Effects of Chromic Treatment on the Surface Properties of Polypropylene (PP) Wood Composites

: The moisture sensitivity of wood–polymer composites (WPCs) is mainly related to their hydrophilic wood components. Coatings are among the alternatives that improve the dimensional stability of these composites. However, the adhesion of most coatings to the WPC surface is generally poor. Thus, chemical and/or mechanical treatments should be applied to the WPC surface to improve the coating adhesion. Therefore, the main objective of this study was to improve the adhesion coating of polypropylene (PP) WPCs through a chromic treatment. PP was reinforced by three different pulp ﬁbers (kraft, thermomechanical (TMP), and chemothermomechanical (CTMP)) at three ﬁber contents (50, 60, and 70% w / w ). A chromic treatment was applied to the PP-based WPCs to activate the surface of the composites and alter their roughness parameters, creating a higher interfacial zone that improved the bonding of the epoxy coating to the surface of the PP composites. The chromic treatment increased the roughness of the surface. An increase in proﬁle and surface parameters was observed after treatment. This treatment modiﬁed the chemical composition of the surface by creating polar carbon–oxygen groups and increasing the carbonyl and hydroxyl indexes.


Introduction
Wood-polymer composites (also called wood-plastic composites, WPCs) are materials that combine two or more distinct components: the polymer as a matrix and the lignocellulosic fiber as reinforcement. The use of WPCs in humid environments requires good resistance to water absorption and swelling. Their sensitivity to moisture is mainly due to the presence of hydroxyl groups from the lignocellulosic components [1]. To improve WPC behavior for exterior use, it is relevant to consider protective coatings. However, knowledge of the surface properties of the composite is essential for the development of a suitable coating system. Indeed, adhesive bonding is necessary for the assembly of WPCs and the application of coatings. WPCs have low surface energy and poor adhesion properties. In this respect, the adhesion of the coating to a WPC can be improved by surface pretreatments, especially for composites that contain polyolefins as their contact surface is not active. The most effective surface treatments increase surface energy (especially the polar component) and produce surface oxidation. The improvement of the adhesion of WPCs depends on wood content, the nature of the polymer, and surface roughness [2].
The most effective method for improving the adhesion of the coating on a surface is to apply surface treatments, which will enhance wettability. These treatments include plasma 2 of 12 and corona techniques that activate the wood surface and improve its wettability [3]. Wolkenhauer et al. [4] reported that plasma treatment of wood surfaces is superior to sanding for increasing surface energy, which is even more important when combining the two techniques.
The surface heterogeneity and lack of adhesion of coatings to WPCs are a result of inactive plastic on the surface [2]. Polyolefins are polymers with low surface energy that do not have a polar component, making it difficult to coat plastic onto their surfaces. The surface treatment of polyolefin has been studied to improve many properties, such as adhesion, wettability, roughness, printability, transparency, and lubricity, by introducing polar groups or surface roughening. Several surface modification techniques have been applied to polyolefins, e.g., chemical etching with sulfuric acid or chromic acid, physical etching, flame, corona discharge, and plasma treatment [5]. These surface treatments have a limited lifetime and require a rapid coating of the activated surface [6].
It is expected that surface activation processes can improve coating adhesion to WPCs due to the presence of plastic on the surface. Akhtarkhavari et al. [7] reported improved paint adhesion after a surface pretreatment of compression-molded WPCs. Similarly, Oporto et al. [8] studied the shear strength of epoxy adhesive with extruded WPCs. They reported an increase in the shear strength of both wet and dry adhesives after sanding and flame treatment. To date, there has been little systematic evaluation of potential surface activation techniques on the adhesion of coatings to WPCs.
The surface inactivity of WPCs is mainly attributed to the hydrophobic nature of the polymer matrices, whose effect is more noticeable than the wood content. Gupta et al. [2] listed surface activation pretreatment methods that improve adhesion properties: oxygen plasma treatment, chromic acid treatment, flame treatment, and UV/BP treatment. This study showed that the surface treatment of WPCs with chromic acid was the most effective due to the chemical modifications made to the surface. Gramlich et al. [9] found that surface treatment with flames, water, or a combination of the two improves the shear strength of adhesive joints made with polyolefin WPCs, but not as much as a chromic acid treatment. Yáñez-Pacios et al. [10] proposed ultraviolet (UV) and ozone treatments to improve WPCs' surface energy and peel strength. According to Mirabedini et al. [11], exposing PP films to microwave irradiation in the presence of potassium permanganate (PPM) was found to be simple and effective. It is a means to improve the wettability of the polymer surfaces. According to FTIR data, oxidation reactions can occur on the PP surface. The adhesion tests showed an increase in the bonding strength of the acrylic-based lacquer on PP samples [11].
Oporto et al. [8] studied the effect of a chromic treatment on the surface of WPCs made from pine flour and polypropylene. This treatment allowed for an increase in the oxygen content on the surfaces and showed the highest surface energy values. These results suggested that the strong bonding of WPCs with epoxy resin could be attributed to acid-based interactions. Chromic acid etching is a process for modifying the surface of polymer wood composites. The chromic solution is usually prepared by mixing dichromate and sulfuric acid at room temperature according to the ASTM D 2093 standard method [12]. Blais et al. [13] conducted a thorough study of chromic etching and suggested that surface removal rate improves with a higher temperature and longer reaction time.
Teng et al. [14] demonstrated that the surface of the wood/polyethylene composites decreased and the surface's wettability improved after liquid oxidation; the functional groups -C-O-and C=O were formed on the treated surface, and the surface roughness increased. Thus, after treatment, the shear bond strength of the treated sample increased significantly.
The adhesion of the coating to the composite also depends on the nature of the coating. The effectiveness of the WPC surface treatment also depends on the wood content, the nature of the polymer, and the surface roughness. Moghadamzadeh et al. [15] followed the evolution of oxidized groups on FTIR spectra. To this end, they focused on the carbonyl and hydroxyl group indexes calculated from the intensities of the different peaks. The peak at 3344.71 cm −1 corresponded to hydroxyl groups (-OH) bound to cellulose or hemicellulose. The peak at 2916.4 cm −1 corresponded to the (-CH) methyl and methylene groups. The 1454.39 cm −1 peak corresponded to the hydrocarbon chains of the (CH 2 ) groups.
The chromic treatment implies a manual or mechanical abrasion step, carried out using sandpaper. It is an essential step to prepare the surface. On the other hand, mechanical abrasion is one of the methods used to improve the surface activity of WPCs. This process increases the roughness and hydroxyl and wood content of the surface [16]. Indeed, the mechanical treatment effectively removes the surface layers and exposes the wood to the surface layer.
According to the literature, the chromic treatment showed the best results in surface activation compared to other techniques for surface activation. According to Table 1, the roughness parameters were more pronounced following this treatment. The chromic treatment also provided one of the lowest contact angle measurements, suggesting better wettability. Ryntz [17] compared different pretreatment methods, including chromic acid, plasma, flame, and UV. This study showed that the chromic acid treatment had a high oxygen content and subsequent total oxidation. To our knowledge, few or no studies have investigated the effect of chromic treatment on composites highly filled with paper fibers. This study allowed us to understand the effects of this treatment on the surface properties of such composites produced by an injection molding process. The main objective of this work was to study the impact of chromic pretreatment on the surface properties of polypropylene-based WPCs to improve the wettability of composites before the application of coatings. The specific objectives were to determine the effect of this treatment on the surface roughness of composites and to evaluate the effect of chromic treatment on the surface chemistry of composites.

Materials
Polypropylene (PP) (NexeoSolutions, The Woodlands, TX, USA) with a density of 0.903 g cm −3 , and a 20 g/10 min melt index, three types of fibers from three papermaking processes (kraft provided by Domtar Inc., Windsor, QC, Canada, thermomechanical (TMP) obtained from Resolu Amos, QC, Canada, and chemi-thermomechanical (CTMP) provided by the Université du Québec à Trois-Rivières, Trois Rivières, QC, Canada) at three different fiber proportions (50, 60, and 70%, weight basis) were used for WPC manufacturing. STRUKTOL ® TPW 113 from Struktol Company of America (Stow, OH, USA) was used as a coupling agent at a rate of 5% on a weight basis.

Composite Manufacturing
WPCs were manufactured according to a factorial plan where the factors were polymer fiber type (kraft, TMP, CTMP) and fiber proportion (50, 60, and 70%). A total of 9 formulations were prepared. The blends were extruded into wood-polymer pellets using a twin-screw extruder (Thermo Scientific HAAKE PolyLab OS Rheodrive 7 with Rheomex OS extruding module, Thermo Electron GmbH, Karlsruhe, Germany). The temperature profile was 160-170-180 • C, and the rotation speed was 70 rpm. The pellets were then dried for 24 h at 80 • C. The last step consisted of manufacturing standard test samples using an injection molding machine (Haitian MA600II/130, Ningbo, China).

Surface Chemical and Physical Properties
The surface chemistry of coated and uncoated WPCs was investigated by Fourier Transform Infrared Spectroscopy (FTIR), which allows the detection of chemical functions in the material via the characteristic vibrations of each chemical bond. The FTIR was performed on small composite samples using the Shimadzu IRTracer-100 spectrometer (Kyoto, Japan) equipped with an attenuated total reflectance (ATR). The FTIR was performed by applying a baseline correction under an absorption measurement mode. The number of scans was 64 with a resolution of 8 in the range of 500-4000 cm −1 . For each formulation, two measurements were taken.
Carbonyl and hydroxyl indexes were computed according to Equations (1) and (2)  Stark et al. [25] introduced the wood index (I wood) for surface cellulosic hydroxyl groups. It was measured by normalizing the cellulosic hydroxyl peak intensity at 1023.9 cm −1 for the polyolefinic vC-H stretching peak intensity at 2916.4 cm −1 (Equation (3)).
Surface roughness parameters were measured using a Keyence VK-X150 LASER confocal microscope (Itaska, IL, USA). Measured parameters were the arithmetic mean height for a roughness profile (Ra), maximal profile height (Rz), arithmetic mean height (Sa), and maximal areal height (Sz). These parameters are defined as follows [26,27]: Ra: Arithmetic mean height expressed in micrometers (µm) when sampling only the reference length from the roughness curve in the direction of the mean line, taking the X-axis in the direction of the mean line and the Y-axis in the direction of longitudinal magnification of this sampled part, and the roughness curve is expressed by y = Z(x) (Equation (4)).
lr: Sampling length Rz: The maximum height of the profile indicates the absolute vertical distance between the maximum profile peak height and the maximum profile valley depth along the sampling length (Equation (5)).
Rv: Maximum profile valley depth (for a roughness profile); Rp: Maximum profile peak height (for a roughness profile). The arithmetic mean height (Sa) is the mean of the absolute value of the height of points within the defined area (Equation (6)).
Sz: This parameter is defined as the sum of the largest peak height value and the largest pit depth value within the defined area (Equation (7)).
Sp: maximum peak height; Sv: maximum pit height.

Contact Angle
A Goniometer (DataPhysics company model OCA 15EC; Filderstadt, Germany) was used to perform the contact angle measurements. The images were analyzed with SCA 26 software. The contact angle measurement accuracy is ±3 • . Three repetitions were performed for each formulation (9 formulations * 2 treatments (untreated, treated) * 3 repetitions).

Statistical Analysis
The surface properties (Ra, Rz, Sa, and Sz), chemical properties (carbonyl, hydroxyl, and wood indexes), and contact angle were subjected to an analysis of variance using the ANOVA procedure and customized factorial model using the SAS statistical package, version 9.4 (SAS, 2008). Studied factors were fiber type (kraft, CTMP, and TMP), fiber proportion (0, 50, 60, and 70%), and treatment (untreated and chromic treatment). All factors were considered fixed. Effects and differences between means were considered statistically significant at p < 0.05. A graphical analysis of the residuals verified the variance homogeneity, and no transformation was used.

Analysis of Variance
The analysis of variance (Table 2) investigated the impact of the studied factors (fiber type, fiber proportion, and treatment) and their interactions on the roughness parameters, surface chemistry, and contact angle. The carbonyl, hydroxyl, wood indexes, and the contact angle all significantly varied with the fiber type and proportion changes, and  (Table 2). Regarding the surface properties, only the fiber content and the treatment had highly significant effects (α = 0.0001). This indicates that the chromic treatment had a significant effect on the surface roughness of the composites.

Effect of Chromic Treatment on Surface Chemistry
The surface chromic treatment led to important increases in the carbonyl (Figure 1a) and hydroxyl (Figure 1b) indexes of kraft and TMP composites. For the CTMP composites, both indexes increased for the 70% fiber WPC, remained constant for the 60% fiber content WPC, and decreased for the 50% fiber content composites.
It has been proven that the reaction mechanism of chromium VI in the chromic acid solution on the surface is the cross-linking and cleavage of the PP polymer chain [28]. Specifically, the wood index designates the quantity of wood present on the surface [25], which is the ratio of the two peaks of the spectrum at 2916.4 and 1033.89 cm −1 (Equation (5)) associated with the wood and polymer, respectively. The wood index increased with fiber proportion and decreased after the chromic treatment (Figure 1c).
The wood index dropped considerably after the chromic treatment, showing that PP-based composites have a surface layer that is rich in the polymer. This index increases with the fiber content and is more important in the case of kraft-based WPCs. This can be explained by the higher cellulose content in the kraft fiber compared to TMP and CTMP fibers. However, after chromic treatment, the wood index decreased for all formulations since the wood component was less exposed at the surface. There was also a decrease in the OH-band intensity of the wood component at 3344.7 cm −1 , indicating that the treated WPC surface was enriched with PP. This can be explained by the treatment temperature and its corrosive effect on the wood component.
The FTIR spectra for TMP-filled WPCs (Figure 2) showed the formation of a new C=O band at 1712.9 cm −1 , and a new C-O-C band appeared at 1253.8 cm −1 for TMP-based WPCs, showing more pronounced oxidation of the surfaces and higher polarity [29].
The results above indicate that the chromic treatment of PP-based WPCs limited the exposition of the wood chemical groups at the surface and exposed PP. Therefore, this treatment significantly changed the chemical composition of the surface. An improvement in oxidation is creating new carbon-oxygen polar groups and increasing the carbonyl and hydroxyl indexes.
with the fiber content and is more important in the case of kraft-based WPCs. This can be explained by the higher cellulose content in the kraft fiber compared to TMP and CTMP fibers. However, after chromic treatment, the wood index decreased for all formulations since the wood component was less exposed at the surface. There was also a decrease in the OH-band intensity of the wood component at 3344.7 cm −1 , indicating that the treated WPC surface was enriched with PP. This can be explained by the treatment temperature and its corrosive effect on the wood component. The FTIR spectra for TMP-filled WPCs (Figure 2) showed the formation of a new C=O band at 1712.9 cm −1 , and a new C-O-C band appeared at 1253.8 cm −1 for TMP-based WPCs, showing more pronounced oxidation of the surfaces and higher polarity [29].
The results above indicate that the chromic treatment of PP-based WPCs limited the exposition of the wood chemical groups at the surface and exposed PP. Therefore, this treatment significantly changed the chemical composition of the surface. An improvement in oxidation is creating new carbon-oxygen polar groups and increasing the carbonyl and hydroxyl indexes. Similar findings were reported by Mohamed et al. [24] when they compared the effects of different surface treatments on the chemical properties of composites. Their study mentioned that the chromic treatment led to the apparition of three new FTIR peaks, which were 3360 (-OH band), 1610 = (-C=O), and 1065 cm −1 (-CO band) compared to untreated composites. These newly generated polar groups were of great benefit to the wettability and adhesion ability of wood/PE composites [24].
Gupta et al. [2] reported that the flame, UV/BP, and chromic treated WPCs have a similar O=C/C-H ratio to the untreated WPCs, not only due to the fact that oxidation did Similar findings were reported by Mohamed et al. [24] when they compared the effects of different surface treatments on the chemical properties of composites. Their study mentioned that the chromic treatment led to the apparition of three new FTIR peaks, which were 3360 (-OH band), 1610 = (-C=O), and 1065 cm −1 (-CO band) compared to untreated composites. These newly generated polar groups were of great benefit to the wettability and adhesion ability of wood/PE composites [24].
Gupta et al. [2] reported that the flame, UV/BP, and chromic treated WPCs have a similar O=C/C-H ratio to the untreated WPCs, not only due to the fact that oxidation did not occur but also likely owing to the higher concentration of the polyolefin (C-H) on the surface. Their study found that the chromic and UV/BP treatments showed the lowest OH-CH ratios (1.01 and 1.25, respectively).  Figures 3 and 4 show that roughness values depend on the type and content of the fibers before the chromic treatment. Indeed, the addition of fiber results in a rougher surface. A 5 and 25% increase in Ra (Figure 3a) and Sa (Figure 4a), respectively, can be seen when switching from pure polymer to a 50% kraft fiber-reinforced composite. Moreover, when increasing the fiber content, the roughness parameters evolve proportionally as the fiber content at the surface increases. Furthermore, kraft fiber-reinforced composites have the roughest surfaces. These results are consistent with the wood index results (Figure 1c) since kraft-based WPCs showed the highest indexes. As shown in Figures 3 and 4, a chromium treatment increases surface roughness. Indeed, the profile parameters (Ra and Rz) shown in Figure 3 and the surface parameters (Sa and Sz) shown in Figure 4 follow the same trend. Remarkably, the transition from a pure matrix to a high-fiber composite promotes roughness, with all composites having higher roughness values than pure PP.

Effect of Chromic Treatment on Topography and Roughness
Untreated composites showed a variation in all roughness parameters. The increase in fiber content increased Ra, Rz, Sa, and Sz. Ayrilmis et al. [30] reported that the rise in wood fiber content significantly increased the surface roughness of WPC samples. This was mainly attributed to the anatomical structure of the wood particles, such as caves (vessels and cell lumens). However, the nature of the fiber did not present an important change factor. Sieminsky et al. [31] reported that the wood species influenced the surface roughness properties. The surface roughness of high-density hardwoods was lower than that of low-density softwoods. This can be explained by the wood index, which remains almost uniform, regardless of fiber type and content after treatment. The Ra value for the untreated PP-composites filled with 50% CTMP increased from 2.07 to 4.84 µm after chromium treatment. The AFM and the profilometer showed higher amounts of roughness for all four parameters. Thus, the chromic acid treatment considerably increased WPC surface roughness. The chromic treatment probably resulted in cracks, pores, and surface pitting on the WPC surface. Moreover, the surface roughness caused a higher interfacial zone for bonding with the coating [2].  Figures 3 and 4 show that roughness values depend on the type and content of the fibers before the chromic treatment. Indeed, the addition of fiber results in a rougher surface. A 5 and 25% increase in Ra ( Figure 3a) and Sa (Figure 4a), respectively, can be seen when switching from pure polymer to a 50% kraft fiber-reinforced composite. Moreover, when increasing the fiber content, the roughness parameters evolve proportionally as the fiber content at the surface increases. Furthermore, kraft fiber-reinforced composites have the roughest surfaces. These results are consistent with the wood index results (Figure 1c) since kraft-based WPCs showed the highest indexes. As shown in Figures 3 and 4, a chromium treatment increases surface roughness. Indeed, the profile parameters (Ra and Rz) shown in Figure 3 and the surface parameters (Sa and Sz) shown in Figure 4 follow the same trend. Remarkably, the transition from a pure matrix to a high-fiber composite promotes roughness, with all composites having higher roughness values than pure PP.

Effect of Chromic Treatment on Topography and Roughness
Untreated composites showed a variation in all roughness parameters. The increase in fiber content increased Ra, Rz, Sa, and Sz. Ayrilmis et al. [30] reported that the rise in wood fiber content significantly increased the surface roughness of WPC samples. This was mainly attributed to the anatomical structure of the wood particles, such as caves (vessels and cell lumens). However, the nature of the fiber did not present an important change factor. Sieminsky et al. [31] reported that the wood species influenced the surface roughness properties. The surface roughness of high-density hardwoods was lower than that of low-density softwoods. This can be explained by the wood index, which remains almost uniform, regardless of fiber type and content after treatment. The Ra value for the untreated PP-composites filled with 50% CTMP increased from 2.07 to 4.84 µm after chromium treatment. The AFM and the profilometer showed higher amounts of roughness for all four parameters. Thus, the chromic acid treatment considerably increased WPC surface roughness. The chromic treatment probably resulted in cracks, pores, and surface pitting on the WPC surface. Moreover, the surface roughness caused a higher interfacial zone for bonding with the coating [2]. The apparition of a new hydrophilic band and a higher amount of roughness demonstrated the efficiency of the chromic treatment. Mohamed et al. [24] measured the contact angle of composites treated with chromic acid, benzophenone/ultraviolet, and flame and heat. The chromic acid-treated WPCs showed the lowest contact angle, which indicated an enhancement of the hydrophilic character of the WPC surface. This could be attributed to the fact that chromic acid treatment functionalizes the WPC surface via an oxidative mechanism. In addition to their impact on WPC hydrophobicity, chromic treatments also affect adhesion. Indeed, Mohamed et al. [24] reported that the adhesion of WPCs treated with chromic acid is much higher than WPCs treated with the other two treatment methods. Gramlich et al. [9] found that chromic acid and flame retardment treatments caused the oxidation of both PP and wood, respectively, thus showing better WPC/epoxy bond strength. By increasing the fiber content in treated composites, the roughness values slightly varied. The apparition of a new hydrophilic band and a higher amount of roughness demonstrated the efficiency of the chromic treatment. Mohamed et al. [24] measured the contact angle of composites treated with chromic acid, benzophenone/ultraviolet, and flame and heat. The chromic acid-treated WPCs showed the lowest contact angle, which indicated an enhancement of the hydrophilic character of the WPC surface. This could be attributed to the fact that chromic acid treatment functionalizes the WPC surface via an oxidative mechanism. In addition to their impact on WPC hydrophobicity, chromic treatments also affect adhesion. Indeed, Mohamed et al. [24] reported that the adhesion of WPCs treated with chromic acid is much higher than WPCs treated with the other two treatment methods. Gramlich et al. [9] found that chromic acid and flame retardment treatments caused the oxidation of both PP and wood, respectively, thus showing better WPC/epoxy bond strength. By increasing the fiber content in treated composites, the roughness values slightly varied.
Gupta et al. [2] compared the surface roughness of treated WPCs with chromic acid, oxygen plasma, flame, and UV/benzophenone (BP) treatments. The highest results were observed in WPCs treated with chromic acid (5.22 ± 2.3 Å). Surface roughness causes a higher interfacial area for bonding, and possibly greater energy dissipation mechanisms for plastics. A significant increase in surface oxidation was reported in plasma-treated WPCs, and a related increase in wettability was observed. According to Gupta et al. [2], chromic treated WPCs clearly display larger variations in surface roughness than plasma (1.99 ± 0.6 Å), BP/UV (2.48 ± 0.6 Å), or flame (3.4 ± 1.9 Å) treatments. Gupta et al. [2] showed that UV/BP and plasma-treated WPCs have a similar topography to the untreated composites.  Gupta et al. [2] compared the surface roughness of treated WPCs with chromic acid, oxygen plasma, flame, and UV/benzophenone (BP) treatments. The highest results were observed in WPCs treated with chromic acid (5.22 ± 2.3 Å). Surface roughness causes a higher interfacial area for bonding, and possibly greater energy dissipation mechanisms for plastics. A significant increase in surface oxidation was reported in plasma-treated WPCs, and a related increase in wettability was observed. According to Gupta et al. [2], chromic treated WPCs clearly display larger variations in surface roughness than plasma (1.99 ± 0.6 Å), BP/UV (2.48 ± 0.6 Å), or flame (3.4 ± 1.9 Å) treatments. Gupta et al. [2] showed that UV/BP and plasma-treated WPCs have a similar topography to the untreated composites.

Effect of Chromic Treatment on Contact Angle
The contact angles of the composites before chromic treatment were high (between 85 and 101°), which confirms that the composites are low-surface energy materials. Figure 5 shows that chromic treatment reduced the contact angle by up to 22% for composites loaded with 60% CTMP fiber. A minor decrease (about 3%) was observed for composites filled with 50% Kraft fiber.
On average, the chromic treatment reduced the contact angle values by 12%. A decrease in the contact angle resulted in better surface wettability. The work of Teng et al. [14] showed that the chromic treatment reduced the contact angle for wood-HDPE composites, and Moghadamzadeh et al. [15] noted a decrease in the contact angle from 83 to

Effect of Chromic Treatment on Contact Angle
The contact angles of the composites before chromic treatment were high (between 85 and 101 • ), which confirms that the composites are low-surface energy materials. Figure 5 shows that chromic treatment reduced the contact angle by up to 22% for composites loaded with 60% CTMP fiber. A minor decrease (about 3%) was observed for composites filled with 50% Kraft fiber.
On average, the chromic treatment reduced the contact angle values by 12%. A decrease in the contact angle resulted in better surface wettability. The work of Teng et al. [14] showed that the chromic treatment reduced the contact angle for wood-HDPE composites, and Moghadamzadeh et al. [15] noted a decrease in the contact angle from 83 to 60 • after the chromic treatment on 30% HDPE and 70% wood composites. This decrease indicated an improvement in the surface free energy and promoted the adhesion of the coatings to the composite surface. 60° after the chromic treatment on 30% HDPE and 70% wood composites. This decrease indicated an improvement in the surface free energy and promoted the adhesion of the coatings to the composite surface.

Conclusions
The chromic treatment allowed for a more pronounced oxidation of the surfaces and a higher polarity. This treatment limited most of the wood components and exposed the PP to the surface. As a result, this treatment significantly altered the chemical composition of the surface. Improved oxidation took place due to the creation of new carbon-oxygen polar groups and increasing carbonyl and hydroxyl indices. The surface roughness of WPCs increased considerably with the chromic acid treatment. Chromic treatment probably caused cracks, pores, and surface pitting on the surface of the WPCs. This surface roughness resulted in a higher interfacial zone for bonding with the coating. In addition to this, after chromic treatment, the composites showed lower contact angles, indicating that the surface became more wettable, which would promote adhesion between the coatings and the composites.