Optical Absorption in Si:H Thin Films: Revisiting the Role of the Refractive Index and the Absorption Coefﬁcient

: This paper reports on absorption properties of thin ﬁlms of hydrogenated amorphous and microcrystalline silicon considered for absorption-based applications, such as solar cell, photodetectors, ﬁlters, sensors, etc. A series of four amorphous and four microcrystalline samples PECVD deposited under varied hydrogen dilution was under consideration. Various absorption metrics, based separately on the absorption coefﬁcient and the refractive index (single pass absorption, optical path length, classical light trapping limit) or direct absorptance calculated by the Yablonovitch concept based on a mutual role of them were examined and compared. Differences in absorption abilities are related to the evolving thin ﬁlm microstructure.


Introduction
Effective photon management has been still a current challenge in all optical absorptionbased applications of thin films. Improvements in efficiency of amorphous (a-Si:H) and microcrystalline hydrogenated silicon (µc-Si:H) thin-film absorbers as photodetectors, solar cells, filters, sensors, photonic integrated circuits etc. have been constantly under an extensive interest depending to a great extent on thin film structure, microstructure of Si-H bonds and the resistance against degradation [1][2][3][4][5]. Light trapping structures with different degrees of order resulting in changing absorption have been frequently published and applied [6][7][8][9]. This concept is based on increased optical path length in comparison with the actual absorber thickness. Main strategies to achieve increased absorption due to light trapping are anti-reflection coatings, incoherent light trapping (random scattering inside the absorber or at interfaces that is usually achieved by special patterning), and coherent light trapping in thin films or thin film stacks [10][11][12][13][14][15]. The role of microstructure, i.e., nanocrystalline features inside the thin films, has been frequently studied as playing an important role in the light absorption, e.g., for photodetection [16,17].
Coherent light trapping in thin films does not require costly nanoscale patterning. In a thin film absorber with parallel smooth interfaces the optical path length is increased by multiple light reflections at opposite parallel thin film interfaces although most light is absorbed in the first pass [18]. It is frequent that only reflectance and transmittance is used to consider absorption in thin film absorbers as an extrinsic effect. But it is crucial to remember that the amount of reflected, transmitted and absorbed light depends on fundamental optical properties of the thin film, i.e., on the refractive index and the absorption coefficient. In case of known fundamental optical characteristics-refractive indices and absorption coefficients-and the way how to influence them by the preparation method, some explicit absorption criterion is necessary to characterize a thin film absorber.
Refractive indices are usually minor target of interest, special attention is mostly concentrated on absorption coefficients. However, mutual implementation of the refractive index and the absorption coefficient offers a quite different picture of absorption properties and light trapping limits.
This paper analyzes various metrics to review optical absorption and consider how it can be changed in thin films with different refractive indices and absorption coefficients. The objective of the analysis is a series of Si:H thin films PECVD deposited under increasing hydrogen to silane gas flows that cause the phase transition from amorphous to microcrystalline structure with crystalline grains of~9 nm and a certain degree of porosity. Absorption metrics used for the comparison are the absorption coefficient, single pass absorption, optical path length, classical light trapping limit and the Yablonovitch absorptance. The results are compared and correlated with the thin film microstructure.

Materials, Microstructure and Optical Characterization
A series of thin undoped Si:H films was deposited from silane (SiH 4 ) and argon (Ar) plasma on clean EAGLE 2000 glass substrates (Corning, Corning, NY, USA) by a 13.56 MHz rf excited parallel plate PECVD PD-220N system (SAMCO, Kyoto, Japan). Additional hydrogen (H 2 ) was added to SiH 4 +Ar to provide different dilutions of silane plasma flow to hydrogen flow defined as R = (H 2 )/(SiH 4 ). The dilutions applied to the sample series varied in the wide range from 0 (no additional hydrogen) to 70. To avoid the thicknessdependent deposition of Si:H, the thickness of the films was kept at approximately 400 nm. More details on the deposition conditions are in [19] where also prior studies on samples structure and microstructure were published. XRD, Raman scattering analysis and FTIR spectroscopy show that at dilutions R ≤ 30 the thin films consist of amorphous a-Si:H. At depositions with dilutions R > 30 material transforms to microcrystalline µc-Si:H. Volume fraction ratios of crystalline to amorphous phase p c /p a determined from XRD analysis are in Table 1. Table 1. Sample characterization: d thickness by UV Vis, p c p a crystalline/amorphous phase volume fraction ratio, p porosity, n ∞ refractive index in the long-wavelength limit, all from [19], c H hydrogen concentration according to FTIR, L R crystallite size according to Raman scattering, λ b benchmark wavelength, A Yint integrated direct Yablonovitch absorptance. FTIR spectra show hydrogen bonding in two stretching vibrational modes corresponding to monohydrides in small volumes of vacancies (~2000 cm −1 ) and dihydrides at internal surfaces of voids or at the boundaries between the crystalline grains (~2100 cm −1 ). The ratio of hydrogen bonded in dihydrides to the total bonded hydrogen is the microstructural factor. High values of this factor indicate the porosity of the samples [19] that was determined by the method described in [20].
The concentration c H of bonded hydrogen was determined from the stretching vibrations by the procedure described in [20]. The values of c H in atomic % in Table 1 show that after increasing the crystalline phase volume fraction at R = 40 and higher, µc-Si:H samples suddenly receive less hydrogen than a-Si:H. This result confirms the dominating role of hydrogen in a-Si:H in compensating the defects, relaxing the strained a-Si network, improving medium-range order and assisting crystallization. Overall low values of hydrogen concentration can be caused by the presence of Ar ions at the deposition that reconstruct Si network [21].
The decomposition of baseline corrected Raman scattering spectra in the region of 450-520 cm −1 revealed peaks at~450 and 480 cm −1 corresponding to amorphous phase in a-Si:H and additional peaks at 510 and 520 cm −1 corresponding to grain boundaries and crystalline components in µc-Si:H [22]. The crystalline grain size can be calculated from the shift of the peak at 520 cm −1 according to the formula L R = 88.43 − |ν − 520.7| [23] where ν is the position of the transverse optical mode with respect to the crystalline Si peak position of 520.7 cm −1 . The values of L R~9 nm are similar for all µc-Si:H samples that then differ only by the individual phase volume fractions.
Optical transmittance spectra in the wavelength range of (430 ÷ 1100) nm at nearly normal incidence were recorded by a Specord 210 spectrophotometer (Analytic Jena, Jena, Germany) and processed by optimization procedure based on genetic algorithm described in [19] to obtain the wavelength-dependent complex refractive indexn = n + ik, where the refractive index n and the extinction coefficient k are the real and imaginary parts ofn.
In the used optimization model the thin film was considered homogeneous with parallel smooth interfaces. The absorption coefficients α are related to k as α = 4πk/λ where λ is the wavelength. The results of n, α are in Figures 1 and 2. The thickness d of the samples was determined from optimization of spectral transmittance, too (Table 1).
improving medium-range order and assisting crystallization. Overall low values of hydrogen concentration can be caused by the presence of Ar ions at the deposition that reconstruct Si network [21].
The decomposition of baseline corrected Raman scattering spectra in the region of 450-520 cm −1 revealed peaks at ~450 and 480 cm −1 corresponding to amorphous phase in a-Si:H and additional peaks at 510 and 520 cm −1 corresponding to grain boundaries and crystalline components in μc-Si:H [22]. The crystalline grain size can be calculated from the shift of the peak at 520 cm −1 according to the formula L R = 88.43 − | ̅ − 520.7| [23] where ̅ is the position of the transverse optical mode with respect to the crystalline Si peak position of 520.7 cm −1 . The values of LR ~9 nm are similar for all μc-Si:H samples that then differ only by the individual phase volume fractions.
Optical transmittance spectra in the wavelength range of (430 ÷ 1100) nm at nearly normal incidence were recorded by a Specord 210 spectrophotometer (Analytic Jena, Jena, Germany) and processed by optimization procedure based on genetic algorithm described in [19] to obtain the wavelength-dependent complex refractive index = + , where the refractive index n and the extinction coefficient k are the real and imaginary parts of . In the used optimization model the thin film was considered homogeneous with parallel smooth interfaces. The absorption coefficients α are related to k as = 4 / where is the wavelength. The results of n, are in Figures 1 and 2. The thickness d of the samples was determined from optimization of spectral transmittance, too ( Table 1).
The refractive index apparently decreases with increasing dilution (Figure 1). Its extrapolation to the non-absorbing region provides the so-called refractive index in the longwavelength limit related to the atomic structure and the mass density of the sample. The values of decrease with increasing dilution according to Table 1 what indicates the decreasing density of the samples.  Absorption coefficients in Figure 2 are clearly divided into two groups according to the structure. The transition from a-Si:H to μc-Si:H shown clearly in microstructural characteristics is responsible for this division indicating the threshold of forming crystalline grains and thus material with prevailing crystalline phase under increasing amount of hydrogen at deposition. Due to the crystalline grains in μc-Si:H thin films, internal scattering effect may contribute to the absorption coefficients [24,25]. As it can be expected absorption edges of μc-Si:H are obviously shifted to lower photon energies (i.e., higher wavelengths) in comparison to a-Si:H, so μc-Si:H absorbs red and near IR light better. Optical band gaps of these mixed-phase thin films based on several approaches were also reported [19,26].
The comparison of the areas under the curves of absorption coefficients depicted in Figure 2 shows that a-Si:H thin films under study are better absorbers per cm −1 than μc-Si:H thin films over the visible and near IR region.  photon energy (eV) The refractive index apparently decreases with increasing dilution (Figure 1). Its extrapolation to the non-absorbing region provides the so-called refractive index in the long-wavelength limit n ∞ related to the atomic structure and the mass density of the sample. The values of n ∞ decrease with increasing dilution according to Table 1 what indicates the decreasing density of the samples. Absorption coefficients in Figure 2 are clearly divided into two groups according to the structure. The transition from a-Si:H to µc-Si:H shown clearly in microstructural characteristics is responsible for this division indicating the threshold of forming crystalline grains and thus material with prevailing crystalline phase under increasing amount of hydrogen at deposition. Due to the crystalline grains in µc-Si:H thin films, internal scattering effect may contribute to the absorption coefficients [24,25].

Results and Discussion
As it can be expected absorption edges of µc-Si:H are obviously shifted to lower photon energies (i.e., higher wavelengths) in comparison to a-Si:H, so µc-Si:H absorbs red and near IR light better. Optical band gaps of these mixed-phase thin films based on several approaches were also reported [19,26].
The comparison of the areas under the curves of absorption coefficients depicted in Figure 2 shows that a-Si:H thin films under study are better absorbers per cm −1 than µc-Si:H thin films over the visible and near IR region.

Results and Discussion
The absorption coefficient α(λ) is a material property related to the penetration of light of a specific wavelength λ into a material. However, generally said, as the thickness of individual thin films and reflections at interfaces may differ, deeper comprehension may be helpful. Several metrics are usually available for considering light absorption abilities.

Single Pass Absorption and Optical Path Length
A metric to express how much light is absorbed before reaching the bottom interface of a thin film of the thickness d is the single pass absorption A singlepass = 1 − exp(−α(λ)d) α(λ)d while normal light incidence and homogeneous material are supposed. The normalized results are shown in Figure 3 where different A singlepass of four a-Si:H and four µc-Si:H thin films can be distinguished. As it can be expected absorption edges of μc-Si:H are obviously shifted to lower photon energies (i.e., higher wavelengths) in comparison to a-Si:H, so μc-Si:H absorbs red and near IR light better. Optical band gaps of these mixed-phase thin films based on several approaches were also reported [19,26].
The comparison of the areas under the curves of absorption coefficients depicted in Figure 2 shows that a-Si:H thin films under study are better absorbers per cm −1 than μc-Si:H thin films over the visible and near IR region.

Results and Discussion
The absorption coefficient ( ) is a material property related to the penetration of light of a specific wavelength into a material. However, generally said, as the thickness of individual thin films and reflections at interfaces may differ, deeper comprehension may be helpful. Several metrics are usually available for considering light absorption abilities.

Single Pass Absorption and Optical Path Length
A metric to express how much light is absorbed before reaching the bottom interface of a thin film of the thickness d is the single pass absorption (λ)d while normal light incidence and homogeneous material are supposed. The normalized results are shown in Figure 3 where different Asinglepass of four a-Si:H and four μc-Si:H thin films can be distinguished.   Optical path length OPL = nd is an optical metric considering the differences of light travelling through samples of varied density expressed by the refractive index. The values of OPL calculated as n ∞ d are in Table 1 in which positive increase of OPL in µc-Si:H thin films with increasing dilution can be seen. Differences between a-Si:H and µc-Si:H are obvious. Nevertheless, there are several constraints on the usage of OPL as a figure of absorption merit, namely overlooking reflections at the interfaces and additional optical losses and interference effects.

Refractive Indices and Absorption Coefficients in Light Trapping Limits
Overall lower absorption in µc-Si:H compared to a-Si:H evokes the need to use thicker microcrystalline thin films as optical absorbers, e.g., solar cells and/or to use light trapping texturization to achieve higher absorption efficiency. Light trapping schemes are characterized by limits based on fundamental optical properties of material. Importance of the refractive index for light trapping schemes such as nanostructures or texturization is known and manifested in the so-called classical Yablonovitch light trapping limit. This limit in planar optical absorbers surrounded by isotropic medium is 4n 2 . The 4n 2 metric is acknowledged as a maximum increase of OPL concluding a factor enhancing the single pass absorption α(λ)d [27][28][29][30][31]. In thin-film solar cells classical upper light trapping limit 4n 2 is the key factor to consider achieving high power conversion efficiencies. It is widely accepted as an appropriate reference point to compare light trapping concepts, although being generally valid for a specific geometry. Figure 4 shows that there are not significant differences in normalized 4n 2 of all investigated samples regardless of their structure and therefore this does not seem to be an appropriate tool to select properly the most efficient absorber. In [31] the so-called apparent OPL (AOPL) was introduced to include trapping limit into OPL defined as AOPL = 4n 2 (nd). absorption merit, namely overlooking reflections at the interfaces and additional optical losses and interference effects.

Refractive Indices and Absorption Coefficients in Light Trapping Limits
Overall lower absorption in μc-Si:H compared to a-Si:H evokes the need to use thicker microcrystalline thin films as optical absorbers, e.g., solar cells and/or to use light trapping texturization to achieve higher absorption efficiency.
Light trapping schemes are characterized by limits based on fundamental optical properties of material. Importance of the refractive index for light trapping schemes such as nanostructures or texturization is known and manifested in the so-called classical Yablonovitch light trapping limit. This limit in planar optical absorbers surrounded by isotropic medium is 4n 2 . The 4n 2 metric is acknowledged as a maximum increase of OPL concluding a factor enhancing the single pass absorption ( ) [27][28][29][30][31]. In thin-film solar cells classical upper light trapping limit 4n 2 is the key factor to consider achieving high power conversion efficiencies. It is widely accepted as an appropriate reference point to compare light trapping concepts, although being generally valid for a specific geometry. Figure 4 shows that there are not significant differences in normalized 4n 2 of all investigated samples regardless of their structure and therefore this does not seem to be an appropriate tool to select properly the most efficient absorber. In [31] the so-called apparent OPL (AOPL) was introduced to include trapping limit into OPL defined as AOPL = 4n 2 (nd). In Figure 5 we can see the normalized AOPL. The differences between the samples are better distinguished and favouring μc-Si:H in comparison with a-Si:H. In comparison with single pass absorption (Figure 3), AOPLs including light trapping limit are well shifted to higher wavelengths.
As the refractive index is wavelength-dependent, 4n 2 in Figure 5 is also wavelengthdependent. To acquire one numerical value to estimate the trapping limit, can be applied. Table 1 shows 4 , i.e., the classical Yablonovitch limit calculated with . This metric also obviously favours a-Si-H deposited at lower dilutions R = 10 or 20 over μc-Si:H.  In Figure 5 we can see the normalized AOPL. The differences between the samples are better distinguished and favouring µc-Si:H in comparison with a-Si:H. In comparison with single pass absorption (Figure 3), AOPLs including light trapping limit are well shifted to higher wavelengths. The major limitation of 4n 2 and AOPL metrics is that they apply only in weakly absorbing region and therefore can be confusing. A practical extension of this approach accommodating also higher absorption regions is the direct absorptance according to the Yablonovitch concept defined as [32]: As the refractive index is wavelength-dependent, 4n 2 in Figure 5 is also wavelengthdependent. To acquire one numerical value to estimate the trapping limit, n ∞ can be applied. Table 1 shows 4n ∞ 2 , i.e., the classical Yablonovitch limit calculated with n ∞ . This metric also obviously favours a-Si-H deposited at lower dilutions R = 10 or 20 over µc-Si:H. The major limitation of 4n 2 and AOPL metrics is that they apply only in weakly absorbing region and therefore can be confusing. A practical extension of this approach accommodating also higher absorption regions is the direct absorptance according to the Yablonovitch concept defined as [32]: where A(λ) assumes perfect antireflections and perfect Lambertian light trapping with the 4n 2 limit of the OPL enhancement [27,28]. It can be used to consider the light trapping limit, e.g., in sensing, photodetecting or photovoltaics [33][34][35][36]. Figure 6 shows that A(λ) better distinguishes between the members of the series and apparently organizes them in two separate groups of a-Si:H and µc-Si:H again. On the other hand, µc-Si:H Yablonovitch absorptance (R > 30) is desirably shifted to higher wavelengths similarly than optical band gaps. Then we can conclude that µc-Si:H members of the series have better prospects for light trapping. Although in this metric also the thickness d enters the calculation, similar thicknesses of 8 members of the series cannot be responsible for the apparent separation of a-Si:H and µc-Si:H thin films in Figure 6. Therefore, in spite of the fact that a-Si:H thin films are in general better in absorption coefficients, the Yablonovitch absorptance limits of µc-Si:H are higher and better light trapping can be expected in µc-Si:H thin films deposited under dilutions R > 30. The major limitation of 4n 2 and AOPL metrics is that they apply only in weakly absorbing region and therefore can be confusing. A practical extension of this approach accommodating also higher absorption regions is the direct absorptance according to the Yablonovitch concept defined as [32]: where ( ) assumes perfect antireflections and perfect Lambertian light trapping with the 4 limit of the OPL enhancement [27,28]. It can be used to consider the light trapping limit, e.g., in sensing, photodetecting or photovoltaics [33][34][35][36]. Figure 6 shows that ( ) better distinguishes between the members of the series and apparently organizes them in two separate groups of a-Si:H and μc-Si:H again. On the other hand, μc-Si:H Yablonovitch absorptance (R > 30) is desirably shifted to higher wavelengths similarly than optical band gaps. Then we can conclude that μc-Si:H members of the series have better prospects for light trapping. Although in this metric also the thickness d enters the calculation, similar thicknesses of 8 members of the series cannot be responsible for the apparent separation of a-Si:H and μc-Si:H thin films in Figure 6. Therefore, in spite of the fact that a-Si:H thin films are in general better in absorption coefficients, the Yablonovitch absorptance limits of μc-Si:H are higher and better light trapping can be expected in μc-Si:H thin films deposited under dilutions R > 30.  A(λ) from Figure 6 integrated over the wavelength range of (430 ÷ 1100) nm denoted as the integrated direct Yablonovitch absorptance A Yint is listed in Table 1 as a figure of merit of the overall Yablonovitch absorptance. Although direct absorptances A(λ) of a-Si:H (R ≤ 30) thin films are closer to a perfect step function, the amount of absorbed photons proportional to the integrated area under the curves can be obviously higher for µc-Si:H.
The benchmark wavelength λ b introduced in [29] is another criterion of light trapping scheme. It is defined as a wavelength at which the direct Yablonovitch absorptance A(λ b ) = 0.5, what according to Equation (1) means 4n 2 (λ b )d = 1. At wavelengths < λ b the absorption is relatively high and light trapping is not very essential. For wavelengths > λ b the direct absorptance decreases and light trapping is of practical importance. From Table 1 an opposite influence of increasing dilution for a-Si:H and µc-Si:H on λ b implies that λ b may be connected mainly with the microstructure.
The importance of the direct Yablonovitch absorptance is clearly seen in considering the absorption of solar light in solar cells or sensors based on solar light absorption, e.g., motion sensors. A merit of the suitability of a thin film absorber of solar light is the spectrum of A(λ) S AM1.5g (λ). S AM1.5g (λ) is the AM1.5 reference solar global spectral irradiance Coatings 2021, 11, 1081 7 of 10 according to ASTM G173-03 [37]. In solar cells A(λ) S AM1.5g is directly proportional to the photo-generated current density and correlating with solar cell efficiency.
The spectrum of A(λ) S AM1.5g (λ) is related to the spectral solar global irradiance absorbed by the sample. Better performance of µc-Si:H is obvious from Figure 7 where relative values of A(λ) S AM1.5g (λ) versus the wavelength are presented.
> the direct absorptance decreases and light trapping is of practical importance. From Table 1 an opposite influence of increasing dilution for a-Si:H and μc-Si:H on implies that may be connected mainly with the microstructure. The importance of the direct Yablonovitch absorptance is clearly seen in considering the absorption of solar light in solar cells or sensors based on solar light absorption, e.g., motion sensors. A merit of the suitability of a thin film absorber of solar light is the spectrum of A(λ) . ( ). . ( ) is the AM1.5 reference solar global spectral irradiance according to ASTM G173-03 [37].

In solar cells A(λ)
. is directly proportional to the photo-generated current density and correlating with solar cell efficiency.
The spectrum of A(λ) . ( ) is related to the spectral solar global irradiance absorbed by the sample. Better performance of μc-Si:H is obvious from Figure 7 where relative values of A(λ) . ( ) versus the wavelength are presented.

Absorption Characteristics Versus Thin Film Structure and Microstructure
For the thin films under study, it is reasonable to correlate the results on absorption with changes in structure and microstructure under increasing additional hydrogen at the deposition. Thin films of a-Si:H, μc-Si:H as well as nanocrystalline Si:H under hydrogen incorporation are often reported as mixed-phase silicon [38,39] whereas the exact phase structure apparently influences the optical properties. The samples under study were also found to be mixed-phase materials containing microvoids inducing sample porosity [19].
According to our previous study we expect the microvoids of subnanometer range [20]. In μc-Si:H samples the crystalline grain size of ~9 nm derived from Raman scattering spectra is approximately the same, but the crystalline volume fraction and porosity differ. The transition from a-Si:H to μc-Si:H is accompanied by sharp change of crystalline volume fraction and hydrogen content decrease and therefore also absorption coefficients (Figure 2), Yablonovitch absorptances ( Figure 6) and relative absorptances of solar global spectral irradiance (Figure 7) manifest an abrupt change.

Absorption Characteristics versus Thin Film Structure and Microstructure
For the thin films under study, it is reasonable to correlate the results on absorption with changes in structure and microstructure under increasing additional hydrogen at the deposition. Thin films of a-Si:H, µc-Si:H as well as nanocrystalline Si:H under hydrogen incorporation are often reported as mixed-phase silicon [38,39] whereas the exact phase structure apparently influences the optical properties. The samples under study were also found to be mixed-phase materials containing microvoids inducing sample porosity [19].
According to our previous study we expect the microvoids of subnanometer range [20]. In µc-Si:H samples the crystalline grain size of~9 nm derived from Raman scattering spectra is approximately the same, but the crystalline volume fraction and porosity differ. The transition from a-Si:H to µc-Si:H is accompanied by sharp change of crystalline volume fraction and hydrogen content decrease and therefore also absorption coefficients (Figure 2), Yablonovitch absorptances ( Figure 6) and relative absorptances of solar global spectral irradiance ( Figure 7) manifest an abrupt change.
Porosity of the samples defined as the void volume fraction ratio was calculated applying refractive indices and crystalline/amorphous phase volume fraction ratio p c /p a from XRD studies upon Bruggeman effective medium theory (Table 1) [19].
The correlation of the porosity and absorption shows that increased porosity causes the increase of the integrated direct Yablonovitch absorptance A Yint after the transition from a-Si:H to µc-Si:H occurs (Figure 8). On the contrary, AOPL shows opposite behavior in and below the transition region of the dilutions R = (30 ÷ 40) ( Table 1). AOPL based on the refractive index follows the decreasing refractive index with increasing dilution that is accompanied with increasing porosity (Figure 9). It is the direct evidence that selected absorption metrics must be interpreted in terms of involved fundamental optical properties-refractive indices and/or absorption coefficients. from a-Si:H to μc-Si:H occurs (Figure 8). On the contrary, AOPL shows opposite behavior in and below the transition region of the dilutions R = (30 ÷ 40) ( Table 1). AOPL based on the refractive index follows the decreasing refractive index with increasing dilution that is accompanied with increasing porosity (Figure 9). It is the direct evidence that selected absorption metrics must be interpreted in terms of involved fundamental optical properties-refractive indices and/or absorption coefficients.

Conclusions
This paper presents the absorption analysis of Si:H thin film PECVD deposited from silane under varied dilution of hydrogen. The investigation is based on the fact that single thin films absorbers can serve as light trapping tools due to coherent reflections at interfaces of an absorbing material with appropriate absorption coefficients and refractive indices. Moreover, thin films offer a simplified design and the absorption response can be engineered by deposition conditions. in and below the transition region of the dilutions R = (30 ÷ 40) ( Table 1). AOPL based on the refractive index follows the decreasing refractive index with increasing dilution that is accompanied with increasing porosity (Figure 9). It is the direct evidence that selected absorption metrics must be interpreted in terms of involved fundamental optical properties-refractive indices and/or absorption coefficients.

Conclusions
This paper presents the absorption analysis of Si:H thin film PECVD deposited from silane under varied dilution of hydrogen. The investigation is based on the fact that single thin films absorbers can serve as light trapping tools due to coherent reflections at interfaces of an absorbing material with appropriate absorption coefficients and refractive indices. Moreover, thin films offer a simplified design and the absorption response can be engineered by deposition conditions.

Conclusions
This paper presents the absorption analysis of Si:H thin film PECVD deposited from silane under varied dilution of hydrogen. The investigation is based on the fact that single thin films absorbers can serve as light trapping tools due to coherent reflections at interfaces of an absorbing material with appropriate absorption coefficients and refractive indices. Moreover, thin films offer a simplified design and the absorption response can be engineered by deposition conditions.
The results demonstrate clearly that investigated a-Si:H and µc-Si:H thin films of different optical properties and thickness absorb light in a distinct way. Several absorption metrics were adopted to consider the differences and the correlation with the microstructure. It was found out that the absorption metrics based only on the refractive index such as optical path length are not informative enough and therefore not recommended as decision-makers for absorption-based applications such as photodiodes, sensors, solar cells, etc. According to the results the direct Yablonovitch absorptance should be advised to distinguish between thin film optical absorbers. The classical light trapping limit and the Yablonovitch absorptance show that in µc-Si:H better light trapping can be expected.