Effects of Additives Containing Cyanopyridine on Electrodeposition of Bright Al Coatings from AlCl3-EMIC Ionic Liquids
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Preparation of Ionic Liquid Electrolyte
2.3. Pretreatment
2.4. Electrodeposition of Al Coatings
2.5. Characterization
3. Results and Discussion
3.1. Voltammogram Measurements
3.2. Electrodeposition and Microstructures of Al Coatings
3.3. Corrosion Properties
3.4. Discussion
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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TC (hkl) | TC (111) | TC (200) | TC (220) | TC (311) |
---|---|---|---|---|
Al-blank | 0.99 | 1.36 | 0.57 | 0.61 |
Al-2-cyanopyridine | 0.48 | 2.38 | 0.0 | 0.0 |
Al-3-cyanopyridine | 0.34 | 2.51 | 0.0 | 0.0 |
Al-4-cyanopyridine | 0.0 | 2.84 | 0.0 | 0.0 |
Materials | Ecorr (V) | Icorr (A/cm2) |
---|---|---|
Al-blank | −0.764 | 2.9 × 10−5 |
Al-2-cyanopyridine | −0.703 | 1.02 × 10−6 |
Al-3-cyanopyridine | −1.057 | 9.88 × 10−8 |
Al-4-cyanopyridine | −1.123 | 6.34 × 10−8 |
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Zhang, M.; Peng, D.; Peng, F.; Huang, A.; Song, K.; He, Q.; Yin, C.; Rao, J.; Zhang, Y.; Chen, H.; et al. Effects of Additives Containing Cyanopyridine on Electrodeposition of Bright Al Coatings from AlCl3-EMIC Ionic Liquids. Coatings 2021, 11, 1396. https://doi.org/10.3390/coatings11111396
Zhang M, Peng D, Peng F, Huang A, Song K, He Q, Yin C, Rao J, Zhang Y, Chen H, et al. Effects of Additives Containing Cyanopyridine on Electrodeposition of Bright Al Coatings from AlCl3-EMIC Ionic Liquids. Coatings. 2021; 11(11):1396. https://doi.org/10.3390/coatings11111396
Chicago/Turabian StyleZhang, Min, Dong Peng, Feifei Peng, Anwei Huang, Kaiqiang Song, Qingbing He, Changqing Yin, Jinsong Rao, Yuxin Zhang, Haitao Chen, and et al. 2021. "Effects of Additives Containing Cyanopyridine on Electrodeposition of Bright Al Coatings from AlCl3-EMIC Ionic Liquids" Coatings 11, no. 11: 1396. https://doi.org/10.3390/coatings11111396