Facile In Situ Synthesis of Co(OH)2–Ni3S2 Nanowires on Ni Foam for Use in High-Energy-Density Supercapacitors

Ni3S2 nanowires were synthesized in situ using a one-pot hydrothermal reaction on Ni foam (NF) for use in supercapacitors as a positive electrode, and various contents (0.3−0.6 mmol) of Co(OH)2 shells were coated onto the surfaces of the Ni3S2 nanowire cores to improve the electrochemical properties. The Ni3S2 nanowires were uniformly formed on the smooth NF surface, and the Co(OH)2 shell was formed on the Ni3S2 nanowire surface. By direct NF participation as a reactant without adding any other Ni source, Ni3S2 was formed more closely to the NF surface, and the Co(OH)2 shell suppressed the loss of active material during charging–discharging, yielding excellent electrochemical properties. The Co(OH)2–Ni3S2/Ni electrode produced using 0.5 mmol Co(OH)2 (Co0.5–Ni3S2/Ni) exhibited a high specific capacitance of 1837 F g−1 (16.07 F cm−2) at a current density of 5 mA cm−2, and maintained a capacitance of 583 F g−1 (16.07 F cm−2) at a much higher current density of 50 mA cm−2. An asymmetric supercapacitor (ASC) with Co(OH)2–Ni3S2 and active carbon displayed a high-power density of 1036 kW kg−1 at an energy density of 43 W h kg−1 with good cycling stability, indicating its suitability for use in energy storage applications. Thus, the newly developed core–shell structure, Co(OH)2–Ni3S2, was shown to be efficient at improving the electrochemical performance.


Introduction
Currently, the main concerns in society are efficient energy storage and clean energy. Supercapacitors are the most ideal devices for use in clean energy storage, owing to their low costs, rapid discharge rates, and high electrochemical activities, in addition to mechanical and thermal stabilities [1,2]. However, despite numerous advantages, supercapacitors exhibit lower energy densities (~10 W h kg −1 ) compared to those of Li-ion batteries (LIBs, typically <300 Wh kg −1 ) [3,4]. Supercapacitors can be divided into electrochemical doublelayer capacitors (EDLCs) and pseudocapacitors. EDLCs employ an electric double layer formed at the interface of an electrolyte and a polarizable electrode, such as activated carbon (AC), and pseudocapacitors are based on the Faradaic electrochemical redox mechanism of charge storage [5]. Carbons with high surface areas are mainly used in EDLCs, whereas in pseudocapacitor research, oxides, such as ruthenium and manganese, are mainly used. According to a review of recent advances in carbon-based materials for use in supercapacitor electrodes, the specific energy is generally <10 Wh kg −1 [3,6,7]. Recently, mono-and bimetallic oxides, layered double hydroxides, and transition metal sulfides were proposed to overcome the lower energy densities in supercapacitors [8][9][10][11]. The transition metal sulfides (nickel or cobalt sulfide) exhibited considerable potential; in particular, nickel

Synthesis of Ni 3 S 2 and Co(OH) 2 -Ni 3 S 2 Positive Electrode
Ni 3 S 2 nanowires for use as positive active materials were synthesized using a one-pot hydrothermal reaction. For synthesizing the Ni 3 S 2 nanowires, the NF (2 × 1 cm 2 ) was used as the reactant and substrate. First, NF was sonicated in 3 M HCl for 30 min, and then washed for 30 min by deionized water and ethanol with volume ration of 1:1 to remove organic impurities and surface oxidized layer. The washed NF was subsequently vacuum-dried overnight at 50 • C.
The detailed experimental procedure for synthesizing the NF-supported Ni 3 S 2 nanowires is shown in Figure 1. The source of sulfur was the natural sulfur powder in molar ratios of 2 mmol. Sulfur powder (99.5%) was added to 8 mL of 3 M KOH and sonicated at 70 • C until the solution turned transparent yellow. A total of 8 mL of ethyl alcohol and NF (2 × 1 cm 2 ) were then added, and the solution was sonicated for a few minutes. Subsequently, the uniform solution was transferred to hydrothermal reactor. The reactor was heated for 18 h at 160 • C. The product, Ni 3 S 2 , was collected after the reaction system was cooled to below 30 • C. Thereafter, the Ni 3 S 2 film was washed and vacuum-dried at 50 • C overnight. During the hydrothermal process, sulfur reacts with the NF to uniformly deposit Ni 3 S 2 on the NF surface. The reaction formula for the formation of nickel sulfide on the NF may be as below: 3OH − + 4S → 2S 2− + S 2 O 3 2− + 3H + Ni + 2OH − → Ni(OH) 2 + 2e − 3Ni(OH) 2 + 2S 2− → Ni 3 S 2 + 6OH −

Synthesis of Ni3S2 and Co(OH)2-Ni3S2 Positive Electrode
Ni3S2 nanowires for use as positive active materials were synthesized using a one-pot hydrothermal reaction. For synthesizing the Ni3S2 nanowires, the NF (2 × 1 cm 2 ) was used as the reactant and substrate. First, NF was sonicated in 3 M HCl for 30 min, and then washed for 30 min by deionized water and ethanol with volume ration of 1:1 to remove organic impurities and surface oxidized layer. The washed NF was subsequently vacuumdried overnight at 50 °C.
The detailed experimental procedure for synthesizing the NF-supported Ni3S2 nanowires is shown in Figure 1. The source of sulfur was the natural sulfur powder in molar ratios of 2 mmol. Sulfur powder (99.5%) was added to 8 mL of 3 M KOH and sonicated at 70 °C until the solution turned transparent yellow. A total of 8 mL of ethyl alcohol and NF (2 × 1 cm 2 ) were then added, and the solution was sonicated for a few minutes. Subsequently, the uniform solution was transferred to hydrothermal reactor. The reactor was heated for 18 h at 160 °C. The product, Ni3S2, was collected after the reaction system was cooled to below 30 °C. Thereafter, the Ni3S2 film was washed and vacuum-dried at 50 °C overnight. During the hydrothermal process, sulfur reacts with the NF to uniformly deposit Ni3S2 on the NF surface. The reaction formula for the formation of nickel sulfide on the NF may be as below: For preparation of core-shell structured Co(OH)2-Ni3S2, after all sonication steps were completed, the 0.3, 0.4, 0.5, or 0.6 mmol of the source of cobalt was added and in the solution, followed by hydrothermal reaction at 160 °C for 18 h. The 0.3, 0.4, 0.5, or 0.6 mmol cobalt-containing Co(OH)2-Ni3S2 electrodes are denoted as Co0.3-, Co0.4-, Co0.5-, and Co0.6-Ni3S2, with a mass loading of 6.2, 6.8, 7.3, and 8.1 mg cm −2 , respectively.

Cell Assembly
For the electrochemical performance study, a three-electrode system was assembled using material formed in situ on NF (area ≈ 1 × 1 cm 2 ). Ni3S2 or Co(OH)2-Ni3S2 was used For preparation of core-shell structured Co(OH) 2 -Ni 3 S 2 , after all sonication steps were completed, the 0.3, 0.4, 0.5, or 0.6 mmol of the source of cobalt was added and in the solution, followed by hydrothermal reaction at 160 • C for 18 h. The 0.3, 0.4, 0.5, or 0.6 mmol cobalt-containing Co(OH) 2 -Ni 3 S 2 electrodes are denoted as Co 0.3 -, Co 0.4 -, Co 0.5 -, and Co 0.6 -Ni 3 S 2 , with a mass loading of 6.2, 6.8, 7.3, and 8.1 mg cm −2 , respectively.

Cell Assembly
For the electrochemical performance study, a three-electrode system was assembled using material formed in situ on NF (area ≈ 1 × 1 cm 2 ). Ni 3 S 2 or Co(OH) 2 -Ni 3 S 2 was used as the working electrode and Ag/AgCl and a Pt plate were used as the reference and counter electrodes, respectively. In the three-electrode configuration, 3 M KOH solution was used as the electrolyte.
The ASC device was assembled by Co 0.5 -Ni 3 S 2 and AC electrodes as the positive and as negative electrodes, respectively. KOH (3 M) and filter paper (Whatman 42) were used as the electrolyte and separator, respectively. Prior to assembling the ASC device, the AC negative electrode was prepared as follows: super-p carbon black, polyvinylidene fluoride, and AC as the conductive material, binder, and active material, respectively, were mixed in a mass ratio of 1:1:8 in N-methyl-2-pyrrolidinone (NMP) to form a uniform slurry. The slurry was uniformly coated on a Ni mesh and dried in an electrical oven at 60 • C for 1 h. The dried electrode was pressed and vacuum-dried at 110 • C for a day. In addition, the filter paper and as-prepared Co 0.5 -Ni 3 S 2 were immersed in electrolyte for a day. The ASC device was then assembled by sequentially stacking the soaked Co 0.5 -Ni 3 S 2 electrode, filter paper, and AC electrode.
The electrochemical performance of the three-electrode configuration was measured using an Autolab electrochemical workstation (AUT84455, Metrohm, Herisau, Switzerland). Electrochemical impedance spectroscopy (EIS) was performed in the frequency range 10 5 -10 −2 Hz at an amplitude of 10 mV using an Autolab electrochemical workstation (PGSTAT302N, Metrohm, The Netherlands). All resistances were determined using the NOVA program (Version 1.10.4, Metrohm, The Netherlands) to fit the related EI spectra. Cyclic voltammetry (CV, WBCS3000L, WonATech, Seoul, Korea) was measured at a scanning rate of 0.1 mV s −1 in the voltage range 1.5-3.2 V, and charge-discharge studies were performed at 0.1 C with a cut-off voltage of 1.5-3.2 V.

Results and Discussion
The XRD patterns of the Ni 3 S 2 and Co(OH) 2 -Ni 3 S 2 electrodes are shown in Figure 2 [42]. These nickel patterns are observed because Ni 3 S 2 was formed on the NF. The Co(OH) 2 -Ni 3 S 2 electrodes exhibit hexagonal and cubic phases, and their patterns lack the characteristic peaks representing Co(OH) 2 because they overlap with the hexagonal peaks representing Co(OH) 2 and/or the amorphous phase, which is formed by the hydrothermal reaction after CoCl 2 addition [43]. Peaks representing Co(OH) 2 [44]. Figure 3 shows the surface morphologies of the Ni 3 S 2 and Co(OH) 2 -Ni 3 S 2 electrodes with different Co contents were characterized using FE-SEM and elemental mapping analysis. Ni 3 S 2 exhibits a smooth surface, with the Ni 3 S 2 nanowires uniformly formed on the NF surface following the hydrothermal reaction, clearly indicating that the NF reacts with the added sulfur. The Ni 3 S 2 nanowires form very uniformly in terms of length and thickness, and no other form of Ni 3 S 2 is observed in the SEM images. As shown in the highly magnified SEM image of Ni 3 S 2 (inset of Figure 3b), long, thin nanowires are observed, with an average diameter of~150 ± 10 nm. As the amount of added Co increases, the smoothness of the nanowire surface decreases and the Co(OH) 2 shell thickness increases (Figure 3c-f), because Co(OH) 2 is only formed on the surfaces of the Ni 3 S 2 nanowires, rendering their surfaces rough. A rough surface may exhibit high electrolyte adsorption capacity due to its large specific surface area, and Co(OH) 2 may suppress the Ni 3 S 2 active material loss during the cycling, resulting in excellent electrochemical properties. In addition, as shown by the side views of the elemental mapping images (Figure 3g,h), all elements are distributed uniformly on the nanowires. Therefore, the synthesis via hydrothermal reaction at 160 • C for 18 h is successful.  Figure 3 shows the surface morphologies of the Ni3S2 and Co(OH)2-Ni3S2 electrodes with different Co contents were characterized using FE-SEM and elemental mapping analysis. Ni3S2 exhibits a smooth surface, with the Ni3S2 nanowires uniformly formed on the NF surface following the hydrothermal reaction, clearly indicating that the NF reacts with the added sulfur. The Ni3S2 nanowires form very uniformly in terms of length and thickness, and no other form of Ni3S2 is observed in the SEM images. As shown in the highly magnified SEM image of Ni3S2 (inset of Figure 3b), long, thin nanowires are observed, with an average diameter of ~150 ± 10 nm. As the amount of added Co increases, the smoothness of the nanowire surface decreases and the Co(OH)2 shell thickness increases (Figure 3c-f), because Co(OH)2 is only formed on the surfaces of the Ni3S2 nanowires, rendering their surfaces rough. A rough surface may exhibit high electrolyte adsorption capacity due to its large specific surface area, and Co(OH)2 may suppress the Ni3S2 active material loss during the cycling, resulting in excellent electrochemical properties. In addition, as shown by the side views of the elemental mapping images (Figure 3g,h), all elements are distributed uniformly on the nanowires. Therefore, the synthesis via hydrothermal reaction at 160 °C for 18 h is successful.    Figure 3 shows the surface morphologies of the Ni3S2 and Co(OH)2-Ni3S2 electrodes with different Co contents were characterized using FE-SEM and elemental mapping analysis. Ni3S2 exhibits a smooth surface, with the Ni3S2 nanowires uniformly formed on the NF surface following the hydrothermal reaction, clearly indicating that the NF reacts with the added sulfur. The Ni3S2 nanowires form very uniformly in terms of length and thickness, and no other form of Ni3S2 is observed in the SEM images. As shown in the highly magnified SEM image of Ni3S2 (inset of Figure 3b), long, thin nanowires are observed, with an average diameter of ~150 ± 10 nm. As the amount of added Co increases, the smoothness of the nanowire surface decreases and the Co(OH)2 shell thickness increases (Figure 3c-f), because Co(OH)2 is only formed on the surfaces of the Ni3S2 nanowires, rendering their surfaces rough. A rough surface may exhibit high electrolyte adsorption capacity due to its large specific surface area, and Co(OH)2 may suppress the Ni3S2 active material loss during the cycling, resulting in excellent electrochemical properties. In addition, as shown by the side views of the elemental mapping images (Figure 3g,h), all elements are distributed uniformly on the nanowires. Therefore, the synthesis via hydrothermal reaction at 160 °C for 18 h is successful.  HRTEM was conducted to further explore the structures of the Co 0.5 -Ni 3 S 2 nanowires. As shown in Figure 4a,b, the Ni 3 S 2 nanowires cores are uniformly covered by Co(OH) 2 nanosheets shells. The interphase between Ni 3 S 2 and Co(OH) 2 is no clear boundary observed, indicating that a close contact was formed between them. Such a structure may result in improved electrochemical performance as it favors electron transfer during the Faradaic redox reactions [45]. The diameters of the core Ni 3 S 2 nanowires are~150 nm, and the Co(OH) 2 layers covering the Ni 3 S 2 nanowires exhibit thicknesses in the range 20-40 nm. As shown in Figure 4c, the Co 0.5 -Ni 3 S 2 nanowires exhibit uniform distributions of Ni, S, and Co. This further confirming the formation of a uniform, well-defined coreshell structure. The HRTEM image of the Co 0.5 -Ni 3  Faradaic redox reactions [45]. The diameters of the core Ni3S2 nanowires are ~150 nm, and the Co(OH)2 layers covering the Ni3S2 nanowires exhibit thicknesses in the range 20-40 nm. As shown in Figure 4c, the Co0.5-Ni3S2 nanowires exhibit uniform distributions of Ni, S, and Co. This further confirming the formation of a uniform, well-defined core-shell structure. The HRTEM image of the Co0.5-Ni3S2 nanowire (Figure 4d) reveals lattice spacings of 0.4, 0.28, and 0.24 nm, corresponding to the (110) and (101) interplanar spacings of Ni3S2 and the (101) interplanar spacings of Co(OH)2, respectively. As shown in the selected area electron diffraction (SAED) pattern (Figure 4e), several distinct concentric rings clearly indicate the polycrystallinity of Ni3S2, and the diffraction rings from inside to outside correspond to the (101), (110), (003), (202), (113), and (104) crystalline planes of Ni3S2, respectively. Additional evidence regarding the chemical state of the as-synthesized Co0.5-Ni3S2 electrode was obtained using XPS. The full survey spectrum (Figure 5a) of the Co0.5-Ni3S2 electrode reveals that only Ni, Co, O, and C are present, with no other impurity peaks observed. The presence of Co and O is likely caused by the adsorption of Co(OH)2 at the surface of the Ni3S2 nanowire, and the small C presence may be due to the reference and the exposure of the sample to the atmosphere [46]. The high-resolution spectrum of Ni 2p (Figure 5b) shows two main core levels of Ni 2p3/2 and Ni 2p1/2 that are characteristic of the Ni state are located at 855.1 and 872.8 eV, with two satellite peaks at 860.9 and 878.9 eV, respectively, indicating the formation of Ni 2+ and Ni 3+ [47][48][49]. To investigate the Co(OH)2 shell formation on the surfaces of the Ni3S2 nanowires, the Co 2p XP spectrum was obtained, as shown in Figure   Additional evidence regarding the chemical state of the as-synthesized Co 0.5 -Ni 3 S 2 electrode was obtained using XPS. The full survey spectrum (Figure 5a) of the Co 0.5 -Ni 3 S 2 electrode reveals that only Ni, Co, O, and C are present, with no other impurity peaks observed. The presence of Co and O is likely caused by the adsorption of Co(OH) 2 at the surface of the Ni 3 S 2 nanowire, and the small C presence may be due to the reference and the exposure of the sample to the atmosphere [46]. The high-resolution spectrum of Ni 2p (Figure 5b) shows two main core levels of Ni 2p 3/2 and Ni 2p 1/2 that are characteristic of the Ni state are located at 855.1 and 872.8 eV, with two satellite peaks at 860.9 and 878.9 eV, respectively, indicating the formation of Ni 2+ and Ni 3+ [47][48][49]. To investigate the Co(OH) 2 shell formation on the surfaces of the Ni 3 S 2 nanowires, the Co 2p XP spectrum was obtained, as shown in Figure 5c. Peaks representing Co 2p 3/2 (780.4 and 774.0 eV) and Co 2p 1/2 (796.5 and 796.0 eV) are observed. These peaks (796.0 and 780.4 eV) are attributed to Co 2+ , indicating the formation of Co(OH) 2 [50][51][52]. For detailed insight into the presence of hydroxide, the O 1s spectrum of the Co 0.5 -Ni 3 S 2 electrode was analyzed, as shown in Figure 5d. The curve fitting of the O 1s spectrum indicates that the sample consists of two components, represented by peaks at 531.5 and 530.4 eV. The 531.5 eV peak indicates a bound hydroxide group (OH − ), confirming that Co(OH) 2 is successfully formed on the Ni 3 S 2 surface [53,54]. The small peak at 530.4 eV indicates the H-O bonds in water [55][56][57]. Therefore, the XP spectra, when combined with the XRD and TEM results, indicate the successful preparation of the Co(OH) 2 shells on the surfaces of the Ni 3 S 2 nanowire cores. components, represented by peaks at 531.5 and 530.4 eV. The 531.5 eV peak indicates a bound hydroxide group (OH − ), confirming that Co(OH)2 is successfully formed on the Ni3S2 surface [53,54]. The small peak at 530.4 eV indicates the H-O bonds in water [55][56][57]. Therefore, the XP spectra, when combined with the XRD and TEM results, indicate the successful preparation of the Co(OH)2 shells on the surfaces of the Ni3S2 nanowire cores. The electrochemical behaviors of the Ni3S2 and Co(OH)2-Ni3S2 electrodes were initially investigated using CV (Figure 6a). For Ni3S2, redox peaks are observed at 0.20 and 0.30 V, respectively, indicating pseudocapacitive behavior [58]. Compared to those of Ni3S2, the redox peaks shift negatively in the voltammogram of Co(OH)2-Ni3S2, indicating that the surface redox reactions of Co 2+ /Co 3+ /Co 4+ and Ni 2+ /Ni 3+ may facilitate OH − transfer from the electrolyte [59,60]. The voltammogram of Co0.5-Ni3S2 clearly shows a large integrated area, suggesting that the former exhibits a higher electrochemical capacitance. Figure 6b shows the CV of the Co0.5-Ni3S2 electrode at scan rates ranging from 5 to 50 mV s −1 . The response current density increases linearly with increasing scan rate and the cathodic and cathodic current peaks are shifted more positively and negatively, respectively. However, as the scan rates increase, clear redox peaks are observed, indicating the slow electron or ion transfer kinetics of the interfacial redox reactions [61]. Conversely, the voltammograms of Co0.5-Ni3S2 at scan rates of ≤20 mV s −1 retain their original shapes, and the currents are higher than that of Ni3S2, indicating the rapid kinetics of electron or ion transfer in the interfacial redox reactions [62]. Figure 6c shows the galvanostatic charge/discharge (GCD) curves of Co0.5-Ni3S2 at different current densities. All GCD curves shows the clear voltage plateaus suggesting Faradaic redox reactions. The specific capacitance, SCs, (CS, F g −1 ) and area capacitances (CA, F cm −2 ) of the electrodes are calculated based on the GCD curves using the following equations [63]: The electrochemical behaviors of the Ni 3 S 2 and Co(OH) 2 -Ni 3 S 2 electrodes were initially investigated using CV (Figure 6a). For Ni 3 S 2 , redox peaks are observed at 0.20 and 0.30 V, respectively, indicating pseudocapacitive behavior [58]. Compared to those of Ni 3 S 2 , the redox peaks shift negatively in the voltammogram of Co(OH) 2 -Ni 3 S 2 , indicating that the surface redox reactions of Co 2+ /Co 3+ /Co 4+ and Ni 2+ /Ni 3+ may facilitate OH − transfer from the electrolyte [59,60]. The voltammogram of Co 0.5 -Ni 3 S 2 clearly shows a large integrated area, suggesting that the former exhibits a higher electrochemical capacitance. Figure 6b shows the CV of the Co 0.5 -Ni 3 S 2 electrode at scan rates ranging from 5 to 50 mV s −1 . The response current density increases linearly with increasing scan rate and the cathodic and cathodic current peaks are shifted more positively and negatively, respectively. However, as the scan rates increase, clear redox peaks are observed, indicating the slow electron or ion transfer kinetics of the interfacial redox reactions [61]. Conversely, the voltammograms of Co 0.5 -Ni 3 S 2 at scan rates of ≤20 mV s −1 retain their original shapes, and the currents are higher than that of Ni 3 S 2 , indicating the rapid kinetics of electron or ion transfer in the interfacial redox reactions [62]. Figure 6c shows the galvanostatic charge/discharge (GCD) curves of Co 0.5 -Ni 3 S 2 at different current densities. All GCD curves shows the clear voltage plateaus suggesting Faradaic redox reactions. The specific capacitance, SCs, (C S , F g −1 ) and area capacitances (C A , F cm −2 ) of the electrodes are calculated based on the GCD curves using the following equations [63]: where I, ∆V, ∆t, m, and A denote the discharge current (mA), working potential window (V), discharging time (s), deposited mass of the active material (g), and area of the NF coated with the active material (1 × 1 cm 2 ), respectively.
to 451.8 F g −1 (5.63 F cm −2 ) when the current density increases to 50 mA cm −2 . As shown in the GCD curve, the electrode materials of the Ni3S2 and Co-Ni3S2 shows the clearly redox plateau; therefore, the specific and area capacities (dotted lines) were also plotted in the Figure 6d,e. The discharge capacity of Co0.5-Ni3S2 shows that the 90.1 mAh g −1 at a current density of 10 mA cm −2 and 52.8 mAh g −1 at 50 mA cm −2 . The high SC and capacity of Co0.5-Ni3S2 may be due to the unique core-shell nanowires, wherein highly conductive Ni3S2 with a high SC is critical in enhancing the capacitance of Co(OH)2 with an ultrathin nanosheet morphology. Figure 6f shows the cycling performances of Ni3S2 and Co-Ni3S2. Ni3S2 and Co0.5-Ni3S2 showed retention rates of 83.7% and 95.4%, respectively, up to 1000 cycles, indicating that the core-shell structure improves the long-term electrochemical stability of the KOH electrolyte system. The optimal SC and cycling performance of the electroactive Ni3S2 electrode are superior or comparable to those of previously reported Ni3S2 electrodes (Table 1) [25,[64][65][66][67][68].   Figure 6d,e shows the rate capabilities of various electrodes calculated during GCD. Co 0.5 -Ni 3 S 2 exhibits a very high SC compared to those of the other samples. The SC (plot with slid lines) is 742.6 F g −1 (9.25 F cm −2 ) at a current density of 10 mA cm −2 , which declines to 451.8 F g −1 (5.63 F cm −2 ) when the current density increases to 50 mA cm −2 . As shown in the GCD curve, the electrode materials of the Ni 3 S 2 and Co-Ni 3 S 2 shows the clearly redox plateau; therefore, the specific and area capacities (dotted lines) were also plotted in the Figure 6d,e. The discharge capacity of Co 0.5 -Ni 3 S 2 shows that the 90.1 mAh g −1 at a current density of 10 mA cm −2 and 52.8 mAh g −1 at 50 mA cm −2 . The high SC and capacity of Co 0.5 -Ni 3 S 2 may be due to the unique core-shell nanowires, wherein highly conductive Ni 3 S 2 with a high SC is critical in enhancing the capacitance of Co(OH) 2 with an ultrathin nanosheet morphology. Figure 6f shows the cycling performances of Ni 3 S 2 and Co-Ni 3 S 2 . Ni 3 S 2 and Co 0.5 -Ni 3 S 2 showed retention rates of 83.7% and 95.4%, respectively, up to 1000 cycles, indicating that the core-shell structure improves the long-term electrochemical stability of the KOH electrolyte system. The optimal SC and cycling performance of the electroactive Ni 3 S 2 electrode are superior or comparable to those of previously reported Ni 3 S 2 electrodes (Table 1) [25,[64][65][66][67][68].
The electrochemical performance of the AC electrode in the three-electrode configuration was measured, with the AC coated on a nickel mesh (1 × 1 cm 2 ) used as the working electrode. Figure 7 shows the electrochemical behavior of the AC electrode at different scan rates. The CV curves (Figure 7a) of the AC electrode reveal excellent symmetrical rectangular shapes at all scan rates. This is characteristic of an ideal EDLC material and suggests good charge propagation, rapid ion diffusion within the pores and reorganization of the electrical double layer, and low contact resistance [69]. Figure 7b,c show the GCD curves of the AC electrode at different current densities (10-50 mA cm −2 ) and the rate capabilities, respectively. The charge-discharge curves of AC electrodes are linear and symmetrical, indicating the good reversibility. The SCs of the AC electrode are calculated Nanomaterials 2022, 12, 34 9 of 15 based on the GCD curves using Equation (1). An SC is 109.8 F g −1 (0.4 F cm −2 ) appears at 5 mA cm −2 , which declines to 101.5 F g −1 (0.34 F cm −2 ) at 50 mA cm −2 . The AC electrode maintains 99.5% of its initial capacitance after 2000 cycles as shown in Figure 6d. The electrochemical performance of the AC electrode in the three-electrode configuration was measured, with the AC coated on a nickel mesh (1 × 1 cm 2 ) used as the working electrode. Figure 7 shows the electrochemical behavior of the AC electrode at different scan rates. The CV curves (Figure 7a) of the AC electrode reveal excellent symmetrical rectangular shapes at all scan rates. This is characteristic of an ideal EDLC material and suggests good charge propagation, rapid ion diffusion within the pores and reorganization of the electrical double layer, and low contact resistance [69]. Figure 7b, c show the GCD curves of the AC electrode at different current densities (10-50 mA cm −2 ) and the rate capabilities, respectively. The charge-discharge curves of AC electrodes are linear and symmetrical, indicating the good reversibility. The SCs of the AC electrode are calculated based on the GCD curves using Equation (1). An SC is 109.8 F g −1 (0.4 F cm −2 ) appears at 5 mA cm −2 , which declines to 101.5 F g −1 (0.34 F cm −2 ) at 50 mA cm −2 . The AC electrode maintains 99.5% of its initial capacitance after 2000 cycles as shown in Figure 6d. The ASC device was assembled in a two-electrode configuration using a Co0.5-Ni3S2 positive electrode and an AC negative electrode. Prior to assembling the ASC device, the mass balance of the positive and negative electrodes was determined. The mass (m) of the positive and negative electrodes was determined by Equation The ASC device was assembled in a two-electrode configuration using a Co 0.5 -Ni 3 S 2 positive electrode and an AC negative electrode. Prior to assembling the ASC device, the mass balance of the positive and negative electrodes was determined. The mass (m) of the positive and negative electrodes was determined by Equation (3) [70]: where m, C, and ∆V are the masses, SCs, and potential windows of the Co 0.5 -Ni 3 S 2 positive (+) and AC negative (−) electrodes, in a typical three-electrode configuration. The mass ratio of AC and Co 0.5 -Ni 3 S 2 is 2.73:1. The SC of the device was calculated using Equation (1), where m is the sum of the deposited masses of Co 0.5 -Ni 3 S 2 and AC (cathode and anode materials, respectively). The total active mass is 27 mg. The potential window of the Co 0.5 -Ni 3 S 2 //AC device is obtained from the cyclic voltammograms of Co 0.5 -Ni 3 S 2 ( Figure 6b) and AC (Figure 7a) in a three-electrode cell. AC exhibits the typical EDLC pattern in the potential range from −1.0-0.0 V and Co 0.5 -Ni 3 S 2 exhibits the potential range 0-0.4 V. Based on the cyclic voltammograms of the Co 0.5 -Ni 3 S 2 and AC electrodes, the potential window of the ASC device may be extended to 1.6 V [71]. The cyclic voltammograms exhibit large current areas with broad redox peaks, which are typical of asymmetric supercapacitors that combine electrochemical capacitors and EDLC properties [72]. The potential window of the Co 0.5 -Ni 3 S 2 //AC device was again confirmed using CV at different windows. As shown in Figure 8a, no clear polarization is observed in the voltage range 0.0-1.60 V, indicating that 1.40 V is a reasonable potential window limit for this ASC in 3.0 M KOH electrolyte. Therefore, the combined working potential of the ASC is 1.6 V. Figure 8b shows the CV of the ASC at different scan rates in the potential window 0-1.6 V. The CV exhibit broad redox peaks, which are associated with the pseudocapacitive Ni 3 S 2 and AC, indicating the ideal capacitive behavior of the device [73]. Figure 8c shows the typical GCD curves of the ASC with observed SCs of 2.37 F cm −2 (58.41 F g −1 ) at 20 mA cm −2 . In addition, the SC retention of the ASC device is 94% at 20 mA cm −2 , as shown in the inset of Figure 8c. To study the interfacial charge transfer resistance of the supercapacitor with the Co 0.5 -Ni 3 S 2 //AC device, EIS was performed after the 1st and 1000th discharges, as shown in Figure 8d. The Nyquist plot in the high-frequency region reveals that the electronic resistance of the device, also denoted the solution resistance (R S ), is the equivalent series resistance (ESR), which describes the resistance of the electrolyte combined with the internal resistance of the electrode [74]. The semicircle is the result of the double-layer charging of the AC electrode and the Faradaic reaction of the Co 0.5 -Ni 3 S 2 electrode. The slope of the curve in the low-frequency region corresponds to the Warburg element, which represents the electrolyte diffusion within the porous electrode and proton diffusion within the host material [75,76]. The Nyquist plot was fitted using the Randles equivalent circuit, as shown in the inset of Figure 8d, using the NOVA program, where R ct is the electrode-electrolyte charge transfer resistance, R L is the leakage resistance, C L is the double-layer capacitance, CPE DL is the constant phase element of the double layer, and CPE L is the mass capacitance. The ESR of the asymmetric device decreases from 0.25 to 0.22 Ω after 1000 cycles, and R ct also decreases after 1000 cycles, suggesting a significant decrease in the R S and R ct due to the increased surface area available during repeated cycling, which may improve the supercapacitor performance [77].
The Co 0.5 -Ni 3 S 2 //AC asymmetric device exhibits a maximum energy density of 60.3 W h kg −1 (20 mA cm −2 ) at a power density of 1944.3 W kg −1 (50 mA cm −2 ) and 36.0 W h kg −1 at a power density of 4309 W kg −1 . The energy (E, W h kg −1 ) and power densities (P, W kg −1 ) are calculated based on the discharge curve using Equations (4) and (5), respectively [78]: where, I, Vdt, m, and t are the discharge current (mA), integral area under the discharge curve, masses, and discharging time (s), respectively. The results are comparable or even superior to those of previously reported supercapacitors (  [66,[79][80][81][82][83][84][85]. A comparison of these results based on power and energy densities with related reported devices is also summarized. To further evaluate the practical applications of the Co 0.5 -Ni 3 S 2 //AC asymmetric device, the assembled device easily powers an LED after charging, as shown in the inset of Figure 8c. The Co 0.5 -Ni 3 S 2 //AC asymmetric device exhibits consid-erable potential for use in next-generation flexible energy storage devices, for applications in smart, wearable electronics. The Co0.5-Ni3S2//AC asymmetric device exhibits a maximum energy density of 60.3 W h kg −1 (20 mA cm −2 ) at a power density of 1944.3 W kg −1 (50 mA cm −2 ) and 36.0 W h kg −1 at a power density of 4309 W kg −1 . The energy (E, W h kg −1 ) and power densities (P, W kg −1 ) are calculated based on the discharge curve using Equations (4) and (5), respectively [78]: where, I, ∫ , m, and t are the discharge current (mA), integral area under the discharge curve, masses, and discharging time (s), respectively. The results are comparable or even superior to those of previously reported supercapacitors (  [66,[79][80][81][82][83][84][85]. A comparison of these results based on power and energy densities with related reported devices is also summarized. To further evaluate the practical applications of the Co0.5-Ni3S2//AC asymmetric device, the assembled device easily powers an LED after charging, as shown in the inset of Figure 8c. The Co0.5-Ni3S2//AC asymmetric device exhibits considerable potential for use in next-generation flexible energy storage devices, for applications in smart, wearable electronics.

Conclusions
Ni 3 S 2 and Co(OH) 2 shell-coated Ni 3 S 2 nanowires were successfully prepared using a facile one-step hydrothermal reaction as positive electrodes for use in supercapacitors. The Ni 3 S 2 nanowires were uniformly formed on the smooth NF surface, and the Co(OH) 2 shell was uniformly formed on the Ni 3 S 2 nanowire surface. As NF participates directly as the nickel source, Ni 3 S 2 was formed more closely to the NF surface, and the Co(OH) 2 shell suppressed the loss of active material during charging-discharging. The 0.5 mmol Co(OH) 2 shell-coated Co 0.5 -Ni 3 S 2 electrode exhibited superior performance, with a high discharge capacity of 1837 F g −1 (16.07 F cm −2 ) at a current density of 5 mA cm −2 , and maintained a satisfactory rate capability of 583 F g −1 (16.07 F cm −2 ) at a much higher current density of 50 mA cm −2 . The ASC delivers a power density as high as 1036 W kg −1 at an energy density of 43 W h kg −1 , with a good cycling stability of 92%, which reveals its suitability for use in numerous energy storage applications. Therefore, the core-shell architecture developed in this study is an efficient way to improve the electrochemical performances in various promising energy storage applications.