Plasmonic Ag Nanoparticle-Loaded n-p Bi2O2CO3/α-Bi2O3 Heterojunction Microtubes with Enhanced Visible-Light-Driven Photocatalytic Activity

In this study, n-p Bi2O2CO3/α-Bi2O3 heterojunction microtubes were prepared via a one-step solvothermal route in an H2O-ethylenediamine mixed solvent for the first time. Then, Ag nanoparticles were loaded onto the microtubes using a photo-deposition process. It was found that a Bi2O2CO3/α-Bi2O3 heterostructure was formed as a result of the in situ carbonatization of α-Bi2O3microtubes on the surface. The photocatalytic activities of α-Bi2O3 microtubes, Bi2O2CO3/α-Bi2O3 microtubes, and Ag nanoparticle-loaded Bi2O2CO3/α-Bi2O3 microtubes were evaluated based on their degradation of methyl orange under visible-light irradiation (λ > 420 nm). The results indicated that Bi2O2CO3/α-Bi2O3 with a Bi2O2CO3 mass fraction of 6.1% exhibited higher photocatalytic activity than α-Bi2O3. Loading the microtubes with Ag nanoparticles significantly improved the photocatalytic activity of Bi2O2CO3/α-Bi2O3. This should be ascribed to the internal static electric field built at the heterojunction interface of Bi2O2CO3 and α-Bi2O3 resulting in superior electron conductivity due to the Ag nanoparticles; additionally, the heterojunction at the interfaces between two semiconductors and Ag nanoparticles and the local electromagnetic field induced by the surface plasmon resonance effect of Ag nanoparticles effectively facilitate the photoinduced charge carrier transfer and separation of α-Bi2O3. Furthermore, loading of Ag nanoparticles leads to the formation of new reactive sites, and a new reactive species ·O2− for photocatalysis, compared with Bi2O2CO3/α-Bi2O3.


Introduction
In the past decades, photocatalytic technology through semiconductor oxides for the purification and treatment of polluted water and air has been extensively studied. Recent research activity in the field of heterogeneous photocatalysis is focused on exploiting novel and more efficient photocatalysts capable of using visible light for the degradation of organic contaminants. Many Bi-based semiconductors, such as BiVO 4 [1], Bi 2 O 3 [2], Bi 2 WO 6 [3], Bi 2 O 2 CO 3 [4], Bi 2 MoO 6 [5], and BiPO 4 [6] have been developed as visiblelight-driven photocatalysts. Among them, Bi 2 O 3 has received significant attention in recent years. It is well known that Bi 2 O 3 is a p-type semiconductor with five crystallographic polymorphs denoted as monoclinic α-Bi 2 O 3 , tetragonal β-Bi 2 O 3 , cubic (BCC) γ-Bi 2 O 3 , cubic (FCC) δ-Bi 2 O 3 , and triclinic ω-Bi 2 O 3 [2]. Monoclinic α-Bi 2 O 3 , which is nontoxic and chemically stable in aqueous solution under irradiation, has been proved to be a visible-light-driven photocatalyst, owing to its narrow band-gap energy (band gap around 2.6-2.8 eV). However, as a photocatalyst, α-Bi 2 O 3 suffered severe problems in practical

Synthesis of Ag NP-Loaded Bi2O2CO3/α-Bi2O3 Heterostructure Microtubes
The fabrication of Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterostructure microtubes was conducted as follows. First, 0.5 g of Bi2O2CO3/α-Bi2O3 heterostructure microtubes was dispersed into the AgNO3 ((AR grade, Sinopharm Chemical Reagent Co., Ltd, Shanghai, China) aqueous solution under stirring. The theoretical loading amount of silver was set at 3 wt% in the Ag/Bi2O2CO3/α-Bi2O3 sample. After being ultrasonically treated for 10 min, the suspension was further magnetically stirred for 10 h in the dark, followed by UV illumination for 2 h under stirring. The black powder was centrifuged, rinsed with distilled water repeatedly to purify the product, and finally dried at 80 °C in air.

Characterization
The crystalline structure of the samples was analyzed by a Rigaku D/Max 2500 powder diffractometer (XRD) (Tokyo, Japan) with Cu Kα radiation (λ = 1.5406 Å). The morphology of the as-prepared samples was characterized by field-emission scanning electron microscopy (FESEM, FEI SIRION 200, Hillsboro, OR, USA), and transmission electron microscopy (TEM, Philips Tecnai 20 G2 S-TWIN, Hillsboro, OR, USA). X-ray photoelectron spectroscopy (XPS) data of the samples were determined with a K-Alpha 1063 electron spectrometer from Thermo Fisher Scientific (East Grinstead, West Sussex, UK) using 72W Al Kα radiation. Infrared spectroscopy analysis (IR) of the samples was performed on an AVATAR360 IR analyzer (Madison, WI, USA). UV-vis diffuse reflectance spectra (UV-vis) were measured with a Specord 200 UV spectrophotometer (Schönwalde-Glien, Germany).

Photocatalytic Experiments
The photocatalytic properties of the as-prepared samples were assessed by degradation of MO under the irradiation of visible light (λ > 420 nm). First, 0.5 g of photocatalyst was added to 100 mL of 10 mg/L MO aqueous solution. Then, the suspension was magnetically stirred in the dark for 1h before commencing the photocatalytic reactions, to allow the system to reach an adsorption/desorption equilibrium. All photocatalytic reactions were carried out in a laboratory constructed photo-reactor under visible light irradiation from a 500W Xe lamp equipped with a 420-nanometer cutoff filter. The photocatalytic system was magnetically stirred simultaneously during the course of illumination.

Synthesis of Ag NP-Loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 Heterostructure Microtubes
The fabrication of Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterostructure microtubes was conducted as follows. First, 0.5 g of Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterostructure microtubes was dispersed into the AgNO 3 ((AR grade, Sinopharm Chemical Reagent Co., Ltd, Shanghai, China) aqueous solution under stirring. The theoretical loading amount of silver was set at 3 wt% in the Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 sample. After being ultrasonically treated for 10 min, the suspension was further magnetically stirred for 10 h in the dark, followed by UV illumination for 2 h under stirring. The black powder was centrifuged, rinsed with distilled water repeatedly to purify the product, and finally dried at 80 • C in air.

Characterization
The crystalline structure of the samples was analyzed by a Rigaku D/Max 2500 powder diffractometer (XRD) (Tokyo, Japan) with Cu Kα radiation (λ = 1.5406 Å). The morphology of the as-prepared samples was characterized by field-emission scanning electron microscopy (FESEM, FEI SIRION 200, Hillsboro, OR, USA), and transmission electron microscopy (TEM, Philips Tecnai 20 G2 S-TWIN, Hillsboro, OR, USA). X-ray photoelectron spectroscopy (XPS) data of the samples were determined with a K-Alpha 1063 electron spectrometer from Thermo Fisher Scientific (East Grinstead, West Sussex, UK) using 72W Al Kα radiation. Infrared spectroscopy analysis (IR) of the samples was performed on an AVATAR360 IR analyzer (Madison, WI, USA). UV-vis diffuse reflectance spectra (UV-vis) were measured with a Specord 200 UV spectrophotometer (Schönwalde-Glien, Germany).

Photocatalytic Experiments
The photocatalytic properties of the as-prepared samples were assessed by degradation of MO under the irradiation of visible light (λ > 420 nm). First, 0.5 g of photocatalyst was added to 100 mL of 10 mg/L MO aqueous solution. Then, the suspension was magnetically stirred in the dark for 1h before commencing the photocatalytic reactions, to allow the system to reach an adsorption/desorption equilibrium. All photocatalytic reactions were carried out in a laboratory constructed photo-reactor under visible light irradiation from a 500W Xe lamp equipped with a 420-nanometer cutoff filter. The photocatalytic system was magnetically stirred simultaneously during the course of illumination. At given time intervals, 3.5-milliliter aliquots of the aqueous solution were collected and centrifuged. The concentrations of MO solution were evaluated by measuring its absorption on a UNICO UV-2100 spectrophotometer (Palo Alto, CA, USA) at 463 nm, from which the photocatalytic activity was calculated.

Results and Discussion
XRD was used to analyze the phase composition and crystal structure of the samples. Figure 2 shows the XRD patterns of the samples produced at 140 • C for 10 h in the ethylenediamine-water mixture with various ratios of V en :V water . For all the samples, the diffraction peaks are sharp, and the intensity of the diffraction is high, indicating that the products are well-crystallized. In addition, the diffraction peaks assigned to α-Bi 2 O 3 (JCPDS Card No. 71-2274) are accompanied by three characteristic peaks of Bi 2 O 2 CO 3 (JCPDS Card No. 41-1488) at 12.9 • , 23.8 • , and 30.2 • . No peaks of any additional phases were detected, indicating that the products exhibit a coexistence of both α-Bi 2 O 3 and Bi 2 O 2 CO 3 phases. Furthermore, when increasing the ratio of V en :V water , the intensity of the characteristic peaks attributed to Bi 2 O 2 CO 3 gradually increases, whereas the intensity of the diffraction peaks assigned to α-Bi 2 O 3 decreases. The mass fractions of the Bi 2 O 2 CO 3 in the samples are 0%, 6.1%, 15.5%, 36.7%, 47.9%, and 51.3% for the samples prepared at V en :V water ratios of 1:7, 2:6, 3:5, 4:4, 5:3, and 6:2, respectively, which were estimated from XRD intensity data by using the formula as expressed by Equation (1): where I C and I O are the integrated intensities of Bi 2 O 2 CO 3 (013) and α-Bi 2 O 3 (113) diffraction peaks, respectively. It can be inferred that the ratio of V en :V water plays a key role in the phase composition of the products, and that a larger proportion of en favors the generation of Bi 2 O 2 CO 3 . At given time intervals, 3.5-milliliter aliquots of the aqueous solution were collected and centrifuged. The concentrations of MO solution were evaluated by measuring its absorption on a UNICO UV-2100 spectrophotometer (Palo Alto, CA, USA) at 463 nm, from which the photocatalytic activity was calculated.

Results and Discussion
XRD was used to analyze the phase composition and crystal structure of the samples. Figure 2 shows the XRD patterns of the samples produced at 140 °C for 10 h in the ethylenediamine-water mixture with various ratios of Ven:Vwater. For all the samples, the diffraction peaks are sharp, and the intensity of the diffraction is high, indicating that the products are well-crystallized. In addition, the diffraction peaks assigned to α-Bi2O3 (JCPDS Card No. 71-2274) are accompanied by three characteristic peaks of Bi2O2CO3 (JCPDS Card No. 41-1488) at 12.9°, 23.8°, and 30.2°. No peaks of any additional phases were detected, indicating that the products exhibit a coexistence of both α-Bi2O3 and Bi2O2CO3 phases. Furthermore, when increasing the ratio of Ven:Vwater, the intensity of the characteristic peaks attributed to Bi2O2CO3 gradually increases, whereas the intensity of the diffraction peaks assigned to α-Bi2O3 decreases. The mass fractions of the Bi2O2CO3 in the samples are 0%, 6.1%, 15.5%, 36.7%, 47.9%, and 51.3% for the samples prepared at Ven:Vwater ratios of 1:7, 2:6, 3:5, 4:4, 5:3, and 6:2, respectively, which were estimated from XRD intensity data by using the formula as expressed by Equation (1): where IC and IO are the integrated intensities of Bi2O2CO3 (013) and α-Bi2O3 (113) diffraction peaks, respectively. It can be inferred that the ratio of Ven:Vwater plays a key role in the phase composition of the products, and that a larger proportion of en favors the generation of Bi2O2CO3. How are the α-Bi2O3 and Bi2O2CO3 generated? Why does the proportion of en in the mixed solvent have such a significant effect on the generation of Bi2O2CO3? In order to answer these questions, XRD investigations on the precursor and the products obtained at 140 °C for 1, 3, 5, 7.5, 10, and 12.5 h in the en-water mixture with a Ven:Vwater ratio of 2:6 were carried out. The results are presented in Figure 3. For the precursor and the products obtained after solvothermal treatment for 1 h, 3 h, 5 h, and 7.5 h, all the diffraction peaks How are the α-Bi 2 O 3 and Bi 2 O 2 CO 3 generated? Why does the proportion of en in the mixed solvent have such a significant effect on the generation of Bi 2 O 2 CO 3 ? In order to answer these questions, XRD investigations on the precursor and the products obtained at 140 • C for 1, 3, 5, 7.5, 10, and 12.5 h in the en-water mixture with a V en :V water ratio of 2:6 were carried out. The results are presented in Figure 3. For the precursor and the products obtained after solvothermal treatment for 1 h, 3 h, 5 h, and 7.5 h, all the diffraction peaks can be readily indexed to a pure α-Bi 2 O 3 (JCPDS Card No. 71-2274) phase, revealing that α-Bi 2 O 3 was formed before solvothermal treatment, and that a pure α-Bi 2 O 3 phase could be maintained via controlling the reaction time using this technique. Moreover, the diffraction peaks of the solvothermal-treated products are much narrower than that of the precursor, and the peak intensities of the solvothermal-treated products are much higher, indicating that solvothermal treatment improved the crystallinity of the products. As the time increased to 10 h, the diffraction pattern of the sample indexed to the mixture of α- can be readily indexed to a pure α-Bi2O3 (JCPDS Card No. 71-2274) phase, revealing that α-Bi2O3 was formed before solvothermal treatment, and that a pure α-Bi2O3 phase could be maintained via controlling the reaction time using this technique. Moreover, the diffraction peaks of the solvothermal-treated products are much narrower than that of the precursor, and the peak intensities of the solvothermal-treated products are much higher, indicating that solvothermal treatment improved the crystallinity of the products. As the time increased to 10 h, the diffraction pattern of the sample indexed to the mixture of α-Bi2O3 and Bi2O2CO3 (JCPDS Card No. 41-1488). Three weak peaks at 12.9°, 23.8°, and 30.2° can be attributed to Bi2O2CO3. Further prolonging the time to 12.5 h, the intensity of the peaks indexed to Bi2O2CO3 increases, suggesting an increase in the amount of Bi2O2CO3. From the XRD results, it can be seen that the Bi2O2CO3/α-Bi2O3 composite is derived from α-Bi2O3, but not formed at the precursor stage. This is also supported by FT-IR spectra of the precursor and the products obtained after solvothermal treatment for 7.5 h and 10 h ( Figure 4). For all the samples, the weak adsorptions at 1460, 1384, and 1315 cm −1 may be attributed to the carbonated species formed by the reactions between the surface hydroxyl groups and atmospheric CO2. The peaks at around 545, 505, and 430 cm −1 are due to the vibration of Bi-O bonds in BiO6 octahedral units [24,25]. It is necessary to mention that only the product obtained after solvothermal treatment for 10 h shows an extra band at 850 cm −1 , which is ascribed to the CO3 2− , indicating the formation of Bi2O2CO3 at this stage [24,25]. This is also supported by FT-IR spectra of the precursor and the products obtained after solvothermal treatment for 7.5 h and 10 h ( Figure 4). For all the samples, the weak adsorptions at 1460, 1384, and 1315 cm −1 may be attributed to the carbonated species formed by the reactions between the surface hydroxyl groups and atmospheric CO 2 . The peaks at around 545, 505, and 430 cm −1 are due to the vibration of Bi-O bonds in BiO 6 octahedral units [24,25]. It is necessary to mention that only the product obtained after solvothermal treatment for 10 h shows an extra band at 850 cm −1 , which is ascribed to the CO 3 2− , indicating the formation of Bi 2 O 2 CO 3 at this stage [24,25].  Based on the XRD and FT-IR analyses, formation of the Bi2O2CO3/α-Bi2O3 composite in the present solvothermal process could be described by following reactions: Based on the XRD and FT-IR analyses, formation of the Bi 2 O 2 CO 3 /α-Bi 2 O 3 composite in the present solvothermal process could be described by following reactions: When Bi(NO 3 ) 3 ·5H 2 O was added to the en-water mixture with a V en :V water ratio of 2:6, the reaction was performed in a strong alkali condition, as indicated in Equation (2). Abundant hydroxide ions firstly reacted with Bi 3+ to produce Bi(OH) 3 , which then dehydrated to form α-Bi 2 O 3 under vigorous stirring, as illustrated in Equations (3) and (4). Due to the presence of en, the mixed solvent easily captured CO 2 from the air to generate CO 3 2− before being transferred into the autoclave. In prolonging the solvothermal treatment time to 10 h, a small amount of obtained α-Bi 2 O 3 reacted with CO 3 2− in the solvent to give rise to Bi 2 O 2 CO 3 , as summarized in Equations (5) and (6) [26]. It can be concluded that Bi 2 O 2 CO 3 was formed by in situ carbonatization of α-Bi 2 O 3 . A larger proportion of en in the solvent captures more CO 2 to generate more CO 3 2− , resulting in a higher ratio of Bi 2 O 2 CO 3 in the product. Figure 5a,b show the SEM images of the products obtained by solvothermal treatment at 140 • C for 10 h in the ethylenediamine-water mixture with V en :V water ratios of 1:7 and 2:6, respectively. It can be seen that both samples consist of microtubes. The magnified image of the microtubes presented in the left insert of Figure 5b clearly demonstrates that the microtubes have well-defined hexagonal cross sections. The SEM image with low magnification (Figure 5c) reveals that the products obtained in the ethylenediaminewater mixture with a V en :V water ratio of 2:6 are almost entirely microtubes with lengths of 5-30 µm, and side lengths of 0.2-1 µm, indicating the high yield of microtubes in this condition. However, when the V en :V water ratio was controlled at 4:4, 5:3, and 6:2, the as-prepared products contain microtubes and a lot of irregular particles, as presented in Figure 5d-f, respectively. This indicates that the proportion of en in the mixed solvent also has a significant effect on the morphology of the products. More en in the solvent captures more CO 2 to generate more CO 3 2− , which makes more α-Bi 2 O 3 carbonatized, resulting in the destruction of microtubes. Figure 6a presents the TEM image of the obtained α-Bi 2 O 3 microtube prepared at a V en :V water ratio of 2:6 for 7.5 h. There is a contrast between the inner and outside parts of the sample, confirming its tubular structure. The lattice spacing of about 0.34 nm between adjacent lattice planes in the insert corresponds to the interplanar spacing of the (002) plane of α-Bi 2 O 3 . Figure 6b shows the TEM image of Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes prepared at a V en :V water ratio of 2:6 for 10 h. It can be clearly seen that a lot of nanoparticles highly disperse on the surface of α-Bi 2 O 3 microtubes, which are considered to be Bi 2 O 2 CO 3 particles. No "support-free" Bi 2 O 2 CO 3 nanoparticles are found, indicating that those nanoparticles are strongly anchored to the α-Bi 2 O 3 microtubes. From the HRTEM image of the sample shown in Figure 6c, it can be seen that the lattice structure of α-Bi 2 O 3 is very orderly and different from that of Bi 2 O 2 CO 3 nanoparticles. The measured lattice fringes of 0.34 nm well match the (002) crystallographic planes of α-Bi 2 O 3 . In particular, it can be well confirmed that the Bi 2 O 2 CO 3 nanoparticles are anchored on the surface of the α-Bi 2 O 3 substrate, forming a good attachment. The obvious interface between the Bi 2 O 2 CO 3 nanoparticles and the α-Bi 2 O 3 microtubes shown in HRTEM images implies the formation of a well-defined heterojunction structure. Because α-Bi 2 O 3 and Bi 2 O 2 CO 3 are p-type and n-type semiconductors, respectively, the heterojunction can be considered to be a well-defined and well-formed p-n junction.  Figure 6a presents the TEM image of the obtained α-Bi2O3 microtube prepared at a Ven:Vwater ratio of 2:6 for 7.5 h. There is a contrast between the inner and outside parts of the sample, confirming its tubular structure. The lattice spacing of about 0.34 nm between adjacent lattice planes in the insert corresponds to the interplanar spacing of the (002) plane of α-Bi2O3. Figure 6b shows the TEM image of Bi2O2CO3/α-Bi2O3 heterojunction microtubes prepared at a Ven:Vwater ratio of 2:6 for 10 h. It can be clearly seen that a lot of nanoparticles highly disperse on the surface of α-Bi2O3 microtubes, which are considered to be Bi2O2CO3 particles. No "support-free" Bi2O2CO3 nanoparticles are found, indicating that those nanoparticles are strongly anchored to the α-Bi2O3 microtubes. From the HRTEM image of the sample shown in Figure 6c, it can be seen that the lattice structure of α-Bi2O3 is very orderly and different from that of Bi2O2CO3 nanoparticles. The measured lattice fringes of 0.34 nm well match the (002) crystallographic planes of α-Bi2O3. In particular, it can be well confirmed that the Bi2O2CO3 nanoparticles are anchored on the surface of the α-Bi2O3 substrate, forming a good attachment. The obvious interface between the Bi2O2CO3 nanoparticles and the α-Bi2O3 microtubes shown in HRTEM images implies the formation of a well-defined heterojunction structure. Because α-Bi2O3 and Bi2O2CO3 are p-type and n-type semiconductors, respectively, the heterojunction can be considered to be a well-defined and well-formed p-n junction.   Figure 7 shows the high-resolution XPS spectra of Bi, O, and Ag in Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes with R c of 6.1%. As observed in the XPS spectrum of Bi 4f (Figure 7a), two strong peaks at 163.8 and 158.5 eV are assigned to Bi 4f 5/2 and Bi 4f 7/2 , respectively, confirming that the bismuth species in the sample are Bi 3+ cations [27]. In the O 1s XPS spectrum (Figure 7b), the O 1s region is fitted by two peaks at 529.6 and 531.3 eV, which are attributed to the oxygen in the Bi-O bond and carbonate species, respectively [27]. Figure 7c presents the Ag 3d XPS spectrum, with two peaks at 368.3 and 374.3 eV, which correspond to Ag 3d 5/2 and Ag 3d 3/2 , respectively, suggesting that the silver species in the sample is metallic silver, as the bonding energy corresponding to Ag 3d 5/2 of metallic Ag and Ag 2 O are 368.25 eV and 367.70 eV, respectively, according to the previous report [28]. The TEM image of Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterojunction microtubes with Rc of 6.1% is shown in Figure 8a. As seen from the image, many nanoparticles are evenly dispersed on the surface of microtubes, and strongly anchored. HRTEM was carried out to verify the nanoparticles, as shown in Figure 8b. The lattice structure of nanoparticles anchored on the surface of microtubes is very orderly, and obviously different from that of the microtubes. The measured lattice fringes of 0.245 nm well match the (200) crystallographic planes of metallic Ag, suggesting that Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterojunction microtubes are achieved by this strategy.  The TEM image of Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes with R c of 6.1% is shown in Figure 8a. As seen from the image, many nanoparticles are evenly dispersed on the surface of microtubes, and strongly anchored. HRTEM was carried out to verify the nanoparticles, as shown in Figure 8b. The lattice structure of nanoparticles anchored on the surface of microtubes is very orderly, and obviously different from that of the microtubes. The measured lattice fringes of 0.245 nm well match the (200) crystallographic planes of metallic Ag, suggesting that Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes are achieved by this strategy.
Rc of 6.1% is shown in Figure 8a. As seen from the image, many nanoparticles are evenly dispersed on the surface of microtubes, and strongly anchored. HRTEM was carried out to verify the nanoparticles, as shown in Figure 8b. The lattice structure of nanoparticles anchored on the surface of microtubes is very orderly, and obviously different from that of the microtubes. The measured lattice fringes of 0.245 nm well match the (200) crystallographic planes of metallic Ag, suggesting that Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterojunction microtubes are achieved by this strategy.   Figure 9 shows the UV−vis diffuse reflectance spectra of α-Bi 2 O 3 microtubes, Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes, and Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes. The α-Bi 2 O 3 microtubes prepared at V en :V water = 1:7 exhibit strong absorption in the visible range in addition to the UV range. The absorption edge occurs at about 450 nm. The spectrum is steep, indicating that the absorption of visible light is not due to the transition from impurity levels, but to the band-gap transition. The Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes with R c of 6.1% and 51.3% show dual absorption edges at 365 and 450 nm, which are related to their mixed-phase structure. Moreover, the absorbance in the 360-450 nm range of Bi 2 O 2 CO 3 /α-Bi 2 O 3 is much weaker compared with that of α-Bi 2 O 3 due to the its substantial Bi 2 O 2 CO 3 phase content. The band-gap energies were estimated to be 2.75 and 3.4 eV for α-Bi 2 O 3 and Bi 2 O 2 CO 3 , respectively, and were calculated from the formula λ g = 1239.8/E g , where λ g is the band-gap wavelength, and E g is the bandgap energy [29]. Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes with R c of 6.1% show an extended absorption in the visible region, which is due to the typical surface plasmon band exhibited by the Ag nanoparticles [30]. The spectrum is steep, indicating that the absorption of visible light is not due to the transition from impurity levels, but to the band-gap transition. The Bi2O2CO3/α-Bi2O3 heterojunction microtubes with Rc of 6.1% and 51.3% show dual absorption edges at 365 and 450 nm, which are related to their mixed-phase structure. Moreover, the absorbance in the 360-450 nm range of Bi2O2CO3/α-Bi2O3 is much weaker compared with that of α-Bi2O3 due to the its substantial Bi2O2CO3 phase content. The band-gap energies were estimated to be 2.75 and 3.4 eV for α-Bi2O3 and Bi2O2CO3, respectively, and were calculated from the formula λg = 1239.8/Eg, where λg is the band-gap wavelength, and Eg is the bandgap energy [29]. Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterojunction microtubes with Rc of 6.1% show an extended absorption in the visible region, which is due to the typical surface plasmon band exhibited by the Ag nanoparticles [30]. Photodegradation of MO under visible light irradiation was carried out to estimate the photocatalytic performance of the as-prepared samples. The photodegradation efficiencies of MO as a function of irradiation time by α-Bi2O3, Bi2O2CO3/α-Bi2O3 with Rc of 6.7%, Bi2O2CO3/α-Bi2O3 with Rc of 15.5%, Ag/Bi2O2CO3/α-Bi2O3 with Rc of 6.7%, as well as in the absence of photocatalysts, are presented in Figure 10. It can be seen that all the samples show visible light photocatalytic activities. After 140 min of irradiation, the photodegradation efficiencies of MO by α-Bi2O3, Bi2O2CO3/α-Bi2O3 with Rc of 6.7%, and Bi2O2CO3/α-Bi2O3 with Rc of 15.5%, reach 69%, 100%, and 65%, respectively. For Ag/Bi2O2CO3/α-Bi2O3 with Rc of 6.7%, it reaches 100% after 60 min. Generally, the overall photocatalytic activity of a semiconductor is primarily dictated by surface area, photoabsorption ability, and the separation and transporting rates of photoinduced electron/hole pairs in the catalysts [31]. Since α-Bi2O3, Bi2O2CO3/α-Bi2O3 with Rc of 6.7%, and Ag/Bi2O2CO3/α-Bi2O3 possess similar size and morphology, the enhanced photocatalytic activities of Ag/Bi2O2CO3/α-Bi2O3 and Bi2O2CO3/α-Bi2O3 with Rc of 6.7% should be ascribed   Photodegradation of MO under visible light irradiation was carried out to estimate the photocatalytic performance of the as-prepared samples. The photodegradation efficiencies of MO as a function of irradiation time by α-Bi 2 O 3 , Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7%, Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 15.5%, Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7%, as well as in the absence of photocatalysts, are presented in Figure 10. It can be seen that all the samples show visible light photocatalytic activities. After 140 min of irradi-ation, the photodegradation efficiencies of MO by α-Bi 2 O 3 , Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7%, and Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 15.5%, reach 69%, 100%, and 65%, respectively. For Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7%, it reaches 100% after 60 min. Generally, the overall photocatalytic activity of a semiconductor is primarily dictated by surface area, photoabsorption ability, and the separation and transporting rates of photoinduced electron/hole pairs in the catalysts [31]. Since α-Bi 2 O 3 , Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7%, and Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 possess similar size and morphology, the enhanced photocatalytic activities of Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 and Bi 2 O 2 CO 3 /α-Bi 2 O 3 with R c of 6.7% should be ascribed to the improved separation and transporting rates of photoinduced electron/hole pairs. Photogenerated electrons, holes, ·O2 − , and ·OH are considered to be major reactive species in organics photodegradation [32]. MO can be degraded into CO2, H2O, and other products by those reactive species [33]. In order to clarify the reaction mechanism further, 1 mmol of various scavengers was introduced to explore the specific reactive species that might play important roles in MO degradation by Ag/Bi2O2CO3/α-Bi2O3. Benzoquinone (BQ), ethylene diaminetetraacetic acid (EDTA), and tertiary butanol (TBA) were used as the scavengers for ·O2 − , holes, and ·OH, respectively [34]. Figure 11 shows the photodegradation efficiencies of MO by Ag/Bi2O2CO3/α-Bi2O3 in the presence of these scavengers under visible light irradiation for 60 min. Both BQ and TBA show suppression of the degradation rate of MO, with TBA exhibiting a stronger suppressing effect. Meanwhile, EDTA shows a much weaker suppressing effect than BQ and TBA, suggesting that ·OH and ·O2 − are the major reactive species responsible for the photodegradation of MO by Ag/Bi2O2CO3/α-Bi2O3. The effects of Bi2O2CO3/α-Bi2O3 and Ag NPs on the efficiency of photoinduced electrons and holes separation were investigated by the photocurrent tests, as shown in Figure  12. The photocurrent intensities of the samples follow the order of Ag/Bi2O2CO3/α-Bi2O3 > Bi2O2CO3/α-Bi2O3 > α-Bi2O3. As demonstrated in the previous research, higher photocurrent intensity means higher separation efficiency of the photoinduced electron/hole pairs. Photogenerated electrons, holes, ·O 2 − , and ·OH are considered to be major reactive species in organics photodegradation [32]. MO can be degraded into CO 2 , H 2 O, and other products by those reactive species [33]. In order to clarify the reaction mechanism further, 1 mmol of various scavengers was introduced to explore the specific reactive species that might play important roles in MO degradation by Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 . Benzoquinone (BQ), ethylene diaminetetraacetic acid (EDTA), and tertiary butanol (TBA) were used as the scavengers for ·O 2 − , holes, and ·OH, respectively [34]. Figure 11 shows the photodegradation efficiencies of MO by Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 in the presence of these scavengers under visible light irradiation for 60 min. Both BQ and TBA show suppression of the degradation rate of MO, with TBA exhibiting a stronger suppressing effect. Meanwhile, EDTA shows a much weaker suppressing effect than BQ and TBA, suggesting that ·OH and ·O 2 − are the major reactive species responsible for the photodegradation of MO by Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 . Photogenerated electrons, holes, ·O2 − , and ·OH are considered to be major reactive species in organics photodegradation [32]. MO can be degraded into CO2, H2O, and other products by those reactive species [33]. In order to clarify the reaction mechanism further, 1 mmol of various scavengers was introduced to explore the specific reactive species that might play important roles in MO degradation by Ag/Bi2O2CO3/α-Bi2O3. Benzoquinone (BQ), ethylene diaminetetraacetic acid (EDTA), and tertiary butanol (TBA) were used as the scavengers for ·O2 − , holes, and ·OH, respectively [34]. Figure 11 shows the photodegradation efficiencies of MO by Ag/Bi2O2CO3/α-Bi2O3 in the presence of these scavengers under visible light irradiation for 60 min. Both BQ and TBA show suppression of the degradation rate of MO, with TBA exhibiting a stronger suppressing effect. Meanwhile, EDTA shows a much weaker suppressing effect than BQ and TBA, suggesting that ·OH and ·O2 − are the major reactive species responsible for the photodegradation of MO by Ag/Bi2O2CO3/α-Bi2O3. The effects of Bi2O2CO3/α-Bi2O3 and Ag NPs on the efficiency of photoinduced electrons and holes separation were investigated by the photocurrent tests, as shown in Figure  12. The photocurrent intensities of the samples follow the order of Ag/Bi2O2CO3/α-Bi2O3 > Bi2O2CO3/α-Bi2O3 > α-Bi2O3. As demonstrated in the previous research, higher photocurrent intensity means higher separation efficiency of the photoinduced electron/hole pairs. The effects of Bi 2 O 2 CO 3 /α-Bi 2 O 3 and Ag NPs on the efficiency of photoinduced electrons and holes separation were investigated by the photocurrent tests, as shown in Figure 12. The photocurrent intensities of the samples follow the order of Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 > Bi 2 O 2 CO 3 /α-Bi 2 O 3 > α-Bi 2 O 3 . As demonstrated in the previous research, higher photocurrent intensity means higher separation efficiency of the photoinduced electron/hole pairs. The photocurrent measurement results suggest that the formation of Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterostructures improves charge carrier transfer and separation of α-Bi 2 O 3 , while loading of Ag NPs on the heterostructures further enhances this effect. It is consistent with the photocatalytic performance. The photocurrent measurement results suggest that the formation of Bi2O2CO3/α-Bi2O3 heterostructures improves charge carrier transfer and separation of α-Bi2O3, while loading of Ag NPs on the heterostructures further enhances this effect. It is consistent with the photocatalytic performance. According to the experimental results, we believe that there are four major reasons responsible for the enhanced photodegradation of MO by Ag NP-loaded Bi2O2CO3/α-Bi2O3 heterojunction microtubes, as illustrated in Figure 13. Firstly, Bi2O2CO3/α-Bi2O3 heterojunction facilitates the charge separation. As reported in the previous work, α-Bi2O3 is a p-type semiconductor, while Bi2O2CO3 is determined as an n-type material. The conduction band edge of α-Bi2O3 and Bi2O2CO3 at the point of zero charge (pHzpc) can be theoretically predicted from the formula ECB 0 = X − Ec − 0.5Eg, where X is the absolute electronegativity of the semiconductor, and Ec is the energy of free electrons on the hydrogen scale (4.5 eV) [35]. The values of X are 5.95 eV for α-Bi2O3 and 6.35 eV for Bi2O2CO3, while the estimated Eg is 2.75 eV for α-Bi2O3 and 3.4 eV for Bi2O2CO3. Given the formula above, the calculated ECB and EVB values are 0.075 eV and 2.825 eV for α-Bi2O3, respectively, and 0.15 eV and 3.55 eV for Bi2O2CO3, respectively. Therefore, both the conduction band (CB) and valence band (VB) of Bi2O2CO3 are considered to be at lower levels than those of α-Bi2O3. Thus, a Type II p-n heterojunction is formed at the interfaces as Bi2O3 and Bi2O2CO3 are closely joined together. When Bi2O2CO3/α-Bi2O3 heterojunction microtubes are exposed to visible light irradiation, the electrons in the VB of α-Bi2O3 are excited to its CB, leaving holes in the VB. However, for Bi2O2CO3, the electrons in the VB cannot be excited because of the wide bandgap of 3.4 eV. Due to the internal field resulting from the potential of band energy difference between α-Bi2O3 and Bi2O2CO3, there is a great tendency for α-Bi2O3 to transfer its photoexcited electrons into the CB of Bi2O2CO3, facilitating electronhole separation in α-Bi2O3, and providing more holes for photocatalytic reactions. Secondly, as the Ag NPs loaded on the surface of Bi2O2CO3/α-Bi2O3 heterojunction microtubes are in close contact with α-Bi2O3 or Bi2O2CO3, the electrons in the CB of α-Bi2O3 and Bi2O2CO3 will transfer to the Ag NPs because of the superior electron conductivity of Ag NPs, along with the formation of heterojunctions at the interface between two semiconductors and the Ag NPs as a result of their work function differences, further suppressing charge carrier recombination [30]. Thirdly, as mentioned above, the valence bands of α-Bi2O3 are located at a deep position of about 2.825 eV versus NHE, which is more positive than that of ·OH/OH − (1.9 eV vs. NHE), indicating that the photogenerated holes in the VB of α-Bi2O3 can react with OH − to produce ·OH for oxidation of MO [35,36]. Meanwhile, the conduction band potentials of α-Bi2O3 and Bi2O2CO3 are close to +0.075 eV and +0.15 eV According to the experimental results, we believe that there are four major reasons responsible for the enhanced photodegradation of MO by Ag NP-loaded Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes, as illustrated in Figure 13. Firstly, Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction facilitates the charge separation. As reported in the previous work, α-Bi 2 O 3 is a p-type semiconductor, while Bi 2 O 2 CO 3 is determined as an n-type material. The conduction band edge of α-Bi 2 O 3 and Bi 2 O 2 CO 3 at the point of zero charge (pH zpc ) can be theoretically predicted from the formula E CB 0 = X − E c − 0.5E g , where X is the absolute electronegativity of the semiconductor, and E c is the energy of free electrons on the hydrogen scale (4.5 eV) [35]. The values of X are 5.95 eV for α-Bi 2 O 3 and 6.35 eV for Bi 2 O 2 CO 3 , while the estimated E g is 2.75 eV for α-Bi 2 O 3 and 3.4 eV for Bi 2 O 2 CO 3 . Given the formula above, the calculated E CB and E VB values are 0.075 eV and 2.825 eV for α-Bi 2 O 3 , respectively, and 0.15 eV and 3.55 eV for Bi 2 O 2 CO 3 , respectively. Therefore, both the conduction band (CB) and valence band (VB) of Bi 2 O 2 CO 3 are considered to be at lower levels than those of α-Bi 2 O 3 . Thus, a Type II p-n heterojunction is formed at the interfaces as Bi 2 O 3 and Bi 2 O 2 CO 3 are closely joined together. When Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes are exposed to visible light irradiation, the electrons in the VB of α-Bi 2 O 3 are excited to its CB, leaving holes in the VB. However, for Bi 2 O 2 CO 3 , the electrons in the VB cannot be excited because of the wide bandgap of 3.4 eV. Due to the internal field resulting from the potential of band energy difference between α-Bi 2 O 3 and Bi 2 O 2 CO 3 , there is a great tendency for α-Bi 2 O 3 to transfer its photoexcited electrons into the CB of Bi 2 O 2 CO 3 , facilitating electron-hole separation in α-Bi 2 O 3 , and providing more holes for photocatalytic reactions. Secondly, as the Ag NPs loaded on the surface of Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes are in close contact with α-Bi 2 O 3 or Bi 2 O 2 CO 3 , the electrons in the CB of α-Bi 2 O 3 and Bi 2 O 2 CO 3 will transfer to the Ag NPs because of the superior electron conductivity of Ag NPs, along with the formation of heterojunctions at the interface between two semiconductors and the Ag NPs as a result of their work function differences, further suppressing charge carrier recombination [30]. Thirdly, as mentioned above, the valence bands of α-Bi 2 O 3 are located at a deep position of about 2.825 eV versus NHE, which is more positive than that of ·OH/OH − (1.9 eV vs. NHE), indicating that the photogenerated holes in the VB of α-Bi 2 O 3 can react with OH − to produce ·OH for oxidation of MO [35,36]. Meanwhile, the conduction band potentials of α-Bi 2 O 3 and Bi 2 O 2 CO 3 are close to +0.075 eV and +0.15 eV versus NHE, respectively, which are more positive than that of O 2 /·O 2 − (−0.33 eV vs. NHE). Thus, it is impossible for the adsorption oxygen to capture an electron from the conduction bands of α-Bi 2 O 3 and Bi 2 O 2 CO 3 to form active oxygen species (·O 2 − ) [35,36]. However, the electrons transferred to Ag NPs from the CBs of α-Bi 2 O 3 and Bi 2 O 2 CO 3 in Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 might be trapped by oxygen molecules in the solutions to form ·O 2 − for reaction [30,35,36]. This means that loading Ag NPs onto the surface of Bi 2 O 2 CO 3 /α-Bi 2 O 3 can bring another benefit that leads to the formation of new reaction active sites, and a new reactive species ·O 2 − , enhancing the photocatalytic activity of Bi 2 O 2 CO 3 /α-Bi 2 O 3 . The possible reactions in the Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 ternary photocatalytic system are illustrated by the following equations: Nanomaterials 2022, 12, 1608 13 of 16 versus NHE, respectively, which are more positive than that of O2/·O2 − (−0.33 eV vs. NHE). Thus, it is impossible for the adsorption oxygen to capture an electron from the conduction bands of α-Bi2O3 and Bi2O2CO3 to form active oxygen species (·O2 − ) [35,36]. However, the electrons transferred to Ag NPs from the CBs of α-Bi2O3 and Bi2O2CO3 in Ag/Bi2O2CO3/α-Bi2O3 might be trapped by oxygen molecules in the solutions to form ·O2 − for reaction [30,35,36]. This means that loading Ag NPs onto the surface of Bi2O2CO3/α-Bi2O3 can bring another benefit that leads to the formation of new reaction active sites, and a new reactive species ·O2 − , enhancing the photocatalytic activity of Bi2O2CO3/α-Bi2O3. The possible reactions in the Ag/Bi2O2CO3/α-Bi2O3 ternary photocatalytic system are illustrated by the following equations: Lastly, the surface plasmon resonance effect caused by the mutual oscillation between incident light and the electrons on the surface of metallic Ag NPs causes the rise of a local electromagnetic field [35]. Under the influence of this local electromagnetic field, the photogenerated electron/hole pairs on the α-Bi2O3 surface are effectively separated, which also enhances photocatalytic activity.  Figure 14 presents the results of repeated experiments on photodegradation of MO by Ag/Bi2O2CO3/α-Bi2O3 under visible light irradiation. After each run, the photocatalysts were collected by centrifugation, followed by ultrasonic cleaning with distilled water. As shown in the image, no significant loss is found after four successive cycles; 89.8% of MO was degraded in the fifth run after 60 min of visible light irradiation, suggesting that the sample is stale and not photo-corroded in the photocatalytic reactions. Lastly, the surface plasmon resonance effect caused by the mutual oscillation between incident light and the electrons on the surface of metallic Ag NPs causes the rise of a local electromagnetic field [35]. Under the influence of this local electromagnetic field, the photogenerated electron/hole pairs on the α-Bi 2 O 3 surface are effectively separated, which also enhances photocatalytic activity. Figure 14 presents the results of repeated experiments on photodegradation of MO by Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 under visible light irradiation. After each run, the photocatalysts were collected by centrifugation, followed by ultrasonic cleaning with distilled water. As shown in the image, no significant loss is found after four successive cycles; 89.8% of MO was degraded in the fifth run after 60 min of visible light irradiation, suggesting that the sample is stale and not photo-corroded in the photocatalytic reactions.

Conclusions
In summary, we have developed a facile solvothermal approach to prepare n-p Bi2O2CO3/α-Bi2O3 heterojunction microtubes. Plasmonic Ag NPs were loaded onto the Bi2O2CO3/α-Bi2O3 microtubes using a simple photo-deposition process, to construct an Ag/Bi2O2CO3/α-Bi2O3 ternary photocatalytic system. This Ag/Bi2O2CO3/α-Bi2O3 ternary system showed much higher photocatalytic activity than α-Bi2O3 and Bi2O2CO3/α-Bi2O3. Under visible light irradiation, the well-defined interfaces between Bi2O2CO3 and α-Bi2O3 in the heterojunctions due to the in situ carbonation of α-Bi2O3 on the surface into Bi2O2CO3, facilitate the transfer of photoinduced electrons from the CB of α-Bi2O3 to that of Bi2O2CO3. Meanwhile, the superior electron conductivity of Ag NPs, the heterojunction at the interface between two semiconductors and Ag NPs, and the local electromagnetic field induced by the surface plasmon resonance effect of Ag NPs, further promote the transfer of photoinduced electrons and suppress the recombination of hole/electron pairs, leaving more holes in the VB of α-Bi2O3 to produce more ·OH for photodegradation of MO. After the photoinduced electrons in the CB of α-Bi2O3 and Bi2O2CO3 that cannot form ·O2 − are transferred to Ag NPs, they combine with O2 to form ·O2 − , which means that loading of Ag NPs onto Bi2O2CO3/α-Bi2O3 creates new reaction active sites and a new reactive species ·O2 − for photocatalysis, compared with Bi2O2CO3/α-Bi2O3.

Conclusions
In summary, we have developed a facile solvothermal approach to prepare n-p Bi 2 O 2 CO 3 /α-Bi 2 O 3 heterojunction microtubes. Plasmonic Ag NPs were loaded onto the Bi 2 O 2 CO 3 /α-Bi 2 O 3 microtubes using a simple photo-deposition process, to construct an Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 ternary photocatalytic system. This Ag/Bi 2 O 2 CO 3 /α-Bi 2 O 3 ternary system showed much higher photocatalytic activity than α-Bi 2 O 3 and Bi 2 O 2 CO 3 /α-Bi 2 O 3 . Under visible light irradiation, the well-defined interfaces between Bi 2 O 2 CO 3 and α-Bi 2 O 3 in the heterojunctions due to the in situ carbonation of α-Bi 2 O 3 on the surface into Bi 2 O 2 CO 3 , facilitate the transfer of photoinduced electrons from the CB of α-Bi 2 O 3 to that of Bi 2 O 2 CO 3 . Meanwhile, the superior electron conductivity of Ag NPs, the heterojunction at the interface between two semiconductors and Ag NPs, and the local electromagnetic field induced by the surface plasmon resonance effect of Ag NPs, further promote the transfer of photoinduced electrons and suppress the recombination of hole/electron pairs, leaving more holes in the VB of α-Bi 2 O 3 to produce more ·OH for photodegradation of MO. After the photoinduced electrons in the CB of α-Bi 2 O 3 and Bi 2 O 2 CO 3 that cannot form ·O 2 − are transferred to Ag NPs, they combine with O 2 to form ·O 2 − , which means that loading of Ag NPs onto Bi 2 O 2 CO 3 /α-Bi 2 O 3 creates new reaction active sites and a new reactive species ·O 2 − for photocatalysis, compared with Bi 2 O 2 CO 3 /α-Bi 2 O 3 .