Superhydrophobic Al 2 O 3 –Polymer Composite Coating for Self-Cleaning Applications

: Superhydrophobic coatings have a huge impact in various applications due to their extreme water-repellent properties. The main novelty of the current research work lies in the development of cheap, stable, superhydrophobic and self-cleaning coatings with extreme water-repellency. In this work, a composite of hydrothermally synthesized alumina (Al 2 O 3 ), polymethylhydrosiloxane (PMHS) and polystyrene (PS) was deposited on a glass surface by a dip-coating technique. The Al 2 O 3 nanoparticles form a rough structure, and low-surface-energy PHMS enhances the water-repellent properties. The composite coating revealed a water contact angle (WCA) of 171 ± 2 ◦ and a sliding angle (SA) of 3 ◦ . In the chemical analysis, Al2p, Si2p, O1s, and C1s elements were detected in the XPS survey. The prepared coating showed a self-cleaning property through the rolling action of water drops. Such a type of coating could have various industrial applications in the future.


Introduction
Superhydrophobic surfaces have earned much attention from researchers in the last two decades due to their excellent water repellent behavior and the high mobility of water, which can be used to avoid accumulating dirt, fouling, fogging, and icing [1][2][3][4]. Natural leaf surfaces, such as that of a lotus leaf, possess micro-scale papillae and nano-scale epicuticular wax crystals on their surface, forming a hierarchical surface morphology, which is responsible for their self-cleaning superhydrophobic properties by quickly removing the dirt particles from the surface by rolling water drops [5]. To date, many efforts have been devoted to the development of superhydrophobic coatings by forming a rough structure and/or reducing the surface energy by using low surface energy materials [6][7][8][9][10]. The use of low surface energy-based materials on the rough hierarchical structure may create a thin hydrophobic layer that could resist the adherence of water droplets [8,11,12]. The presence of a hierarchical surface with a thin layer of hydrophobic materials may also be another reason for the superhydrophobic property [13]. Similarly, different kinds of bio-mimicking surfaces were developed using natural or synthetic materials to achieve a micro-nano hierarchical surface structure with an extreme water repellent coating for self-cleaning, as well as oil-water sorption and separation applications [14,15]. Several studies were studied a mechanism of superhydrophobic as well as photocatalytic superhydrophilic surfaces in self-cleaning applications [16,17]. Photocatalytic superhydrophilic surfaces have also attracted considerable attention in terms of self-cleaning coatings due to the complete wettability of their substrates, which can easily remove an organic pollutant from the surfaces by the action of the flow of a water film [16,17]. Esmeryan et al. developed a novel soot-inspired superhydrophobic surface containing a quartz crystal microbalance (QCM)-based biosensor for the detection of human semen, and human spermatozoa quality assessment [18]. Similarly, the authors also studied the effect of soot-inspired superhydrophobic surfaces for human urine detection, as well as improving the success rate of the cryopreservation of human spermatozoa [19,20]. Here, we only focused on the fabrication of superhydrophobic coatings for self-cleaning applications.
Aluminium oxide (Al 2 O 3 ) is one of the cheapest materials, with excellent usability in various applications. The use of Al 2 O 3 in coatings also attracted significant attention in recent years due to its antibacterial property; excellent mechanical, electrical insulation, high-temperature properties; and first-rate impact, abrasion, and chemical resistance [21]. Several studies have focused on developing superhydrophobic surfaces using Al 2 O 3 particles or on the Al 2 O 3 surface [22][23][24][25]. Sutha et al. fabricated an optically transparent, anti-reflective, and self-cleaning superhydrophobic Al 2 O 3 coating on a glass substrate [25]. In this process, the authors first prepared Al 2 O 3 sol by mixing aluminium nitrate nonahydrate with 2-methoxyethanol solution by magnetic stirring in a monoethanolamine stabilizer at room temperature. Multiple layers of Al 2 O 3 nanoparticles were applied onto a glass substrate by a spin-coating method. After annealing, the film was immersed in hot water to obtain a porous structure. Finally, low surface energy 1H,1H,2H,2Hperfluorooctyltrichlorosilane was coated onto a porous Al 2 O 3 film by spin coating. On the other hand, Karapanagiotis et al. dispersed different-sized hydrophilic alumina nanoparticles (25,35, and 150 nm) in different concentrations in solutions of a hydrophobic poly(alkyl siloxane), and the prepared suspensions were sprayed onto a glass surface [26]. They stated that the wettability of the composite film is independent of the size, but is affected by the concentration of the particles. However, Richard et al. dispersed stearic acid modified Al 2 O 3 particles in ethanol, and sprayed them onto a glass slide in order to attain a superhydrophobic surface [27]. Tie et al. prepared a superhydrophobic and underwater superoleophobic surface by an aqueous mixture of hydrophilic nanoparticles (TiO 2 , SiO 2 , and Al 2 O 3 ) and fluorocarbon surfactants through dip, brush, or spray coating on various substrates, such as fabric, sponge, cotton, nickel foam, stainless steel mesh, copper sheet, glass, and ceramics [28]. Byun et al. prepared a superhydrophobic surface by spraying phosphonic acid-functionalized Al 2 O 3 nanoparticles onto glass, paper, cotton fabric, and flexible plastic substrates [29]. Several studies are available on the fabrication of superhydrophobic surfaces with extreme wettability by different techniques [13,14].
Although several techniques were used to fabricate superhydrophobic surfaces with self-cleaning behavior using various materials, only a few works were reported using Al 2 O 3 nanoparticle-based nanocomposites for superhydrophobic and self-cleaning coatings [22,30,31]. Al 2 O 3 based composites are highly useful in coating applications due to the abundant availability of the Al source and its antibacterial characteristics [32]. In the present work, we exclusively focused on a facile dip-coating method to coat an Al 2 O 3 -PMHS-PS hybrid system onto glass substrates. First, hydrothermally synthesized hydrophilic Al 2 O 3 nanoparticles were modified with low-surface-energy PMHS. The flake-shaped Al 2 O 3 nanoparticles were agglomerated during the deposition, forming a rough hierarchical structure and attaining a superhydrophobic surface. The chemical analysis of the prepared coating was also performed. Water jet impact, adhesive tape peeling and sandpaper abrasion tests were performed in order to evaluate the mechanical durability of the coating. Additionally, self-cleaning tests were conducted on the prepared superhydrophobic coatings. The coated substrates exhibited extreme water-repellent behavior as well as excellent mechanical stability.

Synthesis of the Al 2 O 3 Nanoparticles
Aluminum nitrate nonahydrate has been used to synthesize Al 2 O 3 nanoparticles via a hydrothermal method [33,34]. In the synthesis process, 3.6 g dextrose, 3.75 g aluminum nitrate nonahydrate, and 3 g urea were dissolved in 50 mL distilled water under vigorous stirring for 30 min. The prepared homogeneous transparent solution was transferred to a 100 mL Teflon-lined stainless-steel autoclave and kept in an oven at 170 • C for 6 h for the hydrothermal process. A black powder of hydrated alumina was collected by filtration and washed with distilled water and ethanol several times, and was dried at 80 • C for 8 h. The dried black powder of hydrated alumina was placed in a silica crucible and kept in a muffle furnace at 1000 • C for 3 h, with a heating rate of 4 • C min −1 in air atmosphere. Finally, the collected Al 2 O 3 particles were stored in the bottle for further use.

Preparation of the Superhydrophobic Coating
The micro-glass slides were washed using tap water and laboratory detergent (Molyclean 02 Neutral, Molychem, Mumbai, India) and, afterwards, cleaned ultrasonically using distilled water and ethanol for 10 min. A coating solution was prepared by the following process: 0.15 mL PMHS was mixed with 20 mL chloroform in a beaker, and kept on magnetic stirrer at 100 rpm. After 20 min of stirring, 400 mg Al 2 O 3 was added and stirred continuously for another 1 h. Meanwhile, in a second beaker, 10 mg/mL PS solution in 20 mL of chloroform was prepared. This PS solution was poured into the beaker containing PMHS-Al 2 O 3 and stirred further for 30 min.
The cleaned glass slide was dipped in a suspension of Al 2 O 3 -PMHS-PS for 10 s, with a controlled dip and withdrawal rate of 50 mm/s using a dip coating machine (Delta Scientific Equipment Pvt. Ltd., Kolkata, India); a coated sample was dried at room temperature (~25 • C). This is considered as one deposition layer of the coating solution. The coatings were repeated by applying 2, 4, and 6 deposition layers, and finally dried at 100 • C in an oven for 1 h. The samples with two, four, and six coating layers were labelled as the AD-1, AD-2 and AD-3 coating, respectively. In this work, we only focused on the study of the effect of dip-coating cycles on the superhydrophobic coating. Of course, changing the chemical compositions would alter the surface properties either partially or completely based on the formation of a hierarchical surface morphology, with more hydrophobic or hydrophilic characteristics based on the combinations of material.

Characterizations
A Scanning Electron Microscope (SEM, JEOL, JSM-7610F, Tokyo, Japan) was used to investigate the surface micro/nanostructure of the prepared coatings. The surface roughness was calculated using a Stylus profiler (Mitutoyo, SJ 210, Sakado, Japan). The water contact angle (WCA) and sliding angle (SA) were measured on at least three places on the samples using a contact angle meter (HO-IAD-CAM-01, Holmarc Opto-Mechatronics Pvt. Ltd., Kochi, India). The average value of the WCA and SA of samples were noted. The chemical composition of the coating was analyzed by X-ray photoelectron spectroscopy (XPS, PHI Quantera-II, Tokyo, Japan). The mechanical stability of the coatings was examined using a water jet created by a syringe on the coating. The mechanical sustainability of the coatings was evaluated further by an adhesive tape test and a sandpaper abrasion test using commercial adhesive tape and sandpaper. The self-cleaning performance of the coatings was observed by scattering fine particles of chalk as a dust contaminant onto the coating.

Surface Morphology, Roughness and Wettability of the Prepared Coatings
The surface micro/nanostructure has been given much attention in the definition of the wetting property of the coating surface. Mostly, micro-and nano-scale hierarchical surface structures with low surface energy are responsible for superhydrophobicity. The surface morphologies of the prepared coatings was analyzed by SEM, and are given in Figure 1a-f. The flake-shaped alumina nanoparticles formed during the hydrothermal synthesis are visible in the SEM images [35]. The addition of PMHS and PS molecules to the flake-shaped nanoparticles can form an aggregated micro-nano-sized random particles during the deposition process. Moreover, the agglomerated particles provided microand nano-sized hierarchical rough structures on the glass surface. The active Si-H bond and methyl groups present in the PMHS were utilized in the surface modification of hydrophilic alumina nanoparticles. The formation of a thin layer of hydrophobic PMHS on Al 2 O 3 would facilitate the enhancement of the hydrophobic property on the modified Al 2 O 3 -PMHS surface. Radwan et al. reported that the mixture of PS and Al 2 O 3 can deliver the superhydrophobic property while forming three dimensional nanofibers by an electrospinning technique [22]. PS nanofibers can display an excellent hydrophobic property, which becomes superhydrophobic through the introduction of Al 2 O 3 to the PS due to the formation of a multiscale hierarchical rough structure [22]. Likewise, the modification of PS with various hydrophobic agents can also develop a superhydrophobic surface property [36][37][38]. As such, the addition of a PS solution to Al 2 O 3 -PMHS would also help to form the multiscale hierarchical roughness by aggregation, as well as the formation of closely packed particles on the coated substrate. of the coatings was evaluated further by an adhesive tape test and a sandpaper abrasion test using commercial adhesive tape and sandpaper. The self-cleaning performance of the coatings was observed by scattering fine particles of chalk as a dust contaminant onto the coating.

Surface Morphology, Roughness and Wettability of the Prepared Coatings
The surface micro/nanostructure has been given much attention in the definition of the wetting property of the coating surface. Mostly, micro-and nano-scale hierarchical surface structures with low surface energy are responsible for superhydrophobicity. The surface morphologies of the prepared coatings was analyzed by SEM, and are given in Figure 1a-f. The flake-shaped alumina nanoparticles formed during the hydrothermal synthesis are visible in the SEM images [35]. The addition of PMHS and PS molecules to the flake-shaped nanoparticles can form an aggregated micro-nano-sized random particles during the deposition process. Moreover, the agglomerated particles provided microand nano-sized hierarchical rough structures on the glass surface. The active Si-H bond and methyl groups present in the PMHS were utilized in the surface modification of hydrophilic alumina nanoparticles. The formation of a thin layer of hydrophobic PMHS on Al2O3 would facilitate the enhancement of the hydrophobic property on the modified Al2O3-PMHS surface. Radwan et al. reported that the mixture of PS and Al2O3 can deliver the superhydrophobic property while forming three dimensional nanofibers by an electrospinning technique [22]. PS nanofibers can display an excellent hydrophobic property, which becomes superhydrophobic through the introduction of Al2O3 to the PS due to the formation of a multiscale hierarchical rough structure [22]. Likewise, the modification of PS with various hydrophobic agents can also develop a superhydrophobic surface property [36][37][38]. As such, the addition of a PS solution to Al2O3-PMHS would also help to form the multiscale hierarchical roughness by aggregation, as well as the formation of closely packed particles on the coated substrate. At two layers (AD-1) of deposition, the particles were agglomerated and uniformly distributed on the glass surface, as shown in Figure 1a,d. The AD-1 coating showed a surface roughness of 0.019 µm with WCA 120 ± 2°, and a water drop becomes stuck on the surface. The size of the agglomerated particles increased with increasing numbers of layers, up to four (AD-2), resulting in a highly rough structure with a roughness value of At two layers (AD-1) of deposition, the particles were agglomerated and uniformly distributed on the glass surface, as shown in Figure 1a,d. The AD-1 coating showed a surface roughness of 0.019 µm with WCA 120 ± 2 • , and a water drop becomes stuck on the surface. The size of the agglomerated particles increased with increasing numbers of layers, up to four (AD-2), resulting in a highly rough structure with a roughness value of 0.038 µm, which is similar to a Cassie-Baxter surface. The developed micro/nano-sized rough structure of the coating is clearly seen in Figure 1b,e. In such a hierarchical surface structure, air pockets are trapped; consequently, WCA increased to 171 ± 2 • , and water drops roll off at an inclination angle of 3 ± 0.5 • . Based on the formation of a multiscale micro-nano hierarchical structure as well as the formation of thin layer of low surface energy hydrophobic PMHS, this provides an extreme superhydrophobic property on a dip-coated substrate [39]. Further increasing the number of deposition layers to six, we noticed that more agglomerated particles are formed on the glass surface, and the surface roughness decreased partially to 0.034 µm (Figure 1c,f). At the same time, the six-layer coated sample also exhibited WCA 170 ± 2 • , with no changes in sliding angles. The AD-3 coated substrate can also deliver good mechanical durability when it forms densely packed particles on the coated surface, whereas the loosely packed particles on the surface mean that it can easily come out from the substrate under adhesive tape peeling and sandpaper abrasion tests [40]. As such, we further studied the effect of an AD-2-coated superhydrophobic substrate for the rest of the studies, because at four layers of coating, the fabricated substrate can exhibit the maximum contact angle, as well as a surface roughness which was reduced by the further increase of coating layers. As such, considering the practical point of view as well industrial applications, four layers of coating would be the optimum in order to minimize the time consumption of the coated solution.
The typical photographs of Al 2 O 3 -PMHS-PS composite-coated substrates are shown in Figure 2. A coated substrate has a translucent or opaque color due to the deposition of white Al 2 O 3 and PS on the glass substrate. The PMHS solution was transparent, and its addition was helpful for a stronger adhesion of the composite coating the substrate. The extreme superhydrophobic property of the AD-2 sample was confirmed by placing water droplets on the coated substrate. Figure 2a shows spherical-shaped color-dyed water drops, which explain the exceptional water-repellent behavior of the coated substrate. The inset of Figure 2a reveals an optical image of the water drop (approximately 10 µL volume) on a superhydrophobic AD-2 coating, which is obtained from a contact-angle meter. A water drop rolled off when the substrate was inclined by nearly 3 • with the help of the stage of the contact-angle meter. Figure 2(c1-c3) shows the rolling action of a water drop on a superhydrophobic coating. The water drops quickly rolled down from an inclined surface, as shown in the inset of Figure 2(c3). The stability of the coating against running water was checked using a water jet hitting test. The water jet was formed using a 10 mL syringe, hitting a specific place on the coating for more than one minute (Figure 2b). The continuous reflecting water jet from the superhydrophobic surface confirmed that the prepared coating is highly stable. More results on the mechanical durability of the coating are provided in Section 3.3. Unfortunately, we are unable to provide an alternative image to showcase the sliding angle. Because of the extreme water repellent behavior of the coated superhydrophobic surface, as well as the very low sliding angle, a droplet can easily run away after contacting the substrate. Moreover, the inset image of c3 also clearly suggests the non-adherence of the water droplet after the transportation of the water droplet from the substrate. As such, we hope this image is enough to illustrate the low sliding angle and extreme water-repellency of the superhydrophobic substrate.

XPS Study
The surface elemental compositions of the prepared superhydrophobic Al2O3-PMHS-PS composite AD-2 coating were analyzed using XPS studies (Figure 3a). Four peaks were observed at 74.85 eV, 102.61 eV, 284.8 eV and 532.11 eV, and are related to Al2p, Si2p, C1s, and O1s, respectively. The presence of Al, Si, C and O elements confirms that the Al2O3-PMHS-PS composite exists on the glass substrate. In Al2p scan spectra (Figure 3b

XPS Study
The surface elemental compositions of the prepared superhydrophobic Al 2 O 3 -PMHS-PS composite AD-2 coating were analyzed using XPS studies (Figure 3a). Four peaks were observed at 74.85 eV, 102.61 eV, 284.8 eV and 532.11 eV, and are related to Al2p, Si2p, C1s, and O1s, respectively. The presence of Al, Si, C and O elements confirms that the Al 2 O 3 -PMHS-PS composite exists on the glass substrate. In Al2p scan spectra (Figure 3b), the peaks correspond to Al-O (74.6 eV) and Al-O-Si (75.5 eV) bonds. In Figure 3c, the Si2p peak at 102.4 eV and 103.7 eV corresponds to the Si-O-Si and Si-O-Al bonds [41]. In the O1s scan (Figure 3d), the highest peak is associated to Al-O-Si (532.7 eV) and Al-O-Al (531.1 eV) bonds, corresponding to the PMHS chain and Al 2 O 3 nanoparticles [42,43]. In the high-resolution C1s XPS spectrum (Figure 3e), the BEs of 284.2 to 286.1 eV are related C-C/C-H and C=O, respectively.

Mechanical Durability Tests
The mechanical durability of the prepared superhydrophobic coating is highly important for commercial applications. A fragile hierarchical structure of superhydrophobic coatings can be ruined when exposed to outdoor applications. The preparation of a robust superhydrophobic property is always a challenging issue because the superhydrophobic surface property can be damaged under severe mechanical stress, as well as under hot water or acidic and basic conditions. Several studies focused on improving the robustness of superhydrophobic surfaces by introducing highly strong adhesives.
The adhesive tape peeling and sandpaper abrasion tests are the most commonly used methods to evaluate the mechanical durability of superhydrophobic coatings [44]. A Cello tape no.405 (adhesiveness 3.93 N/10 mm) was placed on the AD-2 coating, and a metal disc of weight of 200 g was rolled on it to create good contact between the coating's surface and the tape. The tape was peeled off slowly from the coating's surface to check the adhesive tape peeling test performance, and this is considered one cycle of the tapepeeling test [44]. The WCA was also measured after test to check wetting property of the coating. The analysis of the WCA versus the number of tape peeling tests revealed that the superhydrophobicity remained stable for up to five cycles of tape peeling. After seven cycles, the WCA decreased to lower than~140 • . A variation of the WCA with an increasing number of tape-peeling cycles is shown in Figure 4a, and a photograph of the tape-peeling test is shown in the inset of Figure 4a.  The AD-2 sample was placed on sandpaper of grit no. 400, then a 50 g weight was loaded onto it, and subsequently the sample was rubbed with a speed of~5 mm/s for 10 cm (one cycle of the sandpaper abrasion test). A WCA was recorded after every sandpaper abrasion cycle (Figure 4b). The experimental setup of the sandpaper abrasion test is shown in the inset of Figure 4b. The WCA was reduced to~162 • , and the SA slightly increased (7 • ) after the completion of three cycles of the sandpaper abrasion test. This result indicated that the prepared coating is highly stable. After five abrasion cycles, the WCA decreased tõ 150 • . Subsequently, at seven cycles, water drops start to spread on the coating surface, as the composite material might have been removed by abrasion. A weak van der Waals force of attraction and hydrogen bonding can occur between the Al 2 O 3 and PMHS, whereas the addition of PS to the Al 2 O 3 -PMHS suspension can have a hydrophobic-hydrophobic interaction between the hydrophobic PMHS and PS. While coating Al 2 O 3 -PMHS-PS composites onto a hydrophilic glass substrate, it would show a stronger interaction with the hydrophilic Al 2 O 3 . At the same time, an aggregated hydrophobic micro-nano hierarchical structure was observed on the surface, which produced a highly stable superhydrophobic property on the coated substrate under the thermal curing at 100 • C. These results suggest that the prepared Al 2 O 3 -PMHS-PS composite-coated substrate has excellent mechanical durability and robustness, which are important for practical applications. The coated substrate can maintain the superhydrophobic property for up to 5 to 6 cycles of adhesive tape peeling and sandpaper abrasion tests. We hope this mechanical durability is quite enough for various applications. Most of the superhydrophobic coatings reported can last less than five cycles of adhesive tape peeling and sandpaper abrasion tests [45][46][47]. As such, we hope that our coated substrate is better than the reported superhydrophobic coatings. Of course, enhanced robustness with the maintenance of superhydrophobicity and self-cleaning properties over 10 cycles of adhesive tape peeling and sandpaper abrasion tests are particularly recommended for high-end product development.

Self-Cleaning Test
Self-cleaning is one of the most desirable properties of a superhydrophobic coating. Such coatings can easily clean dust particles from their surface by the action of rolling water drops or without external force. Figure 5a shows a spreading of fine particles of colored chalk that are randomly scattered on the prepared superhydrophobic AD-2 coating, which was kept at an inclination angle nearly 10 • . When a water shower produced by the syringe was sprinkled on this coating surface, owing to the highly water repellent property, the water drops rolled down the surface by collecting dust particles from the coating's surface (Figure 5b). Figure 5c illustrates that rolling water drops completely remove dust particles from the superhydrophobic surface, supporting the excellent selfcleaning property of the Al 2 O 3 -PMHS-PS composite coating. The superhydrophobic and self-cleaning properties are retained on the coated substrate by repeated wetting, and are also more durable in nature.
PMHS-PS composites onto a hydrophilic glass substrate, it would show a stronger interaction with the hydrophilic Al2O3. At the same time, an aggregated hydrophobic micronano hierarchical structure was observed on the surface, which produced a highly stable superhydrophobic property on the coated substrate under the thermal curing at 100 °C. These results suggest that the prepared Al2O3-PMHS-PS composite-coated substrate has excellent mechanical durability and robustness, which are important for practical applications. The coated substrate can maintain the superhydrophobic property for up to 5 to 6 cycles of adhesive tape peeling and sandpaper abrasion tests. We hope this mechanical durability is quite enough for various applications. Most of the superhydrophobic coatings reported can last less than five cycles of adhesive tape peeling and sandpaper abrasion tests [45][46][47]. As such, we hope that our coated substrate is better than the reported superhydrophobic coatings. Of course, enhanced robustness with the maintenance of superhydrophobicity and self-cleaning properties over 10 cycles of adhesive tape peeling and sandpaper abrasion tests are particularly recommended for high-end product development.

Self-Cleaning Test
Self-cleaning is one of the most desirable properties of a superhydrophobic coating. Such coatings can easily clean dust particles from their surface by the action of rolling water drops or without external force. Figure 5a shows a spreading of fine particles of colored chalk that are randomly scattered on the prepared superhydrophobic AD-2 coating, which was kept at an inclination angle nearly 10°. When a water shower produced by the syringe was sprinkled on this coating surface, owing to the highly water repellent property, the water drops rolled down the surface by collecting dust particles from the coating's surface (Figure 5b). Figure 5c illustrates that rolling water drops completely remove dust particles from the superhydrophobic surface, supporting the excellent selfcleaning property of the Al2O3-PMHS-PS composite coating. The superhydrophobic and self-cleaning properties are retained on the coated substrate by repeated wetting, and are also more durable in nature.

Conclusions
We demonstrated a facile dip-coating method for the fabrication of a stable superhydrophobic coating. A stable superhydrophobic surface was achieved by the four-time dip coating of an Al 2 O 3 -PHMS-PS composite onto a glass substrate. The coated substrate presented a WCA~171 • and an SA~3 • . SEM micrographs of the coating showed flakeshaped alumina particles which were agglomerated and formed a rough microstructure. The XPS analysis revealed the co-existence of Al 2 O 3 , PHMS, and PS on the surface. The durability tests-such as the water jet impact, adhesive tape, and sandpaper abrasion testdisplayed the high mechanical stability of the coating. In addition, the superhydrophobic Al 2 O 3 -PHMS-PS composite coating revealed excellent self-cleaning performance. The overall results suggest that the prepared Al 2 O 3 -PHMS-PS composite coating can be used to develop excellent superhydrophobic surfaces which might be potentially useful for various applications.