black crumb rubber particles-asphalt system. By comparing the colors of the fluorescent microscope images, it can be seen that the surface of crumb rubber particles absorbs the light components of asphalt, and the swelling effect is caused. The swelling effect promotes the degradation of crumb rubber. Degraded crumb rubber cross-links to form uniform network structures. Based on the characteristics of TOR, it can further enhance the swelling and network crosslinking effects of rubberasphalt blend. In Figure 22, with the increase in loading time, J'(t) values gradually decrease and eventually tend to be stable. Therefore, the longtime load makes the low temperature crack resistances of asphalts tend to be stable, and the low temperature performances of three kinds of asphalts are no longer affected by the load action time. When the loading time is short, the J"(t) values of the same asphalt decrease with the decrease in temperature. When the temperature is low, J'(t) values tend to be stable, indicating that temperature has the most significant effect on the low temperature performances of three kinds of asphalts.

Microscopic Mechanism Analysis
Based on viscoelastic theory and BBR creep test, the low temperature performances of JZ, AR, and TAR were evaluated and analyzed by m and S values, dissipated energy ratio, m/s value, and creep compliance derivative. The results of the four evaluation methods are consistent. The low temperature performances of the three kinds of asphalts are AR > TAR > JZ. Figure 23 shows fluorescence microscope images of three kinds of asphalts. The JZ is green-yellow. The additions of crumb rubber and TOR cause the color to deepen, so AR and TAR are dark green. The crumb rubber particles are black without fluorescence, and evenly disperse in the asphalt. TOR particles have no fluorescence effect and appear white. TOR particles evenly disperse in black crumb rubber particles-asphalt system. By comparing the colors of the fluorescent microscope images, it can be seen that the surface of crumb rubber particles absorbs the light components of asphalt, and the swelling effect is caused. The swelling effect promotes the degradation of crumb rubber. Degraded crumb rubber cross-links to form uniform network structures. Based on the characteristics of TOR, it can further enhance the swelling and network crosslinking effects of rubber-asphalt blend. Figure 24 shows the scanning electron microscope images of AR and TAR. The crumb rubber particles are evenly dispersed in the asphalt system, but there is obvious difference in the interface between the asphalt and crumb rubber particles. In AR, the crumb rubbers are angular, and there are obvious gaps in the stacking place. In TAR, the swelling effects of asphalt and crumb rubbers are more sufficient. The interfaces of asphalt and crumb rubbers are seamless and integrated, indicating that TOR significantly enhances the compatibility of asphalt and crumb rubbers blending system. white. TOR particles evenly disperse in black crumb rubber particles-asphalt system. By comparing the colors of the fluorescent microscope images, it can be seen that the surface of crumb rubber particles absorbs the light components of asphalt, and the swelling effect is caused. The swelling effect promotes the degradation of crumb rubber. Degraded crumb rubber cross-links to form uniform network structures. Based on the characteristics of TOR, it can further enhance the swelling and network crosslinking effects of rubberasphalt blend.  Figure 24 shows the scanning electron microscope images of AR and TAR. The crumb rubber particles are evenly dispersed in the asphalt system, but there is obvious difference in the interface between the asphalt and crumb rubber particles. In AR, the crumb rubbers are angular, and there are obvious gaps in the stacking place. In TAR, the swelling effects of asphalt and crumb rubbers are more sufficient. The interfaces of asphalt and crumb rubbers are seamless and integrated, indicating that TOR significantly enhances the compatibility of asphalt and crumb rubbers blending system.  Figure 25 shows infrared spectrum diagrams of three kinds of asphalts. The infrared spectra diagrams of JZ, AR, and TAR are similar, indicating that the modification process is mainly physical modification. 1599 cm −1 is stretching vibration of C=C bond; 1456 cm −1 is the vibrational effect of the methylene -CH2-in-plane surface; and 1376 cm −1 is flexural vibration of C-H bond in -CH3-. The benzene-ring substitution region of 1000 to 650 cm −1 is the vibrational effect of C-H and C-C bond of the benzene ring. Based on the infrared spectrum of crumb rubber and TOR, comparing the areas at the peak of curves, the absorption peak areas of AR and TAR at 1599 cm −1 decrease relatively, caused by the skeletal vibration of the conjugate double bond C=C of benzene ring. The main reason is the bending vibration of C-H bond of crumb rubber at 1400 cm −1 , indicating that there are weak chemical modification effects inside crumb rubber modified asphalt. The addition of TOR enhances the weak chemical interactions between crumb rubber and the asphalt interface to a certain extent.  Figure 25 shows infrared spectrum diagrams of three kinds of asphalts. The infrared spectra diagrams of JZ, AR, and TAR are similar, indicating that the modification process is mainly physical modification. 1599 cm −1 is stretching vibration of C=C bond; 1456 cm −1 is the vibrational effect of the methylene -CH 2 -in-plane surface; and 1376 cm −1 is flexural vibration of C-H bond in -CH 3 -. The benzene-ring substitution region of 1000 to 650 cm −1 is the vibrational effect of C-H and C-C bond of the benzene ring. Based on the infrared spectrum of crumb rubber and TOR, comparing the areas at the peak of curves, the absorption peak areas of AR and TAR at 1599 cm −1 decrease relatively, caused by the skeletal vibration of the conjugate double bond C=C of benzene ring. The main reason is the bending vibration of C-H bond of crumb rubber at 1400 cm −1 , indicating that there are weak chemical modification effects inside crumb rubber modified asphalt. The addition of TOR enhances the weak chemical interactions between crumb rubber and the asphalt interface to a certain extent. Figure 26 shows the schematic diagram of AR and TAR asphalt molecular structure. Asphalt is composed of light components and asphaltene. When crumb rubber and asphalt are mixed at high temperatures, crumb rubber absorbs part of the light components in asphalt and expands in volume. The gel structure is formed around it. When TOR is added, the circular macromolecules and linear molecules of TOR intertwine with each other on the surface of crumb rubber, which gives TOR great deformation resistance and improved resilience after crosslinking.

Microscopic Mechanism Analysis
vibration of the conjugate double bond C=C of benzene ring. The main reason is the bending vibration of C-H bond of crumb rubber at 1400 cm −1 , indicating that there are weak chemical modification effects inside crumb rubber modified asphalt. The addition of TOR enhances the weak chemical interactions between crumb rubber and the asphalt interface to a certain extent.  Figure 26 shows the schematic diagram of AR and TAR asphalt molecular structure. Asphalt is composed of light components and asphaltene. When crumb rubber and asphalt are mixed at high temperatures, crumb rubber absorbs part of the light components in asphalt and expands in volume. The gel structure is formed around it. When TOR is added, the circular macromolecules and linear molecules of TOR intertwine with each other on the surface of crumb rubber, which gives TOR great deformation resistance and improved resilience after crosslinking.

Conclusions
In this study, the preparation process and parameters of crumb rubber modified asphalt suitable for alpine regions were proposed in detail. Meanwhile, the temperature susceptibility evaluations of matrix asphalt (JZ), crumb rubber modified asphalt (AR), and crumb rubber modified asphalt blended with TOR (TAR) were investigated by multi-parameter The following conclusions were drawn.

•
The preparation process of crumb rubber modified asphalt (AR and TAR) suitable

Conclusions
In this study, the preparation process and parameters of crumb rubber modified asphalt suitable for alpine regions were proposed in detail. Meanwhile, the temperature susceptibility evaluations of matrix asphalt (JZ), crumb rubber modified asphalt (AR), and crumb rubber modified asphalt blended with TOR (TAR) were investigated by multiparameter The following conclusions were drawn.

•
The preparation process of crumb rubber modified asphalt (AR and TAR) suitable for alpine region was determined. Crumb rubber is selected 30 mesh, and the content is 24%. The preparation temperature and shearing rate are 205 • C and 5000 r/min, respectively. Shearing time is confirmed to be 60 min. TOR content is 4.5% of the quality of crumb rubber. • PG grading is PG64-22 of JZ, PG70-34 of AR, and PG82-28 of TAR. The deformation resistance of TAR at high temperatures is superior to AR, but its crack resistance at low temperatures is relatively poor.

•
The crumb rubber can improve the temperature susceptibility, and enhance its viscoelasticity at low temperatures. Meanwhile, the relaxation time is reduced. The dissipated energy and stress relaxation capacity are increased. Under the same temperature, the velocity of asphalt entering the creep stable phase decreases. The lower the temperature is, the less time it takes for asphalt to reach creep stability.

•
When the crumb rubber is dispersed in the asphalt system, the surface of the crumb rubber absorbs the light components to produce swelling, and the network structures are cross-linked inside. If TOR is added, it can further enhance the swelling and network crosslinking effects of rubber-asphalt. In the asphalt system, the amount of precipitation of crumb rubber is reduced in a certain time. TOR, and the effects of desulfurization and depolymerization, enhance the storage stability in high temperature conditions. • Based on the research results of temperature susceptibility of crumb rubber modified asphalt in alpine regions, its storage stability and weather resistance under the coupling effect of multiple factors should be further explored. The references for the design and construction of crumb rubber modified asphalt pavement are provided in alpine regions.

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Informed Consent Statement: Not applicable.

Data Availability Statement:
The authors confirm that the data supporting the findings of this study are available within the article.

Conflicts of Interest:
The authors declare no conflict of interest.