Evaluation of Photoelectrocatalysis with Electrode Based on Ti/RuO2-TiO2 Modified with Tin and Tantalum Oxides for the Degradation of Indigo Blue Dye

Indigo Blue (IB) is a dye widely used by the textile sector for dyeing cellulose cotton fibers and jeans, being considered a recalcitrant substance, and therefore resistant to traditional treatments. Several methodologies are reported in the literature for the removal or degradation of dyes from the aqueous medium, among which photoelectrocatalysis stands out, which presents promising results in the degradation of dyes when a dimensionally stable anode (DSA) is used as a photoanode. In the present work, we sought to investigate the efficiency of a Ti/RuO2-TiO2 DSA modified with tin and tantalum for the degradation of Indigo Blue dye by photoelectrocatalysis. For this, electrodes were prepared by the thermal decomposition method and then a physical–chemical and electrochemical analysis of the material was carried out. The composition Ti/RuO2-TiO2-SnO2Ta2O5 (30:40:10:20) was compared to Ti/RuO2-TiO2 (30:70) in the photocatalysis, electrocatalysis, and photoelectrocatalysis tests. The photocatalysis was able to degrade only 63% of the IB at a concentration of 100 mg L−1 in 3 h, whereas the electrocatalysis and photoelectrocatalysis were able to degrade 100% of the IB at the same initial concentration in 65 and 60 min, respectively.


Introduction
Dyes are organic substances used in several industrial sectors, such as cosmetics [1], paints [2], leather dyeing [3], and especially in the textile sector [4]. The textile industry is responsible for a large amount of highly polluting effluents, with a high organic load. From an environmental point of view, the dyeing stage is the most worrying due to the large number of substances that do not bind to the fibers and generate residues that are released into aquatic environments [5]. Knowing that dyes are potentially toxic pollutants and resistant to conventional treatment systems, it is necessary to study alternative methods [6]. Numerous alternatives to bleach textile effluents have been proposed [7], including studies on Advanced Oxidative Processes (AOPs).
AOPs are methods capable of processing high organic loads and causing less secondary pollution compared to traditional treatment methods [8]. These methods use the in-situ formation of highly reactive oxidizing species that are capable of promoting the mineralization of various organic pollutants, originating substances with low toxic potential [9,10]. The generation of these reactive species can be obtained through several processes, such as electrocatalysis, photocatalysis, and photoelectrocatalysis.
On electrocatalysis, the effluent is subjected to a defined current applied between two electrodes, the anode, and the cathode, in the presence of a supporting electrolyte. In this . The temperature of these solutions was controlled between 60 and 65 • C and a mixture of citric acid (Dinâmica ® , Serra, ES, Brazil) and ethylene glycol (Dinâmica ® , Serra, ES, Brazil) was added and heated to 80-95 • C to promote the esterification reaction. The mixture was kept in this temperature range for 1 to 2 h until the volume of the solution was reduced to half.
The 21 cm 2 Ti supports, previously blasted with a glass microsphere using the GJS blaster (PR Jateamento ® , Boa Esperança do Sul, SP, Brazil) were washed with running water and kept in hot ultrapure water for 30 min. Then, they were immersed in a beaker containing 99.5% pure isopropyl alcohol (NEON ® , Suzano, SP, Brazil), and placed in the USC-1400 ultrasound (UNIQUE ® , Indaiatuba, Brazil) with a power of 135 Watts RMS for 30 min to degrease their surface. Subsequently, the Ti supports were placed in a 20% HCl solution (NEON ® , Suzano, SP, Brazil) at boiling point for 30 min, and subjected to a chemical attack by 10% oxalic acid (Dinâmica ® , Serra, ES, Brazil) for 20 min. The electrodes were dried in a Toyo TA-1060 heat gun (Toyo ® , Curitiba, PR, Brazil), weighed, and brushed with polymeric resins. After depositing the material, the resin was dried, taken to an oven at 130 • C for 10 min, and then to a muffle furnace at 450 • C for 5 min until reaching a mass of 2 mg. Upon reaching the desired mass, the electrode was calcined for 1 h at 450 • C.

Characterization of Electrodes 2.2.1. Physicochemical Characterization
In order to analyze the formation of oxides formed during the electrode calcination process and to determine the crystalline phases present, a study of the film by X-ray diffraction (XRD) was carried out. Measurements were performed under a grazing angle, measuring interval 2θ = 10 • to 90 • in the interval 0.01 • min −1 , using a Shimadzu diffractometer (Belo Horizonte, MG, Brazil), model XRD-6000 SSC with a Kα-Cu radiation source (λ = 1.5406 Å) of the Core Competencies in Petroleum Chemistry (Labpetro).
Other techniques used were scanning electron microscopy (SEM) (São Paulo, SP, Brazil) and Energy scattering X-ray spectroscopy (EDX) (São Paulo, SP, Brazil)to obtain information about the structural properties of the material, as well as its morphology, both from JEOL

Electrochemical Characterization
The electrodes were investigated via cyclic voltammetry using the VersaSTAT 4 potentiostat/galvanostat from Princeton Applied Research. The technique allows knowing the redox processes that occur on the surface of the electrodes, making it possible to obtain information on the reversibility of the reaction and on the occurrence or not of reactions parallel to the electron transfer processes, as well as on the charge involved in the process and the reproducibility of the surface [29].
Electrode hydration was performed with fifty successive sweeps in the region of 0.2-1.0 V vs. Ag/AgCl in H 2 SO 4 (Sigma-Aldrich ® , Cotia, SP, Brazil) 0.5 mol L −1 at 0.05 V s −1 . Other analyses were performed using two sequential voltammetric cycles at 0.01 V s −1 and a potential window of 0.00 to 1.20 V vs. RHE (reference hydrogen electrode). All reagents used were of analytical grade, and the ultrapure water used was obtained by the Sartorius purification Arium TM , model MA-UVT (São Bernado do Campo, SP, Brazil) with a resistivity of 18.0 MΩ cm at 22 • C.
In addition, the Ti/RuO 2 -SnO 2 -TiO 2 -Ta 2 O 5 system was evaluated according to its composition by the stability test at a corresponding density of 750 mA cm −2 in a 0.5 mol L −1 H 2 SO 4 solution. The electrode potential was recorded as a function of time and its useful lifetime, considering the time required for the potential to reach 6 V vs. RHE.

Electrocatalysis
For the electrocatalysis tests, the IB dye concentration was at 100 mg L −1 , and an AFR source, model FA3010-M was used, providing a current of 0.02 A at 25 • C until the complete degradation of the dye. In the electrochemical cell, DSAs of composition Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 were used, which were compared to the standard electrode of Ti/RuO 2 -TiO 2 , in both cases a graphite electrode with an area of 3.15 cm 2 was used as the counter electrode and 150 mL of dye solution were used. The aliquots of the solution were taken every 10 min and the samples were analyzed with the aid of a UV-Vis spectrophotometer (Hach DR5000, Jundiaí, SP, Brazil). Color removal percentages were calculated according to Equation (1).
Wherein C 0, and C t correspond to the dye concentration at time zero and time t, respectively.

Photocatalysis
For the photocatalysis tests, an Ultraviolet (UV) light booth, 365 nm wavelength from T&M instruments model CL6i-45S (Brooklin, SP, Brazil) was used, and no current was applied to the process. For these tests, electrodes of composition Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 and Ti/RuO 2 -TiO 2 were used, a counter carbon electrode, 150 mL of dye solution 100 mg L −1, and the aliquots of the solution were also taken every 10 min and analyzed with the aid of a UV-Vis spectrophotometer (Hach DR5000). Results were expressed as a percentage of color removal, calculated using Equation (1).

Photoelectrocatalysis
For the photoelectrocatalysis test, the radiation emitted by the UV light cabin was associated with a current of 20 mA applied by a source, a volume of 150 mL of the dye IB 100 mg L −1 was used with the electrodes of composition Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 and Ti/RuO 2 -TiO 2 . The samples were taken every 10 min for analysis in the spectrophotometer. Equation (1) was also used to analyze the results.

X-ray Diffraction
The surface morphology of the quaternary electrodes, of composition Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 , was analyzed by X-ray Diffraction (XRD) in order to verify the oxides present, and the result is shown in Figure 1.
L −1, and the aliquots of the solution were also taken every 10 min and analyzed w aid of a UV-Vis spectrophotometer (Hach DR5000). Results were expresse percentage of color removal, calculated using Equation (1).

Photoelectrocatalysis
For the photoelectrocatalysis test, the radiation emitted by the UV light ca associated with a current of 20 mA applied by a source, a volume of 150 mL of th 100 mg L −1 was used with the electrodes of composition Ti/RuO2-TiO2-SnO2-Ta Ti/RuO2-TiO2. The samples were taken every 10 min for analysis in the spectrophot Equation (1) was also used to analyze the results.

X-ray Diffraction
The surface morphology of the quaternary electrodes, of composition Ti/RuO SnO2-Ta2O5, was analyzed by X-ray Diffraction (XRD) in order to verify the oxides and the result is shown in Figure 1    Comparing the positions of the peaks obtained with the values established for metallic titanium and for the Ru, Ti, Sn, and Ta oxides (Figure 1), it is possible to observe that the material exhibits the presence of metallic titanium, coming from the metallic base, and also the presence of films in the tetragonal phase of RuO 2 and in the rutile phase TiO 2 . According to the analysis, it is not possible to observe the presence of SnO 2 and Ta 2 O 5 . However, according to the Hume-Rothery rules, in substitutional solid solutions, the atomic size factor establishes that the difference between the atomic rays of two elements cannot exceed 15% [30], which occurs when we are considering the ions used for the electrode (Ru 4+ , Ti 4+ , Sn 4+ , and Ta 5+ ) according to Table 1. Thus, it is possible to say that Sn 4+ , and Ta 5+ ions were also present in the electrode. Using XRD data, it was also possible to calculate the average crystallite size for the different crystalline planes of RuO 2 and TiO 2 , using the Scherrer equation [31]: where D is the average size of the crystallite, λ the wavelength of the radiation, β the width of the reflection in radians and θ β the angle of maximum intensity of the reflection. The results are shown in Table 2. From the data obtained in Table 2, it is noted that lower values were obtained for Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 (30:50:10:10), which according to Cheng et al. could provide better electronic and photocatalytic properties [32]. Knowing that better electronic and photocatalytic properties are possible when smaller crystallite radii are found, it is expected that the quaternary electrodes of composition Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 in both studied proportions will obtain promising results when compared to the standard Ti/TiO 2 RuO 2 (70:30).

Scanning Electron Microscopy
The analysis of the physical characteristics of the DSA electrodes of composition Ti/TiO 2 RuO 2 and Ti/RuO 2 -TiO 2 -SnO 2 -Ta 2 O 5 was performed by scanning electron microscope, SEM. This equipment is widely used for microstructural analysis of solid materials and images can be obtained with magnifications of up to 100,000 times and resolutions of up to 20 nm [32,33]. In Figure 2, the morphology of the materials is presented at 500× magnification, obtained through SEM, it is evident that the surfaces of both materials have structure considered by the literature similar to "mud cracked", typical for DSAs prepared by the thermal decomposition method. In this morphology, the cracks designated the macro roughness, while the pores exhibited the micro-roughness [19].

Cyclic Voltammetry
The electrochemical behavior of the previously prepared DSAs was investigated via cyclic voltammetry, the following compositions were tested: Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) and Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:50:10:10) in duplicate, so the first tests were carried out to find the electrolyte with the highest charge. The electrolytes tested were: Na 2 SO 4 (0.05 mol L −1 ), NaCl (1.67 mol L −1 ), and H 2 SO 4 (0.5 mol L −1 ), so that the concentrations were defined so that all solutions had the same ionic strength (µ = 0.25). In this way, the values between the anodic (qa) and cathodic (qc) charge densities were calculated based on Figure 3, as shown in Table 3.
Nanomaterials 2022, 12, x FOR PEER REVIEW 7 of 17 typical for DSAs prepared by the thermal decomposition method. In this morphology, the cracks designated the macro roughness, while the pores exhibited the micro-roughness [19].

Cyclic Voltammetry
The electrochemical behavior of the previously prepared DSAs was investigated via cyclic voltammetry, the following compositions were tested: Ti/RuO2-TiO2-SnO2Ta2O5 (30:40:10:20) and Ti/RuO2-TiO2-SnO2Ta2O5 (30:50:10:10) in duplicate, so the first tests were carried out to find the electrolyte with the highest charge. The electrolytes tested were: Na2SO4 (0.05 mol L −1 ), NaCl (1.67 mol L −1 ), and H2SO4 (0.5 mol L −1 ), so that the concentrations were defined so that all solutions had the same ionic strength (μ = 0.25). In this way, the values between the anodic (qa) and cathodic (qc) charge densities were calculated based on Figure 3, as shown in Table 3.  cracks designated the macro roughness, while the pores exhibited the micro-roughness [19].

Cyclic Voltammetry
The electrochemical behavior of the previously prepared DSAs was investigated via cyclic voltammetry, the following compositions were tested: Ti/RuO2-TiO2-SnO2Ta2O5 (30:40:10:20) and Ti/RuO2-TiO2-SnO2Ta2O5 (30:50:10:10) in duplicate, so the first tests were carried out to find the electrolyte with the highest charge. The electrolytes tested were: Na2SO4 (0.05 mol L −1 ), NaCl (1.67 mol L −1 ), and H2SO4 (0.5 mol L −1 ), so that the concentrations were defined so that all solutions had the same ionic strength (μ = 0.25). In this way, the values between the anodic (qa) and cathodic (qc) charge densities were calculated based on Figure 3, as shown in Table 3.   In the investigated potential range (0.00 to 1.20 V vs. Ag/AgCl), it is possible to observe in all voltammograms an increase in the current response by 1.1 V vs. Ag/AgCl which is associated with the oxygen evolution reaction (OER) of water oxidation. In the region of 0.10 to 0.70 V vs. Ag/AgCl, it is possible to observe a peak attributed to the Ru(III)/Ru(IV) redox transition, this is more visible in the composition sample (30:50:10:10) with H 2 SO 4 electrolyte. It is also possible to observe the second peak in the region between 0.8-1.1 V vs. Ag/AgCl, assigned to Ru(IV)/Ru(VI) redox transition [18,34].
In the region of 1.0 V vs. Ag/AgCl, begins the chlorine evolution reaction and an increase in the current response is also observed, normally associated with the coexistence of the water oxidation [18]. However, the composition DSA (30:40:10:20) in Na 2 SO 4 and NaCl medium overlap, which indicates that this peak must be attributed just to the oxidation of water. Finally, a slight increase in charge is observed in relation to the voltammogram when the Na 2 SO 4 electrolyte is used, compared to NaCl and Na 2 SO 4 under an identical ionic strength, which is also possible to observe in Table 1. Finally, it is also possible to observe that, except for sample two of Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) when Na 2 SO 4 0.050 mol L −1 was used, all samples present their ratios between cathodic and anodic charge close to the unit value, which indicates a behavior close to reversible.
The following experiments were carried out with the DSA of composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20), due to the high value of the cathodic and anodic charge when using NaCl as a supporting electrolyte. The electrolyte was chosen because when using NaCl, it was possible to notice that after some voltammetry the solution became translucent, as can be seen in Figure 4. The initial hypothesis is that the IB is oxidized by the presence of NaCl in the solution when a certain potential is applied. Since it is reported in the literature that when the NaCl salt is used as a supporting electrolyte, and an overpotential is applied in relation to the chloride reduction potential (Equation (3)), there is the generation of active chlorine species (Cl 2 , HClO, ClO − ) within the solution so that these species are capable of promoting indirect oxidation of the dye in question [35,36]. The formation of active chlorine species occurs by the oxidation of the chloride anion (Cl − ) at the anode, releasing chlorine (Cl 2 (aq)). As chlorine diffuses within the reaction, it is hydrolyzed, forming HClO and Cl − , as can be seen in Equations (4)-(6) [37].

Stability Test
The stability of the Ti/RuO2-SnO2-TiO2-Ta2O5 system as a function of its composition was evaluated at a current density of 750 mA cm −2 in 0.5 mol L −1 H2SO4, considering the

Stability Test
The stability of the Ti/RuO 2 -SnO 2 -TiO 2 -Ta 2 O 5 system as a function of its composition was evaluated at a current density of 750 mA cm −2 in 0.5 mol L −1 H 2 SO 4 , considering the time required for the potential reaches 6 V vs. RHE, as shown in Figure 5 and Table 4. Once above this potential, DSA is considered inactive, due to the total degradation of the active layer of the deposited oxide, or by the formation of a TiO 2 film in the metallic Ti layer/active layer [38].

Stability Test
The stability of the Ti/RuO2-SnO2-TiO2-Ta2O5 system as a function of its composition was evaluated at a current density of 750 mA cm −2 in 0.5 mol L −1 H2SO4, considering the time required for the potential reaches 6 V vs. RHE, as shown in Figure 5 and Table 4 Once above this potential, DSA is considered inactive, due to the total degradation of the active layer of the deposited oxide, or by the formation of a TiO2 film in the metallic T layer/active layer [38].

Electrocatalysis
The electrocatalysis assay was performed with a DSA of composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) which was compared to the standard Ti/RuO 2 -TiO 2 (30:70). The degraded solution consisted of IB at a concentration of 100 mg L −1 , with 2 mL of concentrated sulfuric acid, used to solubilize the dye and NaCl electrolyte 0.167 mol L −1 . In Figure 6, it is possible to observe the UV-Vis spectrum of the solution in the visible wavelength region.
The electrocatalysis assay was performed with a DSA of composition Ti/RuO2-TiO2 SnO2Ta2O5 (30:40:10:20) which was compared to the standard Ti/RuO2-TiO2 (30:70). The degraded solution consisted of IB at a concentration of 100 mg L −1 , with 2 mL o concentrated sulfuric acid, used to solubilize the dye and NaCl electrolyte 0.167 mol L −1 In Figure 6, it is possible to observe the UV-Vis spectrum of the solution in the visible wavelength region.  During the electrocatalysis process, it was possible to observe the formation of bubbles on the surface of the electrode, due to the reaction of the detachment of oxygen and chlorine, which can negatively influence the reactive area of the DSA. However, based on the curve, the DSA obtained a good response, even with a low current (20 mA) and During the electrocatalysis process, it was possible to observe the formation of bubbles on the surface of the electrode, due to the reaction of the detachment of oxygen and chlorine, which can negatively influence the reactive area of the DSA. However, based on the curve, the DSA obtained a good response, even with a low current (20 mA) and both tested anodes were able to remove 100% of the color of the IB dye in 65 min, demonstrating that the anodic oxidation was effective for the removal of color background. As reported by Soni et al. (2020), the use of NaCl as an electrolyte provides indirect oxidation, in addition, as sulfuric acid is being used in the dilution of IB, it is an acidic medium, which is also favorable for a high color reduction with electrodes like DSA by indirect oxidation [41]. When comparing the performance of the electrodes, it is possible to observe that at the beginning of the reaction the standard Ti/RuO 2 -TiO 2 (30:70) obtained a better performance, until it matched the performance of the composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) in 25 min, and from that moment the quaternary electrode started to perform better when compared to the standard. The good performance with a standard electrode was already expected because it is a widely used composition, with 70% TiO 2 which is a catalyst with great light absorption properties [15] and 30% of RuO 2 , a promising catalyst for hydrogen evolution reaction [42]. On the other hand, the composition of the quaternary anode also presents Ta 2 O 5 with excellent properties as a semiconductor and stabilizer [20], but its application has been little studied in DSAs and SnO 2 with a significant electrooxidation capacity and corrosion stability [23]. In this way, when used together, it was possible to obtain a competitive result with the standard formulation.

Photocatalysis
For the photocatalysis assay with the same DSAs of composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) and Ti/RuO 2 -TiO 2 (30:70), in addition to the same solution of AI 100 mg L −1 , with 2 mL of concentrated sulfuric acid, used to solubilize the dye and NaCl electrolyte 0.0167 mol L −1 . The test was performed in triplicate and the results obtained are shown in Figure 8. As the color removal process by photocatalysis was inefficient, the time was limite to 3 h. It is possible to observe that in the photocatalysis DSA Ti/RuO2-TiO2 (30:70), typ as standard, more effective color removal was obtained when compared to the new DS As the color removal process by photocatalysis was inefficient, the time was limited to 3 h. It is possible to observe that in the photocatalysis DSA Ti/RuO 2 -TiO 2 (30:70), type as standard, more effective color removal was obtained when compared to the new DSA formulation tested (Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 ), showing that standard DSA has a better response to UV light when compared to quaternary composition. This is due to the higher proportion of TiO 2 in the second electrode, which is a material that has great light absorption properties and, due to this characteristic, it is currently widely applied to photocatalytic and antibacterial technology [15].

Photoelectrocatalysis
The photoelectrocatalysis assay was performed with the same DSAs of composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) and Ti/RuO 2 -TiO 2 (30:70), and the same solution of IB 100 mg L −1 , with 2 mL of concentrated sulfuric acid, and a supporting electrolyte NaCl 0.0167 mol L −1 . The test was performed in triplicate and the results obtained are shown in Figure 9. For the photoelectrocatalysis test, the performance of DSA Ti/RuO2-TiO2-SnO (30:40:10:20) was better than the standard, since a color removal of 100% in 60 m achieved; however, only 5 min later the DSA Ti/RuO2-TiO2 (30:70) achieved 100% removal. When combining UV irradiation with the current, the quaternary formu again obtained competitive results, since, as mentioned, SnO2 has sign electrooxidation and Ta2O5 acted as a stabilizer. In Figure 10, it is possible to obser color of the solution before and after 65 min of photoelectrocatalysis, the final soluti a yellowish color. For the photoelectrocatalysis test, the performance of DSA Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) was better than the standard, since a color removal of 100% in 60 min was achieved; however, only 5 min later the DSA Ti/RuO 2 -TiO 2 (30:70) achieved 100% color removal. When combining UV irradiation with the current, the quaternary formulation again obtained competitive results, since, as mentioned, SnO 2 has significant electrooxidation and Ta 2 O 5 acted as a stabilizer. In Figure 10, it is possible to observe the color of the solution before and after 65 min of photoelectrocatalysis, the final solution has a yellowish color. As the initial suspicion is that the characteristic color is due to the presence of chlorinated compounds from the electrolyte (Equations (3)-(6)), sodium sulfide was used in this final solution. When reacting with chlorine and water, HCl was formed (Equation (7)), with translucent color, as can be seen in Figure 10, which confirms that the yellow color is due to the presence of chlorine in the solution.
Cl2(aq) + Na2SO3(aq) + H2O(l) → Na2SO4(aq) + 2HCl(aq) (7) Figure 6 shows the UV-vis spectrum of the initial solution of IB dye 100 mg L −1 and after different reaction times. The IB dye has only one peak in the visible region, at λ = 657 nm, and Figure 6 shows that in the first 15 min of reaction there is a decrease in this characteristic band, which continues to become smaller and smaller until it is no longer possible to be observed after 60 min. At that time, the absorbance of the solution was 0.007 and the color removal was 100%. At the time of 60 and 65 min, it is also possible to observe the formation of a new peak, close to 430 nm, characteristic of the yellow color that the solution takes on at that time due to the formation of chlorinated compounds. Other techniques have already been tested in the removal of IB, Table 5 presents some works and the results obtained in this article. Among the techniques used, the use of fungi stands out, which, in addition to being environmentally friendly, presented 100% color removal; on the other hand, for the removal to be complete, it took 4 days. Another technique that stands out is adsorption, because it uses a high initial concentration and obtains a removal of 90%; however, adsorption consists only of the transfer of mass from the fluid phase to the surface of the solid, allowing the separation of the components of the fluid, but not its degradation. In this work, the techniques of photocatalysis, electrocatalysis, and photoelectrocatalysis were explored using the DSA Ti/RuO2-TiO2-SnO2Ta2O5 (30:40:10:20) compared to Ti/RuO2-TiO2 (30:70). Photocatalysis did not perform well, as it took 3 h to remove just 63% of the dye, whereas the electrocatalysis and photoelectrocatalysis techniques had an excellent performance when degrading 100% of the IB at a concentration of 100 mg L −1 at 65 and 60 min, respectively, using a current of 20 mA. It is important to highlight that in the last two techniques mentioned, the performance of the new formulation was very similar to the standard composition of the electrode, demonstrating that the new composition is competitive, as well as interesting because they bring into their formulation SnO2 and Ta2O5, which, as mentioned, are materials with As the initial suspicion is that the characteristic color is due to the presence of chlorinated compounds from the electrolyte (Equations (3)-(6)), sodium sulfide was used in this final solution. When reacting with chlorine and water, HCl was formed (Equation (7)), with translucent color, as can be seen in Figure 10, which confirms that the yellow color is due to the presence of chlorine in the solution.
Cl 2 (aq) + Na 2 SO 3 (aq) + H 2 O(l) → Na 2 SO 4 (aq) + 2HCl(aq) (7) Figure 6 shows the UV-vis spectrum of the initial solution of IB dye 100 mg L −1 and after different reaction times. The IB dye has only one peak in the visible region, at λ = 657 nm, and Figure 6 shows that in the first 15 min of reaction there is a decrease in this characteristic band, which continues to become smaller and smaller until it is no longer possible to be observed after 60 min. At that time, the absorbance of the solution was 0.007 and the color removal was 100%. At the time of 60 and 65 min, it is also possible to observe the formation of a new peak, close to 430 nm, characteristic of the yellow color that the solution takes on at that time due to the formation of chlorinated compounds. Other techniques have already been tested in the removal of IB, Table 5 presents some works and the results obtained in this article. Among the techniques used, the use of fungi stands out, which, in addition to being environmentally friendly, presented 100% color removal; on the other hand, for the removal to be complete, it took 4 days. Another technique that stands out is adsorption, because it uses a high initial concentration and obtains a removal of 90%; however, adsorption consists only of the transfer of mass from the fluid phase to the surface of the solid, allowing the separation of the components of the fluid, but not its degradation. In this work, the techniques of photocatalysis, electrocatalysis, and photoelectrocatalysis were explored using the DSA Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) compared to Ti/RuO 2 -TiO 2 (30:70). Photocatalysis did not perform well, as it took 3 h to remove just 63% of the dye, whereas the electrocatalysis and photoelectrocatalysis techniques had an excellent performance when degrading 100% of the IB at a concentration of 100 mg L −1 at 65 and 60 min, respectively, using a current of 20 mA. It is important to highlight that in the last two techniques mentioned, the performance of the new formulation was very similar to the standard composition of the electrode, demonstrating that the new composition is competitive, as well as interesting because they bring into their formulation SnO 2 and Ta 2 O 5 , which, as mentioned, are materials with good stability. However, the new composition is still in the testing phase and therefore more in-depth studies are needed.

Conclusions
With the data obtained, it is possible to say that the DSA of composition Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20) has promising results in the degradation of the IB dye, especially when applying a current, even if low. Since the results found when the photoelectrocatalysis technique was applied, with a current of 20 mA and UV irradiation, were the best, with a color removal of 100% in 60 min. However, electrocatalysis obtained similar results, when applying at the current of 20 mA with a removal also of 100% in 65 min. Color removal when using photocatalysis with both DSAs was unsatisfactory, with maximum removal of 48% when using the quaternary anode. When comparing the results of the standard DSA and Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 , it is possible to affirm that the new composition performed well, with results that just did not stand out when using photocatalysis. Thus, the data obtained show the applicability of DSA Ti/RuO 2 -TiO 2 -SnO 2 Ta 2 O 5 (30:40:10:20), which is shown to be an effective activity for removing color from textile effluents such as IB from the aqueous medium.