Physical Experiment and Numerical Simulation on Thermal Effect of Aerogel Material for Steel Ladle Insulation Layer

The selection of lining material for a steel ladle is important to heat preservation of molten steel. Aerogel insulation materials have very low thermal conductivity, however, they are rarely used in steel ladles. In this paper, the application of a new silica aerogel material on the steel ladle insulation layer is tested, and a new calculation method is designed to study its insulation effect. In other words, the ladle wall temperature is obtained by finite element model (FEM) and experiments, then the heat emission from the ladle wall is calculated by the Boltzmann mathematical model according to the ladle wall temperature, and the temperature loss of molten steel is calculated inversely according to the heat emission of ladle wall. Compared with the original steel ladle (comparison ladle), the application effect is analyzed. Due to the stable heat storage of the ladle wall after refining, the validity of the models are verified in ladle furnace (LF) process. The results show that the new calculation method is feasible, and the relevant parameter settings in the FEM and Boltzmann mathematical model are correct. Finally, after using the new aerogel insulation material, the temperature of molten steel is reduced by 16.67 °C, and the production cost is reduced by CNY 5.15/ton of steel.


Introduction
In the steelmaking process, the steel ladle is an extremely important piece of equipment. It has multi-functional uses, including temporary smelting, molten steel heat preservation and transportation [1,2]. In the context of the current global advocacy of energy conservation and emission reduction, the steel ladle is particularly important for the thermal insulation effect of molten steel. When the heat preservation effect of the steel ladle is poor [3][4][5]: (1). The steel ladle dissipates more heat and the temperature of molten steel drops quickly. To increase the temperature of the molten steel, higher power consumption is necessary, which will also lead to longer power supply time and more deoxidizer consumption. The corrosion of the refractory lining is accelerated, thus the steel ladle life is reduced and the cost is significantly increased; (2). The extension of the steelmaking time has led to lower steelmaking efficiency, insufficient production capacity and increased cost; (3). The surface temperature of the steel shell is increased, which increases the thermal fatigue effect of the steel shell and significantly reduces the service life of the steel shell; (4). Rapid heat dissipation of the steel ladle leads to increased temperature fluctuations of the molten steel, which has a very adverse effect on stable continuous casting and improving the yield of continuous casting slabs. In short, the steel ladle heat preservation effect is good, and it will have a positive effect on all aspects of production. of the 2D heat transfer model and Boltzmann mathematical equation were verifie analysis process, the method used to measure the temperature of the molten steel temperature of the ladle wall, 2D heat transfer model of grid points, heat transf the boundary temperature parameter, and the selection and calculation methods parameters such as the Rayleigh number in Boltzmann mathematical model w cussed extensively. In addition, the test ladle was compared with the original terms of ladle wall temperature, molten steel temperature, steelmaking cost, temp drop rate, etc. Finally, some reasonable suggestions for a building model were pr

Composition and Morphology
SACIP was purchased from Beijing Zhongheng New Material Refractory C Beijing, China, it is a kind of high strength viscoelastic microporous insulation and it is composed of nanoscale silicon powder, metal aluminum foil, and fiber c surface is metal aluminum foil (the detailed structure is shown in Figure 2). The s × 400 × 600 mm (thickness × width × length). The finished product is shown in Fig   Figure 2. SACIP structure diagram.

Composition and Morphology
SACIP was purchased from Beijing Zhongheng New Material Refractory Co., Ltd., Beijing, China, it is a kind of high strength viscoelastic microporous insulation material and it is composed of nanoscale silicon powder, metal aluminum foil, and fiber cloth. Its surface is metal aluminum foil (the detailed structure is shown in Figure 2). The size is 10 × 400 × 600 mm (thickness × width × length). The finished product is shown in Figure 3. of the 2D heat transfer model and Boltzmann mathematical equation were verified. In the analysis process, the method used to measure the temperature of the molten steel and the temperature of the ladle wall, 2D heat transfer model of grid points, heat transfer units, the boundary temperature parameter, and the selection and calculation methods of some parameters such as the Rayleigh number in Boltzmann mathematical model were discussed extensively. In addition, the test ladle was compared with the original ladle in terms of ladle wall temperature, molten steel temperature, steelmaking cost, temperature drop rate, etc. Finally, some reasonable suggestions for a building model were presented.

Composition and Morphology
SACIP was purchased from Beijing Zhongheng New Material Refractory Co., Ltd., Beijing, China, it is a kind of high strength viscoelastic microporous insulation material and it is composed of nanoscale silicon powder, metal aluminum foil, and fiber cloth. Its surface is metal aluminum foil (the detailed structure is shown in Figure 2). The size is 10 × 400 × 600 mm (thickness × width × length). The finished product is shown in Figure 3.

Composition and Morphology
SACIP was purchased from Beijing Zhongheng New Material Refractory Co., Ltd., Beijing, China, it is a kind of high strength viscoelastic microporous insulation material and it is composed of nanoscale silicon powder, metal aluminum foil, and fiber cloth. Its surface is metal aluminum foil (the detailed structure is shown in Figure 2). The size is 10 × 400 × 600 mm (thickness × width × length). The finished product is shown in Figure 3.

Main Performance Parameters
The SACIP and OCRIP were sent to the National Refractory Quality Supervision and Inspection Center of Luoyang, China for testing. The test results are shown in Table 1.  Table 1 shows that the SACIP has high refractoriness, low bulk density and low thermal conductivity. The thermal conductivity is only 0.031 W/mK at 800 • C, which is 0.042 W/mK lower than the OCRIP.

Method of Use
The steel ladle is composed of two parts: steel shell and refractory materials. The refractory materials are built against the inner wall of the steel shell in order, which are inner (working) layer, back (safety) layer, and insulating layer. This study took 130-ton of slab steel ladle as the research object. Between the back layer and steel shell, avoiding the steel nails on the steel shell, were pasted two layers of 20 mm thickness SACIP with castable. The profile structure of the test ladle is shown in Figure 4.  Table 1 shows that the SACIP has high refractoriness, low bulk density and low thermal conductivity. The thermal conductivity is only 0.031 W/mk at 800 °C , which is 0.042 W/mk lower than the OCRIP.

Method of Use
The steel ladle is composed of two parts: steel shell and refractory materials. The refractory materials are built against the inner wall of the steel shell in order, which are inner (working) layer, back (safety) layer, and insulating layer. This study took 130-ton of slab steel ladle as the research object. Between the back layer and steel shell, avoiding the steel nails on the steel shell, were pasted two layers of 20 mm thickness SACIP with castable. The profile structure of the test ladle is shown in Figure 4. The on-site construction of SACIP is shown in Figure 5.  The on-site construction of SACIP is shown in Figure 5.

Main Performance Parameters
The SACIP and OCRIP were sent to the National Refractory Quality Supervision and Inspection Center of Luoyang, China for testing. The test results are shown in Table 1.  Table 1 shows that the SACIP has high refractoriness, low bulk density and low thermal conductivity. The thermal conductivity is only 0.031 W/mk at 800 °C , which is 0.042 W/mk lower than the OCRIP.

Method of Use
The steel ladle is composed of two parts: steel shell and refractory materials. The refractory materials are built against the inner wall of the steel shell in order, which are inner (working) layer, back (safety) layer, and insulating layer. This study took 130-ton of slab steel ladle as the research object. Between the back layer and steel shell, avoiding the steel nails on the steel shell, were pasted two layers of 20 mm thickness SACIP with castable. The profile structure of the test ladle is shown in Figure 4. The on-site construction of SACIP is shown in Figure 5.   (1). Establishment of Model Without affecting the calculation results, in order to facilitate the establishment of the model, the following assumptions were proposed [24,25]: (1). The steel ladle trunnels, bottom breathable bricks and some driving devices structural reinforcements valves have little effect on the temperature field in the FEM of steel ladle wall, so these parts are omitted in the model; (2). The contact thermal resistance between the steel ladle insulating layer and the steel shell is negligible; (3). Due to the small slope angle of the steel ladle, the steel ladle can be regarded as a cylinder after removing the mechanical parts for loading and unloading around the steel ladle; (4). The temperature of molten steel is the same everywhere in the steel ladle; (5). Because the steel ladle has axially symmetrical geometry, a part of the steel ladle wall is taken for the FEM. The thermal conductivity equation is shown in Equation (1).
where λ is the thermal conductivity of the material, W/mK; T is the temperature, K; r is the normal distance, m; z is axial distance, m.
(2). Meshing Figure 6 is a 2D model of the ladle wall which was designed by Solidworks 19.0, and imported into APDL of Ansys 2020 R2 for processing. Because it's a solid heat transfer model, plane 77 was chosen specifically for the heat transfer model which is a 2-dimensional 8-node thermal unit entity (each node has only one degree of freedom-temperature, and each element has a consistent temperature shape function), suitable for 2D steady-state or transient thermal analysis [26]. Therefore, the plane 77 was used in the ladle wall model to improve calculation accuracy. The steel ladle wall model was divided into 4450 units, and the total number of nodes is 11,236. The type of unit is quadrilateral. The advantage of this quadrilateral is that on the one hand it can reduce the amount of calculation. However, on the other hand, it doesn't cause the mesh to be too distorted, resulting in inaccurate results.
By comparing temperature difference of ladle wall with the counterparts calculated in the numerical model which contains a double quantity of mesh elements (including the test ladle wall model and the comparison ladle model), the difference in temperature difference remains constant, further refining of the mesh did not affect the results significantly, and the numerical computation independence on mesh is confirmed. Considering this result, the steel ladle wall model was divided into 4450 units, and the total number of nodes is 11,236. The type of unit is quadrilateral.
The temperature condition and convective heat transfer coefficient were used at the inner wall of thermal insulation material and the surface of OSS, the density, specific heat capacity, and thermal conductivity of materials were set, respectively. The calculation process adopted the stepped; the solution time was automatically set, and the steady-state solution was adopted. (3). Initial and Boundary Conditions According to steel ladle heat transfer form, in the process of heat transfer to the steel ladle wall, the inner wall of the steel ladle was set as the first type of boundary condition, as shown in Equation (2).
where r is the radius of steel ladle wall, m; and TW is the temperature of the inner wall, °C .
The steel shell was set as the third type of boundary condition. As shown in Equation (3). (3). Initial and Boundary Conditions According to steel ladle heat transfer form, in the process of heat transfer to the steel ladle wall, the inner wall of the steel ladle was set as the first type of boundary condition, as shown in Equation (2). where r is the radius of steel ladle wall, m; and T ω is the temperature of the inner wall, • C. The steel shell was set as the third type of boundary condition. As shown in Equation (3).
In the Equation (3), k is thermal conductivity along the normal direction, W/mK; T f is the ambient temperature, • C, and h is the comprehensive convective heat transfer coefficient of air, W/m 2 K. T is the OSS temperature, • C.
Under the working condition of steel ladle containing molten steel, the working layer of the steel ladle directly contacts the high temperature molten steel of 1570-1630 • C. According to related references [27,28], the temperature of the inner wall of the insulating layer is between 700-900 • C, take the average value 800 • C (T ω ) in this paper according to references [27,28], the OSS is in an external environment of 30 • C (T f ), and the heat transfer between OSS and the surrounding environment is convective heat exchange and radiation heat exchange. Generally, when the temperature exceeds 300 • C, the radiation heat transfer is strong, when the temperature is below 300 • C, the radiation heat transfer phenomenon is not obvious [29]. In the process of steel ladle turnaround, the surface temperatures of OSS are mainly 200-300 • C, the radiation heat transfer has little effect during the entire heat transfer process. Therefore, convective heat transfer and radiation heat transfer are converted into comprehensive convective heat transfer coefficient [30], so h is 8.1 W/mK. The physical parameters of the insulating layer are derived from the test data of Table 1.

The Surface Temperature of Outer Steel Shell Measurement
Many factors affect the temperature of the steel shell, especially the steel ladle used for converter steelmaking. The steel ladle is affected by its own conditions and external factors (such as the state of steel ladle, vacancy time, the tapping temperature of the molten steel, the type of alloy material, the added weight, and argon blowing stirring time). The temperature of the steel shell changes greatly, which is not easy to accurately compare. When the steel ladle is out-station of the LF, the molten steel temperature is uniform, sufficient and stable heat storage in each layer of the steel ladle wall, and the temperature fluctuation is small. After comprehensive thinking, the surface temperature data of the OSS after soft blowing at the out-station of the LF were collected.
Meanwhile, in order to reduce the influence of other production conditions on the measurement of surface temperature of OSS, it is stipulated that the steel ladle, steel type, temperature of molten steel, measuring temperature time and measuring temperature position are all measured under the same conditions.
In addition, during the use of steel ladle in a mid-maintenance period (the time from the steel ladle to the repair of the inner lining of the steel ladle is called a mid-maintenance period), the condition of steel ladle will gradually deteriorate due to the erosion of molten steel and other reasons, the heat storage of steel ladle wall is slightly different in a medium repair period, so in order to improve the measurement accuracy, the furnace age(the time interval between steel ladle passing through the same process each time is called one furnace age) was divided into early stage (1-50) and later stage(51-100). Details are as follows: (1) Steel ladle: steel ladle during the first mid-maintenance period.
(2) Steel type: SPHC (The first S is the abbreviation of Steel, P is the abbreviation of Plate, H is the abbreviation of hot Heat, and C is the abbreviation of Commercial, which generally means hot-rolled Steel Plate and Steel belt).  The temperature measuring tool uses a handheld infrared temperature measuring thermometer (Smart Sensor AS882) (Dongguan Wanchuang Electronic Products Co., Ltd., Dongguan, China). The temperature measuring range is from −18 • C to 1650 • C. The infrared temperature measuring thermometer and its working principle are shown in Figure 7. Figure 8 shows on-site temperature measurement method. That is, within the effective distance, the infrared probe is aligned with the 0.01 m 2 circle area marked of the surface OSS which is 1000 mm away from the upper stiffener and 800 mm from the right stiffener, and the temperature key is pressed for about 2 s to display the measured temperature. Measuring three times, then take the average of the three measured temperature values. A total of 70 steel ladles were measured (there are 36 test furnaces and 34 comparison furnaces).
generally means hot-rolled Steel Plate and Steel belt).
(3) Temperature of molten steel: 1580 ± 2 °C . (4) Temperature measuring tools: infrared temperature measuring thermometer. The temperature measuring tool uses a handheld infrared temperature measuring thermometer (Smart Sensor AS882) (Dongguan Wanchuang Electronic Products Co., Ltd., Dongguan, China). The temperature measuring range is from −18 °C to 1650 °C . The infrared temperature measuring thermometer and its working principle are shown in Figure 7. Figure 8 shows on-site temperature measurement method. That is, within the effective distance, the infrared probe is aligned with the 0.01 m 2 circle area marked of the surface OSS which is 1000 mm away from the upper stiffener and 800 mm from the right stiffener, and the temperature key is pressed for about 2 s to display the measured temperature. Measuring three times, then take the average of the three measured temperature values. A total of 70 steel ladles were measured (there are 36 test furnaces and 34 comparison furnaces).   (2) Steel type: SPHC (The first S is the abbreviation of Steel, P is the abbreviation of Plate, H is the abbreviation of hot Heat, and C is the abbreviation of Commercial, which generally means hot-rolled Steel Plate and Steel belt). The temperature measuring tool uses a handheld infrared temperature measuring thermometer (Smart Sensor AS882) (Dongguan Wanchuang Electronic Products Co., Ltd., Dongguan, China). The temperature measuring range is from −18 °C to 1650 °C . The infrared temperature measuring thermometer and its working principle are shown in Figure 7. Figure 8 shows on-site temperature measurement method. That is, within the effective distance, the infrared probe is aligned with the 0.01 m 2 circle area marked of the surface OSS which is 1000 mm away from the upper stiffener and 800 mm from the right stiffener, and the temperature key is pressed for about 2 s to display the measured temperature. Measuring three times, then take the average of the three measured temperature values. A total of 70 steel ladles were measured (there are 36 test furnaces and 34 comparison furnaces).   There are three basic ways of heat transfer: heat conduction, heat convection and heat radiation [31]. The heat transfer of high-temperature molten steel from the inside to the outside of the steel ladle is also divided into three parts. The first part is that the high-temperature molten steel heat enters the steel ladle wall through thermal conduction, among them, part of the heat is stored in the steel ladle wall, and the other part of the heat is radiated and convective through the OSS; the second part is the heat dissipation through the bottom of the steel ladle, the principle is the same as the first part; the third part is the heat dissipation of molten steel indirectly through the slag surface, which also includes three basic methods of heat conduction, heat convection and heat radiation at the same time. The proportion of heat dissipation in these three parts is shown in Figure 9 [32]. So the outward heat dissipation of the steel ladle becomes the calculation of the outward heat dissipation from the steel ladle wall. is radiated and convective through the OSS; the second part is the heat dissipation through the bottom of the steel ladle, the principle is the same as the first part; the third part is the heat dissipation of molten steel indirectly through the slag surface, which also includes three basic methods of heat conduction, heat convection and heat radiation at the same time. The proportion of heat dissipation in these three parts is shown in Figure 9 [32]. So the outward heat dissipation of the steel ladle becomes the calculation of the outward heat dissipation from the steel ladle wall. According to the steel ladle heat transfer model, think of the steel ladle as a heat source with a constant surface temperature that dissipates heat to the outside. The difference of heat dissipation at different surface temperatures is only investigated here. In other words, the steel ladle and the molten steel are considered as a whole object. Since the steel ladle filled with molten steel has much more heat than its surface heat dissipation, the internal temperature of the steel ladle is much higher than the ambient temperature, and there is no forced cooling medium on the outer surface of the steel ladle. Therefore, the steel ladle can be used as a cylinder with a constant surface temperature. The amount of heat dissipation has nothing to do with the temperature of the molten steel, only related to factors such as steel ladle surface temperature and environmental conditions. Therefore, the formula can be used to calculate the change of molten steel temperature [33].
Heat loss of the steel ladle heat transfer is Equation (4).
where φ1 is the heat flow of thermal radiation of OSS, W; φ2 is the heat flow of thermal convection of the OSS, W. The steel shell's radiant heat flow can be described as follows.
where ε is the emissivity of steel shell; А is the OSS surface area, m 2 ; σ is the Boltzmann constant (5.67 × 10 −8 W/m 2 K 4 ); T1 is the surface temperature of OSS, K; T2 is the ambient temperature, K. φ2 can be regarded as the convective heat transfer of a vertical cylinder, which is applicable to the convective heat transfer Equation (6). According to the steel ladle heat transfer model, think of the steel ladle as a heat source with a constant surface temperature that dissipates heat to the outside. The difference of heat dissipation at different surface temperatures is only investigated here. In other words, the steel ladle and the molten steel are considered as a whole object. Since the steel ladle filled with molten steel has much more heat than its surface heat dissipation, the internal temperature of the steel ladle is much higher than the ambient temperature, and there is no forced cooling medium on the outer surface of the steel ladle. Therefore, the steel ladle can be used as a cylinder with a constant surface temperature. The amount of heat dissipation has nothing to do with the temperature of the molten steel, only related to factors such as steel ladle surface temperature and environmental conditions. Therefore, the formula can be used to calculate the change of molten steel temperature [33].
Heat loss of the steel ladle heat transfer is Equation (4).
where ϕ 1 is the heat flow of thermal radiation of OSS, W; ϕ 2 is the heat flow of thermal convection of the OSS, W. The steel shell's radiant heat flow can be described as follows.
where ε is the emissivity of steel shell; A is the OSS surface area, m 2 ; σ is the Boltzmann constant (5.67 × 10 −8 W/m 2 K 4 ); T 1 is the surface temperature of OSS, K; T 2 is the ambient temperature, K. ϕ 2 can be regarded as the convective heat transfer of a vertical cylinder, which is applicable to the convective heat transfer Equation (6).
where h is convective heat transfer coefficient the surface of OSS, W/m 2 k; A is the heat transfer surface area of OSS, m 2 ; ∆T is the difference between the surface of OSS and the surrounding environment, K. h can be estimated as (7).
where Nu is Nusselt Number, λ is the thermal conductivity of air, W/mK; l is the height of the OSS, m. Nu can be estimated as (8). where Gr is the Grashof Number, Pr is the Prandtl Number, C, n is the constant. Gr can be estimated as (9).
where g is the gravitational acceleration, m/s 2 ; α is the volume expansion coefficient of air (the air in this paper is an ideal gas), the value is 3.676 × 10 −3 [34]; ∆T is the difference between the surface of OSS and the surrounding environment, K; H is the height of steel ladle, m; v is the kinematic viscosity of air, m 2 /s.

Related Parameters of Model
According to the surface properties of different objects "Table of Emissivity of Various Surfaces" [35], the value of the steel shell ε is 0.80. According to Table 2, A is 44.71 m 2 . T qualitative temperature as the qualitative temperature of air, K, and its value is half the sum of ambient temperature and surface temperature of OSS. The values of v, λ, and Pr are shown in Table 3. The value of C and n can be determined by the product of GrPr (see Table 4). When the minimum and maximum surface temperatures of the OSS are taken into GrPr, the value range of GrPr is shown in Formula (11). According to Formula (11) and Table 4, C is 0.135 and n is 1/3.

Verification of the Model
Temperature data of molten steel are collected respectively: (1). Measure molten steel temperature data immediately after soft blowing of LF; (2). The temperature data of molten steel with an interval of 15 min from the last measurement. According to the temperature difference, the actual temperature drop rate of molten steel is calculated. Then, the results of the mathematical model are verified.

The Simulated Results
According to the simulation results, the steady-state temperature field distribution cloud map of the two different thermal insulation materials on the ladle wall is obtained (see Figures 10 and 11). After the heat flux passes through the insulation layer, the following conclusions were obtained (see Table 5): (1). The temperature of the comparative ladle's OSS was 309 • C, and the temperature at the interface OCRIP and steel shell was 417 • C. It can be calculated that the thermal resistance rate of the SACIP is 47.9%. (2). The temperature of the test ladle OSS was 242 • C, and the temperature at the interface between SACIP and steel shell was 304 • C (see Figure 8). It can be calculated that the thermal resistance rate of the SACIP is 62.0%.
It can be seen that the thermal resistance of the SACIP was 14.1% higher than the OCRIP, and the surface temperature of OSS was 67 • C lower. The difference of the temperature of OSS between comparison ladle and test ladle is similar to that reported by Luo B [36], where they established that convective mechanisms were dominant in the heat transfer of temperature.      Figure 12 shows the surface temperature of the OSS measured with an infrared te perature measuring thermometer. It can be seen that the surface average temperature the test ladle's OSS fluctuates between 233-260 °C , and the surface average temperat of the comparison ladle's OSS fluctuates between 309-319 °C . In addition, the surface erage temperature of the test ladle's OSS is 59-73 °C lower than the comparison la when the steel ladle furnace age is 1-100.   Figure 12 shows the surface temperature of the OSS measured with an infrared temperature measuring thermometer. It can be seen that the surface average temperature of the test ladle's OSS fluctuates between 233-260 • C, and the surface average temperature of the comparison ladle's OSS fluctuates between 309-319 • C. In addition, the surface average temperature of the test ladle's OSS is 59-73 • C lower than the comparison ladle when the steel ladle furnace age is 1-100.   Figure 12 shows the surface temperature of the OSS measured with an infrared temperature measuring thermometer. It can be seen that the surface average temperature of the test ladle's OSS fluctuates between 233-260 °C , and the surface average temperature of the comparison ladle's OSS fluctuates between 309-319 °C . In addition, the surface average temperature of the test ladle's OSS is 59-73 °C lower than the comparison ladle when the steel ladle furnace age is 1-100.   Table 6 shows that the measurement results of the surface temperature OSS of test ladle and comparison ladle, and their average values range from 233-260 • C and 306-319 • C, respectively. The simulation results of test ladle and comparison ladle are 242 • C and 309 • C, respectively. The simulation results of the OSS surface temperature are all within the range of the measured temperature fluctuations, which verifies the validity of the finite element analysis of the ladle wall. This shows that the initial boundary temperature of the finite element was a reasonable choice at 800 • C, the selection of Plane 77 element is correct, also shows that the grid segmentation method, step solution setting is correct. However, Farrera-Buenrostro, J. E and others [37] pointed out that the temperature of the inner wall boundary of the insulation layer varies with factors such as the thermal conductivity of the insulation material and the state of molten steel. Therefore, this is the deficiency of the 2D heat transfer model. However, in this paper, on the basis of a large number of previous simulation results [38,39], the selected boundary temperature and model assumptions are feasible, and the experimental results also prove that the selected boundary conditions are within a reasonable range.

Simulation Result Verification
The results of measurement and simulation show that the insulation effect of the test ladle is better than for the comparison ladle; that is to say, SACIP has a better insulation effect than OCRIP. However, from the actual measurement results, the difference between the temperature of the test ladle wall in the early stage and the later stage is 27 • C, and the difference between the temperature of the comparison ladle wall is 13 • C, indicating that the temperature of the test ladle wall is greatly changed, and the specific reasons are still not clear. In subsequent tests, a large number of ladle wall temperatures should be measured to reduce the impact of less temperature data on the data. Meanwhile, more stringent temperature measurement measures should be established. The heat flux of the comparison ladle and the test ladle ϕ c ladle and ϕ t ladle can be calculated by Formulas (4)- (9). According to (12), the temperature loss of molten steel can be calculated.
where: ∆T is the temperature difference of molten steel, • C; Q is the total heat transferred by OSS, J; m is the quality of molten steel, kg; C P is the specific heat capacity of molten steel, J/kg • C; t is the time of a furnace age under working conditions, s. The drop rate of molten steel temperature can be calculated by Formula (13).
where: ∆V is the drop rate of steel molten temperature, • C/min; ∆T is the temperature difference of molten steel, • C; t is the time of a furnace age under working conditions, s.
Related parameter values are shown in Table 7.  [40], the main reason for the difference of 2.13 • C is that the thermal conductivity of the insulation layer is 0.042 W/mK, ladle walls transfer heat outward quickly. The molten steel drop rate of the test ladle is 0.18 • C/min lower than the comparison ladle (see Appendix A for calculation process of temperature loss of molten steel). Table 8 shows the actual measured drop rate of steel molten temperature. It can be seen from Table 8, when the steel ladle furnace age is 1-50, the temperature drop rates of comparison ladle and test ladle are 0.54 • C/min and 0.41 • C/min, respectively, the difference temperature drop rates of is 0.13 • C /min. when the steel ladle furnace age is 51-100; the temperature drop rates of comparison ladle and test ladle are 0.52 • C/min and 0.40 • C/min, respectively, the difference temperature drop rates of is 0.12 • C /min. Therefore, when the steel ladle furnace age is 1-100, the temperature drop rate of the test ladle can be 0.12-0.13 • C/min lower than comparison ladle.

Measuring Result
According to the calculating model, the molten steel drop rate of the test ladle is 0.18 • C/min lower than the comparison ladle in a furnace age. The difference of molten steel temperature drop rate between test ladle and comparison ladle is 0.05-0.06 • C/min lower than obtained by calculation model. The reason is that the thermal insulation effect of the test ladle is better than comparison ladle, the heat loss of the ladle wall is small, the molten steel temperature is high, and the heat loss of the ladle slag layer and bottom is greater than the comparison ladle. However, in the mathematical calculation model, the heat loss of the slag layer and the ladle bottom is not considered, only the heat loss of ladle wall is considered [41].

Cost Comparison
In the production, the test ladle adopts the measure that the refining temperature of the LF is lowered by 16.67 • C than the comparison ladle. The relevant smelting parameters of the 130-ton LF are shown in Table 9 (CNY: Chinese Yuan).
It can be seen from Table 9, When the LF out-station molten steel temperature of the test ladle is 16.67 • C lower than the comparison ladle, compared with the comparison ladle, the total cost of electricity and electrode saved by the test ladle is CNY 6.01/ton.
When the insulating layer is removed, the steel ladle furnace age is 600 furnaces, the steel ladle volume is 130 tons on average, the price of the SACIP is CNY 1200/m 2 , the steel ladle insulating layer is double layer, and the usable area is 89.4 m 2 , Therefore, it is concluded that the cost of using the SACIP in the test ladle is CNY 1.38/ton.
According to the factory's annual production cost data, the cost of using the OCRIP for the comparison ladle is CNY 0.52/ton. Therefore, the cost of the insulating layer of the test ladle exceeds the cost of the comparison ladle by CNY 0.86/ton. The cost of the test ladle for saving electrodes and electricity is CNY 6.01/ton, so the total cost savings of the test ladle is CNY 5.15/ton compared to the comparison ladle.

Conclusions
To study the application effect of steel ladle insulation materials, a new research method is designed in this paper. The main conclusions can be drawn as follows: 1.
The actual measurement of the surface OSS temperature shows that the surface OSS average temperature of the test ladle is 59-73 • C lower than the comparison OSS. According to the simulation results of the steel ladle wall, the surface OSS temperature of the test ladle is 67 • C lower than that the comparison OSS. The simulation results are within the range of the average temperature of the actual measured surface OSS, which proves the accuracy of the FEM and the selection of related parameters.

2.
According to the calculation model of molten steel temperature loss, compared with the comparison ladle, the test ladle in a furnace age, can save the temperature loss of molten steel 16.67 • C, and reduce the temperature drop rate of molten steel by 0.18 • C/min. In addition, when the steel ladle furnace age is 1-100, the temperature drop rate of the test ladle can be 0.12-0.13 • C/min lower than comparison ladle. Although the difference of molten steel temperature drop rate between test ladle and comparison ladle is 0.05-0.06 • C/min lower than obtained by calculation model, the Boltzmann mathematical model is still valid in evaluating the effect of the insulation layer and relevant parameters and solutions are correct.

3.
In the LF, by reducing the temperature of molten steel in the test ladle by 16.67 • C, the cost of a test ladle can be reduced by CNY 5.15/ton compared with the comparison ladle. Using silica aerogel composite insulation panels on a steel ladle plays a very positive role in reducing production costs and energy consumption.

4.
The new method designed in this paper to calculate the thermal insulation effect of steel ladle insulation layers is feasible. The ladle wall temperature is obtained by finite element model and experiment, then the heat emission from the ladle wall is calculated by the Boltzmann equation according to ladle wall temperature, and the temperature loss of molten steel is calculated inversely according to the heat emission. 5.
In a furnace age, the surface temperature of OSS of the test ladle measured fluctuated by a larger amount than did the comparison ladle. The specific reason for this is still unclear, and further study is required. When the steel ladle furnace age is 51-100, suppose: the heat dissipation of the test OSS is ϕ t3 , W; the convective heat transfer is ϕ t4 , W; The radiation heat dissipation of the comparative shell is ϕ c3 , W; the convective heat transfer is ϕ c4 , W; ϕ C ladle(51-100) is the sum of ϕ c3 and ϕ c4 , W; ϕ T ladle(51-100) is the sum of ϕ t3 and ϕ t4 , W.
ϕ Total is the difference between the heat dissipation of the comparative steel ladle and the test steel ladle. Therefore, the mid-repair period of each steel ladle age (the steel ladle furnace age is 1-100, the steel ladle turnaround once). The value of ϕ is as follows. ϕ = (0.323 + 0.07) × 10 6 W = 0.33 × 10 6 W.
According to the heat dissipation Formula (A6).
where: ∆T is the decreasing temperature of molten steel due to the heat dissipation by the steel ladle shell, • C; Q is the heat dissipation of the OSS, J; m is the quality of molten steel, kg; C P is the specific heat capacity of molten steel, J/kg • C; t is the steel ladle turnaround once time under working conditions, s. Related parameters of Formula (A6) are shown in Table 2.