A Versatile Porous Silver-Coordinated Material for the Heterogeneous Catalysis of Chemical Conversion with Propargylic Alcohols and CO2

The efficient transformation of carbon dioxide into useful chemical feedstock is of great significance, attracting intense research interest. The widely studied porous-coordinated polymers possess large pores to adsorb guest molecules and further allow the contact and to transfer the substrate molecule within their microenvironment. Here we present the synthesis of a silver-based metal-organic frameworks (MOFs) material with a three-dimensional structure by incorporating a tetraphenyl-ethylene moiety as the four-point connected node via the solvothermal method. This polymer exhibits as an efficient heterogeneous catalyst for the carboxylative cyclization of CO2 to α-methylene cyclic carbonates in excellent yields. Moreover, the introduction of silver (Ag (I)) chains in this framework shows the specific alkynophilicity to activate C≡C bonds in propargylic alcohols to greatly accelerate the efficient conversion, and the large pores in the catalyst exhibit a size-selective catalytic performance.


Introduction
Recently the utilization and transformation of carbon dioxide as a C1 source into valuable chemical products has become important for research purposes and attractive for both chemists and environmentalists [1][2][3]. Until now, a great deal of effort has been made to develop porous materials towards the adsorption and fixation of carbon dioxide [4][5][6][7][8]. Within the numerous examples, the porous coordination polymers, the metal-organic frameworks (MOFs), have been regarded as an excellent platform because of their intriguing structural diversity, modular nature and facile tenability [9][10][11][12]. Moreover, in terms of catalysis, these materials usually possess rich open metal sites, which are capable of CO 2 activation and further converting into catalysis products, highlighting the advantages of MOF materials for applications in many fields [13][14][15][16].
Silver (Ag (I)) complexes, which function as σand/or π-Lewis acids, have been shown to be powerful catalysts for alkyne transformations due to their d 10 electronic configurations, favoring interactions with the carbon-carbon π-bond of the alkynes, referred to as alkynophilicity [17,18]. The superior alkynophilicity leads to the facilitating of the π-coordination of Ag···C≡C bonds by nucleophilic attack. Therefore, the silver (I) ion is considered as one of the most ideal activators of the carbon-carbon triple bond in many usable organic reactions, including cycloaddition, hydroazidation

Structure Description
The synthesis of 1 was starting with the raw materials of AgNO3 and H4TCPE under the solvothermal reaction at 100 °C with the yield of 10%. Elemental and powder X-ray diffraction (XRD) analyses indicated that the bulk samples of 1 consisted of a pure, single phase ( Figure S5). Singlecrystal X-ray structural analysis revealed that 1 crystallizes in C2c space group. There are six independent Ag ions and one and a half ligands in its asymmetric unit (Figure 1b). All the Ag (I) ions are four-coordinated in a tetrahedral fashion and possess the same coordination environment, which includes two µ2-O bridges, one µ-O atom and onelattice water molecules. The Ag (I) ions are connected to form an infinite 1D chains (Figure 1d). The H4TCPE ligands are well-ordered arranged and the eight carboxylic groups in each ligand are all coordinated, acting as a µ4-bridge to connect each Ag chains extending the structure to the 3D frameworks ( Figure 2, see Figure S1, S2 in the supplementary materials for details). 1 possesses two kinds of channels along the c axis; including a triangular channel (A) and a hexagonal channel (B). These two channels are edge-sharing each other, with the overall lengths of the edges approximately 16.8 Å , and thus one hexagonal channel is surrounded by six triangular channels. The diagonal distances of the hexagonal channel are ranged from 31.1 to 33.8 Å . In the absence of guest molecules, the effective free volume of 1 calculated by PLATON program, was proven to be 59.3% of the crystal volume. The Ag chains are regarded as four-point-connected nodes, and the ligands are considered to be the linkers. The 3D framework of 1 can be depicted with the Schläfli symbol of 4 6 6 4 •7•8 ( Figure  S3). Notably, the type of this framework is similar to the reported MOF PCN-222, which self-assembly is by Zr ions and porphyrin ligand [31]. The major difference between these two MOFs is the vertex of each hexagonal and triangular one-dimensional open channel. Unlike the metal oxide Zr6 clusters as the vertices in PCN-222, the Ag chains in 1 are regarded as the edges of each hexagonal and triangular channel, and the C=C bonds of the TCPE ligands are located at the vertices ( Figure S4).

General Experimental Details
All chemicals were of reagent grade quality obtained from commercial sources and used without further purification. All epoxides were purchased from Acros (Shanghai, China) and distilled under a nitrogen atmosphere from calcium hydride (CaH 2 ) prior to use. Carbon dioxide (CO 2 , 99.995%) was purchased from the Dalian Institute of Special Gases (Dalian, China), and was then used as received. The elemental analyses of C, H and N were performed on a Vario EL III elemental analyzer (Frankfurt, Germany). Inductively-coupled plasma (ICP) analysis was performed on a Jarrel-AshJ-A1100 spectrometer (Waltham, MA, USA). The powder XRD diffractograms were obtained on a Rigaku D/MAX-2400 X-ray diffractometer (Tokyo, Japan) with a Cu sealed tube (λ = 1.54178 Å). IR spectra were recorded as KBr pellets on a NEXUS instrument (Madison, WI, USA). Thermogravimetric analyses (TGA) were carried out at a ramp rate of 10 • C min −1 in nitrogen flow with a SDTQ600 instrument (TA Instruments, New Castle, DE, USA). Gas sorption isotherms were measured using an Autosorb-IQ-C analyzer of Quantachrome (Boynton Beach, FL, USA). The CO 2 adsorption isotherms for desolvated compounds were collected in a relative pressure range from 10 to 1.0 × 10 5 Pa. Liquid UV-Vis spectra were performed on a TU-1900 spectrophotometer (Beijing, China). 1 H spectra were recorded on a Varian INOVA-400 MHz type spectrometer (Varian, Palo Alto, CA, USA). Their peak frequencies were referenced versus an internal standard (TMS) shifts at 0 ppm for 1 H NMR.

Preparation of 1
All reagents were used as purchased without further purification. Tetrakis (4-carboxyphenyl) ethylene (H 4 TCPE) was prepared according to the literature methods [26] and characterized by 1

Crystallography
X-ray intensity data were measured on a Bruker SMART APEX CCD-based diffractometer (Mo-Kα radiation, λ = 0.71073 Å, Karlsruhe, Germany) using the SMART and SAINT programs [27,28]. The crystal data was solved by direct methods and further refined by full-matrix least-squares refinements on F 2 using the SHELXL-97 software (Göttingen, Germany) and an absorption correction was performed using the SADABS program (Göttingen, Germany) [29,30]. The remaining atoms were found from successive full-matrix least-squares refinements on F 2 and Fourier syntheses. Non-H atoms were refined with anisotropic displacement parameters. The hydrogen atoms within the ligand backbones were fixed geometrically at calculated distances and allowed to ride on the parent non-hydrogen atoms. Details of the crystal parameters, data collection and refinement are summarized in Table 1.

Catalysis Experiments
In a typical reaction, the catalytic reaction was conducted by adding propargylic alcohols (3 mmol), catalyst (0.3 mmol% loading, based on each Ag site), triphenylphosphine (Ph 3 P, 2.5 mmol%) and acetonitrile (CH 3 CN) (1 mL) in a 25 mL autoclave reactor, purged with 0.5 MPa CO 2 under a constant pressure for 10 min to allow the system to equilibrate. The vessel was set in an oil bath with frequent stirring at the temperature of 50 • C for 30 h. At the end of the reaction, the reactor was placed into an ice bath for 20 min and then opened. The catalysts were separated by centrifugation, and a small aliquot of the supernatant reaction mixture was taken to be analyzed by 1 H NMR to calculate the yields of the reaction. The organic phase was collected and then purified by flash column chromatography on silica gel using petroleum ether-ethyl acetate as an eluent to give the desired products.

Structure Description
The synthesis of 1 was starting with the raw materials of AgNO 3 and H 4 TCPE under the solvothermal reaction at 100 • C with the yield of 10%. Elemental and powder X-ray diffraction (XRD) analyses indicated that the bulk samples of 1 consisted of a pure, single phase ( Figure S5). Single-crystal X-ray structural analysis revealed that 1 crystallizes in C2c space group. There are six independent Ag ions and one and a half ligands in its asymmetric unit ( Figure 1b). All the Ag (I) ions are four-coordinated in a tetrahedral fashion and possess the same coordination environment, which includes two µ 2 -O bridges, one µ-O atom and onelattice water molecules. The Ag (I) ions are connected to form an infinite 1D chains ( Figure 1d).
The H 4 TCPE ligands are well-ordered arranged and the eight carboxylic groups in each ligand are all coordinated, acting as a µ 4 -bridge to connect each Ag chains extending the structure to the 3D frameworks ( Figure 2, see Figures S1 and S2 in the supplementary materials for details). 1 possesses two kinds of channels along the c axis; including a triangular channel (A) and a hexagonal channel (B). These two channels are edge-sharing each other, with the overall lengths of the edges approximately 16.8 Å, and thus one hexagonal channel is surrounded by six triangular channels. The diagonal distances of the hexagonal channel are ranged from 31.1 to 33.8 Å. In the absence of guest molecules, the effective free volume of 1 calculated by PLATON program, was proven to be 59.3% of the crystal volume. The Ag chains are regarded as four-point-connected nodes, and the ligands are considered to be the linkers. The 3D framework of 1 can be depicted with the Schläfli symbol of 4 6 6 4 ·7·8 ( Figure S3). Notably, the type of this framework is similar to the reported MOF PCN-222, which self-assembly is by Zr ions and porphyrin ligand [31]. The major difference between these two MOFs is the vertex of each hexagonal and triangular one-dimensional open channel. Unlike the metal oxide Zr 6 clusters as the vertices in PCN-222, the Ag chains in 1 are regarded as the edges of each hexagonal and triangular channel, and the C=C bonds of the TCPE ligands are located at the vertices ( Figure S4).

XPS Analysis and CO2 Sorption Studies
The XPS analysis of 1 was examined in the solid state. Both survey and high-resolution spectra of Ag 3d are shown in Figure 3. The binding energy for the C 1s peak at 284.8 eV was used as a reference. From the XPS survey spectrum, we can observe that the elements Ag, O and N were contained in 1. In Figure 3b, two peaks at 374.7 and 368.8 eV are ascribed to Ag + (3d3/2) and Ag + (3d5/2), respectively [32]. To evaluate the porosity and affinity toward CO2 of this material, the CO2 sorption capability of 1 was evaluated. Before the measurement, the crystal samples were immersed in ethanol to exchange the uncoordinated solvent molecules. The PXRD pattern of the activated sample is a match with the

XPS Analysis and CO 2 Sorption Studies
The XPS analysis of 1 was examined in the solid state. Both survey and high-resolution spectra of Ag 3d are shown in Figure 3. The binding energy for the C 1s peak at 284.8 eV was used as a reference. From the XPS survey spectrum, we can observe that the elements Ag, O and N were contained in 1. In Figure 3b, two peaks at 374.7 and 368.8 eV are ascribed to Ag + (3d 3/2 ) and Ag + (3d 5/2 ), respectively [32].
To evaluate the porosity and affinity toward CO 2 of this material, the CO 2 sorption capability of 1 was evaluated. Before the measurement, the crystal samples were immersed in ethanol to exchange the uncoordinated solvent molecules. The PXRD pattern of the activated sample is a match with the fresh sample and calculated patterns, indicating the unchanged structure after desolvation ( Figure S5), and the TG curve of 1 has also been presented ( Figure S6). Then, the outgassing process was conducted at 100 • C under high vacuum for 6 h to obtain the activated samples. First of all, for further confirmation of the porosity, the N 2 adsorption measurement of the activated 1 was carried out at 77 K ( Figure S7) and this indicated a high uptake of 927.4 cm 3 g −1 . The Brunauer-Emmett-Teller (BET) surface area was calculated to be 1241.0 m 2 g −1 .
The XPS analysis of 1 was examined in the solid state. Both survey and high-resolution spectra of Ag 3d are shown in Figure 3. The binding energy for the C 1s peak at 284.8 eV was used as a reference. From the XPS survey spectrum, we can observe that the elements Ag, O and N were contained in 1. In Figure 3b, two peaks at 374.7 and 368.8 eV are ascribed to Ag + (3d3/2) and Ag + (3d5/2), respectively [32]. To evaluate the porosity and affinity toward CO2 of this material, the CO2 sorption capability of 1 was evaluated. Before the measurement, the crystal samples were immersed in ethanol to exchange the uncoordinated solvent molecules. The PXRD pattern of the activated sample is a match with the fresh sample and calculated patterns, indicating the unchanged structure after desolvation ( Figure  S5), and the TG curve of 1 has also been presented ( Figure S6). Then, the outgassing process was conducted at 100 °C under high vacuum for 6 h to obtain the activated samples. First of all, for further confirmation of the porosity, the N2 adsorption measurement of the activated 1 was carried out at 77 K ( Figure S7) and this indicated a high uptake of 927.4 cm 3 g −1 . The Brunauer-Emmett-Teller (BET) surface area was calculated to be 1241.0 m 2 g −1 . As shown in Figure 4, The CO 2 adsorption measurements for the activated 1 at 275 and 298 K are reversible, and the CO 2 absorbent amounts show a steady rise tendency as the increase of pressure with the uptake of 55.4 cm 3 g −1 (corresponding 2.47 mmol g −1 ) and 20.8 cm 3 g −1 (0.928 mmol g −1 ) at 1 bar, respectively. These results give a strong evidence of the high porosity for this MOF material and the possibility of adsorbing the CO 2 molecules within the pores. We envision that the high CO 2 uptake ability could play a significant role in facilitating this material to activate and catalyze CO 2 molecules as a C1 source in the following catalysis studies. As shown in Figure 4, The CO2 adsorption measurements for the activated 1 at 275 and 298 K are reversible, and the CO2 absorbent amounts show a steady rise tendency as the increase of pressure with the uptake of 55.4 cm 3 g −1 (corresponding 2.47 mmol g −1 ) and 20.8 cm 3 g −1 (0.928 mmol g −1 ) at 1 bar, respectively. These results give a strong evidence of the high porosity for this MOF material and the possibility of adsorbing the CO2 molecules within the pores. We envision that the high CO2 uptake ability could play a significant role in facilitating this material to activate and catalyze CO2 molecules as a C1 source in the following catalysis studies.

Dye Adsorption Properties
To verify the ability of this porous material to accommodate guest molecules, the dye adsorption studies of 1 have been examined. The dye molecule rhodamine B (RhB, where the structure of RhB is shown in the supplementary materials as Figure S8) was chosen for the adsorption experiments, not only due to its excellent photophysical properties, such as long adsorption, long emission wavelength and high fluorescence quantum yield [33], but also the suitable kinetic size with the window scale of the hexagonal channel in 1. By immersing the 5 mg sample 1 in 10 mL aqueous solution containing RhB, we can observe that the color of the solution has been gradually faded within 2 h. 10 µ L supernatant of the solution was taken at several time intervals and diluted for UV-Vis analysis. As shown in Figure 5, the UV-Vis absorption spectra of RhB solution exhibited an intense absorption band centered at 554 nm, which is assignable to the typical absorption band of RhB. With the addition of 1, the absorption intensity of the maximum absorption peak decreases from 2.4 to 0.2 in 120 min and no additional decrease was observed after that. These results indicate the absorption of RhB molecules, which are accessible into the pores of 1. We speculate that the ππ interactions and potential hydrogen bonds between the framework and dye molecules play an intrinsic role in the adsorption process [34]. Additionally, the dye-adsorbed crystals, after the UV-vis measurement and

Dye Adsorption Properties
To verify the ability of this porous material to accommodate guest molecules, the dye adsorption studies of 1 have been examined. The dye molecule rhodamine B (RhB, where the structure of RhB is shown in the supplementary materials as Figure S8) was chosen for the adsorption experiments, not only due to its excellent photophysical properties, such as long adsorption, long emission wavelength and high fluorescence quantum yield [33], but also the suitable kinetic size with the window scale of the hexagonal channel in 1. By immersing the 5 mg sample 1 in 10 mL aqueous solution containing RhB, we can observe that the color of the solution has been gradually faded within 2 h. 10 µL supernatant of the solution was taken at several time intervals and diluted for UV-Vis analysis. As shown in Figure 5, the UV-Vis absorption spectra of RhB solution exhibited an intense absorption band centered at 554 nm, which is assignable to the typical absorption band of RhB. With the addition of 1, the absorption intensity of the maximum absorption peak decreases from 2.4 to 0.2 in 120 min and no additional decrease was observed after that. These results indicate the absorption of RhB molecules, which are accessible into the pores of 1. We speculate that the π···π interactions and potential hydrogen bonds between the framework and dye molecules play an intrinsic role in the adsorption process [34]. Additionally, the dye-adsorbed crystals, after the UV-vis measurement and being isolated from the solution, have been further examined by confocal laser scanning microscopy. The bright-field images and confocal images of the obtained samples were scanned at λ em = 510-610 nm, exited by λ ex = 488 nm through a 405/488 nm filter. A strong green fluorescence response can be observed in the bright-field image that can be assigned to adsorbed RhB molecules. These results are consist with the UV-vis experiments and suggest that the accessible pores and adsorption ability of 1 provides the superiority for further catalysis studies.

Catalysis Studies
Our catalytic experiments were initially investigated for the carboxylic cyclization of propargylic alcohols as the model reacted with CO2. In a typical experiment, the reactions were conducted in an autoclave reactor using the propargyl alcohol (3 mmol) with CO2 purged to 0.5 MPa in 1 mL CH3CN at 50 °C. 1 H NMR analysis reveal that catalyst 1 (0.3 mol% loading, based on each Ag site) could act as an effective heterogeneous catalyst for this catalysis reaction in the presence of 2.5 mol% triphenyl phosphine (Ph3P), which afforded the 97% yield, and the TON value is 320 within 30 h (Table 2). Control experiments suggest that no detectable conversion occurs in the absence of catalysts or the additive Ph3P, and we replaced the Ph3P with other additives (such as, TBUP, DBU and TEA), which also could not afford the high yields (20%, 32% and 18%, respectively). However, Ph3P itself was ineffective to this reaction under the given conditions.

Catalysis Studies
Our catalytic experiments were initially investigated for the carboxylic cyclization of propargylic alcohols as the model reacted with CO 2 . In a typical experiment, the reactions were conducted in an autoclave reactor using the propargyl alcohol (3 mmol) with CO 2 purged to 0.5 MPa in 1 mL CH 3 CN at 50 • C. 1 H NMR analysis reveal that catalyst 1 (0.3 mol% loading, based on each Ag site) could act as an effective heterogeneous catalyst for this catalysis reaction in the presence of 2.5 mol% triphenyl phosphine (Ph 3 P), which afforded the 97% yield, and the TON value is 320 within 30 h (Table 2). Control experiments suggest that no detectable conversion occurs in the absence of catalysts or the additive Ph 3 P, and we replaced the Ph 3 P with other additives (such as, TBUP, DBU and TEA), which also could not afford the high yields (20%, 32% and 18%, respectively). However, Ph 3 P itself was ineffective to this reaction under the given conditions.
The high yield of our Ag-based catalytic system was mainly attributed to the abound presence of Ag (I) ions capable of activating carbon-carbon triple bonds of the substrate propargyl alcohol. As for the catalyst 1, this react ion was also carried out and underwent the smooth CO 2 balloon at room temperature to afford a low yield of 4.9%, suggesting that relatively high temperature and slight CO 2 pressure were required for the activation of the substrates. However, when we just increased the pressure of CO 2 to 1 MPa, the reaction yields were not remarkably increased under other fixed conditions, and at a fixed CO 2 pressure (0.5 MPa), the yields increased from 6.2 to 97% with an increased temperature from 25 to 50 • C, but remained almost invariable with the temperature further increased to 80 • C ( Figure 6). These results fully suggest that the activation of CO 2 was not the rate-limit step, but the activation of carbon-carbon triple bonds by the Ag (I) ions. Additionally, the removal of 1 by filtration after 18 h shut down the reaction, and no additional conversions were observed for another 18 h under the same reaction conditions. This observation suggested that 1 features a typical heterogeneous catalyst nature in the catalytic system and is stable enough to ensure that no leaching of metal ions occurs during the catalysis process. The recyclability studies of catalyst 1 were also performed by simple filtration, washed with dichloromethane and dried, and reused for successive rounds with fresh Ph 3 P under the same conditions. The yields of cyclic carbonates were not significantly affected in the five catalytic cycles (Figure S9), ranging from 97% to 90%, although the loss of small amounts of the catalyst is unavoidable. IR spectroscopy of the catalyst after recycle reactions could match with the fresh catalyst ( Figure S10), indicating the structural integrity and chemical stability of 1.  Subsequently, several propargyl alcohols with various substituted R 1 groups were performed for the carboxylative cyclization with CO2 under the same reaction conditions, and no significant change in the conversion was observed which all gave high yields, except for the CMe3 group, which showed a large decline in the reaction yield (78%, Entry 5). Moreover, changing a larger aromatic substrate in the substituted R 2 group of propargyl alcohols could also cause the yield and TON value to obvious decreases (Entry 8). These results indicate that the electron-drawing or the electrondonating groups on the phenyl of propargyl alcohol have less effect on the reaction yields, and the main factor affecting the yield is the size of substrates. It is postulated that the strong interaction between the substrate propargyl alcohol and our catalyst existed as a significant factor to enhance the high conversion of the catalytic reaction. Combining the analysis of dye absorption studies, we envision that the propargyl alcohol molecules were adsorbed and activated within the channels of our MOFs. Thus, the size of the channels is also an important factor that controls the efficiency of the conversion by influencing the transport of the substrates and products through the channels, which shows the size-selectivity in the catalytic reaction. Additionally, the unique decentralized silver (I) chains, which endow the specific Subsequently, several propargyl alcohols with various substituted R 1 groups were performed for the carboxylative cyclization with CO 2 under the same reaction conditions, and no significant change in the conversion was observed which all gave high yields, except for the CMe 3 group, which showed a large decline in the reaction yield (78%, Entry 5). Moreover, changing a larger aromatic substrate in the substituted R 2 group of propargyl alcohols could also cause the yield and TON value to obvious decreases (Entry 8). These results indicate that the electron-drawing or the electron-donating groups on the phenyl of propargyl alcohol have less effect on the reaction yields, and the main factor affecting the yield is the size of substrates.
It is postulated that the strong interaction between the substrate propargyl alcohol and our catalyst existed as a significant factor to enhance the high conversion of the catalytic reaction. Combining the analysis of dye absorption studies, we envision that the propargyl alcohol molecules were adsorbed and activated within the channels of our MOFs. Thus, the size of the channels is also an important factor that controls the efficiency of the conversion by influencing the transport of the substrates and products through the channels, which shows the size-selectivity in the catalytic reaction. Additionally, the unique decentralized silver (I) chains, which endow the specific alkynophilicity to activate C≡C bonds, and thus greatly accelerate the efficient conversion of CO 2 to α-alkylidene cyclic carbonates in a heterogeneous manner. From a mechanistic point of view, the Ph 3 P plays a key role in the promotion of CO 2 fixation and activation in the first step of the catboxylative cycloaddition, which the alcoholic hydroxyl was activated by the catalyst 1, and CO 2 was activated by Ph 3 P to form the carbonate intermediate (Figure 7). The O atom in hydroxyl group is more favorable to the electrophilic attack of the C atom in CO 2 . Subsequently, a nucleophilic attack to the silver propargylic carbonate intermediate that generated the Ag···C≡C bonds by π-activation occurred for the next intramolecular ring-closing [35]. The corresponding carboxylative cyclization product is thus yielded with the process of proto-demetallation and the regeneration of Ph 3 P [36].

Conclusions
In conclusion, a porous Ag(I)-based polymer has been synthesized by incorporating the tetraphenylethylene moiety as the backbone, and proven to be an efficient heterogeneous catalyst for the carboxylative cyclization of CO2 to α-methylene cyclic carbonates in excellent yields. The large pores of 1 benefit for the adsorption of dye molecules and also allow the interaction and a fast transportation of the substrate molecule within their microenvironments. The introduced Ag (I) chains in the frameworks play an important role in the activation of subtract molecules for the internal alkynes by π-activation. This approach provided a highly promising method for the development of more practical industrial synthesis. Further work will focus on designing more efficient catalysts to optimize such reactions by improving the conversion and shortening the whole reaction times.
Supplementary Materials: The following are available online at www.mdpi.com/xxx/s1, Figure S1: the 3D structural framework of 1 along a axis, Figure S2: the 3D structural framework of 1 along b axis, Figure S3: the truncated 3D structure and schematic representation of 1 network, Figure S4: structure comparison of 1 in this

Conclusions
In conclusion, a porous Ag(I)-based polymer has been synthesized by incorporating the tetraphenylethylene moiety as the backbone, and proven to be an efficient heterogeneous catalyst for the carboxylative cyclization of CO 2 to α-methylene cyclic carbonates in excellent yields. The large pores of 1 benefit for the adsorption of dye molecules and also allow the interaction and a fast transportation of the substrate molecule within their microenvironments. The introduced Ag (I) chains in the frameworks play an important role in the activation of subtract molecules for the internal alkynes by π-activation. This approach provided a highly promising method for the development of more practical industrial synthesis. Further work will focus on designing more efficient catalysts to optimize such reactions by improving the conversion and shortening the whole reaction times.

Supplementary Materials:
The following are available online at http://www.mdpi.com/2079-4991/9/11/1566/s1, Figure S1: the 3D structural framework of 1 along a axis, Figure S2: the 3D structural framework of 1 along b axis, Figure S3: the truncated 3D structure and schematic representation of 1 network, Figure S4: structure comparison of 1 in this work and the reported MOF PCN-222, Figure S5: PXRD patterns of 1 (red), its calculated pattern based on the single-crystal simulation (black) and the activated sample after desolvation (blue), Figure S6: TG curve of 1, Figure S7: Gas adsorption isotherms of activated 1 of N 2 at 77 K, Figure S8: The structure of RhB molecule used in the dye adsorption experiments, Figure S9: The recycling experiments of 1 at each round, Figure S10: IR spectra of 1 and the sample after reaction.
Author Contributions: L.Y. and Z.Z. conceived and designed the experiments; L.Y. and Y.D. fabricated and tested the experiments; D.Z. and S.W. analyzed the experimental data; L.Y. and Z.Z. wrote, reviewed and edited the paper. All authors discussed the results and commented on the manuscript.
Funding: This research was funded by Shandong Province Natural Science Foundation (ZR2018BB002) and also co-financed by the National Natural Science Foundation of China (21801156) and the State Key Laboratory of Fine Chemicals (KF1815).

Conflicts of Interest:
The authors declare no conflict of interest.