The Dependence of InAs/InAsSb Superlattice Detectors’ Spectral Response on Molecular Beam Epitaxy Growth Temperature

: In this paper, we report on the inﬂuence of molecular beam epitaxial (MBE) growth temperature on the spectral response of the long-wavelength infrared radiation (LWIR), three-stage thermoelectrically (TE) cooled ( T = 210, 230 K) InAs/InAsSb type-II superlattice (T2SL)-based detectors grown on the GaSb/GaAs buffer layers/substrates. Likewise, antimony (Sb) composition and the superlattice (SL) period could be used for spectral response selection. The presented results indicate that the growth temperature affects the 50% cut-off ( λ 50%cut-off ) of the fabricated devices and could be used for operating wavelength tunning. Assuming constant Sb composition and T2SL period during MBE process, the growth temperature is presented to inﬂuence λ 50%cut-off covering entire LWIR (e.g., temperature growth change within the range of 400–450 ◦ C contributes to the λ 50%cut-off ~ 11.6–8.3 µ m estimated for operating temperature, T = 230 K). An increase in temperature growth makes a blueshift of the λ 50%cut-off , and this is postulated to be a consequence of a modiﬁcation of the SL interfaces. These results show an approach to the T2SL InAs/InAsSb deposition optimization by the growth temperature in terms of the spectral response, without inﬂuencing the T2SLs’ structural properties (Sb composition, SL period).


Introduction
Long-wavelength infrared radiation (LWIR; 8-12 µm) is still one of the most exploited spectral ranges for military, spectroscopy, gas sensing, or meteorology applications [1,2].Nowadays, due to the improvement of epitaxial techniques, especially molecular beam epitaxy (MBE), the superlattice (SL) concept presented by Esaki and Tsu in 1970 has presented itself as a potential candidate (proved by many scientific papers) to supersede HgCdTe [3].SL detectors made of III-V materials have stronger covalent bonds than HgCdTe, which results in a higher operating temperature range and better material uniformity [4].Growth temperature is one of the most important control parameters during the MBE process.Omitting the problem connected with the temperature measurements inside the chamber, it is commonly known that the growth temperature (T growth ) mainly influences crystal quality.Over the past few years, the dependence of the crystal quality, nucleation mode, and carrier mobility on the T growth of the simple bulk semiconductor structures has been investigated, to find the optimal growth condition.However, research data are lacking for much more sophisticated structures such as type-II superlattice (T2SLs) [5][6][7].The T2SL InAs/InAsSb is a quantum structure consisting of connected InAs and InAsSb layers (generally with an antimony (Sb) composition, x Sb ~0.4).The structure is designed to be lattice matched to GaSb substrate or GaSb buffer layer/GaAs substrate.The ideal T2SL InAs/InAsSb structure consists of sharp interfaces without the addition of any extra sublayers such as in T2SLs InAs/GaSb, as shown in Figure 1 [8].In the real T2SL, it is hard to obtain defect-free interfaces, especially when a thin InAsSb layer is utilized.This requires growth interruptions and necessitates soaking time between each layer.Moreover, the potential composition changes at the interfaces are hard to predict.These interface issues are directly responsible for discrepancies between a theoretical computer simulation of band structure and experimental results.In this study, we show that the MBE growth temperature can indirectly affect the detector's spectral response, just as a thicker SL period or higher Sb composition results in a redshift of λ50%cut-off InAs/InAsSb T2SLs, which gives flexibility in detector's designing procedure without influencing any SL structural parameters.In this paper, a series of T2SL InAs/InAsSb detectors optimized for the LWIR range were investigated with a particular focus on the growth temperature, in order to show the cut-off wavelength range tunning for LWIR.

Material Growth Procedure
Each T2SL InAs/InAsSb structure was grown in a RIBER Compact 21-DZ solid source MBE system, on 2" semi-insulating GaA (001) substrates.The substrate temperature during the growth was monitored by a manipulator thermocouple.The substrate temperature was the only parameter being changed intentionally during the growth campaigns.A detailed description of the buffer layer growth and substrate preparation procedure can be found elsewhere [9].The T2SLs growth conditions and parameters were adapted after Lee et al. and Sarney et al. [10,11].The GaA substrates were used to implement low-cost substrates in the mass fabrication of the backside-illuminated devices.Two sets of samples were prepared.The T2SL growth parameters are presented in Table 1.The approx.300 periods (P) T2SLs InAs/InAsSb were grown on 250 nm GaAs smoothing layer, followed by 1.2 μm thick GaSb buffer on the GaAs substrates.The 1.2 μm thick buffer connected with interfacial misfit array (IMF) growth mode allowed high-quality structures to be obtained without any surface corrugations for the IR photoconductor's final fabrication [12][13][14].
Sets I and II differ in the superlattice period and include samples with and without beryllium (Be) doping marked, respectively (superscripts: "+"; "−"), as shown in Table 1.The Be doping was used to increase the final device sheet resistance, and it is not a focus of this research.The Be doping is used to reach the HOT condition for the LWIR detectors-that is why Be-p-type doping was implemented.Auger generation recombination rates are strongly dependent on temperature via the dependence of carrier concentration and intrinsic times on temperature.Therefore, cooling is one of the effective ways to suppress Auger processes.Since intrinsic τA7 is larger than intrinsic τA1, Auger processes can be minimized also by optimized p-type doping.An optimized p-type significantly improves the performance, compared with that of an undoped material, but excessive doping lowers the device's performance [15].In the real T2SL, it is hard to obtain defect-free interfaces, especially when a thin InAsSb layer is utilized.This requires growth interruptions and necessitates soaking time between each layer.Moreover, the potential composition changes at the interfaces are hard to predict.These interface issues are directly responsible for discrepancies between a theoretical computer simulation of band structure and experimental results.In this study, we show that the MBE growth temperature can indirectly affect the detector's spectral response, just as a thicker SL period or higher Sb composition results in a redshift of λ 50%cut-off InAs/InAsSb T2SLs, which gives flexibility in detector's designing procedure without influencing any SL structural parameters.In this paper, a series of T2SL InAs/InAsSb detectors optimized for the LWIR range were investigated with a particular focus on the growth temperature, in order to show the cut-off wavelength range tunning for LWIR.

Material Growth Procedure
Each T2SL InAs/InAsSb structure was grown in a RIBER Compact 21-DZ solid source MBE system, on 2" semi-insulating GaA (001) substrates.The substrate temperature during the growth was monitored by a manipulator thermocouple.The substrate temperature was the only parameter being changed intentionally during the growth campaigns.A detailed description of the buffer layer growth and substrate preparation procedure can be found elsewhere [9].The T2SLs growth conditions and parameters were adapted after Lee et al. and Sarney et al. [10,11].The GaA substrates were used to implement low-cost substrates in the mass fabrication of the backside-illuminated devices.Two sets of samples were prepared.The T2SL growth parameters are presented in Table 1.The approx.300 periods (P) T2SLs InAs/InAsSb were grown on 250 nm GaAs smoothing layer, followed by 1.2 µm thick GaSb buffer on the GaAs substrates.The 1.2 µm thick buffer connected with interfacial misfit array (IMF) growth mode allowed high-quality structures to be obtained without any surface corrugations for the IR photoconductor's final fabrication [12][13][14].
Sets I and II differ in the superlattice period and include samples with and without beryllium (Be) doping marked, respectively (superscripts: "+"; "−"), as shown in Table 1.The Be doping was used to increase the final device sheet resistance, and it is not a focus of this research.The Be doping is used to reach the HOT condition for the LWIR detectors-that is why Be-p-type doping was implemented.Auger generation recombination rates are strongly dependent on temperature via the dependence of carrier concentration and intrinsic times on temperature.Therefore, cooling is one of the effective ways to suppress Auger processes.Since intrinsic τ A7 is larger than intrinsic τ A1, Auger processes can be minimized also by optimized p-type doping.An optimized p-type significantly improves the performance, compared with that of an undoped material, but excessive doping lowers the device's performance [15].Table 1.MBE growth temperatures, analyzed T2SL structure properties (period, Sb composition), T2SLs' active layer thickness, and measured λ 50%cut-off at 210, 230 K, FWHM for 0 th -order HRXRD peaks of theT2SLs/GaSb and lattice mismatch ∆a/a GaAs-0 th /GaSb.No Be "−" no Be doping; "+" Be doping.
High-resolution X-ray diffraction (PANalytical X'Pert-HRXRD) was utilized to assess the structural properties of the T2SLs InAs/InAsSb.The MBE growth temperature is presented as a variation from a nominal value ~425 • C.This is motivated by the general problem of the temperature representation in the MBE chamber.There are three dominant methods of temperature measurements: pyrometer, thermocouple of the manipulator (used here), or the BadniT system.Each method exhibits its own limitation, and the combination of at least two was used in the early stage for the growth condition optimization.The value ~425 • C represents optimal growth parameters in our MBE chamber, which included the type of manipulator, substrate, and molybdenum block thicknesses or molecular beams.
Figure 2 presents the HRXRD spectra for the samples given in Table 1.The full-width at half-maximum (FWHM) values of the 0 th /GaSb-order HRXRD peaks of the analyzed T2SL samples should be considered indicators of the grown T2SLs material quality and are presented in Table 1.
The samples were optimized in terms of the material used during the MBE growth procedure and lattice-matched condition to GaSb buffer, which was confirmed by ∆a/a GaAs-0 th /GaSb, assuming 7.274% (average) for Set I and 7.273% for Set II samples, respectively.For Set I samples, the material quality improved as the substrate temperature decreased from 450 • C to 400 • C, and the lowest FWHMs were observed for the samples grown at 400 • C. For SET II, this behavior was not observed, and the highest FWHM corresponded to the longest λ 50%cut-off (18 µm and 16 µm) and highest values of ∆a/a GaAs-0 th /GaSb (7.312% and 7.278%).That is related to the non-intentional period and Sb composition distribution, which was also confirmed by the T2SLs' high-order peak shift.
Samples were grown in different periods of time (all within three months of one another), with proper reproducibility.The 66.05 • (in average) peak represents GaAs substrate, as presented in Figure 2a-d.
It must be stressed that the FWHM of the ~5 µm GaSb buffer layer grown on GaAs substrate changed from 120 arcsec to 130 arcsec, respectively.In our case, with the 1.2 µm GaSb buffer, the FWHM of the GaSb layer grown on GaAs substrate read ~200 arcsec [13].It must be underlined that even if the intensity of T2SL InAs/InAsSb was much higher than from GaSb, the FWHM of the 0 th peak was dominated by the GaSb buffer layer.
It must be underlined that even if the intensity of T2SL InAs/InAsSb was much higher than from GaSb, the FWHM of the 0 th peak was dominated by the GaSb buffer layer.
T2SLs InAs/InAsSb period and Sb composition values were simulated by PANalytical software, and their data are presented in Table 1.For the simulation, sharp interfaces between InAs/InAsSb were assumed.In addition, the magnified 0 th /GaSb HRXRD spectra for samples 4, 5, 6 (FWHM 236, 200, 180 arcsec) are presented in Figure 3.It must be stressed that an average (for samples 4, 5, 6) ∆a/a GaAs-0 th /GaSb was 7.271%.T2SLs InAs/InAsSb period and Sb composition values were simulated by PANalytical software, and their data are presented in Table 1.For the simulation, sharp interfaces between InAs/InAsSb were assumed.
than from GaSb, the FWHM of the 0 peak was dominated by the GaSb buffer layer.
T2SLs InAs/InAsSb period and Sb composition values were simulated by PANalyti cal software, and their data are presented in Table 1.For the simulation, sharp interface between InAs/InAsSb were assumed.In addition, the magnified 0 th /GaSb HRXRD spectra for samples 4, 5, 6 (FWHM 236 200, 180 arcsec) are presented in Figure 3.It must be stressed that an average (for sample 4, 5, 6) ∆a/a GaAs-0 th /GaSb was 7.271%.

Optical Characterization
The photoconductors structures of the grown T2SLs InAs/InAsSb were processed with standard photolithography technique and wet etching.The intent T2SLs active layer thickness (l) was assumed at the level of 3 µm (Table 1).For Set 1, the number of periods (intentional number) was assumed at the level of 317.For Set 2 (intentional number), the number of periods was assumed at the level of 288.Period (P) and Sb composition were estimated based on XRD simulation.As presented in Table 1, thickness l varies within the range of 2.95-3.04µm.
The spectral characteristics were presented by normalized responsivities (R in ) according to the following relation: where η is the quantum efficiency, q is the electron charge, l is the length between contacts, E is the electric field, and µ e is the electron mobility.R in enables the determination of responsivity (R i ) normalized versus electric field and device length.The spectrophotometer's incident beam (which was used in experiments) illuminated all active areas of the photoconductor with the same incident power density.That minimized the device's geometry contribution to the R in .
Figures 4 and 5 show the spectral characteristic versus temperature and wavelength (λ), respectively.λ 50%cut-off correlated strongly versus growth temperature, with a marked redshift at 400 • C and blueshift at 450 • C. In addition to the blueshift, Set I samples grown at 450 • C showed broadening due to higher-order satellite peaks.Only Set I samples 1, 2, and 3 (Figure 4a) did not follow the trend in terms of the λ 50%cut-off versus T growth .

Optical Characterization
The photoconductors structures of the grown T2SLs InAs/InAsSb were processed with standard photolithography technique and wet etching.The intent T2SLs active layer thickness (l) was assumed at the level of 3 μm (Table 1).For Set 1, the number of periods (intentional number) was assumed at the level of 317.For Set 2 (intentional number), the number of periods was assumed at the level of 288.Period (P) and Sb composition were estimated based on XRD simulation.As presented in Table 1, thickness l varies within the range of 2.95-3.04μm.
The spectral characteristics were presented by normalized responsivities (Rin) according to the following relation: , where η is the quantum efficiency, q is the electron charge, l is the length between contacts, E is the electric field, and µe is the electron mobility.Rin enables the determination of responsivity (Ri) normalized versus electric field and device length.The spectrophotometer's incident beam (which was used in experiments) illuminated all active areas of the photoconductor with the same incident power density.That minimized the device's geometry contribution to the Rin.
Figures 4 and 5 show the spectral characteristic versus temperature and wavelength (λ), respectively.λ50%cut-off correlated strongly versus growth temperature, with a marked redshift at 400 °C and blueshift at 450 °C.In addition to the blueshift, Set I samples grown at 450 °C showed broadening due to higher-order satellite peaks.Only Set I samples 1, 2, and 3 (Figure 4a) did not follow the trend in terms of the λ50%cut-off versus Tgrowth.Investigation of the observed behavior was more complicated.The T2SLs InAs/InAsSb energy bandgap (Eg) is defined as a distance between valence and conduction minibands.The main factors contributing to the location of minibands are strain, InAsSb Sb composition (xSb), and T2SLs period (P) [16][17][18].
According to the measured structure properties, variations in the T2SLs period and Sb composition were small within each sample and assumed negligible in our analysis.The only interfaces regions within T2SLs InAs/InAsSb could affect the location of minibands.At the interfaces between InAs and InAsSb, the strain could be changed due to InAsSb Sb composition distribution within InAsSb and InAs layers, which will be discussed later.
Our research identified only two papers on the growth temperature influence on the T2SLs cut-off wavelength.Liu et al. changed the Tgrowth of T2SLs InAs/InAsSb from 400 °C to 450 C. Unfortunately, the presented samples prepared for each temperature also differed in period and xSb, and no direct comparison was possible [19].The Sb cross-incorporation into InAs layers was observed but also not explained.
The same situation could be found in a paper by Haugan et al. [20].The samples were grown in selected temperatures without compensation of the As and Sb beams.The higher growth temperature lowers Sb composition in the InAsSb layer and changes the T2SL InAs/InAsSb bandgap.The detailed investigation of epitaxial T2SL InAs/InAsSb was carried out first by Wood et al. and later by Kim et al. [21,22].In both papers, the authors measured interfaces of the same sample by scanning tunneling microscope (STM) and scanning transmission electron microscope (STEM), respectively.Wood et al. provided information on the interfaces inside the structure, where Sb segregation was observed and fitted to a standard segregation model formulated by Muraki et al. [23].
The newest results shown by Kotulak et al. indicate that the Sb in some circumstances (such as thin InAs layers) could be observed in all InAs regions, which contradicts the common As-to-Sb atom exchange at the interfaces [24].The T2SLs presented by Kotulak et al. were fully Sb dispersed.
The preliminary theoretical calculations of Sb distribution in the InAsSb layer were presented by Lu et al. [25].One of the important observations that could explain our results is that variation in Sb profiles results in blue-and redshifts and must be taken into consideration during bandgap engineering.Based on the observed changes in spectral Investigation of the observed behavior was more complicated.The T2SLs InAs/InAsSb energy bandgap (E g ) is defined as a distance between valence and conduction minibands.The main factors contributing to the location of minibands are strain, InAsSb Sb composition (x Sb ), and T2SLs period (P) [16][17][18].
According to the measured structure properties, variations in the T2SLs period and Sb composition were small within each sample and assumed negligible in our analysis.The only interfaces regions within T2SLs InAs/InAsSb could affect the location of minibands.At the interfaces between InAs and InAsSb, the strain could be changed due to InAsSb Sb composition distribution within InAsSb and InAs layers, which will be discussed later.
Our research identified only two papers on the growth temperature influence on the T2SLs cut-off wavelength.Liu et al. changed the T growth of T2SLs InAs/InAsSb from 400 • C to 450 • C. Unfortunately, the presented samples prepared for each temperature also differed in period and x Sb , and no direct comparison was possible [19].The Sb cross-incorporation into InAs layers was observed but also not explained.
The same situation could be found in a paper by Haugan et al. [20].The samples were grown in selected temperatures without compensation of the As and Sb beams.The higher growth temperature lowers Sb composition in the InAsSb layer and changes the T2SL InAs/InAsSb bandgap.The detailed investigation of epitaxial T2SL InAs/InAsSb was carried out first by Wood et al. and later by Kim et al. [21,22].In both papers, the authors measured interfaces of the same sample by scanning tunneling microscope (STM) and scanning transmission electron microscope (STEM), respectively.Wood et al. provided information on the interfaces inside the structure, where Sb segregation was observed and fitted to a standard segregation model formulated by Muraki et al. [23].
The newest results shown by Kotulak et al. indicate that the Sb in some circumstances (such as thin InAs layers) could be observed in all InAs regions, which contradicts the common As-to-Sb atom exchange at the interfaces [24].The T2SLs presented by Kotulak et al. were fully Sb dispersed.
The preliminary theoretical calculations of Sb distribution in the InAsSb layer were presented by Lu et al. [25].One of the important observations that could explain our results is that variation in Sb profiles results in blue-and redshifts and must be taken into consideration during bandgap engineering.Based on the observed changes in spectral characteristics, we believe that the distribution of Sb generally in InAsSb or even in the InAs layer can affect the strain, which could result in the observed bandgap variations, contributing to the cut-off wavelength changes assuming constant T2SLs Sb composition and period [24].These results have been assessed theoretically in analyses presented by Lu et al. and Ciani et al. [25,26].
Given the necessity of soaking time at the InAs/InAsSb interfaces, the exchange reaction between As and Sb molecules on the surface is inevitable, and the assumption of abrupt interfaces in the T2SLs InAs/InAsSb theoretical simulations can lead to unrealistic results.Our results showed that T growth is probably the main parameter influencing and modifying the Sb distribution at interfaces (or in all layers) in T2SLs InAs/InAsSb.

Discussion
As mentioned, the Sb distribution in InAsSb or even in the InAs layer can affect the strain, which could result in the observed energy bandgap changes versus T growth .In order to present the Sb distribution in the InAsSb layer in the Set I samples 4, 5, and 6, Muraki's model was incorporated [23].In this model, the Sb background (x b ) should be determined, and the R parameter corresponds to the rate of the As-Sb exchange in InAsSb.Knowing the T2SL period (P = 9.4 nm) and intended Sb profile (x Sb = 0.39), one can simulate the Sb distribution profile (z-direction) according to the following relations: For the Set I samples 4, 5, and 6, we made the following assumptions related to Muraki's model characteristic parameters versus growth temperature presented in Table 2.The SIMS measurements show the Sb background composition at the level of ~5% [9].The 3% Sb background, R = 0.7 (for the comparable growth temperature, T growth = 420 • C) contributing to the similar Sb distribution in T2SLs InAs/InAsSb were reported by Kim et al. [22].The InAsSb thickness (N) for which maximum Sb composition occurred was assumed at the level of 2 nm, assuming nominal InAsSb thickness 2.49 nm, similarly to the Sb composition distribution presented by Kim et al. [22].
When we increased the T growth , the R parameter increased, which could result in higher Sb background composition (that is marked by arrows).Figure 6 presents the Sb composition distribution within the InAsSb layer (2.49 nm).We assumed the following R parameters for the Set I samples 4, 5, and 6: R = 0.9/0.7/0.4 and R = 0.8/0.7/0.6;these values correspond to the T growth to present the 1D in-plane strain ε I I = (a f − a GaSb /a GaSb ) distribution within InAsSb (out-of-plane strain could be calculated by the equation ε ⊥ = −2C 12 /C 11 for (001) GaA substrates).The InAsSb layer was in compression in relation to the GaSb buffer layer for in-plane and in tensile for out-of-plane direction.It must be stressed that an average (for samples 4, 5, 6) ∆a/a GaAs-0 th /GaSb was assumed as 7.271%.As presented in Figure 6a-d, a decrease in the exchange rate R parameter lowered Sb composition distribution and strain within the InAsSb layer in relation to GaSb.As mentioned above, the segregation efficiency R increases with growth temperature, as expected, the results of which are presented in Figure 6   The measured 100% cut-off wavelengths (λ100%cut-off) for Set I samples 4, 5, and 6 read ~9.4 μm (450 °C), ~11.5 μm (425 °C), and ~12.8 μm (400 °C) (Figure 7).We calculated the energy bandgap dependence versus strain in T2SLs InAs/InAsSb (samples 4, 5, and 6) based on an 8 × 8 kp solver.The results are presented in Figure 8.The measured 100% cut-off wavelengths (λ100%cut-off) for Set I samples 4, 5, and 6 read ~9.4 μm (450 °C), ~11.5 μm (425 °C), and ~12.8 μm (400 °C) (Figure 7).We calculated the energy bandgap dependence versus strain in T2SLs InAs/InAsSb (samples 4, 5, and 6) based on an 8 × 8 kp solver.The results are presented in Figure 8.We calculated the energy bandgap dependence versus strain in T2SLs InAs/InAsSb (samples 4, 5, and 6) based on an 8 × 8 kp solver.The results are presented in Figure 8. Assuming average strain 1.27%, 0.6%, and 0.05% (Figure 6), our simulation results read the following measurements: Appl.Sci.2022, 12, x FOR PEER REVIEW Assuming average strain 1.27%, 0.6%, and 0.05% (Figure 6), our simulation the following measurements:  The presented theoretical energy bandgap and λ100%cut-off trends versus Tgr the experimental results.The discrepancy is believed to be connected to the a rupt interfaces in the T2SLs InAs/InAsSb.In addition, assuming strain-bala tions, the Sb composition drop increased the effective T2SLs InAs/InA bandgap, which was also presented previously by Steenbergen et al. [28,29].tion results also followed the trend presented by Ting et al. for the T2 InAs/InAs0.6Sb0.4[30].According to the Sb composition distribution presented the average Sb composition distribution decreases with an increase in the R p addition, it must be stressed that we made a theoretical assumption on strain in the InAsSb layer (similar distribution was presented by Kim et al. [22]).In is revealed from data presented in Figure 6a-d that Sb distribution created ex the InAs layer.

Conclusions
We presented observations of strain modification in T2SLs InAs/InAsSb by Tgrowth within 400-450 °C (optimal 425 °C) and presented the results of chang bandgap, contributing to the changes in spectral responses.The growth tem believed to impact the Sb distribution at the interfaces, and an increase in T blueshift of the λ50%cut-off.It was shown that the Tgrowth could be used to tune th wavelength in LWIR range (e.g., temperature growth change within the range contributed to the λ50%cut-off ~ 11.6-8.3μm, estimated for operating temperatur while keeping the period and Sb composition constant, which provides much  The presented theoretical energy bandgap and λ 100%cut-off trends versus T growth followed the experimental results.The discrepancy is believed to be connected to the assumed abrupt interfaces in the T2SLs InAs/InAsSb.In addition, assuming strain-balanced conditions, the Sb composition drop increased the effective T2SLs InAs/InAsSb energy bandgap, which was also presented previously by Steenbergen et al. [28,29].Our simulation results also followed the trend presented by Ting et al. for the T2SLs (3n, n) InAs/InAs 0.6 Sb 0.4 [30].According to the Sb composition distribution presented in Figure 6, the average Sb composition distribution decreases with an increase in the R parameter.In addition, it must be stressed that we made a theoretical assumption on strain distribution in the InAsSb layer (similar distribution was presented by Kim et al. [22]).In addition, it is revealed from data presented in Figure 6a-d that Sb distribution created extra strain in the InAs layer.

Conclusions
We presented observations of strain modification in T2SLs InAs/InAsSb introduced by T growth within 400-450 • C (optimal 425 • C) and presented the results of changes in energy bandgap, contributing to the changes in spectral responses.The growth temperature is believed to impact the Sb distribution at the interfaces, and an increase in T growth led to a blueshift of the λ 50%cut-off .It was shown that the T growth could be used to tune the operating wavelength in LWIR range (e.g., temperature growth change within the range 400-450 • C contributed to the λ 50%cut-off ~11.6-8.3 µm, estimated for operating temperature T = 230 K), while keeping the period and Sb composition constant, which provides much more flexibility in the device's design process without affecting T2SLs' structural parameters-Sb composition and period.

Figure 5 .
Figure 5. Spectral response characteristic at 210 K for T2SLs from (a) Set I and (b) Set II. [27].