Eye-Resolvable Surface-Plasmon-Enhanced Fluorescence Temperature Sensor

Temperature sensors are widely used in important fields such as daily home, medical care, and aerospace as a commonly used device for measuring temperature. Traditional temperature sensors such as thermocouples, thermal resistances, and infrared sensors are technically mature; however, they have limitations in the application environment, temperature measurement range, and temperature measurement accuracy. An eye-resolvable surface plasmon-enhanced fluorescence temperature sensor based on dual-emission Ag@SiO2@CdS/ZnS composite nanoparticle film with multiple-parameter detectable signals and high response sensitivity was proposed in this work. The temperature sensor’s x-chromaticity coordinate varied from 0.299 to 0.358 in the range of 77–297 K, while the y-chromaticity coordinate varied from 0.288 to 0.440, displaying eye-resolvable surface plasmon-enhanced fluorescence. The ratiometric response of two isolated photoluminescence (PL) peak-integrated areas located around 446 and 592 nm was found to be significantly temperature dependent, with a thermal sensitivity of 1.4% K−1, which can be used as an additional parameter to measure the precise temperature. Furthermore, the surface state emission peak intensity was linearly related to temperature, with a correlation index Adj. R-Square of 99.8%. Multiple independent temperature estimates can help with self-calibration and improve the measurement accuracy. Our findings show that the designed sensors can detect low temperatures while maintaining stability and reproducibility.


Introduction
Temperature sensor technology is widely used in aerospace, aviation, navigation, and other technical fields as well as in people's daily work and lives [1,2]. Traditional temperature sensors such as thermocouples, thermal resistances, and infrared sensors are technically mature; however, they have limitations in the application environment, temperature measurement range, and temperature measurement accuracy. At low temperatures close to liquid nitrogen, conventional thermocouple and resistance temperature sensors would self-heat, making it difficult to accurately measure low temperatures [3]. Because of their tunable particle size and composition as well as their high luminous efficiency, semiconductor quantum dots (QDs) have recently become widely used in lighting-emitting diodes, solar cells, temperature sensors, and optically pumped lasers [4][5][6]. Luminescence thermometry is a general optical technique used to measure the local temperature by using the variation in the luminescence properties of an indicator or probe (emission intensity and wavelength) with temperature [7,8]. As a result, it is critical to investigate the optical According to a previous study [27], Ag@SiO 2 @CdS/ZnS composite nanoparticles were synthesized. First, Ag nanoparticles were synthesized using the standard polyol method, and then the SiO 2 shell was deposited using the Stöber method. Here, 5 µL TEOS was used to control the thickness of the SiO 2 shell, which was about 10 nm. The reaction solution was then activated at 12,000 rpm after 10 µL (3-aminopropyl) triethoxylsiane (APS) was added to 2-mL Ag/SiO 2 solution stirred at room temperature for 8 h. Finally, a small amount of water-soluble CdS/ZnS QDs were added to the ethanol solution of the aminated Ag@SiO 2 nanoparticles and stirred for 1-2 h at room temperature. The film was prepared by spin coating Ag@SiO 2 @CdS/ZnS composite solutions onto a quartz substrate at 4500 rpm for 60 s using a Laurell WS-650MZ-23NPP adjustable speed homogenizer. The spun-coated Ag@SiO 2 @CdS/ZnS composite nanoparticles were placed in a vacuum liquid nitrogen cryostat within a temperature range of 77 to 297 K. The Ag@SiO 2 @CdS/ZnS composite nanoparticle film was spin-coated with a layer of polysilazane, which converts to a layer of silicon dioxide in the atmosphere to encapsulate the device.

Characterization Methods
Both low resolution and high-resolution transmission electron microscope (TEM) images were measured by Tecnai G20 of the FEI Company, with an acceleration voltage of 200 kV. The sample is dropped on the ultra-thin micro grid copper mesh covered with ultra-thin carbon film, and can be measured after the solvent evaporates. The atomic force microscope image is measured by a Multimode-8-AM atomic force microscope by Banker Nano. The absorption spectra were measured using a UV-Vis NIR spectrophotometer (UV-3600, Shimadzu). The temperature-variable measuring device of Edinburgh's F900 steady-state/transient fluorescence spectrometer was used, and liquid nitrogen was used as the cooling material. The PL spectra and time-resolved PL decay spectra of all samples were acquired by a fluorescence spectrometer (F900, Edinburgh instrument) under excitation at 375 nm. When measuring the steady-state PL spectrum, the power density of the exciting laser radiation was 2 W/cm 2 . When measuring the time-resolved PL decay spectrum, no more than one emission photon was generated under 1000 pulse pumping through continuous attenuator adjustment. The PL spectrum and lifetime of the Ag@SiO 2 @CdS/ZnS composite nanoparticles were measured under variable temperature in the experiment. The temperature options are as follows: 77,87,97,107,117,132,147,162,177,192,207,222,237,257,277, and 297 K. At each temperature point, we measured the PL spectrum and the lifetime decay curve separately. To reduce the experimental error in the measurement results, 30 min was added after each stable temperature point to ensure that the difference between the temperature in the cryostat and the set temperature was as small as possible. Figure 1 depicts the structure of a temperature sensor device with a broad measurement range based on the photo-induced fluorescence temperature change characteristics of an Ag@SiO 2 @CdS/ZnS composite nanoparticle film. The Ag@SiO 2 @CdS/ZnS composite nanoparticles were created using a multi-step procedure that included the fabrication of Ag nanoparticles, the deposition of SiO 2 shell, the decoration of the SiO 2 surface with -NH 2 groups, and finally, the self-assembly of water-soluble CdS-ZnS on the particle surface, as detailed in the experimental section. Spin-coating was used to coat the prepared Ag@SiO 2 @CdS/ZnS composite nanoparticles on a quartz wafer, which was then placed in a vacuum liquid nitrogen cryostat with a temperature range of 77 to 297 K. The PL spectrum and lifetime of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film were measured under variable temperature conditions in the experiment.  TEM images of CdS/ZnS core-shell QDs with an average size of 5.7 nm are shown in Figure 2a. The lattice spacing is clearly visible in the high-resolution transmission electron microscopy images (Figure 2a inset), indicating that the QDs are highly crystalline. Figur 2e shows the UV-Visible absorption and PL spectra of CdS/ZnS QDs. The absorption max imum of CdS/ZnS QDs was 431 nm. In addition to the first exciton absorption peak, th absorption spectrum showed several other absorption peaks, demonstrating that thes CdS QDs had a narrow particle size distribution. The fluorescence spectrum showed that in addition to a strong eigenstate emission peak, CdS QDs had an emission peak with larger half width in the long wavelength direction. A high number of dangling bond resulted in a high number of surface defect states. When the CdS QDs are excited, a por tion of the photogenerated carriers is captured by these defect states, resulting in surfac state luminescence. The peak positions of the BEE and SSE PL were 446 nm and 592 nm respectively. The TEM image shows that the Ag nanoparticles have a quasi-spherical mor phology with an average size of 32 nm (Figure 2b), and the nanoparticle-localized surfac plasmon resonance peak (LSPR) was found at 412 nm ( Figure 2e). The TEM image o Ag@SiO2 core/shell nanoparticles with a SiO2 shell thickness of about 10 nm is shown in Figure 1c, and the LSPR peak red-shifted to 424 nm ( Figure 1e). The CdS/ZnS QDs formed uniform monolayers on the Ag@SiO2 nanoparticles, as shown in Figure 2d. Moreover, th thickness of the Ag@SiO2@CdS/ZnS composite nanoparticle film measured by the step meter was about 150 nm. Figure S1 shows the atomic force microscopy (AFM) diagram o a representative Ag@SiO2@CdS/ZnS composite nanoparticle film. Within the measure ment range of 100 μm 2 , the root mean square and peak-to-peak surface roughness wer ~6 nm and ~55 nm, respectively (much less than the excitation and emission wavelengths) indicating that the film had a high-quality surface morphology and did not cause larg scattering noise. The light-emitting layer (Ag@SiO2@CdS/ZnS composite nanoparticl film) was composed of pure and dense Ag@SiO2@CdS/ZnS composite nanoparticles, and thus the distribution of nanoparticles in the film was uniform. The encapsulated SiO2 laye was only covered on the surface of the light-emitting layer film.  Figure 2e shows the UV-Visible absorption and PL spectra of CdS/ZnS QDs. The absorption maximum of CdS/ZnS QDs was 431 nm. In addition to the first exciton absorption peak, the absorption spectrum showed several other absorption peaks, demonstrating that these CdS QDs had a narrow particle size distribution. The fluorescence spectrum showed that, in addition to a strong eigenstate emission peak, CdS QDs had an emission peak with a larger half width in the long wavelength direction. A high number of dangling bonds resulted in a high number of surface defect states. When the CdS QDs are excited, a portion of the photogenerated carriers is captured by these defect states, resulting in surface state luminescence. The peak positions of the BEE and SSE PL were 446 nm and 592 nm, respectively. The TEM image shows that the Ag nanoparticles have a quasi-spherical morphology with an average size of 32 nm (Figure 2b), and the nanoparticle-localized surface plasmon resonance peak (LSPR) was found at 412 nm ( Figure 2e). The TEM image of Ag@SiO 2 core/shell nanoparticles with a SiO 2 shell thickness of about 10 nm is shown in Figure 1c, and the LSPR peak red-shifted to 424 nm ( Figure 1e). The CdS/ZnS QDs formed uniform monolayers on the Ag@SiO 2 nanoparticles, as shown in Figure 2d. Moreover, the thickness of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film measured by the step meter was about 150 nm. Figure S1 shows the atomic force microscopy (AFM) diagram of a representative Ag@SiO 2 @CdS/ZnS composite nanoparticle film. Within the measurement range of 100 µm 2 , the root mean square and peak-to-peak surface roughness were~6 nm and 55 nm, respectively (much less than the excitation and emission wavelengths), indicating that the film had a high-quality surface morphology and did not cause large scattering noise. The light-emitting layer (Ag@SiO 2 @CdS/ZnS composite nanoparticle film) was composed of pure and dense Ag@SiO 2 @CdS/ZnS composite nanoparticles, and thus the distribution of nanoparticles in the film was uniform. The encapsulated SiO 2 layer was only covered on the surface of the light-emitting layer film. Figure 3a depicts the temperature-dependent PL spectra of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film recorded at temperatures ranging from 77 to 297 K. The PL spectra of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film changed as the temperature changed. The BEE intensity of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film decreased with increasing temperature, which was attributed to the thermally activated nonradiative defects. The SSE intensity of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film decreased as the test temperature rose. It has been reported in the literature that the carriers of the intrinsic state will be transferred to the surface state (the trapping process of the surface trap state), increasing the luminescence intensity of the surface state [29]. Simultaneously, the effect of thermally activated nonradiative defects exists in this luminescence process, so the temperature-dependent change trend of the SSE intensity is determined by the competition of these two processes [9]. The quantum yield of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film at 297 K and 77 K were about 17% and 90%, respectively. Figure 3a depicts the temperature-dependent PL spectra of a Ag@SiO2@CdS/ZnS composite nanoparticle film recorded at temperatures ranging from 77 to 297 K. The PL spectra of a Ag@SiO2@CdS/ZnS composite nanoparticle film changed as the temperature changed. The BEE intensity of a Ag@SiO2@CdS/ZnS composite nanoparticle film decreased with increasing temperature, which was attributed to the thermally activated nonradiative defects. The SSE intensity of the Ag@SiO2@CdS/ZnS composite nanoparticle film decreased as the test temperature rose. It has been reported in the literature that the carriers of the intrinsic state will be transferred to the surface state (the trapping process of the surface trap state), increasing the luminescence intensity of the surface state [29]. Simultaneously, the effect of thermally activated nonradiative defects exists in this luminescence process, so the temperature-dependent change trend of the SSE intensity is determined by the competition of these two processes [9]. The quantum yield of the Ag@SiO2@CdS/ZnS composite nanoparticle film at 297 K and 77 K were about 17% and 90%, respectively.

Results and Discussion
The CIE chromaticity diagram depicts the trajectory of the (x, y) coordinates of the temperature-dependent dual-emission PL-spectrum from the Ag@SiO2@CdS/ZnS composite nanoparticle film (Figure 3b , which change dramatically with temperature. At 77 K, the ratio of the SSE and BEE emission intensities was 0.85, resulting in the effective green color. The BEE intensity decreased nearly half-fold at temperatures ranging from 77 to 162 K, while the SSE intensity decreased by about 30%. Because of these changes, the overall spectrally integrated PL intensity decreased by 30% and the emission color changed to yellow, as shown in Figure 3b. When the temperature was set to 297 K, the ratio of the SSE and BEE emission intensities was 0.36, and the CIE chromaticity diagram showed that the (x, y) coordinate of the emission light from the Ag@SiO2@CdS/ZnS composite nanoparticle film was located in the white area. Under different temperatures, the corresponding x-chromaticity coordinate of the as-prepared sensor was verified from 0.299 to 0.358, while the y-chromaticity coordinate was verified from 0.288 to 0.440, indicating that the temperature sensor displayed eye-resolvable surface plasmon-enhanced fluorescence. To demonstrate the function of Ag and SiO2 in plasmon-enhanced fluorescence and highlight why Ag@SiO2(10 nm)@CdS/ZnS composite nanoparticles were chosen to prepare the temperature sensor in this work, the CdS/ZnS nanoparticle film was also investigated. Figure S2a depicts the temperature-dependent PL spectra of a CdS/ZnS composite nanoparticle film recorded at temperatures ranging from 77 to 297 K. The CIE chromaticity diagram depicts the trajectory of (x, y) coordinates of the temperature-dependent PL-spectrum from the The BEE intensity decreased nearly half-fold at temperatures ranging from 77 to 162 K, while the SSE intensity decreased by about 30%. Because of these changes, the overall spectrally integrated PL intensity decreased by 30% and the emission color changed to yellow, as shown in Figure 3b. When the temperature was set to 297 K, the ratio of the SSE and BEE emission intensities was 0.36, and the CIE chromaticity diagram showed that the (x, y) coordinate of the emission light from the Ag@SiO 2 @CdS/ZnS composite nanoparticle film was located in the white area. Under different temperatures, the corresponding x-chromaticity coordinate of the as-prepared sensor was verified from 0.299 to 0.358, while the y-chromaticity coordinate was verified from 0.288 to 0.440, indicating that the temperature sensor displayed eye-resolvable surface plasmon-enhanced fluorescence. To demonstrate the function of Ag and SiO 2 in plasmon-enhanced fluorescence and highlight why Ag@SiO 2 (10 nm)@CdS/ZnS composite nanoparticles were chosen to prepare the temperature sensor in this work, the CdS/ZnS nanoparticle film was also investigated. Figure S2a depicts the temperature-dependent PL spectra of a CdS/ZnS composite nanoparticle film recorded at temperatures ranging from 77 to 297 K. The CIE chromaticity diagram depicts the trajectory of (x, y) coordinates of the temperature-dependent PL-spectrum from the CdS/ZnS QD film ( Figure S2b). Compared to Ag@SiO 2 @CdS/ZnS PCs, as the temperature increased, the SSE intensity changed very little ( Figure S2a) and the corresponding range of color coordinate changes was also very narrow ( Figure S2b). As shown in Figure S2b, the emission color range span was small, mainly distributed in the blue area. Moreover, the quantum yield of the CdS/ZnS QD film at 297 K was about 2%, indicating the PL signal of CdS/ZnS QDs was weak.
CdS/ZnS QD film ( Figure S2b). Compared to Ag@SiO2@CdS/ZnS PCs, as the temperature increased, the SSE intensity changed very little ( Figure S2a) and the corresponding range of color coordinate changes was also very narrow ( Figure S2b). As shown in Figure S2b, the emission color range span was small, mainly distributed in the blue area. Moreover, the quantum yield of the CdS/ZnS QD film at 297 K was about 2%, indicating the PL signal of CdS/ZnS QDs was weak. Temperature-dependent dual-emission PL spectroscopy allows for ratiometric measurements. As shown in Figure 3c, the ratiometric measurement result of the integrated PL peak area, R = I I ⁄ , showed two distinct regions. R is linearly dependent on temperature, with a slope of 0.00459 K −1 at low temperatures (77-130 K), and a slope of −0.00496 K −1 in the range of 130-297 K. Table 1 shows the linear function relationship parameters. The thermal sensitivity S is defined as S = , where R is the integrated PL peak area ratio at a given temperature ( T ). [7,30] The maximum sensitivity value for the Temperature-dependent dual-emission PL spectroscopy allows for ratiometric measurements. As shown in Figure 3c, the ratiometric measurement result of the integrated PL peak area, R = I SSE /I BEE , showed two distinct regions. R is linearly dependent on temperature, with a slope of 0.00459 K −1 at low temperatures (77-130 K), and a slope of −0.00496 K −1 in the range of 130-297 K. Table 1 shows the linear function relationship parameters. The thermal sensitivity S is defined as S = 1dR RdT , where R is the integrated PL peak area ratio at a given temperature (T) [7,30]. The maximum sensitivity value for the Ag@SiO 2 @CdS/ZnS composite nanoparticle film was easily observed to be 1.4% K −1 measured at 297 K, which was higher than most of the previously reported temperature sensors based on semiconductor QDs (Table 2). In comparison to CdHgTe QDs@NaCl and CdTe QD-layered double hydroxide ultrathin film luminophores, the dual-emission peaks of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film displayed two resolvable emission bands for different eye-resolvable surface plasmon-enhanced fluorescence. Furthermore, the dual emission with two different lifetimes (several nanoseconds for BEE and tens of nanoseconds for SSE) allows for the mutual calibration, which improves the temperature detection accuracy. The cycling experiment results are shown in Figure 3d; a minimal change in the PL peak intensities was observed during six consecutive cycles of repeated heating and cooling between 77 and 297 K, indicating its excellent reversibility and reliability as an optical sensor for thermometer applications. As a result, the integrated PL peak area ratio can be used as a further parameter to determine the precise temperature.  [21] Furthermore, the relationship between the PL spectra parameters and temperature, which included the PL peak wavelength and peak intensity, was investigated. The PL peak wavelength clearly redshifted as the temperature increased, indicating that the energy gap shrinks with increasing temperature due to the lattice transformation state and exciton-phonon coupling [38,39]. Figure 3e depicts the relationships between the SSE and BEE peak wavelengths of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film and temperature. A quadratic fitting polynomial can be used to represent the variation in the peak wavelength of the PL spectrum of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film with temperature, and the quadratic function relationship parameters are shown in Table 3. The Adj. R-Square represents the quadratic fitting degree, and the closer it is to one, the better [1]. Clearly, the Adj. R-Square of the relationship between the BEE or SSE peak wavelength of the temperature sensor based on the Ag@SiO 2 @CdS/ZnS composite nanoparticle film and temperature was greater than 0.995, indicating that both had an apparent quadratic function relationship. The dotted line in Figure 3e represents the quadratic fitting relationship between the PL peak wavelength and temperature, as shown in Figure 3a. Because the PL peak wavelength can be obtained by monitoring the PL spectrum, the temperature value can be calculated using the quadratic fitting relationship between the PL peak wavelength of the QD-based sensor and temperature. The temperature dependence of the Ag@SiO 2 @CdS/ZnS composite nanoparticles synthesized in the same batch was noted to be relatively stable. As a result, after calibrating a fluorescence sensor from the same batch of QD-based sensors, the fluorescence temperature sensors can be used to detect temperature. The PL spectra of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film were strongly temperature dependent. Figure 3f shows the PL peak intensity of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film as a function of temperature from 77 to 297 K. The PL intensity of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film decreased rapidly with increasing temperature, as shown in Figure 3a, indicating the presence of many nonradiative traps on the nanoparticle surface, resulting in strong thermal quenching. At room temperature, PL from a relatively broad excitonic emission near the CdS/ZnS band-edge dominated the emission from the Ag@SiO 2 @CdS/ZnS composite nanoparticle film. However, at low temperatures, the nanoparticles' internal structure generated two PL bands associated with an exciton emission near the CdS/ZnS band-edge and defect emission at lower energies. The normalized PL spectra intensity of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film at different temperatures is displayed to visualize the variation in the PL peak intensity with temperature. The linear fit relationship between the SSE peak intensity and temperature is shown in Figure 3f. A cubic fitting polynomial can simply represent the variation in the peak intensity of the BEE PL spectrum of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film with temperature. Table 4 displays the linear or cubic function relationship parameters. The results show that the SSE peak intensity had the best linear relationship with temperature increase among the PL spectral parameters, and the corresponding correlation index Adj. R-Square was 99.8%.  Figure 4a,b shows the BEE and SSE fluorescence lifetimes of a Ag@SiO 2 @CdS/ZnS composite nanoparticle film at various temperatures ranging from 77 to 297 K. The triple exponential mode fit all fluorescence relaxation curves well with F(t) = A + B 1 exp(−t/τ 1 ) + B 2 exp(−t/τ 2 ) + B 3 exp(−t/τ 3 ), where τ i is the characteristic lifetime component, B i is the exponential term coefficient, and A is the additional background value, respectively. Average lifetime is calculated using . The fluorescence lifetime decay curve in this experiment can be fitted by a triple exponential decay function, revealing three exciton recombination processes in nanocrystals: a fast decay process (τ 1 ) with a time of several nanoseconds; a moderate decay process (τ 2 ), with a time of 10 nanoseconds; and a slow decay process (τ 3 ), with a time of close to one hundred nanoseconds. The fast decay process is thought to be caused by the direct recombination of internal excitons [40][41][42], whereas the moderate and slow decay processes are thought to be caused by the interaction of exciton states and surface states [43][44][45]. At room temperature, the BEE and SSE lifetimes of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film were 5.8 ns and 6.8 ns, respectively, with the SSE lifetime being longer than the corresponding BEE lifetime due to the trapping and releasing effects of surface states. The fluorescence lifetimes of the SSE of the Ag@SiO 2 @CdS/ZnS composite nanoparticle film were 25.9 ns at 77 K and 6.8 ns at 297 K, with high-temperature decaying faster than lowtemperature decaying (Figure 4b,d). Nonradiative decay is significantly enhanced at high temperatures, decreasing the luminous intensity [21,46]. Furthermore, it has the largest exponential term coefficient B 1 among τ i , so the average lifetime is primarily determined by τ 1 , exhibiting a lifetime of several to tens of nanoseconds, which can support a very fast device response, as shown in Figure 4c,d. As a result, the Ag@SiO 2 @CdS/ZnS composite nanoparticle film's dual parameters (steady-state and transient fluorescence) will ensure its practical application.
being longer than the corresponding BEE lifetime due to the trapping and releasing effects of surface states. The fluorescence lifetimes of the SSE of the Ag@SiO2@CdS/ZnS composite nanoparticle film were 25.9 ns at 77 K and 6.8 ns at 297 K, with high-temperature decaying faster than low-temperature decaying (Figure 4b,d). Nonradiative decay is significantly enhanced at high temperatures, decreasing the luminous intensity [21,46]. Furthermore, it has the largest exponential term coefficient among , so the average lifetime is primarily determined by , exhibiting a lifetime of several to tens of nanoseconds, which can support a very fast device response, as shown in Figure 4c,d. As a result, the Ag@SiO2@CdS/ZnS composite nanoparticle film's dual parameters (steady-state and transient fluorescence) will ensure its practical application.

Conclusions
A dual-emission Ag@SiO2@CdS/ZnS composite nanoparticle film was used to construct a fluorescence temperature sensor. The PL spectral intensity gradually decreased with increasing temperature in the temperature range of 77-297 K. Under different temperatures, the as-prepared sensor's corresponding x-chromaticity coordinate varied from 0.299 to 0.358, while the y-chromaticity coordinate varied from 0.288 to 0.440, displaying eye-resolvable surface plasmon-enhanced fluorescence. The ratiometric response of the two isolated PL peak-integrated areas at around 446 and 592 nm was found to be significantly temperature dependent, with a thermal sensitivity of 1.4% K −1 , which can be used as an additional parameter to measure the precise temperature. Furthermore, the temperature-dependent PL peak intensity and peak wavelength were investigated to facilitate self-calibration and improve the temperature detection accuracy. This work demonstrates the successful design and fabrication of a simple, low-temperature detectable and eyeresolvable fluorescent film based on the Ag@SiO2@CdS/ZnS composite nanoparticles as well as its promising application as a fluorescence temperature sensor.

Conclusions
A dual-emission Ag@SiO 2 @CdS/ZnS composite nanoparticle film was used to construct a fluorescence temperature sensor. The PL spectral intensity gradually decreased with increasing temperature in the temperature range of 77-297 K. Under different temperatures, the as-prepared sensor's corresponding x-chromaticity coordinate varied from 0.299 to 0.358, while the y-chromaticity coordinate varied from 0.288 to 0.440, displaying eye-resolvable surface plasmon-enhanced fluorescence. The ratiometric response of the two isolated PL peak-integrated areas at around 446 and 592 nm was found to be significantly temperature dependent, with a thermal sensitivity of 1.4% K −1 , which can be used as an additional parameter to measure the precise temperature. Furthermore, the temperature-dependent PL peak intensity and peak wavelength were investigated to facilitate self-calibration and improve the temperature detection accuracy. This work demonstrates the successful design and fabrication of a simple, low-temperature detectable and eye-resolvable fluorescent film based on the Ag@SiO 2 @CdS/ZnS composite nanoparticles as well as its promising application as a fluorescence temperature sensor.