Influence of Heat Reflective Coating on the Cooling and Pavement Performance of Large Void Asphalt Pavement

To reduce the temperature of asphalt pavement in summer, and alleviate the urban heat island effect, a comprehensive method of combining a heat reflective coating and large void asphalt pavement was proposed. Using the developed coating cooling test equipment, the cooling effect of the coating on a large void asphalt mixture was studied in six different proportions, four different colors, and four different dosages, and the durability of the coating was verified by abrasion tests. Finally, the best dosage of the coating was recommended through an adhesion test of the coating, and a water permeability and anti-skid performance test of the pavement. The results show that the reflectivity of the coating can be improved by adding functional fillers, of titanium dioxide and floating beads, into the coating. The order by reflectivity and cooling effect of the four color coatings was green > red > gray > blue, and the maximum cooling value of the green coating reached 9.7 ◦C. The cooling performance of the coating decreased with the increase of wear time, and the rate of decrease was fast, then slow, and finally tended to be stable after 20,000 times wear. The coating reduced the anti-skid performance and the water permeability coefficient of large void asphalt pavement, but still maintained a high level. The green coating with 15% titanium dioxide and 10% floating beads is recommended as the cooling coating for large void asphalt pavement, and its dosage should be controlled at about 0.4–0.8 kg/m2.


Introduction
Asphalt pavement has the advantages of low noise and comfortable driving, and is widely used in expressways and urban roads. However, black asphalt pavement has a very strong heat absorption property, especially under strong solar radiation in summer. Therefore, asphalt pavement easily produces rutting [1,2]. Furthermore, the heat absorbed by the pavement further aggravates the "heat island effect" of the city [3][4][5], and affects human health [6]. In order to reduce the temperature of asphalt pavement, several methods are being adopted currently, including thermal resistance pavement [7][8][9], water retention pavement [10][11][12], added phase change material pavement [13][14][15], and heat reflective coating pavement [16]. Among them, the heat reflective coating method is the most effective, and has been widely used. Zhu XY [17] applied a heat reflective coating to the sidewalk, which can reduce the temperature by 5.9 • C; Sha AM [18] designed a special solar heating reflective coating layer that can reduce the temperature by 10 • C; and Jiang L [19] designed a coating composed of a three-layer structure that can reduce the temperature by 13 • C. Yi Y [20] designed a red coating that can reduce the temperature by 10.2 • C. reflective coating layer that can reduce the temperature by 10 °C; and Jiang L [19] designed a coating composed of a three-layer structure that can reduce the temperature by 13 °C. Yi Y [20] designed a red coating that can reduce the temperature by 10.2 °C.
Although the cooling effect of the heat reflective coating is preferable, it has an obvious influence on the anti-skid performance of the original pavement, and its wear resistance is poor. Cao XJ [21] applied a heat reflective coating to a dense asphalt pavement, and the anti-skid performance of the British pendulum number (BPN) decreased from 57 to 29 with the seriously worn coating. Zheng ML [22] applied a heat reflective coating to an AC-16 pavement at an amount of 0.6 kg/m 2 , and the BPN dropped from 68 to 31. However, large void asphalt pavement has the advantages of low thermal conductivity, good thermal insulation effect, and high anti-skid performance. The research of Hassn A [23] and Xie XG [24] showed that a large void mixture had a low specific heat capacity and thermal conductivity, which could be used to alleviate the urban heat island effect [25]. Therefore, it may be a good method to combine a heat reflective coating with large void asphalt pavement to give full play to their advantages. The coating is not only sprayed onto the road surface but also filled into the gaps, which can improve the wear resistance and durability of the coating, and meanwhile having little impact on the skid resistance of the original pavement, to ensure driving safety. This paper intends to study the application of heat reflective coatings on large void asphalt pavement for better cooling and pavement performance.

The Cooling Mechanism of Large Void Coated Pavement
The heat exchange of asphalt pavement is related to the natural environment. As shown in Figure 1 [26], the heat sources of the asphalt pavement mainly include direct solar radiation, scattering radiation, and atmospheric reverse radiation. The heat dissipation includes road reflection, heat convection, and heat conduction. All of these constitute the heat exchange between the asphalt pavement and the environment. To reduce the temperature, the fundamental method is to change the surface characteristics and heat transfer performance of the asphalt pavement, as shown in Figure 2, which is the composition of the large void coated pavement.  To reduce the temperature, the fundamental method is to change the surface characteristics and heat transfer performance of the asphalt pavement, as shown in Figure 2, which is the composition of the large void coated pavement.
Coatings 2020, 10, x FOR PEER REVIEW 2 of 15 reflective coating layer that can reduce the temperature by 10 °C; and Jiang L [19] designed a coating composed of a three-layer structure that can reduce the temperature by 13 °C. Yi Y [20] designed a red coating that can reduce the temperature by 10.2 °C. Although the cooling effect of the heat reflective coating is preferable, it has an obvious influence on the anti-skid performance of the original pavement, and its wear resistance is poor. Cao XJ [21] applied a heat reflective coating to a dense asphalt pavement, and the anti-skid performance of the British pendulum number (BPN) decreased from 57 to 29 with the seriously worn coating. Zheng ML [22] applied a heat reflective coating to an AC-16 pavement at an amount of 0.6 kg/m 2 , and the BPN dropped from 68 to 31. However, large void asphalt pavement has the advantages of low thermal conductivity, good thermal insulation effect, and high anti-skid performance. The research of Hassn A [23] and Xie XG [24] showed that a large void mixture had a low specific heat capacity and thermal conductivity, which could be used to alleviate the urban heat island effect [25]. Therefore, it may be a good method to combine a heat reflective coating with large void asphalt pavement to give full play to their advantages. The coating is not only sprayed onto the road surface but also filled into the gaps, which can improve the wear resistance and durability of the coating, and meanwhile having little impact on the skid resistance of the original pavement, to ensure driving safety. This paper intends to study the application of heat reflective coatings on large void asphalt pavement for better cooling and pavement performance.

The Cooling Mechanism of Large Void Coated Pavement
The heat exchange of asphalt pavement is related to the natural environment. As shown in Figure 1 [26], the heat sources of the asphalt pavement mainly include direct solar radiation, scattering radiation, and atmospheric reverse radiation. The heat dissipation includes road reflection, heat convection, and heat conduction. All of these constitute the heat exchange between the asphalt pavement and the environment. To reduce the temperature, the fundamental method is to change the surface characteristics and heat transfer performance of the asphalt pavement, as shown in Figure 2, which is the composition of the large void coated pavement.   The cooling pavement is mainly composed of a heat reflective coating and a large void asphalt pavement. The use of a heat reflective coating can improve the reflection of the road surface to sunlight. The application of large void asphalt pavement can, not only reduce the thermal conductivity of the road and the heat conducted to the inside of the road surface, but also facilitate the convection of road heat and the air, and increase the heat dissipation capacity of the road surface. In this way, the comprehensive application of the coating and the large-void asphalt pavement can fully achieve the purpose of reducing the surface and internal temperature of the pavement.

Raw Materials for Coating
The heat reflective coating material is mainly composed of three parts: matrix material, functional filler, and admixture, as shown in Figure 3. The cooling pavement is mainly composed of a heat reflective coating and a large void asphalt pavement. The use of a heat reflective coating can improve the reflection of the road surface to sunlight. The application of large void asphalt pavement can, not only reduce the thermal conductivity of the road and the heat conducted to the inside of the road surface, but also facilitate the convection of road heat and the air, and increase the heat dissipation capacity of the road surface. In this way, the comprehensive application of the coating and the large-void asphalt pavement can fully achieve the purpose of reducing the surface and internal temperature of the pavement.

Raw Materials for Coating
The heat reflective coating material is mainly composed of three parts: matrix material, functional filler, and admixture, as shown in Figure 3. The matrix material plays a major role in the mechanical properties of the coating, and includes epoxy resin and curing agent. E-51 epoxy resin and 593 curing agent were selected for this study. E-51 epoxy resin is a kind of thermosetting polymer synthetic material, with a high epoxy value, low viscosity, and light color. Due to its advantages of high strength, good adhesion, corrosion resistance, and low shrinkage after curing, it is widely used in pavements and coatings. The 593 curing agent can react with epoxy resin at room temperature, which can accelerate the curing of the coating for the purpose of reopening traffic quickly.
Functional fillers include rutile titanium dioxide, floating beads, and inorganic pigments, as shown in Figure 4. Titanium dioxide has a large shading index and can improve the scattering ability of the coating to sunlight. The floating bead is a kind of fly ash hollow ball that can float on water. Its chemical composition mainly includes silica and aluminum oxide. It has the functions of wear resistance, heat insulation, and flame retardance. The pigment can adjust the color of the coating. Four colors of inorganic pigment, green, red, blue, and gray, were selected. The main chemical composition of the inorganic pigments is iron oxide.
The additives include diluent, defoamer, and dispersant, which can reduce the viscosity of the coating and improve its workability, eliminate bubbles, and disperse the fillers, respectively. The matrix material plays a major role in the mechanical properties of the coating, and includes epoxy resin and curing agent. E-51 epoxy resin and 593 curing agent were selected for this study. E-51 epoxy resin is a kind of thermosetting polymer synthetic material, with a high epoxy value, low viscosity, and light color. Due to its advantages of high strength, good adhesion, corrosion resistance, and low shrinkage after curing, it is widely used in pavements and coatings. The 593 curing agent can react with epoxy resin at room temperature, which can accelerate the curing of the coating for the purpose of reopening traffic quickly.
Functional fillers include rutile titanium dioxide, floating beads, and inorganic pigments, as shown in Figure 4. Titanium dioxide has a large shading index and can improve the scattering ability of the coating to sunlight. The floating bead is a kind of fly ash hollow ball that can float on water. Its chemical composition mainly includes silica and aluminum oxide. It has the functions of wear resistance, heat insulation, and flame retardance. The pigment can adjust the color of the coating. Four colors of inorganic pigment, green, red, blue, and gray, were selected. The main chemical composition of the inorganic pigments is iron oxide.

Ratio Design and Preparation of Coating
According to the different dosages of filler, six different coating ratios were designed, as shown in Table 1. ; 2 The dosages of floating beads, curing agent, and diluent are the mass percentage of epoxy resin; 3 The dosage of pigment is the mass percentage of titanium dioxide; 4 The dosages of dispersant and defoamer are the mass percentage of the coating.
The heat reflective coating was prepared according to the process shown in Figure 5. The amount of each material was weighed, according to the designed ratio, before coating preparation. First, the diluent was added into the epoxy resin and stirred with a blender at a rate of 500-1000 r/min for 5-10 min. Second, the titanium dioxide, floating beads, and pigments were mixed together and added into the epoxy resin, and then the mixture was stirred at a rate of 1000-1500 r/min The additives include diluent, defoamer, and dispersant, which can reduce the viscosity of the coating and improve its workability, eliminate bubbles, and disperse the fillers, respectively.

Ratio Design and Preparation of Coating
According to the different dosages of filler, six different coating ratios were designed, as shown in Table 1.  2 The dosages of floating beads, curing agent, and diluent are the mass percentage of epoxy resin; 3 The dosage of pigment is the mass percentage of titanium dioxide; 4 The dosages of dispersant and defoamer are the mass percentage of the coating.
The heat reflective coating was prepared according to the process shown in Figure 5.

Ratio Design and Preparation of Coating
According to the different dosages of filler, six different coating ratios were designed, as shown in Table 1. ; 2 The dosages of floating beads, curing agent, and diluent are the mass percentage of epoxy resin; 3 The dosage of pigment is the mass percentage of titanium dioxide; 4 The dosages of dispersant and defoamer are the mass percentage of the coating.
The heat reflective coating was prepared according to the process shown in Figure 5. The amount of each material was weighed, according to the designed ratio, before coating preparation. First, the diluent was added into the epoxy resin and stirred with a blender at a rate of 500-1000 r/min for 5-10 min. Second, the titanium dioxide, floating beads, and pigments were mixed together and added into the epoxy resin, and then the mixture was stirred at a rate of 1000-1500 r/min The amount of each material was weighed, according to the designed ratio, before coating preparation. First, the diluent was added into the epoxy resin and stirred with a blender at a rate of 500-1000 r/min for 5-10 min. Second, the titanium dioxide, floating beads, and pigments were mixed together and added into the epoxy resin, and then the mixture was stirred at a rate of 1000-1500 r/min for 15-20 min. During the stirring, the dispersant and defoamer were added into the mixture, so we Coatings 2020, 10, 1065 5 of 15 could get the semi-finished coating product. Finally, the curing agent was added into the mixture and stirring continued for 10 min to obtain the finished coating.

Large Void Asphalt Mixture
OGFC-10 grade was selected to prepare the large void asphalt mixture, as shown in Figure 6. Shell high viscosity asphalt, basalt aggregate, and limestone powder were selected for the asphalt, coarse and fine aggregate, and mineral powder, respectively. Basalt aggregate has a high polishing value, and pavement constructed with it has a good skid resistance. A high viscosity asphalt can improve the road performance of the large void mixture. All materials had to meet the requirements of specification JTG F40-2004. The main technical indexes of the large void mixture, determined by the Marshall test, are shown in Table 2.
Coatings 2020, 10, x FOR PEER REVIEW 5 of 15 for 15-20 min. During the stirring, the dispersant and defoamer were added into the mixture, so we could get the semi-finished coating product. Finally, the curing agent was added into the mixture and stirring continued for 10 min to obtain the finished coating.

Large Void Asphalt Mixture
OGFC-10 grade was selected to prepare the large void asphalt mixture, as shown in Figure 6. Shell high viscosity asphalt, basalt aggregate, and limestone powder were selected for the asphalt, coarse and fine aggregate, and mineral powder, respectively. Basalt aggregate has a high polishing value, and pavement constructed with it has a good skid resistance. A high viscosity asphalt can improve the road performance of the large void mixture. All materials had to meet the requirements of specification JTG F40-2004. The main technical indexes of the large void mixture, determined by the Marshall test, are shown in Table 2.

Reflectivity Test of Coating
The No. 4 coatings of blue, gray, red, and green, and the No. 1-6 green coatings were prepared and sprayed on the surface of the specimen at the dosage of 0.6 kg/m 2 . The specimen cut from the Marshall specimen was a quarter circle with a height of 2 cm and a radius of 5 cm, as shown in Figure  7a. Then, UV-Vis spectrophotometer (UV-2600, produced by Shimadzu, Kyoto, Japan) was used to test the reflectance of the coated and uncoated samples in 350-800 nm visible light, as shown in Figure  7b. Spectral reflectance measurements were performed according to ASTM E275 [27].

Reflectivity Test of Coating
The No. 4 coatings of blue, gray, red, and green, and the No. 1-6 green coatings were prepared and sprayed on the surface of the specimen at the dosage of 0.6 kg/m 2 . The specimen cut from the Marshall specimen was a quarter circle with a height of 2 cm and a radius of 5 cm, as shown in Figure 7a. Then, UV-Vis spectrophotometer (UV-2600, produced by Shimadzu, Kyoto, Japan) was used to test the reflectance of the coated and uncoated samples in 350-800 nm visible light, as shown in Figure 7b. Spectral reflectance measurements were performed according to ASTM E275 [27].

Cooling Performance Test
A special piece of equipment was developed and used in the cooling test of the coating, as shown in Figure 8. It is mainly composed of a closed box, an iodine tungsten lamp, and a temperature collector. The test specimen was a rutting plate with a size of 30 cm × 30 cm × 5 cm. Before the test, No.1-6 green coatings (0.6 kg/m 2 ), four colors of No. 4 coating (0.6 kg/m 2 ), and No.5 green coating (0.2 kg/m 2 , 0.4 kg/m 2 , 0.6 kg/m 2 , 0.8 kg/m 2 ) were sprayed on the surface of the specimen. After the coating was fully cured, two small holes were drilled symmetrically at a distance of 2 cm from the top surface of the plate to embed the temperature sensor. At the same time, two temperature sensors were placed symmetrically at the top and bottom of the plate, and then the test piece was put into the heat insulation box of the equipment, as shown in Figure 8.
During the test, first, the equipment was opened, and meanwhile the initial temperature was set at 20 °C, for 4 h so that the temperature of each position of the rutting plate specimen was about 20 °C. Then, the iodine tungsten lamp was turned on to radiate for 5 h, the radiation intensity of the plate surface was controlled at about 850 W/m 2 , and temperature data were recorded every 20 min with

Cooling Performance Test
A special piece of equipment was developed and used in the cooling test of the coating, as shown in Figure 8. It is mainly composed of a closed box, an iodine tungsten lamp, and a temperature collector.

.2. Cooling Performance Test
A special piece of equipment was developed and used in the cooling test of the coating, as shown in Figure 8. It is mainly composed of a closed box, an iodine tungsten lamp, and a temperature collector. The test specimen was a rutting plate with a size of 30 cm × 30 cm × 5 cm. Before the test, No.1-6 green coatings (0.6 kg/m 2 ), four colors of No. 4 coating (0.6 kg/m 2 ), and No.5 green coating (0.2 kg/m 2 , 0.4 kg/m 2 , 0.6 kg/m 2 , 0.8 kg/m 2 ) were sprayed on the surface of the specimen. After the coating was fully cured, two small holes were drilled symmetrically at a distance of 2 cm from the top surface of the plate to embed the temperature sensor. At the same time, two temperature sensors were placed symmetrically at the top and bottom of the plate, and then the test piece was put into the heat insulation box of the equipment, as shown in Figure 8.
During the test, first, the equipment was opened, and meanwhile the initial temperature was set at 20 °C, for 4 h so that the temperature of each position of the rutting plate specimen was about 20 °C. Then, the iodine tungsten lamp was turned on to radiate for 5 h, the radiation intensity of the plate surface was controlled at about 850 W/m 2 , and temperature data were recorded every 20 min with The test specimen was a rutting plate with a size of 30 cm × 30 cm × 5 cm. Before the test, No.1-6 green coatings (0.6 kg/m 2 ), four colors of No. 4 coating (0.6 kg/m 2 ), and No.5 green coating (0.2 kg/m 2 , 0.4 kg/m 2 , 0.6 kg/m 2 , 0.8 kg/m 2 ) were sprayed on the surface of the specimen. After the coating was fully cured, two small holes were drilled symmetrically at a distance of 2 cm from the top surface of the plate to embed the temperature sensor. At the same time, two temperature sensors were placed symmetrically at the top and bottom of the plate, and then the test piece was put into the heat insulation box of the equipment, as shown in Figure 8.
During the test, first, the equipment was opened, and meanwhile the initial temperature was set at 20 • C, for 4 h so that the temperature of each position of the rutting plate specimen was about 20 • C. Then, the iodine tungsten lamp was turned on to radiate for 5 h, the radiation intensity of the plate surface was controlled at about 850 W/m 2 , and temperature data were recorded every 20 min with the Coatings 2020, 10, 1065 7 of 15 temperature collector. Finally, the collected temperature data were exported, and the average value of the two sensors data was taken as the final result.

Coating Abrasion Test
No. 1-6 green coatings were sprayed on half of the rutting plate at a dosage of 0.6 kg/m 2 . After the coating was completely cured, the abrasion test was carried out on the coated side with the rutting tester, in accordance with JTG E20-2011, as shown in Figure 9. The test temperature was set at 60 • C, the wheel pressure was 0.7 Mpa, the wear width was 50 mm, and the wear rate was 42 times/min. After every 10,000 wear cycles, the specimen was taken out for a cooling performance test, and the wear was stopped after 30,000 times.
Coatings 2020, 10, x FOR PEER REVIEW 7 of 15 the temperature collector. Finally, the collected temperature data were exported, and the average value of the two sensors data was taken as the final result.

Coating Abrasion Test
No. 1-6 green coatings were sprayed on half of the rutting plate at a dosage of 0.6 kg/m 2 . After the coating was completely cured, the abrasion test was carried out on the coated side with the rutting tester, in accordance with JTG E20-2011, as shown in Figure 9. The test temperature was set at 60 °C, the wheel pressure was 0.7 Mpa, the wear width was 50 mm, and the wear rate was 42 times/min. After every 10,000 wear cycles, the specimen was taken out for a cooling performance test, and the wear was stopped after 30,000 times. After the coating was fully cured, the adhesion performance between the coating and the pavement, the water permeability, and skid resistance of the pavement were tested.
The adhesion performance was evaluated by a drawing test in accordance with ASTM D4541 [28]. The drawing head and the coating were bonded together before the coating was cured. After curing, the drawing test was conducted. The test temperature was 25 ℃, and the drawing rate was 0.1 MPa/s, as shown in Figure 10a.
The water permeability coefficient was tested with a water seepage meter, in accordance with JTG E60-2008, as shown in Figure 10b. The measuring cylinder was filled with water, and then the valve was opened. When the water level dropped to 100 mL, the stopwatch was pressed to count the time. When the water level dropped to 500 mL, the stopwatch was pressed again to record the required time. The water seepage coefficient was calculated according to Equation (1).
where CW is the permeability coefficient, mL/min; V1 is the water volume (mL) of the first timer, usually 100 mL; V2 is the water volume (mL) of the second timer, usually 500 mL; T1 is the time of the first timing (s); T2 is the time of second timing (s). The anti-skid performance was measured by a pendulum friction tester, as shown in Figure 10c. The anti-skid performance test was performed according to ASTM E275.

The Impact Tests of Coating on Pavement Service Performance
The prepared No. 4 green coating was sprayed on the surface of the rutting plate at the dosage of 0.2 kg/m 2 , 0.4 kg/m 2 , 0.6 kg/m 2 , 0.8 kg/m 2 , 1.0 kg/m 2 , and 1.2 kg/m 2 . After the coating was fully cured, the adhesion performance between the coating and the pavement, the water permeability, and skid resistance of the pavement were tested.
The adhesion performance was evaluated by a drawing test in accordance with ASTM D4541 [28]. The drawing head and the coating were bonded together before the coating was cured. After curing, the drawing test was conducted. The test temperature was 25°C, and the drawing rate was 0.1 MPa/s, as shown in Figure 10a.
The water permeability coefficient was tested with a water seepage meter, in accordance with JTG E60-2008, as shown in Figure 10b. The measuring cylinder was filled with water, and then the valve was opened. When the water level dropped to 100 mL, the stopwatch was pressed to count the time. When the water level dropped to 500 mL, the stopwatch was pressed again to record the required time. The water seepage coefficient was calculated according to Equation (1).
where C W is the permeability coefficient, mL/min; V 1 is the water volume (mL) of the first timer, usually 100 mL; V 2 is the water volume (mL) of the second timer, usually 500 mL; T 1 is the time of the first timing (s); T 2 is the time of second timing (s). The anti-skid performance was measured by a pendulum friction tester, as shown in Figure 10c. The anti-skid performance test was performed according to ASTM E275.

Reflectivity of Coating
The reflectance test results of the coatings, with four different colors and different ratios of No. 1-6, are shown in Figure 11. From Figure 11a it can be seen that under the same ratio, the reflectivity of the green coating is the highest, with an average of about 60%, followed by the red coating, with an average of about 50%. When the wavelength is between 350 nm and 600 nm, the reflectance of the gray coating is higher than that of blue, and when the wavelength is between 600 nm and 800 nm, the reflectance of the blue coating is higher than that of gray. This may be because the reflection curve of gray without hue is relatively smooth, and the reflectivity of each wavelength is basically the same. The solar radiation is mainly concentrated in the visible region (400-760 nm), when the wavelength is 350-600 nm, it is close to the blue wavelength range (450-490 nm). The blue pigment absorbs other wavelengths and only reflects blue light, so the reflectivity is low. When the wavelength is 600-800 nm, it is all reflected, so the reflectivity increases.
From Figure 11b it can be seen that the reflectivity of the control group is only about 10%. While the reflectivity after the coating spraying was significantly increased, which shows that the coating could effectively increase the reflectivity of the specimen surface. The reflectivity of the coatings with different ratios was as follows: No. 4 > No. 5 > No. 6

Reflectivity of Coating
The reflectance test results of the coatings, with four different colors and different ratios of No. 1-6, are shown in Figure 11.

Reflectivity of Coating
The reflectance test results of the coatings, with four different colors and different ratios of No. 1-6, are shown in Figure 11. From Figure 11a it can be seen that under the same ratio, the reflectivity of the green coating is the highest, with an average of about 60%, followed by the red coating, with an average of about 50%. When the wavelength is between 350 nm and 600 nm, the reflectance of the gray coating is higher than that of blue, and when the wavelength is between 600 nm and 800 nm, the reflectance of the blue coating is higher than that of gray. This may be because the reflection curve of gray without hue is relatively smooth, and the reflectivity of each wavelength is basically the same. The solar radiation is mainly concentrated in the visible region (400-760 nm), when the wavelength is 350-600 nm, it is close to the blue wavelength range (450-490 nm). The blue pigment absorbs other wavelengths and only reflects blue light, so the reflectivity is low. When the wavelength is 600-800 nm, it is all reflected, so the reflectivity increases.
From Figure 11b it can be seen that the reflectivity of the control group is only about 10%. While the reflectivity after the coating spraying was significantly increased, which shows that the coating could effectively increase the reflectivity of the specimen surface. The reflectivity of the coatings with different ratios was as follows: No. 4 > No. 5 > No. 6   From Figure 11a it can be seen that under the same ratio, the reflectivity of the green coating is the highest, with an average of about 60%, followed by the red coating, with an average of about 50%. When the wavelength is between 350 nm and 600 nm, the reflectance of the gray coating is higher than that of blue, and when the wavelength is between 600 nm and 800 nm, the reflectance of the blue coating is higher than that of gray. This may be because the reflection curve of gray without hue is relatively smooth, and the reflectivity of each wavelength is basically the same. The solar radiation is mainly concentrated in the visible region (400-760 nm), when the wavelength is 350-600 nm, it is close to the blue wavelength range (450-490 nm). The blue pigment absorbs other wavelengths and only reflects blue light, so the reflectivity is low. When the wavelength is 600-800 nm, it is all reflected, so the reflectivity increases.
From Figure 11b it can be seen that the reflectivity of the control group is only about 10%. While the reflectivity after the coating spraying was significantly increased, which shows that the coating could effectively increase the reflectivity of the specimen surface. The reflectivity of the coatings with different ratios was as follows: No. 4 > No. 5 > No. 6  Comparing No. 4-6, it can be seen that the reflectivity of the coating is reduced after more floating beads are added. This may be because there are too many floating beads to disperse evenly, and they will cover the titanium dioxide, resulting in a decrease of reflectivity.

Cooling Performance of Coatings with Different Ratios
The cooling performance of No. 1-6 coating is shown in Figure 12.
Coatings 2020, 10, x FOR PEER REVIEW 9 of 15 beads. Comparing No. 4-6, it can be seen that the reflectivity of the coating is reduced after more floating beads are added. This may be because there are too many floating beads to disperse evenly, and they will cover the titanium dioxide, resulting in a decrease of reflectivity.

Cooling Performance of Coatings with Different Ratios
The cooling performance of No. 1-6 coating is shown in Figure 12. From Figure 12 it can be seen that compared with the uncoated specimens, the temperature of each layer of the coated specimens decreased to different degrees, and the cooling effect order was No. 4 > No. 6 > No. 5 > No. 3 > No. 2 > No. 1, and the cooling effect of No. 4 coated specimen was the best. This was mainly because the No. 4 coating contains more titanium dioxide, and an appropriate amount of floating beads, which can play an important role in heat reflection and heat insulation. The maximum temperature difference at different positions of the coated specimen was 4.9-9.1 °C on the upper surface, 3.45-7.6 °C at 2 cm of the specimen, and 4.2-7.5 °C at the bottom of the specimen. This shows that the coating could effectively reduce the temperature at each height of the specimen. From Figure 12 it can be seen that compared with the uncoated specimens, the temperature of each layer of the coated specimens decreased to different degrees, and the cooling effect order was No. 4 > No. 6 > No. 5 > No. 3 > No. 2 > No. 1, and the cooling effect of No. 4 coated specimen was the best. This was mainly because the No. 4 coating contains more titanium dioxide, and an appropriate amount of floating beads, which can play an important role in heat reflection and heat insulation. The maximum temperature difference at different positions of the coated specimen was 4.9-9.1 • C on the upper surface, 3.45-7.6 • C at 2 cm of the specimen, and 4.2-7.5 • C at the bottom of the specimen. This shows that the coating could effectively reduce the temperature at each height of the specimen.

Cooling Performance of Different Color Coatings
The cooling effect of the four color coatings of blue, gray, red, and green is shown in Figure 13.

Cooling Performance of Different Color Coatings
The cooling effect of the four color coatings of blue, gray, red, and green is shown in Figure 13. From Figure 13 it can be seen that the temperatures of each layer of the four color coating specimens were in the order of blue > gray > red > green, which indicates that the cooling effect of green coating was the best, and that of the blue coating was the worst. This is mainly because the wavelength range of the iodine tungsten lamp is 190-1100 nm, which is close to the wavelength of the visible light (400-760 nm) of the sun. The lamp can simulate solar radiation very well. The green coating had the highest reflectivity, so the cooling effect was the best. Compared with the control groups, the maximum cooling value of green coating reached 9.7 °C, 8.3 °C, and 6.6 °C, respectively.

Cooling Performances of Coating with Different Dosages
The cooling performances of the coating with different dosages are shown in Figure 14. From Figure 13 it can be seen that the temperatures of each layer of the four color coating specimens were in the order of blue > gray > red > green, which indicates that the cooling effect of green coating was the best, and that of the blue coating was the worst. This is mainly because the wavelength range of the iodine tungsten lamp is 190-1100 nm, which is close to the wavelength of the visible light (400-760 nm) of the sun. The lamp can simulate solar radiation very well. The green coating had the highest reflectivity, so the cooling effect was the best. Compared with the control groups, the maximum cooling value of green coating reached 9.7 • C, 8.3 • C, and 6.6 • C, respectively.

Cooling Performances of Coating with Different Dosages
The cooling performances of the coating with different dosages are shown in Figure 14. From Figure 14 it can be seen that the temperature of the surface, at 2 cm, and bottom of the specimen decreases with the increase of the coating dosage. When the coating dosage was increased from 0.4 kg/m 2 to 0.6 kg/m 2 , the maximum temperature difference changed the most. Compared with the control group, when the coating dosage was 0.8 kg/m 2 , the temperature drop on the surface of the specimen was the largest, reaching 8.1 °C, 6.8 °C, and 7.3 °C, respectively.

Wear Performance
The wear of the coating specimen is shown in Figure 15, and the cooling performance test results of the coating after wear are shown in Figure 16.
From Figure 15 it can be seen that the wear makes the coating fall off from the surface of the mixture, and that the wear phenomenon becomes more obvious with the increase of wear time. However, some coatings in the voids of the mixture were not worn off, and could still play a cooling role. From Figure 16 it can be seen that when the number of wear increased, the maximum cooling value of each coating decreased. After 20,000 times of wear, the cooling performance tended to be stable. The cooling performance of No. 1-3 coating decreased by about 19%, and that of No. 5-6 coating decreased by 15% per 10,000 times of wear, which indicates that the wear resistance of the coating can be improved by adding floating beads. From Figure 14 it can be seen that the temperature of the surface, at 2 cm, and bottom of the specimen decreases with the increase of the coating dosage. When the coating dosage was increased from 0.4 kg/m 2 to 0.6 kg/m 2 , the maximum temperature difference changed the most. Compared with the control group, when the coating dosage was 0.8 kg/m 2 , the temperature drop on the surface of the specimen was the largest, reaching 8.1 • C, 6.8 • C, and 7.3 • C, respectively.

Wear Performance
The wear of the coating specimen is shown in Figure 15, and the cooling performance test results of the coating after wear are shown in Figure 16.
From Figure 15 it can be seen that the wear makes the coating fall off from the surface of the mixture, and that the wear phenomenon becomes more obvious with the increase of wear time. However, some coatings in the voids of the mixture were not worn off, and could still play a cooling role. From Figure 16 it can be seen that when the number of wear increased, the maximum cooling value of each coating decreased. After 20,000 times of wear, the cooling performance tended to be stable. The cooling performance of No. 1-3 coating decreased by about 19%, and that of No. 5-6 coating decreased by 15% per 10,000 times of wear, which indicates that the wear resistance of the coating can be improved by adding floating beads.

Influence of Coating on Pavement Performance
The influence of the coating on pavement performance of the mixture is shown in Figure 17. From Figure 17 it can be seen that the adhesion strength increased at first, and then decreased with the increase of the coating dosage, reaching the maximum value of 1.65 MPa at about 0.6 kg/m 2 . The anti-skid performance and water permeability coefficient of the mixture both decreased with the increase of the coating dosage, but still maintained a high level. To ensure driving safety, the dosage of coating should be controlled at about 0.4-0.8 kg/m 2 .

Influence of Coating on Pavement Performance
The influence of the coating on pavement performance of the mixture is shown in Figure 17. From Figure 17 it can be seen that the adhesion strength increased at first, and then decreased with the increase of the coating dosage, reaching the maximum value of 1.65 MPa at about 0.6 kg/m 2 . The anti-skid performance and water permeability coefficient of the mixture both decreased with the increase of the coating dosage, but still maintained a high level. To ensure driving safety, the dosage of coating should be controlled at about 0.4-0.8 kg/m 2 .

Influence of Coating on Pavement Performance
The influence of the coating on pavement performance of the mixture is shown in Figure 17. From Figure 17 it can be seen that the adhesion strength increased at first, and then decreased with the increase of the coating dosage, reaching the maximum value of 1.65 MPa at about 0.6 kg/m 2 . The anti-skid performance and water permeability coefficient of the mixture both decreased with the increase of the coating dosage, but still maintained a high level. To ensure driving safety, the dosage of coating should be controlled at about 0.4-0.8 kg/m 2 .

Influence of Coating on Pavement Performance
The influence of the coating on pavement performance of the mixture is shown in Figure 17. From Figure 17 it can be seen that the adhesion strength increased at first, and then decreased with the increase of the coating dosage, reaching the maximum value of 1.65 MPa at about 0.6 kg/m 2 . The anti-skid performance and water permeability coefficient of the mixture both decreased with the increase of the coating dosage, but still maintained a high level. To ensure driving safety, the dosage of coating should be controlled at about 0.4-0.8 kg/m 2 .

Conclusions
The following conclusions were obtained from the results of this study: • Both titanium dioxide and floating beads can improve the reflectivity of the coating, and the reflectivity is proportional to the dosage of titanium dioxide.

•
The order of reflectivity and cooling effect of the four color coatings was green > red > gray > blue. The green coating is recommended, and its maximum cooling value can reach 9.7 °C • The cooling performance of the coating with 15% titanium dioxide and 10% floating beads was the best, and the higher dosage, the better the cooling effect. The cooling performance decreased with the increase of wear time and tended to be stable after 20,000 times of wear.

•
The adhesion strength between the coating and pavement reached the maximum value of 1.65 MPa when the dosage of coating was 0.6 kg/m 2 . The skid resistance and seepage coefficient of pavement decreased with the increase of coating dosage, but still maintained a high level.

•
The green coating with 15% titanium dioxide and 10% floating beads is recommended as the cooling coating of large void asphalt pavement, and its dosage should be controlled at about 0.4-0.8 kg/m 2 .

Conclusions
The following conclusions were obtained from the results of this study: • Both titanium dioxide and floating beads can improve the reflectivity of the coating, and the reflectivity is proportional to the dosage of titanium dioxide.

•
The order of reflectivity and cooling effect of the four color coatings was green > red > gray > blue. The green coating is recommended, and its maximum cooling value can reach 9.7 • C • The cooling performance of the coating with 15% titanium dioxide and 10% floating beads was the best, and the higher dosage, the better the cooling effect. The cooling performance decreased with the increase of wear time and tended to be stable after 20,000 times of wear.

•
The adhesion strength between the coating and pavement reached the maximum value of 1.65 MPa when the dosage of coating was 0.6 kg/m 2 . The skid resistance and seepage coefficient of pavement decreased with the increase of coating dosage, but still maintained a high level.

•
The green coating with 15% titanium dioxide and 10% floating beads is recommended as the cooling coating of large void asphalt pavement, and its dosage should be controlled at about 0.4-0.8 kg/m 2 .